BR112015025959A2 - método para produção de metacrilato de metila - Google Patents
método para produção de metacrilato de metilaInfo
- Publication number
- BR112015025959A2 BR112015025959A2 BR112015025959A BR112015025959A BR112015025959A2 BR 112015025959 A2 BR112015025959 A2 BR 112015025959A2 BR 112015025959 A BR112015025959 A BR 112015025959A BR 112015025959 A BR112015025959 A BR 112015025959A BR 112015025959 A2 BR112015025959 A2 BR 112015025959A2
- Authority
- BR
- Brazil
- Prior art keywords
- production
- methyl methacrylate
- steps
- methacrolein
- reaction
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/39—Preparation of carboxylic acid esters by oxidation of groups which are precursors for the acid moiety of the ester
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
- C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
- C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
- C07C45/75—Reactions with formaldehyde
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C67/00—Preparation of carboxylic acid esters
- C07C67/44—Preparation of carboxylic acid esters by oxidation-reduction of aldehydes, e.g. Tishchenko reaction
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
Abstract
resumo patente de invenção: "método para produção de metacrilato de metila". a presente invenção se refere a um método para produção de metacrilato de metila, compreendendo as seguintes etapas: a) produção de metacroleína e b) reação da metacroleína obtida na etapa a) em uma reação de esterificação oxidativa de modo a proporcionar metacrilato de metila, caracterizado pelo fato de que as duas etapas a) e b) ocorrem em uma fase líquida em uma pressão de a partir de 200 até 10000 kpa (2 até 100 bar), e a etapa b) é realizada na presença de um catalisador contendo metais nobres heterogêneo compreendendo metais e/ou compreendendo óxidos de metais.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP13002076 | 2013-04-19 | ||
EP13002076.1 | 2013-04-19 | ||
PCT/EP2014/057380 WO2014170223A1 (de) | 2013-04-19 | 2014-04-11 | Verfahren zur herstellung von methylmethacrylat |
Publications (2)
Publication Number | Publication Date |
---|---|
BR112015025959A2 true BR112015025959A2 (pt) | 2017-07-25 |
BR112015025959B1 BR112015025959B1 (pt) | 2021-08-24 |
Family
ID=48142608
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR112015025959-6A BR112015025959B1 (pt) | 2013-04-19 | 2014-04-11 | Método para produção de metacrilato de metila |
Country Status (14)
Country | Link |
---|---|
US (4) | US9890105B2 (pt) |
EP (1) | EP2986589B1 (pt) |
JP (1) | JP6501754B2 (pt) |
KR (1) | KR102213622B1 (pt) |
CN (2) | CN108164417B (pt) |
BR (1) | BR112015025959B1 (pt) |
ES (1) | ES2673104T3 (pt) |
HK (1) | HK1250509A1 (pt) |
MY (1) | MY176555A (pt) |
RU (1) | RU2665708C2 (pt) |
SA (1) | SA515370017B1 (pt) |
SG (1) | SG11201508639WA (pt) |
TW (1) | TWI617542B (pt) |
WO (1) | WO2014170223A1 (pt) |
Families Citing this family (49)
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SG11201600170PA (en) | 2013-07-24 | 2016-02-26 | Evonik Roehm Gmbh | Recirculation and disposal of aqueous catalyst solutions in amine catalytic processes |
EP2829531A1 (de) | 2013-07-24 | 2015-01-28 | Evonik Industries AG | Verfahren zur Regulierung des Wassergehalts in einem kontinuierlichen Verfahren zur Herstellung von Methacrolein |
