BR0112482A - Processo para preparar um elastÈmero de termocura de poliuretano, e, elastÈmero de termocura - Google Patents
Processo para preparar um elastÈmero de termocura de poliuretano, e, elastÈmero de termocuraInfo
- Publication number
- BR0112482A BR0112482A BR0112482-0A BR0112482A BR0112482A BR 0112482 A BR0112482 A BR 0112482A BR 0112482 A BR0112482 A BR 0112482A BR 0112482 A BR0112482 A BR 0112482A
- Authority
- BR
- Brazil
- Prior art keywords
- weight
- isocyanate
- polyol
- elastomer
- preparing
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4833—Polyethers containing oxyethylene units
- C08G18/4837—Polyethers containing oxyethylene units and other oxyalkylene units
- C08G18/4841—Polyethers containing oxyethylene units and other oxyalkylene units containing oxyethylene end groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
- C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
- C08G18/6666—Compounds of group C08G18/48 or C08G18/52
- C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
- C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
- C08G18/78—Nitrogen
- C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
- C08G18/797—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing carbodiimide and/or uretone-imine groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/0066—≥ 150kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2120/00—Compositions for reaction injection moulding processes
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S521/914—Polyurethane cellular product formed from a polyol which has been derived from at least two 1,2 epoxides as reactants
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
"PROCESSO PARA PREPARAR UM ELASTÈMERO DE TERMOCURA DE POLIURETANO, E, ELASTÈMERO DE TERMOCURA". Um processo para preparar um elastómero de poliuretano tendo uma densidade global aparente de mais que 150 kg/m^ 3^ compreendendo reagir um poliisocianato e uma composição reativa com isocianato, opcionalmente na presença de água, em que a reação e conduzida em um índice de isocianato de 85 a 120, o poliisocianato consiste de a) 80-100% em peso de diisocianato de difenilmetano compreendendo pelo menos 40% em peso de diisocianato de 4,4'-difenilmetano e/ou um derivado do dito diisocianato de difenilmetano cujo derivado é líquido a 25<198> C e tem um valor NCO de pelo menos 20% em peso, e 20-0% em peso de outro poliisocianato, e em que a composição reativa com isocianato consiste de a) 80-100% em peso de um poliol de poliéster tendo uma funcionalidade média nominal de 2-8, um peso equivalente médio de 750-5000, um peso molecular médio de 2000-12000, um teor de oxietileno de 60-90% em peso e um teor de hidroxila primária de 70-100% calculados sobre o número total de grupos hidroxila primária e secundária no poliol, b) um extensor de cadeia reativo com isocianato em uma quantidade de modo que a razão de bloco duro seja menor que 0,50 e c) 20-0% em peso de um ou mais outros compostos reativos de isocianato excluindo água, a quantidade de poliol a) e de composto reativo com isocianato c) sendo calculada sobre a quantidade total deste poliol a) e composto c).
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP00115290A EP1172387A1 (en) | 2000-07-14 | 2000-07-14 | Process for preparing an elastomer |
PCT/EP2001/007137 WO2002006370A1 (en) | 2000-07-14 | 2001-06-21 | Process for preparing an elastomer |
Publications (2)
Publication Number | Publication Date |
---|---|
BR0112482A true BR0112482A (pt) | 2003-07-01 |
