ATE181930T1 - Katalysatorzusammensetzungen und verfahren zur herstellung von polyolefinen - Google Patents

Katalysatorzusammensetzungen und verfahren zur herstellung von polyolefinen

Info

Publication number
ATE181930T1
ATE181930T1 AT94300118T AT94300118T ATE181930T1 AT E181930 T1 ATE181930 T1 AT E181930T1 AT 94300118 T AT94300118 T AT 94300118T AT 94300118 T AT94300118 T AT 94300118T AT E181930 T1 ATE181930 T1 AT E181930T1
Authority
AT
Austria
Prior art keywords
catalyst compositions
methods
producing polyolefins
complexes
polyolefins
Prior art date
Application number
AT94300118T
Other languages
English (en)
Inventor
John Paul Mcnally
Original Assignee
Bp Chem Int Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bp Chem Int Ltd filed Critical Bp Chem Int Ltd
Application granted granted Critical
Publication of ATE181930T1 publication Critical patent/ATE181930T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901—Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
AT94300118T 1993-01-19 1994-01-07 Katalysatorzusammensetzungen und verfahren zur herstellung von polyolefinen ATE181930T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB939300934A GB9300934D0 (en) 1993-01-19 1993-01-19 Metallocene complexes

Publications (1)

Publication Number Publication Date
ATE181930T1 true ATE181930T1 (de) 1999-07-15

Family

ID=10728908

Family Applications (1)

Application Number Title Priority Date Filing Date
AT94300118T ATE181930T1 (de) 1993-01-19 1994-01-07 Katalysatorzusammensetzungen und verfahren zur herstellung von polyolefinen

Country Status (13)

Country Link
US (2) US5814574A (de)
EP (1) EP0608054B1 (de)
JP (1) JP3481285B2 (de)
KR (1) KR100299701B1 (de)
CN (1) CN1087303C (de)
AT (1) ATE181930T1 (de)
CA (1) CA2113601A1 (de)
DE (1) DE69419326T2 (de)
ES (1) ES2135539T3 (de)
FI (1) FI940266A (de)
GB (1) GB9300934D0 (de)
GR (1) GR3030725T3 (de)
NO (1) NO308133B1 (de)

Families Citing this family (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1996013529A1 (en) * 1994-10-31 1996-05-09 Dsm N.V. Catalyst composition and process for the polymerization of an olefin
ES2161919T3 (es) * 1994-11-22 2001-12-16 Atofina Res Metalocenos puenteados para uso en sistemas cataliticos para la polimerizacion de olefinas.
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
ATE186919T1 (de) * 1995-10-27 1999-12-15 Dow Chemical Co Metallische komplexe, die geträgert werden können
US6066588A (en) * 1995-11-22 2000-05-23 Fina Research, S.A. Bridged metallocenes catalyst for polymerization of olefins
DE19602543A1 (de) 1996-01-25 1997-07-31 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alkenen in Gegenwart von Metallocenkomplexen mit kationisch funktionalisierten Cyclopentadienylliganden
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
EP0878486B1 (de) * 1997-02-21 2006-01-25 Council of Scientific and Industrial Research Verfahren zur Herstellung eines geträgerten Metallocen-Katalysators
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6268447B1 (en) 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
GB9722447D0 (en) * 1997-10-23 1997-12-24 Borealis As Process
CN1098867C (zh) * 1998-01-14 2003-01-15 中国石油化工集团公司 淤浆法全密度聚乙烯高效催化剂
KR100358225B1 (ko) 1998-04-09 2003-01-24 주식회사 엘지화학 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법
KR100380018B1 (ko) 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
DE19903695A1 (de) * 1999-02-01 2000-08-03 Elenac Gmbh Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtsverteilung
DE19903783A1 (de) * 1999-02-01 2000-08-03 Elenac Gmbh Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtsverteilung
US7247595B2 (en) * 1999-06-22 2007-07-24 Lg Chem, Ltd. Supported metallocene catalyst and olefin polymerization using the same
US7041618B2 (en) * 1999-06-22 2006-05-09 Lg Chemical Ltd. Supported metallocene catalyst and olefin polymerization using the same
KR100354290B1 (ko) * 1999-06-22 2002-09-28 주식회사 엘지화학 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합
US6548442B1 (en) * 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
US6723675B1 (en) * 2000-05-25 2004-04-20 Univation Technologies, Llc Catalyst for the production of olefin polymers
CN100379745C (zh) * 2001-10-26 2008-04-09 埃普切公司 化学气相淀积用的改良的前体
CA2480006A1 (en) * 2002-04-12 2003-10-23 Hong Yang Azaborolyl group 4 metal complexes, catalysts and olefin polymerization process
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
KR101113341B1 (ko) 2002-10-15 2012-09-27 엑손모빌 케미칼 패턴츠 인코포레이티드 올레핀 중합용 다중 촉매 시스템 및 이로부터 제조된중합체
ATE469927T1 (de) 2003-03-21 2010-06-15 Dow Global Technologies Inc Verfahren zur herstellung von polyolefinen mit kontrollierter morphologie
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법
ES2339956T3 (es) 2004-12-17 2010-05-27 Dow Global Technologies Inc. Composiciones de polietileno con reologia modificada.
GB2432363B (en) * 2005-11-16 2010-06-23 Epichem Ltd Hafnocene and zirconocene precursors, and use thereof in atomic layer deposition
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
CN101356226B (zh) 2006-05-02 2012-09-05 陶氏环球技术有限责任公司 高密度聚乙烯组合物、其制备方法、由其制得的制品以及该制品的制备方法
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US7956207B2 (en) * 2006-09-28 2011-06-07 Praxair Technology, Inc. Heteroleptic organometallic compounds
BRPI0713185B1 (pt) * 2007-05-02 2018-08-28 Dow Global Technologies Inc composição de polietileno de alta densidade, método para produzir uma composição de polietileno de alta densidade, tampa de garrafa, método para produzir uma tampa de garrafa e composição de polietileno de alta densidade
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
BRPI0922454A2 (pt) 2008-12-18 2018-05-22 Univation Tech Llc método para tratamento de leito de semente para uma reação de polimerização
MX2011008053A (es) 2009-01-30 2012-01-12 Dow Global Technologies Llc Composiciones de polietileno de alta densidad, metodo para producir las mismas, dispositivos de cierre elaborados de las mismas, y metodo para elaborar dichos dispositivos de cierre.
WO2011056432A2 (en) 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
WO2011056423A2 (en) * 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
WO2011056431A2 (en) * 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
CN102666597A (zh) * 2009-10-28 2012-09-12 埃克森美孚化学专利公司 催化剂化合物和它们的用途
CN102597015A (zh) * 2009-10-28 2012-07-18 埃克森美孚化学专利公司 催化剂化合物和它们的用途
WO2014105614A1 (en) 2012-12-28 2014-07-03 Univation Technologies, Llc Methods of integrating aluminoxane production into catalyst production
RU2647855C2 (ru) 2013-01-14 2018-03-21 ЮНИВЕЙШН ТЕКНОЛОДЖИЗ, ЭлЭлСи Способы получения каталитических систем с повышенной производительностью
CA2985112C (en) 2015-05-08 2020-06-30 Exxonmobil Chemical Patents Inc. Polymerization process comprising 2,2-dimethylpropane as condensing agent
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
WO2019118073A1 (en) 2017-12-13 2019-06-20 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization process
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
CN112055720B (zh) 2018-05-02 2022-11-22 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
CN112055719B (zh) 2018-05-02 2022-11-25 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
WO2020023207A1 (en) 2018-07-26 2020-01-30 Exxonmobil Chemical Patents Inc. Multilayer foam films and methods for making the same
WO2020102380A1 (en) 2018-11-13 2020-05-22 Exxonmobil Chemical Patents Inc. Polyethylene blends and films
EP3880739A1 (de) 2018-11-13 2021-09-22 ExxonMobil Chemical Patents Inc. Polyethylenfilme
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
US20230018505A1 (en) 2019-12-17 2023-01-19 Exxonmobil Chemical Patents Inc. Films Made of Polyethylene Blends for Improved Sealing Performance and Mechanical Properties
WO2021183337A1 (en) 2020-03-12 2021-09-16 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
US20240209124A1 (en) 2021-04-30 2024-06-27 Exxonmobil Chemical Patents Inc. Processes for transitioning between different polymerization catalysts in a polymerization reactor

