CN110105623B - 添加剂组合物和其使用方法 - Google Patents
添加剂组合物和其使用方法 Download PDFInfo
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- CN110105623B CN110105623B CN201910374433.6A CN201910374433A CN110105623B CN 110105623 B CN110105623 B CN 110105623B CN 201910374433 A CN201910374433 A CN 201910374433A CN 110105623 B CN110105623 B CN 110105623B
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- additive composition
- polymer
- nucleating agent
- extruder
- wax
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- ZHROMWXOTYBIMF-UHFFFAOYSA-M sodium;1,3,7,9-tetratert-butyl-11-oxido-5h-benzo[d][1,3,2]benzodioxaphosphocine 11-oxide Chemical compound [Na+].C1C2=CC(C(C)(C)C)=CC(C(C)(C)C)=C2OP([O-])(=O)OC2=C1C=C(C(C)(C)C)C=C2C(C)(C)C ZHROMWXOTYBIMF-UHFFFAOYSA-M 0.000 description 1
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- XYGNGXOAIOVNFU-UHFFFAOYSA-L strontium;cyclohexane-1,2-dicarboxylate Chemical compound [Sr+2].[O-]C(=O)C1CCCCC1C([O-])=O XYGNGXOAIOVNFU-UHFFFAOYSA-L 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/203—Solid polymers with solid and/or liquid additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
- C08K5/0083—Nucleating agents promoting the crystallisation of the polymer matrix
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/01—Hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
- C08J2491/06—Waxes
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Crystallography & Structural Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
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| CN201380066343.1A CN104870540B (zh) | 2012-12-21 | 2013-11-01 | 添加剂组合物和其使用方法 |
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| CN201380066343.1A Division CN104870540B (zh) | 2012-12-21 | 2013-11-01 | 添加剂组合物和其使用方法 |
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| CN110105623A CN110105623A (zh) | 2019-08-09 |
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| CN201380066343.1A Active CN104870540B (zh) | 2012-12-21 | 2013-11-01 | 添加剂组合物和其使用方法 |
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| CN201380066343.1A Active CN104870540B (zh) | 2012-12-21 | 2013-11-01 | 添加剂组合物和其使用方法 |
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| CN (2) | CN110105623B (enExample) |
| BR (1) | BR112015014135B1 (enExample) |
| IN (1) | IN2015DN03299A (enExample) |
| WO (1) | WO2014099144A1 (enExample) |
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| GB201317300D0 (en) * | 2013-09-30 | 2013-11-13 | Remet Uk Ltd | Casting Wax |
| JP2018024824A (ja) * | 2016-08-01 | 2018-02-15 | 日本ポリプロ株式会社 | ポリオレフィン系樹脂組成物の製造法および該ポリオレフィン系樹脂組成物を用いたフィルム |
| CN107177229B (zh) * | 2017-04-24 | 2020-12-29 | 东莞市隆海新材料科技有限公司 | 一种水性蜡分散体及其制备方法 |
| JP6397153B1 (ja) | 2018-05-18 | 2018-09-26 | 株式会社Adeka | 粒状核剤、樹脂組成物、成形品およびその製造方法 |
| CN110023393B (zh) | 2018-05-18 | 2020-02-21 | 株式会社艾迪科 | 粒状成核剂、树脂组合物、成型品及其制造方法 |
| JP6423982B1 (ja) | 2018-07-04 | 2018-11-14 | 株式会社Adeka | 粒状核剤、樹脂組成物、成形品およびその製造方法 |