BR0112482B1 BR0112482B1 (pt) | 2010-10-19 |
Family
ID=8169263
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
BRPI0112482-0A BR0112482B1 (pt) | 2000-07-14 | 2001-06-21 | processo para preparar um elastÈmero de termocura de poliuretano, e, elastÈmero de termocura. |
Country Status (20)
Country | Link |
---|---|
US (1) | US6884824B2 (pt) |
EP (2) | EP1172387A1 (pt) |
JP (1) | JP5031969B2 (pt) |
KR (1) | KR100739966B1 (pt) |
CN (1) | CN1289565C (pt) |
AR (1) | AR029831A1 (pt) |
AT (1) | ATE308575T1 (pt) |
AU (2) | AU2001266090B2 (pt) |
BR (1) | BR0112482B1 (pt) |
CA (1) | CA2413419C (pt) |
CZ (1) | CZ297690B6 (pt) |
DE (1) | DE60114625T2 (pt) |
ES (1) | ES2247135T3 (pt) |
MX (1) | MXPA02012931A (pt) |
PL (1) | PL360390A1 (pt) |
RU (1) | RU2263123C2 (pt) |
SI (1) | SI1303551T1 (pt) |
TW (1) | TW538063B (pt) |
WO (1) | WO2002006370A1 (pt) |
ZA (1) | ZA200210394B (pt) |
Families Citing this family (30)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CA2239482C (en) * | 1995-12-08 | 2008-03-18 | Imperial Chemical Industries Plc | Polyurethane elastomers |
DE60114582T2 (de) * | 2000-02-14 | 2006-07-20 | Huntsman International Llc, Salt Lake City | Verfahren zur herstellung eines flexiblen polyurethanschaums |
US6906111B2 (en) * | 2002-05-10 | 2005-06-14 | Kao Corporation | Foamed article |
JP4818104B2 (ja) | 2003-06-12 | 2011-11-16 | ハンツマン・インターナショナル・エルエルシー | ポリイソシアヌレートポリウレタン材料の製造プロセス |
JP4641711B2 (ja) * | 2003-08-13 | 2011-03-02 | 花王株式会社 | 衝撃緩衝性発泡体 |
DE102004009939A1 (de) * | 2004-02-26 | 2005-09-15 | Basf Ag | Quellbeständige Polyurethanintegralschaumstoffe |
KR100586037B1 (ko) | 2004-07-19 | 2006-06-08 | 오주영 | 친환경적 우레탄 시트 및 그 제조방법 |
WO2007042411A1 (en) | 2005-10-13 | 2007-04-19 | Huntsman International Llc | Process for preparing polyisocyanurate polyurethane material |
CA2620757C (en) * | 2005-10-13 | 2013-11-12 | Huntsman International Llc | Process for preparing a polyisocyanurate polyurethane material |
RU2434027C2 (ru) * | 2006-02-21 | 2011-11-20 | Хантсмэн Интернэшнл Ллс | Способ производства полиизоциануратного композиционного материала |
CN101410430B (zh) * | 2006-03-24 | 2011-12-21 | 亨茨曼国际有限公司 | 聚氨酯泡沫体制造方法 |
US9987776B2 (en) | 2006-06-14 | 2018-06-05 | Huntsman International Llc | Composite panel |
CN101096409B (zh) * | 2006-06-26 | 2010-05-12 | 山东东大一诺威聚氨酯有限公司 | 一种用于鼠标垫的聚氨酯弹性体的制备方法 |
US20090110894A1 (en) * | 2007-10-26 | 2009-04-30 | Nybakken George H | Polyurethane elastomer articles from low free diphenylmethane diisocyanate prepolymers |
WO2009101027A1 (en) * | 2008-02-14 | 2009-08-20 | Huntsman International Llc | Elastomeric materials having a high hardblock content and process for preparing them |
US8399062B2 (en) * | 2008-09-12 | 2013-03-19 | Guardian Building Products, Inc. | Elastomeric foam product |
US8062706B2 (en) * | 2009-03-31 | 2011-11-22 | Ppg Industries Ohio, Inc. | Recovery of monobutyltin trichloride |
CN102428120A (zh) * | 2009-05-19 | 2012-04-25 | 因温斯特技术公司 | 多元醇组合物,树脂共混物组合物,喷发组合物,及其各自的使用方法,及其各自的制备方法 |
US20120202945A1 (en) * | 2009-07-07 | 2012-08-09 | Baulé S.A.S. | Polyurethanes and use thereof |
CN101993520B (zh) * | 2009-08-24 | 2014-02-19 | 拜耳材料科技(中国)有限公司 | 异氰酸酯封端预聚物、及其制备方法和用途 |
PL2718340T3 (pl) | 2011-06-13 | 2017-12-29 | Invista Technologies S.À.R.L. | Alifatyczne poliole poliestrowe ze strumieni produktu ubocznego utleniania cykloheksanu jako prekursory dla polimerów poliuretanowych i poliizocyjanuratowych |
KR20150041067A (ko) * | 2012-08-06 | 2015-04-15 | 가부시키가이샤 구라레 | 열가소성 폴리우레탄 및 이의 조성물 |
