BR0214577A - Copolìmero de etileno/alfa-olefina feito com uma combinação de um catalisador de sìtio-único/sìtio-não-único, sua preparação e uso - Google Patents
Copolìmero de etileno/alfa-olefina feito com uma combinação de um catalisador de sìtio-único/sìtio-não-único, sua preparação e usoInfo
- Publication number
- BR0214577A BR0214577A BR0214577-4A BR0214577A BR0214577A BR 0214577 A BR0214577 A BR 0214577A BR 0214577 A BR0214577 A BR 0214577A BR 0214577 A BR0214577 A BR 0214577A
- Authority
- BR
- Brazil
- Prior art keywords
- site
- ethylene
- preparation
- olefin copolymer
- alpha
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/02—Ethene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/04—Polymerisation in solution
- C08F2/06—Organic solvent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
- C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
- C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
- C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/02—Ziegler natta catalyst
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2314/00—Polymer mixtures characterised by way of preparation
- C08L2314/06—Metallocene or single site catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31855—Of addition polymer from unsaturated monomers
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
"COPOLìMERO DE ETILENO/ALFA-OLEFINA FEITO COM UMA COMBINAçãO DE UM CATALISADOR DE SìTIO-úNICO/SìTIO-NãO-úNICO, SUA PREPARAçãO E USO". A presente invenção refere-se a um copolímero de etileno/<244>-olefina compreendendo um componente produzido por um catalisador de polimerização de sítio-não-único e um componente produzido por um catalisador de polimerização de sítio-único, sua preparação e uso são descritos. O copolímero tem um teor de <244>-olefina de 5 a 20 por cento em peso e mostra pelo menos duas temperaturas de pico CRYSTAF diferindo em pelo menos 15<198>C e/ou pelo menos duas temperaturas de pico de fusão por DSC diferindo em pelo menos 15<198>C.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US33456601P | 2001-11-30 | 2001-11-30 | |
PCT/US2002/032806 WO2003048213A1 (en) | 2001-11-30 | 2002-10-11 | Ethylene/alpha-olefin copolymer made with a non-single-site/single-site catalyst combination, its preparation and use |
Publications (1)
Publication Number | Publication Date |
---|---|
BR0214577A true BR0214577A (pt) | 2004-11-03 |
Family
ID=23307800
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BR0214577-4A BR0214577A (pt) | 2001-11-30 | 2002-10-11 | Copolìmero de etileno/alfa-olefina feito com uma combinação de um catalisador de sìtio-único/sìtio-não-único, sua preparação e uso |
Country Status (9)
Country | Link |
---|---|
US (1) | US7101939B2 (pt) |
EP (1) | EP1461364A4 (pt) |
JP (1) | JP2005511804A (pt) |
KR (1) | KR20050035183A (pt) |
CN (1) | CN1275985C (pt) |
AU (1) | AU2002332129A1 (pt) |
BR (1) | BR0214577A (pt) |
CA (1) | CA2465647C (pt) |
WO (1) | WO2003048213A1 (pt) |
Families Citing this family (29)
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ES2268493T3 (es) * | 2002-12-24 | 2007-03-16 | Basell Polyolefine Gmbh | Composicion de polietileno para la produccion de bidones del tipo l-ring. |
SG151301A1 (en) * | 2004-03-17 | 2009-04-30 | Dow Global Technologies Inc | Catalyst composition comprising shuttling agent for ethylene multi- block copolymer formation |
CN1938341B (zh) * | 2004-04-07 | 2011-08-10 | 尤尼威蒂恩技术有限责任公司 | 控制烯烃聚合的方法 |
CN101133092B (zh) * | 2005-03-04 | 2011-01-12 | 尤尼威蒂恩技术有限公司 | 生产率提高的齐格勒型催化剂 |
