KR100756821B1 - 술폰화 멀티블록 공중합체 및 이를 이용한 전해질막 - Google Patents

술폰화 멀티블록 공중합체 및 이를 이용한 전해질막 Download PDF

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KR100756821B1
KR100756821B1 KR1020050122400A KR20050122400A KR100756821B1 KR 100756821 B1 KR100756821 B1 KR 100756821B1 KR 1020050122400 A KR1020050122400 A KR 1020050122400A KR 20050122400 A KR20050122400 A KR 20050122400A KR 100756821 B1 KR100756821 B1 KR 100756821B1
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formula
block
group
copolymer
precursor
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Korean (ko)
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KR20060067844A (ko
Inventor
장재혁
태영지
신정규
이봉근
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주식회사 엘지화학
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G61/00—Macromolecular compounds obtained by reactions forming a carbon-to-carbon link in the main chain of the macromolecule
    • C08G61/12—Macromolecular compounds containing atoms other than carbon in the main chain of the macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/38—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols
    • C08G65/40—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives derived from phenols from phenols (I) and other compounds (II), e.g. OH-Ar-OH + X-Ar-X, where X is halogen atom, i.e. leaving group
    • C08G65/4012—Other compound (II) containing a ketone group, e.g. X-Ar-C(=O)-Ar-X for polyetherketones
    • C08G65/4056—(I) or (II) containing sulfur
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/48—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/20—Manufacture of shaped structures of ion-exchange resins
    • C08J5/22—Films, membranes or diaphragms
    • C08J5/2206—Films, membranes or diaphragms based on organic and/or inorganic macromolecular compounds
    • C08J5/2218—Synthetic macromolecular compounds
    • C08J5/2256—Synthetic macromolecular compounds based on macromolecular compounds obtained by reactions other than those involving carbon-to-carbon bonds, e.g. obtained by polycondensation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1025—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon and oxygen, e.g. polyethers, sulfonated polyetheretherketones [S-PEEK], sulfonated polysaccharides, sulfonated celluloses or sulfonated polyesters
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1027—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having carbon, oxygen and other atoms, e.g. sulfonated polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1032—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having sulfur, e.g. sulfonated-polyethersulfones [S-PES]
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2371/00—Characterised by the use of polyethers obtained by reactions forming an ether link in the main chain; Derivatives of such polymers
    • C08J2371/08—Polyethers derived from hydroxy compounds or from their metallic derivatives
    • C08J2371/10—Polyethers derived from hydroxy compounds or from their metallic derivatives from phenols
    • C08J2371/12—Polyphenylene oxides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Sustainable Energy (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
  • Graft Or Block Polymers (AREA)
  • Polyethers (AREA)
KR1020050122400A 2004-12-14 2005-12-13 술폰화 멀티블록 공중합체 및 이를 이용한 전해질막 Expired - Lifetime KR100756821B1 (ko)

Priority Applications (1)

Application Number Priority Date Filing Date Title
KR1020050122400A KR100756821B1 (ko) 2004-12-14 2005-12-13 술폰화 멀티블록 공중합체 및 이를 이용한 전해질막

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
KR1020040105493 2004-12-14
KR20040105493 2004-12-14
KR1020050122400A KR100756821B1 (ko) 2004-12-14 2005-12-13 술폰화 멀티블록 공중합체 및 이를 이용한 전해질막

Publications (2)

Publication Number Publication Date
KR20060067844A KR20060067844A (ko) 2006-06-20
KR100756821B1 true KR100756821B1 (ko) 2007-09-07

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Country Status (7)

Country Link
US (1) US7601785B2 (enExample)
EP (1) EP1828284B1 (enExample)
JP (1) JP2008521999A (enExample)
KR (1) KR100756821B1 (enExample)
CN (1) CN101076551B (enExample)
TW (1) TWI294432B (enExample)
WO (1) WO2006065068A1 (enExample)

