HUP0001816A2 - Eljárás flexibilis poliuretán habok előállítására - Google Patents
Eljárás flexibilis poliuretán habok előállításáraInfo
- Publication number
- HUP0001816A2 HUP0001816A2 HU0001816A HUP0001816A HUP0001816A2 HU P0001816 A2 HUP0001816 A2 HU P0001816A2 HU 0001816 A HU0001816 A HU 0001816A HU P0001816 A HUP0001816 A HU P0001816A HU P0001816 A2 HUP0001816 A2 HU P0001816A2
- Authority
- HU
- Hungary
- Prior art keywords
- weight
- parts
- pipe
- nco
- poly
- Prior art date
Links
- 229920005830 Polyurethane Foam Polymers 0.000 title abstract 2
- 238000004519 manufacturing process Methods 0.000 title abstract 2
- 239000011496 polyurethane foam Substances 0.000 title abstract 2
- -1 poly(oxyethylene) Polymers 0.000 abstract 5
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 abstract 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 3
- 239000000203 mixture Substances 0.000 abstract 3
- 239000004575 stone Substances 0.000 abstract 3
- 150000001875 compounds Chemical class 0.000 abstract 2
- 125000006353 oxyethylene group Chemical group 0.000 abstract 2
- 229920005862 polyol Polymers 0.000 abstract 2
- ZTNJGMFHJYGMDR-UHFFFAOYSA-N 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O ZTNJGMFHJYGMDR-UHFFFAOYSA-N 0.000 abstract 1
- 239000004721 Polyphenylene oxide Substances 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- HIFVAOIJYDXIJG-UHFFFAOYSA-N benzylbenzene;isocyanic acid Chemical class N=C=O.N=C=O.C=1C=CC=CC=1CC1=CC=CC=C1 HIFVAOIJYDXIJG-UHFFFAOYSA-N 0.000 abstract 1
- 239000006227 byproduct Substances 0.000 abstract 1
- 239000000945 filler Substances 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 239000000546 pharmaceutical excipient Substances 0.000 abstract 1
- 229920000570 polyether Polymers 0.000 abstract 1
- 229920001228 polyisocyanate Polymers 0.000 abstract 1
- 239000005056 polyisocyanate Substances 0.000 abstract 1
- 229920000642 polymer Polymers 0.000 abstract 1
- 150000003077 polyols Chemical class 0.000 abstract 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 239000000047 product Substances 0.000 abstract 1
- 239000011541 reaction mixture Substances 0.000 abstract 1
- 239000011347 resin Substances 0.000 abstract 1
- 229920005989 resin Polymers 0.000 abstract 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/08—Processes
- C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/409—Dispersions of polymers of C08G in organic compounds having active hydrogen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7614—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring
- C08G18/7621—Polyisocyanates or polyisothiocyanates cyclic aromatic containing only one aromatic ring being toluene diisocyanate including isomer mixtures
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/76—Polyisocyanates or polyisothiocyanates cyclic aromatic
- C08G18/7657—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings
- C08G18/7664—Polyisocyanates or polyisothiocyanates cyclic aromatic containing two or more aromatic rings containing alkylene polyphenyl groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0008—Foam properties flexible
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0041—Foam properties having specified density
- C08G2110/005—< 50kg/m3
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S521/00—Synthetic resins or natural rubbers -- part of the class 520 series
