CN101076551B - 磺化多嵌段共聚物以及使用该共聚物的电解质膜 - Google Patents

磺化多嵌段共聚物以及使用该共聚物的电解质膜 Download PDF

Info

Publication number
CN101076551B
CN101076551B CN2005800424506A CN200580042450A CN101076551B CN 101076551 B CN101076551 B CN 101076551B CN 2005800424506 A CN2005800424506 A CN 2005800424506A CN 200580042450 A CN200580042450 A CN 200580042450A CN 101076551 B CN101076551 B CN 101076551B
Authority
CN
China
Prior art keywords
chemical formula
block
group
unit represented
block copolymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CN2005800424506A
Other languages
English (en)
Chinese (zh)
Other versions
CN101076551A (zh
Inventor
张宰赫
太泳智
申程圭
李奉根
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
LG Chem Ltd
Original Assignee
LG Chem Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by LG Chem Ltd filed Critical LG Chem Ltd
Publication of CN101076551A publication Critical patent/CN101076551A/zh
Application granted granted Critical
Publication of CN101076551B publication Critical patent/CN101076551B/zh
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
    • C08G65/4056—(I) or (II) containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/48—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2371/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08J2371/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08J2371/12—Polyphenylene oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Graft Or Block Polymers (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Polyethers (AREA)
CN2005800424506A 2004-12-14 2005-12-14 磺化多嵌段共聚物以及使用该共聚物的电解质膜 Expired - Lifetime CN101076551B (zh)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
KR10-2004-0105493 2004-12-14
KR1020040105493 2004-12-14
KR20040105493 2004-12-14
PCT/KR2005/004291 WO2006065068A1 (en) 2004-12-14 2005-12-14 Sulphonated multiblock copolymer and electrolyte membrane using the same

Publications (2)

Publication Number Publication Date
CN101076551A CN101076551A (zh) 2007-11-21
CN101076551B true CN101076551B (zh) 2010-06-02

Family

ID=36588089

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2005800424506A Expired - Lifetime CN101076551B (zh) 2004-12-14 2005-12-14 磺化多嵌段共聚物以及使用该共聚物的电解质膜

Country Status (7)

Country Link
US (1) US7601785B2 (enExample)
EP (1) EP1828284B1 (enExample)
JP (1) JP2008521999A (enExample)
KR (1) KR100756821B1 (enExample)
CN (1) CN101076551B (enExample)
TW (1) TWI294432B (enExample)
WO (1) WO2006065068A1 (enExample)

