CN1009249B - 制备含银催化剂的方法 - Google Patents

制备含银催化剂的方法

Info

Publication number
CN1009249B
CN1009249B CN87103074A CN87103074A CN1009249B CN 1009249 B CN1009249 B CN 1009249B CN 87103074 A CN87103074 A CN 87103074A CN 87103074 A CN87103074 A CN 87103074A CN 1009249 B CN1009249 B CN 1009249B
Authority
CN
China
Prior art keywords
silver
catalyst
compound
ethylene
carrier
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
CN87103074A
Other languages
English (en)
Chinese (zh)
Other versions
CN87103074A (zh
Inventor
格斯·鲍克斯胡尔恩
安·亨德里克·克拉辛格
奥托·孟特·维尔休斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of CN87103074A publication Critical patent/CN87103074A/zh
Publication of CN1009249B publication Critical patent/CN1009249B/zh
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/48—Silver or gold
    • B01J23/50—Silver
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/66—Silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/06—Halogens; Compounds thereof
    • B01J27/138—Halogens; Compounds thereof with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Epoxy Compounds (AREA)
  • Compounds Of Alkaline-Earth Elements, Aluminum Or Rare-Earth Metals (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Nitrogen Condensed Heterocyclic Rings (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
CN87103074A 1986-04-29 1987-04-27 制备含银催化剂的方法 Expired CN1009249B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB8610441 1986-04-29
GB868610441A GB8610441D0 (en) 1986-04-29 1986-04-29 Preparation of silver-containing catalyst

Publications (2)

Publication Number Publication Date
CN87103074A CN87103074A (zh) 1988-11-09
CN1009249B true CN1009249B (zh) 1990-08-22

Family

ID=10597028

Family Applications (1)

Application Number Title Priority Date Filing Date
CN87103074A Expired CN1009249B (zh) 1986-04-29 1987-04-27 制备含银催化剂的方法

Country Status (24)

Country Link
US (1) US4731350A (https=)
EP (1) EP0243996B1 (https=)
JP (1) JPH0829250B2 (https=)
KR (1) KR950005750B1 (https=)
CN (1) CN1009249B (https=)
AT (1) ATE68372T1 (https=)
AU (1) AU585442B2 (https=)
BG (1) BG50714A3 (https=)
BR (1) BR8702008A (https=)
CS (1) CS268178B2 (https=)
DE (1) DE3773734D1 (https=)
DK (1) DK164804C (https=)
ES (1) ES2025136B3 (https=)
FI (1) FI86966C (https=)
GB (1) GB8610441D0 (https=)
GR (1) GR3002994T3 (https=)
HU (1) HU203290B (https=)
IN (1) IN170009B (https=)
MX (1) MX168704B (https=)
PL (1) PL152415B1 (https=)
RU (1) RU1836144C (https=)
SG (1) SG95792G (https=)
TR (1) TR24543A (https=)
ZA (1) ZA872977B (https=)

