BRPI0812643B1 - interpolímero de etileno/a-olefina - Google Patents
interpolímero de etileno/a-olefina Download PDFInfo
- Publication number
- BRPI0812643B1 BRPI0812643B1 BRPI0812643A BRPI0812643A BRPI0812643B1 BR PI0812643 B1 BRPI0812643 B1 BR PI0812643B1 BR PI0812643 A BRPI0812643 A BR PI0812643A BR PI0812643 A BRPI0812643 A BR PI0812643A BR PI0812643 B1 BRPI0812643 B1 BR PI0812643B1
- Authority
- BR
- Brazil
- Prior art keywords
- ethylene
- interpolymer
- polymer
- olefin
- percent
- Prior art date
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- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 title claims description 164
- 239000005977 Ethylene Substances 0.000 title claims description 164
- 239000004711 α-olefin Substances 0.000 title claims description 36
- 229920000642 polymer Polymers 0.000 claims description 163
- 239000000203 mixture Substances 0.000 claims description 56
- 239000000178 monomer Substances 0.000 claims description 40
- 238000002844 melting Methods 0.000 claims description 26
- 229920001577 copolymer Polymers 0.000 claims description 25
- 238000009826 distribution Methods 0.000 claims description 25
- 230000008018 melting Effects 0.000 claims description 25
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 16
- 238000005259 measurement Methods 0.000 claims description 15
- 229920005604 random copolymer Polymers 0.000 claims description 10
- 229910052775 Thulium Inorganic materials 0.000 claims description 6
- 239000013256 coordination polymer Substances 0.000 description 105
- 239000003054 catalyst Substances 0.000 description 51
- 238000000034 method Methods 0.000 description 38
- -1 2,6-di (1methylethyl) phenyl Chemical group 0.000 description 34
- 229920001400 block copolymer Polymers 0.000 description 26
- 150000001993 dienes Chemical class 0.000 description 24
- 239000000243 solution Substances 0.000 description 23
- 239000002904 solvent Substances 0.000 description 17
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 16
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 16
- 238000006116 polymerization reaction Methods 0.000 description 15
- KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 14
- 238000005481 NMR spectroscopy Methods 0.000 description 14
- 150000001336 alkenes Chemical class 0.000 description 14
- 238000000113 differential scanning calorimetry Methods 0.000 description 14
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 14
- 239000003921 oil Substances 0.000 description 13
- 230000000052 comparative effect Effects 0.000 description 12
- 230000004044 response Effects 0.000 description 12
- 239000000126 substance Substances 0.000 description 12
- 238000012546 transfer Methods 0.000 description 12
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 11
- 230000008569 process Effects 0.000 description 11
- RFFLAFLAYFXFSW-UHFFFAOYSA-N 1,2-dichlorobenzene Chemical compound ClC1=CC=CC=C1Cl RFFLAFLAYFXFSW-UHFFFAOYSA-N 0.000 description 10
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 10
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 239000000523 sample Substances 0.000 description 10
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Natural products C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 9
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 238000005194 fractionation Methods 0.000 description 9
- 238000005227 gel permeation chromatography Methods 0.000 description 9
- 238000005033 Fourier transform infrared spectroscopy Methods 0.000 description 8
- 238000004364 calculation method Methods 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 8
- 125000000524 functional group Chemical group 0.000 description 8
- YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 8
- 239000000047 product Substances 0.000 description 8
- 239000007787 solid Substances 0.000 description 8
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 7
- 239000000155 melt Substances 0.000 description 7
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 7
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 7
- 229920006030 multiblock copolymer Polymers 0.000 description 7
- TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 7
- 229910052757 nitrogen Inorganic materials 0.000 description 7
- 229920000573 polyethylene Polymers 0.000 description 7
- OJOWICOBYCXEKR-APPZFPTMSA-N (1S,4R)-5-ethylidenebicyclo[2.2.1]hept-2-ene Chemical compound CC=C1C[C@@H]2C[C@@H]1C=C2 OJOWICOBYCXEKR-APPZFPTMSA-N 0.000 description 6
- PRBHEGAFLDMLAL-GQCTYLIASA-N (4e)-hexa-1,4-diene Chemical class C\C=C\CC=C PRBHEGAFLDMLAL-GQCTYLIASA-N 0.000 description 6
- XWJBRBSPAODJER-UHFFFAOYSA-N 1,7-octadiene Chemical class C=CCCCCC=C XWJBRBSPAODJER-UHFFFAOYSA-N 0.000 description 6