Families Citing this family (27)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI326691B (en) 2005-07-22 2010-07-01 Kraton Polymers Res Bv Sulfonated block copolymers, method for making same, and various uses for such block copolymers
US20080004443A1 (en) * 2006-07-03 2008-01-03 General Electric Company Sulfonated polyaryletherketone-block-polyethersulfone copolymers
US20080231712A1 (en) * 2007-03-22 2008-09-25 Property Monitors, Inc. Portable video acquisition and internet broadcast system
KR100843569B1 (ko) * 2007-06-26 2008-07-03 연세대학교 산학협력단 수소이온 전도성 복합 트리블록 공중합체 전해질막 및 그제조방법
JP2009091568A (ja) * 2007-09-20 2009-04-30 Sumitomo Chemical Co Ltd 高分子電解質組成物
US8440365B2 (en) * 2008-01-08 2013-05-14 Kabushiki Kaisha Toyota Chuo Kenkyusho Electrolyte, production process therefor, electrolyte membrane, production process therefor, catalyst layer and fuel cell
US8012539B2 (en) 2008-05-09 2011-09-06 Kraton Polymers U.S. Llc Method for making sulfonated block copolymers, method for making membranes from such block copolymers and membrane structures
US8574664B2 (en) * 2008-09-02 2013-11-05 General Electric Company Electrolyte membrane, methods of manufacture thereof and articles comprising the same
US8461287B2 (en) 2008-11-04 2013-06-11 Lg Chem, Ltd. Polymer electrolyte membrane
JP5590568B2 (ja) * 2009-03-27 2014-09-17 国立大学法人山梨大学 ブロック共重合体、およびその利用
CN101531759B (zh) * 2009-04-17 2011-03-30 南京林业大学 冰片烯聚砜树脂的制备方法
US8445631B2 (en) 2009-10-13 2013-05-21 Kraton Polymers U.S. Llc Metal-neutralized sulfonated block copolymers, process for making them and their use
US8263713B2 (en) 2009-10-13 2012-09-11 Kraton Polymers U.S. Llc Amine neutralized sulfonated block copolymers and method for making same
US9394414B2 (en) 2010-09-29 2016-07-19 Kraton Polymers U.S. Llc Elastic, moisture-vapor permeable films, their preparation and their use
US9429366B2 (en) 2010-09-29 2016-08-30 Kraton Polymers U.S. Llc Energy recovery ventilation sulfonated block copolymer laminate membrane
BR112013007705A2 (pt) 2010-10-18 2016-08-09 Kraton Polymers Us Llc solução tendo uma composição de copolímero em bloco sulfonado, película ou membrana, dispersão aquosa, compósito, composição de copolímeto em bloco sulfonado, processo, método para formar uma composição de copolímero em bloco sulfonado, e, célula eletrodialítica
US9861941B2 (en) 2011-07-12 2018-01-09 Kraton Polymers U.S. Llc Modified sulfonated block copolymers and the preparation thereof
EP2554564A1 (de) * 2011-08-05 2013-02-06 Basf Se Verfahren zur Herstellung eines Blockcopolymers
US8952109B2 (en) * 2011-08-05 2015-02-10 Basf Se Process for preparing a block copolymer
TWI452063B (zh) * 2012-03-29 2014-09-11 Univ Nat Sun Yat Sen 磺酸化聚芳香醚高分子及其製造方法
KR101627930B1 (ko) * 2013-09-16 2016-06-07 주식회사 엘지화학 이온 교환성 고분자 층을 포함하는 수처리 분리막 및 그 제조 방법
US9533254B2 (en) * 2013-11-01 2017-01-03 Virginia Tech Intellectual Properties, Inc. Crosslinked polymer compositions, gas separation membranes of such crosslinked polymer compositions, methods of making such membranes, and methods of separating gases using such membranes
KR101771323B1 (ko) * 2014-10-28 2017-08-24 주식회사 엘지화학 브랜처용 불소계 화합물, 이를 이용한 고분자 및 이를 이용한 고분자 전해질막
EP3212693B1 (en) * 2014-10-31 2020-12-09 Basf Se Copolymers for making membranes
EP3228642B1 (en) * 2014-12-02 2019-02-13 LG Chem, Ltd. Polymer, method for manufacturing same, and electrolyte membrane comprising same
KR102068872B1 (ko) * 2015-09-22 2020-01-21 주식회사 엘지화학 블록 중합체 및 이를 포함하는 고분자 전해질막
CN116997595A (zh) * 2021-03-23 2023-11-03 东丽株式会社 嵌段共聚物和其制造方法、高分子电解质材料、高分子电解质成型体、高分子电解质膜、带催化剂层的电解质膜、膜电极复合体、固体高分子型燃料电池以及水电解式氢气产生装置

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1394889A (zh) * 2001-07-03 2003-02-05 住友化学工业株式会社 聚合物电解质膜和燃料电池
US6586561B1 (en) * 1999-02-18 2003-07-01 Case Western Reserve University Rigid rod ion conducting copolymers
CN1490345A (zh) * 2002-07-06 2004-04-21 三星Sdi株式会社 质子导电聚合物及其制法，用该聚合物的膜，和用该膜的燃料电池

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4625000A (en) 1985-06-12 1986-11-25 Union Carbide Corporation Process for preparing sulfonated poly(aryl ether) resins
JP4802354B2 (ja) 1999-12-27 2011-10-26 住友化学株式会社 高分子電解質およびその製造方法
JP3820888B2 (ja) 2001-01-31 2006-09-13 Ｊｓｒ株式会社 スルホン酸基を有するポリエーテル系共重合体およびプロトン伝導膜
KR100408877B1 (ko) 2001-02-09 2003-12-18 이무성 불소화, 술폰화에 의한 스티렌-디엔계 공중합체와 그제조방법 및 이 공중합체를 이용한 연료전지용 고분자전해질막
KR20020076825A (ko) 2001-03-30 2002-10-11 대주정밀화학 주식회사 직접메탄올 연료전지용 이온교환막
JP3599041B2 (ja) 2001-05-08 2004-12-08 宇部興産株式会社 固体高分子型燃料電池用高分子電解質及び燃料電池
US7258941B2 (en) * 2001-05-08 2007-08-21 Ube Industries, Ltd. Polymer electrolyte for solid polymer type fuel cell and fuel cell
JP4408599B2 (ja) * 2001-11-16 2010-02-03 東洋紡績株式会社 スルホン酸基含有芳香族ポリアリーレンエーテル化合物および高分子電解質膜
KR100977234B1 (ko) * 2002-05-13 2010-08-23 더 유니버시티 오브 노스 플로리다 보드 오브 트러스티즈 술폰화된 공중합체
DE602004030358D1 (de) * 2003-10-02 2011-01-13 Univ Yamanashi Sulfonierte aromatische polyether, herstellungsverfahren dafür und elektrolytmembranen
KR20060019492A (ko) 2004-08-26 2006-03-03 주식회사 엘지화학 신규한 술폰화 폴리이미드 공중합체 및 이를 이용한전해질막

