BR9713144A - Composição de álcool primário ramificado, processo para preparar a mesma, álcool primário ramificado, composição alcoxilada de ácool primário ramificado, sulfato de alquila primária alcoxilada ramificada, carboxilato de alquila primária ramificada, e, composição detergente. - Google Patents

Composição de álcool primário ramificado, processo para preparar a mesma, álcool primário ramificado, composição alcoxilada de ácool primário ramificado, sulfato de alquila primária alcoxilada ramificada, carboxilato de alquila primária ramificada, e, composição detergente.

Info

Publication number
BR9713144A
BR9713144A BR9713144-0A BR9713144A BR9713144A BR 9713144 A BR9713144 A BR 9713144A BR 9713144 A BR9713144 A BR 9713144A BR 9713144 A BR9713144 A BR 9713144A
Authority
BR
Brazil
Prior art keywords
branched
primary alcohol
alkylate
composition
branched primary
Prior art date
Application number
BR9713144-0A
Other languages
English (en)
Other versions
BR9713144B1 (pt
Inventor
Louis Kravetz
Brendan Dermot Murray
David Michael Singleton
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=27116135&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=BR9713144(A) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority claimed from US08/755,843 external-priority patent/US5849960A/en
Priority claimed from US08/755,827 external-priority patent/US5780694A/en
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of BR9713144A publication Critical patent/BR9713144A/pt
Publication of BR9713144B1 publication Critical patent/BR9713144B1/pt

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00—Esters of sulfuric acids
    • C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
    • C07C305/10—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated being further substituted by singly-bound oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C305/00—Esters of sulfuric acids
    • C07C305/02—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton
    • C07C305/04—Esters of sulfuric acids having oxygen atoms of sulfate groups bound to acyclic carbon atoms of a carbon skeleton being acyclic and saturated
    • C07C305/06—Hydrogenosulfates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C31/00—Saturated compounds having hydroxy or O-metal groups bound to acyclic carbon atoms
    • C07C31/02—Monohydroxylic acyclic alcohols
    • C07C31/125—Monohydroxylic acyclic alcohols containing five to twenty-two carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/10—Saturated ethers of polyhydroxy compounds
    • C07C43/11—Polyethers containing —O—(C—C—O—)n units with ≤ 2 n≤ 10
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C07C43/04—Saturated ethers
    • C07C43/13—Saturated ethers containing hydroxy or O-metal groups
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/04—Carboxylic acids or salts thereof
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
    • C11D1/146—Sulfuric acid esters
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/02—Anionic compounds
    • C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
    • C11D1/29—Sulfates of polyoxyalkylene ethers
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/66—Non-ionic compounds
    • C11D1/72—Ethers of polyoxyalkylene glycols

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Detergent Compositions (AREA)
  • Catalysts (AREA)

Abstract

''COMPOSIçãO DE áLCOOL PRIMáRIO RAMIFICADO, PROCESSO PARA PREPARAR A MESMA, áLCOOL PRIMáRIO RAMIFICADO, COMPOSIçãO ALCOXILADA DE áLCOOL PRIMáRIO RAMIFICADO, SULFATO DE ALQUILA PRIMáRIA ALCOXILADA RAMIFICADA, CARBOXILATO DE ALQUILA PRIMáRIA RAMIFICADA, E, COMPOSIçãO DETERGENTE''. Proporciona-se uma nova composição de álcool primário ramificado, e os seus sulfatos, alcoxilatos, alcóxi sulfatos e carboxilatos, apresentando boa detergência e biodegradabilidade em água fria. A composição de álcool primário ramificado tem um número médio de ramificações por cadeia de 0,7 a 3,0, tendo pelo menos 8 átomos de carbono e contendo tanto ramificações de metila, quanto de etila. A composição de álcool primário pode também conter menos do que 0,5% em átomo de átomos de carbono quaternário, e um número significativo de ramificações de etila, ramificações de isopropila terminal, e ramificando na posição C~ 3~ em relação ao carbono hidroxílico. O processo para a sua fabricação é por isomerização estrutural de uma alimentação de olefina tendo pelo menos 7 átomos de carbono, ou por dimerização de uma olefina C~ 6~-C~ 10~, seguida por conversão em um álcool, por intermédio de hidroformilação, e finalmente sulfatação, alcoxilação ou ambas, para obter-se um tensoativo detergente. Catalisadores de isomerização estrutural úteis incluem os zeólitos tendo pelo menos um canal com um diâmetro cristalográfico livre ao longo dos planos x e/ou y da vista [001], variando de 42 a 70 nanómetros. Catalisadores de dimerização úteis incluem uma combinação de um carboxilato de níquel com haletos aluminados de alquila, ou uma combinação de um quelato de níquel com um alcóxido aluminado de alquila.
BRPI9713144-0A 1996-11-26 1997-11-25 composiÇço de Álcool primÁrio ramificado, processo para preparar a mesma, Álcool primÁrio ramificado, composiÇço alcoxilada de Ácool primÁrio ramificado, sulfato de alquila primÁria, carboxilato de alquila primÁria ramificada, e, composiÇço detergente. BR9713144B1 (pt)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US08/755,843 US5849960A (en) 1996-11-26 1996-11-26 Highly branched primary alcohol compositions, and biodegradable detergents made therefrom
US08/755,827 US5780694A (en) 1996-11-26 1996-11-26 Dimerized alcohol compositions and biodegradible surfactants made therefrom having cold water detergency
PCT/EP1997/006694 WO1998023566A1 (en) 1996-11-26 1997-11-25 Highly branched primary alcohol compositions, and biodegradable detergents made therefrom

