CA2489511C - Glass fiber filled thermoplastic compositions with good surface appearance - Google Patents
Glass fiber filled thermoplastic compositions with good surface appearance Download PDFInfo
- Publication number
- CA2489511C CA2489511C CA2489511A CA2489511A CA2489511C CA 2489511 C CA2489511 C CA 2489511C CA 2489511 A CA2489511 A CA 2489511A CA 2489511 A CA2489511 A CA 2489511A CA 2489511 C CA2489511 C CA 2489511C
- Authority
- CA
- Canada
- Prior art keywords
- weight
- percent
- composition
- copolymer
- styrene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 93
- 239000003365 glass fiber Substances 0.000 title claims abstract description 43
- 229920001169 thermoplastic Polymers 0.000 title description 3
- 239000004416 thermosoftening plastic Substances 0.000 title description 3
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 45
- 229920001577 copolymer Polymers 0.000 claims abstract description 30
- 239000000945 filler Substances 0.000 claims abstract description 21
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229920001971 elastomer Polymers 0.000 claims abstract description 18
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 14
- 239000004952 Polyamide Substances 0.000 claims abstract description 14
- 229920002647 polyamide Polymers 0.000 claims abstract description 14
- 229910052882 wollastonite Inorganic materials 0.000 claims abstract description 14
- 239000010456 wollastonite Substances 0.000 claims abstract description 14
- 239000005060 rubber Substances 0.000 claims abstract description 13
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims abstract description 8
- 238000009757 thermoplastic moulding Methods 0.000 claims abstract description 8
- 239000002245 particle Substances 0.000 claims description 11
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical class CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 4
- 150000003440 styrenes Chemical group 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 3
- 125000005843 halogen group Chemical group 0.000 claims 1
- 238000000465 moulding Methods 0.000 abstract description 16
- 238000002360 preparation method Methods 0.000 abstract description 5
- 229920001778 nylon Polymers 0.000 description 10
- 229920005989 resin Polymers 0.000 description 10
- 239000011347 resin Substances 0.000 description 10
- -1 vinyl compounds Chemical class 0.000 description 10
- 239000004677 Nylon Substances 0.000 description 9
- 239000000806 elastomer Substances 0.000 description 5
- SCUZVMOVTVSBLE-UHFFFAOYSA-N prop-2-enenitrile;styrene Chemical compound C=CC#N.C=CC1=CC=CC=C1 SCUZVMOVTVSBLE-UHFFFAOYSA-N 0.000 description 5
- 229920000638 styrene acrylonitrile Polymers 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 4
- 229920006122 polyamide resin Polymers 0.000 description 4
- 229920002292 Nylon 6 Polymers 0.000 description 3
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 3
- 238000013329 compounding Methods 0.000 description 3
- 150000004985 diamines Chemical class 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 229920000305 Nylon 6,10 Polymers 0.000 description 2
- 229920002302 Nylon 6,6 Polymers 0.000 description 2
- 239000006096 absorbing agent Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 150000003951 lactams Chemical class 0.000 description 2
- 239000004611 light stabiliser Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- GUOSQNAUYHMCRU-UHFFFAOYSA-N 11-Aminoundecanoic acid Chemical compound NCCCCCCCCCCC(O)=O GUOSQNAUYHMCRU-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical compound CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- ZMWRRFHBXARRRT-UHFFFAOYSA-N 2-(benzotriazol-2-yl)-4,6-bis(2-methylbutan-2-yl)phenol Chemical compound CCC(C)(C)C1=CC(C(C)(C)CC)=CC(N2N=C3C=CC=CC3=N2)=C1O ZMWRRFHBXARRRT-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- PPKRHKAXRRVXBQ-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine;dodecanamide Chemical compound CCCCCCCCCCCC(N)=O.C1CC(N)CCC1CC1CCC(N)CC1 PPKRHKAXRRVXBQ-UHFFFAOYSA-N 0.000 description 1
- ACYXOHNDKRVKLH-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile prop-2-enoic acid Chemical compound OC(=O)C=C.N#CC=CC=CC1=CC=CC=C1 ACYXOHNDKRVKLH-UHFFFAOYSA-N 0.000 description 1
- 239000004609 Impact Modifier Substances 0.000 description 1
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 description 1
- 101100002888 Neurospora crassa (strain ATCC 24698 / 74-OR23-1A / CBS 708.71 / DSM 1257 / FGSC 987) asa-1 gene Proteins 0.000 description 1
- 229920000571 Nylon 11 Polymers 0.000 description 1
- 229920000299 Nylon 12 Polymers 0.000 description 1
- 229920001007 Nylon 4 Polymers 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000012963 UV stabilizer Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- 229920006127 amorphous resin Polymers 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 125000003710 aryl alkyl group Chemical group 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 238000012662 bulk polymerization Methods 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000011258 core-shell material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 150000001990 dicarboxylic acid derivatives Chemical class 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- NAQMVNRVTILPCV-UHFFFAOYSA-N hexamethylene diamine Natural products NCCCCCCN NAQMVNRVTILPCV-UHFFFAOYSA-N 0.000 description 1
- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 238000010191 image analysis Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 125000005395 methacrylic acid group Chemical class 0.000 description 1
- 239000006082 mold release agent Substances 0.000 description 1
- FJXWKBZRTWEWBJ-UHFFFAOYSA-N nonanediamide Chemical compound NC(=O)CCCCCCCC(N)=O FJXWKBZRTWEWBJ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- QLNJFJADRCOGBJ-UHFFFAOYSA-N propionamide Chemical compound CCC(N)=O QLNJFJADRCOGBJ-UHFFFAOYSA-N 0.000 description 1
- 229940080818 propionamide Drugs 0.000 description 1
- 230000003014 reinforcing effect Effects 0.000 description 1
- 239000003340 retarding agent Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- BPILDHPJSYVNAF-UHFFFAOYSA-M sodium;diiodomethanesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C(I)I BPILDHPJSYVNAF-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 239000011145 styrene acrylonitrile resin Substances 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/186,487 | 2002-07-01 | ||
| US10/186,487 US7135520B2 (en) | 2002-07-01 | 2002-07-01 | Glass fiber filled thermoplastic compositions with good surface appearance |
| PCT/US2003/020796 WO2004003075A1 (en) | 2002-07-01 | 2003-06-30 | Glass fiber filled thermoplastic compositions with good surface appearance |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CA2489511A1 CA2489511A1 (en) | 2004-01-08 |
| CA2489511C true CA2489511C (en) | 2011-03-08 |
Family
ID=29779898
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CA2489511A Expired - Fee Related CA2489511C (en) | 2002-07-01 | 2003-06-30 | Glass fiber filled thermoplastic compositions with good surface appearance |
Country Status (8)
| Country | Link |
|---|---|
| US (1) | US7135520B2 (enExample) |
| EP (1) | EP1519990A1 (enExample) |
| JP (1) | JP2005532435A (enExample) |
| CN (1) | CN1305957C (enExample) |
| AU (1) | AU2003247692A1 (enExample) |
| CA (1) | CA2489511C (enExample) |
| MX (1) | MXPA05000170A (enExample) |
| WO (1) | WO2004003075A1 (enExample) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20120100784A1 (en) * | 2006-09-15 | 2012-04-26 | Saint-Gobain Abrasifs | Microfiber Reinforcement for Abrasive Tools |
| US8808412B2 (en) | 2006-09-15 | 2014-08-19 | Saint-Gobain Abrasives, Inc. | Microfiber reinforcement for abrasive tools |
| WO2012053700A1 (ko) * | 2010-10-20 | 2012-04-26 | 제일모직 주식회사 | 열가소성 수지 조성물 및 그 성형품 |
| CN102775639B (zh) * | 2011-05-10 | 2013-12-11 | 郭晓明 | 磨碎纤维以及含磨碎纤维的玻璃纤维网盖及其制造方法 |
| KR101418755B1 (ko) * | 2011-10-05 | 2014-07-11 | 주식회사 엘지화학 | 광학 필름용 수지 조성물 및 이를 이용한 보상필름 |
| KR101711241B1 (ko) | 2013-08-29 | 2017-02-28 | 롯데첨단소재(주) | 내변색특성 및 내충격성이 우수한 열가소성 수지 조성물 |
| JP6250339B2 (ja) * | 2013-09-11 | 2017-12-20 | 旭化成株式会社 | ポリアミド樹脂組成物を成形して得られ、かつ、中空部分がある成形体の、内面平滑性を向上させる方法 |
