CN100439406C - 向苯乙烯聚合的悬浮方法中计量加料过氧化物 - Google Patents

向苯乙烯聚合的悬浮方法中计量加料过氧化物 Download PDF

Info

Publication number
CN100439406C
CN100439406C CNB2004800129074A CN200480012907A CN100439406C CN 100439406 C CN100439406 C CN 100439406C CN B2004800129074 A CNB2004800129074 A CN B2004800129074A CN 200480012907 A CN200480012907 A CN 200480012907A CN 100439406 C CN100439406 C CN 100439406C
Authority
CN
China
Prior art keywords
initiator
polymerization
monomer
monomers
polymerized
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CNB2004800129074A
Other languages
English (en)
Chinese (zh)
Other versions
CN1788025A (zh
Inventor
H·G·贝维布林克
F-J·霍格斯特格尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nouryon Chemicals International BV
Original Assignee
Akzo Nobel Co ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Akzo Nobel Co ltd filed Critical Akzo Nobel Co ltd
Publication of CN1788025A publication Critical patent/CN1788025A/zh
Application granted granted Critical
Publication of CN100439406C publication Critical patent/CN100439406C/zh
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/46—Polymerisation initiated by wave energy or particle radiation
    • C08F2/48—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light
    • C08F2/50—Polymerisation initiated by wave energy or particle radiation by ultraviolet or visible light with sensitising agents

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Polymerization Catalysts (AREA)
  • Graft Or Block Polymers (AREA)
CNB2004800129074A 2003-04-14 2004-04-02 向苯乙烯聚合的悬浮方法中计量加料过氧化物 Expired - Fee Related CN100439406C (zh)

Applications Claiming Priority (7)

Application Number Priority Date Filing Date Title
EP03076088 2003-04-14
EP03076088.8 2003-04-14
US47196303P 2003-05-20 2003-05-20
US60/471,963 2003-05-20
US53022203P 2003-12-17 2003-12-17
US60/530,222 2003-12-17
PCT/EP2004/003661 WO2004089999A2 (en) 2003-04-14 2004-04-02 Dosing of peroxide to a suspension process wherein styrene is polymerized

Publications (2)

Publication Number Publication Date
CN1788025A CN1788025A (zh) 2006-06-14
CN100439406C true CN100439406C (zh) 2008-12-03

Family

ID=33162639

Family Applications (1)

Application Number Title Priority Date Filing Date
CNB2004800129074A Expired - Fee Related CN100439406C (zh) 2003-04-14 2004-04-02 向苯乙烯聚合的悬浮方法中计量加料过氧化物

Country Status (12)

Country Link
US (1) US7132485B2 (enExample)
EP (1) EP1613672B1 (enExample)
JP (1) JP4524279B2 (enExample)
KR (1) KR101093477B1 (enExample)
CN (1) CN100439406C (enExample)
AR (1) AR043865A1 (enExample)
BR (1) BRPI0409446B1 (enExample)
CL (1) CL2004000789A1 (enExample)
MX (1) MXPA05011015A (enExample)
PL (1) PL1613672T3 (enExample)
TW (1) TWI343924B (enExample)
WO (1) WO2004089999A2 (enExample)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2879207B1 (fr) * 2004-12-10 2007-07-06 Commissariat Energie Atomique Procede et dispositif de fabrication de billes ou de ballons en mousse polymere
JP2011503335A (ja) * 2007-11-20 2011-01-27 アクゾ ノーベル ナムローゼ フェンノートシャップ スチレン系（コ）ポリマーの調製方法
US8822610B2 (en) * 2008-12-22 2014-09-02 ATRP Solutions, Inc. Control over controlled radical polymerization processes
US8815971B2 (en) 2008-12-22 2014-08-26 ATRP Solutions, Inc. Control over controlled radical polymerization processes
SA110310245B1 (ar) 2009-04-03 2014-11-12 اكزو نوبل كيميكا معلق بيروكسيد ثنائي آسيل صلب مائي
FR2948375B1 (fr) * 2009-07-27 2011-12-30 Arkema France Procede de preparation de polystyrene expansible par injection en continu d'un peroxyde organique liquide
KR20120117980A (ko) * 2009-12-10 2012-10-25 아크조 노벨 케미칼즈 인터내셔널 비.브이. 스티렌 중합 방법
CN102603929B (zh) * 2012-02-29 2014-10-29 无锡知益微球科技有限公司 一种高分子颗粒的制备方法
KR101336251B1 (ko) * 2012-08-29 2013-12-03 포항공과대학교 산학협력단 스티렌 단량체를 이용한 전기 방사된 폴리스티렌 나노 섬유의 제조 방법 및 폴리스티렌-양자점 하이브리드 나노섬유의 제조 방법
CN102875734B (zh) * 2012-09-29 2014-08-06 东莞新长桥塑料有限公司 回收级可发性聚苯乙烯以及利用种子聚合法制备回收级可发性聚苯乙烯的方法
CN102863569B (zh) * 2012-09-29 2014-05-14 东莞新长桥塑料有限公司 低挥发性有机物含量的阻燃型可发性聚苯乙烯树脂及其制备方法
KR102156109B1 (ko) * 2017-09-29 2020-09-15 주식회사 엘지화학 탄소섬유 제조용 아크릴로니트릴계 중합체의 제조방법
WO2023136699A1 (ko) * 2022-01-17 2023-07-20 주식회사 엘지화학 중합체의 제조방법
WO2025186291A1 (en) 2024-03-08 2025-09-12 Nouryon Chemicals International B.V. Process for recycling polystyrene