Publications (2)

Publication Number Publication Date
BR9713144A true BR9713144A (pt) 2000-02-08
BR9713144B1 BR9713144B1 (pt) 2009-01-13

Family

ID=27116135

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI9713144-0A BR9713144B1 (pt) 1996-11-26 1997-11-25 composiÇço de Álcool primÁrio ramificado, processo para preparar a mesma, Álcool primÁrio ramificado, composiÇço alcoxilada de Ácool primÁrio ramificado, sulfato de alquila primÁria, carboxilato de alquila primÁria ramificada, e, composiÇço detergente.

Country Status (19)

Country Link
EP (1) EP0958267B1 (pt)
JP (1) JP4118960B2 (pt)
KR (1) KR100641537B1 (pt)
CN (1) CN1090599C (pt)
AU (1) AU725968B2 (pt)
BG (1) BG64047B1 (pt)
BR (1) BR9713144B1 (pt)
CA (1) CA2271200C (pt)
CZ (1) CZ297436B6 (pt)
DE (1) DE69728429T2 (pt)
ES (1) ES2214650T3 (pt)
NZ (1) NZ334834A (pt)
PL (1) PL197319B1 (pt)
PT (1) PT958267E (pt)
RO (1) RO120404B1 (pt)
RU (1) RU2198159C2 (pt)
SK (1) SK285235B6 (pt)
TR (1) TR199901169T2 (pt)
WO (1) WO1998023566A1 (pt)

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DE69728429T2 (de) 2005-03-03
JP4118960B2 (ja) 2008-07-16
CA2271200C (en) 2009-02-03
CN1090599C (zh) 2002-09-11
CA2271200A1 (en) 1998-06-04
SK68699A3 (en) 1999-11-08
WO1998023566A1 (en) 1998-06-04
AU5656998A (en) 1998-06-22
AU725968B2 (en) 2000-10-26
PT958267E (pt) 2004-08-31
CZ297436B6 (cs) 2006-12-13
DE69728429D1 (de) 2004-05-06
BG103445A (en) 2000-05-31
BG64047B1 (bg) 2003-11-28
CN1238749A (zh) 1999-12-15
PL333503A1 (en) 1999-12-20
JP2001506597A (ja) 2001-05-22
NZ334834A (en) 2000-07-28
RO120404B1 (ro) 2006-01-30
SK285235B6 (sk) 2006-09-07
EP0958267A1 (en) 1999-11-24
CZ184899A3 (cs) 1999-11-17
TR199901169T2 (xx) 1999-08-23
KR20000069117A (ko) 2000-11-25
KR100641537B1 (ko) 2006-10-31
EP0958267B1 (en) 2004-03-31
PL197319B1 (pl) 2008-03-31
ES2214650T3 (es) 2004-09-16
BR9713144B1 (pt) 2009-01-13
RU2198159C2 (ru) 2003-02-10

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