ES2659048T3 - Polímeros de derivados de acetileno carbamida-poliurea y microcápsulas y formulaciones de los mismos para liberación controlada - Google Patents
Polímeros de derivados de acetileno carbamida-poliurea y microcápsulas y formulaciones de los mismos para liberación controlada Download PDFInfo
- Publication number
- ES2659048T3 ES2659048T3 ES06006748.5T ES06006748T ES2659048T3 ES 2659048 T3 ES2659048 T3 ES 2659048T3 ES 06006748 T ES06006748 T ES 06006748T ES 2659048 T3 ES2659048 T3 ES 2659048T3
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- ES
- Spain
- Prior art keywords
- microcapsules
- isocyanate
- acetylene carbamide
- wall
- derivatives
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- 238000013270 controlled release Methods 0.000 title description 3
- 239000012948 isocyanate Substances 0.000 abstract description 71
- -1 aliphatic isocyanate Chemical class 0.000 abstract description 51
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- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
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- 230000008901 benefit Effects 0.000 description 1
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- 201000011510 cancer Diseases 0.000 description 1
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- 235000014113 dietary fatty acids Nutrition 0.000 description 1
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- TVFJAZCVMOXQRK-UHFFFAOYSA-N ethenyl 7,7-dimethyloctanoate Chemical compound CC(C)(C)CCCCCC(=O)OC=C TVFJAZCVMOXQRK-UHFFFAOYSA-N 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
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- 239000012467 final product Substances 0.000 description 1
- GDSRMADSINPKSL-HSEONFRVSA-N gamma-cyclodextrin Chemical compound OC[C@H]([C@H]([C@@H]([C@H]1O)O)O[C@H]2O[C@@H]([C@@H](O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O[C@H]3O[C@H](CO)[C@H]([C@@H]([C@H]3O)O)O3)[C@H](O)[C@H]2O)CO)O[C@@H]1O[C@H]1[C@H](O)[C@@H](O)[C@@H]3O[C@@H]1CO GDSRMADSINPKSL-HSEONFRVSA-N 0.000 description 1
- 229940080345 gamma-cyclodextrin Drugs 0.000 description 1
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- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
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- 238000006460 hydrolysis reaction Methods 0.000 description 1
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- 238000010348 incorporation Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 239000002917 insecticide Substances 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 238000005304 joining Methods 0.000 description 1
- 235000010494 karaya gum Nutrition 0.000 description 1
- 239000000231 karaya gum Substances 0.000 description 1
- 229940039371 karaya gum Drugs 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- DSSXKBBEJCDMBT-UHFFFAOYSA-M lead(2+);octanoate Chemical compound [Pb+2].CCCCCCCC([O-])=O DSSXKBBEJCDMBT-UHFFFAOYSA-M 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 231100000647 material safety data sheet Toxicity 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
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- 238000011169 microbiological contamination Methods 0.000 description 1
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- 125000003136 n-heptyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 239000002088 nanocapsule Substances 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 150000004005 nitrosamines Chemical class 0.000 description 1
- 231100001223 noncarcinogenic Toxicity 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 125000002524 organometallic group Chemical group 0.000 description 1
- 229920001277 pectin Polymers 0.000 description 1
- 239000001814 pectin Substances 0.000 description 1
- 235000010987 pectin Nutrition 0.000 description 1
- 239000003090 pesticide formulation Substances 0.000 description 1
- OOCYPIXCHKROMD-UHFFFAOYSA-M phenyl(propanoyloxy)mercury Chemical compound CCC(=O)O[Hg]C1=CC=CC=C1 OOCYPIXCHKROMD-UHFFFAOYSA-M 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 229920001290 polyvinyl ester Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- ZUFQCVZBBNZMKD-UHFFFAOYSA-M potassium 2-ethylhexanoate Chemical compound [K+].CCCCC(CC)C([O-])=O ZUFQCVZBBNZMKD-UHFFFAOYSA-M 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 229910000027 potassium carbonate Inorganic materials 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
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- 235000017709 saponins Nutrition 0.000 description 1
- 150000007949 saponins Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
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- 235000017550 sodium carbonate Nutrition 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
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- 238000001179 sorption measurement Methods 0.000 description 1
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- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 150000003456 sulfonamides Chemical class 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 239000004546 suspension concentrate Substances 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 230000008646 thermal stress Effects 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- KSBAEPSJVUENNK-UHFFFAOYSA-L tin(ii) 2-ethylhexanoate Chemical compound [Sn+2].CCCCC(CC)C([O-])=O.CCCCC(CC)C([O-])=O KSBAEPSJVUENNK-UHFFFAOYSA-L 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- YXFVVABEGXRONW-UHFFFAOYSA-N toluene Substances CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical class CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- 230000002110 toxicologic effect Effects 0.000 description 1
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- 239000000196 tragacanth Substances 0.000 description 1
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- 238000012546 transfer Methods 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 150000003624 transition metals Chemical class 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- 150000003672 ureas Chemical group 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
- B01J13/16—Interfacial polymerisation
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/72—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms
- A01N43/80—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,2
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/30—Low-molecular-weight compounds
- C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
- C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
- C08G18/3842—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring
- C08G18/3848—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen containing heterocyclic rings having at least one nitrogen atom in the ring containing two nitrogen atoms in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7607—Compounds of C08G18/7614 and of C08G18/7657
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2310/00—Agricultural use or equipment
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2982—Particulate matter [e.g., sphere, flake, etc.]
- Y10T428/2984—Microcapsule with fluid core [includes liposome]
- Y10T428/2985—Solid-walled microcapsule from synthetic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Plant Pathology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Toxicology (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Polyurethanes Or Polyureas (AREA)
- Medicinal Preparation (AREA)
- Polymerisation Methods In General (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP06006748.5A EP1840145B1 (en) | 2006-03-30 | 2006-03-30 | Acetylene carbamide derivatives-polyurea polymers and microcapsules and formulations thereof for controlled release |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2659048T3 true ES2659048T3 (es) | 2018-03-13 |
Family
ID=36922138
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES06006748.5T Active ES2659048T3 (es) | 2006-03-30 | 2006-03-30 | Polímeros de derivados de acetileno carbamida-poliurea y microcápsulas y formulaciones de los mismos para liberación controlada |
| ES10011557T Active ES2864019T3 (es) | 2006-03-30 | 2006-03-30 | Microencapsulación de Clomazona por medio de un proceso de refinado y microcápsulas específicas producidas de la misma |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES10011557T Active ES2864019T3 (es) | 2006-03-30 | 2006-03-30 | Microencapsulación de Clomazona por medio de un proceso de refinado y microcápsulas específicas producidas de la misma |
Country Status (23)
| Country | Link |
|---|---|
| US (2) | US8216598B2 (enExample) |
| EP (2) | EP1840145B1 (enExample) |
| JP (1) | JP5523826B2 (enExample) |
| CN (2) | CN101460534B (enExample) |
| AU (1) | AU2007234042B2 (enExample) |
| BR (1) | BRPI0710109A8 (enExample) |
| CA (1) | CA2647349C (enExample) |
| DK (1) | DK1840145T3 (enExample) |
| ES (2) | ES2659048T3 (enExample) |
| HR (1) | HRP20180231T1 (enExample) |
| HU (1) | HUE038015T2 (enExample) |
| LT (1) | LT1840145T (enExample) |
| ME (1) | ME02956B (enExample) |
| MX (1) | MX2008012476A (enExample) |
| MY (1) | MY165085A (enExample) |
| NZ (1) | NZ572314A (enExample) |
| PL (1) | PL1840145T3 (enExample) |
| RS (1) | RS56792B1 (enExample) |
| RU (1) | RU2443723C2 (enExample) |
| SI (1) | SI1840145T1 (enExample) |
| UA (1) | UA91750C2 (enExample) |
| WO (1) | WO2007112934A1 (enExample) |
| ZA (2) | ZA200807779B (enExample) |
Families Citing this family (69)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1844653B1 (en) * | 2006-03-30 | 2017-07-26 | GAT Microencapsulation GmbH | Novel agrochemical formulations containing microcapsules |
| EP2628530A1 (de) * | 2008-03-11 | 2013-08-21 | Basf Se | Mikrokapseln mit Wänden aus Acylharnstoff |
| EP2225940B1 (en) | 2009-03-05 | 2014-03-12 | GAT Microencapsulation GmbH | Oil dispersions of nAChR binding neonicotinoids |
| EP2461689A1 (en) * | 2009-08-07 | 2012-06-13 | GAT Microencapsulation AG | Microcapsules containing macrolide lactones abamectin, milbemectin, avermectins, milbemycins, emamectins, ivermectins and mectins in general |
| AR079413A1 (es) * | 2009-10-07 | 2012-01-25 | Basf Se | Uso de particulas polimericas que comprenden insecticida para mejorar la movilidad en el suelo de insecticidas, formulaciones insecticidas, particulas polimericas que comprenden insecticida, y metodos para controlar plagas |