Families Citing this family (41)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
EP0808215B1 (en) * 1995-02-01 1998-09-09 Shell Internationale Researchmaatschappij B.V. Alkylene oxide catalyst and process
US5908942A (en) * 1995-09-15 1999-06-01 Eastman Chemical Company Epoxidation of butadiene using cesium fluoride promoted silver catalyst with enhanced thermal stability under reaction conditions
TW426545B (en) * 1997-12-25 2001-03-21 Nippon Catalytic Chem Ind Silver catalyst for production of ethylene oxide, method for production thereof, and method for production of ethylene oxide
IN193645B (https=) * 1998-11-17 2004-07-31 Nippon Catalytic Chem Ind
US6011163A (en) * 1999-05-20 2000-01-04 Eastman Chemical Company Use of fluorinated hydrocarbons as reaction media for selective epoxidation of olefins
US20040224841A1 (en) * 2003-05-07 2004-11-11 Marek Matusz Silver-containing catalysts, the manufacture of such silver-containing catalysts, and the use thereof
AU2004238820B2 (en) 2003-05-07 2008-01-31 Shell Internationale Research Maatschappij B.V. Silver-containing catalysts, the manufacture of such silver containing catalysts, and the use thereof
US20040225138A1 (en) * 2003-05-07 2004-11-11 Mcallister Paul Michael Reactor system and process for the manufacture of ethylene oxide
US20060293180A1 (en) * 2003-08-22 2006-12-28 Thorsteinson Erlind M Modified alumina carriers and silver-based catalysts for the production of alkylene oxides
CN1838991A (zh) * 2003-08-22 2006-09-27 联合碳化化学及塑料技术公司 改进的氧化铝载体和用于制造烯化氧的银基催化剂
EP2277622B1 (en) * 2003-10-16 2013-01-09 Dow Technology Investments LLC Method for the preparation of catalysts having enhanced stability, efficiency and/or activity for alkylene oxide production
US7281341B2 (en) * 2003-12-10 2007-10-16 The Burton Corporation Lace system for footwear
TW200613056A (en) * 2004-04-01 2006-05-01 Shell Int Research A process for preparing a silver catalyst, the catalyst, and a use of the catalyst for olefin oxidation
TW200600190A (en) * 2004-04-01 2006-01-01 Shell Int Research Process for preparing a silver catalyst, the catalyst, and use thereof in olefin oxidation
TW200602123A (en) * 2004-04-01 2006-01-16 Shell Int Research Process for preparing a catalyst, the catalyst, and a use of the catalyst
EP1765800B1 (en) 2004-06-18 2012-04-18 Shell Internationale Research Maatschappij B.V. A process for the production of an olefin oxide, a 1,2-diol, a 1.2-diol ether, or an alkanolamine
EP1765799A1 (en) * 2004-06-18 2007-03-28 Shell Oil Company A process for the production of an olefin oxide, a 1,2-diol, a 1,2-diol ether, or an alkanolamine
US8536083B2 (en) * 2004-09-01 2013-09-17 Shell Oil Company Olefin epoxidation process, a catalyst for use in the process, a carrier for use in preparing the catalyst, and a process for preparing the carrier
KR20070058576A (ko) * 2004-09-01 2007-06-08 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀 에폭시화 방법, 이 방법에 사용되는 촉매, 이촉매의 제조에 사용되는 담체, 및 이 담체의 제조방법
JP2008514405A (ja) * 2004-09-24 2008-05-08 シエル・インターナシヨナル・リサーチ・マートスハツペイ・ベー・ヴエー 成形粒子を選択するプロセス、システムを取り付けるプロセス、このようなシステム内で気体原料を反応させるプロセス、コンピュータプログラム製品、およびコンピュータシステム
KR20070106772A (ko) * 2005-02-21 2007-11-05 셀 인터나쵸나아레 레사아치 마아츠샤피 비이부이 올레핀의 에폭시화 방법, 그 방법에 사용하기 위한 촉매,그 촉매를 제조하는데 이용하기 위한 담체, 및 그 담체의제조방법
RU2009120540A (ru) * 2006-11-01 2010-12-10 Дау Глобал Текнолоджиз Инк. (Us) Формованные пористые элементы из альфа-оксида алюминия и способы их получения
CN102247845B (zh) * 2010-05-21 2014-01-08 中国石油化工股份有限公司 一种负载型银催化剂及其制备方法
US8987482B2 (en) 2011-10-28 2015-03-24 Basf Se Process for producing a supported silver catalyst
WO2014105924A1 (en) * 2012-12-31 2014-07-03 Scientific Design Company, Inc. Calcination process for producing an improved ethylene oxide catalyst
CN111655368A (zh) 2018-02-07 2020-09-11 巴斯夫欧洲公司 制备银浸渍溶液的方法
EP3639923A1 (en) 2018-10-15 2020-04-22 Basf Se Process for producing ethylene oxide by gas-phase oxidation of ethylene
EP3639924A1 (en) 2018-10-15 2020-04-22 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3659703A1 (en) 2018-11-28 2020-06-03 Basf Se Catalyst for producing ethylene oxide by gas-phase oxidation
EP3885038A1 (en) 2020-03-27 2021-09-29 Basf Se Process for producing an epoxidation catalyst
CN113663699B (zh) * 2020-05-15 2024-05-07 中国石油化工股份有限公司 一种氧化铝载体及其制备方法
CN113694941B (zh) * 2020-05-20 2024-05-07 中国石油化工股份有限公司 一种负载型金属催化剂及其制备方法与应用
CN113713795B (zh) * 2020-05-25 2024-05-07 中国石油化工股份有限公司 一种复合氧化物载体及其制备方法
WO2021260138A1 (en) 2020-06-26 2021-12-30 Basf Se Shaped catalyst body for the production of ethylene oxide
WO2021260140A1 (en) 2020-06-26 2021-12-30 Basf Se Production of porous alpha-alumina supports from boehmitic derived aluminas
EP4171802A1 (de) 2020-06-26 2023-05-03 Basf Se Poröser katalysatorträger-formkörper
WO2022161924A1 (en) 2021-01-26 2022-08-04 Basf Se Epoxidation catalyst
CN117545552A (zh) 2021-06-25 2024-02-09 巴斯夫欧洲公司 高纯度压片阿尔法氧化铝催化剂载体
TW202421267A (zh) 2022-10-12 2024-06-01 德商巴斯夫歐洲公司 環氧化催化劑
WO2026027443A1 (en) 2024-07-29 2026-02-05 Basf Se Blended catalyst mix for epoxidation