- AFFLGGQVNFXPEV-UHFFFAOYSA-N 1-decene Chemical compound CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 6
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 6
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical compound CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 239000004698 Polyethylene Substances 0.000 description 6
- LPIQUOYDBNQMRZ-UHFFFAOYSA-N cyclopentene Chemical compound C1CC=CC1 LPIQUOYDBNQMRZ-UHFFFAOYSA-N 0.000 description 6
- 229920001971 elastomer Polymers 0.000 description 6
- 239000000806 elastomer Substances 0.000 description 6
- 238000010828 elution Methods 0.000 description 6
- MGDOJPNDRJNJBK-UHFFFAOYSA-N ethylaluminum Chemical compound [Al].C[CH2] MGDOJPNDRJNJBK-UHFFFAOYSA-N 0.000 description 6
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical class CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 6
- 229920000098 polyolefin Polymers 0.000 description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 5
- 238000004566 IR spectroscopy Methods 0.000 description 5
- 238000011088 calibration curve Methods 0.000 description 5
- 125000004432 carbon atom Chemical group C* 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- 238000001816 cooling Methods 0.000 description 5
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 238000010348 incorporation Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000011541 reaction mixture Substances 0.000 description 5
- 238000003756 stirring Methods 0.000 description 5
- 238000003786 synthesis reaction Methods 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- WTQBISBWKRKLIJ-UHFFFAOYSA-N 5-methylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C)CC1C=C2 WTQBISBWKRKLIJ-UHFFFAOYSA-N 0.000 description 4
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- 229920002472 Starch Polymers 0.000 description 4
- 239000000654 additive Substances 0.000 description 4
- 238000004458 analytical method Methods 0.000 description 4
- HGCIXCUEYOPUTN-UHFFFAOYSA-N cyclohexene Chemical compound C1CCC=CC1 HGCIXCUEYOPUTN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- SOEVKJXMZBAALG-UHFFFAOYSA-N octylalumane Chemical compound CCCCCCCC[AlH2] SOEVKJXMZBAALG-UHFFFAOYSA-N 0.000 description 4
- 229920002959 polymer blend Polymers 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 239000008107 starch Substances 0.000 description 4
- 235000019698 starch Nutrition 0.000 description 4
- PBKONEOXTCPAFI-UHFFFAOYSA-N 1,2,4-trichlorobenzene Chemical group ClC1=CC=C(Cl)C(Cl)=C1 PBKONEOXTCPAFI-UHFFFAOYSA-N 0.000 description 3
- JQOATXDBTYKMEX-UHFFFAOYSA-N CC[Zn] Chemical compound CC[Zn] JQOATXDBTYKMEX-UHFFFAOYSA-N 0.000 description 3
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000012986 chain transfer agent Substances 0.000 description 3
- 238000012512 characterization method Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 230000004927 fusion Effects 0.000 description 3
- 229910052735 hafnium Inorganic materials 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- SJYNFBVQFBRSIB-UHFFFAOYSA-N norbornadiene Chemical compound C1=CC2C=CC1C2 SJYNFBVQFBRSIB-UHFFFAOYSA-N 0.000 description 3
- RGSFGYAAUTVSQA-UHFFFAOYSA-N pentamethylene Natural products C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 230000000379 polymerizing effect Effects 0.000 description 3
- 239000002244 precipitate Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 3
- 239000003039 volatile agent Substances 0.000 description 3
- ZGEGCLOFRBLKSE-UHFFFAOYSA-N 1-Heptene Chemical compound CCCCCC=C ZGEGCLOFRBLKSE-UHFFFAOYSA-N 0.000 description 2
- CRSBERNSMYQZNG-UHFFFAOYSA-N 1-dodecene Chemical compound CCCCCCCCCCC=C CRSBERNSMYQZNG-UHFFFAOYSA-N 0.000 description 2
- GQEZCXVZFLOKMC-UHFFFAOYSA-N 1-hexadecene Chemical compound CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 description 2
- HFDVRLIODXPAHB-UHFFFAOYSA-N 1-tetradecene Chemical compound CCCCCCCCCCCCC=C HFDVRLIODXPAHB-UHFFFAOYSA-N 0.000 description 2
- AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical class C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 2
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004322 Butylated hydroxytoluene Substances 0.000 description 2
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 2
- UQTVWGHDJHVLEP-UHFFFAOYSA-N CCCC[Zn]CCCC Chemical compound CCCC[Zn]CCCC UQTVWGHDJHVLEP-UHFFFAOYSA-N 0.000 description 2
- 229920002943 EPDM rubber Polymers 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 239000004609 Impact Modifier Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 238000013019 agitation Methods 0.000 description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- 125000003118 aryl group Chemical group 0.000 description 2
- 239000012267 brine Substances 0.000 description 2