| WO2020023384A1 (en) * | 2018-07-24 | 2020-01-30 | Milliken & Company | Additive composition and method for producing a polymer composition using the same |
| WO2020054492A1 (ja) | 2018-09-11 | 2020-03-19 | 新日本理化株式会社 | ポリオレフィン系樹脂中での分散性に優れた脂環式ジカルボン酸の金属塩、該脂環式ジカルボン酸の金属塩の製造方法、該脂環式ジカルボン酸の金属塩を含むポリオレフィン系樹脂用の結晶核剤、該結晶核剤を含んでなる結晶核剤組成物、ポリオレフィン系樹脂組成物、並びに、ポリオレフィン系樹脂成形体 |
| JP7143508B2 (ja) * | 2018-09-26 | 2022-09-28 | ミリケン・アンド・カンパニー | 添加剤組成物およびこれを使用してポリマー組成物を製造するための方法 |
| US11661504B2 (en) | 2019-01-23 | 2023-05-30 | Milliken & Company | Thermoplastic composition |
| KR102898835B1 (ko) * | 2019-06-27 | 2025-12-11 | 다우 글로벌 테크놀로지스 엘엘씨 | 폴리올레핀과 액체 유기 산의 균질한 혼합물을 제조하는 방법 |
| JP6731128B1 (ja) | 2020-03-16 | 2020-07-29 | 株式会社Adeka | 粒状核剤、樹脂組成物およびその製造方法ならびに成形品 |
| WO2025196487A1 (en) * | 2024-03-20 | 2025-09-25 | Biehl Flores Alejandro Jose | Formulation and procedure for the manufacturing of polymeric rectangular and quadrangular prisms |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03207738A (ja) * | 1990-01-10 | 1991-09-11 | Dainippon Ink & Chem Inc | ポリプロピレン用核剤組成物及びその製法 |
| CN1256705A (zh) * | 1997-04-14 | 2000-06-14 | 陶氏化学公司 | 具有改进伸长性的聚合物组合物 |
| CN1525992A (zh) * | 2001-03-29 | 2004-09-01 | 六氢化邻苯二甲酸二钠盐组合物和包括该组合物的成核聚合物 | |
| JP4063037B2 (ja) * | 2002-10-16 | 2008-03-19 | 東ソー株式会社 | ポリエチレン系架橋発泡体 |
| KR20100077500A (ko) * | 2008-12-29 | 2010-07-08 | 주식회사 효성 | 올레핀 중합용 촉매를 이용하여 제조된 폴리프로필렌 수지 |
| CN102046719A (zh) * | 2008-11-06 | 2011-05-04 | 科莱恩金融(Bvi)有限公司 | 制造有机聚合物型材的方法 |
| CN102171855A (zh) * | 2008-09-03 | 2011-08-31 | 三菱树脂株式会社 | 隔板用叠层多孔膜 |
| CN102295807A (zh) * | 2011-09-05 | 2011-12-28 | 浙江俊尔新材料有限公司 | 挤出发泡聚丙烯珠粒及其制备方法 |
| CN103450556A (zh) * | 2013-01-24 | 2013-12-18 | 长春天成高新纳米复合材料有限公司 | 一种聚丙烯透相性纳米级均聚专用材料的制备方法 |
| CN103547624A (zh) * | 2011-05-20 | 2014-01-29 | 宝洁公司 | 聚合物-蜡组合物的模塑制品 |
Family Cites Families (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59124949A (ja) | 1983-01-05 | 1984-07-19 | Mitsubishi Rayon Co Ltd | ポリエステル樹脂用核剤マスタ−ペレツト組成物及びその製造方法 |
| US5049605A (en) | 1989-09-20 | 1991-09-17 | Milliken Research Corporation | Bis(3,4-dialkylbenzylidene) sorbitol acetals and compositions containing same |
| GB0020080D0 (en) | 2000-08-15 | 2000-10-04 | Borealis Tech Oy | Injection moulding |
| US6465551B1 (en) | 2001-03-24 | 2002-10-15 | Milliken & Company | Bicyclo[2.2.1]heptane dicarboxylate salts as polyolefin nucleators |
| US6599968B2 (en) | 2001-03-24 | 2003-07-29 | Milliken & Company | Thermoplastic nucleating compounds |
| US6534574B1 (en) | 2001-03-24 | 2003-03-18 | Milliken & Company | Highly nucleated thermoplastic articles |
| US6599971B2 (en) | 2001-03-29 | 2003-07-29 | Milliken & Company | Metals salts of hexahydrophthalic acid as nucleating additives for crystalline thermoplastics |
| US6559211B2 (en) | 2001-05-23 | 2003-05-06 | Milliken & Company | Highly versatile thermoplastic nucleators |
| US20030136046A1 (en) | 2001-11-21 | 2003-07-24 | Graham Jackson | Fuel additive |
| US7262236B2 (en) | 2004-04-26 | 2007-08-28 | Milliken & Company | Acetal-based compositions |