SG11201703365VA (en) * | 2014-10-31 | 2017-05-30 | Dow Global Technologies Llc | Process for in situ water removal from an oxidative esterification reaction using a coupled reactor-distillation system |
WO2016069225A1 (en) * | 2014-10-31 | 2016-05-06 | Rohm And Haas Company | Oxidative esterification process for making methyl methacrylate |
EP3023408A1 (de) * | 2014-11-19 | 2016-05-25 | Evonik Röhm GmbH | Optimiertes Verfahren zur Herstellung von Methacrylsäure |
TWI715627B (zh) | 2015-09-16 | 2021-01-11 | 德商羅伊姆公司 | 含鈉鹽之mma-甲醇混合物的萃取後處理 |
EP3144291A1 (de) | 2015-09-16 | 2017-03-22 | Evonik Röhm GmbH | Synthese von methacrylsäure aus auf methacrolein basierenden alkylmethacrylat |
TW201722903A (zh) * | 2015-12-18 | 2017-07-01 | 陶氏全球科技責任有限公司 | 用於純化甲基丙烯酸甲酯之方法 |
EP3235560A1 (de) | 2016-04-22 | 2017-10-25 | Evonik Röhm GmbH | Verfahren zur durchführung einer heterogen-katalysierten reaktion |
EP3301084B1 (de) * | 2016-09-30 | 2018-12-12 | OXEA GmbH | Kontinuierliches herstellungsverfahren für 2-methylenalkanale |
RU2019137896A (ru) * | 2017-05-09 | 2021-05-25 | Рём ГмбХ | Способ окислительной эстерификации альдегидов до сложных эфиров карбоновых кислот |
WO2018217961A1 (en) | 2017-05-25 | 2018-11-29 | Rohm And Haas Company | Process for preparing methacrolein |
EP3630711B1 (en) * | 2017-05-25 | 2021-03-17 | Rohm and Haas Company | Process for preparing methacrolein |
KR102639234B1 (ko) * | 2017-07-28 | 2024-02-21 | 다우 글로벌 테크놀로지스 엘엘씨 | 불균일 촉매를 사용하여 산화적 에스터화에 의해 메틸 메타크릴레이트를 제조하는 방법 |
CN111372910A (zh) * | 2017-07-28 | 2020-07-03 | 罗门哈斯公司 | 通过使用非均相催化剂进行氧化酯化来生产甲基丙烯酸甲酯的方法 |
WO2019022891A1 (en) * | 2017-07-28 | 2019-01-31 | Rohm And Haas Company | PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDATIVE ESTERIZATION USING A HETEROGENEOUS CATALYST |
EP3658534A1 (en) * | 2017-07-28 | 2020-06-03 | Rohm and Haas Company | A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst |
US10829434B2 (en) * | 2017-07-28 | 2020-11-10 | Dow Global Technologies Llc | Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst |
US10745341B2 (en) * | 2017-07-28 | 2020-08-18 | Dow Global Technologies Llc | Method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst |
EP3450422A1 (de) | 2017-08-29 | 2019-03-06 | Evonik Röhm GmbH | Verfahren zur herstellung optischer formmassen |
WO2019060192A1 (en) * | 2017-09-19 | 2019-03-28 | Dow Global Technologies Llc | PROCESS FOR THE PRODUCTION OF METHYL METHACRYLATE BY OXIDIZING ESTERIZATION USING A HETEROGENEOUS CATALYST |
EP3456704A1 (de) * | 2017-09-19 | 2019-03-20 | Evonik Röhm GmbH | Katalysator für die oxidative veresterung von aldehyden zu carbonsäureestern |
EP3737496A1 (en) * | 2018-01-10 | 2020-11-18 | Dow Global Technologies, LLC | Heterogeneous catalyst for the production of methyl methacrylate by oxidative esterification |
EP3737661A1 (en) | 2018-01-10 | 2020-11-18 | Dow Global Technologies, LLC | A method for production of methyl methacrylate by oxidative esterification using a heterogeneous catalyst |
EP3587390A1 (de) * | 2018-06-26 | 2020-01-01 | Röhm GmbH | Verfahren zur herstellung von mma in hohen ausbeuten |
KR20210022621A (ko) * | 2018-06-28 | 2021-03-03 | 다우 글로벌 테크놀로지스 엘엘씨 | 불균일 촉매 |
EP3608305A1 (en) | 2018-08-10 | 2020-02-12 | Röhm GmbH | Process for producing methacrylic acid or methacrylic acid esters |
CN109331839B (zh) * | 2018-11-29 | 2021-11-02 | 中国科学院大连化学物理研究所 | 一种生产甲基丙烯酸甲酯的催化剂的制备方法及其应用 |
EP3760608A1 (de) * | 2019-07-05 | 2021-01-06 | Röhm GmbH | Verfahren zur herstellung von alkylmethacrylaten und optional methacrylsäure |
EP3786148A1 (de) * | 2019-08-28 | 2021-03-03 | Röhm GmbH | Vereinfachte aufarbeitung des reaktoraustrags einer oxidativen veresterung |
EP3786146A1 (de) | 2019-08-30 | 2021-03-03 | Röhm GmbH | Verfahren zur herstellung von methacrolein aus formaldehyd und propionaldehyd sowie herstellanlage hierfür |
EP3798202A1 (de) * | 2019-09-25 | 2021-03-31 | Röhm GmbH | Verfahren zur aufreinigung von methylmethacrylat von leichtsiedenden komponenten |
EP3798206A1 (de) | 2019-09-25 | 2021-03-31 | Röhm GmbH | Verfahren zur herstellung von alkylmethacrylaten mit verbesserter wasser- und säureführung |
CN110975929A (zh) * | 2019-12-06 | 2020-04-10 | 中国科学院大连化学物理研究所 | 一种合成甲基丙烯酸甲酯的催化剂的制备方法及应用 |
WO2021247177A1 (en) * | 2020-06-05 | 2021-12-09 | SCION Holdings LLC | Alcohols production |
US20220024837A1 (en) * | 2020-06-05 | 2022-01-27 | SCION Holdings LLC | Branched Alcohols |
CN113877560B (zh) * | 2020-07-03 | 2024-01-26 | 中国石油化工股份有限公司 | 一种丙烯酸甲酯的合成方法及其固体碱催化剂 |
EP3945088A1 (de) | 2020-07-30 | 2022-02-02 | Röhm GmbH | Vorgehen zur minimierung des aktivitätsverlusts bei im kreislaufbetrieb ausgeführten reaktionsschritten |
CN112608237B (zh) * | 2020-12-11 | 2023-06-23 | 青岛科技大学 | 一种基于多尺度模拟的高效生产甲基丙烯酸甲酯的方法 |
US20220194886A1 (en) | 2020-12-17 | 2022-06-23 | SCION Holdings LLC | Branched Products |
EP4052789A1 (en) | 2021-03-01 | 2022-09-07 | Evonik Operations GmbH | Process for producing propanal from methanol and syngas using heterogeneous catalysts |
JP2022148434A (ja) * | 2021-03-24 | 2022-10-06 | トヨタ自動車株式会社 | 排ガス浄化材料及び排ガス浄化装置 |
CN115141099A (zh) * | 2021-03-31 | 2022-10-04 | 中国石油天然气集团有限公司 | 甲基丙烯酸甲酯的生产装置和工艺 |
KR20240006654A (ko) | 2021-05-10 | 2024-01-15 | 룀 게엠베하 | 황색도 지수 감소 및 안정화를 위한 불포화 에스테르 함유 첨가제 |
WO2022248321A1 (en) | 2021-05-28 | 2022-12-01 | Röhm Gmbh | Reactor and process for producing alkyl methacrylates |
WO2023025676A1 (de) | 2021-08-23 | 2023-03-02 | Röhm Gmbh | Aufbereitung eines katalysators für die oxidative veresterung von methacrolein zu methylmethacrylat zur verlängerung der lebensdauer |
US20230150912A1 (en) | 2021-11-12 | 2023-05-18 | Röhm Gmbh | Process for eliminating interfering by-products in the direct oxidative esterification of methacrolein |
WO2023117754A1 (de) | 2021-12-23 | 2023-06-29 | Röhm Gmbh | Verfahren zur herstellung von alkylmethacrylaten mit verbesserter ausbeute und verminderten emissionen flüchtiger organischer verbindungen |
WO2024099859A1 (de) | 2022-11-09 | 2024-05-16 | Röhm Gmbh | Verfahren zur herstellung von c4- bis c12- (meth)acrylaten |
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RU2428251C1 (ru) * | 2007-08-13 | 2011-09-10 | Асахи Касеи Кемикалз Корпорейшн | Катализатор для получения сложных эфиров карбоновых кислот, способ его получения и способ получения сложных эфиров карбоновых кислот |
US8450235B2 (en) | 2007-10-26 | 2013-05-28 | Asahi Kasei Chemicals Corporation | Supported composite particle material, production process of same and process for producing compounds using supported composite particle material as catalyst for chemical synthesis |
KR20140041529A (ko) * | 2011-05-11 | 2014-04-04 | 아처 다니엘 미드랜드 캄파니 | 아크릴형 단량체의 제조방법 및 이로부터 제조된 생성물 |
US20140206897A1 (en) * | 2013-01-22 | 2014-07-24 | Saudi Basic Industries Corporation | Method for making methyl methacrylate from propionaldehyde and formaldehyde via oxidative esterification |
-
2014
- 2014-04-11 US US14/784,320 patent/US9890105B2/en active Active
- 2014-04-11 EP EP14720514.0A patent/EP2986589B1/de active Active
- 2014-04-11 RU RU2015149480A patent/RU2665708C2/ru active
- 2014-04-11 CN CN201711060427.0A patent/CN108164417B/zh active Active
- 2014-04-11 SG SG11201508639WA patent/SG11201508639WA/en unknown
- 2014-04-11 CN CN201480022228.9A patent/CN105189444B/zh active Active
- 2014-04-11 WO PCT/EP2014/057380 patent/WO2014170223A1/de active Application Filing
- 2014-04-11 MY MYPI2015002482A patent/MY176555A/en unknown
- 2014-04-11 KR KR1020157032717A patent/KR102213622B1/ko active IP Right Grant
- 2014-04-11 BR BR112015025959-6A patent/BR112015025959B1/pt active IP Right Grant
- 2014-04-11 JP JP2016508104A patent/JP6501754B2/ja active Active
- 2014-04-11 ES ES14720514.0T patent/ES2673104T3/es active Active
- 2014-04-16 TW TW103113877A patent/TWI617542B/zh active
-
2015
- 2015-10-18 SA SA515370017A patent/SA515370017B1/ar unknown
-
2017
- 2017-10-27 US US15/795,887 patent/US10273201B2/en active Active
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2018
- 2018-07-31 HK HK18109876.0A patent/HK1250509A1/zh unknown
- 2018-10-16 US US16/161,378 patent/US10457626B2/en active Active
- 2018-10-16 US US16/161,395 patent/US10766847B2/en active Active
Also Published As
Publication number | Publication date |
---|---|
TW201509895A (zh) | 2015-03-16 |
US9890105B2 (en) | 2018-02-13 |
WO2014170223A1 (de) | 2014-10-23 |
CN105189444A (zh) | 2015-12-23 |
SG11201508639WA (en) | 2015-11-27 |
US20190077742A1 (en) | 2019-03-14 |
EP2986589B1 (de) | 2018-03-14 |
SA515370017B1 (ar) | 2018-08-09 |
US10273201B2 (en) | 2019-04-30 |
TWI617542B (zh) | 2018-03-11 |
JP2016515645A (ja) | 2016-05-30 |
KR20150143785A (ko) | 2015-12-23 |
CN108164417B (zh) | 2021-07-06 |
US20160068464A1 (en) | 2016-03-10 |
EP2986589A1 (de) | 2016-02-24 |
JP6501754B2 (ja) | 2019-04-17 |
RU2665708C2 (ru) | 2018-09-04 |
CN108164417A (zh) | 2018-06-15 |
US10457626B2 (en) | 2019-10-29 |
ES2673104T3 (es) | 2018-06-19 |
RU2015149480A3 (pt) | 2018-03-19 |
KR102213622B1 (ko) | 2021-02-08 |
US10766847B2 (en) | 2020-09-08 |
MY176555A (en) | 2020-08-16 |
RU2015149480A (ru) | 2017-05-24 |
BR112015025959B1 (pt) | 2021-08-24 |
US20190112255A1 (en) | 2019-04-18 |
HK1250509A1 (zh) | 2018-12-21 |
CN105189444B (zh) | 2017-12-12 |
US20180050977A1 (en) | 2018-02-22 |
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B06U | Preliminary requirement: requests with searches performed by other patent offices: procedure suspended [chapter 6.21 patent gazette] | ||
B25D | Requested change of name of applicant approved |
Owner name: ROEHM GMBH (DE) |
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B25G | Requested change of headquarter approved |
Owner name: ROEHM GMBH (DE) |
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B25G | Requested change of headquarter approved |
Owner name: ROEHM GMBH (DE) |
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B06A | Patent application procedure suspended [chapter 6.1 patent gazette] | ||
B09A | Decision: intention to grant [chapter 9.1 patent gazette] | ||
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 11/04/2014, OBSERVADAS AS CONDICOES LEGAIS. |