- 229940095259 butylated hydroxytoluene Drugs 0.000 description 2
- 235000010354 butylated hydroxytoluene Nutrition 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 239000007795 chemical reaction product Substances 0.000 description 2
- MGNZXYYWBUKAII-UHFFFAOYSA-N cyclohexa-1,3-diene Chemical compound C1CC=CC=C1 MGNZXYYWBUKAII-UHFFFAOYSA-N 0.000 description 2
- URYYVOIYTNXXBN-UPHRSURJSA-N cyclooctene Chemical compound C1CCC\C=C/CC1 URYYVOIYTNXXBN-UPHRSURJSA-N 0.000 description 2
- 239000004913 cyclooctene Substances 0.000 description 2
- NLDGJRWPPOSWLC-UHFFFAOYSA-N deca-1,9-diene Chemical compound C=CCCCCCCC=C NLDGJRWPPOSWLC-UHFFFAOYSA-N 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- HQWPLXHWEZZGKY-UHFFFAOYSA-N diethylzinc Chemical compound CC[Zn]CC HQWPLXHWEZZGKY-UHFFFAOYSA-N 0.000 description 2
- 229920001038 ethylene copolymer Polymers 0.000 description 2
- 239000000706 filtrate Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000004128 high performance liquid chromatography Methods 0.000 description 2
- 229920001519 homopolymer Polymers 0.000 description 2
- VAMFXQBUQXONLZ-UHFFFAOYSA-N icos-1-ene Chemical compound CCCCCCCCCCCCCCCCCCC=C VAMFXQBUQXONLZ-UHFFFAOYSA-N 0.000 description 2
- 230000000977 initiatory effect Effects 0.000 description 2
- 230000010354 integration Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- JACMPVXHEARCBO-UHFFFAOYSA-N n-pentylpentan-1-amine Chemical compound CCCCCNCCCCC JACMPVXHEARCBO-UHFFFAOYSA-N 0.000 description 2
- JFNLZVQOOSMTJK-KNVOCYPGSA-N norbornene Chemical compound C1[C@@H]2CC[C@H]1C=C2 JFNLZVQOOSMTJK-KNVOCYPGSA-N 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N octadec-1-ene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- 239000012044 organic layer Substances 0.000 description 2
- 125000001037 p-tolyl group Chemical group [H]C1=C([H])C(=C([H])C([H])=C1*)C([H])([H])[H] 0.000 description 2
- 239000008188 pellet Substances 0.000 description 2
- 150000002978 peroxides Chemical class 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 238000010992 reflux Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 238000007789 sealing Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- 238000001542 size-exclusion chromatography Methods 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- KEMUGHMYINTXKW-NQOXHWNZSA-N (1z,5z)-cyclododeca-1,5-diene Chemical compound C1CCC\C=C/CC\C=C/CC1 KEMUGHMYINTXKW-NQOXHWNZSA-N 0.000 description 1
- RJUCIROUEDJQIB-GQCTYLIASA-N (6e)-octa-1,6-diene Chemical compound C\C=C\CCCC=C RJUCIROUEDJQIB-GQCTYLIASA-N 0.000 description 1
- PMJHHCWVYXUKFD-SNAWJCMRSA-N (E)-1,3-pentadiene Chemical compound C\C=C\C=C PMJHHCWVYXUKFD-SNAWJCMRSA-N 0.000 description 1
- PRBHEGAFLDMLAL-UHFFFAOYSA-N 1,5-Hexadiene Natural products CC=CCC=C PRBHEGAFLDMLAL-UHFFFAOYSA-N 0.000 description 1
- VYXHVRARDIDEHS-UHFFFAOYSA-N 1,5-cyclooctadiene Chemical compound C1CC=CCCC=C1 VYXHVRARDIDEHS-UHFFFAOYSA-N 0.000 description 1
- 239000004912 1,5-cyclooctadiene Substances 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- PPWUTZVGSFPZOC-UHFFFAOYSA-N 1-methyl-2,3,3a,4-tetrahydro-1h-indene Chemical compound C1C=CC=C2C(C)CCC21 PPWUTZVGSFPZOC-UHFFFAOYSA-N 0.000 description 1
- DKCPKDPYUFEZCP-UHFFFAOYSA-N 2,6-di-tert-butylphenol Chemical compound CC(C)(C)C1=CC=CC(C(C)(C)C)=C1O DKCPKDPYUFEZCP-UHFFFAOYSA-N 0.000 description 1
- YXRZFCBXBJIBAP-UHFFFAOYSA-N 2,6-dimethylocta-1,7-diene Chemical compound C=CC(C)CCCC(C)=C YXRZFCBXBJIBAP-UHFFFAOYSA-N 0.000 description 1
- ATGFTMUSEPZNJD-UHFFFAOYSA-N 2,6-diphenylphenol Chemical compound OC1=C(C=2C=CC=CC=2)C=CC=C1C1=CC=CC=C1 ATGFTMUSEPZNJD-UHFFFAOYSA-N 0.000 description 1
- GWYSGBSSRNFQBQ-UHFFFAOYSA-L 2,6-ditert-butylphenolate;octylaluminum(2+) Chemical compound CCCCCCCC[Al+2].CC(C)(C)C1=CC=CC(C(C)(C)C)=C1[O-].CC(C)(C)C1=CC=CC(C(C)(C)C)=C1[O-] GWYSGBSSRNFQBQ-UHFFFAOYSA-L 0.000 description 1
- SDTMFDGELKWGFT-UHFFFAOYSA-N 2-methylpropan-2-olate Chemical compound CC(C)(C)[O-] SDTMFDGELKWGFT-UHFFFAOYSA-N 0.000 description 1
- MHGWNYIERCEISS-UHFFFAOYSA-N 2-methylpropyl(dioctadecyl)alumane Chemical compound CCCCCCCCCCCCCCCCCC[Al](CC(C)C)CCCCCCCCCCCCCCCCCC MHGWNYIERCEISS-UHFFFAOYSA-N 0.000 description 1
- KPYCVQASEGGKEG-UHFFFAOYSA-N 3-hydroxyoxolane-2,5-dione Chemical compound OC1CC(=O)OC1=O KPYCVQASEGGKEG-UHFFFAOYSA-N 0.000 description 1
- YHQXBTXEYZIYOV-UHFFFAOYSA-N 3-methylbut-1-ene Chemical compound CC(C)C=C YHQXBTXEYZIYOV-UHFFFAOYSA-N 0.000 description 1
- LDTAOIUHUHHCMU-UHFFFAOYSA-N 3-methylpent-1-ene Chemical compound CCC(C)C=C LDTAOIUHUHHCMU-UHFFFAOYSA-N 0.000 description 1
- UFERIGCCDYCZLN-UHFFFAOYSA-N 3a,4,7,7a-tetrahydro-1h-indene Chemical compound C1C=CCC2CC=CC21 UFERIGCCDYCZLN-UHFFFAOYSA-N 0.000 description 1
- FSWNZCWHTXTQBY-UHFFFAOYSA-N 4,6-dimethylhept-1-ene Chemical compound CC(C)CC(C)CC=C FSWNZCWHTXTQBY-UHFFFAOYSA-N 0.000 description 1
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- BBDKZWKEPDTENS-UHFFFAOYSA-N 4-Vinylcyclohexene Chemical compound C=CC1CCC=CC1 BBDKZWKEPDTENS-UHFFFAOYSA-N 0.000 description 1
- NWPQAENAYWENSD-UHFFFAOYSA-N 5-butylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=CCCC)CC1C=C2 NWPQAENAYWENSD-UHFFFAOYSA-N 0.000 description 1
- IZLXZVWFPZWXMZ-UHFFFAOYSA-N 5-cyclohexylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1=CC2CC1CC2=C1CCCCC1 IZLXZVWFPZWXMZ-UHFFFAOYSA-N 0.000 description 1
- DGBJYYFKBCUCNY-UHFFFAOYSA-N 5-cyclopentylbicyclo[2.2.1]hept-2-ene Chemical compound C1CCCC1C1C(C=C2)CC2C1 DGBJYYFKBCUCNY-UHFFFAOYSA-N 0.000 description 1
- INYHZQLKOKTDAI-UHFFFAOYSA-N 5-ethenylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=C)CC1C=C2 INYHZQLKOKTDAI-UHFFFAOYSA-N 0.000 description 1
- VSQLAQKFRFTMNS-UHFFFAOYSA-N 5-methylhexa-1,4-diene Chemical compound CC(C)=CCC=C VSQLAQKFRFTMNS-UHFFFAOYSA-N 0.000 description 1
- CJQNJRMLJAAXOS-UHFFFAOYSA-N 5-prop-1-enylbicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(C=CC)CC1C=C2 CJQNJRMLJAAXOS-UHFFFAOYSA-N 0.000 description 1
- UGJBFMMPNVKBPX-UHFFFAOYSA-N 5-propan-2-ylidenebicyclo[2.2.1]hept-2-ene Chemical compound C1C2C(=C(C)C)CC1C=C2 UGJBFMMPNVKBPX-UHFFFAOYSA-N 0.000 description 1
- OOVQLEHBRDIXDZ-UHFFFAOYSA-N 7-ethenylbicyclo[4.2.0]octa-1,3,5-triene Chemical class C1=CC=C2C(C=C)CC2=C1 OOVQLEHBRDIXDZ-UHFFFAOYSA-N 0.000 description 1
- JUOCTSZRGAFSKS-UHFFFAOYSA-N CCCCCC[Zn]CCCCCC Chemical compound CCCCCC[Zn]CCCCCC JUOCTSZRGAFSKS-UHFFFAOYSA-N 0.000 description 1
- VCFQUHAHCQJWKL-UHFFFAOYSA-N CC[Zn+].CC(C)(C)[O-] Chemical compound CC[Zn+].CC(C)(C)[O-] VCFQUHAHCQJWKL-UHFFFAOYSA-N 0.000 description 1
- DVZWQGLVEOWFOU-UHFFFAOYSA-N C[Hf]C Chemical compound C[Hf]C DVZWQGLVEOWFOU-UHFFFAOYSA-N 0.000 description 1
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- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- XXUJMEYKYHETBZ-UHFFFAOYSA-N ethyl 4-nitrophenyl ethylphosphonate Chemical compound CCOP(=O)(CC)OC1=CC=C([N+]([O-])=O)C=C1 XXUJMEYKYHETBZ-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- ZPGYSJMGYASTOM-UHFFFAOYSA-N ethyl(naphthalen-1-yl)azanide;octylaluminum(2+) Chemical compound CCCCCCCC[Al+2].C1=CC=C2C([N-]CC)=CC=CC2=C1.C1=CC=C2C([N-]CC)=CC=CC2=C1 ZPGYSJMGYASTOM-UHFFFAOYSA-N 0.000 description 1
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- KETWBQOXTBGBBN-UHFFFAOYSA-N hex-1-enylbenzene Chemical compound CCCCC=CC1=CC=CC=C1 KETWBQOXTBGBBN-UHFFFAOYSA-N 0.000 description 1
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- FFUAGWLWBBFQJT-UHFFFAOYSA-N hexamethyldisilazane Chemical compound C[Si](C)(C)N[Si](C)(C)C FFUAGWLWBBFQJT-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Graft Or Block Polymers (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US94967007P | 2007-07-13 | 2007-07-13 | |
| PCT/US2008/069964 WO2009012215A1 (en) | 2007-07-13 | 2008-07-14 | Ethylene/a-olefin interpolymers containing low crystallinity hard blocks |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0812643A2 BRPI0812643A2 (pt) | 2014-12-23 |
| BRPI0812643B1 true BRPI0812643B1 (pt) | 2019-01-15 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0812643A BRPI0812643B1 (pt) | 2007-07-13 | 2008-07-14 | interpolímero de etileno/a-olefina |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US8476393B2 (enExample) |
| EP (1) | EP2170604B1 (enExample) |
| JP (1) | JP2011528041A (enExample) |
| CN (1) | CN101855078B (enExample) |
| BR (1) | BRPI0812643B1 (enExample) |
| SG (1) | SG183028A1 (enExample) |
| WO (1) | WO2009012215A1 (enExample) |
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| WO2009012153A1 (en) * | 2007-07-13 | 2009-01-22 | Dow Global Technologies Inc. | Viscosity index improver for lubricant compositions |
| EP2179013B1 (en) * | 2007-07-13 | 2016-04-13 | Dow Global Technologies LLC | Lubricant compositions |
| EP2170993B1 (en) * | 2007-07-13 | 2019-05-15 | Dow Global Technologies LLC | Catalytic olefin block copolymers with controlled block sequence distribution and at least one low crystallinity hard block |
| US8318874B2 (en) | 2009-06-26 | 2012-11-27 | Dow Global Technologies Llc | Process of selectively polymerizing ethylene and catalyst therefor |
| WO2011016992A2 (en) | 2009-07-29 | 2011-02-10 | Dow Global Technologies Inc. | Polymeric chain transfer/shuttling agents |
| BR112012001942B1 (pt) | 2009-07-29 | 2019-10-22 | Dow Global Technologies Llc | agente de permuta de cadeia multifuncional, processo para preparar um agente de permuta de cadeia multifuncional, processo para preparar uma composição multifuncional, composição multifuncional, processo para preparar um agente de permuta de cadeia multifuncional contendo poli-radical poliolefina, poliolefina telequélica, processo para preparar uma poliolefina com funcionalidade terminal e separador de bateria |
