BR0112482B1 - processo para preparar um elastÈmero de termocura de poliuretano, e, elastÈmero de termocura. - Google Patents

processo para preparar um elastÈmero de termocura de poliuretano, e, elastÈmero de termocura.

Info

Publication number
BR0112482B1
BR0112482B1 BRPI0112482-0A BR0112482A BR0112482B1 BR 0112482 B1 BR0112482 B1 BR 0112482B1 BR 0112482 A BR0112482 A BR 0112482A BR 0112482 B1 BR0112482 B1 BR 0112482B1
Authority
BR
Brazil
Prior art keywords
thermosetting elastomer
preparing
polyurethane
elastomer
thermosetting
Prior art date
Application number
BRPI0112482-0A
Other languages
English (en)
Portuguese (pt)
Other versions
BR0112482A (pt
Inventor
Gerhard Jozef Bleys
Eric Huygens
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed filed Critical
Publication of BR0112482A publication Critical patent/BR0112482A/pt
Publication of BR0112482B1 publication Critical patent/BR0112482B1/pt

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4833Polyethers containing oxyethylene units
    • C08G18/4837Polyethers containing oxyethylene units and other oxyalkylene units
    • C08G18/4841Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/74Polyisocyanates or polyisothiocyanates cyclic
    • C08G18/76Polyisocyanates or polyisothiocyanates cyclic aromatic
    • C08G18/7657Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72Polyisocyanates or polyisothiocyanates
    • C08G18/77Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78Nitrogen
    • C08G18/79Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/797Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2110/00Foam properties
    • C08G2110/0041Foam properties having specified density
    • C08G2110/0066≥ 150kg/m3
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2120/00Compositions for reaction injection moulding processes
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S521/00Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S521/914Polyurethane cellular product formed from a polyol which has been derived from at least two 1,2 epoxides as reactants

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyurethanes Or Polyureas (AREA)
BRPI0112482-0A 2000-07-14 2001-06-21 processo para preparar um elastÈmero de termocura de poliuretano, e, elastÈmero de termocura. BR0112482B1 (pt)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP00115290A EP1172387A1 (en) 2000-07-14 2000-07-14 Process for preparing an elastomer
PCT/EP2001/007137 WO2002006370A1 (en) 2000-07-14 2001-06-21 Process for preparing an elastomer

Publications (2)

Publication Number Publication Date
BR0112482A BR0112482A (pt) 2003-07-01
BR0112482B1 true BR0112482B1 (pt) 2010-10-19

Family

ID=8169263

Family Applications (1)

Application Number Title Priority Date Filing Date
BRPI0112482-0A BR0112482B1 (pt) 2000-07-14 2001-06-21 processo para preparar um elastÈmero de termocura de poliuretano, e, elastÈmero de termocura.

Country Status (20)

Country Link
US (1) US6884824B2 (https=)
EP (2) EP1172387A1 (https=)
JP (1) JP5031969B2 (https=)
KR (1) KR100739966B1 (https=)
CN (1) CN1289565C (https=)
AR (1) AR029831A1 (https=)
AT (1) ATE308575T1 (https=)
AU (2) AU2001266090B2 (https=)
BR (1) BR0112482B1 (https=)
CA (1) CA2413419C (https=)
CZ (1) CZ297690B6 (https=)
DE (1) DE60114625T2 (https=)
ES (1) ES2247135T3 (https=)
MX (1) MXPA02012931A (https=)
PL (1) PL360390A1 (https=)
RU (1) RU2263123C2 (https=)
SI (1) SI1303551T1 (https=)
TW (1) TW538063B (https=)
WO (1) WO2002006370A1 (https=)
ZA (1) ZA200210394B (https=)

