DE69328955T2 - Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen - Google Patents

Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen

Info

Publication number
DE69328955T2
DE69328955T2 DE69328955T DE69328955T DE69328955T2 DE 69328955 T2 DE69328955 T2 DE 69328955T2 DE 69328955 T DE69328955 T DE 69328955T DE 69328955 T DE69328955 T DE 69328955T DE 69328955 T2 DE69328955 T2 DE 69328955T2
Authority
DE
Germany
Prior art keywords
catalyst compositions
processes
complexes
polyolefins
making polyolefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69328955T
Other languages
English (en)
Other versions
DE69328955D1 (de
Inventor
Ian Raymond C O Bp Chem Little
John Paul Mcnally
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB929218814A external-priority patent/GB9218814D0/en
Priority claimed from GB939308078A external-priority patent/GB9308078D0/en
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of DE69328955D1 publication Critical patent/DE69328955D1/de
Application granted granted Critical
Publication of DE69328955T2 publication Critical patent/DE69328955T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts
DE69328955T 1992-09-04 1993-08-23 Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen Expired - Lifetime DE69328955T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB929218814A GB9218814D0 (en) 1992-09-04 1992-09-04 Catalyst compositions and uses therefor
GB939308078A GB9308078D0 (en) 1993-04-20 1993-04-20 Catalyst compositions and uses thereof

Publications (2)

Publication Number Publication Date
DE69328955D1 DE69328955D1 (de) 2000-08-10
DE69328955T2 true DE69328955T2 (de) 2000-11-09

Family

ID=26301556

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69328955T Expired - Lifetime DE69328955T2 (de) 1992-09-04 1993-08-23 Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen

Country Status (15)

Country Link
US (1) US5747405A (de)
EP (1) EP0586168B1 (de)
JP (1) JP3382311B2 (de)
KR (1) KR100293264B1 (de)
CN (1) CN1080268C (de)
AT (1) ATE194361T1 (de)
CA (1) CA2105013A1 (de)
DE (1) DE69328955T2 (de)
ES (1) ES2148205T3 (de)
FI (1) FI112235B (de)
GR (1) GR3033857T3 (de)
MY (1) MY108939A (de)
NO (1) NO308134B1 (de)
PT (1) PT586168E (de)
RU (1) RU2165435C2 (de)