| EP3243846B1 (en) | 2009-07-29 | 2021-01-06 | Dow Global Technologies LLC | Multi-headed chain shuttling agents and their use for the preparation of block copolymers |
| US20110054122A1 (en) | 2009-08-31 | 2011-03-03 | Jerzy Klosin | Catalyst and process for polymerizing an olefin and polyolefin prepared thereby |
| WO2011041696A1 (en) | 2009-10-02 | 2011-04-07 | Dow Global Technologies Inc. | Block composites and impact modified compositions |
| CN102712796B (zh) | 2009-10-02 | 2015-05-27 | 陶氏环球技术有限责任公司 | 软混配物中的嵌段共聚物 |
| US8686087B2 (en) | 2009-10-02 | 2014-04-01 | Dow Global Technologies Llc | Block composites in soft compounds |
| JP5693590B2 (ja) | 2009-10-02 | 2015-04-01 | ダウ グローバル テクノロジーズ エルエルシー | 熱可塑性加硫物用途におけるブロック複合材料 |
| CN102822180B (zh) | 2010-02-19 | 2016-06-15 | 陶氏环球技术有限责任公司 | 金属配体配合物和催化剂 |
| SG183310A1 (en) | 2010-02-19 | 2012-09-27 | Dow Global Technologies Llc | Process for polymerizing an olefin monomer and catalyst therefor |
| CN102906129B (zh) | 2010-05-17 | 2015-02-25 | 陶氏环球技术有限责任公司 | 选择性聚合乙烯的方法及其催化剂 |
| EP2582749B1 (en) | 2010-06-21 | 2019-07-24 | Dow Global Technologies LLC | Crystalline block composites as compatibilizers |
| US8785554B2 (en) | 2010-06-21 | 2014-07-22 | Dow Global Technologies Llc | Crystalline block composites as compatibilizers |
| BR112012032980B1 (pt) | 2010-06-21 | 2020-08-25 | Dow Global Technologies Llc | composição |
| ES2659733T3 (es) | 2010-08-25 | 2018-03-19 | Dow Global Technologies Llc | Proceso de polimerización de olefina polimerizable y catalizador para ello |
| JP5968321B2 (ja) | 2010-09-30 | 2016-08-10 | ダウ グローバル テクノロジーズ エルエルシー | ポリマー組成物およびそれを用いたシーラント層 |
| BR112013007286B1 (pt) | 2010-09-30 | 2020-03-31 | Dow Global Technologies Llc | Película e bolsa de autoclave |
| WO2012061706A1 (en) | 2010-11-04 | 2012-05-10 | Dow Global Technologies Llc | Double shuttling of polyolefin polymeryl chains |
| WO2012103080A1 (en) | 2011-01-26 | 2012-08-02 | Dow Global Technologies Llc | Process for making a polyolefin-polysiloxane block copolymer |
| US9296836B2 (en) | 2011-05-12 | 2016-03-29 | Dow Global Technologies Llc | Non-cyclopentadienyl-based chromium catalysts for olefin polymerization |
| WO2013003541A1 (en) * | 2011-06-30 | 2013-01-03 | Dow Global Technologies Llc | Multilayered polyolefin-based films having a layer comprising a crystalline block copolymer composite or a block copolymer composite resin |
| US20140096825A1 (en) | 2011-06-30 | 2014-04-10 | Dow Global Technologies Llc | Multilayered polyolefin-based films having integrated backsheet and encapsulation performance comprising a layer comprising crystalline block copolymer composite or block copolymer composite |
| DE112012005025T5 (de) | 2011-12-02 | 2014-10-16 | Sumitomo Chemical Company, Limited | Verfahren zur Herstellung eines Olefinblockpolymers unter Verwendung mehrerer Arten von Übergangsmetallkatalysatoren |
| BR112014014469B1 (pt) | 2011-12-14 | 2020-09-08 | Dow Global Technologies Llc | Composição |
| CN104245834B (zh) | 2011-12-14 | 2017-10-13 | 陶氏环球技术有限责任公司 | 官能化的嵌段复合材料和结晶嵌段复合材料组合物 |
| CN110655886A (zh) | 2012-03-30 | 2020-01-07 | 陶氏环球技术有限责任公司 | 聚烯烃粘合剂组合物 |
| US8691916B2 (en) | 2012-05-07 | 2014-04-08 | Dow Global Technologies Llc | Retortable easy opening seals for film extrusion |
| WO2014003908A1 (en) | 2012-06-27 | 2014-01-03 | Dow Global Technologies Llc | Polymeric coatings for coated conductors |
| JP6254166B2 (ja) | 2012-09-14 | 2017-12-27 | ダウ グローバル テクノロジーズ エルエルシー | 多層化ポリオレフィン系フィルム |
| EP3058027B1 (en) | 2013-10-15 | 2019-08-14 | Dow Global Technologies LLC | Compatibilized polyolefin blends |
| CA2927060C (en) | 2013-10-18 | 2021-03-30 | Dow Global Technologies Llc | Optical fiber cable components |
| WO2015061440A1 (en) | 2013-10-25 | 2015-04-30 | Dow Global Technologies Llc | Polyethylene and polypropylene composition suitable for the use as retortable easy opening seals |
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| ES2743478T3 (es) | 2014-06-24 | 2020-02-19 | Dow Global Technologies Llc | Lámina posterior fotovoltaica de poliolefina que comprende una capa de polipropileno estabilizado |
| WO2015200204A1 (en) | 2014-06-24 | 2015-12-30 | Dow Global Technologies Llc | Photovoltaic modules comprising organoclay |
| KR102378767B1 (ko) | 2014-08-21 | 2022-03-28 | 다우 글로벌 테크놀로지스 엘엘씨 | 결정성 블록 복합체를 포함하는 핫멜트 접착제 |
| WO2016026120A1 (en) | 2014-08-21 | 2016-02-25 | Dow Global Technologies Llc | Hot melt adhesive composition including crystalline block composite |
| JP6831323B2 (ja) | 2014-10-29 | 2021-02-17 | ダウ グローバル テクノロジーズ エルエルシー | オレフィンブロック複合熱伝導性材料 |
