CA1311603C - Catalyseur servant a la reduction de la teneur en no _des gaz d'echappement et procede connexe - Google Patents

Catalyseur servant a la reduction de la teneur en no _des gaz d'echappement et procede connexe

Info

Publication number
CA1311603C
CA1311603C CA000557577A CA557577A CA1311603C CA 1311603 C CA1311603 C CA 1311603C CA 000557577 A CA000557577 A CA 000557577A CA 557577 A CA557577 A CA 557577A CA 1311603 C CA1311603 C CA 1311603C
Authority
CA
Canada
Prior art keywords
zsm
catalyst
nox
dri
zeolite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
CA000557577A
Other languages
English (en)
Inventor
Thomas R. Kiliany, Jr.
Sowmithri Krishnamurphy
John Paul Mcwilliams
David Andrew Pappal
Catherine Teague Sigal
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
ExxonMobil Oil Corp
Original Assignee
Mobil Oil Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=21753381&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CA1311603(C) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Mobil Oil Corp filed Critical Mobil Oil Corp
Application granted granted Critical
Publication of CA1311603C publication Critical patent/CA1311603C/fr
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/38—Removing components of undefined structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/02—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances
    • H01B3/08—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances quartz; glass; glass wool; slag wool; vitreous enamels
    • H01B3/082—Wires with glass or glass wool
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
    • H01B3/308—Wires with resins
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/26—After treatment, characterised by the effect to be obtained to stabilize the total catalyst structure
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/36—Steaming
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/65—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the ferrierite type, e.g. types ZSM-21, ZSM-35 or ZSM-38, as exemplified by patent documents US4046859, US4016245 and US4046859, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
  • Treating Waste Gases (AREA)
  • Cylinder Crankcases Of Internal Combustion Engines (AREA)
  • Vaporization, Distillation, Condensation, Sublimation, And Cold Traps (AREA)
  • Glass Compositions (AREA)
  • Crystals, And After-Treatments Of Crystals (AREA)
CA000557577A 1987-02-06 1988-01-28 Catalyseur servant a la reduction de la teneur en no _des gaz d'echappement et procede connexe Expired - Lifetime CA1311603C (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US012,097 1987-02-06
US07/012,097 US4778665A (en) 1986-09-09 1987-02-06 Abatement of NOx in exhaust gases

Publications (1)

Publication Number Publication Date
CA1311603C true CA1311603C (fr) 1992-12-22

Family

ID=21753381

Family Applications (1)

Application Number Title Priority Date Filing Date
CA000557577A Expired - Lifetime CA1311603C (fr) 1987-02-06 1988-01-28 Catalyseur servant a la reduction de la teneur en no _des gaz d'echappement et procede connexe

Country Status (19)

Country Link
US (1) US4778665A (fr)
EP (1) EP0284181B2 (fr)
JP (1) JP2515365B2 (fr)
KR (1) KR960003151B1 (fr)
AT (1) ATE86879T1 (fr)
AU (1) AU609083B2 (fr)
BR (1) BR8800486A (fr)
CA (1) CA1311603C (fr)
DE (1) DE3879244T3 (fr)
DK (1) DK170271B1 (fr)
ES (1) ES2038748T3 (fr)
FI (1) FI85823C (fr)
GR (1) GR3007406T3 (fr)
MX (1) MX165201B (fr)
MY (1) MY100859A (fr)
NO (1) NO169700C (fr)
PT (1) PT86707B (fr)
TR (1) TR24162A (fr)
ZA (1) ZA88832B (fr)

Families Citing this family (49)