Families Citing this family (47)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69518104T2 (de) * 1994-04-07 2000-12-14 Bp Chem Int Ltd Polymerisationsverfahren
US5498581A (en) * 1994-06-01 1996-03-12 Phillips Petroleum Company Method for making and using a supported metallocene catalyst system
US5529965A (en) * 1994-10-28 1996-06-25 Exxon Chemical Patents Inc. Polymerization catalyst systems, their production and use
US5770755A (en) * 1994-11-15 1998-06-23 Phillips Petroleum Company Process to prepare polymeric metallocenes
US5700748A (en) * 1995-09-29 1997-12-23 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers comprising a bridging allyl-cyclodienyl ligand on a metal atom
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
DE69821528T2 (de) 1997-12-08 2004-07-01 Albemarle Corp. Katalysatorzusammensetzungen mit gesteigertem leistungsvermögen
US6677265B1 (en) 1997-12-08 2004-01-13 Albemarle Corporation Process of producing self-supported catalysts
US6551955B1 (en) 1997-12-08 2003-04-22 Albemarle Corporation Particulate group 4 metallocene-aluminoxane catalyst compositions devoid of preformed support, and their preparation and their use
GB9806407D0 (en) * 1998-03-25 1998-05-20 Bp Chem Int Ltd Novel polymer compositions
US6136747A (en) * 1998-06-19 2000-10-24 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst composition for the production of olefin polymers
CN1091451C (zh) * 1998-10-06 2002-09-25 中国石油化工集团公司 合成宽或双峰分子量分布的聚烯烃的催化剂及制备方法
US6340651B1 (en) * 1999-04-26 2002-01-22 Phillips Petroleum Company Multicyclic metallocycle metallocenes and their use
US6291382B1 (en) * 1999-05-24 2001-09-18 Phillips Petroleum Company Metallocenes, polymerization catalyst systems, their preparation, and use
US6475947B1 (en) * 1999-09-10 2002-11-05 Phillips Petroleum Company Oligomeric metallocenes and their use
KR100336618B1 (ko) * 1999-09-28 2002-05-16 박호군 아민기가 치환된 유기실란을 포함한 신규의 메탈로센 화합물
US6399531B1 (en) 1999-12-28 2002-06-04 Union Carbide Chemicals & Plastics Technology Corporation Hybrid ziegler-natta and cycloalkadienyl catalysts for the production of polyolefins
US6444605B1 (en) 1999-12-28 2002-09-03 Union Carbide Chemicals & Plastics Technology Corporation Mixed metal alkoxide and cycloalkadienyl catalysts for the production of polyolefins
US6528448B1 (en) 2000-04-28 2003-03-04 Phillips Petroleum Company Polymerization catalyst compositions and processes to produce polymers and bimodal polymers
KR100365869B1 (ko) * 2000-08-05 2002-12-27 호남석유화학 주식회사 메탈로센 화합물 및 이를 사용하는 중합방법
BR0214577A (pt) * 2001-11-30 2004-11-03 Exxonmobil Chem Patents Inc Copolìmero de etileno/alfa-olefina feito com uma combinação de um catalisador de sìtio-único/sìtio-não-único, sua preparação e uso
US6916892B2 (en) * 2001-12-03 2005-07-12 Fina Technology, Inc. Method for transitioning between Ziegler-Natta and metallocene catalysts in a bulk loop reactor for the production of polypropylene
US7166553B2 (en) * 2002-05-06 2007-01-23 Union Carbide Chemicals & Plastics Technology Corporation Mixed catalyst compositions for the production of polyolefins
US20040043214A1 (en) * 2002-08-30 2004-03-04 Kimberly-Clark Worldwide, Inc. Method of forming a 3-dimensional fiber and a web formed from such fibers
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
JP4972284B2 (ja) 2002-10-15 2012-07-11 エクソンモービル・ケミカル・パテンツ・インク オレフィン重合のための複数触媒系及びそれらから生成されたポリマー
US7226880B2 (en) * 2002-12-31 2007-06-05 Kimberly-Clark Worldwide, Inc. Breathable, extensible films made with two-component single resins
EP1496069A1 (de) * 2003-07-09 2005-01-12 Total Petrochemicals Research Feluy Polymerisationsverfahren
US7932196B2 (en) 2003-08-22 2011-04-26 Kimberly-Clark Worldwide, Inc. Microporous stretch thinned film/nonwoven laminates and limited use or disposable product applications
US7163906B2 (en) * 2004-11-04 2007-01-16 Chevron Phillips Chemical Company, Llp Organochromium/metallocene combination catalysts for producing bimodal resins
CN1328310C (zh) * 2004-11-05 2007-07-25 中国科学院化学研究所 聚烯烃复合材料及其制备方法
KR20100015391A (ko) * 2007-03-07 2010-02-12 다우 글로벌 테크놀로지스 인크. 테더링된 담지 전이 금속 착체
US7884165B2 (en) 2008-07-14 2011-02-08 Chevron Phillips Chemical Company Lp Half-metallocene catalyst compositions and their polymer products
US8309748B2 (en) 2011-01-25 2012-11-13 Chevron Phillips Chemical Company Lp Half-metallocene compounds and catalyst compositions
KR101503567B1 (ko) * 2011-08-18 2015-03-17 주식회사 엘지화학 폴리올레핀 수지의 제조방법
KR101331556B1 (ko) 2012-03-30 2013-11-20 대림산업 주식회사 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체
CN102887967B (zh) * 2012-10-17 2015-03-18 上海化工研究院 用于生产宽分子量分布聚乙烯的复合催化剂及制法和应用
KR101437509B1 (ko) 2012-12-03 2014-09-03 대림산업 주식회사 성형성 및 기계적 물성이 우수한 멀티모달 폴리올레핀 수지 제조를 위한 촉매 조성물 및 이를 이용한 중합 방법
MX2017016934A (es) 2015-07-08 2018-04-10 Chevron Phillips Chemical Co Lp Sistemas de catalizadores duales de metaloceno y ziegler-natta con soportes activadores.
US9540457B1 (en) 2015-09-24 2017-01-10 Chevron Phillips Chemical Company Lp Ziegler-natta—metallocene dual catalyst systems with activator-supports
US9845367B2 (en) 2015-09-24 2017-12-19 Chevron Phillips Chemical Company Lp Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina
US9758599B2 (en) 2015-09-24 2017-09-12 Chevron Phillips Chemical Company Lp Heterogeneous Ziegler-Natta catalysts with fluorided silica-coated alumina
KR101800866B1 (ko) 2016-04-26 2017-12-21 대림산업 주식회사 용융강도가 높은 멀티모달 폴리올레핀 수지 및 이로부터 제조되는 성형체
KR102219407B1 (ko) * 2018-11-20 2021-02-23 한화솔루션 주식회사 올레핀 중합 촉매용 전이금속 화합물 및 이를 포함하는 올레핀 중합 촉매
KR102565859B1 (ko) * 2019-07-22 2023-08-11 한화솔루션 주식회사 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀
KR102565858B1 (ko) * 2019-07-30 2023-08-11 한화솔루션 주식회사 올레핀 중합 촉매용 전이금속 화합물, 이를 포함하는 올레핀 중합 촉매 및 이를 이용하여 중합된 폴리올레핀
KR102486137B1 (ko) * 2019-10-29 2023-01-06 한화솔루션 주식회사 올레핀계 중합체 및 필름의 제조방법