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| EP3347411B1 (en) | 2015-09-10 | 2023-10-25 | Dow Global Technologies LLC | Polyolefin blends including polyoctene with compatibilizer |
| CN107922686B (zh) | 2015-09-10 | 2021-01-08 | 陶氏环球技术有限责任公司 | 包括增容剂的聚烯烃共混物 |
| US11732064B2 (en) | 2015-09-30 | 2023-08-22 | Dow Global Technologies Llc | Process for preparing functional polymers through addition of amino and polymeryl groups to aldehyde moieties |
| EP3356374B1 (en) | 2015-09-30 | 2025-09-24 | Dow Global Technologies LLC | Multi- or dual-headed compositions useful for chain shuttling and process to prepare the same |
| JP6906517B2 (ja) | 2015-12-10 | 2021-07-21 | ダウ グローバル テクノロジーズ エルエルシー | 光ファイバーケーブルバッファチューブのための高弾性率オレフィン化合物 |
| CN109071893B (zh) | 2016-03-25 | 2021-06-01 | 陶氏环球技术有限责任公司 | 用于光纤电缆的缓冲管 |
| JP6976268B2 (ja) | 2016-03-31 | 2021-12-08 | ダウ グローバル テクノロジーズ エルエルシー | Ｐｖｃ不含摩耗層のための結晶性ブロック複合体を含むポリオレフィンブレンド |
| EP3293002A1 (en) | 2016-09-09 | 2018-03-14 | Dow Global Technologies LLC | Multilayer films and laminates and packages formed from same |
| WO2018058354A1 (en) | 2016-09-28 | 2018-04-05 | Dow Global Technologies Llc | Multilayer film and pouch with same |
| TW201840572A (zh) | 2016-09-30 | 2018-11-16 | 美商陶氏全球科技有限責任公司 | 適用於鏈梭移之多頭或雙頭組合物及其製備方法 |
| TWI756272B (zh) | 2016-09-30 | 2022-03-01 | 美商陶氏全球科技有限責任公司 | 適用於鏈梭移之封端多頭或雙頭組合物及其製備方法 |
| EP4435013A3 (en) | 2016-09-30 | 2024-12-25 | Dow Global Technologies LLC | Process for preparing multi- or dual-headed compositions useful for chain shuttling |
| US20210276305A1 (en) | 2016-10-12 | 2021-09-09 | Dow Global Technologies Llc | Multilayer structures, articles comprising the same, and methods of making multilayer structures |
| ES2783948T3 (es) | 2017-03-10 | 2020-09-21 | Dow Global Technologies Llc | Películas multicapa y métodos de las mismas |
| CN110612315B (zh) | 2017-03-15 | 2022-08-26 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
| US20200247936A1 (en) | 2017-03-15 | 2020-08-06 | Dow Global Technologies Llc | Catalyst system for multi-block copolymer formation |
| KR102710284B1 (ko) | 2017-03-15 | 2024-09-27 | 다우 글로벌 테크놀로지스 엘엘씨 | 다중-블록 공중합체 형성을 위한 촉매 시스템 |
| EP3596146B1 (en) | 2017-03-15 | 2023-07-19 | Dow Global Technologies LLC | Catalyst system for multi-block copolymer formation |
| CN110582518B (zh) | 2017-03-15 | 2022-08-09 | 陶氏环球技术有限责任公司 | 用于形成多嵌段共聚物的催化剂体系 |
| US11131130B2 (en) | 2017-06-29 | 2021-09-28 | Dow Global Technologies Llc | Plastic living hinges with block composite polymer |
| ES2926247T3 (es) | 2017-07-18 | 2022-10-24 | Dow Global Technologies Llc | Resinas, películas multicapa y envases que comprenden las mismas |
| EP3431546A1 (en) | 2017-07-18 | 2019-01-23 | Dow Global Technologies Llc | Resins, multilayer films and packages comprising the same |
| CN119684341A (zh) | 2017-12-29 | 2025-03-25 | 陶氏环球技术有限责任公司 | 双头有机铝组合物 |
| SG11202005532YA (en) | 2017-12-29 | 2020-07-29 | Dow Global Technologies Llc | Capped dual-headed organoaluminum compositions |
| CN111918904B (zh) | 2018-03-19 | 2022-08-19 | 美国陶氏有机硅公司 | 聚烯烃-聚二有机硅氧烷嵌段共聚物和其合成方法 |
| US11332583B2 (en) | 2018-03-19 | 2022-05-17 | Dow Silicones Corporation | Polyolefin-polydiorganosiloxane block copolymer and hydrosilylation reaction method for the synthesis thereof |
| BR112020019174A2 (pt) | 2018-03-19 | 2021-01-05 | Dow Global Technologies Llc | Composições de poliolefina telequélica terminadas com silício e processos para a preparação das mesmas |
| EP3768687A1 (en) | 2018-03-19 | 2021-01-27 | Dow Global Technologies LLC | Silicon-terminated organo-metal compounds and processes for preparing the same |
| CA3093558A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Polyorganosiloxane hot melt adhesive compositions containing polyolefin - polydiorganoosiloxane copolymers and methods for the preparation and use thereof |
| CA3101628A1 (en) | 2018-03-19 | 2019-09-26 | Dow Silicones Corporation | Hot melt adhesive composition containing a polyolefin - polydiorganoosiloxane copolymer and methods for the preparation and use thereof |
| KR20200135419A (ko) | 2018-03-19 | 2020-12-02 | 다우 글로벌 테크놀로지스 엘엘씨 | 실릴계 작용화제로 오르가노-금속 화합물을 작용화하는 방법 및 이에 의해 제조된 실릴계 작용화제 화합물 |
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| US20210252774A1 (en) | 2018-11-06 | 2021-08-19 | Dow Global Technologies Llc | Additive manufacturing with an olefin block copolymer and articles made therefrom |
| US12180314B2 (en) | 2018-12-28 | 2024-12-31 | Dow Global Technologies Llc | Curable compositions comprising unsaturated polyolefins |
| CN113412264B (zh) | 2018-12-28 | 2024-06-25 | 陶氏环球技术有限责任公司 | 有机金属链转移剂 |
| CN113498414A (zh) | 2018-12-28 | 2021-10-12 | 陶氏环球技术有限责任公司 | 包括遥爪聚烯烃的可固化组合物 |