DE102012218848A1 (de) * | 2012-10-16 | 2014-04-17 | Bayer Materialscience Ag | Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen |
DE102012218846A1 (de) * | 2012-10-16 | 2014-04-17 | Bayer Materialscience Ag | Herstellung und Verwendung neuer thermoplastischer Polyurethan-Elastomere auf Basis von Polyethercarbonatpolyolen |
US20150011711A1 (en) * | 2013-07-06 | 2015-01-08 | Nike, Inc | Method of forming a cured elastomer and articles of the cured elastomer |
EP3533816B1 (en) | 2014-11-10 | 2024-07-17 | Polytech A/S | Preformed protective cover and wind turbine blade |
JP6908621B2 (ja) * | 2016-03-28 | 2021-07-28 | ダウ グローバル テクノロジーズ エルエルシー | 2成分無溶剤接着剤組成物及びその作製方法 |
CA3035985C (en) * | 2016-09-23 | 2024-01-16 | Huntsman International Llc | Polyurethane foams having sufficient hardness and good flexibility |
CN107573475B (zh) * | 2017-09-15 | 2020-11-24 | 山东一诺威聚氨酯股份有限公司 | 用于制作实心足球的聚氨酯组合物及其制备方法和应用 |
CN116284654A (zh) * | 2023-01-02 | 2023-06-23 | 黎明化工研究设计院有限责任公司 | 一种低气味、快速脱模自结皮聚氨酯泡沫组合物及其制备方法 |
Family Cites Families (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4202957A (en) * | 1974-09-09 | 1980-05-13 | The Upjohn Company | Thermoplastic polyurethane elastomers from polyoxypropylene polyoxyethylene block copolymers |
JPS58224728A (ja) * | 1982-06-25 | 1983-12-27 | Mitsubishi Plastics Ind Ltd | 発泡樹脂成形品の製造方法 |
JPS6142526A (ja) * | 1984-08-03 | 1986-03-01 | Sanyo Chem Ind Ltd | ポリウレタン成形品の製法 |
US4686240A (en) | 1985-10-25 | 1987-08-11 | Union Carbide Corporation | Process for producing polyurethane foams using foam modifiers |
US4764540A (en) * | 1987-01-23 | 1988-08-16 | Mobay Corporation | Rim polyurethane or polyurea compositions containing internal mold release agents |
EP0275907A3 (en) * | 1987-01-23 | 1989-05-24 | Mobay Corporation | Rim polyurethane or polyurea compositions containing internal mold release agents |
GB8712988D0 (en) | 1987-06-03 | 1987-07-08 | Ici Plc | Polyurethane foams |
JP2954631B2 (ja) * | 1990-02-05 | 1999-09-27 | 旭硝子株式会社 | コーティング剤組成物 |
GB9126740D0 (en) * | 1991-12-17 | 1992-02-12 | Ici Plc | Polyol compositions |
DE69220338T2 (de) * | 1991-12-17 | 1997-11-06 | Ici Plc | Polyurethanschäume |
DE69406656T2 (de) | 1993-04-13 | 1998-03-26 | Ici Plc | Verfahren zur herstellung eines weichschaumstoffs |
US5773483A (en) * | 1993-04-13 | 1998-06-30 | Imperial Chemical Industries Plc | Process for preparing a flexible foam |
US5504180A (en) | 1993-10-04 | 1996-04-02 | Ecp Enichem Polimeri Netherlands, B.V. | Process for the preparation of polyurethane articles from uretonimine based compositions |
US5418260A (en) | 1993-10-04 | 1995-05-23 | Ecp Enichem Polimeri Netherlands, B.V. | Process for the production of polyurethane articles from uretonimine based compositions and ethylene oxide rich polyether polyols |
DK0656380T3 (da) | 1993-12-03 | 1999-10-25 | Enichem Spa | Fremgangsmåde til fremstilling af polyurinstofbaserede artikler |
US5591779A (en) * | 1994-11-22 | 1997-01-07 | Imperial Chemical Industries Plc | Process for making flexible foams |
US5677413A (en) | 1995-06-15 | 1997-10-14 | Arco Chemical Technology, L.P. | Polyurethane elastomers exhibiting improved demold green strength and water absorption and haze-free polyols suitable for their preparation |
US5670601A (en) | 1995-06-15 | 1997-09-23 | Arco Chemical Technology, L.P. | Polyurethane elastomers having improved green strength and demold time and polyoxyalkylene polyols suitable for their preparation |
US5576409B1 (en) * | 1995-08-25 | 1998-09-22 | Ici Plc | Internal mold release compositions |
CZ351996A3 (en) * | 1995-12-07 | 1997-06-11 | Shell Int Research | Polyol formulation for preparing flexible polyurethane foam similar to latex |
CA2239482C (en) * | 1995-12-08 | 2008-03-18 | Imperial Chemical Industries Plc | Polyurethane elastomers |
CA2258677C (en) | 1996-06-27 | 2008-05-13 | Imperial Chemical Industries Plc | Microcellular elastomeric polyurethane foams |
US5919395A (en) * | 1997-10-30 | 1999-07-06 | Shell Oil Company | Polyol combination |
CZ298940B6 (cs) | 1999-03-17 | 2008-03-19 | Huntsman International Llc | Zpusob pripravy tvarovaných polyuretanových materiálu |
DE60114582T2 (de) * | 2000-02-14 | 2006-07-20 | Huntsman International Llc, Salt Lake City | Verfahren zur herstellung eines flexiblen polyurethanschaums |
-
2000
- 2000-07-14 EP EP00115290A patent/EP1172387A1/en not_active Withdrawn
-
2001
- 2001-06-21 BR BRPI0112482-0A patent/BR0112482B1/pt not_active IP Right Cessation
- 2001-06-21 KR KR1020037000483A patent/KR100739966B1/ko not_active IP Right Cessation
- 2001-06-21 CN CNB018127096A patent/CN1289565C/zh not_active Expired - Fee Related
- 2001-06-21 CA CA002413419A patent/CA2413419C/en not_active Expired - Fee Related
- 2001-06-21 SI SI200130455T patent/SI1303551T1/sl unknown
- 2001-06-21 AU AU2001266090A patent/AU2001266090B2/en not_active Ceased
- 2001-06-21 WO PCT/EP2001/007137 patent/WO2002006370A1/en active IP Right Grant
- 2001-06-21 RU RU2003104360/04A patent/RU2263123C2/ru not_active IP Right Cessation
- 2001-06-21 AU AU6609001A patent/AU6609001A/xx active Pending
- 2001-06-21 JP JP2002512270A patent/JP5031969B2/ja not_active Expired - Fee Related
- 2001-06-21 MX MXPA02012931A patent/MXPA02012931A/es active IP Right Grant
- 2001-06-21 DE DE60114625T patent/DE60114625T2/de not_active Expired - Lifetime
- 2001-06-21 ES ES01943539T patent/ES2247135T3/es not_active Expired - Lifetime
- 2001-06-21 CZ CZ20030094A patent/CZ297690B6/cs not_active IP Right Cessation
- 2001-06-21 AT AT01943539T patent/ATE308575T1/de not_active IP Right Cessation
- 2001-06-21 PL PL36039001A patent/PL360390A1/xx not_active IP Right Cessation
- 2001-06-21 EP EP01943539A patent/EP1303551B1/en not_active Expired - Lifetime
- 2001-06-27 TW TW090115604A patent/TW538063B/zh not_active IP Right Cessation
- 2001-07-13 AR ARP010103359A patent/AR029831A1/es active IP Right Grant
-
2002
- 2002-12-20 ZA ZA200210394A patent/ZA200210394B/en unknown
-
2003
- 2003-01-03 US US10/336,519 patent/US6884824B2/en not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
US6884824B2 (en) | 2005-04-26 |
US20030162931A1 (en) | 2003-08-28 |
BR0112482B1 (pt) | 2010-10-19 |
AU6609001A (en) | 2002-01-30 |
PL360390A1 (en) | 2004-09-06 |
KR20030017621A (ko) | 2003-03-03 |
CN1441817A (zh) | 2003-09-10 |
CZ297690B6 (cs) | 2007-03-07 |
ZA200210394B (en) | 2003-11-03 |
AU2001266090B2 (en) | 2005-06-16 |
AR029831A1 (es) | 2003-07-16 |
WO2002006370A1 (en) | 2002-01-24 |
CA2413419C (en) | 2008-09-02 |
KR100739966B1 (ko) | 2007-07-16 |
JP5031969B2 (ja) | 2012-09-26 |
JP2004504426A (ja) | 2004-02-12 |
SI1303551T1 (sl) | 2006-02-28 |
CA2413419A1 (en) | 2002-01-24 |
EP1172387A1 (en) | 2002-01-16 |
TW538063B (en) | 2003-06-21 |
RU2263123C2 (ru) | 2005-10-27 |
CZ200394A3 (cs) | 2003-04-16 |
ATE308575T1 (de) | 2005-11-15 |
EP1303551B1 (en) | 2005-11-02 |
CN1289565C (zh) | 2006-12-13 |
DE60114625D1 (de) | 2005-12-08 |
DE60114625T2 (de) | 2006-07-27 |
MXPA02012931A (es) | 2003-10-24 |
ES2247135T3 (es) | 2006-03-01 |
EP1303551A1 (en) | 2003-04-23 |
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