Families Citing this family (31)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ATE198756T1 (de) * 1995-12-08 2001-02-15 Huntsman Ici Chem Llc Polyurethanelastomere
DE60114582T2 (de) * 2000-02-14 2006-07-20 Huntsman International Llc, Salt Lake City Verfahren zur herstellung eines flexiblen polyurethanschaums
US6906111B2 (en) * 2002-05-10 2005-06-14 Kao Corporation Foamed article
PL1631606T3 (pl) * 2003-06-12 2011-11-30 Huntsman Int Llc Sposób wytwarzania policyjanurowego materiału poliuretanowego
JP4641711B2 (ja) * 2003-08-13 2011-03-02 花王株式会社 衝撃緩衝性発泡体
DE102004009939A1 (de) * 2004-02-26 2005-09-15 Basf Ag Quellbeständige Polyurethanintegralschaumstoffe
KR100586037B1 (ko) 2004-07-19 2006-06-08 오주영 친환경적 우레탄 시트 및 그 제조방법
KR101288266B1 (ko) 2005-10-13 2013-07-29 헌트스만 인터내셔날, 엘엘씨 폴리이소시아누레이트 폴리우레탄 물질을 제조하는 방법
EP1940899B1 (en) 2005-10-13 2009-08-05 Huntsman International Llc Process for preparing polyisocyanurate polyurethane material
RU2411255C2 (ru) * 2005-12-16 2011-02-10 ПиПиДжи ИНДАСТРИЗ ОГАЙО, ИНК. Полиуретаны, изготовленные из них изделия и покрытия и способы их производства
KR101360637B1 (ko) * 2006-02-21 2014-02-07 헌트스만 인터내셔날, 엘엘씨 폴리이소시아누레이트 복합재의 제조 방법
EP2001922B1 (en) * 2006-03-24 2010-11-10 Huntsman International Llc Process for making a polyurethane foam
JP5000713B2 (ja) 2006-06-14 2012-08-15 ハンツマン・インターナショナル・エルエルシー 複合パネル
CN101096409B (zh) * 2006-06-26 2010-05-12 山东东大一诺威聚氨酯有限公司 一种用于鼠标垫的聚氨酯弹性体的制备方法
US20090110894A1 (en) * 2007-10-26 2009-04-30 Nybakken George H Polyurethane elastomer articles from low free diphenylmethane diisocyanate prepolymers
US8519062B2 (en) * 2008-02-14 2013-08-27 Huntsman International Llc Elastomeric materials having a high hardblock content and process for preparing them
US8399062B2 (en) * 2008-09-12 2013-03-19 Guardian Building Products, Inc. Elastomeric foam product
US8062706B2 (en) * 2009-03-31 2011-11-22 Ppg Industries Ohio, Inc. Recovery of monobutyltin trichloride
KR20120029392A (ko) * 2009-05-19 2012-03-26 인비스타 테크놀러지스 에스.에이.알.엘. 폴리올 조성물, 수지 블렌드 조성물, 스프레이 조성물, 및 각각의 사용 방법, 및 각각의 제조 방법
US20120202945A1 (en) * 2009-07-07 2012-08-09 Baulé S.A.S. Polyurethanes and use thereof
CN101993520B (zh) * 2009-08-24 2014-02-19 拜耳材料科技(中国)有限公司 异氰酸酯封端预聚物、及其制备方法和用途
JP2014522446A (ja) 2011-06-13 2014-09-04 インヴィスタ テクノロジーズ エスアエルエル ポリウレタンおよびポリイソシアヌレートポリマーのための前駆体としてのシクロヘキサン酸化副生成物ストリーム由来の脂肪族ポリエステルポリオール
US9593200B2 (en) 2012-08-06 2017-03-14 Kuraray Co., Ltd. Thermoplastic polyurethane and a composition thereof
DE102012218846A1 (de) * 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
DE102012218848A1 (de) * 2012-10-16 2014-04-17 Bayer Materialscience Ag Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen
US20150011711A1 (en) 2013-07-06 2015-01-08 Nike, Inc Method of forming a cured elastomer and articles of the cured elastomer
JP2018503775A (ja) 2014-11-10 2018-02-08 ポリテック エー/エス ポリウレタン材料、かかる材料を作るための方法、及び風力タービン翼のための保護カバー
EP3436497B1 (en) * 2016-03-28 2022-08-31 Dow Global Technologies LLC Two-component solventless adhesive compositions and methods of making same
US11292867B2 (en) * 2016-09-23 2022-04-05 Huntsman International Llc Polyurethane foams having improved mechanical performance
CN107573475B (zh) * 2017-09-15 2020-11-24 山东一诺威聚氨酯股份有限公司 用于制作实心足球的聚氨酯组合物及其制备方法和应用
CN116284654B (zh) * 2023-01-02 2024-10-11 黎明化工研究设计院有限责任公司 一种低气味、快速脱模自结皮聚氨酯泡沫组合物及其制备方法