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5077255A (en) * 1986-09-09 1991-12-31 Exxon Chemical Patents Inc. New supported polymerization catalyst
DE3840772A1 (de) * 1988-12-03 1990-06-07 Hoechst Ag Verfahren zur herstellung einer heterogenen metallocenkatalysatorkomponente
ATE166077T1 (de) * 1991-01-12 1998-05-15 Targor Gmbh Metallocen(co)polymere, verfahren zu ihrer herstellung und ihre verwendung als katalysatoren; metallocene hierfür.
US5169818A (en) * 1991-01-12 1992-12-08 Hoechst Aktiengesellschaft Metallocene (co)polymers, process for their preparation and their use as catalysts

Also Published As

Publication number Publication date
KR940007062A (ko) 1994-04-26
NO933079D0 (no) 1993-08-30
FI933806A0 (fi) 1993-08-31
DE69328955D1 (de) 2000-08-10
GR3033857T3 (en) 2000-10-31
NO933079L (no) 1994-03-07
FI933806A (fi) 1994-03-05
EP0586168A1 (de) 1994-03-09
ES2148205T3 (es) 2000-10-16
CN1087095A (zh) 1994-05-25
CN1080268C (zh) 2002-03-06
ATE194361T1 (de) 2000-07-15
PT586168E (pt) 2000-12-29
EP0586168B1 (de) 2000-07-05
MY108939A (en) 1996-11-30
CA2105013A1 (en) 1994-03-05
FI112235B (fi) 2003-11-14
JPH06157631A (ja) 1994-06-07
RU2165435C2 (ru) 2001-04-20
KR100293264B1 (ko) 2001-09-17
JP3382311B2 (ja) 2003-03-04
NO308134B1 (no) 2000-07-31
US5747405A (en) 1998-05-05

Similar Documents

Publication Publication Date Title
DE69328955D1 (de) Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen
RU93050069A (ru) Композиция катализатора и процесс изготовления полиолефинов
ATE181930T1 (de) Katalysatorzusammensetzungen und verfahren zur herstellung von polyolefinen
ATE224399T1 (de) Polymerisationskatalysatore, verfahren zur herstellung davon, vorläufer dafür und verfahren zur verwendung
DE59409990D1 (de) Verfahren zur Herstellung von Polyolefinen
DE69330163D1 (de) Reaktive viskose olefinpolymere und copolymere mit niedrigem molekulargewicht und verfahren zur herstellung davon
ATE66935T1 (de) Titanium-, zirconium- und hafnium-enolate als initiatoren bei der polymerisation von acrylatmonomeren zu lebenden polymeren.
DE59204800D1 (de) Verfahren zur Herstellung von syndiotaktischen Polyolefinen mit breiter Molmassenverteilung
EP0307755A3 (de) Verfahren zur Herstellung von Ethylen/Vinylacetat-Copolymerisaten, neue Ethylen/Vinylacetat-Copolymerisate und ihre Verwendung
DE59304393D1 (de) Verfahren zur Herstellung eines Katalysatorsystems für die Polymerisation und Copolymerisation von Ethylen zu ultrahochmolekularen Ethylpolymeren
DE738287T1 (de) Ungesättigtes ethylen copolymer und verfahren zu dessen herstellung
DE69032420D1 (de) Syndiotaktische Polymere von arylcyclobutenfunktionalen Monomeren, Verfahren zur Herstellung und daraus hergestellte vernetzte Derivate
DE59406383D1 (de) Verfahren zur Herstellung eines Katalysatorsystems für die Polymerisation und Copolymerisation von Ethylen zu ultrahochmolekularen Ethylenhomo- und copolymeren
DE59503492D1 (de) Verfahren zur Herstellung einer Katalysatorkomponente für die Polymerisation von Ethylen und 1-Olefinen zu ultrahochmolekuloren Ethylenpolymeren
DE69121321T2 (de) Polymerperoxid, Polymerisationsinitiator und Verfahren zur Herstellung von Blockcopolymeren
ATE167877T1 (de) Verfahren zur herstellung von geträgertem katalysator und seine verwendung bei der polymerisation oder copolymerisation von ethylen
DE69101837T2 (de) Polymerisationskatalysator zur herstellung von 1-olefinpolymeren mit einer breiten molekulargewichtsverteilung.
DE69133380D1 (de) Katalysatorzusammensetzung und Verfahren zur Herstellung von Polymeren mit einer multimodalen Molekulargewichtsverteilung

Legal Events

Date Code Title Description
8364 No opposition during term of opposition