BRPI0509507A - catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador - Google Patents

catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador

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Publication number
BRPI0509507A
BRPI0509507A BRPI0509507-7A BRPI0509507A BRPI0509507A BR PI0509507 A BRPI0509507 A BR PI0509507A BR PI0509507 A BRPI0509507 A BR PI0509507A BR PI0509507 A BRPI0509507 A BR PI0509507A
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BR
Brazil
Prior art keywords
zeolite
catalyst
metals
weight
phosphorus
Prior art date
Application number
BRPI0509507-7A
Other languages
English (en)
Inventor
Jun Long
Zhijian Da
Huiping Tian
Zhenyu Chen
Weilin Zhang
Xingtian Shu
Jiushun Zhang
Yuxia Zhu
Yujian Liu
Original Assignee
China Petroleum & Chemical
Res Inst Petroleum Processing
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from CN 200410029861 external-priority patent/CN1292051C/zh
Priority claimed from CN 200410029862 external-priority patent/CN1292052C/zh
Priority claimed from CNB2004100689364A external-priority patent/CN1332756C/zh
Priority claimed from CNB2004100689379A external-priority patent/CN1323136C/zh
Application filed by China Petroleum & Chemical, Res Inst Petroleum Processing filed Critical China Petroleum & Chemical
Publication of BRPI0509507A publication Critical patent/BRPI0509507A/pt
Publication of BRPI0509507B1 publication Critical patent/BRPI0509507B1/pt

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/405—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing rare earth elements, titanium, zirconium, hafnium, zinc, cadmium, mercury, gallium, indium, thallium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/80—Mixtures of different zeolites
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G11/00—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G11/02—Catalytic cracking, in the absence of hydrogen, of hydrocarbon oils characterised by the catalyst used
    • C10G11/04—Oxides
    • C10G11/05—Crystalline alumino-silicates, e.g. molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/08—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the faujasite type, e.g. type X or Y
    • B01J29/084—Y-type faujasite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/80—Additives
    • C10G2300/805—Water
    • C10G2300/807—Steam
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/20—C2-C4 olefins

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  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)

Abstract

CATALISADOR DE CONVERSãO DE HIDROCARBONETOS CONTENDO ZEóLITO, O PROCESSO DE PREPARAçãO DOS MESMOS, E UM PROCESSO PARA CONVERTER óLEOS HIDROCARBONETOS COM O CATALISADOR A presente invenção refere-se a um catalisador para conversão de hidrocarbonetos, cujo catalisador contém, com base no peso do catalisador, 1-60% em peso de um zeólito, 0,1-10% em peso de um componente catalítico auxiliar, 5-98% em peso de um óxido inorgânico termotolerante, e 0-70% em peso de uma argila em termos do óxido. O referido zeólito é um zeólito estruturado MFI contendo fósforo e um ou mais metais de transição ou uma mistura do referido zeólito e um zeólito macroporoso, o qual compreende, com base no peso da mistura, 75-100% em peso do referido zeálito estruturado MFI contenda fósforo e um ou mais metais de transição e 0-25% em peso do zeólito macropomso. Em termos da massa do óxido, o referido zeólito estruturado MFI contendo fósforo e um au mais metais de transição têm a seguinte fórmula química anídrica: (0-0,3)Na2O. (0,3-5,5)AI2O3. (1,0-10)P2O5. (0,7-15)M1xOy (0,01-5)M2mOn.(0-10)RE2O3. (70-97)SiO2 ou (0-0,3)Na2O (0,3-5)AI2O3 (1,0-10)P2O5 (0,7-15)MpOq. (0-10)RE2O3 (70-98)SiO2 O referido componente catalítico auxiliar é um ou mais selecionados entre o grupo consistindo nos metais alcalino terrosos, metais do Grupo IVB, metais não nobres do Grupo VIII, e metais terrosos raros da Tabela Periódica das Elementos. Este catalisador tem uma capacidade maior de converter hidrocarbonetos de petróleo e maiores produções para propi- leno, etileno, e aromáticos leves.
BRPI0509507-7A 2004-03-31 2005-03-31 catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador BRPI0509507B1 (pt)

Applications Claiming Priority (9)

Application Number Priority Date Filing Date Title
CN200410029862.3 2004-03-31
CN 200410029861 CN1292051C (zh) 2004-03-31 2004-03-31 一种烃油转化方法
CN200410029861.9 2004-03-31
CN 200410029862 CN1292052C (zh) 2004-03-31 2004-03-31 一种含沸石的烃类转化催化剂及其制备方法
CN200410068936.4 2004-07-14
CNB2004100689364A CN1332756C (zh) 2004-07-14 2004-07-14 一种含沸石的烃类转化催化剂
CN200410068937.9 2004-07-14
CNB2004100689379A CN1323136C (zh) 2004-07-14 2004-07-14 一种烃油转化方法
PCT/CN2005/000427 WO2005094992A1 (en) 2004-03-31 2005-03-31 A catalyst containing zeolite for hydrocarbon converting and preparation thereof, and a hydrocarbon oil converting method using said catalyst

Publications (2)

Publication Number Publication Date
BRPI0509507A true BRPI0509507A (pt) 2007-09-11
BRPI0509507B1 BRPI0509507B1 (pt) 2021-02-23

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Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0509507-7A BRPI0509507B1 (pt) 2004-03-31 2005-03-31 catalisador de conversão de hidrocarbonetos contendo zeólito, o processo de preparação dos mesmos, e um processo para converter óleos hidrocarbonados com o catalisador

Country Status (6)

Country Link
US (1) US7923399B2 (pt)
EP (1) EP1762299B1 (pt)
JP (1) JP4987693B2 (pt)
BR (1) BRPI0509507B1 (pt)
CA (1) CA2563262C (pt)
WO (1) WO2005094992A1 (pt)

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BRPI0509507B1 (pt) 2021-02-23
JP2007530266A (ja) 2007-11-01
US7923399B2 (en) 2011-04-12
EP1762299A1 (en) 2007-03-14
US20070293714A1 (en) 2007-12-20
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