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4202957A (en) * 1974-09-09 1980-05-13 The Upjohn Company Thermoplastic polyurethane elastomers from polyoxypropylene polyoxyethylene block copolymers
SU778206A1 (ru) * 1978-02-20 1983-06-23 Всесоюзный научно-исследовательский институт синтетических смол Способ получени пенополиуретана
JPS58224728A (ja) * 1982-06-25 1983-12-27 Mitsubishi Plastics Ind Ltd 発泡樹脂成形品の製造方法
JPS6142526A (ja) * 1984-08-03 1986-03-01 Sanyo Chem Ind Ltd ポリウレタン成形品の製法
US4686240A (en) 1985-10-25 1987-08-11 Union Carbide Corporation Process for producing polyurethane foams using foam modifiers
EP0275907A3 (en) * 1987-01-23 1989-05-24 Mobay Corporation Rim polyurethane or polyurea compositions containing internal mold release agents
US4764540A (en) * 1987-01-23 1988-08-16 Mobay Corporation Rim polyurethane or polyurea compositions containing internal mold release agents
GB8712988D0 (en) 1987-06-03 1987-07-08 Ici Plc Polyurethane foams
JP2954631B2 (ja) * 1990-02-05 1999-09-27 旭硝子株式会社 コーティング剤組成物
DE69220338T2 (de) * 1991-12-17 1997-11-06 Ici Plc Polyurethanschäume
GB9126740D0 (en) * 1991-12-17 1992-02-12 Ici Plc Polyol compositions
US5773483A (en) * 1993-04-13 1998-06-30 Imperial Chemical Industries Plc Process for preparing a flexible foam
CA2158653A1 (en) 1993-04-13 1994-10-27 Huntsman International Llc Process for preparing a flexible foam
US5504180A (en) 1993-10-04 1996-04-02 Ecp Enichem Polimeri Netherlands, B.V. Process for the preparation of polyurethane articles from uretonimine based compositions
US5418260A (en) * 1993-10-04 1995-05-23 Ecp Enichem Polimeri Netherlands, B.V. Process for the production of polyurethane articles from uretonimine based compositions and ethylene oxide rich polyether polyols
SI0656380T1 (en) 1993-12-03 1999-08-31 Enichem S.P.A. Process for the production of polyurea based articles
US5591779A (en) * 1994-11-22 1997-01-07 Imperial Chemical Industries Plc Process for making flexible foams
US5670601A (en) * 1995-06-15 1997-09-23 Arco Chemical Technology, L.P. Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation
US5677413A (en) * 1995-06-15 1997-10-14 Arco Chemical Technology, L.P. Polyurethane elastomers exhibiting improved demold green strength and water absorption and haze-free polyols suitable for their preparation
US5576409B1 (en) * 1995-08-25 1998-09-22 Ici Plc Internal mold release compositions
CZ351996A3 (en) * 1995-12-07 1997-06-11 Shell Int Research Polyol formulation for preparing flexible polyurethane foam similar to latex
ATE198756T1 (de) 1995-12-08 2001-02-15 Huntsman Ici Chem Llc Polyurethanelastomere
CN1282680C (zh) * 1996-06-27 2006-11-01 亨茨曼Ici化学品有限公司 微孔弹性聚氨基甲酸酯泡沫体
US5919395A (en) * 1997-10-30 1999-07-06 Shell Oil Company Polyol combination
JP4679728B2 (ja) 1999-03-17 2011-04-27 ハンツマン・インターナショナル・エルエルシー 成型ポリウレタン材料の調製方法
DE60114582T2 (de) * 2000-02-14 2006-07-20 Huntsman International Llc, Salt Lake City Verfahren zur herstellung eines flexiblen polyurethanschaums

Also Published As

Publication number Publication date
SI1303551T1 (sl) 2006-02-28
CN1441817A (zh) 2003-09-10
JP5031969B2 (ja) 2012-09-26
CN1289565C (zh) 2006-12-13
ATE308575T1 (de) 2005-11-15
EP1303551A1 (en) 2003-04-23
PL360390A1 (en) 2004-09-06
AR029831A1 (es) 2003-07-16
DE60114625D1 (de) 2005-12-08
ES2247135T3 (es) 2006-03-01
DE60114625T2 (de) 2006-07-27
BR0112482A (pt) 2003-07-01
KR20030017621A (ko) 2003-03-03
KR100739966B1 (ko) 2007-07-16
CZ200394A3 (cs) 2003-04-16
AU6609001A (en) 2002-01-30
EP1172387A1 (en) 2002-01-16
TW538063B (en) 2003-06-21
CZ297690B6 (cs) 2007-03-07
CA2413419C (en) 2008-09-02
WO2002006370A1 (en) 2002-01-24
US20030162931A1 (en) 2003-08-28
ZA200210394B (en) 2003-11-03
AU2001266090B2 (en) 2005-06-16
RU2263123C2 (ru) 2005-10-27
CA2413419A1 (en) 2002-01-24
EP1303551B1 (en) 2005-11-02
US6884824B2 (en) 2005-04-26
JP2004504426A (ja) 2004-02-12
MXPA02012931A (es) 2003-10-24