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6586561B1 (en) * 1999-02-18 2003-07-01 Case Western Reserve University Rigid rod ion conducting copolymers
CN1394889A (zh) * 2001-07-03 2003-02-05 住友化学工业株式会社 聚合物电解质膜和燃料电池
CN1490345A (zh) * 2002-07-06 2004-04-21 三星Sdi株式会社 质子导电聚合物及其制法，用该聚合物的膜，和用该膜的燃料电池

Also Published As

Publication number Publication date
EP1828284A1 (en) 2007-09-05
TW200630404A (en) 2006-09-01
EP1828284B1 (en) 2012-06-13
TWI294432B (en) 2008-03-11
KR20060067844A (ko) 2006-06-20
KR100756821B1 (ko) 2007-09-07
CN101076551A (zh) 2007-11-21
US7601785B2 (en) 2009-10-13
EP1828284A4 (en) 2009-06-10
WO2006065068A1 (en) 2006-06-22
US20060160960A1 (en) 2006-07-20
JP2008521999A (ja) 2008-06-26
WO2006065068A9 (en) 2007-06-07

Similar Documents

Publication Publication Date Title
KR100756821B1 (ko) 술폰화 멀티블록 공중합체 및 이를 이용한 전해질막
TWI406895B (zh) 高分子電解質材料、以及使用它之高分子電解質成型體與它之製法、膜電極複合體及固體高分子型燃料電池
KR100657740B1 (ko) 브랜치된 술폰화 멀티 블록 공중합체 및 이를 이용한전해질막
JP4051736B2 (ja) 高分子電解質、高分子電解質膜、及び燃料電池
JP3724064B2 (ja) 燃料電池用高分子電解質及び燃料電池
JP2003147074A (ja) スルホン酸基含有芳香族ポリアリーレンエーテル化合物および高分子電解質膜
JP2008521999A5 (enExample)
JP5905857B2 (ja) 高分子電解質、高分子電解質膜、燃料電池用触媒層バインダー、およびその利用
CN102086265B (zh) 磺化聚(芳醚)共聚物及相关聚合物电解质膜和燃料电池
KR20060115886A (ko) 양자 교환 멤브레인용의 친수성-소수성 부분을 함유하는다중블록 공중합체
CN102807668A (zh) 聚亚芳基类聚合物、该聚合物的制备方法、以及使用该聚合物的燃料电池用聚合物电解质膜
KR101267905B1 (ko) 술폰산기가 도입된 디페닐플루오렌기를 포함하는 수소이온 전도성 공중합체, 그의 제조방법, 그로부터 제조된 고분자 전해질 막, 이를 이용한 막-전극 접합체 및 이를 채용한 고분자 전해질 막 연료전지
WO2017029967A1 (ja) ポリフェニルスルホン系プロトン伝導性高分子電解質、プロトン伝導性固体高分子電解質膜、固体高分子形燃料電池用の電極触媒層及びその製造方法、並びに燃料電池
EP1519435A1 (en) Polymeric laminates, processes for producing the same, and use thereof
JP2009217950A (ja) イオン伝導性高分子電解質膜およびその製造方法
JP2014071971A (ja) 固体高分子電解質膜およびそれを用いた燃料電池
JP5867863B2 (ja) 高分子電解質およびその利用
KR20070056746A (ko) 브랜치된 술폰화 멀티 블록 공중합체 및 이를 이용한전해질막
Mehta Synthesis and Characterization of Hydrophobic-Hydrophilic Multiblock Copolymers for Proton Exchange Membrane and Segmented Copolymer Precursors for Reverse Osmosis Applications

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CX01 Expiry of patent term

Granted publication date: 20100602

CX01 Expiry of patent term