- Y10S521/914—Polyurethane cellular product formed from a polyol which has been derived from at least two 1,2 epoxides as reactants
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Dispersion Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
A találmány tárgya eljárás flexibilis pőliűretán habelőállítására őly módőn, hőgy a) egy pőliizőcianát kőmpőzíciót, amelya kőmpőzíció 100 tömegrészére vőnatkőztatva 5-20 tömegrészmennyiségben tartalmaz tőlűilén-diizőcianátőt és 80-95 tömegrészmennyiségben tartalmaz difenil-metán-diizőcianátőt és annak 3 vagynagyőbb izőcianát-fűnkciőnalitású hőmőlógjait, ahől a difenil-metán-diiző-cianát mennyisége a difenil-metán-diizőcianátők és hőmőlógjaikmennyiségének 70-95 tömeg %-át képezi, és a difenil-metán-di-izőcianátsaját tömegére vőnatkőztatva 8-45 tömeg% mennyiségben tartalmaz őlyanvegyületet, amelynek legalább egy őrtő helyzetű NCO-csőpőrtja van, ésahől a hárőm NCO-csőpőrtőt tartalmazó hőmőlógőknak a négy vagy többNCO-csőpőrtőt tartalmazó hőmőlógők és a melléktermékekösszmennyiségéhez viszőnyítőtt tömegaránya előnyösen 1,0-nél kisebb,70 és 120 közötti NCO-index betartásával b) egy őlyanpőliőlkőmpőzícióval reagáltatnak, amely (1) pőli (őxi-etilén)-pőli(őxi-prőpilén)-pőliőlt, amelynek átlagős névleges hidrőxil-fűnkciőnalitása 2-6, előnyösen 2-4, különösen előnyösen 3, átlagősegyenérték-tömege 1000-4000, és 5-25 tömeg% mennyiségben tartalmaz(őxi-etilén)-csőpőrtőkat, amelyek előnyösen a pőlimer lánc végeinélhelyezkednek el, (2) 100 tömegrész fenti (1) kőmpőnensre vőnatkőztatva2-7 tömegrész vizet, (3) 100 tömegrész fenti (1) kőmpőnensrevőnatkőztatva 2-10 tömegrész pőliéter-pőliőlt, amelynek átlagősegyenérték-tömege 200-1500, átlagős névleges hidrőxil-fűnkciőnalitása2-6, és legalább 60 tömeg% mennyiségben tartalmaz (őxi-etilén)-csőpőrtőkat, (4) 100 tömegrész fenti (1) kőmpőnensre vőnatkőztatva 1-15 tömegrész szemcsés anyagőt, ami egy pőliizőcianát és egy hidrőxil-,primer aminő- és/vagy szekűnder amínőcsőpőrtők sőkaságát tartalmazó,legföljebb 400-as egyenérték-tömegű vegyület reakcióterméke,tartalmaz, űtóbbit a pőliől kőmpőzícióban diszpergált állapőtban, (5)adőtt esetben egy vagy több önmagában ismert adalék és/vagysegédanyaggal együtt. ŕ
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP97200886 | 1997-03-25 | ||
PCT/EP1998/000867 WO1998042763A1 (en) | 1997-03-25 | 1998-02-16 | Process for preparing flexible polyurethane foam |
Publications (2)
Publication Number | Publication Date |
---|---|
HUP0001816A2 true HUP0001816A2 (hu) | 2000-09-28 |
HUP0001816A3 HUP0001816A3 (en) | 2001-04-28 |
Family
ID=8228143
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
HU0001816A HUP0001816A3 (en) | 1997-03-25 | 1998-02-16 | Process for preparing flexible polyurethane foam |
Country Status (26)
Country | Link |
---|---|
US (1) | US6037382A (hu) |
EP (1) | EP0970134B1 (hu) |
JP (2) | JP4023831B2 (hu) |
KR (1) | KR20010005629A (hu) |
CN (1) | CN1131256C (hu) |
AR (1) | AR012564A1 (hu) |
AT (1) | ATE205228T1 (hu) |
AU (1) | AU726107B2 (hu) |
BG (1) | BG103819A (hu) |
BR (1) | BR9808055A (hu) |
CA (1) | CA2283340A1 (hu) |
CO (1) | CO5031268A1 (hu) |
CZ (1) | CZ292768B6 (hu) |
DE (1) | DE69801564T2 (hu) |
ES (1) | ES2162426T3 (hu) |
HU (1) | HUP0001816A3 (hu) |
ID (1) | ID22640A (hu) |
MY (1) | MY132848A (hu) |
NO (1) | NO994675L (hu) |
PL (1) | PL335859A1 (hu) |
PT (1) | PT970134E (hu) |
RU (1) | RU2198187C2 (hu) |
TR (1) | TR199902333T2 (hu) |
TW (1) | TW538078B (hu) |
