DE69419326D1 - Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen - Google Patents

Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen

Info

Publication number
DE69419326D1
DE69419326D1 DE69419326T DE69419326T DE69419326D1 DE 69419326 D1 DE69419326 D1 DE 69419326D1 DE 69419326 T DE69419326 T DE 69419326T DE 69419326 T DE69419326 T DE 69419326T DE 69419326 D1 DE69419326 D1 DE 69419326D1
Authority
DE
Germany
Prior art keywords
catalyst compositions
processes
making polyolefins
complexes
polyolefins
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69419326T
Other languages
English (en)
Other versions
DE69419326T2 (de
Inventor
John Paul Mcnally
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BP Chemicals Ltd
Original Assignee
BP Chemicals Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BP Chemicals Ltd filed Critical BP Chemicals Ltd
Publication of DE69419326D1 publication Critical patent/DE69419326D1/de
Application granted granted Critical
Publication of DE69419326T2 publication Critical patent/DE69419326T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00Metallocenes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02Ethene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65904Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with another component of C08F4/64
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62Refractory metals or compounds thereof
    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/901Monomer polymerized in vapor state in presence of transition metal containing catalyst
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943Polymerization with metallocene catalysts
DE69419326T 1993-01-19 1994-01-07 Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen Expired - Fee Related DE69419326T2 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB939300934A GB9300934D0 (en) 1993-01-19 1993-01-19 Metallocene complexes

Publications (2)

Publication Number Publication Date
DE69419326D1 true DE69419326D1 (de) 1999-08-12
DE69419326T2 DE69419326T2 (de) 1999-11-04

Family

ID=10728908

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69419326T Expired - Fee Related DE69419326T2 (de) 1993-01-19 1994-01-07 Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen

Country Status (13)

Country Link
US (2) US5814574A (de)
EP (1) EP0608054B1 (de)
JP (1) JP3481285B2 (de)
KR (1) KR100299701B1 (de)
CN (1) CN1087303C (de)
AT (1) ATE181930T1 (de)
CA (1) CA2113601A1 (de)
DE (1) DE69419326T2 (de)
ES (1) ES2135539T3 (de)
FI (1) FI940266A (de)
GB (1) GB9300934D0 (de)
GR (1) GR3030725T3 (de)
NO (1) NO308133B1 (de)