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TWI326691B (en) 2005-07-22 2010-07-01 Kraton Polymers Res Bv Sulfonated block copolymers, method for making same, and various uses for such block copolymers
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JP2009091568A (ja) * 2007-09-20 2009-04-30 Sumitomo Chemical Co Ltd 高分子電解質組成物
US8440365B2 (en) * 2008-01-08 2013-05-14 Kabushiki Kaisha Toyota Chuo Kenkyusho Electrolyte, production process therefor, electrolyte membrane, production process therefor, catalyst layer and fuel cell
US8012539B2 (en) * 2008-05-09 2011-09-06 Kraton Polymers U.S. Llc Method for making sulfonated block copolymers, method for making membranes from such block copolymers and membrane structures
US8574664B2 (en) * 2008-09-02 2013-11-05 General Electric Company Electrolyte membrane, methods of manufacture thereof and articles comprising the same
CN102203159B (zh) * 2008-11-04 2013-05-22 Lg化学株式会社 聚合物电解质膜
WO2010110444A1 (ja) * 2009-03-27 2010-09-30 国立大学法人山梨大学 ブロック共重合体、およびその利用
CN101531759B (zh) * 2009-04-17 2011-03-30 南京林业大学 冰片烯聚砜树脂的制备方法
US8445631B2 (en) 2009-10-13 2013-05-21 Kraton Polymers U.S. Llc Metal-neutralized sulfonated block copolymers, process for making them and their use
US8263713B2 (en) 2009-10-13 2012-09-11 Kraton Polymers U.S. Llc Amine neutralized sulfonated block copolymers and method for making same
US9394414B2 (en) 2010-09-29 2016-07-19 Kraton Polymers U.S. Llc Elastic, moisture-vapor permeable films, their preparation and their use
US9429366B2 (en) 2010-09-29 2016-08-30 Kraton Polymers U.S. Llc Energy recovery ventilation sulfonated block copolymer laminate membrane
KR101539512B1 (ko) 2010-10-18 2015-07-24 크레이튼 폴리머즈 유.에스. 엘엘씨 설폰화된 블록 공중합체 조성물의 생산 방법
US9861941B2 (en) 2011-07-12 2018-01-09 Kraton Polymers U.S. Llc Modified sulfonated block copolymers and the preparation thereof
US8952109B2 (en) * 2011-08-05 2015-02-10 Basf Se Process for preparing a block copolymer
EP2554564A1 (de) * 2011-08-05 2013-02-06 Basf Se Verfahren zur Herstellung eines Blockcopolymers
TWI452063B (zh) * 2012-03-29 2014-09-11 Univ Nat Sun Yat Sen 磺酸化聚芳香醚高分子及其製造方法
JP6302074B2 (ja) * 2013-09-16 2018-03-28 エルジー・ケム・リミテッド イオン交換性高分子層を含む水処理分離膜およびその製造方法
EP3063224A4 (en) * 2013-11-01 2017-06-21 Virginia Tech Intellectual Properties, Inc. Crosslinked polymer compositions for gas separation membranes
CN107074706B (zh) * 2014-10-28 2021-06-29 株式会社Lg化学 用于支化剂的氟系化合物、使用该氟系化合物的聚合物以及使用该聚合物的聚合物电解质膜
CN107075110A (zh) * 2014-10-31 2017-08-18 巴斯夫欧洲公司 制备膜的共聚物
EP3228642B1 (en) * 2014-12-02 2019-02-13 LG Chem, Ltd. Polymer, method for manufacturing same, and electrolyte membrane comprising same
KR102068872B1 (ko) * 2015-09-22 2020-01-21 주식회사 엘지화학 블록 중합체 및 이를 포함하는 고분자 전해질막

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JP2002226575A (ja) 2001-01-31 2002-08-14 Jsr Corp ポリエーテル系共重合体およびプロトン伝導膜
JP2003031232A (ja) 2001-05-08 2003-01-31 Ube Ind Ltd 固体高分子型燃料電池用高分子電解質及び燃料電池
JP2003147074A (ja) * 2001-11-16 2003-05-21 Toyobo Co Ltd スルホン酸基含有芳香族ポリアリーレンエーテル化合物および高分子電解質膜
KR20050023259A (ko) * 2002-05-13 2005-03-09 폴리퓨얼, 인코포레이티드 술폰화된 공중합체

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KR20020076825A (ko) 2001-03-30 2002-10-11 대주정밀화학 주식회사 직접메탄올 연료전지용 이온교환막
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KR100748049B1 (ko) * 2003-10-02 2007-08-09 고쿠리츠다이가쿠호징 야마나시다이가쿠 술폰산화 방향족 폴리에테르, 그의 제조 방법, 및 전해질막
KR20060019492A (ko) 2004-08-26 2006-03-03 주식회사 엘지화학 신규한 술폰화 폴리이미드 공중합체 및 이를 이용한전해질막

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Publication number Priority date Publication date Assignee Title
JP2002226575A (ja) 2001-01-31 2002-08-14 Jsr Corp ポリエーテル系共重合体およびプロトン伝導膜
JP2003031232A (ja) 2001-05-08 2003-01-31 Ube Ind Ltd 固体高分子型燃料電池用高分子電解質及び燃料電池
JP2003147074A (ja) * 2001-11-16 2003-05-21 Toyobo Co Ltd スルホン酸基含有芳香族ポリアリーレンエーテル化合物および高分子電解質膜
KR20050023259A (ko) * 2002-05-13 2005-03-09 폴리퓨얼, 인코포레이티드 술폰화된 공중합체

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JP2008521999A (ja) 2008-06-26
EP1828284A1 (en) 2007-09-05
US20060160960A1 (en) 2006-07-20
EP1828284B1 (en) 2012-06-13
TWI294432B (en) 2008-03-11
KR20060067844A (ko) 2006-06-20
US7601785B2 (en) 2009-10-13
TW200630404A (en) 2006-09-01
WO2006065068A1 (en) 2006-06-22
EP1828284A4 (en) 2009-06-10
CN101076551A (zh) 2007-11-21
CN101076551B (zh) 2010-06-02
WO2006065068A9 (en) 2007-06-07

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