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059912A (zh) * 1990-09-15 1992-04-01 希尔斯股份公司 悬浮聚合制备可膨胀的苯乙烯聚合物时控制粒度的方法
CN1059917A (zh) * 1990-09-20 1992-04-01 国际壳牌研究有限公司 制备含有聚乙烯基芳环和乙丙三元橡胶的聚合物组合物的方法
US5905096A (en) * 1995-08-22 1999-05-18 Basf Aktiengesellschaft Continuous production process of expandable styrene polymer beads

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3451985A (en) * 1964-03-26 1969-06-24 Monsanto Co Method of polymerizing vinyl monomers
US4173688A (en) 1973-07-23 1979-11-06 Sekisui Kagaku Kogyo Kabushiki Kaisha Process for preparing styrenic polymer foams
GB1416405A (en) 1973-07-27 1975-12-03 Sekisui Chemical Co Ltd Process for preparing styrenic polymer particles
US4363881A (en) 1980-11-26 1982-12-14 Cellofoam A.G. Method of making uniformly-sized expandable polymeric particles
ZA818026B (en) * 1980-11-26 1982-10-27 Cellofoam Ag Method of making uniformly-sized expandable polymeric particles
JPS6047037A (ja) * 1983-08-24 1985-03-14 Hitachi Chem Co Ltd 発泡性スチレン系樹脂粒子の製造法
EP0234705A3 (en) 1986-01-23 1989-01-25 Mitsubishi Yuka Badische Co., Ltd. Process for producing expandable polystyrene beads
JP2684400B2 (ja) * 1989-01-09 1997-12-03 出光石油化学株式会社 スチレン系重合体及びその製造方法
JPH02255708A (ja) 1989-03-30 1990-10-16 Idemitsu Petrochem Co Ltd スチレン系重合体の製造方法
JP2933707B2 (ja) 1990-11-21 1999-08-16 鐘淵化学工業株式会社 発泡性スチレン系重合体粒子の製造方法
EP0492712A1 (en) 1990-12-24 1992-07-01 Akzo Nobel N.V. Peroxide compositions with ethoxylated water-soluble polymers
JP3054014B2 (ja) * 1993-12-27 2000-06-19 積水化成品工業株式会社 発泡性スチレン系重合体粒子の製造方法
JPH1017698A (ja) * 1996-07-04 1998-01-20 Shell Japan Kk 発泡性スチレン系樹脂粒子
GB9721603D0 (en) 1997-10-10 1997-12-10 Dyno Ind Asa Method
AU3819399A (en) 1998-04-17 1999-11-08 Shell Internationale Research Maatschappij B.V. Process for the preparation of expandable polymer particles
HU230607B1 (hu) 1998-09-21 2017-03-28 Akzo Nobel N.V. Nagyon gyors iniciátorok folytonos adagolása polimerizációs reakciók során
DE19911960A1 (de) 1999-03-17 2000-09-21 Basf Ag Verfahren zur Herstellung von Stilben/Styrol-Copolymeren
US6984702B2 (en) 2000-03-22 2006-01-10 Dynal Biotech Asa Process for the preparation of functionalized polymer particles
DE10039388A1 (de) 2000-08-11 2002-02-21 Basf Ag Stärkehaltige Polymerdispersionen

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1059912A (zh) * 1990-09-15 1992-04-01 希尔斯股份公司 悬浮聚合制备可膨胀的苯乙烯聚合物时控制粒度的方法
CN1059917A (zh) * 1990-09-20 1992-04-01 国际壳牌研究有限公司 制备含有聚乙烯基芳环和乙丙三元橡胶的聚合物组合物的方法
US5905096A (en) * 1995-08-22 1999-05-18 Basf Aktiengesellschaft Continuous production process of expandable styrene polymer beads

Also Published As

Publication number Publication date
MXPA05011015A (es) 2005-12-12
JP2006522844A (ja) 2006-10-05
CL2004000789A1 (es) 2005-01-21
CN1788025A (zh) 2006-06-14
US20060111529A1 (en) 2006-05-25
TW200508258A (en) 2005-03-01
EP1613672A2 (en) 2006-01-11
WO2004089999A2 (en) 2004-10-21
BRPI0409446B1 (pt) 2016-06-07
EP1613672B1 (en) 2019-06-12
BRPI0409446A (pt) 2006-04-18
KR20060012583A (ko) 2006-02-08
AR043865A1 (es) 2005-08-17
JP4524279B2 (ja) 2010-08-11
KR101093477B1 (ko) 2011-12-13
WO2004089999A3 (en) 2005-01-06
US7132485B2 (en) 2006-11-07
PL1613672T3 (pl) 2019-12-31
TWI343924B (en) 2011-06-21

Similar Documents

Publication Publication Date Title
CN100439406C (zh) 向苯乙烯聚合的悬浮方法中计量加料过氧化物
AU2010329986B2 (en) Process for the polymerization of styrene
JP2009007590A5 (enExample)
JP6161680B2 (ja) 有機過酸化物によって開始する生産性の高いエチレンのフリーラジカル重合
EP3597674B1 (en) Method for preparing copolymer
RU2605093C2 (ru) Способ получения полистирола, имеющего высокий показатель текучести расплава
JP2002526574A (ja) 重合反応中の非常に速い開始剤の連続的配量
US6410654B1 (en) Highly rigid, high-tenacity impact-resistant polystyrene
EP1668059B1 (en) High impact polystyrene and process for preparing same
JP3319485B2 (ja) 耐熱分解性を有するメタクリル樹脂の製造方法
JP7680441B2 (ja) 超高度制御ラジカル重合
JP2001192403A (ja) 場合によりエチレン性不飽和ニトリルを含有した、ビニル芳香族ポリマーの生産プロセス
JPS5919576B2 (ja) ゴム変性スチレン系樹脂の製造方法
CN101868480A (zh) 制备基于苯乙烯的(共)聚合物的方法
RU2360929C2 (ru) Дозирование пероксида в суспензионном способе, по которому полимеризуют стирол
JP3344201B2 (ja) スチレン系重合体の製造方法
EP4053178B1 (en) Polymer production method
JP3319484B2 (ja) 耐熱分解性を有するメタクリル樹脂の製造方法
KR970009238B1 (ko) 올리고머를 이용한 고분자의 중합도 조절 방법
JPH075685B2 (ja) ニトリル系共重合体の製造方法
JP2006282737A (ja) α−アルキルスチレン系耐熱樹脂の製造方法および該樹脂
JPH09188709A (ja) スチレン系重合体の製造方法
JPH10231303A (ja) スチレン系共重合体の製造方法
JPH07157507A (ja) アクリロニトリル系共重合体の製造方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
TR01 Transfer of patent right

Effective date of registration: 20171228

Address after: Holland Arnhem

Patentee after: Akzo Nobel Chemicals International B.V

Address before: Holland Arnhem

Patentee before: Akzo Nobel N. V.

TR01 Transfer of patent right
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20081203

Termination date: 20210402

CF01 Termination of patent right due to non-payment of annual fee