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4010115A (en) * 1972-01-07 1977-03-01 Shell Oil Company Catalyst for the oxidation of ethylene to ethylene oxide
BE793658A (fr) * 1972-01-07 1973-07-04 Shell Int Research Catalyseur utilisable pour la production d'oxyde d'ethylene
EP0096130A1 (en) * 1982-06-11 1983-12-21 Exxon Research And Engineering Company Process for the epoxidation of olefins
US4575494A (en) * 1984-02-08 1986-03-11 The Dow Chemical Company Alumina compositions useful as catalyst supports for ethylene oxidation
DE3426699A1 (de) * 1984-07-20 1986-01-23 Hoechst Ag, 6230 Frankfurt Verfahren zur verbesserung der wirksamkeit von silbertraegerkatalysatoren
JPS61148361A (ja) * 1984-12-24 1986-07-07 Toshiba Corp 熱量計

Also Published As

Publication number Publication date
EP0243996A3 (en) 1989-05-31
DK213887A (da) 1987-10-30
EP0243996B1 (en) 1991-10-16
FI86966B (fi) 1992-07-31
KR950005750B1 (ko) 1995-05-30
FI871825L (fi) 1987-10-30
JPS62258745A (ja) 1987-11-11
CN87103074A (zh) 1988-11-09
DE3773734D1 (de) 1991-11-21
BR8702008A (pt) 1988-02-02
US4731350A (en) 1988-03-15
HU203290B (en) 1991-07-29
FI86966C (fi) 1992-11-10
IN170009B (https=) 1992-01-25
RU1836144C (ru) 1993-08-23
PL152415B1 (en) 1990-12-31
AU585442B2 (en) 1989-06-15
CS268178B2 (en) 1990-03-14
MX168704B (es) 1993-06-04
EP0243996A2 (en) 1987-11-04
DK164804B (da) 1992-08-24
ATE68372T1 (de) 1991-11-15
DK213887D0 (da) 1987-04-27
BG50714A3 (bg) 1992-10-15
ES2025136B3 (es) 1992-03-16
GB8610441D0 (en) 1986-06-04
DK164804C (da) 1993-01-11
AU7199787A (en) 1987-11-05
FI871825A0 (fi) 1987-04-27
GR3002994T3 (en) 1993-01-25
SG95792G (en) 1992-12-04
HUT48482A (en) 1989-06-28
CS299087A2 (en) 1989-04-14
TR24543A (tr) 1991-11-21
KR870009758A (ko) 1987-11-30
ZA872977B (en) 1987-11-25
PL265396A1 (en) 1988-08-18
JPH0829250B2 (ja) 1996-03-27

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SE01 Entry into force of request for substantive examination
C13 Decision
GR02 Examined patent application
C14 Grant of patent or utility model
GR01 Patent grant
C15 Extension of patent right duration from 15 to 20 years for appl. with date before 31.12.1992 and still valid on 11.12.2001 (patent law change 1993)
OR01 Other related matters
C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee