CA2560041C - Polymers for use in cleaning compositions - Google Patents
Polymers for use in cleaning compositions Download PDFInfo
- Publication number
- CA2560041C CA2560041C CA2560041A CA2560041A CA2560041C CA 2560041 C CA2560041 C CA 2560041C CA 2560041 A CA2560041 A CA 2560041A CA 2560041 A CA2560041 A CA 2560041A CA 2560041 C CA2560041 C CA 2560041C
- Authority
- CA
- Canada
- Prior art keywords
- polymer
- water
- monomers
- polymers
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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- 229920000642 polymer Polymers 0.000 title claims abstract description 104
- 239000000203 mixture Substances 0.000 title claims abstract description 35
- 238000004140 cleaning Methods 0.000 title claims abstract description 26
- 239000000178 monomer Substances 0.000 claims abstract description 92
- -1 half-esters thereof Chemical class 0.000 claims description 20
- 150000003839 salts Chemical class 0.000 claims description 18
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 17
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims description 17
- QNILTEGFHQSKFF-UHFFFAOYSA-N n-propan-2-ylprop-2-enamide Chemical compound CC(C)NC(=O)C=C QNILTEGFHQSKFF-UHFFFAOYSA-N 0.000 claims description 17
- 239000002932 luster Substances 0.000 claims description 15
- 229920003169 water-soluble polymer Polymers 0.000 claims description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 14
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 7
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims description 6
- 229910006069 SO3H Inorganic materials 0.000 claims description 6
- 239000000654 additive Substances 0.000 claims description 6
- 230000014759 maintenance of location Effects 0.000 claims description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 4
- 150000001735 carboxylic acids Chemical class 0.000 claims description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 claims description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 4
- 239000010452 phosphate Substances 0.000 claims description 4
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 3
- 150000004820 halides Chemical class 0.000 claims description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 claims 3
- 230000000996 additive effect Effects 0.000 claims 2
- 125000002947 alkylene group Chemical group 0.000 claims 2
- 150000001991 dicarboxylic acids Chemical class 0.000 claims 2
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 claims 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 1
- NVBNXMILSFTKHF-UHFFFAOYSA-N [Cl-].C[NH+](C)C.CCCC=C(C)C(N)=O Chemical compound [Cl-].C[NH+](C)C.CCCC=C(C)C(N)=O NVBNXMILSFTKHF-UHFFFAOYSA-N 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 26
- 125000004432 carbon atom Chemical group C* 0.000 description 14
- 238000009472 formulation Methods 0.000 description 10
- 239000003999 initiator Substances 0.000 description 10
- 239000012459 cleaning agent Substances 0.000 description 9
- 238000006116 polymerization reaction Methods 0.000 description 8
- 229920000536 2-Acrylamido-2-methylpropane sulfonic acid Polymers 0.000 description 6
- 230000008901 benefit Effects 0.000 description 6
- 239000000919 ceramic Substances 0.000 description 6
- 238000004851 dishwashing Methods 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 6
- 239000002253 acid Substances 0.000 description 5
- 229910052783 alkali metal Inorganic materials 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 150000003254 radicals Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 229920001897 terpolymer Polymers 0.000 description 5
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 150000001340 alkali metals Chemical class 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000003863 ammonium salts Chemical class 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003599 detergent Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 3
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- 229940048053 acrylate Drugs 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 229920001577 copolymer Polymers 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 230000002209 hydrophobic effect Effects 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000004033 plastic Substances 0.000 description 3
- 229920003023 plastic Polymers 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- VHYFNPMBLIVWCW-UHFFFAOYSA-N 4-Dimethylaminopyridine Chemical compound CN(C)C1=CC=NC=C1 VHYFNPMBLIVWCW-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- CIUQDSCDWFSTQR-UHFFFAOYSA-N [C]1=CC=CC=C1 Chemical compound [C]1=CC=CC=C1 CIUQDSCDWFSTQR-UHFFFAOYSA-N 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 2
- 239000001530 fumaric acid Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- WCYWZMWISLQXQU-UHFFFAOYSA-N methyl Chemical group [CH3] WCYWZMWISLQXQU-UHFFFAOYSA-N 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- 238000000569 multi-angle light scattering Methods 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000012966 redox initiator Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical class [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 2
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 2
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 2
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 2
- HGXJDMCMYLEZMJ-UHFFFAOYSA-N (2-methylpropan-2-yl)oxy 2,2-dimethylpropaneperoxoate Chemical compound CC(C)(C)OOOC(=O)C(C)(C)C HGXJDMCMYLEZMJ-UHFFFAOYSA-N 0.000 description 1
- WYGWHHGCAGTUCH-UHFFFAOYSA-N 2-[(2-cyano-4-methylpentan-2-yl)diazenyl]-2,4-dimethylpentanenitrile Chemical compound CC(C)CC(C)(C#N)N=NC(C)(C#N)CC(C)C WYGWHHGCAGTUCH-UHFFFAOYSA-N 0.000 description 1
- AQKYLAIZOGOPAW-UHFFFAOYSA-N 2-methylbutan-2-yl 2,2-dimethylpropaneperoxoate Chemical compound CCC(C)(C)OOC(=O)C(C)(C)C AQKYLAIZOGOPAW-UHFFFAOYSA-N 0.000 description 1
- 229960000549 4-dimethylaminophenol Drugs 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- HNUALPPJLMYHDK-UHFFFAOYSA-N C[CH]C Chemical compound C[CH]C HNUALPPJLMYHDK-UHFFFAOYSA-N 0.000 description 1
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical class OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 description 1
- 235000011941 Tilia x europaea Nutrition 0.000 description 1
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 1
- 239000003082 abrasive agent Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 150000003926 acrylamides Chemical class 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000008064 anhydrides Chemical group 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000000149 argon plasma sintering Methods 0.000 description 1
- 239000011668 ascorbic acid Substances 0.000 description 1
- 229960005070 ascorbic acid Drugs 0.000 description 1
- 235000010323 ascorbic acid Nutrition 0.000 description 1
- KQNZLOUWXSAZGD-UHFFFAOYSA-N benzylperoxymethylbenzene Chemical compound C=1C=CC=CC=1COOCC1=CC=CC=C1 KQNZLOUWXSAZGD-UHFFFAOYSA-N 0.000 description 1
- 239000003139 biocide Substances 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Chemical class [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical group 0.000 description 1
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical class [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-M hydrogensulfate Chemical compound OS([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-M 0.000 description 1
- 230000005660 hydrophilic surface Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 238000004900 laundering Methods 0.000 description 1
- 239000004571 lime Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 150000002976 peresters Chemical class 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 230000005588 protonation Effects 0.000 description 1
- 238000005956 quaternization reaction Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000000375 suspending agent Substances 0.000 description 1
- WYKYCHHWIJXDAO-UHFFFAOYSA-N tert-butyl 2-ethylhexaneperoxoate Chemical compound CCCCC(CC)C(=O)OOC(C)(C)C WYKYCHHWIJXDAO-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000002888 zwitterionic surfactant Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3796—Amphoteric polymers or zwitterionic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
- C08F20/04—Acids, Metal salts or ammonium salts thereof
- C08F20/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F120/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
- C08F120/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F120/04—Acids; Metal salts or ammonium salts thereof
- C08F120/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/56—Acrylamide; Methacrylamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
- C08F220/60—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide containing nitrogen in addition to the carbonamido nitrogen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/65—Mixtures of anionic with cationic compounds
- C11D1/655—Mixtures of sulfonated products with alkylolamides of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/52—Amides or imides
- C08F220/54—Amides, e.g. N,N-dimethylacrylamide or N-isopropylacrylamide
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Detergent Compositions (AREA)
- Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US71912905P | 2005-09-21 | 2005-09-21 | |
| US60/719,129 | 2005-09-21 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2560041A1 CA2560041A1 (en) | 2007-03-21 |
| CA2560041C true CA2560041C (en) | 2013-03-26 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2560041A Expired - Fee Related CA2560041C (en) | 2005-09-21 | 2006-09-19 | Polymers for use in cleaning compositions |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7807766B2 (enExample) |
| EP (1) | EP1767554B1 (enExample) |
| JP (1) | JP5072299B2 (enExample) |
| KR (1) | KR101288785B1 (enExample) |
| AT (1) | ATE451403T1 (enExample) |
| CA (1) | CA2560041C (enExample) |
| DE (1) | DE602006010946D1 (enExample) |
| ES (1) | ES2337814T3 (enExample) |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| DE102007013141A1 (de) | 2007-03-15 | 2008-09-18 | Cognis Ip Management Gmbh | Amphotere Polymere als Soil Release Additive in Wasch- und Reinigungsmitteln |
| US7741265B2 (en) * | 2007-08-14 | 2010-06-22 | S.C. Johnson & Son, Inc. | Hard surface cleaner with extended residual cleaning benefit |
| EP2036973A1 (de) | 2007-09-07 | 2009-03-18 | Cognis IP Management GmbH | Tensidsysteme |
| US8211846B2 (en) | 2007-12-14 | 2012-07-03 | Lam Research Group | Materials for particle removal by single-phase and two-phase media |
| US7994112B2 (en) | 2009-01-26 | 2011-08-09 | Procter & Gamble Comany | Fabric softening laundry detergent |
| CA2713528A1 (en) * | 2008-02-01 | 2009-08-06 | The Procter & Gamble Company | Fabric softening laundry detergent |
| DE502008003350D1 (de) | 2008-03-07 | 2011-06-09 | Cognis Ip Man Gmbh | Verwendung von Polymeren zur Modifizierung der Oberflächenladung fester Teilchen |
| DE102008029939A1 (de) | 2008-06-26 | 2009-12-31 | Henkel Ag & Co. Kgaa | Schmutzabweisendes Reinigungsmittel |
| CA2755982A1 (en) * | 2009-03-20 | 2010-09-23 | Ciba Corporation | Fast drying ampholytic polymers for cleaning compositions |
| ES2415804T3 (es) | 2010-03-23 | 2013-07-29 | Cognis Ip Management Gmbh | Composición para lavar platos manualmente, suave con la piel |
| US8585829B2 (en) * | 2010-12-13 | 2013-11-19 | Ecolab Usa Inc. | Soil resistant floor cleaner |
| JP5726571B2 (ja) * | 2011-02-26 | 2015-06-03 | 大阪有機化学工業株式会社 | 感温性界面活性剤 |
| US9656104B2 (en) | 2011-07-08 | 2017-05-23 | Cognis Ip Management Gmbh | Use of microemulsions in cosmetic cleaning compositions |
| HUE026648T2 (en) | 2012-06-19 | 2016-07-28 | Chemische Fabrik Dr Weigert Gmbh & Co Kg | Machine cleaning of plastic parts |
| WO2014093249A1 (en) * | 2012-12-10 | 2014-06-19 | Hanley Howard J M | Co-polymer soil subgrade binder |
| WO2015028344A1 (de) | 2013-08-29 | 2015-03-05 | Basf Se | Kosmetische mittel |
| US20160237380A1 (en) * | 2013-10-11 | 2016-08-18 | Carl Freudenberg Kg | Set, comprising a cloth and a liquid, and composition for the hydrophilization of surfaces |
| HUE044064T2 (hu) | 2013-12-20 | 2019-09-30 | Chemische Fabrik Dr Weigert Gmbh & Co Kg | Fertõtlenítõszer |
| DE102016223590A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymer enthaltende reinigungsmittelzusammensetzungen |
| DE102016223588A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymere und deren verwendung in reinigungsmittel-zusammensetzungen |
| DE102016223586A1 (de) | 2016-11-28 | 2018-05-30 | Clariant International Ltd | Copolymere und deren verwendung in reinigungsmittel-zusammensetzungen |
| DE102018003035A1 (de) * | 2018-04-13 | 2019-10-17 | Henkel Ag & Co. Kgaa | Textilpflegeprodukt mit optional vernetztem Copolymer und Verfahren zur Ausrüstung von Textilien |
| EP3766952A1 (en) * | 2019-07-16 | 2021-01-20 | The Procter & Gamble Company | Disinfectant composition |
| EP3771339A1 (en) * | 2019-07-29 | 2021-02-03 | The Procter & Gamble Company | Disinfectant composition |
| EP3868854A1 (en) * | 2020-02-20 | 2021-08-25 | Clariant International Ltd | Cleaning compositions comprising copolymers and their use |
| CN120359286A (zh) | 2022-12-19 | 2025-07-22 | 联合利华知识产权控股有限公司 | 可发泡硬表面清洁组合物 |
| WO2025186296A1 (en) | 2024-03-06 | 2025-09-12 | Unilever Ip Holdings B.V. | A solid toilet block composition |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CA1180827A (en) | 1982-03-23 | 1985-01-08 | Michael Heskins | Polymeric flocculants |
| US4631136A (en) * | 1985-02-15 | 1986-12-23 | Jones Iii Reed W | Non-polluting non-toxic drilling fluid compositions and method of preparation |
| CA2072319C (en) | 1991-06-28 | 2005-11-22 | Shih-Ruey T. Chen | Ampholyte terpolymers providing superior conditioning properties in skin and nail care products |
| DE69320082T2 (de) | 1992-03-10 | 1999-05-06 | Rohm And Haas Co., Philadelphia, Pa. | Verwendung von wasserlöslichen Polymeren in Reinigungsmittelzusammensetzungen und für solche Anwendungen geeignete wasserlösliche Polymere |
| US5308532A (en) * | 1992-03-10 | 1994-05-03 | Rohm And Haas Company | Aminoacryloyl-containing terpolymers |
| JP2627129B2 (ja) * | 1992-09-22 | 1997-07-02 | ハイモ株式会社 | 乾燥痕防止剤及び乾燥痕防止法 |
| AU6915894A (en) | 1993-05-17 | 1994-12-12 | Massachusetts Institute Of Technology | Artificial receptors, antibodies, and enzymes |
| JP3247795B2 (ja) * | 1994-03-24 | 2002-01-21 | 日本下水道事業団 | 両性高分子汚泥脱水剤及びこれを用いた汚泥脱水方法 |
| SE503380C2 (sv) * | 1994-09-22 | 1996-06-03 | Wiklund Innovation Ab | Anordning för upphängning av undertak |
| JP3587267B2 (ja) * | 1994-10-07 | 2004-11-10 | 東洋紡績株式会社 | 耐塩水性ラテックス |
| JPH08194170A (ja) * | 1995-01-13 | 1996-07-30 | Olympus Optical Co Ltd | 立体視内視鏡 |
| CA2296719A1 (en) | 1997-07-23 | 1999-02-04 | Joseph Oreste Carnali | Automatic dishwashing compositions containing water soluble cationic or amphoteric polymers |
| US6007803A (en) | 1997-09-19 | 1999-12-28 | Geltex Pharmaceuticals, Inc. | Ionic polymers as toxin binding agents |
| JPH11193314A (ja) * | 1997-12-27 | 1999-07-21 | Lion Corp | 新規両性両親媒性高分子電解質 |
| US7006132B2 (en) * | 1998-02-25 | 2006-02-28 | California Institute Of Technology | Aperture coded camera for three dimensional imaging |
| AU5355599A (en) * | 1998-10-22 | 2000-05-04 | Rohm And Haas Company | Polymer compositions and a method of promoting soil release from fabrics using said polymer compositions |
| FR2796390B1 (fr) | 1999-07-15 | 2001-10-26 | Rhodia Chimie Sa | Utilisation d'un polymere amphotere pour traiter une surface dure |
| FR2796391B1 (fr) | 1999-07-15 | 2003-09-19 | Rhodia Chimie Sa | Composition nettoyante pour surfaces dures |
| BR0108014B1 (pt) * | 2000-02-02 | 2011-04-05 | composição para a lavagem e/ou enxágüe em lavagem de roupa e processo de liberação de sujeira de um artigo para lavagem de roupa. | |
| DE10037629A1 (de) * | 2000-08-02 | 2002-02-14 | Skw Bauwerkstoffe Deutschland | Wasserlösliche oder wasserquellbare sulfogruppenhaltige assoziativverdickende Copolymere, Verfahren zu deren Herstellung und deren Verwendung |
| JP4583569B2 (ja) * | 2000-09-22 | 2010-11-17 | オリンパス株式会社 | 観察光学系および撮像光学系 |
| CN1476593A (zh) * | 2000-10-25 | 2004-02-18 | �������ϰ�װ��������˾ | 用于座舱交通显示的飞行员可编程高度范围过滤器 |
| JP4430843B2 (ja) * | 2001-01-05 | 2010-03-10 | ザ プロクター アンド ギャンブル カンパニー | 第四級窒素含有及び／又は両性イオン性の高分子石鹸泡増進剤を含む液体洗剤組成物 |
| US6696067B2 (en) * | 2001-04-12 | 2004-02-24 | Ondeo Nalco Company | Cosmetic compositions containing dispersion polymers |
| JP2002344999A (ja) * | 2001-05-21 | 2002-11-29 | Asahi Optical Co Ltd | ステレオ画像撮像装置 |
| DE10243312A1 (de) | 2002-09-18 | 2004-04-01 | Cognis Deutschland Gmbh & Co. Kg | Bohrlochbehandlungsmittel mit niedrig-toxischer Ölphase |
| DE10334441A1 (de) | 2003-07-29 | 2005-02-17 | Cognis Deutschland Gmbh & Co. Kg | Bohrlochbehandlungsmittel, enthaltend Ethercarbonsäuren |
| FR2862235B1 (fr) | 2003-11-13 | 2007-12-28 | Rhodia Chimie Sa | Emulsion pour vehiculer une matiere active hydrophobe vers un substrat en milieu aqueux |
| US7646550B2 (en) * | 2006-02-13 | 2010-01-12 | 3M Innovative Properties Company | Three-channel camera systems with collinear apertures |
| US7372642B2 (en) * | 2006-02-13 | 2008-05-13 | 3M Innovative Properties Company | Three-channel camera systems with non-collinear apertures |
-
2006
- 2006-09-08 US US11/530,240 patent/US7807766B2/en active Active
- 2006-09-12 ES ES06019028T patent/ES2337814T3/es active Active
- 2006-09-12 AT AT06019028T patent/ATE451403T1/de not_active IP Right Cessation
- 2006-09-12 DE DE602006010946T patent/DE602006010946D1/de active Active
- 2006-09-12 EP EP06019028A patent/EP1767554B1/en active Active
- 2006-09-19 KR KR1020060090430A patent/KR101288785B1/ko not_active Expired - Fee Related
- 2006-09-19 CA CA2560041A patent/CA2560041C/en not_active Expired - Fee Related
- 2006-09-21 JP JP2006256013A patent/JP5072299B2/ja not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| US7807766B2 (en) | 2010-10-05 |
| KR101288785B1 (ko) | 2013-07-22 |
| EP1767554A1 (en) | 2007-03-28 |
| ATE451403T1 (de) | 2009-12-15 |
| EP1767554B1 (en) | 2009-12-09 |
| JP5072299B2 (ja) | 2012-11-14 |
| US20070179265A1 (en) | 2007-08-02 |
| DE602006010946D1 (de) | 2010-01-21 |
| JP2007100085A (ja) | 2007-04-19 |
| ES2337814T3 (es) | 2010-04-29 |
| KR20070033260A (ko) | 2007-03-26 |
| CA2560041A1 (en) | 2007-03-21 |
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| EEER | Examination request | ||
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Effective date: 20140919 |