Families Citing this family (64)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU3817595A (en) * 1994-10-31 1996-05-23 Dsm N.V. Catalyst composition and process for the polymerization of an olefin
KR100417970B1 (ko) * 1994-11-22 2004-06-26 아토피나 리서치 올레핀중합촉매시스템에유용한가교메탈로센
DE19517851A1 (de) * 1995-05-16 1996-11-21 Hoechst Ag Organometallverbindung
AT403376B (de) * 1995-07-03 1998-01-26 Danubia Petrochem Polymere Metallocene mit silylsubstituierten brücken und deren einsatz für die olefinpolymerisation
ATE186919T1 (de) * 1995-10-27 1999-12-15 Dow Chemical Co Metallische komplexe, die geträgert werden können
US6002033A (en) * 1995-11-22 1999-12-14 Fina Research, S.A. Bridged metallocenes for use in catalyst systems
DE19602543A1 (de) 1996-01-25 1997-07-31 Basf Ag Verfahren zur Herstellung von Polymerisaten von C¶2¶- bis C¶1¶¶0¶-Alkenen in Gegenwart von Metallocenkomplexen mit kationisch funktionalisierten Cyclopentadienylliganden
US6759499B1 (en) * 1996-07-16 2004-07-06 Exxonmobil Chemical Patents Inc. Olefin polymerization process with alkyl-substituted metallocenes
US5965477A (en) * 1997-02-21 1999-10-12 Council Of Scientific & Industrial Research Process for the preparation of supported metallocene catalyst
US6103657A (en) 1997-07-02 2000-08-15 Union Carbide Chemicals & Plastics Technology Corporation Catalyst for the production of olefin polymers
US6268447B1 (en) 1998-12-18 2001-07-31 Univation Technologies, L.L.C. Olefin polymerization catalyst
GB9722447D0 (en) * 1997-10-23 1997-12-24 Borealis As Process
CN1098867C (zh) * 1998-01-14 2003-01-15 中国石油化工集团公司 淤浆法全密度聚乙烯高效催化剂
KR100358225B1 (ko) 1998-04-09 2003-01-24 주식회사 엘지화학 조촉매의 재순환이 가능한 메탈로센 촉매 중합 방법
KR100380018B1 (ko) 1998-04-09 2003-10-04 주식회사 엘지화학 메탈로센담지촉매및이를이용한올레핀중합방법
US6303719B1 (en) 1998-12-18 2001-10-16 Univation Technologies Olefin polymerization catalyst system
DE19903783A1 (de) * 1999-02-01 2000-08-03 Elenac Gmbh Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtsverteilung
DE19903695A1 (de) * 1999-02-01 2000-08-03 Elenac Gmbh Verfahren zur Herstellung von Polyolefinen mit breiter Molekulargewichtsverteilung
KR100354290B1 (ko) * 1999-06-22 2002-09-28 주식회사 엘지화학 담지 메탈로센 촉매 및 이를 이용한 올레핀 중합
US7247595B2 (en) * 1999-06-22 2007-07-24 Lg Chem, Ltd. Supported metallocene catalyst and olefin polymerization using the same
US7041618B2 (en) * 1999-06-22 2006-05-09 Lg Chemical Ltd. Supported metallocene catalyst and olefin polymerization using the same
US6548442B1 (en) 1999-12-03 2003-04-15 Phillips Petroleum Company Organometal compound catalyst
US6846943B2 (en) 2000-05-23 2005-01-25 Chisso Corporation Metallocene compound, olefin polymerization catalyst containing the compound, and method for producing an olefin polymer by use of the catalyst
US6723675B1 (en) * 2000-05-25 2004-04-20 Univation Technologies, Llc Catalyst for the production of olefin polymers
WO2003035926A2 (en) * 2001-10-26 2003-05-01 Epichem Limited Improved precursors for chemical vapour deposition
EP1495038B1 (de) * 2002-04-12 2008-07-23 Dow Global Technologies Inc. Azaborolylkomplexe mit metallen der gruppe 4, katalysatoren und verfahren zur olefinepolymerisation
WO2004046214A2 (en) 2002-10-15 2004-06-03 Exxonmobil Chemical Patents Inc. Multiple catalyst system for olefin polymerization and polymers produced therefrom
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
CN100351275C (zh) 2003-03-21 2007-11-28 陶氏环球技术公司 形态控制的烯烃聚合方法
KR100690345B1 (ko) * 2004-09-03 2007-03-09 주식회사 엘지화학 담지 메탈로센 촉매, 그 제조방법 및 이를 이용한폴리올레핀의 제조방법
CA2591662C (en) 2004-12-17 2014-01-28 Dow Global Technologies Inc. Rheology modified relatively high melt strength polyethlene compositions and methods of making pipes, films, sheets, and blow molded articles
GB2432363B (en) * 2005-11-16 2010-06-23 Epichem Ltd Hafnocene and zirconocene precursors, and use thereof in atomic layer deposition
EP1803747A1 (de) 2005-12-30 2007-07-04 Borealis Technology Oy Oberflächemodifizierte Polymerisationskatalysatoren zur Herstellung von Polyolefinfilmen mit niedrigem Gelgehalt
KR101439556B1 (ko) 2006-05-02 2014-09-11 다우 글로벌 테크놀로지스 엘엘씨 고밀도 폴리에틸렌 조성물, 이것의 제조 방법,이것으로부터 제조된 와이어 및 케이블 자켓, 및 이러한와이어 및 케이블 자켓의 제조 방법
US7456244B2 (en) * 2006-05-23 2008-11-25 Dow Global Technologies High-density polyethylene compositions and method of making the same
US7956207B2 (en) * 2006-09-28 2011-06-07 Praxair Technology, Inc. Heteroleptic organometallic compounds
EP2052026B2 (de) * 2007-05-02 2021-07-14 Dow Global Technologies LLC Hochdichte polyethylenzusammensetzungen, verfahren zu deren herstellung, daraus hergestellte einspritzgeformte artikel und verfahren zur herstellung derartiger artikel
US7981517B2 (en) * 2007-08-28 2011-07-19 Dow Global Technologies Inc. Bituminous compositions and methods of making and using same
US8148481B2 (en) 2008-12-18 2012-04-03 Univation Technologies, Llc Method for seed bed treatment for a polymerization reaction
BRPI1005286A2 (pt) 2009-01-30 2016-07-05 Dow Global Technologies Llc composição de polietileno de alta densidade, método para produzir uma composição de polietileno de alta densidade, dispositivo de fechamento e método para produzir um dispositivo de fechamento
CN102597015A (zh) * 2009-10-28 2012-07-18 埃克森美孚化学专利公司 催化剂化合物和它们的用途
WO2011056432A2 (en) 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
US8557936B2 (en) * 2009-10-28 2013-10-15 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
US8541522B2 (en) * 2009-10-28 2013-09-24 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
WO2011056431A2 (en) * 2009-10-28 2011-05-12 Exxonmobil Chemical Patents Inc. Catalyst compounds and use thereof
ES2823768T3 (es) 2012-12-28 2021-05-10 Univation Tech Llc Métodos para integrar la producción de aluminoxano en la producción de catalizador
ES2723878T3 (es) 2013-01-14 2019-09-03 Univation Tech Llc Métodos para preparar sistemas catalíticos con productividad aumentada
JP6621845B2 (ja) 2015-05-08 2019-12-18 エクソンモービル ケミカル パテンツ インコーポレイテッド 重合方法
WO2018063765A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063767A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018063764A1 (en) 2016-09-27 2018-04-05 Exxonmobil Chemical Patents Inc. Polymerization process
WO2018118155A1 (en) 2016-12-20 2018-06-28 Exxonmobil Chemical Patents Inc. Polymerization process
US11591417B2 (en) 2017-12-13 2023-02-28 Exxonmobil Chemical Patents Inc. Deactivation methods for active components from gas phase polyolefin polymerization processes
WO2019173030A1 (en) 2018-03-08 2019-09-12 Exxonmobil Chemical Patents Inc. Methods of preparing and monitoring a seed bed for polymerization reactor startup
US11459408B2 (en) 2018-05-02 2022-10-04 Exxonmobil Chemical Patents Inc. Methods for scale-up from a pilot plant to a larger production facility
CN112055719B (zh) 2018-05-02 2022-11-25 埃克森美孚化学专利公司 从中试装置放大到较大生产设施的方法
WO2020014138A1 (en) 2018-07-09 2020-01-16 Exxonmobil Chemical Patents Inc. Polyethylene cast films and methods for making the same
CN112469556B (zh) 2018-07-26 2023-05-02 埃克森美孚化学专利公司 多层泡沫膜及其制造方法
US20220025135A1 (en) 2018-11-13 2022-01-27 Exxonmobil Chemical Patents Inc. Polyethylene Films
EP3880738A1 (de) 2018-11-13 2021-09-22 ExxonMobil Chemical Patents Inc. Polyethylenmischungen und -folien
WO2020163079A1 (en) 2019-02-06 2020-08-13 Exxonmobil Chemical Patents Inc. Films and backsheets for hygiene articles
WO2021126458A1 (en) 2019-12-17 2021-06-24 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved sealing performance and mechanical properties
US20230097375A1 (en) 2020-03-12 2023-03-30 Exxonmobil Chemical Patents Inc. Films made of polyethylene blends for improved bending stiffness and high md tear resistance
CN117098785A (zh) 2021-04-30 2023-11-21 埃克森美孚化学专利公司 用于聚合反应器中不同聚合催化剂之间的转变的方法