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US4980052A (en) * 1988-12-05 1990-12-25 Mobil Oil Corporation Catalytic cracking of hydrocarbons
CA1295813C (fr) * 1988-12-14 1992-02-18 Karl T. Chuang Reduction des oxydes nitriques
US5024981A (en) * 1989-04-20 1991-06-18 Engelhard Corporation Staged metal-promoted zeolite catalysts and method for catalytic reduction of nitrogen oxides using the same
JP2928853B2 (ja) * 1989-10-02 1999-08-03 東ソー株式会社 窒素酸化物接触分解触媒及び接触分解方法
US4973399A (en) * 1989-11-03 1990-11-27 Mobil Oil Corporation Catalytic cracking of hydrocarbons
US4988432A (en) * 1989-12-28 1991-01-29 Mobil Oil Corporation Reducing NOx emissions with antimony additive
US5002654A (en) * 1989-12-28 1991-03-26 Mobil Oil Corporation Reducing NOx emissions with zinc catalyst
US4986897A (en) * 1989-12-28 1991-01-22 Mobil Oil Corporation Catalytic conversion of NOx with NH3
US5120516A (en) * 1990-01-08 1992-06-09 Physical Sciences, Inc. Process for removing nox emissions from combustion effluents
US5037538A (en) * 1990-02-26 1991-08-06 Mobil Oil Corporation Catalytic cracking process with isolated catalyst for conversion of NO.sub.x
US5173278A (en) * 1991-03-15 1992-12-22 Mobil Oil Corporation Denitrification of flue gas from catalytic cracking
US5143707A (en) * 1991-07-24 1992-09-01 Mobil Oil Corporation Selective catalytic reduction (SCR) of nitrogen oxides
US5316661A (en) * 1992-07-08 1994-05-31 Mobil Oil Corporation Processes for converting feedstock organic compounds
US5310714A (en) * 1992-07-08 1994-05-10 Mobil Oil Corp. Synthesis of zeolite films bonded to substrates, structures and uses thereof
US5552128A (en) * 1993-08-03 1996-09-03 Mobil Oil Corporation Selective catalytic reduction of nitrogen oxides
US5367889A (en) * 1993-08-25 1994-11-29 Lanyon; Joseph G. Exhaust treatment apparatus
US5417949A (en) * 1993-08-25 1995-05-23 Mobil Oil Corporation NOx abatement process
US5413699A (en) * 1993-10-14 1995-05-09 Mobil Oil Corporation FCC process with fines tolerant SCR reactor
US5589147A (en) * 1994-07-07 1996-12-31 Mobil Oil Corporation Catalytic system for the reducton of nitrogen oxides
US5520895A (en) * 1994-07-07 1996-05-28 Mobil Oil Corporation Method for the reduction of nitrogen oxides using iron impregnated zeolites
US5482692A (en) * 1994-07-07 1996-01-09 Mobil Oil Corporation Selective catalytic reduction of nitrogen oxides using a ferrocene impregnated zeolite catalyst
US5451387A (en) * 1994-07-07 1995-09-19 Mobil Oil Corporation Selective catalytic reduction of nitrogen oxides using an iron impregnated zeolite catalyst
US5552129A (en) * 1994-07-07 1996-09-03 Mobil Oil Corporation Catalytic system for the reduction of nitrogen oxides
FI98926C (fi) * 1994-10-05 1997-09-10 Valtion Teknillinen Menetelmä ammoniakin poistamiseksi kaasutuskaasusta
US5565394A (en) * 1994-10-11 1996-10-15 Corning Incorporated Low expansion molecular sieves and method of making same
GB9802504D0 (en) 1998-02-06 1998-04-01 Johnson Matthey Plc Improvements in emission control
US8833062B1 (en) 2013-03-15 2014-09-16 Daimier Ag Catalytic reduction of NOx
FR2806322B1 (fr) * 2000-03-14 2002-04-26 Abb Alstom Power Nv Utilisation de zeolithes pour reduire les emissions d'oxydes nitreux
DE10020100A1 (de) * 2000-04-22 2001-10-31 Dmc2 Degussa Metals Catalysts Verfahren und Katalysator zur Reduktion von Stickoxiden
EP1164266B1 (fr) * 2000-06-13 2009-10-07 Ford Global Technologies, Inc. Procédé pour l'optimisation de l'addition d'un reducteur à un catalyseur SCR d'un moteur à combustion interne
DE10123402A1 (de) * 2001-05-14 2002-11-28 Fraunhofer Ges Forschung Verfahren zum Behandeln von ammoniakhaltigen Rauchgasen
US20040074809A1 (en) * 2002-10-21 2004-04-22 George Yaluris Reduction of gas phase reduced nitrogen species in partial burn FCC processes
JP4334316B2 (ja) * 2003-10-16 2009-09-30 原子燃料工業株式会社 重ウラン酸アンモニウム粒子製造装置
US20050100494A1 (en) 2003-11-06 2005-05-12 George Yaluris Ferrierite compositions for reducing NOx emissions during fluid catalytic cracking
WO2005061387A1 (fr) * 2003-12-24 2005-07-07 Nuclear Fuel Industries, Ltd. Alimentation liquide au goutte-a-goutte et methode correspondante, obtention d'une solution de nitrate d'uranlye, et obtention d'une solution d'alcool polyvinylique
US7378069B2 (en) * 2004-07-27 2008-05-27 Los Alamos National Security, Llc Catalyst and method for reduction of nitrogen oxides
WO2006031297A2 (fr) 2004-07-27 2006-03-23 The Regents Of The University Of California Catalyseurs et procede pour la reduction d'oxydes d'azote
KR101382014B1 (ko) * 2005-04-27 2014-04-04 더블유.알. 그레이스 앤드 캄파니-콘. 유동상 접촉 분해 중의 ＮＯｘ 방출 감소를 위한 조성물 및공정
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US7914666B1 (en) * 2006-09-29 2011-03-29 Uop Llc Low NOx FCC catalyst regeneration process
DE102007022678A1 (de) 2007-05-11 2008-11-13 Hydraulik-Ring Gmbh Abgasnachbehandlungseinheit auf Ammoniakbasis und Verfahren zur Reinigung stickoxidhaltiger Abgase von Verbrennungskraftmaschinen
FR2945962B1 (fr) * 2009-05-29 2012-06-08 Peugeot Citroen Automobiles Sa Dispositif, vehicule comportant ce dispositif et procede de traitement des gaz d'echappement
EP2308596B1 (fr) 2009-10-07 2016-09-21 Ford Global Technologies, LLC Catalyseur à base de zéolithe au cuivre utilisé dans le procédé SCR pour la réduction de NOx et sa methode de préparation
EP2817083A1 (fr) * 2012-02-23 2014-12-31 Johnson Matthey Process Technologies, Inc. Procédé d'élimination de nox à partir de gaz de combustion
SG11201506038YA (en) 2013-02-22 2015-09-29 Johnson Matthey Process Technologies Inc Process of removing hcn from flue gas
US8850802B1 (en) 2013-03-15 2014-10-07 Daimler Ag Catalytic reduction of NOx
GB201608643D0 (en) * 2016-05-17 2016-06-29 Thermo Fisher Scient Bremen Elemental analysis system and method
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Also Published As

