BRPI0710109A8 - Microcapsulas com polímeros acetilenos carbamide-pokyeurea e decorrentes formulações para liberação controlada - Google Patents
Microcapsulas com polímeros acetilenos carbamide-pokyeurea e decorrentes formulações para liberação controladaInfo
- Publication number
- BRPI0710109A8 BRPI0710109A8 BRPI0710109A BRPI0710109A BRPI0710109A8 BR PI0710109 A8 BRPI0710109 A8 BR PI0710109A8 BR PI0710109 A BRPI0710109 A BR PI0710109A BR PI0710109 A BRPI0710109 A BR PI0710109A BR PI0710109 A8 BRPI0710109 A8 BR PI0710109A8
- Authority
- BR
- Brazil
- Prior art keywords
- microcapsules
- controlled release
- carbamide
- pokyeurea
- formulations
- Prior art date
Links
- 239000003094 microcapsule Substances 0.000 title abstract 4
- HSFWRNGVRCDJHI-UHFFFAOYSA-N Acetylene Chemical compound C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 title abstract 3
- 239000000203 mixture Substances 0.000 title abstract 3
- 238000013270 controlled release Methods 0.000 title abstract 2
- 229920000642 polymer Polymers 0.000 title abstract 2
- 238000009472 formulation Methods 0.000 abstract 2
- 238000012695 Interfacial polymerization Methods 0.000 abstract 1
- 229920002396 Polyurea Polymers 0.000 abstract 1
- 239000003905 agrochemical Substances 0.000 abstract 1
- 239000003054 catalyst Substances 0.000 abstract 1
- 239000003814 drug Substances 0.000 abstract 1
- 229940079593 drug Drugs 0.000 abstract 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- HCJTYESURSHXNB-UHFFFAOYSA-N propynamide Chemical class NC(=O)C#C HCJTYESURSHXNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
- C08G18/3848—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7607—Compounds of C08G18/7614 and of C08G18/7657
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2310/00—Agricultural use or equipment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Polyurethanes Or Polyureas (AREA)
- Medicinal Preparation (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06006748.5 | 2006-03-30 | ||
| EP06006748.5A EP1840145B1 (en) | 2006-03-30 | 2006-03-30 | Acetylene carbamide derivatives-polyurea polymers and microcapsules and formulations thereof for controlled release |
| PCT/EP2007/002810 WO2007112934A1 (en) | 2006-03-30 | 2007-03-29 | Microcapsules with acetylene carbamide-polyurea polymers and formulations thereof for controlled release |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| BRPI0710109A2 BRPI0710109A2 (pt) | 2011-08-02 |
| BRPI0710109A8 true BRPI0710109A8 (pt) | 2017-07-11 |
Family
ID=36922138
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| BRPI0710109A BRPI0710109A8 (pt) | 2006-03-30 | 2007-03-29 | Microcapsulas com polímeros acetilenos carbamide-pokyeurea e decorrentes formulações para liberação controlada |
Country Status (23)
| Country | Link |
|---|---|
| US (2) | US8216598B2 (enExample) |
| EP (2) | EP1840145B1 (enExample) |
| JP (1) | JP5523826B2 (enExample) |
| CN (2) | CN101460534B (enExample) |
| AU (1) | AU2007234042B2 (enExample) |
| BR (1) | BRPI0710109A8 (enExample) |
| CA (1) | CA2647349C (enExample) |
| DK (1) | DK1840145T3 (enExample) |
| ES (2) | ES2659048T3 (enExample) |
| HR (1) | HRP20180231T1 (enExample) |
| HU (1) | HUE038015T2 (enExample) |
| LT (1) | LT1840145T (enExample) |
| ME (1) | ME02956B (enExample) |
| MX (1) | MX2008012476A (enExample) |
| MY (1) | MY165085A (enExample) |
| NZ (1) | NZ572314A (enExample) |
| PL (1) | PL1840145T3 (enExample) |
| RS (1) | RS56792B1 (enExample) |
| RU (1) | RU2443723C2 (enExample) |
| SI (1) | SI1840145T1 (enExample) |
| UA (1) | UA91750C2 (enExample) |
| WO (1) | WO2007112934A1 (enExample) |
| ZA (2) | ZA200807779B (enExample) |
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| EP2225940B1 (en) | 2009-03-05 | 2014-03-12 | GAT Microencapsulation GmbH | Oil dispersions of nAChR binding neonicotinoids |
| EP2461689A1 (en) * | 2009-08-07 | 2012-06-13 | GAT Microencapsulation AG | Microcapsules containing macrolide lactones abamectin, milbemectin, avermectins, milbemycins, emamectins, ivermectins and mectins in general |
| AR079413A1 (es) * | 2009-10-07 | 2012-01-25 | Basf Se | Uso de particulas polimericas que comprenden insecticida para mejorar la movilidad en el suelo de insecticidas, formulaciones insecticidas, particulas polimericas que comprenden insecticida, y metodos para controlar plagas |
| CN101707994B (zh) * | 2009-12-09 | 2012-10-17 | 浙江森宇实业有限公司 | 一种针对铁皮石斛虫害的微胶囊靶向性农药制剂 |
| US10342230B2 (en) * | 2010-02-03 | 2019-07-09 | Upl Limited | ZC composition comprising microencapsulated pendimethalin |
| WO2012015467A1 (en) * | 2010-07-30 | 2012-02-02 | Dow Global Technologies Llc | Curable compositions |
| GB2483052B (en) | 2010-08-17 | 2012-12-19 | Rotam Agrochem Int Co Ltd | Herbicidal compositions |
| GB2483050B (en) * | 2010-08-17 | 2012-12-19 | Rotam Agrochem Int Co Ltd | Herbicidal compositions |
| CN103501604A (zh) * | 2010-09-17 | 2014-01-08 | 陶氏益农公司 | 稳定性提高的液体农业制剂 |
| CN102240531B (zh) * | 2011-03-21 | 2013-07-10 | 徐涵 | 一种植物细胞微球及其应用 |
| JP2012240925A (ja) * | 2011-05-16 | 2012-12-10 | Sumitomo Chemical Co Ltd | マイクロカプセル組成物の取得方法及びマイクロカプセル組成物 |
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| US9095135B2 (en) | 2012-01-12 | 2015-08-04 | Fashion Chemicals, Gmbh & Co. Kg | Microencapsulated volatile insect repellent and/or insecticide agent and methods of making and using the same |
| AU2013293454B2 (en) * | 2012-07-27 | 2017-06-22 | Fmc Corporation | Formulations of clomazone |
| RU2572992C2 (ru) * | 2012-08-28 | 2016-01-20 | Федеральное государственное бюджетное образовательное учреждение высшего образования "Курская государственная сельскохозяйственная академия имени И.И. Иванова" | Способ получения микрокапсул водорастворимых препаратов пестицидов |
| WO2014095889A1 (de) * | 2012-12-17 | 2014-06-26 | Lanxess Deutschland Gmbh | Fungizide silikon-dichtungsmassen |
| WO2014160965A1 (en) * | 2013-03-28 | 2014-10-02 | Rohm And Haas Company | Synergistic combination of a flurochloridone compound and zinc pyrithione for dry film protection |
| KR20150138249A (ko) * | 2013-03-28 | 2015-12-09 | 롬 앤드 하스 캄파니 | 건조막을 보호하기 위한 플루오로클로리돈 화합물과 oit의 상승적 배합물 |
| GB2497901B (en) * | 2013-04-12 | 2016-03-02 | Rotam Agrochem Int Co Ltd | A herbicide composition comprising clomazone encapsulated within cross-linked polyacetylene carbamide-polyurea microcapsules |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US428720A (en) | 1890-05-27 | Nicke | ||
| US3959464A (en) | 1971-06-03 | 1976-05-25 | Pennwalt Corporation | Microencapsulated methyl and ethyl parathion insecticide in aqueous carrier |
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| DD108760A1 (enExample) * | 1973-11-02 | 1974-10-05 | ||
| US4056610A (en) * | 1975-04-09 | 1977-11-01 | Minnesota Mining And Manufacturing Company | Microcapsule insecticide composition |
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| DE2633457A1 (de) | 1976-07-24 | 1978-06-08 | Bayer Ag | Verfahren zur herstellung von chemisch nachvernetzten polyurethankunststoffen |
| US4105708A (en) | 1976-09-07 | 1978-08-08 | American Cyanamid Company | Dimethoxymethyl diethoxymethyl glycoluril and coating compositions containing the same as a cross-linking agent |
| US4140516A (en) | 1977-05-31 | 1979-02-20 | Stauffer Chemical Company | Encapsulation process employing phase transfer catalysts |
| DE2738509A1 (de) * | 1977-08-26 | 1979-03-08 | Bayer Ag | Reaktionsdurchschreibepapiere |
| DE2849442A1 (de) | 1978-11-15 | 1980-05-29 | Basf Ag | Verfahren zur herstellung weitgehend reiner pyrazolverbindungen |
| US4280833A (en) | 1979-03-26 | 1981-07-28 | Monsanto Company | Encapsulation by interfacial polycondensation, and aqueous herbicidal composition containing microcapsules produced thereby |
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| US4444941A (en) | 1981-05-18 | 1984-04-24 | Scm Corporation | Low temperature cure latexes |
| FR2527061B1 (fr) | 1982-05-19 | 1985-11-15 | Ami | Siege articule |
| US4458036A (en) | 1983-02-28 | 1984-07-03 | Stauffer Chemical Company | Flexible polyurethane foams containing glycoluril reaction products for a flame and ember drip retardance |
| US4534783A (en) * | 1984-01-03 | 1985-08-13 | Monsanto Co. | High concentration encapsulation of water soluble-materials |
| US4643764A (en) | 1984-01-09 | 1987-02-17 | Stauffer Chemical Company | Multiple types of microcapsules and their production |
| JPH0686154B2 (ja) * | 1985-05-08 | 1994-11-02 | 富士写真フイルム株式会社 | 感熱記録材料 |
| DE3635822A1 (de) | 1986-10-22 | 1988-04-28 | Bayer Ag | Mikrokapseln mit waenden aus polyurethan |
| JPH0818937B2 (ja) | 1987-07-06 | 1996-02-28 | 住友化学工業株式会社 | 農園芸用有機燐系殺虫組成物 |
| JPH07106674B2 (ja) * | 1987-09-16 | 1995-11-15 | 富士写真フイルム株式会社 | 感圧記録シート用マイクロカプセル |
| US4837403A (en) * | 1987-12-14 | 1989-06-06 | Basf Aktiengesellschaft | Novel polyalkylpiperidine derivatives having alkylene bridges, use thereof as stabilizers, and intermediates |
| BR9107287A (pt) * | 1991-02-06 | 1994-06-07 | Ici America Inc | Cápsulas capazes de liberaçao controlada de material orgânico encapsulado |
| JPH04265786A (ja) * | 1991-02-20 | 1992-09-21 | Fuji Photo Film Co Ltd | 感圧記録シート用マイクロカプセル |
| US5180835A (en) | 1991-06-25 | 1993-01-19 | American Cyanamid Company | Process for the preparation of monomeric tetramethoxymethylglycoloril |
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| IL104425A (en) * | 1992-01-22 | 1996-10-31 | Zeneca Ltd | Reducing the content of formaldehyde in tiny capsule preparations |
| JPH05210238A (ja) * | 1992-01-30 | 1993-08-20 | Fuji Photo Film Co Ltd | 感光性マイクロカプセルを含有する感光材料 |
| US5621052A (en) | 1992-12-29 | 1997-04-15 | Cytec Technology Corp. | Aminoplast-anchored ultraviolet light stabilizers |
| DE69529471T2 (de) * | 1994-11-16 | 2003-11-20 | Fmc Corp., Philadelphia | Wenig flüchtige formulierungen von clomazone |
| US5583090A (en) | 1995-06-26 | 1996-12-10 | Monsanto Company | Herbicidal microencapsulated clomazone compositions with reduced vapor transfer |
| AU716712B2 (en) * | 1995-12-29 | 2000-03-02 | Ciba Specialty Chemicals Water Treatments Limited | Particles having a polymeric shell and their production |
| JP3035726B2 (ja) * | 1996-04-26 | 2000-04-24 | 星野化工株式会社 | 含油マイクロカプセル、その製造方法及びマイクロカプセル配合樹脂組成物 |
| US5925595A (en) | 1997-09-05 | 1999-07-20 | Monsanto Company | Microcapsules with readily adjustable release rates |
| US5952595A (en) | 1998-05-12 | 1999-09-14 | Carnell; Richard D. | Chord hand finger conditioner for guitar players |
| US6423425B1 (en) * | 1998-05-26 | 2002-07-23 | Ppg Industries Ohio, Inc. | Article having a chip-resistant electrodeposited coating and a process for forming an electrodeposited coating |
| RU2230606C2 (ru) * | 1998-11-12 | 2004-06-20 | Фмк Корпорейшн | Новый способ получения микрокапсулированных препаратов |
| US6218339B1 (en) | 1999-03-18 | 2001-04-17 | Fmc Corporation | Microencapsulated clomazone in the presence of fat and resin |
| US6485736B1 (en) | 2000-09-07 | 2002-11-26 | Syngenta Ltd. | Variable release microcapsules |
| TWI299101B (en) | 2003-01-30 | 2008-07-21 | Sipix Imaging Inc | High performance capsules for electrophoretic displays |
| US6891012B2 (en) | 2003-05-23 | 2005-05-10 | Bayer Materialscience Llc | Powder coatings produced with crosslinkers capable of curing at low temperatures and coated articles produced therefrom |
-
2006
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- 2006-03-30 HU HUE06006748A patent/HUE038015T2/hu unknown
- 2006-03-30 RS RS20180123A patent/RS56792B1/sr unknown
- 2006-03-30 LT LTEP06006748.5T patent/LT1840145T/lt unknown
- 2006-03-30 ES ES06006748.5T patent/ES2659048T3/es active Active
- 2006-03-30 EP EP06006748.5A patent/EP1840145B1/en not_active Revoked
- 2006-03-30 ES ES10011557T patent/ES2864019T3/es active Active
- 2006-03-30 DK DK06006748.5T patent/DK1840145T3/en active
- 2006-03-30 ME MEP-2018-32A patent/ME02956B/me unknown
- 2006-03-30 SI SI200632238T patent/SI1840145T1/en unknown
- 2006-03-30 EP EP10011557.5A patent/EP2487192B1/en not_active Revoked
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2007
- 2007-03-28 US US12/225,890 patent/US8216598B2/en not_active Expired - Fee Related
- 2007-03-29 CN CN2007800203339A patent/CN101460534B/zh not_active Expired - Fee Related
- 2007-03-29 AU AU2007234042A patent/AU2007234042B2/en not_active Ceased
- 2007-03-29 CA CA2647349A patent/CA2647349C/en not_active Expired - Fee Related
- 2007-03-29 JP JP2009501956A patent/JP5523826B2/ja not_active Expired - Fee Related
- 2007-03-29 BR BRPI0710109A patent/BRPI0710109A8/pt not_active Application Discontinuation
- 2007-03-29 UA UAA200812656A patent/UA91750C2/ru unknown
- 2007-03-29 NZ NZ572314A patent/NZ572314A/en not_active IP Right Cessation
- 2007-03-29 MY MYPI20083905A patent/MY165085A/en unknown
- 2007-03-29 CN CN2007800201390A patent/CN101460533B/zh not_active Expired - Fee Related
- 2007-03-29 WO PCT/EP2007/002810 patent/WO2007112934A1/en not_active Ceased
- 2007-03-29 MX MX2008012476A patent/MX2008012476A/es active IP Right Grant
- 2007-03-29 RU RU2008142751/04A patent/RU2443723C2/ru active
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- 2008-09-10 ZA ZA200807779A patent/ZA200807779B/xx unknown
- 2008-09-10 ZA ZA200807778A patent/ZA200807778B/xx unknown
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- 2012-06-05 US US13/489,208 patent/US8828415B2/en not_active Expired - Fee Related
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