| CN101707994B (zh) * | 2009-12-09 | 2012-10-17 | 浙江森宇实业有限公司 | 一种针对铁皮石斛虫害的微胶囊靶向性农药制剂 |
| US10342230B2 (en) * | 2010-02-03 | 2019-07-09 | Upl Limited | ZC composition comprising microencapsulated pendimethalin |
| WO2012015467A1 (en) * | 2010-07-30 | 2012-02-02 | Dow Global Technologies Llc | Curable compositions |
| GB2483052B (en) | 2010-08-17 | 2012-12-19 | Rotam Agrochem Int Co Ltd | Herbicidal compositions |
| GB2483050B (en) * | 2010-08-17 | 2012-12-19 | Rotam Agrochem Int Co Ltd | Herbicidal compositions |
| CN103501604A (zh) * | 2010-09-17 | 2014-01-08 | 陶氏益农公司 | 稳定性提高的液体农业制剂 |
| CN102240531B (zh) * | 2011-03-21 | 2013-07-10 | 徐涵 | 一种植物细胞微球及其应用 |
| JP2012240925A (ja) * | 2011-05-16 | 2012-12-10 | Sumitomo Chemical Co Ltd | マイクロカプセル組成物の取得方法及びマイクロカプセル組成物 |
| AU2012365434B2 (en) * | 2011-11-02 | 2015-09-03 | Deepak Shah | Variable release water dispersible granule composition |
| US9095135B2 (en) | 2012-01-12 | 2015-08-04 | Fashion Chemicals, Gmbh & Co. Kg | Microencapsulated volatile insect repellent and/or insecticide agent and methods of making and using the same |
| AU2013293454B2 (en) * | 2012-07-27 | 2017-06-22 | Fmc Corporation | Formulations of clomazone |
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2006
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- 2006-03-30 HU HUE06006748A patent/HUE038015T2/hu unknown
- 2006-03-30 RS RS20180123A patent/RS56792B1/sr unknown
- 2006-03-30 LT LTEP06006748.5T patent/LT1840145T/lt unknown
- 2006-03-30 ES ES06006748.5T patent/ES2659048T3/es active Active
- 2006-03-30 EP EP06006748.5A patent/EP1840145B1/en not_active Revoked
- 2006-03-30 ES ES10011557T patent/ES2864019T3/es active Active
- 2006-03-30 DK DK06006748.5T patent/DK1840145T3/en active
- 2006-03-30 ME MEP-2018-32A patent/ME02956B/me unknown
- 2006-03-30 SI SI200632238T patent/SI1840145T1/en unknown
- 2006-03-30 EP EP10011557.5A patent/EP2487192B1/en not_active Revoked
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- 2007-03-28 US US12/225,890 patent/US8216598B2/en not_active Expired - Fee Related
- 2007-03-29 CN CN2007800203339A patent/CN101460534B/zh not_active Expired - Fee Related
- 2007-03-29 AU AU2007234042A patent/AU2007234042B2/en not_active Ceased
- 2007-03-29 CA CA2647349A patent/CA2647349C/en not_active Expired - Fee Related
- 2007-03-29 JP JP2009501956A patent/JP5523826B2/ja not_active Expired - Fee Related
- 2007-03-29 BR BRPI0710109A patent/BRPI0710109A8/pt not_active Application Discontinuation
- 2007-03-29 UA UAA200812656A patent/UA91750C2/ru unknown
- 2007-03-29 NZ NZ572314A patent/NZ572314A/en not_active IP Right Cessation
- 2007-03-29 MY MYPI20083905A patent/MY165085A/en unknown
- 2007-03-29 CN CN2007800201390A patent/CN101460533B/zh not_active Expired - Fee Related
- 2007-03-29 WO PCT/EP2007/002810 patent/WO2007112934A1/en not_active Ceased
- 2007-03-29 MX MX2008012476A patent/MX2008012476A/es active IP Right Grant
- 2007-03-29 RU RU2008142751/04A patent/RU2443723C2/ru active
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- 2008-09-10 ZA ZA200807779A patent/ZA200807779B/xx unknown
- 2008-09-10 ZA ZA200807778A patent/ZA200807778B/xx unknown
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- 2012-06-05 US US13/489,208 patent/US8828415B2/en not_active Expired - Fee Related
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