BR112015014135B1 - composição aditiva e processo para produção de composição de polímero nucleado - Google Patents
composição aditiva e processo para produção de composição de polímero nucleado Download PDFInfo
- Publication number
- BR112015014135B1 BR112015014135B1 BR112015014135-8A BR112015014135A BR112015014135B1 BR 112015014135 B1 BR112015014135 B1 BR 112015014135B1 BR 112015014135 A BR112015014135 A BR 112015014135A BR 112015014135 B1 BR112015014135 B1 BR 112015014135B1
- Authority
- BR
- Brazil
- Prior art keywords
- additive composition
- polymer
- nucleating agent
- wax
- extruder
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 178
- 229920000642 polymer Polymers 0.000 title claims abstract description 170
- 239000000654 additive Substances 0.000 title claims abstract description 148
- 230000000996 additive effect Effects 0.000 title claims abstract description 140
- 238000000034 method Methods 0.000 title claims abstract description 77
- 230000008569 process Effects 0.000 title claims abstract description 72
- 239000002667 nucleating agent Substances 0.000 claims abstract description 110
- 229920000098 polyolefin Polymers 0.000 claims abstract description 68
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 10
- 239000001257 hydrogen Substances 0.000 claims abstract description 10
- 239000000178 monomer Substances 0.000 claims abstract description 8
- 150000001336 alkenes Chemical class 0.000 claims abstract description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 238000006243 chemical reaction Methods 0.000 claims abstract description 6
- 239000001993 wax Substances 0.000 claims description 64
- -1 polyethylene Polymers 0.000 claims description 43
- 239000007788 liquid Substances 0.000 claims description 21
- 150000003839 salts Chemical group 0.000 claims description 19
- 239000004698 Polyethylene Substances 0.000 claims description 13
- 229920000573 polyethylene Polymers 0.000 claims description 13
- 229910052751 metal Inorganic materials 0.000 claims description 8
- 239000002184 metal Substances 0.000 claims description 8
- 239000002904 solvent Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 7
- 150000007524 organic acids Chemical class 0.000 claims description 7
- 238000002156 mixing Methods 0.000 claims description 6
- 239000002245 particle Substances 0.000 claims description 5
- 239000000843 powder Substances 0.000 claims description 5
- 239000004805 Cyclohexane-1,2-dicarboxylic acid Substances 0.000 claims description 4
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical group [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 3
- 239000005977 Ethylene Substances 0.000 claims description 3
- 229910052791 calcium Inorganic materials 0.000 claims description 3
- 239000011575 calcium Substances 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 3
- 239000012164 animal wax Substances 0.000 claims description 2
- 239000004200 microcrystalline wax Substances 0.000 claims description 2
- 235000019808 microcrystalline wax Nutrition 0.000 claims description 2
- 239000012188 paraffin wax Substances 0.000 claims description 2
- 235000019809 paraffin wax Nutrition 0.000 claims description 2
- 235000019271 petrolatum Nutrition 0.000 claims description 2
- 239000012165 plant wax Substances 0.000 claims description 2
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract description 5
- 239000000376 reactant Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 description 21
- 238000006116 polymerization reaction Methods 0.000 description 13
- 229920001169 thermoplastic Polymers 0.000 description 12
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- 239000002253 acid Chemical class 0.000 description 6
- 125000000217 alkyl group Chemical group 0.000 description 6
- 239000003963 antioxidant agent Substances 0.000 description 6
- 239000006185 dispersion Substances 0.000 description 6
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- 239000004594 Masterbatch (MB) Substances 0.000 description 5
