CN100398452C - 用于形成锂化二氧化锰的方法和一次锂电化学电池 - Google Patents
用于形成锂化二氧化锰的方法和一次锂电化学电池 Download PDFInfo
- Publication number
- CN100398452C CN100398452C CNB018140297A CN01814029A CN100398452C CN 100398452 C CN100398452 C CN 100398452C CN B018140297 A CNB018140297 A CN B018140297A CN 01814029 A CN01814029 A CN 01814029A CN 100398452 C CN100398452 C CN 100398452C
- Authority
- CN
- China
- Prior art keywords
- lithium
- manganese dioxide
- electrochemical cell
- reaction mixture
- lithiated manganese
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
- H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
- H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/02—Oxides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G45/00—Compounds of manganese
- C01G45/12—Complex oxides containing manganese and at least one other metal element
- C01G45/1221—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof
- C01G45/1228—Manganates or manganites with trivalent manganese, tetravalent manganese or mixtures thereof of the type (MnO2)-, e.g. LiMnO2 or Li(MxMn1-x)O2
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/06—Electrodes for primary cells
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/50—Solid solutions
- C01P2002/52—Solid solutions containing elements as dopants
- C01P2002/54—Solid solutions containing elements as dopants one element only
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/12—Surface area
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/40—Electric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M2004/021—Physical characteristics, e.g. porosity, surface area
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M6/00—Primary cells; Manufacture thereof
- H01M6/14—Cells with non-aqueous electrolyte
- H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
- H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
- Primary Cells (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US09/612,864 US6403257B1 (en) | 2000-07-10 | 2000-07-10 | Mechanochemical synthesis of lithiated manganese dioxide |
| US09/612,864 | 2000-07-10 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1446180A CN1446180A (zh) | 2003-10-01 |
| CN100398452C true CN100398452C (zh) | 2008-07-02 |
Family
ID=24454925
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB018140297A Expired - Fee Related CN100398452C (zh) | 2000-07-10 | 2001-07-05 | 用于形成锂化二氧化锰的方法和一次锂电化学电池 |
Country Status (9)
| Country | Link |
|---|---|
| US (1) | US6403257B1 (https=) |
| EP (1) | EP1303460B1 (https=) |
| JP (1) | JP2004502629A (https=) |
| CN (1) | CN100398452C (https=) |
| AR (1) | AR029575A1 (https=) |
| AT (1) | ATE320406T1 (https=) |
| AU (1) | AU2001271833A1 (https=) |
| DE (1) | DE60117992T2 (https=) |
| WO (1) | WO2002004352A2 (https=) |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR100417251B1 (ko) * | 1999-12-15 | 2004-02-05 | 주식회사 엘지화학 | 전기화학적 성능이 향상된 리튬망간 스피넬 산화물의 제조방법 |
| JP4151210B2 (ja) * | 2000-08-30 | 2008-09-17 | ソニー株式会社 | 正極活物質及びその製造方法、並びに非水電解質電池及びその製造方法 |
| JP4694721B2 (ja) * | 2000-11-15 | 2011-06-08 | パナソニック株式会社 | 非水電解質二次電池用負極材料およびその製造法 |
| JP2003178755A (ja) * | 2001-09-19 | 2003-06-27 | Wilson Greatbatch Technologies Inc | 改善された電池性能に適した微細粒子径を有する酸化バナジウム銀 |
| US6713037B2 (en) * | 2001-09-28 | 2004-03-30 | Nanox, Inc. | Process for synthesizing noncrystalline lithium based mixed oxides by high energy milling |
| US20040253175A1 (en) * | 2002-08-21 | 2004-12-16 | Stiffler Donald R. | Electrostatically enhanced tribochemical methods and apparatus |
| US20040137327A1 (en) * | 2003-01-13 | 2004-07-15 | Gross Karl J. | Synthesis of carbon/silicon composites |
| US7140567B1 (en) * | 2003-03-11 | 2006-11-28 | Primet Precision Materials, Inc. | Multi-carbide material manufacture and use as grinding media |
| US7578457B2 (en) * | 2003-03-11 | 2009-08-25 | Primet Precision Materials, Inc. | Method for producing fine dehydrided metal particles using grinding media |
| US7342770B2 (en) * | 2003-07-09 | 2008-03-11 | Maxwell Technologies, Inc. | Recyclable dry particle based adhesive electrode and methods of making same |
| US7791860B2 (en) | 2003-07-09 | 2010-09-07 | Maxwell Technologies, Inc. | Particle based electrodes and methods of making same |
| US20050266298A1 (en) * | 2003-07-09 | 2005-12-01 | Maxwell Technologies, Inc. | Dry particle based electro-chemical device and methods of making same |
| US20050250011A1 (en) * | 2004-04-02 | 2005-11-10 | Maxwell Technologies, Inc. | Particle packaging systems and methods |
| US20060147712A1 (en) * | 2003-07-09 | 2006-07-06 | Maxwell Technologies, Inc. | Dry particle based adhesive electrode and methods of making same |
| US7508651B2 (en) * | 2003-07-09 | 2009-03-24 | Maxwell Technologies, Inc. | Dry particle based adhesive and dry film and methods of making same |
| US20100014215A1 (en) * | 2004-04-02 | 2010-01-21 | Maxwell Technologies, Inc. | Recyclable dry particle based electrode and methods of making same |
| US7295423B1 (en) | 2003-07-09 | 2007-11-13 | Maxwell Technologies, Inc. | Dry particle based adhesive electrode and methods of making same |
| US20070122698A1 (en) | 2004-04-02 | 2007-05-31 | Maxwell Technologies, Inc. | Dry-particle based adhesive and dry film and methods of making same |
| US7352558B2 (en) * | 2003-07-09 | 2008-04-01 | Maxwell Technologies, Inc. | Dry particle based capacitor and methods of making same |
| US20050048366A1 (en) | 2003-08-27 | 2005-03-03 | Bowden William L. | Cathode material and method of manufacturing |
| US7920371B2 (en) | 2003-09-12 | 2011-04-05 | Maxwell Technologies, Inc. | Electrical energy storage devices with separator between electrodes and methods for fabricating the devices |
| US7495349B2 (en) | 2003-10-20 | 2009-02-24 | Maxwell Technologies, Inc. | Self aligning electrode |
| US20050164085A1 (en) * | 2004-01-22 | 2005-07-28 | Bofinger Todd E. | Cathode material for lithium battery |
| US8003254B2 (en) | 2004-01-22 | 2011-08-23 | The Gillette Company | Battery cathodes |
| US8137842B2 (en) * | 2004-01-22 | 2012-03-20 | The Gillette Company | Battery cathodes |
| US7090946B2 (en) | 2004-02-19 | 2006-08-15 | Maxwell Technologies, Inc. | Composite electrode and method for fabricating same |
| US7384433B2 (en) | 2004-02-19 | 2008-06-10 | Maxwell Technologies, Inc. | Densification of compressible layers during electrode lamination |
| US20060137158A1 (en) * | 2004-04-02 | 2006-06-29 | Maxwell Technologies, Inc. | Dry-particle packaging systems and methods of making same |
| US7492571B2 (en) * | 2004-04-02 | 2009-02-17 | Linda Zhong | Particles based electrodes and methods of making same |
| US20060246343A1 (en) * | 2004-04-02 | 2006-11-02 | Maxwell Technologies, Inc. | Dry particle packaging systems and methods of making same |
| US7227737B2 (en) | 2004-04-02 | 2007-06-05 | Maxwell Technologies, Inc. | Electrode design |
| US7245478B2 (en) | 2004-08-16 | 2007-07-17 | Maxwell Technologies, Inc. | Enhanced breakdown voltage electrode |
| US7492574B2 (en) | 2005-03-14 | 2009-02-17 | Maxwell Technologies, Inc. | Coupling of cell to housing |
| US7440258B2 (en) | 2005-03-14 | 2008-10-21 | Maxwell Technologies, Inc. | Thermal interconnects for coupling energy storage devices |
| US20060222945A1 (en) * | 2005-04-01 | 2006-10-05 | Bowden William L | Battery cathodes |
| US7771874B2 (en) | 2005-06-29 | 2010-08-10 | Fmc Corporation | Lithium manganese compounds and methods of making the same |
| US20070098803A1 (en) | 2005-10-27 | 2007-05-03 | Primet Precision Materials, Inc. | Small particle compositions and associated methods |
| US20070257394A1 (en) * | 2006-05-08 | 2007-11-08 | Maxwell Technologies, Inc. | Feeder for Agglomerating Particles |
| US8518573B2 (en) * | 2006-09-29 | 2013-08-27 | Maxwell Technologies, Inc. | Low-inductive impedance, thermally decoupled, radii-modulated electrode core |
| US20080201925A1 (en) | 2007-02-28 | 2008-08-28 | Maxwell Technologies, Inc. | Ultracapacitor electrode with controlled sulfur content |
| JP2009203102A (ja) * | 2008-02-27 | 2009-09-10 | Nagoya Institute Of Technology | セラミックス粉体の固化方法及びセラミックス固化体 |
| ES2355001B1 (es) * | 2009-09-09 | 2012-01-25 | Consejo Superior De Investigaciones Científicas (Csic) | Procedimiento de estabilizacion de mercurio liquido mediante cemento polimerico de azufre, via sulfuro de mercurio |
| CN102668178B (zh) | 2009-11-25 | 2014-10-08 | 株式会社Lg化学 | 由两种组分的组合制成的阴极以及使用该阴极的锂二次电池 |
| JP2010095444A (ja) * | 2010-02-04 | 2010-04-30 | Nagoya Institute Of Technology | セラミックスの固化方法 |
| US20110219607A1 (en) * | 2010-03-12 | 2011-09-15 | Nanjundaswamy Kirakodu S | Cathode active materials and method of making thereof |
| CN102263235A (zh) * | 2010-05-27 | 2011-11-30 | 群顺绿能股份有限公司 | 含锂电极材料烧结方法 |
| US8282856B2 (en) * | 2010-05-28 | 2012-10-09 | Harmony Brother Co., Ltd. | Method for sintering lithium contained electrode material |
| KR101728645B1 (ko) * | 2013-10-04 | 2017-04-19 | 닛산 지도우샤 가부시키가이샤 | 비수 전해질 2차 전지용 정극 활물질 및 그 제조 방법 |
| CN103560242A (zh) * | 2013-11-07 | 2014-02-05 | 广西桂柳化工有限责任公司 | 一种加工锂离子电池用电解二氧化锰的装置 |
| EP3134933B1 (en) * | 2014-04-21 | 2020-10-21 | Prince Specialty Products LLC | Method of producing electrolytic manganese dioxide with high compact density and electrolytic manganese dioxide produced therefrom |
| EP3163655B1 (en) | 2015-10-28 | 2019-02-27 | Renata AG | Electro-active material of a cathode of primary battery |
| EP3162764B1 (en) | 2015-11-02 | 2018-04-04 | IMEC vzw | Methods for forming lithium manganese oxide layers |
| EP3661620A4 (en) | 2017-08-02 | 2021-05-12 | Lilac Solutions, Inc. | Ion exchange system for lithium extraction |
| DE102018101041A1 (de) * | 2018-01-18 | 2019-07-18 | Heraeus Medical Gmbh | Knochenzementapplikator mit verschließbarer Begasungsöffnung |
| DE102018000418A1 (de) | 2018-01-20 | 2019-07-25 | Bürkle Consulting Gmbh | Mechanochemisches Verfahren zur Herstellung von von persistenten organischen Schadstoffen und anderen Organohalogenverbindungen freien Wertprodukten aus Abfällen von Kunststoffen und Kunststofflaminaten |
| CN108793256B (zh) * | 2018-06-26 | 2022-10-11 | 普瑞斯矿业(中国)有限公司 | 一种电解二氧化锰粉末及其制备方法 |
| CN109037613B (zh) * | 2018-07-04 | 2021-04-16 | 上海电气集团股份有限公司 | 二氧化钌包覆尖晶石富锂锰酸锂及其制备方法 |
| CN109108048B (zh) * | 2018-08-01 | 2021-06-04 | 湘潭大学 | 一种铝电解阳极炭渣中含钠化合物、含氟化合物的机械化学转化与回收方法 |
| DE102019006084A1 (de) | 2019-02-12 | 2020-08-13 | Elke Münch | Mechanochemisches Verfahren |
| CN110061186A (zh) * | 2019-05-29 | 2019-07-26 | 福建南平南孚电池有限公司 | 高稳定性的一次性锂锰扣式电池正极片及制备方法和应用 |
| CN112216815B (zh) * | 2019-07-11 | 2021-12-07 | 深圳市比亚迪锂电池有限公司 | 锂锰电池正极和锂锰电池 |
| CN110563339A (zh) * | 2019-10-17 | 2019-12-13 | 维沃泰克仪器(扬州)有限公司 | 一种无水硼酸锂助熔剂的制备方法 |
| CN113839029B (zh) * | 2020-06-24 | 2023-10-17 | 深圳市比亚迪锂电池有限公司 | 一种锂锰电池 |
| WO2023192192A1 (en) | 2022-03-28 | 2023-10-05 | Lilac Solutions, Inc. | Lithium extraction enhanced by an alternate phase |
| JP7825889B1 (ja) * | 2024-08-29 | 2026-03-09 | 株式会社メカノクロス | メカノケミカル反応方法及び反応機器 |
| DE102025101736B3 (de) * | 2025-01-19 | 2026-02-19 | Elke Münch | Mechanochemische Reaktoren mit einem selbstregulierenden Wärmemanagementsystem auf der Basis von Wärmerohren |
| CN119725504B (zh) * | 2025-02-27 | 2025-04-29 | 超威电源集团有限公司 | 低温碳包覆γ-MnO2的制备方法及水系锌离子电池 |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5911920A (en) * | 1997-03-25 | 1999-06-15 | Mitsubishi Heavy Industries, Ltd. | Manufacturing method for Li composite oxides employed as electrode materials in Li batteries |
| US5939043A (en) * | 1998-06-26 | 1999-08-17 | Ga-Tek Inc. | Process for preparing Lix Mn2 O4 intercalation compounds |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5342325A (en) | 1976-09-29 | 1978-04-17 | Sanyo Electric Co | Method of making cathode of nonnaqueous battery |
| CA2057946A1 (en) * | 1990-12-20 | 1992-06-21 | Michael M. Thackeray | Electrochemical cell |
| FR2721308B1 (fr) * | 1994-06-21 | 1996-10-11 | Commissariat Energie Atomique | Composés d'insertion à base d'oxyde de manganèse, utilisables comme électrode positive dans un accumulateur au lithium. |
| AU3893795A (en) * | 1994-10-19 | 1996-05-15 | Valence Technology, Inc. | Lithium manganese oxide, method of preparation and uses thereof |
| US5753202A (en) * | 1996-04-08 | 1998-05-19 | Duracell Inc. | Method of preparation of lithium manganese oxide spinel |
| JPH10241682A (ja) * | 1997-02-25 | 1998-09-11 | Mitsubishi Cable Ind Ltd | リチウム二次電池用の正極活物質およびその製造方法 |
| US6337157B1 (en) * | 1997-05-28 | 2002-01-08 | Showa Denki Kabushiki Kaisha | Cathode electroactive material, production method and nonaqueous secondary battery comprising the same |
| JP4066102B2 (ja) * | 1997-12-16 | 2008-03-26 | 日本化学工業株式会社 | リチウムマンガン複合酸化物の製造方法 |
| US6017504A (en) * | 1998-07-16 | 2000-01-25 | Universite Laval | Process for synthesizing perovskites using high energy milling |
| WO2001013446A2 (en) * | 1999-08-10 | 2001-02-22 | Nikko Materials Company, Limited | Material for positive electrode of lithium secondary cell and method for preparing the same |
-
2000
- 2000-07-10 US US09/612,864 patent/US6403257B1/en not_active Expired - Lifetime
-
2001
- 2001-07-05 WO PCT/US2001/021247 patent/WO2002004352A2/en not_active Ceased
- 2001-07-05 CN CNB018140297A patent/CN100398452C/zh not_active Expired - Fee Related
- 2001-07-05 EP EP01950880A patent/EP1303460B1/en not_active Expired - Lifetime
- 2001-07-05 AT AT01950880T patent/ATE320406T1/de not_active IP Right Cessation
- 2001-07-05 AU AU2001271833A patent/AU2001271833A1/en not_active Abandoned
- 2001-07-05 DE DE60117992T patent/DE60117992T2/de not_active Expired - Fee Related
- 2001-07-05 JP JP2002509024A patent/JP2004502629A/ja active Pending
- 2001-07-06 AR ARP010103231A patent/AR029575A1/es unknown
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5911920A (en) * | 1997-03-25 | 1999-06-15 | Mitsubishi Heavy Industries, Ltd. | Manufacturing method for Li composite oxides employed as electrode materials in Li batteries |
| US5939043A (en) * | 1998-06-26 | 1999-08-17 | Ga-Tek Inc. | Process for preparing Lix Mn2 O4 intercalation compounds |
Also Published As
| Publication number | Publication date |
|---|---|
| WO2002004352A3 (en) | 2002-05-30 |
| CN1446180A (zh) | 2003-10-01 |
| US6403257B1 (en) | 2002-06-11 |
| EP1303460B1 (en) | 2006-03-15 |
| WO2002004352A2 (en) | 2002-01-17 |
| JP2004502629A (ja) | 2004-01-29 |
| EP1303460A2 (en) | 2003-04-23 |
| AR029575A1 (es) | 2003-07-02 |
| DE60117992T2 (de) | 2006-09-21 |
| DE60117992D1 (de) | 2006-05-11 |
| ATE320406T1 (de) | 2006-04-15 |
| AU2001271833A1 (en) | 2002-01-21 |
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