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2583307B1 (fr) * 1985-06-14 1993-07-02 Atochem Support a base de silice et de chlorure de magnesium, son procede de fabrication, catalyseurs obtenus a partir de ce support.
US5122491A (en) * 1987-04-20 1992-06-16 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
JP2538595B2 (ja) * 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
GB8716950D0 (en) * 1987-07-17 1987-08-26 Ici Plc Polymers & catalyst components
US5227440A (en) * 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5266544A (en) * 1989-12-29 1993-11-30 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
DE59107926D1 (de) * 1990-11-12 1996-07-18 Hoechst Ag Metallocene mit Liganden aus 2-substituierten Indenylderivaten, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren
US5349100A (en) * 1991-01-02 1994-09-20 Exxon Chemical Patents Inc. Chiral metallocene compounds and preparation thereof by creation of a chiral center by enantioselective hydride transfer
ES2116299T3 (es) * 1991-01-12 1998-07-16 Targor Gmbh (co)polimeros de metaloceno, procedimiento para su obtencion, y su empleo como catalizadores.
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
DE69220675T2 (de) * 1991-12-13 1997-10-23 Exxon Chemical Patents, Inc., Baytown, Tex. ETHYLEN/HöHERE ALPHA-OLEFINCOPOLYMERE

Also Published As

Publication number Publication date
NO940172D0 (no) 1994-01-18
FI940266A0 (fi) 1994-01-19
CA2113601A1 (en) 1994-07-20
ES2135539T3 (es) 1999-11-01
DE69419326D1 (de) 1999-08-12
KR100299701B1 (ko) 2001-10-22
JPH06239916A (ja) 1994-08-30
JP3481285B2 (ja) 2003-12-22
KR940018401A (ko) 1994-08-16
EP0608054A2 (de) 1994-07-27
US5814574A (en) 1998-09-29
GB9300934D0 (en) 1993-03-10
US5767209A (en) 1998-06-16
EP0608054B1 (de) 1999-07-07
DE69419326T2 (de) 1999-11-04
NO940172L (no) 1994-07-20
GR3030725T3 (en) 1999-11-30
NO308133B1 (no) 2000-07-31
EP0608054A3 (de) 1994-11-30
CN1092081A (zh) 1994-09-14
FI940266A (fi) 1994-07-20
CN1087303C (zh) 2002-07-10

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