| US20070036960A1 (en) * | 2005-08-09 | 2007-02-15 | Lambert William S | Film and methods of making film |
| US7662978B2 (en) | 2006-04-24 | 2010-02-16 | Milliken & Company | Dibenzylidene sorbitol (DBS)-based compounds, compositions and methods for using such compounds |
| JP5388263B2 (ja) * | 2007-09-04 | 2014-01-15 | 株式会社Adeka | ポリオレフィン樹脂用造核剤マスターバッチ |
| US8283400B2 (en) | 2008-06-09 | 2012-10-09 | Exxonmobil Chemical Patents Inc. | Polyolefin adhesive compositions |
| US8779045B2 (en) | 2009-10-15 | 2014-07-15 | Milliken & Company | Thermoplastic polymer composition |
| CN102575060A (zh) | 2009-10-21 | 2012-07-11 | 美利肯公司 | 热塑性聚合物组合物 |
| EP2559726B1 (en) * | 2011-08-15 | 2014-02-19 | Holland Colours N. V. | Additive concentrate and use thereof |
-
2013
- 2013-11-01 JP JP2015549381A patent/JP2016501961A/ja not_active Withdrawn
- 2013-11-01 BR BR112015014135-8A patent/BR112015014135B1/pt active IP Right Grant
- 2013-11-01 CN CN201910374433.6A patent/CN110105623B/zh active Active
- 2013-11-01 EP EP13792163.1A patent/EP2935433B1/en active Active
- 2013-11-01 CN CN201380066343.1A patent/CN104870540B/zh active Active
- 2013-11-01 US US14/070,077 patent/US20140179846A1/en not_active Abandoned
- 2013-11-01 IN IN3299DEN2015 patent/IN2015DN03299A/en unknown
- 2013-11-01 WO PCT/US2013/068063 patent/WO2014099144A1/en not_active Ceased
-
2016
- 2016-12-12 US US15/375,546 patent/US10131751B2/en active Active
-
2017
- 2017-03-28 JP JP2017062334A patent/JP6301525B2/ja active Active
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH03207738A (ja) * | 1990-01-10 | 1991-09-11 | Dainippon Ink & Chem Inc | ポリプロピレン用核剤組成物及びその製法 |
| CN1256705A (zh) * | 1997-04-14 | 2000-06-14 | 陶氏化学公司 | 具有改进伸长性的聚合物组合物 |
| CN1525992A (zh) * | 2001-03-29 | 2004-09-01 | 六氢化邻苯二甲酸二钠盐组合物和包括该组合物的成核聚合物 | |
| JP4063037B2 (ja) * | 2002-10-16 | 2008-03-19 | 東ソー株式会社 | ポリエチレン系架橋発泡体 |
| CN102171855A (zh) * | 2008-09-03 | 2011-08-31 | 三菱树脂株式会社 | 隔板用叠层多孔膜 |
| CN102046719A (zh) * | 2008-11-06 | 2011-05-04 | 科莱恩金融(Bvi)有限公司 | 制造有机聚合物型材的方法 |
| KR20100077500A (ko) * | 2008-12-29 | 2010-07-08 | 주식회사 효성 | 올레핀 중합용 촉매를 이용하여 제조된 폴리프로필렌 수지 |
| CN103547624A (zh) * | 2011-05-20 | 2014-01-29 | 宝洁公司 | 聚合物-蜡组合物的模塑制品 |
| CN102295807A (zh) * | 2011-09-05 | 2011-12-28 | 浙江俊尔新材料有限公司 | 挤出发泡聚丙烯珠粒及其制备方法 |
| CN103450556A (zh) * | 2013-01-24 | 2013-12-18 | 长春天成高新纳米复合材料有限公司 | 一种聚丙烯透相性纳米级均聚专用材料的制备方法 |
Also Published As
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|---|---|
| BR112015014135A2 (pt) | 2017-07-11 |
| CN104870540A (zh) | 2015-08-26 |
| JP2016501961A (ja) | 2016-01-21 |
| WO2014099144A1 (en) | 2014-06-26 |
| IN2015DN03299A (enExample) | 2015-10-09 |
| US10131751B2 (en) | 2018-11-20 |
| US20140179846A1 (en) | 2014-06-26 |
| EP2935433B1 (en) | 2019-09-18 |
| US20170088678A1 (en) | 2017-03-30 |
| EP2935433A1 (en) | 2015-10-28 |
| CN104870540B (zh) | 2019-05-14 |
| BR112015014135B1 (pt) | 2021-05-18 |
| JP2017149962A (ja) | 2017-08-31 |
| JP6301525B2 (ja) | 2018-03-28 |
| CN110105623A (zh) | 2019-08-09 |
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