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2583307B1 (fr) * 1985-06-14 1993-07-02 Atochem Support a base de silice et de chlorure de magnesium, son procede de fabrication, catalyseurs obtenus a partir de ce support.
US5122491A (en) * 1987-04-20 1992-06-16 Mitsui Petrochemical Industries, Ltd. Catalyst for polymerizing an olefin and process for polymerizing an olefin
JP2538595B2 (ja) * 1987-05-13 1996-09-25 三井石油化学工業株式会社 オレフイン重合用固体触媒
GB8716950D0 (en) * 1987-07-17 1987-08-26 Ici Plc Polymers & catalyst components
US5057475A (en) * 1989-09-13 1991-10-15 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing group IVB transition metal complexes with MAO: supported catalyst for olefin polymerization
US5026798A (en) * 1989-09-13 1991-06-25 Exxon Chemical Patents Inc. Process for producing crystalline poly-α-olefins with a monocyclopentadienyl transition metal catalyst system
US5227440A (en) * 1989-09-13 1993-07-13 Exxon Chemical Patents Inc. Mono-Cp heteroatom containing Group IVB transition metal complexes with MAO: supported catalysts for olefin polymerization
US5266544A (en) * 1989-12-29 1993-11-30 Mitsui Petrochemical Industries, Ltd. Olefin polymerization catalyst and process for the polymerization of olefins
JP2826362B2 (ja) * 1990-02-13 1998-11-18 三井化学株式会社 オレフィン重合用固体触媒の製造方法、オレフィン重合用固体触媒およびオレフィンの重合方法
ES2090209T3 (es) * 1990-11-12 1996-10-16 Hoechst Ag Metalocenos con ligandos basados en derivados de indenilo sustituidos en posicion 2, procedimiento para su preparacion y su empleo como catalizadores.
US5349100A (en) * 1991-01-02 1994-09-20 Exxon Chemical Patents Inc. Chiral metallocene compounds and preparation thereof by creation of a chiral center by enantioselective hydride transfer
EP0496193B1 (de) * 1991-01-12 1998-05-13 TARGOR GmbH Metallocen(co)polymere, Verfahren zu ihrer Herstellung und ihre Verwendung als Katalysatoren; Metallocene hierfür.
US5189192A (en) * 1991-01-16 1993-02-23 The Dow Chemical Company Process for preparing addition polymerization catalysts via metal center oxidation
WO1993012151A1 (en) * 1991-12-13 1993-06-24 Exxon Chemical Patents Inc. Ethylene/longer alpha-olefin copolymers