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 150000001924 cycloalkanes Chemical class 0.000 description 5
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 5
- 239000010452 phosphate Substances 0.000 description 5
- VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 4
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 4
- 239000004743 Polypropylene Substances 0.000 description 4
- 150000001768 cations Chemical class 0.000 description 4
- 239000013078 crystal Substances 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
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- 229920001155 polypropylene Polymers 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 125000006702 (C1-C18) alkyl group Chemical group 0.000 description 3
- 229930185605 Bisphenol Natural products 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 3
- 150000003934 aromatic aldehydes Chemical class 0.000 description 3
- 125000003118 aryl group Chemical group 0.000 description 3
- 150000008107 benzenesulfonic acids Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- XXHCQZDUJDEPSX-UHFFFAOYSA-L calcium;cyclohexane-1,2-dicarboxylate Chemical compound [Ca+2].[O-]C(=O)C1CCCCC1C([O-])=O XXHCQZDUJDEPSX-UHFFFAOYSA-L 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002430 hydrocarbons Chemical class 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QBYIENPQHBMVBV-HFEGYEGKSA-N (2R)-2-hydroxy-2-phenylacetic acid Chemical class O[C@@H](C(O)=O)c1ccccc1.O[C@@H](C(O)=O)c1ccccc1 QBYIENPQHBMVBV-HFEGYEGKSA-N 0.000 description 2
- PCSMJKASWLYICJ-UHFFFAOYSA-N Succinic aldehyde Chemical compound O=CCCC=O PCSMJKASWLYICJ-UHFFFAOYSA-N 0.000 description 2
- 239000011954 Ziegler–Natta catalyst Substances 0.000 description 2
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- HUMNYLRZRPPJDN-UHFFFAOYSA-N benzaldehyde Chemical compound O=CC1=CC=CC=C1 HUMNYLRZRPPJDN-UHFFFAOYSA-N 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 150000007942 carboxylates Chemical group 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
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- 238000012685 gas phase polymerization Methods 0.000 description 2
- 150000002431 hydrogen Chemical class 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 229920001748 polybutylene Polymers 0.000 description 2
- 229920000306 polymethylpentene Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
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- 150000005846 sugar alcohols Polymers 0.000 description 2
- 239000003826 tablet Substances 0.000 description 2
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 238000011144 upstream manufacturing Methods 0.000 description 2
- 239000003643 water by type Substances 0.000 description 2
- 239000011701 zinc Substances 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 description 1
- GGQHNQQPLWRNHD-UHFFFAOYSA-N 1,3,7,9-tetratert-butyl-11-hydroxy-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical class C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP(O)(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C GGQHNQQPLWRNHD-UHFFFAOYSA-N 0.000 description 1
- MBZMDDQWCGCTMH-UHFFFAOYSA-N 1-n,1-n,1-n-tris(2-methylcyclohexyl)methanetricarboxamide Chemical compound CC1CCCCC1NC(=O)C(C(=O)NC1C(CCCC1)C)C(=O)NC1C(C)CCCC1 MBZMDDQWCGCTMH-UHFFFAOYSA-N 0.000 description 1
- WOPLHDNLGYOSPG-UHFFFAOYSA-N 2-butylbutanedioic acid Chemical compound CCCCC(C(O)=O)CC(O)=O WOPLHDNLGYOSPG-UHFFFAOYSA-N 0.000 description 1
- POQJHLBMLVTHAU-UHFFFAOYSA-N 3,4-Dimethylbenzaldehyde Chemical compound CC1=CC=C(C=O)C=C1C POQJHLBMLVTHAU-UHFFFAOYSA-N 0.000 description 1
- MAUCRURSQMOFGV-UHFFFAOYSA-N 4-propylbenzaldehyde Chemical compound CCCC1=CC=C(C=O)C=C1 MAUCRURSQMOFGV-UHFFFAOYSA-N 0.000 description 1
- QHVJZYJNUUACLR-UHFFFAOYSA-N 5-carbamoylbenzene-1,3-dicarboxylic acid Chemical class NC(=O)C1=CC(C(O)=O)=CC(C(O)=O)=C1 QHVJZYJNUUACLR-UHFFFAOYSA-N 0.000 description 1
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ZETHHMPKDUSZQQ-UHFFFAOYSA-N Betulafolienepentol Natural products C1C=C(C)CCC(C(C)CCC=C(C)C)C2C(OC)OC(OC)C2=C1 ZETHHMPKDUSZQQ-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 125000004036 acetal group Chemical group 0.000 description 1
- 125000002777 acetyl group Chemical class [H]C([H])([H])C(*)=O 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 125000003172 aldehyde group Chemical group 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 150000003935 benzaldehydes Chemical class 0.000 description 1
- 150000001558 benzoic acid derivatives Chemical class 0.000 description 1
- KYQRDNYMKKJUTH-UHFFFAOYSA-N bicyclo[2.2.1]heptane-3,4-dicarboxylic acid Chemical class C1CC2(C(O)=O)C(C(=O)O)CC1C2 KYQRDNYMKKJUTH-UHFFFAOYSA-N 0.000 description 1
- 239000007844 bleaching agent Substances 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- MIHDGSOYBPAAHC-UHFFFAOYSA-L calcium;bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound [Ca+2].C1CC2C(C([O-])=O)C(C(=O)[O-])C1C2 MIHDGSOYBPAAHC-UHFFFAOYSA-L 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- WZHCOOQXZCIUNC-UHFFFAOYSA-N cyclandelate Chemical compound C1C(C)(C)CC(C)CC1OC(=O)C(O)C1=CC=CC=C1 WZHCOOQXZCIUNC-UHFFFAOYSA-N 0.000 description 1
- QYQADNCHXSEGJT-UHFFFAOYSA-N cyclohexane-1,1-dicarboxylate;hydron Chemical class OC(=O)C1(C(O)=O)CCCCC1 QYQADNCHXSEGJT-UHFFFAOYSA-N 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- HEOKFDGOFROELJ-UHFFFAOYSA-N diacetal Natural products COc1ccc(C=C/c2cc(O)cc(OC3OC(COC(=O)c4cc(O)c(O)c(O)c4)C(O)C(O)C3O)c2)cc1O HEOKFDGOFROELJ-UHFFFAOYSA-N 0.000 description 1
- FEZGEUUSODUXAQ-UHFFFAOYSA-L dilithium;cyclohexane-1,2-dicarboxylate Chemical compound [Li+].[Li+].[O-]C(=O)C1CCCCC1C([O-])=O FEZGEUUSODUXAQ-UHFFFAOYSA-L 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- FXDGCBFGSXNGQD-UHFFFAOYSA-L disodium;bicyclo[2.2.1]heptane-2,3-dicarboxylate Chemical compound [Na+].[Na+].C1CC2C(C([O-])=O)C(C(=O)[O-])C1C2 FXDGCBFGSXNGQD-UHFFFAOYSA-L 0.000 description 1
- PKVQSSWKJIPMRR-UHFFFAOYSA-L disodium;cyclohexane-1,2-dicarboxylate Chemical compound [Na+].[Na+].[O-]C(=O)C1CCCCC1C([O-])=O PKVQSSWKJIPMRR-UHFFFAOYSA-L 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000000806 elastomer Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 229910052621 halloysite Inorganic materials 0.000 description 1
- 229920001903 high density polyethylene Polymers 0.000 description 1
- 239000004700 high-density polyethylene Substances 0.000 description 1
- 230000000887 hydrating effect Effects 0.000 description 1
- 230000036571 hydration Effects 0.000 description 1
- 238000006703 hydration reaction Methods 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000002198 insoluble material Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004611 light stabiliser Substances 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- 229920001684 low density polyethylene Polymers 0.000 description 1
- 239000004702 low-density polyethylene Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- IWYDHOAUDWTVEP-UHFFFAOYSA-M mandelate Chemical compound [O-]C(=O)C(O)C1=CC=CC=C1 IWYDHOAUDWTVEP-UHFFFAOYSA-M 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 229920001179 medium density polyethylene Polymers 0.000 description 1
- 239000004701 medium-density polyethylene Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 1
- CNRMAYYJMYPPHU-UHFFFAOYSA-N methanetricarboxamide Chemical class NC(=O)C(C(N)=O)C(N)=O CNRMAYYJMYPPHU-UHFFFAOYSA-N 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- KMQIMDNQSNRDBJ-UHFFFAOYSA-N n-(3,5-diformamidophenyl)formamide Chemical class O=CNC1=CC(NC=O)=CC(NC=O)=C1 KMQIMDNQSNRDBJ-UHFFFAOYSA-N 0.000 description 1
- CPEULHAPWXMDDV-UHFFFAOYSA-N n-[3,5-bis(2,2-dimethylpropanoylamino)phenyl]-2,2-dimethylpropanamide Chemical compound CC(C)(C)C(=O)NC1=CC(NC(=O)C(C)(C)C)=CC(NC(=O)C(C)(C)C)=C1 CPEULHAPWXMDDV-UHFFFAOYSA-N 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- QNGNSVIICDLXHT-UHFFFAOYSA-N para-ethylbenzaldehyde Natural products CCC1=CC=C(C=O)C=C1 QNGNSVIICDLXHT-UHFFFAOYSA-N 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 229910052615 phyllosilicate Inorganic materials 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 150000003077 polyols Chemical class 0.000 description 1
- 229920005629 polypropylene homopolymer Polymers 0.000 description 1
- 229910001848 post-transition metal Inorganic materials 0.000 description 1
- 159000000001 potassium salts Chemical class 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 description 1
- 235000010234 sodium benzoate Nutrition 0.000 description 1
- 239000004299 sodium benzoate Substances 0.000 description 1
- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- XYGNGXOAIOVNFU-UHFFFAOYSA-L strontium;cyclohexane-1,2-dicarboxylate Chemical compound [Sr+2].[O-]C(=O)C1CCCCC1C([O-])=O XYGNGXOAIOVNFU-UHFFFAOYSA-L 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 125000004434 sulfur atom Chemical group 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 229910052723 transition metal Inorganic materials 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 239000000811 xylitol Substances 0.000 description 1
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 1
- 229960002675 xylitol Drugs 0.000 description 1
- 235000010447 xylitol Nutrition 0.000 description 1
- ZMCVIGZGZXZJKM-UHFFFAOYSA-L zinc;benzenesulfonate Chemical compound [Zn+2].[O-]S(=O)(=O)C1=CC=CC=C1.[O-]S(=O)(=O)C1=CC=CC=C1 ZMCVIGZGZXZJKM-UHFFFAOYSA-L 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/203—Solid polymers with solid and/or liquid additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
- C08J2491/06—Waxes
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
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| US61/740,588 | 2012-12-21 | ||
| PCT/US2013/068063 WO2014099144A1 (en) | 2012-12-21 | 2013-11-01 | Additive composition and process for using the same |
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| GB201317300D0 (en) * | 2013-09-30 | 2013-11-13 | Remet Uk Ltd | Casting Wax |
| JP2018024824A (ja) * | 2016-08-01 | 2018-02-15 | 日本ポリプロ株式会社 | ポリオレフィン系樹脂組成物の製造法および該ポリオレフィン系樹脂組成物を用いたフィルム |
| CN107177229B (zh) * | 2017-04-24 | 2020-12-29 | 东莞市隆海新材料科技有限公司 | 一种水性蜡分散体及其制备方法 |
| KR102031524B1 (ko) | 2018-05-18 | 2019-10-11 | 가부시키가이샤 아데카 | 입상 핵제, 수지 조성물, 성형품 및 그 제조 방법 |
| JP6397153B1 (ja) | 2018-05-18 | 2018-09-26 | 株式会社Adeka | 粒状核剤、樹脂組成物、成形品およびその製造方法 |
| JP6423982B1 (ja) | 2018-07-04 | 2018-11-14 | 株式会社Adeka | 粒状核剤、樹脂組成物、成形品およびその製造方法 |
| KR102641627B1 (ko) * | 2018-07-24 | 2024-02-29 | 밀리켄 앤드 캄파니 | 첨가제 조성물, 및 이를 사용한 중합체 조성물의 제조 방법 |
| EP3851432A4 (en) | 2018-09-11 | 2022-06-08 | New Japan Chemical Co., Ltd. | Metal salt of an alicyclic dicarboxylic acid with excellent dispersability in polyolefin resin, procedure for the production of this metal salt of an alicyclic dicarbonic acid, crystal germ form for polyolefin resin with this metal salt of an alicyclic dicarboxylic acid, crystal germ composition with this crystal germal composition and formed. |
| EP3856831A1 (en) * | 2018-09-26 | 2021-08-04 | Milliken & Company | Additive composition and method for producing a polymer composition using the same |
| US11661504B2 (en) | 2019-01-23 | 2023-05-30 | Milliken & Company | Thermoplastic composition |
| JP7591524B2 (ja) * | 2019-06-27 | 2024-11-28 | ダウ グローバル テクノロジーズ エルエルシー | ポリオレフィンと液体有機酸の均質な混合物を作製する方法 |
| JP6731128B1 (ja) | 2020-03-16 | 2020-07-29 | 株式会社Adeka | 粒状核剤、樹脂組成物およびその製造方法ならびに成形品 |
| MX2024003492A (es) * | 2024-03-20 | 2025-10-01 | Alejandro Jose Biehl Flores | Formulacion y procedimiento para la fabricacion de prismas rectangulares y cuadrangulares polimericos para su uso en la construccion de muros, lozas y tejados. |
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| JPS59124949A (ja) | 1983-01-05 | 1984-07-19 | Mitsubishi Rayon Co Ltd | ポリエステル樹脂用核剤マスタ−ペレツト組成物及びその製造方法 |