Publication number Publication date
MY100859A (en) 1991-03-15
NO169700C (no) 1992-08-05
DK170271B1 (da) 1995-07-24
BR8800486A (pt) 1988-09-27
NO880504D0 (no) 1988-02-04
JP2515365B2 (ja) 1996-07-10
TR24162A (tr) 1991-05-01
DE3879244T3 (de) 2002-11-07
US4778665A (en) 1988-10-18
ZA88832B (en) 1989-10-25
EP0284181B2 (fr) 2002-03-06
EP0284181B1 (fr) 1993-03-17
FI880542A0 (fi) 1988-02-05
DK58888D0 (da) 1988-02-05
KR960003151B1 (en) 1996-03-05
DK58888A (da) 1988-08-07
PT86707B (pt) 1992-04-30
JPS6456125A (en) 1989-03-03
DE3879244D1 (de) 1993-04-22
FI85823C (fi) 1992-06-10
NO169700B (no) 1992-04-21
PT86707A (pt) 1988-03-01
ES2038748T3 (es) 1993-08-01
GR3007406T3 (fr) 1993-07-30
MX165201B (es) 1992-10-30
DE3879244T2 (de) 1993-06-24
EP0284181A1 (fr) 1988-09-28
AU1090588A (en) 1988-08-11
FI85823B (fi) 1992-02-28
ATE86879T1 (de) 1993-04-15
KR880009691A (ko) 1988-10-04
NO880504L (no) 1988-08-08
AU609083B2 (en) 1991-04-26
FI880542A (fi) 1988-08-07

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