| CA3125275A1 (en) | 2018-12-28 | 2020-07-02 | Dow Global Technologies Llc | Curable compositions comprising unsaturated polyolefins |
| KR102916971B1 (ko) | 2018-12-28 | 2026-01-23 | 다우 글로벌 테크놀로지스 엘엘씨 | 텔레켈릭 폴리올레핀 및 이의 제조 방법 |
| JP7654639B2 (ja) | 2019-08-29 | 2025-04-01 | ダウ グローバル テクノロジーズ エルエルシー | 改善された熱特性を有するポリマーブレンド |
| JP7652766B2 (ja) | 2019-10-11 | 2025-03-27 | ダウ グローバル テクノロジーズ エルエルシー | オレフィンブロックコポリマーとともにリサイクルポリオレフィンを使用した付加製造、およびそれから造形された物品 |
| CN114929661B (zh) | 2019-12-30 | 2024-11-08 | 陶氏环球技术有限责任公司 | 用于制备α-取代的丙烯酸酯的方法 |
| KR20220120654A (ko) | 2019-12-30 | 2022-08-30 | 다우 글로벌 테크놀로지스 엘엘씨 | 알파-치환 아크릴레이트의 제조 방법 |
| BR112022022053A2 (pt) | 2020-04-29 | 2022-12-27 | Dow Global Technologies Llc | Composições contendo interpolímeros multibloco de etileno/alfa-olefina com alto índice de fusão |
| WO2021231362A1 (en) | 2020-05-12 | 2021-11-18 | Exxonmobil Chemical Patents Inc. | Thermoplastic elastomer compositions for use in pharmaceutical articles |
| EP4189030A4 (en) | 2020-07-29 | 2024-05-22 | Dow Global Technologies LLC | Adhesive formulations based on ethylene multi-block interpolymers and functionalized propylene-based polymers |
| WO2022103803A1 (en) | 2020-11-10 | 2022-05-19 | Dow Global Technologies Llc | Preparation of non-polar–polar block copolymers via vinyl-terminated polyolefins |
| JP2023552277A (ja) | 2020-11-10 | 2023-12-15 | ダウ グローバル テクノロジーズ エルエルシー | ポリエチレンの表面エネルギーを増加させるためのポリオレフィン－ポリアクリレートブロックコポリマー添加剤の調製 |
| JP7630623B2 (ja) | 2020-12-14 | 2025-02-17 | ダウ グローバル テクノロジーズ エルエルシー | ポリオレフィン発泡体ビーズ及びその製造方法 |
| WO2022126313A1 (en) | 2020-12-14 | 2022-06-23 | Dow Global Technologies Llc | A high energy return foam and method for preparing the same |
| EP4448635A4 (en) | 2021-12-17 | 2025-10-08 | Dow Global Technologies Llc | EXPANDED AND CROSSLINKED OLEFIN/SILANE INTERPOLYMER COMPOSITIONS |
| CN118613540A (zh) | 2022-02-09 | 2024-09-06 | 陶氏环球技术有限责任公司 | 3d环制品及其制备方法 |
| JP2025532847A (ja) | 2022-09-30 | 2025-10-03 | ダウ グローバル テクノロジーズ エルエルシー | 優れた衝撃強度及び光透過率を有するポリオレフィン組成物 |
| CN121464252A (zh) | 2023-07-20 | 2026-02-03 | 陶氏环球技术有限责任公司 | 包含纤维混合物的纺粘非织造物 |
| WO2025072678A1 (en) | 2023-09-29 | 2025-04-03 | Dow Global Technologies Llc | Process for preparing an olefin-acrylate block copolymer |
| WO2025096765A1 (en) | 2023-10-31 | 2025-05-08 | Dow Global Technologies Llc | Ethylene-based polymer compositions for tpo applications |
| EP4596231A1 (en) | 2024-01-31 | 2025-08-06 | Dow Global Technologies LLC | Tie layers comprising crystalline block composite components and functionalized polyethylene and multilayer films incorporating same |
| EP4596232A1 (en) | 2024-01-31 | 2025-08-06 | Dow Global Technologies LLC | Tie layers comprising crystalline block composite components and functionalized polyethylene and coated substrates incorporating same |
| WO2025207892A1 (en) | 2024-03-28 | 2025-10-02 | Dow Global Technologies Llc | Olefin-based polymer compositions with good impact performance, stiffness and light transmittance |
| WO2026011423A1 (en) | 2024-07-12 | 2026-01-15 | Dow Global Technologies Llc | Artificial leather |
Family Cites Families (40)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4792595A (en) | 1983-06-15 | 1988-12-20 | Exxon Research & Engineering Co. | Narrow MWD alpha-olefin copolymers |
| US4507515A (en) | 1983-12-21 | 1985-03-26 | Exxon Research & Engineering Co. | Lubricating oil compositions containing ethylene-alpha-olefin polymers of controlled sequence distribution and molecular heterogeneity |
| US4927888A (en) | 1986-09-05 | 1990-05-22 | The Dow Chemical Company | Maleic anhydride graft copolymers having low yellowness index and films containing the same |
| US4950541A (en) | 1984-08-15 | 1990-08-21 | The Dow Chemical Company | Maleic anhydride grafts of olefin polymers |
| US4762890A (en) | 1986-09-05 | 1988-08-09 | The Dow Chemical Company | Method of grafting maleic anhydride to polymers |
| US4798081A (en) | 1985-11-27 | 1989-01-17 | The Dow Chemical Company | High temperature continuous viscometry coupled with analytic temperature rising elution fractionation for evaluating crystalline and semi-crystalline polymers |
| US4804794A (en) | 1987-07-13 | 1989-02-14 | Exxon Chemical Patents Inc. | Viscosity modifier polymers |
| US5244590A (en) | 1989-10-12 | 1993-09-14 | Exxon Chemical Patents Inc. | Viscosity index improver |
| US5310490A (en) | 1991-03-13 | 1994-05-10 | Exxon Chemical Products Inc. | Viscosity modifer polymers |
| US5310814A (en) | 1991-03-15 | 1994-05-10 | Exxon Chemical Patents Inc. | Viscosity modifier polybutadiene polymers |
| WO1995027746A1 (en) | 1994-04-06 | 1995-10-19 | Exxon Chemical Patents Inc. | ETHYLENE α-OLEFIN BLOCK COPOLYMERS AND METHODS FOR PRODUCTION THEREOF |
| KR970702306A (ko) * | 1994-04-06 | 1997-05-13 | 카덴헤드 벤 씨 | 에틸렌 α-올레핀 블록 공중합체 및 그의 제조 방법(ETHYLENE ALPHA-OLEFIN BLOCK COPOLYMERS AND METHODS FOR PRODUCTION THEREOF) |
| EP0889912B1 (en) | 1996-03-27 | 2000-07-12 | The Dow Chemical Company | Highly soluble olefin polymerization catalyst activator |
| ES2224266T3 (es) | 1996-08-08 | 2005-03-01 | Dow Global Technologies Inc. | Copmplejos metalicos que contienen ciclopentadienilo sustituido en la posicion 3 con un heteroatomo y procedimiento de polimerizacion de olefinas. |
| EP1056752B1 (en) | 1998-02-20 | 2003-06-25 | Dow Global Technologies Inc. | Catalyst activators comprising expanded anions |
| BR0009424B1 (pt) | 1999-03-30 | 2011-10-04 | modificador de viscosidade para óleo lubrificante e composição de óleo lubrificante. | |
| US6825295B2 (en) | 1999-12-10 | 2004-11-30 | Dow Global Technologies Inc. | Alkaryl-substituted group 4 metal complexes, catalysts and olefin polymerization process |
| AU2002219882A1 (en) | 2000-12-04 | 2002-06-18 | Exxonmobil Chemical Patents Inc | Ethylene copolymer compositions suitable for viscosity index improvers and lubricant compositions |
| US20030004268A1 (en) * | 2001-05-14 | 2003-01-02 | General Electric Company | Polyimide blends, method of making, and articles made therefrom |
| JP4100961B2 (ja) * | 2001-05-31 | 2008-06-11 | 三井化学株式会社 | オレフィンブロック共重合体、潤滑油用粘度指数向上剤および潤滑油組成物 |
| US6960635B2 (en) | 2001-11-06 | 2005-11-01 | Dow Global Technologies Inc. | Isotactic propylene copolymers, their preparation and use |
| US6919467B2 (en) | 2001-12-18 | 2005-07-19 | Univation Technologies, Llc | Imino-amide catalyst compositions for the polymerization of olefins |
| US6841502B2 (en) | 2002-04-24 | 2005-01-11 | Symyx Technologies, Inc. | Bridged bi-aromatic ligands, catalysts, processes for polymerizing and polymers therefrom |
| WO2004024740A1 (en) | 2002-09-12 | 2004-03-25 | Dow Global Technologies Inc. | Preparation of metal complexes |
| US6953764B2 (en) | 2003-05-02 | 2005-10-11 | Dow Global Technologies Inc. | High activity olefin polymerization catalyst and process |
| US7714071B2 (en) * | 2004-03-17 | 2010-05-11 | Dow Global Technologies Inc. | Polymer blends from interpolymers of ethylene/α-olefins and flexible molded articles made therefrom |
| CN1934150A (zh) | 2004-03-17 | 2007-03-21 | 陶氏环球技术公司 | 用于形成乙烯共聚物的包括穿梭剂的催化剂组合物 |
| BRPI0508173B1 (pt) | 2004-03-17 | 2016-03-15 | Dow Global Technologies Inc | copolímeros em multibloco, polímero, copolímero, um derivado funcional, mistura homogênea de polímero, processo para a preparação de um copolímero em multibloco contendo propileno e processo para preparar um copolímero em multibloco contendo 4-metil-1-penteno |
| US7608668B2 (en) | 2004-03-17 | 2009-10-27 | Dow Global Technologies Inc. | Ethylene/α-olefins block interpolymers |
| BRPI0508148B1 (pt) | 2004-03-17 | 2015-09-01 | Dow Global Technologies Inc. | Interpolímero de etileno em multibloco, derivado reticulado e composição |
| US7355089B2 (en) * | 2004-03-17 | 2008-04-08 | Dow Global Technologies Inc. | Compositions of ethylene/α-olefin multi-block interpolymer for elastic films and laminates |
| MX2007011318A (es) | 2005-03-17 | 2007-11-08 | Dow Global Technologies Inc | Interpolimero de etileno/alfa-olefina de bajo peso molecular como aceites base para lubricantes. |
| AR055045A1 (es) * | 2005-03-17 | 2007-08-01 | Dow Global Technologies Inc | Composiciones de polimero rellenas preparadas a partir de interpolimeros de etileno /alfa-olefinas y sus usos |
| TW200643164A (en) | 2005-03-17 | 2006-12-16 | Dow Global Technologies Inc | Viscosity index improver for lubricant compositions |
| TWI394760B (zh) * | 2005-03-17 | 2013-05-01 | Dow Global Technologies Llc | 乙烯／α-烯烴嵌段異種共聚物 |
| US8053529B2 (en) * | 2005-09-15 | 2011-11-08 | Dow Global Technologies Llc | Catalytic olefin block copolymers with controlled block sequence distribution |
| EP2179013B1 (en) | 2007-07-13 | 2016-04-13 | Dow Global Technologies LLC | Lubricant compositions |
| EP2170993B1 (en) * | 2007-07-13 | 2019-05-15 | Dow Global Technologies LLC | Catalytic olefin block copolymers with controlled block sequence distribution and at least one low crystallinity hard block |
| WO2009012153A1 (en) | 2007-07-13 | 2009-01-22 | Dow Global Technologies Inc. | Viscosity index improver for lubricant compositions |
| CN101983213B (zh) * | 2008-01-30 | 2014-10-01 | 陶氏环球技术有限责任公司 | 乙烯/α-烯烃嵌段互聚物 |
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| BRPI0812643A2 (pt) | 2014-12-23 |
| EP2170604A4 (en) | 2011-03-30 |
| CN101855078A (zh) | 2010-10-06 |
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| B24J | Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12) |
Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2679 DE 10-05-2022 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013. |