Similar Documents

Publication Publication Date Title
BR0112482B1 (pt) processo para preparar um elastÈmero de termocura de poliuretano, e, elastÈmero de termocura.
BR0107571B1 (pt) processo para preparar uma espuma de poliuretano flexìvel, e, espuma de poliuretano flexìvel moldada.
BR0012774B1 (pt) processo para preparação de poliamida.
BR9813857B1 (pt) Processo para a preparação de um desinfetante aquoso, e, desinfetante aquoso.
BR0008301B1 (pt) processo para a fabricaÇço de compostos, e, compostos.
BR0112823B1 (pt) processo para a preparação de uma espuma de poliuretano flexìvel, e, espuma de poliuretano flexìvel.
BR9909730B1 (pt) dihidropirimidinas, bem como processo para a preparação e aplicação das mesmas.
BR0017357B1 (pt) compressor linear, mola em um compressor linear e mÉtodo para fabricaÇço de compressor linear.
BR0002614B1 (pt) processo para recuperaÇço de diàxido de carbono.
BR0112898B1 (pt) processo para a preparaÇço de um material de poliuretana.
BR0110171B1 (pt) filtro de cigarro que compreende fibras de microcavidades, cigarro contendo tal filtro e processo para preparar o filtro de cigarro.
BR0116080B1 (pt) embalagem, especialmente embalagem de cigarros, bem como processo e dispositivo para a fabricação da mesma.
BR0105427B1 (pt) artigo de matriz configurada e método para a fabricação do mesmo.
BR9801181B1 (pt) gênero alimentìcio fortificado com cálcio, bem como processo para preparação do mesmo.
BR0004673B1 (pt) aparelho e processo para fabricação de folha composta elástica.
BR0211391B1 (pt) processo para preparaÇço de 4-aminodifenilaminas.
BR0315969B1 (pt) processo para preparaÇço de 1,3-propanodiol.
BR0214365B1 (pt) composição de revestimento aquosa; dispersão aquosa; processo para preparar a dispersão aquosa; e prepolìmero de uretano.
BR9917475B1 (pt) processo para a manufatura de compostos, e, modificação do processo.
BR9914484B1 (pt) Formulações de microcápsulas, bem como processo para a preparação e aplicação das mesmas
BR0109988B1 (pt) elemento eletroquìmico, e, processo para preparar o mesmo.
BR0013913B1 (pt) compósito lubrificante e processo para a sua preparação.
BR0116045B1 (pt) processo para a fabricação de uma bucha de rebordo.
BR0311997B1 (pt) processo para a preparação de um material de poliuretano moldado, elastomérico, e, material de poliuretano moldado, elastomérico, livre de catalisador.
BR0104432B1 (pt) processo para operar uma coluna de retificação, coluna, e, bloco.

Legal Events

Date Code Title Description
B09A Decision: intention to grant [chapter 9.1 patent gazette]
B16A Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]

Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 21/06/2001, OBSERVADAS AS CONDICOES LEGAIS.

B21F Lapse acc. art. 78, item iv - on non-payment of the annual fees in time

Free format text: REFERENTE A 15A ANUIDADE.

B24J Lapse because of non-payment of annual fees (definitively: art 78 iv lpi, resolution 113/2013 art. 12)

Free format text: EM VIRTUDE DA EXTINCAO PUBLICADA NA RPI 2385 DE 20-09-2016 E CONSIDERANDO AUSENCIA DE MANIFESTACAO DENTRO DOS PRAZOS LEGAIS, INFORMO QUE CABE SER MANTIDA A EXTINCAO DA PATENTE E SEUS CERTIFICADOS, CONFORME O DISPOSTO NO ARTIGO 12, DA RESOLUCAO 113/2013.