| US5049605A (en) | 1989-09-20 | 1991-09-17 | Milliken Research Corporation | Bis(3,4-dialkylbenzylidene) sorbitol acetals and compositions containing same |
| JPH03207738A (ja) * | 1990-01-10 | 1991-09-11 | Dainippon Ink & Chem Inc | ポリプロピレン用核剤組成物及びその製法 |
| AR012582A1 (es) * | 1997-04-14 | 2000-11-08 | Dow Global Technologies Inc | Composiciones polimericas de elongacion mejorada y formulaciones adhesivas de fusion en caliente que incluyen dicha composicion |
| GB0020080D0 (en) | 2000-08-15 | 2000-10-04 | Borealis Tech Oy | Injection moulding |
| US6534574B1 (en) | 2001-03-24 | 2003-03-18 | Milliken & Company | Highly nucleated thermoplastic articles |
| US6599968B2 (en) | 2001-03-24 | 2003-07-29 | Milliken & Company | Thermoplastic nucleating compounds |
| US6465551B1 (en) | 2001-03-24 | 2002-10-15 | Milliken & Company | Bicyclo[2.2.1]heptane dicarboxylate salts as polyolefin nucleators |
| US6562890B2 (en) | 2001-03-29 | 2003-05-13 | Milliken & Company | Disodium hexahydrophthalate salt compositions and nucleated polymers comprising such compositions |
| US6599971B2 (en) | 2001-03-29 | 2003-07-29 | Milliken & Company | Metals salts of hexahydrophthalic acid as nucleating additives for crystalline thermoplastics |
| US6559211B2 (en) | 2001-05-23 | 2003-05-06 | Milliken & Company | Highly versatile thermoplastic nucleators |
| US20030136046A1 (en) | 2001-11-21 | 2003-07-24 | Graham Jackson | Fuel additive |
| JP4063037B2 (ja) * | 2002-10-16 | 2008-03-19 | 東ソー株式会社 | ポリエチレン系架橋発泡体 |
| US7262236B2 (en) | 2004-04-26 | 2007-08-28 | Milliken & Company | Acetal-based compositions |
| US20070036960A1 (en) * | 2005-08-09 | 2007-02-15 | Lambert William S | Film and methods of making film |
| US7662978B2 (en) | 2006-04-24 | 2010-02-16 | Milliken & Company | Dibenzylidene sorbitol (DBS)-based compounds, compositions and methods for using such compounds |
| JP5388263B2 (ja) * | 2007-09-04 | 2014-01-15 | 株式会社Ａｄｅｋａ | ポリオレフィン樹脂用造核剤マスターバッチ |
| US8283400B2 (en) | 2008-06-09 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| CN103311484A (zh) * | 2008-09-03 | 2013-09-18 | 三菱树脂株式会社 | 隔板用叠层多孔膜 |
| EP2184319B1 (en) * | 2008-11-06 | 2011-04-20 | Clariant Finance (BVI) Limited | Process for the production of organic polymeric profiles |
| KR100996844B1 (ko) * | 2008-12-29 | 2010-11-26 | 주식회사 효성 | 올레핀 중합용 촉매를 이용하여 제조된 폴리프로필렌 수지 |
| US8779045B2 (en) | 2009-10-15 | 2014-07-15 | Milliken & Company | Thermoplastic polymer composition |
| US8198351B2 (en) | 2009-10-21 | 2012-06-12 | Milliken & Company | Thermoplastic polymer composition |
| WO2012162149A1 (en) * | 2011-05-20 | 2012-11-29 | The Procter & Gamble Company | Molded articles of polymer-wax compositions |
| PL2559726T3 (pl) * | 2011-08-15 | 2014-07-31 | Holland Colours Nv | Dodatek w postaci koncentratu i jego wykorzystania |
| CN102295807B (zh) * | 2011-09-05 | 2013-11-20 | 浙江俊尔新材料有限公司 | 挤出发泡聚丙烯珠粒及其制备方法 |
| CN103450556B (zh) * | 2013-01-24 | 2016-05-18 | 长春天成高新纳米复合材料有限公司 | 一种聚丙烯透相性纳米级均聚专用材料的制备方法 |
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2013
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- 2013-11-01 IN IN3299DEN2015 patent/IN2015DN03299A/en unknown
- 2013-11-01 US US14/070,077 patent/US20140179846A1/en not_active Abandoned
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2016
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| US10131751B2 (en) | 2018-11-20 |
| CN110105623A (zh) | 2019-08-09 |
| US20170088678A1 (en) | 2017-03-30 |
| BR112015014135A2 (pt) | 2017-07-11 |
| CN104870540B (zh) | 2019-05-14 |
| US20140179846A1 (en) | 2014-06-26 |
| EP2935433B1 (en) | 2019-09-18 |
| CN104870540A (zh) | 2015-08-26 |
| EP2935433A1 (en) | 2015-10-28 |
| WO2014099144A1 (en) | 2014-06-26 |
| JP2017149962A (ja) | 2017-08-31 |
| JP2016501961A (ja) | 2016-01-21 |
| CN110105623B (zh) | 2021-05-25 |
| IN2015DN03299A (enExample) | 2015-10-09 |
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Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 01/11/2013, OBSERVADAS AS CONDICOES LEGAIS. |