CN101208448A - 具有良好的耐蚀性的热浸镀Sn-Zn系钢板 - Google Patents
具有良好的耐蚀性的热浸镀Sn-Zn系钢板 Download PDFInfo
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- CN101208448A CN101208448A CNA2006800232144A CN200680023214A CN101208448A CN 101208448 A CN101208448 A CN 101208448A CN A2006800232144 A CNA2006800232144 A CN A2006800232144A CN 200680023214 A CN200680023214 A CN 200680023214A CN 101208448 A CN101208448 A CN 101208448A
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- 229910020994 Sn-Zn Inorganic materials 0.000 title claims abstract description 98
- 229910009069 Sn—Zn Inorganic materials 0.000 title claims abstract description 98
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- 239000000956 alloy Substances 0.000 description 13
- 238000005204 segregation Methods 0.000 description 13
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 11
- 239000000463 material Substances 0.000 description 11
- 229910001030 Iron–nickel alloy Inorganic materials 0.000 description 10
- 239000002585 base Substances 0.000 description 9
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- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 230000033228 biological regulation Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 6
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- 238000002425 crystallisation Methods 0.000 description 4
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- 229910052742 iron Inorganic materials 0.000 description 4
- 150000002815 nickel Chemical class 0.000 description 4
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- 229910020220 Pb—Sn Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
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- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 2
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- PXFBZOLANLWPMH-UHFFFAOYSA-N 16-Epiaffinine Natural products C1C(C2=CC=CC=C2N2)=C2C(=O)CC2C(=CC)CN(C)C1C2CO PXFBZOLANLWPMH-UHFFFAOYSA-N 0.000 description 1
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Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C2/00—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor
- C23C2/04—Hot-dipping or immersion processes for applying the coating material in the molten state without affecting the shape; Apparatus therefor characterised by the coating material
- C23C2/08—Tin or alloys based thereon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/01—Layered products comprising a layer of metal all layers being exclusively metallic
- B32B15/013—Layered products comprising a layer of metal all layers being exclusively metallic one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C13/00—Alloys based on tin
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12708—Sn-base component
- Y10T428/12722—Next to Group VIII metal-base component
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Coating With Molten Metal (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
Description
实施例 | 试样No. | 镀层组成 | 冷却速度(℃/s) | 镀层 | 外表面耐蚀性 | 内表面耐蚀性 | 综合评价 | 备注 | ||||
伴随Sn-Zn共晶熔化的吸热 | 伴随Sn初晶熔化的吸热 | 吸热量比ΔHp/(ΔHp+ΔHe) | 红锈面积率(%) | 金属溶出量(ppm) | ||||||||
吸热温度(℃) | 吸热量ΔHe(J/g) | 吸热温度(℃) | 吸热量ΔHp(J/g) | |||||||||
1 | 1 | Sn-8质量%Zn | 15 | 199 | 0.11 | 211 | 0.47 | 0.81 | 2 | 35 | A | 发明例 |
2 | Sn-8质量%Zn | 25 | 199 | 0.26 | 208 | 0.67 | 0.72 | 5 | 70 | A | 发明例 | |
3 | Sn-8质量%Zn | 35 | 199 | 0.5 | 203 | 0.31 | 0.38 | 8 | 160 | B | 发明例 | |
4 | Sn-4质量%Zn | 15 | 199 | 0.06 | 217 | 0.6 | 0.91 | 7 | 25 | A | 发明例 | |
5 | Sn-2质量%Zn | 15 | 199 | 0.01 | 224 | 0.44 | 0.98 | 9 | 10 | B | 发明例 | |
6 | Sn-0.5质量%Zn | 15 | 199 | 0.005 | 231 | 0.95 | 0.99 | 30 | 40 | C | 比较例 | |
7 | Sn-10质量%Zn | 15 | 199 | 0.15 | - | - | - | 15 | 600 | C | 比较例 | |
8 | Sn-15质量%Zn | 15 | 199 | 0.18 | - | - | - | 12 | 1300 | C | 比较例 | |
2 | 9 | Sn-8质量%Zn | 15 | 199 | 0.14 | 211 | 0.31 | 0.69 | 0 | 15 | A | 发明例 |
实施例 | 试样No. | 镀层组成 | 冷却速度(℃/s) | 镀层 | 外表面耐蚀性 | 内表面耐蚀性 | 综合评价 | 备注 | ||||
伴随Sn-Zn共晶熔化的吸热 | 伴随Sn初晶熔化的吸热 | 吸热量比ΔHp/(ΔHp+ΔHe) | 红锈面积率(%) | 金属溶出量(ppM) | ||||||||
吸热温度(℃) | 吸热量ΔHe(J/g) | 吸热温度(℃) | 吸热量ΔHp(J/g) | |||||||||
3 | 10 | Sn-8质量%Zn | 15 | 199 | 0.98 | 207 | 0.054 | 0.05 | 80 | 1800 | C | 比较例 |
11 | Sn-7质量%Zn | 15 | 199 | 0.89 | 209 | 0.13 | 0.13 | 60 | 900 | C | 比较例 | |
12 | Sn-6质量%Zn | 15 | 199 | 0.78 | 210 | 0.19 | 0.20 | 25 | 400 | C | 比较例 | |
13 | Sn-5质量%Zn | 15 | 199 | 0.71 | 211 | 0.24 | 0.25 | 15 | 150 | C | 比较例 |
试样No. | 预镀Fe-Ni组成 | 镀层组成 | 镀液温度(℃) | 浸镀时间(s) | 冷却速度(℃/s) | 镀层 | 外表面耐蚀性 | 内表面耐蚀性 | 综合评价 | 备注 | ||||
伴随Sn-Zn共晶熔化的吸热 | 伴随Sn初晶熔化的吸热 | 吸热量比ΔHp/(ΔHp+ΔHe) | 红锈面积率(%) | 金属溶出量(ppm) | ||||||||||
吸热温度(℃) | 吸热量ΔHe(J/g) | 吸热温度(℃) | 吸热量ΔHp(J/g) | |||||||||||
14 | Fe-5质量%Ni | Sn-8质量%Zn | 300 | 5 | 15 | 199 | 0.24 | 208 | 0.1 | 0.29 | 11 | 180 | B | 比较例 |
15 | Fe-10质量%Ni | Sn-8质量%Zn | 300 | 5 | 15 | 199 | 0.18 | 208 | 0.32 | 0.64 | 8 | 90 | A | 发明例 |
16 | Fe-20质量%Ni | Sn-8质量%Zn | 300 | 5 | 15 | 199 | 0.11 | 211 | 0.47 | 0.81 | 1.5 | 25 | A | 发明例 |
17 | Fe-40质量%Ni | Sn-8质量%Zn | 300 | 5 | 15 | 199 | 0.13 | 211 | 0.42 | 0.76 | 3 | 40 | A | 发明例 |
18 | Fe-60质量%Ni | Sn-8质量%Zn | 300 | 5 | 15 | 199 | 0.34 | 210 | 0.4 | 0.54 | 5 | 50 | A | 发明例 |
19 | Fe-80质量%Ni | Sn-8质量%Zn | 300 | 5 | 15 | 199 | 0.41 | 210 | 0.25 | 0.38 | 8 | 90 | A | 发明例 |
20 | Fe-90质量%Ni | Sn-8质量%Zn | 300 | 5 | 15 | 199 | 0.24 | 209 | 0.08 | 0.25 | 25 | 450 | C | 比较例 |
21 | Fe-20质量%Ni | Sn-0.5质量%Zn | 300 | 5 | 15 | 199 | 0.01 | 231 | 0.95 | 0.99 | 30 | 40 | C | 比较例 |
22 | Fe-20质量%Ni | Sn-2质量%Zn | 300 | 5 | 15 | 198 | 0.01 | 224 | 0.44 | 0.98 | 12 | 10 | B | 发明例 |
23 | Fe-20质量%Ni | Sn-4质量%Zn | 300 | 5 | 15 | 199 | 0.06 | 217 | 0.6 | 0.91 | 7 | 25 | A | 发明例 |
试样No. | 预镀Fe-Ni组成 | 镀层组成 | 镀液温度(℃) | 浸镀时间(s) | 冷却速度(℃/s) | 镀层 | 外表面耐蚀性 | 内表面耐蚀性 | 综合评价 | 备注 | ||||
伴随Sn-Zn共晶熔化的吸热 | 伴随Sn初晶熔化的吸热 | 吸热量比ΔHp/(ΔHp+ΔHe) | 红锈面积率(%) | 金属溶出量(ppm) | ||||||||||
吸热温度(℃) | 吸热量ΔHe(J/g) | 吸热温度(℃) | 吸热量ΔHp(J/g) | |||||||||||
24 | Fe-20质量%Ni | Sn-10质量%Zn | 300 | 5 | 15 | 199 | 0.12 | - | - | - | 15 | 600 | C | 比较例 |
25 | Fe-20质量%Ni | Sn-8质量%Zn | 250 | 5 | 15 | 199 | 0.11 | 212 | 0.47 | 0.81 | 2 | 35 | A | 发明例 |
26 | Fe-20质量%Ni | Sn-8质量%Zn | 350 | 5 | 15 | 199 | 0.11 | 211 | 0.48 | 0.82 | 2 | 40 | A | 发明例 |
27 | Fe-20质量%Ni | Sn-8质量%Zn | 400 | 5 | 15 | 199 | 0.09 | 210 | 0.46 | 0.83 | 3 | 55 | A | 发明例 |
28 | Fe-20质量%Ni | Sn-8质量%Zn | 300 | 2 | 15 | 199 | 0.10 | 210 | 0.47 | 0.82 | 2 | 25 | A | 发明例 |
29 | Fe-20质量%Ni | Sn-8质量%Zn | 300 | 10 | 15 | 199 | 0.11 | 211 | 0.45 | 0.81 | 4 | 45 | A | 发明例 |
30 | Fe-20质量%Ni | Sn-8质量%Zn | 300 | 15 | 15 | 199 | 0.11 | 211 | 0.43 | 0.8 | 2 | 35 | A | 发明例 |
31 | Fe-20质量%Ni | Sn-8质量%Zn | 300 | 20 | 15 | 199 | 0.11 | 211 | 0.47 | 0.81 | 2 | 35 | A | 发明例 |
32 | Fe-20质量%Ni | Sn-8质量%Zn | 300 | 5 | 25 | 199 | 0.26 | 208 | 0.67 | 0.72 | 5 | 70 | A | 发明例 |
33 | Fe-20质量%Ni | Sn-8质量%Zn | 300 | 5 | 30 | 199 | 0.51 | 203 | 0.31 | 0.38 | 9 | 140 | B | 发明例 |
Claims (2)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP196192/2005 | 2005-07-05 | ||
JP2005196192 | 2005-07-05 | ||
PCT/JP2006/313394 WO2007004671A1 (ja) | 2005-07-05 | 2006-07-05 | 良好な耐食性を有する溶融Sn-Zn系めっき鋼板 |
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CN101208448A true CN101208448A (zh) | 2008-06-25 |
CN101208448B CN101208448B (zh) | 2010-12-08 |
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CN2006800232144A Expired - Fee Related CN101208448B (zh) | 2005-07-05 | 2006-07-05 | 热浸镀Sn-Zn系钢板 |
Country Status (9)
Country | Link |
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US (2) | US20090047542A1 (zh) |
EP (1) | EP1905859B1 (zh) |
JP (2) | JPWO2007004671A1 (zh) |
KR (2) | KR101085290B1 (zh) |
CN (1) | CN101208448B (zh) |
BR (1) | BRPI0612003B1 (zh) |
CA (1) | CA2611439C (zh) |
RU (1) | RU2387735C2 (zh) |
WO (1) | WO2007004671A1 (zh) |
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CN102828127A (zh) * | 2011-06-14 | 2012-12-19 | 鞍钢股份有限公司 | 一种耐蚀性好的热浸镀锡锌燃油箱高强钢板及其制造方法 |
CN103831543A (zh) * | 2012-11-23 | 2014-06-04 | 吴永恒 | 无铅焊接材料及其制备方法 |
CN104723613A (zh) * | 2013-12-19 | 2015-06-24 | 现代自动车株式会社 | 含有表面处理层的接地螺栓和接地螺栓的表面处理方法 |
CN111989419A (zh) * | 2018-04-26 | 2020-11-24 | 日本制铁株式会社 | 热浸镀Sn-Zn系合金镀层钢板及其制造方法 |
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KR101070061B1 (ko) * | 2006-03-20 | 2011-10-04 | 신닛뽄세이테쯔 카부시키카이샤 | 고내식성 용융 Zn계 도금 강재 |
JP5035610B2 (ja) * | 2007-07-02 | 2012-09-26 | オリオン機械株式会社 | オイルミスト濃度測定方法およびオイルミスト濃度測定装置 |
JP5055504B2 (ja) * | 2007-07-02 | 2012-10-24 | オリオン機械株式会社 | オイルミスト濃度測定装置 |
JP5428571B2 (ja) * | 2009-06-24 | 2014-02-26 | 新日鐵住金株式会社 | 車両用の燃料タンク |
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2006
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- 2006-07-05 RU RU2007149548/02A patent/RU2387735C2/ru not_active IP Right Cessation
- 2006-07-05 KR KR1020107024788A patent/KR101085290B1/ko active IP Right Grant
- 2006-07-05 CN CN2006800232144A patent/CN101208448B/zh not_active Expired - Fee Related
- 2006-07-05 KR KR1020087000004A patent/KR20080019265A/ko not_active Application Discontinuation
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- 2006-07-05 WO PCT/JP2006/313394 patent/WO2007004671A1/ja active Application Filing
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CN102400076A (zh) * | 2010-09-07 | 2012-04-04 | 鞍钢股份有限公司 | 一种燃油箱用热浸镀锡锌合金钢板及其制造方法 |
CN102400076B (zh) * | 2010-09-07 | 2014-03-12 | 鞍钢股份有限公司 | 一种燃油箱用热浸镀锡锌合金钢板及其制造方法 |
CN102828127A (zh) * | 2011-06-14 | 2012-12-19 | 鞍钢股份有限公司 | 一种耐蚀性好的热浸镀锡锌燃油箱高强钢板及其制造方法 |
CN102828127B (zh) * | 2011-06-14 | 2014-12-31 | 鞍钢股份有限公司 | 一种耐蚀性好的热浸镀锡锌燃油箱高强钢板及其制造方法 |
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Also Published As
Publication number | Publication date |
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BRPI0612003B1 (pt) | 2020-11-03 |
EP1905859A1 (en) | 2008-04-02 |
KR20100123781A (ko) | 2010-11-24 |
EP1905859B1 (en) | 2012-04-18 |
KR101085290B1 (ko) | 2011-11-22 |
RU2387735C2 (ru) | 2010-04-27 |
CN101208448B (zh) | 2010-12-08 |
US20090047542A1 (en) | 2009-02-19 |
BRPI0612003A2 (pt) | 2010-10-13 |
RU2007149548A (ru) | 2009-07-10 |
BRPI0612003A8 (pt) | 2020-05-05 |
CA2611439C (en) | 2011-01-04 |
JPWO2007004671A1 (ja) | 2009-01-29 |
JP2012001818A (ja) | 2012-01-05 |
WO2007004671A1 (ja) | 2007-01-11 |
US7981463B2 (en) | 2011-07-19 |
EP1905859A4 (en) | 2010-02-24 |
US20100151117A1 (en) | 2010-06-17 |
CA2611439A1 (en) | 2007-01-11 |
KR20080019265A (ko) | 2008-03-03 |
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