| KR101717812B1 (ko) | 2013-11-29 | 2017-03-17 | 롯데첨단소재(주) | 내변색 및 광특성이 향상된 폴리에스테르 수지 조성물 |
| JP7433996B2 (ja) * | 2014-03-03 | 2024-02-20 | トリンゼオ ヨーロッパ ゲゼルシャフト ミット ベシュレンクテル ハフツング | 長繊維を含有するスチレン組成物 |
| US10711129B2 (en) | 2014-03-03 | 2020-07-14 | Trinseo Europe Gmbh | Styrenic composition containing long fibers |
| KR20180071835A (ko) | 2016-12-20 | 2018-06-28 | 롯데첨단소재(주) | 열가소성 수지 조성물 및 이를 이용한 성형품 |
| WO2022191439A1 (ko) * | 2021-03-08 | 2022-09-15 | (주) 엘지화학 | 열가소성 수지 조성물 및 이의 외장재 |
Family Cites Families (19)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01313557A (ja) * | 1988-06-14 | 1989-12-19 | Mitsubishi Gas Chem Co Inc | 成形材料用樹脂組成物 |
| JPH02150449A (ja) * | 1988-12-02 | 1990-06-08 | Mitsubishi Gas Chem Co Inc | 成形材料 |
| JPH0345640A (ja) * | 1989-07-14 | 1991-02-27 | Mitsubishi Monsanto Chem Co | ガラス繊維強化熱可塑性樹脂組成物 |
| DE3938421A1 (de) | 1989-11-18 | 1991-05-23 | Bayer Ag | Formmassen aus polyamiden und speziellen tert.-alkylester-haltigen pfropfpolymerisaten |
| JPH0481460A (ja) | 1990-07-24 | 1992-03-16 | Mitsubishi Rayon Co Ltd | 耐衝撃性、耐熱安定性に優れた樹脂組成物 |
| JPH04120167A (ja) * | 1990-09-11 | 1992-04-21 | Mitsubishi Rayon Co Ltd | 耐衝撃性、耐熱安定性に優れた熱可塑性樹脂組成物 |
| DE4114590A1 (de) | 1990-10-19 | 1992-04-23 | Bayer Ag | Schlagzaehe polyamid-formmassen |
| DE4114589A1 (de) | 1991-05-04 | 1992-11-05 | Bayer Ag | Polycarbonat/polyamid-formmassen |
| US5519094A (en) * | 1992-03-06 | 1996-05-21 | B. F. Goodrich Company | Fiber-reinforced thermoplastic molding compositions using a modified thermoplastic polyurethane |
| DE4211061A1 (de) | 1992-04-03 | 1993-10-07 | Basf Ag | Thermoplastische Formmassen auf der Basis von Polycarbonaten, Polyamiden und Styrol/Acrylnitril-Polymerisaten |
| DE19501998A1 (de) | 1995-01-24 | 1996-07-25 | Basf Ag | Thermoplastische Polyamidformmassen |
| WO1996036651A1 (en) | 1995-05-16 | 1996-11-21 | Bayer Antwerpen S.A./N.V. | Polymer composition with improved toughness |
| BE1009903A3 (nl) * | 1995-12-29 | 1997-10-07 | Dsm Nv | Rubber gemodificeerde polymeersamenstelling. |
| DE19731230A1 (de) * | 1997-07-21 | 1999-01-28 | Basf Ag | Statistische Copolyamide enthaltende Formmassen, Verfahren zu ihrer Herstellung und ihre Verwendung |
| JP4487154B2 (ja) * | 1998-09-17 | 2010-06-23 | 東洋紡績株式会社 | ポリアミド樹脂組成物 |
| JP2002069295A (ja) * | 2000-08-28 | 2002-03-08 | Toyobo Co Ltd | 無機強化ポリアミド樹脂組成物 |
| DE10024935A1 (de) * | 2000-05-19 | 2001-11-22 | Bayer Ag | Witterungsstabile Polymerblends |
| AR033368A1 (es) | 2000-05-19 | 2003-12-17 | Bayer Ag | Mezclas de polimeros que contienen poliamida, y polimeros modificados con caucho, uso de las mezclas de polimeros en la produccion de cuerpos moldeados, y cuerpos moldeados, partes de gabinetes, placas de cubierta y piezas para el sector automotriz obtenibles a partir de las mezclas de polimeros |
| JP2003082228A (ja) * | 2001-09-14 | 2003-03-19 | Kuraray Co Ltd | ポリアミド組成物 |
-
2002
- 2002-07-01 US US10/186,487 patent/US7135520B2/en not_active Expired - Fee Related
-
2003
- 2003-06-30 AU AU2003247692A patent/AU2003247692A1/en not_active Abandoned
- 2003-06-30 CN CNB038156458A patent/CN1305957C/zh not_active Expired - Fee Related
- 2003-06-30 EP EP03762301A patent/EP1519990A1/en not_active Withdrawn
- 2003-06-30 CA CA2489511A patent/CA2489511C/en not_active Expired - Fee Related
- 2003-06-30 JP JP2004518197A patent/JP2005532435A/ja active Pending
- 2003-06-30 MX MXPA05000170A patent/MXPA05000170A/es active IP Right Grant
- 2003-06-30 WO PCT/US2003/020796 patent/WO2004003075A1/en not_active Ceased
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005532435A (ja) | 2005-10-27 |
| US20040002568A1 (en) | 2004-01-01 |
| CN1665878A (zh) | 2005-09-07 |
| EP1519990A1 (en) | 2005-04-06 |
| MXPA05000170A (es) | 2005-12-06 |
| CA2489511A1 (en) | 2004-01-08 |
| US7135520B2 (en) | 2006-11-14 |
| WO2004003075A1 (en) | 2004-01-08 |
| CN1305957C (zh) | 2007-03-21 |
| AU2003247692A1 (en) | 2004-01-19 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EEER | Examination request | ||
| MKLA | Lapsed |
Effective date: 20170630 |