DE102005030941A1 (de) * | 2005-06-30 | 2007-01-11 | Basell Polyolefine Gmbh | Polyethylen Formmasse zur Herstellung von spritzgegossenen Fertigteilen |
DE102005040390A1 (de) * | 2005-08-25 | 2007-03-01 | Basell Polyolefine Gmbh | Multimodale Polyethylen Formmasse zur Herstellung von Rohren mit verbesserten mechanischen Eigenschaften |
CN101273445B (zh) * | 2005-09-28 | 2012-07-25 | 大见忠弘 | 可控气氛的接合装置、接合方法及电子装置 |
JP5371436B2 (ja) * | 2005-11-23 | 2013-12-18 | ダウ グローバル テクノロジーズ エルエルシー | 不均一な、組成によって相分離された、エチレンα−オレフィンインターポリマー |
BRPI0712945B1 (pt) * | 2006-06-27 | 2018-05-08 | Univation Tech Llc | Processo para a produção de um Copolímero de Etileno Alfa- Olefina |
RU2446179C2 (ru) * | 2006-06-27 | 2012-03-27 | ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи | Усовершенствованные способы полимеризации с использованием металлоценовых катализаторов, полимерные продукты и их применение |
KR101299375B1 (ko) * | 2006-06-27 | 2013-08-22 | 유니베이션 테크놀로지즈, 엘엘씨 | 에틸렌-알파 올레핀 공중합체 및 이의 중합 제조 방법 |
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CN103119071B (zh) * | 2010-09-28 | 2016-07-06 | 巴塞尔聚烯烃股份有限公司 | 聚乙烯挤出制品 |
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CN105229039B (zh) | 2013-09-26 | 2018-04-27 | 株式会社Lg化学 | 催化剂组合物和包括其的聚合物制备方法 |
DE102014009466A1 (de) * | 2014-06-30 | 2015-12-31 | Sig Technology Ag | Flächenförmiger Verbund mit einer mPolyolefinschicht mit verringertem Antioxidansanteil, insbesondere für Nahrungsmittelverpackungen |
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US9540457B1 (en) * | 2015-09-24 | 2017-01-10 | Chevron Phillips Chemical Company Lp | Ziegler-natta—metallocene dual catalyst systems with activator-supports |
US10329412B2 (en) | 2017-02-16 | 2019-06-25 | Nova Chemicals (International) S.A. | Caps and closures |
JP6867187B2 (ja) * | 2017-02-24 | 2021-04-28 | 旭化成株式会社 | ポリエチレン粒子及び成形体 |
JP7421261B2 (ja) * | 2017-03-31 | 2024-01-24 | 三井化学株式会社 | エチレン系樹脂組成物 |
US10442920B2 (en) | 2017-04-19 | 2019-10-15 | Nova Chemicals (International) S.A. | Means for increasing the molecular weight and decreasing the density of ethylene interpolymers employing homogeneous and heterogeneous catalyst formulations |
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-
2002
- 2002-10-11 WO PCT/US2002/032806 patent/WO2003048213A1/en active Application Filing
- 2002-10-11 JP JP2003549399A patent/JP2005511804A/ja active Pending
- 2002-10-11 EP EP02769073A patent/EP1461364A4/en not_active Ceased
- 2002-10-11 US US10/497,249 patent/US7101939B2/en not_active Expired - Lifetime
- 2002-10-11 CN CNB028237153A patent/CN1275985C/zh not_active Expired - Lifetime
- 2002-10-11 AU AU2002332129A patent/AU2002332129A1/en not_active Abandoned
- 2002-10-11 BR BR0214577-4A patent/BR0214577A/pt not_active Application Discontinuation
- 2002-10-11 CA CA2465647A patent/CA2465647C/en not_active Expired - Lifetime
- 2002-10-11 KR KR1020047008308A patent/KR20050035183A/ko not_active Application Discontinuation
Also Published As
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AU2002332129A1 (en) | 2003-06-17 |
EP1461364A1 (en) | 2004-09-29 |
US20050054791A1 (en) | 2005-03-10 |
US7101939B2 (en) | 2006-09-05 |
JP2005511804A (ja) | 2005-04-28 |
EP1461364A4 (en) | 2010-11-17 |
CN1596271A (zh) | 2005-03-16 |
CA2465647C (en) | 2010-12-14 |
KR20050035183A (ko) | 2005-04-15 |
CA2465647A1 (en) | 2003-06-12 |
CN1275985C (zh) | 2006-09-20 |
WO2003048213A1 (en) | 2003-06-12 |
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