WO (1) | WO1998042763A1 (hu) |
ZA (1) | ZA982212B (hu) |
Families Citing this family (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6881783B1 (en) * | 1999-05-31 | 2005-04-19 | Huntsman International Llc | Process for making a PIPA-polyol |
EP1252215B1 (en) | 2000-01-17 | 2005-05-04 | Huntsman International Llc | Process for preparing a free rise or slabstock flexible polyurethane foam |
JP4810011B2 (ja) * | 2001-07-04 | 2011-11-09 | アキレス株式会社 | 滑性ウレタンフォーム |
AU2004236428B2 (en) * | 2003-05-12 | 2008-05-01 | Huntsman International Llc | Process for making a PIPA-polyol |
DE102004051048A1 (de) * | 2004-10-19 | 2006-04-20 | Bayer Materialscience Ag | Weichelastische Schaumstoffe geringer Rohdichten und Stauchhärte |
KR100682398B1 (ko) | 2005-07-20 | 2007-02-15 | 에스엔케이폴리텍(주) | 우수한 충격흡수성 및 복원력을 갖는 폴리우레탄 폼 및이의 제조방법 |
EA010014B1 (ru) * | 2006-07-20 | 2008-06-30 | Андрей Петрович Гончарук | Способ получения стабильной дисперсии полимеров, стабильная дисперсия полимеров и полиуретановая пена |
DE102006060376A1 (de) * | 2006-12-20 | 2008-06-26 | Bayer Materialscience Ag | Verfahren zur Herstellung von PIPA-Polyolen zur Herstellung von hochelastischen Polyurethan-Weichschaumstoffen |
JP2008247996A (ja) * | 2007-03-29 | 2008-10-16 | Nippon Polyurethane Ind Co Ltd | ポリイソシアネート組成物及びそれを用いた軟質ポリウレタンフォームの製造方法 |
US8996294B2 (en) | 2007-12-19 | 2015-03-31 | Nissan Motor Co., Ltd. | Inter-vehicle distance maintenance supporting system and method |
EP2675833B8 (en) | 2011-02-14 | 2017-12-13 | Dow Brasil Sudeste Industrial Ltda. | Low density polyurethane foams |
ES2758076T3 (es) * | 2013-08-02 | 2020-05-04 | Covestro Deutschland Ag | Procedimiento para la preparación de polietercarbonatopolioles |
JP6741420B2 (ja) * | 2015-12-16 | 2020-08-19 | 株式会社ブリヂストン | 乗り物のシート用パッド形成用軟質ポリウレタンフォーム、及び乗り物のシート用パッド |
SG11201804524TA (en) * | 2015-12-21 | 2018-07-30 | Shell Int Research | Process for the production of polyurethane foams |
EP3455270B1 (de) * | 2016-05-12 | 2020-04-29 | Basf Se | Klebefreier polyurethanweichschaumstoff |
ES2960371T3 (es) * | 2017-12-20 | 2024-03-04 | Dow Global Technologies Llc | Espumas de poliuretano para aplicaciones de bienestar |
MX2022009377A (es) * | 2020-01-31 | 2022-09-07 | Dow Global Technologies Llc | Espumas de poliuretano para aplicaciones de confort. |
CN111607061B (zh) * | 2020-04-15 | 2022-04-15 | 黎明化工研究设计院有限责任公司 | 一种无阻燃剂高阻燃低气味全水自结皮聚氨酯泡沫及其制备方法 |
CN116239747A (zh) * | 2021-12-08 | 2023-06-09 | 长华化学科技股份有限公司 | 快速熟化的聚氨酯泡沫及其制备方法与应用 |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB2072204B (en) * | 1980-02-14 | 1983-12-07 | Rowlands J P | Polymer-modified polyols useful in polyurethane manufacture |
US4374209A (en) * | 1980-10-01 | 1983-02-15 | Interchem International S.A. | Polymer-modified polyols useful in polyurethane manufacture |
DE4007063A1 (de) * | 1990-03-07 | 1991-09-12 | Bayer Ag | Stabile dispersionen von polyharnstoffen und/oder polyhydrazodicarbonamiden in hoehermolekularen, mindestens eine hydroxylgruppe aufweisenden verbindungen, ein verfahren zu ihrer herstellung und ihre verwendung zur herstellung von polyurethankunststoffen |
DE3806476A1 (de) * | 1988-03-01 | 1989-09-14 | Bayer Ag | Verfahren zur herstellung von kalthaertenden polyurethan-weichformschaumstoffen mit hervorragenden daempfungseigenschaften |
DE4001556A1 (de) * | 1990-01-20 | 1991-07-25 | Bayer Ag | Neue polyisocyanatmischungen und ihre verwendung bei der herstellung von weichen polyurethan-schaumstoffen |
US5773483A (en) * | 1993-04-13 | 1998-06-30 | Imperial Chemical Industries Plc | Process for preparing a flexible foam |
US5436277A (en) * | 1994-07-28 | 1995-07-25 | Basf Corporation | Polyisocyanate compositions for the preparation of flexible polyurethane foams |
-
1998
- 1998-02-16 BR BR9808055-5A patent/BR9808055A/pt active Search and Examination
- 1998-02-16 CN CN98803541A patent/CN1131256C/zh not_active Expired - Fee Related
- 1998-02-16 ES ES98910678T patent/ES2162426T3/es not_active Expired - Lifetime
- 1998-02-16 CA CA002283340A patent/CA2283340A1/en not_active Abandoned
- 1998-02-16 JP JP54478798A patent/JP4023831B2/ja not_active Expired - Fee Related
- 1998-02-16 ID IDW991065A patent/ID22640A/id unknown
- 1998-02-16 TR TR1999/02333T patent/TR199902333T2/xx unknown
- 1998-02-16 EP EP98910678A patent/EP0970134B1/en not_active Expired - Lifetime
- 1998-02-16 PL PL98335859A patent/PL335859A1/xx unknown
- 1998-02-16 CZ CZ19993360A patent/CZ292768B6/cs not_active IP Right Cessation
- 1998-02-16 RU RU99122340/04A patent/RU2198187C2/ru not_active IP Right Cessation
- 1998-02-16 HU HU0001816A patent/HUP0001816A3/hu unknown
- 1998-02-16 AU AU64977/98A patent/AU726107B2/en not_active Ceased
- 1998-02-16 KR KR1019997008696A patent/KR20010005629A/ko not_active Application Discontinuation
- 1998-02-16 AT AT98910678T patent/ATE205228T1/de not_active IP Right Cessation
- 1998-02-16 DE DE69801564T patent/DE69801564T2/de not_active Expired - Fee Related
- 1998-02-16 WO PCT/EP1998/000867 patent/WO1998042763A1/en not_active Application Discontinuation
- 1998-02-16 PT PT98910678T patent/PT970134E/pt unknown
- 1998-03-16 ZA ZA982212A patent/ZA982212B/xx unknown
- 1998-03-17 US US09/040,073 patent/US6037382A/en not_active Expired - Lifetime
- 1998-03-23 MY MYPI98001251A patent/MY132848A/en unknown
- 1998-03-24 CO CO98016378A patent/CO5031268A1/es unknown
- 1998-03-24 AR ARP980101335A patent/AR012564A1/es unknown
- 1998-03-24 TW TW087104423A patent/TW538078B/zh active
-
1999
- 1999-09-24 NO NO994675A patent/NO994675L/no unknown
- 1999-10-18 BG BG103819A patent/BG103819A/xx unknown
-
2007
- 2007-07-17 JP JP2007211138A patent/JP2007327068A/ja not_active Withdrawn
Also Published As
Publication number | Publication date |
---|---|
NO994675D0 (no) | 1999-09-24 |
ES2162426T3 (es) | 2001-12-16 |
ATE205228T1 (de) | 2001-09-15 |
ZA982212B (en) | 1998-09-28 |
CZ292768B6 (cs) | 2003-12-17 |
EP0970134B1 (en) | 2001-09-05 |
US6037382A (en) | 2000-03-14 |
PT970134E (pt) | 2001-12-28 |
CN1131256C (zh) | 2003-12-17 |
DE69801564T2 (de) | 2002-07-11 |
BR9808055A (pt) | 2000-03-08 |
CA2283340A1 (en) | 1998-10-01 |
AU726107B2 (en) | 2000-11-02 |
EP0970134A1 (en) | 2000-01-12 |
TR199902333T2 (xx) | 2000-04-21 |
RU2198187C2 (ru) | 2003-02-10 |
MY132848A (en) | 2007-10-31 |
JP2007327068A (ja) | 2007-12-20 |
NO994675L (no) | 1999-11-24 |
CZ336099A3 (cs) | 1999-12-15 |
TW538078B (en) | 2003-06-21 |
CO5031268A1 (es) | 2001-04-27 |
WO1998042763A1 (en) | 1998-10-01 |
CN1251113A (zh) | 2000-04-19 |
JP4023831B2 (ja) | 2007-12-19 |
AR012564A1 (es) | 2000-11-08 |
ID22640A (id) | 1999-12-02 |
DE69801564D1 (de) | 2001-10-11 |
AU6497798A (en) | 1998-10-20 |
KR20010005629A (ko) | 2001-01-15 |
PL335859A1 (en) | 2000-05-22 |
HUP0001816A3 (en) | 2001-04-28 |
JP2002510339A (ja) | 2002-04-02 |
BG103819A (en) | 2000-06-30 |
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