Also Published As

Publication number Publication date
EP0608054B1 (de) 1999-07-07
EP0608054A2 (de) 1994-07-27
NO308133B1 (no) 2000-07-31
EP0608054A3 (de) 1994-11-30
KR940018401A (ko) 1994-08-16
JPH06239916A (ja) 1994-08-30
CA2113601A1 (en) 1994-07-20
GR3030725T3 (en) 1999-11-30
JP3481285B2 (ja) 2003-12-22
ATE181930T1 (de) 1999-07-15
DE69419326T2 (de) 1999-11-04
US5767209A (en) 1998-06-16
ES2135539T3 (es) 1999-11-01
KR100299701B1 (ko) 2001-10-22
US5814574A (en) 1998-09-29
GB9300934D0 (en) 1993-03-10
CN1092081A (zh) 1994-09-14
FI940266A0 (fi) 1994-01-19
NO940172L (no) 1994-07-20
CN1087303C (zh) 2002-07-10
NO940172D0 (no) 1994-01-18
FI940266A (fi) 1994-07-20

Similar Documents

Publication Publication Date Title
DE69419326D1 (de) Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen
DE69328996T2 (de) Katalysatorzusammensetzung und Verfahren zur Herstellung von Polyolefinen
DE69701909T2 (de) Olefinpolymerisationskatalysator auf Basis von organometallischen Komplexen und Verfahren zur Herstellung von Polyolefinen mit diesem Katalysator
DE3882253T2 (de) Verfahren zur Herstellung von Olefinpolymeren und verwendeter Katalysator.
DE59405876D1 (de) Geträgertes Katalysatorsystem, seine Herstellung und seine Verwendung zur Polymerisation von Olefinen
DE69307015D1 (de) Katalysatoren und Verfahren zur Herstellung von Olefinpolymeren
ATE141275T1 (de) Katalysatoren zur polymerisation von olefinen
DE69328955T2 (de) Katalysatorzusammensetzungen und Verfahren zur Herstellung von Polyolefinen
DE69418002D1 (de) Katalysatorsystem zur Polymerisation von Alpha-Olefinen und Verfahren zur Herstellung von Katalysatoren zur Polymerisation von Alpha-Olefinen
DE68922017D1 (de) Verfahren zur Herstellung von Polymeren von Kohlenmonoxyd und ungesättigten Verbindungen.
DE68910589D1 (de) Ethylen-alpha-Olefincopolymere und katalytisches Verfahren zur Herstellung derselben.
DE69207975T2 (de) Komponenten und Katalysatoren für die Polymerisation von Äthylen
DE69028004D1 (de) Katalysator für die Olefinpolymerisation und Verfahren zur Herstellung von Ethylencopolymeren
DE69409133D1 (de) Komponenten und Katalysatoren für die Polymerisation von Äthylen
DE69621373D1 (de) Verfahren zur Herstellung von Alpha-Olefin-Polymerisationskatalysatoren und Verfahren zur Herstellung eines Alpha-Olefin-Polymers
DE69710435D1 (de) Katalysator zur Polymerisation von Olefinen und Verfahren zur Herstellung von Olefinpolymeren
DE69528689T2 (de) Olefinpolymerisationskatalysator und Verfahren zur Herstellung von Polyolefinen
ATE99336T1 (de) Katalysatorbestandteil fuer olefinpolymerisation, verfahren zur herstellung davon, olefinpolymerisationskatalysator und verfahren zur polymerisation von olefinen.
ATE98267T1 (de) Olefinpolymerisationskatalysatoren und verfahren zur herstellung eines polyolefins.

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee