AU2005249351B2 - Dental compositions containing nanofillers and related methods - Google Patents
Dental compositions containing nanofillers and related methods Download PDFInfo
- Publication number
- AU2005249351B2 AU2005249351B2 AU2005249351A AU2005249351A AU2005249351B2 AU 2005249351 B2 AU2005249351 B2 AU 2005249351B2 AU 2005249351 A AU2005249351 A AU 2005249351A AU 2005249351 A AU2005249351 A AU 2005249351A AU 2005249351 B2 AU2005249351 B2 AU 2005249351B2
- Authority
- AU
- Australia
- Prior art keywords
- composition
- acid
- paste
- filler
- nanofiller
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
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- 238000000034 method Methods 0.000 title description 23
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- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 49
- 239000000463 material Substances 0.000 claims description 45
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 34
- 150000001875 compounds Chemical class 0.000 claims description 28
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- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical group [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 16
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- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims description 3
- 239000002246 antineoplastic agent Substances 0.000 claims description 3
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
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- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims description 3
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- 239000003193 general anesthetic agent Substances 0.000 claims description 3
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- 239000000499 gel Substances 0.000 claims description 2
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- 239000011797 cavity material Substances 0.000 claims 1
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- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 14
- 210000004268 dentin Anatomy 0.000 description 14
- WOBHKFSMXKNTIM-UHFFFAOYSA-N Hydroxyethyl methacrylate Chemical compound CC(=C)C(=O)OCCO WOBHKFSMXKNTIM-UHFFFAOYSA-N 0.000 description 12
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- AMFGWXWBFGVCKG-UHFFFAOYSA-N Panavia opaque Chemical compound C1=CC(OCC(O)COC(=O)C(=C)C)=CC=C1C(C)(C)C1=CC=C(OCC(O)COC(=O)C(C)=C)C=C1 AMFGWXWBFGVCKG-UHFFFAOYSA-N 0.000 description 9
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- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 description 6
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- PSYGHMBJXWRQFD-UHFFFAOYSA-N 2-(2-sulfanylacetyl)oxyethyl 2-sulfanylacetate Chemical compound SCC(=O)OCCOC(=O)CS PSYGHMBJXWRQFD-UHFFFAOYSA-N 0.000 description 5
- NXBXJOWBDCQIHF-UHFFFAOYSA-N 2-[hydroxy-[2-(2-methylprop-2-enoyloxy)ethoxy]phosphoryl]oxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(=O)OCCOC(=O)C(C)=C NXBXJOWBDCQIHF-UHFFFAOYSA-N 0.000 description 5
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- 230000007246 mechanism Effects 0.000 description 1
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- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical class CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 239000011859 microparticle Substances 0.000 description 1
- 150000007522 mineralic acids Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229910000402 monopotassium phosphate Inorganic materials 0.000 description 1
- 235000019796 monopotassium phosphate Nutrition 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 229910052758 niobium Inorganic materials 0.000 description 1
- 239000010955 niobium Substances 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- NFHFRUOZVGFOOS-UHFFFAOYSA-N palladium;triphenylphosphane Chemical compound [Pd].C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1.C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 NFHFRUOZVGFOOS-UHFFFAOYSA-N 0.000 description 1
- 239000011236 particulate material Substances 0.000 description 1
- 125000000538 pentafluorophenyl group Chemical group FC1=C(F)C(F)=C(*)C(F)=C1F 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 150000004968 peroxymonosulfuric acids Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 239000005365 phosphate glass Substances 0.000 description 1
- PJNZPQUBCPKICU-UHFFFAOYSA-N phosphoric acid;potassium Chemical compound [K].OP(O)(O)=O PJNZPQUBCPKICU-UHFFFAOYSA-N 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
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- 229920001444 polymaleic acid Polymers 0.000 description 1
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- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
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- 230000008569 process Effects 0.000 description 1
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 238000007348 radical reaction Methods 0.000 description 1
- 239000012266 salt solution Substances 0.000 description 1
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- 238000000926 separation method Methods 0.000 description 1
- SCPYDCQAZCOKTP-UHFFFAOYSA-N silanol Chemical compound [SiH3]O SCPYDCQAZCOKTP-UHFFFAOYSA-N 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- HQVNEWCFYHHQES-UHFFFAOYSA-N silicon nitride Chemical compound N12[Si]34N5[Si]62N3[Si]51N64 HQVNEWCFYHHQES-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 1
- 239000011775 sodium fluoride Substances 0.000 description 1
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- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
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- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
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- 235000020679 tap water Nutrition 0.000 description 1
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- 150000003628 tricarboxylic acids Chemical class 0.000 description 1
- IEKWPPTXWFKANS-UHFFFAOYSA-K trichlorocobalt Chemical compound Cl[Co](Cl)Cl IEKWPPTXWFKANS-UHFFFAOYSA-K 0.000 description 1
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- SXPUVBFQXJHYNS-UHFFFAOYSA-N α-furil Chemical compound C=1C=COC=1C(=O)C(=O)C1=CC=CO1 SXPUVBFQXJHYNS-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/20—Protective coatings for natural or artificial teeth, e.g. sealings, dye coatings or varnish
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/30—Compositions for temporarily or permanently fixing teeth or palates, e.g. primers for dental adhesives
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K6/00—Preparations for dentistry
- A61K6/80—Preparations for artificial teeth, for filling teeth or for capping teeth
- A61K6/884—Preparations for artificial teeth, for filling teeth or for capping teeth comprising natural or synthetic resins
- A61K6/887—Compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- A61K6/889—Polycarboxylate cements; Glass ionomer cements
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
Landscapes
- Health & Medical Sciences (AREA)
- Oral & Maxillofacial Surgery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Epidemiology (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Plastic & Reconstructive Surgery (AREA)
- Emergency Medicine (AREA)
- Birds (AREA)
- Dental Preparations (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US10/847,781 | 2004-05-17 | ||
| US10/847,781 US7156911B2 (en) | 2004-05-17 | 2004-05-17 | Dental compositions containing nanofillers and related methods |
| PCT/US2005/010119 WO2005117805A1 (en) | 2004-05-17 | 2005-03-25 | Dental compositions containing nanofillers and related methods |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| AU2005249351A1 AU2005249351A1 (en) | 2005-12-15 |
| AU2005249351B2 true AU2005249351B2 (en) | 2011-10-06 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| AU2005249351A Ceased AU2005249351B2 (en) | 2004-05-17 | 2005-03-25 | Dental compositions containing nanofillers and related methods |
Country Status (10)
| Country | Link |
|---|---|
| US (2) | US7156911B2 (enExample) |
| EP (4) | EP1746967B1 (enExample) |
| JP (1) | JP4851452B2 (enExample) |
| KR (1) | KR101166941B1 (enExample) |
| CN (1) | CN1984631B (enExample) |
| AT (1) | ATE470423T1 (enExample) |
| AU (1) | AU2005249351B2 (enExample) |
| CA (1) | CA2567044C (enExample) |
| DE (1) | DE602005021777D1 (enExample) |
| WO (1) | WO2005117805A1 (enExample) |
Families Citing this family (196)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4748938B2 (ja) * | 2002-01-31 | 2011-08-17 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科ペースト、歯科物品、および方法 |
| US20040206932A1 (en) * | 2002-12-30 | 2004-10-21 | Abuelyaman Ahmed S. | Compositions including polymerizable bisphosphonic acids and methods |
| AU2004266623B8 (en) | 2003-08-12 | 2011-10-27 | 3M Deutschland Gmbh | Self-etching dental compositions and methods |
| JP4261288B2 (ja) * | 2003-08-22 | 2009-04-30 | デンツプライ三金株式会社 | 歯科用接着剤組成物 |
| WO2005072683A1 (en) * | 2004-01-21 | 2005-08-11 | 3M Innovative Properties Company | Dental compositions and kits containing bitterness inhibitors, and related methods |
| US7649029B2 (en) * | 2004-05-17 | 2010-01-19 | 3M Innovative Properties Company | Dental compositions containing nanozirconia fillers |
| US7156911B2 (en) * | 2004-05-17 | 2007-01-02 | 3M Innovative Properties Company | Dental compositions containing nanofillers and related methods |
| JP5214242B2 (ja) | 2004-07-08 | 2013-06-19 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科用の方法、組成物、および酸感受性色素を含むキット |
| AU2004321435A1 (en) * | 2004-07-14 | 2006-01-19 | 3M Espe Ag | Dental composition containing an epoxy functional carbosilane compound |
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| CA2573716A1 (en) * | 2004-07-14 | 2006-02-23 | 3M Innovative Properties Company | Dental compositions containing carbosilane monomers |
| US20080085494A1 (en) * | 2004-07-14 | 2008-04-10 | Mader Roger M | Dental Compositions Containing Oxirane Monomers |
| CN101018536A (zh) * | 2004-07-14 | 2007-08-15 | 3M埃斯佩股份公司 | 含环氧官能可聚合化合物的牙科组合物 |
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| ATE439116T1 (de) * | 2004-09-24 | 2009-08-15 | 3M Espe Ag | Dentalklebstoffzusammensetzung |
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| DE102005023094A1 (de) * | 2005-05-13 | 2006-11-16 | Nies, Berthold, Dr. | Bioaktiver Knochenzement und seine Herstellung |
| US20090012209A1 (en) * | 2005-08-05 | 2009-01-08 | Gunther Eckhardt | Dental compositions containing a surface-modified filler |
| EP1922052B1 (en) * | 2005-08-08 | 2010-11-03 | Angstrom Medica, Inc. | Cement products and methods of making and using the same |
| US7495054B2 (en) * | 2005-09-19 | 2009-02-24 | 3M Innovative Properties Company | Curable compositions containing dithiane monomers |
| JP2007091607A (ja) * | 2005-09-27 | 2007-04-12 | Gc Corp | 歯科用ペースト系グラスアイオノマーセメント組成物 |
| JP4926440B2 (ja) * | 2005-09-30 | 2012-05-09 | 株式会社ジーシー | 歯科用グラスアイオノマーセメント液 |
| US8067402B2 (en) | 2005-12-12 | 2011-11-29 | Allaccem, Inc. | Methods and systems for coating an oral surface |
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| CN101351183A (zh) * | 2005-12-29 | 2009-01-21 | 3M创新有限公司 | 包含水清除剂的牙科用组合物 |
| US9993393B2 (en) * | 2005-12-29 | 2018-06-12 | 3M Innovative Properties Company | Dental compositions and initiator systems with polycyclic aromatic component |
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| WO2007100541A2 (en) * | 2006-02-23 | 2007-09-07 | Research Foundation Of The State University Of New York | Method of treating periodontitis and of reducing dentinal sensitivity |
| US7801319B2 (en) | 2006-05-30 | 2010-09-21 | Sonitus Medical, Inc. | Methods and apparatus for processing audio signals |
| US20120243714A9 (en) * | 2006-05-30 | 2012-09-27 | Sonitus Medical, Inc. | Microphone placement for oral applications |
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| JP2008019183A (ja) * | 2006-07-11 | 2008-01-31 | Gc Corp | 歯科用セメント |
| US8291912B2 (en) * | 2006-08-22 | 2012-10-23 | Sonitus Medical, Inc. | Systems for manufacturing oral-based hearing aid appliances |
| JP2010502376A (ja) * | 2006-09-08 | 2010-01-28 | ソニタス メディカル， インコーポレイテッド | 耳鳴り治療のための方法および装置 |
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| US9539065B2 (en) | 2006-10-23 | 2017-01-10 | 3M Innovative Properties Company | Assemblies, methods, and kits including a compressible material |
| WO2008053552A1 (fr) * | 2006-11-01 | 2008-05-08 | Fujitsu Limited | Appareil de communication sans fil et procédé de communication sans fil |
| JP5507256B2 (ja) | 2006-12-13 | 2014-05-28 | スリーエム イノベイティブ プロパティズ カンパニー | 酸性成分及び光退色性染料を有する歯科用組成物の使用方法 |
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| US20100021869A1 (en) * | 2006-12-28 | 2010-01-28 | Abuelyaman Ahmed S | (meth)acryloyl-containing materials, compositions, and methods |
| JP5465537B2 (ja) * | 2006-12-28 | 2014-04-09 | スリーエム イノベイティブ プロパティズ カンパニー | 硬組織用接着剤組成物 |
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| US20080221291A1 (en) * | 2007-03-07 | 2008-09-11 | 3M Innovative Properties Company | Microstructured optical films comprising biphenyl difunctional monomers |
| JP5154126B2 (ja) * | 2007-03-30 | 2013-02-27 | 株式会社ジーシー | 支台歯築造用コンポジットレジン |
| WO2008147997A1 (en) * | 2007-05-24 | 2008-12-04 | Ada Foundation | Tooth fluoridating and remineralizing compositions and methods, based on nanoaggregate formation |
| US8270638B2 (en) * | 2007-05-29 | 2012-09-18 | Sonitus Medical, Inc. | Systems and methods to provide communication, positioning and monitoring of user status |
| US20080304677A1 (en) * | 2007-06-08 | 2008-12-11 | Sonitus Medical Inc. | System and method for noise cancellation with motion tracking capability |
| US20090018234A1 (en) * | 2007-07-09 | 2009-01-15 | Gc Corporation | Dental cement |
| US20090028352A1 (en) * | 2007-07-24 | 2009-01-29 | Petroff Michael L | Signal process for the derivation of improved dtm dynamic tinnitus mitigation sound |
| US8188068B2 (en) | 2007-08-10 | 2012-05-29 | Allaccem, Inc. | Bridged polycyclic compound based compositions for coating oral surfaces in pets |
| US8153618B2 (en) | 2007-08-10 | 2012-04-10 | Allaccem, Inc. | Bridged polycyclic compound based compositions for topical applications for pets |
| US8153617B2 (en) | 2007-08-10 | 2012-04-10 | Allaccem, Inc. | Bridged polycyclic compound based compositions for coating oral surfaces in humans |
| US20120235632A9 (en) * | 2007-08-20 | 2012-09-20 | Sonitus Medical, Inc. | Intra-oral charging systems and methods |
| US8433080B2 (en) * | 2007-08-22 | 2013-04-30 | Sonitus Medical, Inc. | Bone conduction hearing device with open-ear microphone |
| US8224013B2 (en) * | 2007-08-27 | 2012-07-17 | Sonitus Medical, Inc. | Headset systems and methods |
| EP2203144A2 (en) | 2007-10-01 | 2010-07-07 | 3M Innovative Properties Company | Orthodontic composition with polymeric fillers |
| US7682303B2 (en) | 2007-10-02 | 2010-03-23 | Sonitus Medical, Inc. | Methods and apparatus for transmitting vibrations |
| US20090105523A1 (en) * | 2007-10-18 | 2009-04-23 | Sonitus Medical, Inc. | Systems and methods for compliance monitoring |
| CN102112097B (zh) | 2007-11-01 | 2013-08-07 | 3M创新有限公司 | 牙科组合物以及具有颜色稳定的胺电子供体的引发剂系统 |
| CA2706250C (en) | 2007-11-20 | 2018-07-24 | Sasi Kumar Sunkara | Formulation and method for treatment of teeth |
| US8795172B2 (en) * | 2007-12-07 | 2014-08-05 | Sonitus Medical, Inc. | Systems and methods to provide two-way communications |
| EP2229130A2 (en) * | 2007-12-13 | 2010-09-22 | 3M Innovative Properties Company | Remineralizing compositions and methods |
| WO2009075977A1 (en) * | 2007-12-13 | 2009-06-18 | 3M Innovative Properties Company | Orthodontic article having partially hardened composition and method of its use and manufacture |
| EP2072028A1 (de) | 2007-12-21 | 2009-06-24 | Ernst Mühlbauer GmbH & Co.KG | Stumpfaufbaumaterial |
| US20090197221A1 (en) * | 2008-02-04 | 2009-08-06 | Marshall Jr Grayson W | Dental bonding compositions and methods useful in inhibition of microleakage in resin-bonded dentin |
| US8270637B2 (en) | 2008-02-15 | 2012-09-18 | Sonitus Medical, Inc. | Headset systems and methods |
| US7974845B2 (en) | 2008-02-15 | 2011-07-05 | Sonitus Medical, Inc. | Stuttering treatment methods and apparatus |
| US8023676B2 (en) | 2008-03-03 | 2011-09-20 | Sonitus Medical, Inc. | Systems and methods to provide communication and monitoring of user status |
| US8150075B2 (en) | 2008-03-04 | 2012-04-03 | Sonitus Medical, Inc. | Dental bone conduction hearing appliance |
| US20090226020A1 (en) | 2008-03-04 | 2009-09-10 | Sonitus Medical, Inc. | Dental bone conduction hearing appliance |
| WO2009129074A1 (en) * | 2008-04-18 | 2009-10-22 | 3M Innovative Properties Company | Dental filling composition comprising acidic polymer compound and method of using the same |
| US20110045444A1 (en) * | 2008-04-18 | 2011-02-24 | Rao Prabhakara S | Dental filling composition comprising hyperbranched compound |
| US20090270673A1 (en) * | 2008-04-25 | 2009-10-29 | Sonitus Medical, Inc. | Methods and systems for tinnitus treatment |
| GB0809545D0 (en) * | 2008-05-28 | 2008-07-02 | 3M Innovative Properties Co | Device for dispensing a dental composition |
| BRPI0909575A2 (pt) | 2008-06-03 | 2015-09-22 | 3M Innovative Properties Co | "misturador para misturar uma composição dentária, sistema de liberação para uma composição dentária, sistema e kit de partes" |
| EP2133063A1 (en) * | 2008-06-10 | 2009-12-16 | 3M Innovative Properties Company | Initiator system with biphenylene derivates, method of production and use thereof |
| US8333203B2 (en) * | 2008-07-08 | 2012-12-18 | Sonitus Medical, Inc. | Custom fitted intra-oral appliances |
| DE202009019037U1 (de) | 2008-08-13 | 2015-09-21 | Ormco Corporation | Ästhetisches orthodontisches Bracket |
| WO2010027676A2 (en) * | 2008-09-04 | 2010-03-11 | 3M Innovative Properties Company | Dental composition comprising biphenyl di(meth)acrylate monomer |
| EP2341885A2 (en) * | 2008-09-30 | 2011-07-13 | 3M Innovative Properties Company | Orthodontic composition with heat modified minerals |
| WO2010045096A2 (en) * | 2008-10-15 | 2010-04-22 | 3M Innovative Properties Company | Dental compositions with fluorescent pigment |
| JP5661040B2 (ja) * | 2008-10-15 | 2015-01-28 | スリーエム イノベイティブ プロパティズ カンパニー | ジルコニア及びシリカナノ粒子を含む充填剤、並びにコンポジット材料 |
| WO2010048067A2 (en) * | 2008-10-22 | 2010-04-29 | 3M Innovative Properties Company | Dental composition comprising biphenyl di(meth)acrylate monomer comprising urethane moieties |
| AU2009238317B2 (en) | 2008-11-14 | 2011-10-06 | Ormco Corporation | Surface treated polycrystalline ceramic orthodontic bracket and method of making same |
| US8790707B2 (en) | 2008-12-11 | 2014-07-29 | 3M Innovative Properties Company | Surface-treated calcium phosphate particles suitable for oral care and dental compositions |
| US9296846B2 (en) * | 2008-12-18 | 2016-03-29 | The Trustees Of The University Of Pennsylvania | Porous polymer coating for tooth whitening |
| WO2010085427A1 (en) | 2009-01-22 | 2010-07-29 | 3M Innovative Properties Company | Surface-modified zirconia nanoparticles |
| EP2233123B2 (de) † | 2009-03-24 | 2020-03-11 | Ivoclar Vivadent AG | Selbsthaftender mehrkomponentiger Dentalwerkstoff |
| US9289359B2 (en) * | 2009-03-23 | 2016-03-22 | Ivoclar Vivadent Ag | Self-adhesive multicomponent dental material |
| DE102009016025B4 (de) * | 2009-04-02 | 2014-12-11 | Voco Gmbh | Kunststoffmodifizierter Glasionomerzement, seine Verwendung sowie Verfahren zu seiner Herstellung |
| US8053490B2 (en) | 2009-05-18 | 2011-11-08 | Pentron Clinical Technologies, Llc | Pre-treated acid-reactive fillers and their use in dental applications |
| CN102471077B (zh) * | 2009-08-07 | 2014-07-30 | 株式会社德山齿科 | 被覆有二氧化硅层的二氧化硅-氧化锆复合粒子的制造方法 |
| KR101783062B1 (ko) | 2009-08-28 | 2017-09-28 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 다작용성 양이온을 포함하는 중합성 이온성 액체 및 정전기 방지 코팅 |
| KR20120068009A (ko) | 2009-08-28 | 2012-06-26 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 중합성 이온성 액체 혼합물을 포함하는 조성물 및 물품, 및 경화 방법 |
| CN102640521B (zh) | 2009-10-02 | 2016-07-06 | 声脉有限责任公司 | 用于通过骨传导进行声音传递的口腔内器械 |
| RU2012131166A (ru) | 2009-12-22 | 2014-01-27 | 3М Инновейтив Пропертиз Компани | Отверждаемые стоматологические композиции и изделия, содержащие полимеризуемые ионные жидкости |
| CN102665605B (zh) * | 2009-12-22 | 2016-06-01 | 3M创新有限公司 | 牙科用组合物、铣削块和方法 |
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| US10370322B2 (en) | 2011-02-15 | 2019-08-06 | 3M Innovative Properties Company | Addition-fragmentation agents |
| US20140017637A1 (en) | 2011-03-24 | 2014-01-16 | 3M Iinnovative Properties Company | Dental adhesive comprising a coated polymeric component |
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| WO2013003396A2 (en) | 2011-06-29 | 2013-01-03 | 3M Innovative Properties Company | Dental compositions comprising a fatty mono(meth)acrylate |
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| WO2013028397A2 (en) | 2011-08-23 | 2013-02-28 | 3M Innovative Properties Company | Dental compositions comprising addition-fragmentation agents |
| JP6087355B2 (ja) | 2011-08-23 | 2017-03-01 | スリーエム イノベイティブ プロパティズ カンパニー | 付加開裂剤 |
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| KR102143888B1 (ko) | 2012-11-12 | 2020-08-12 | 쓰리엠 이노베이티브 프로퍼티즈 컴파니 | 부가-단편화제 |
| JP6351608B2 (ja) | 2012-11-12 | 2018-07-04 | スリーエム イノベイティブ プロパティズ カンパニー | 付加開裂剤を含む歯科用組成物 |
| TWI499429B (zh) * | 2012-11-26 | 2015-09-11 | Univ Nat Taiwan | 牙齒黏合劑及塗層劑 |
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| DE102013007894A1 (de) * | 2013-05-08 | 2014-11-13 | Heraeus Kulzer Gmbh | Langlebiges Dentalmaterial mit verbesserten transparenten Eigenschaften |
| US10208232B2 (en) | 2013-05-14 | 2019-02-19 | 3M Innovative Properties Company | Adhesive composition |
| EP2803712A1 (en) | 2013-05-17 | 2014-11-19 | 3M Innovative Properties Company | Multilayer Pressure Sensitive Adhesive Assembly |
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| WO2015034977A1 (en) * | 2013-09-09 | 2015-03-12 | 3M Innovative Properties Company | Dental composition containing polyoxometalates, process of production and use thereof |
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| EP3294783A1 (en) | 2015-05-11 | 2018-03-21 | 3M Innovative Properties Company | High performance (meth)acrylate adhesive composition |
| EP3106146A1 (en) * | 2015-06-15 | 2016-12-21 | Dentsply DeTrey GmbH | Aqueous dental glass ionomer composition |
| EP3156466B1 (en) | 2015-10-15 | 2020-11-25 | 3M Innovative Properties Company | Multilayer pressure sensitive adhesive foam tape for outdooor applications |
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| EP3231412A3 (en) * | 2016-04-15 | 2017-10-25 | DENTSPLY DETREY GmbH | Aqueous dental glass ionomer composition |
| US10105289B2 (en) | 2016-05-26 | 2018-10-23 | Essential Dental Systems, Inc. | Biomimetic mineral based endodontic cement composition and uses thereof |
| WO2018005311A1 (en) | 2016-06-29 | 2018-01-04 | 3M Innovative Properties Company | Polymerizable ionic liquid compositions |
| US10968197B2 (en) | 2016-10-20 | 2021-04-06 | 3M Innovative Properties Company | Photoinitiators with protected carbonyl group |
| WO2018102484A1 (en) | 2016-12-01 | 2018-06-07 | 3M Innovative Properties Company | Basic core material encapsulated in an inorganic shell suitable for use in biological carrier materials |
| EP3338757A1 (en) * | 2016-12-20 | 2018-06-27 | Dentsply DeTrey GmbH | Direct dental filling composition |
| EP3579810A1 (en) * | 2017-02-13 | 2019-12-18 | 3M Innovative Properties Company | Self-adhesive dental resin composition and use thereof |
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| KR102054296B1 (ko) * | 2017-11-09 | 2020-01-22 | 주식회사 마루치 | 의료용 충전재 조성물 |
| WO2019132849A2 (en) * | 2017-12-29 | 2019-07-04 | Yildiz Teknik Universitesi | Production of antibacterial and regenerative dental composite using supportive phases (fillers) antibacterial and bioactive properties of which are improved |
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| CN110946772A (zh) * | 2019-12-27 | 2020-04-03 | 苏格格 | 一种预防牙病的牙膏及其制备方法 |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5063257A (en) * | 1988-12-16 | 1991-11-05 | G-C Dental Industrial Corp. | Dental glass ionomer cement compositions |
| WO2001030307A1 (en) * | 1999-10-28 | 2001-05-03 | 3M Innovative Properties Company | Dental materials with nano-sized silica particles |
| WO2003086328A1 (en) * | 2002-04-12 | 2003-10-23 | 3M Innovative Properties Company | Medical compositions containing an ionic salt |
Family Cites Families (126)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1316129A (en) | 1969-12-15 | 1973-05-09 | Nat Res Dev | Surgical cement |
| US4209434A (en) * | 1972-04-18 | 1980-06-24 | National Research Development Corporation | Dental cement containing poly(carboxylic acid), chelating agent and glass cement powder |
| GB1569021A (en) * | 1976-03-17 | 1980-06-11 | Kuraray Co | Adhesive cementing agents containing partial phosphonic orphosphonic acid esters |
| US4070321A (en) | 1976-12-02 | 1978-01-24 | Nalco Chemical Company | Process for the preparation of water-in-oil emulsions of water soluble vinyl carboxylic acid polymers and copolymers |
| DE2909992A1 (de) * | 1979-03-14 | 1980-10-02 | Basf Ag | Photopolymerisierbare aufzeichnungsmassen, insbesondere zur herstellung von druckplatten und reliefformen |
| DE2909994A1 (de) * | 1979-03-14 | 1980-10-02 | Basf Ag | Acylphosphinoxidverbindungen, ihre herstellung und verwendung |
| DE2830927A1 (de) * | 1978-07-14 | 1980-01-31 | Basf Ag | Acylphosphinoxidverbindungen und ihre verwendung |
| US4695251A (en) * | 1980-04-07 | 1987-09-22 | Minnesota Mining And Manufacturing Company | Orthodontic bracket adhesive and abrasive for removal thereof |
| US4356296A (en) * | 1981-02-25 | 1982-10-26 | The United States Of America As Represented By The Secretary Of The Navy | Fluorinated diacrylic esters and polymers therefrom |
| US4539382A (en) * | 1981-07-29 | 1985-09-03 | Kuraray Co., Ltd. | Adhesive composition |
| ES8301593A1 (es) | 1981-11-16 | 1983-01-01 | Union Ind Y Agro Ganader S A U | Procedimiento de obtencion de una leche humanizada adiciona-da de nucleotidos con destino a la alimentacion infantil. |
| JPS59135272A (ja) * | 1983-01-21 | 1984-08-03 | Kuraray Co Ltd | 接着剤 |
| US4503169A (en) * | 1984-04-19 | 1985-03-05 | Minnesota Mining And Manufacturing Company | Radiopaque, low visual opacity dental composites containing non-vitreous microparticles |
| GR852068B (enExample) | 1984-08-30 | 1985-12-24 | Johnson & Johnson Dental Prod | |
| DE3443221A1 (de) * | 1984-11-27 | 1986-06-05 | ESPE Fabrik pharmazeutischer Präparate GmbH, 8031 Seefeld | Bisacylphosphinoxide, ihre herstellung und verwendung |
| US4642126A (en) * | 1985-02-11 | 1987-02-10 | Norton Company | Coated abrasives with rapidly curable adhesives and controllable curvature |
| DE3516256A1 (de) * | 1985-05-07 | 1986-11-13 | Bayer Ag, 5090 Leverkusen | (meth)-acrylsaeureester und ihre verwendung |
| DE3516257A1 (de) * | 1985-05-07 | 1986-11-13 | Bayer Ag, 5090 Leverkusen | (meth)-acrylsaeureester und ihre verwendung |
| US4652274A (en) * | 1985-08-07 | 1987-03-24 | Minnesota Mining And Manufacturing Company | Coated abrasive product having radiation curable binder |
| DE3536076A1 (de) * | 1985-10-09 | 1987-04-09 | Muehlbauer Ernst Kg | Polymerisierbare zementmischungen |
| US4772530A (en) * | 1986-05-06 | 1988-09-20 | The Mead Corporation | Photosensitive materials containing ionic dye compounds as initiators |
| US4798814A (en) * | 1986-09-26 | 1989-01-17 | Minnesota Mining And Manufacturing Company | Oxidation resistant alumina-silica articles containing silicon carbide and carbon |
| US4874450A (en) * | 1987-01-29 | 1989-10-17 | The Mead Corporation | Laminating transparent or translucent materials using ionic dye-counter ion complexes |
| JPH0755882B2 (ja) * | 1987-02-13 | 1995-06-14 | 而至歯科工業株式会社 | 歯科用グラスアイオノマーセメント用ガラス粉末 |
| CA1323949C (en) * | 1987-04-02 | 1993-11-02 | Michael C. Palazzotto | Ternary photoinitiator system for addition polymerization |
| US5078129A (en) | 1987-05-01 | 1992-01-07 | Research Foundation Of State University Of New York | Device for stimulating salivation |
| CA1317978C (en) * | 1987-06-05 | 1993-05-18 | Thomas E. Wood | Microcrystalline alumina-based ceramic articles |
| AU618772B2 (en) * | 1987-12-30 | 1992-01-09 | Minnesota Mining And Manufacturing Company | Photocurable ionomer cement systems |
| US4871786A (en) * | 1988-10-03 | 1989-10-03 | Minnesota Mining And Manufacturing Company | Organic fluoride sources |
| US4954414A (en) * | 1988-11-08 | 1990-09-04 | The Mead Corporation | Photosensitive composition containing a transition metal coordination complex cation and a borate anion and photosensitive materials employing the same |
| DE3841617C1 (enExample) | 1988-12-10 | 1990-05-10 | Th. Goldschmidt Ag, 4300 Essen, De | |
| US5026902A (en) * | 1988-12-10 | 1991-06-25 | Th. Goldschmidt AG & GDF Gesellschaft fur Dentale Forschung u. Innovationen GmbH | Dental compsition of perfluoroalkyl group-containing (meth-)acrylate esters |
| US5076844A (en) * | 1988-12-10 | 1991-12-31 | Goldschmidt AG & GDF Gesellschaft fur Dentale Forschung u. Innovationen GmbH | Perfluoroalkyl group-containing (meth-)acrylate esters, their synthesis and use in dental technology |
| US5057393A (en) * | 1989-07-10 | 1991-10-15 | The Mead Corporation | Dye branched-alkyl borate photoinitiators |
| GB8924129D0 (en) * | 1989-10-26 | 1989-12-13 | Ellis John | Polyvinylphosphonic acid glass ionomer cement |
| US5037579A (en) * | 1990-02-12 | 1991-08-06 | Nalco Chemical Company | Hydrothermal process for producing zirconia sol |
| US5055372A (en) * | 1990-04-23 | 1991-10-08 | The Mead Corporation | Photohardenable composition containing borate salts and ketone initiators |
| DE4024322A1 (de) | 1990-07-31 | 1992-02-06 | Thera Ges Fuer Patente | Verformbare masse und deren verwendung als fuellmaterial fuer zahnwurzelkanaele |
| DE4105550A1 (de) | 1991-02-22 | 1992-08-27 | Bayer Ag | Adhaesivkomponente zur behandlung der zahnhartsubstanz |
| US5332429A (en) * | 1991-05-31 | 1994-07-26 | Minnesota Mining And Manufacturing Company | Method for treating fluoroaluminosilicate glass |
| US5154762A (en) * | 1991-05-31 | 1992-10-13 | Minnesota Mining And Manufacturing Company | Universal water-based medical and dental cement |
| US5252122B1 (en) * | 1991-08-22 | 1999-12-07 | Mion Int Corp | Ionic bond between amalgam and glas ionomer |
| JP2732968B2 (ja) * | 1991-09-06 | 1998-03-30 | 鐘紡株式会社 | 歯科用充填組成物 |
| US5367002A (en) * | 1992-02-06 | 1994-11-22 | Dentsply Research & Development Corp. | Dental composition and method |
| US5227413A (en) | 1992-02-27 | 1993-07-13 | Minnesota Mining And Manufacturing Company | Cements from β-dicarbonyl polymers |
| JPH05331017A (ja) | 1992-05-27 | 1993-12-14 | Dainippon Toryo Co Ltd | 歯科セメント用ガラス粉末 |
| DE4306997A1 (de) | 1993-03-05 | 1994-09-08 | Thera Ges Fuer Patente | Hydrophilierte Polyether |
| US6696585B1 (en) * | 1993-04-13 | 2004-02-24 | Southwest Research Institute | Functionalized nanoparticles |
| US5720805A (en) * | 1993-04-13 | 1998-02-24 | Southwest Research Institute | Titanium-tin-oxide nanoparticles, compositions utilizing the same, and the method of forming the same |
| US6258974B1 (en) * | 1993-04-13 | 2001-07-10 | Southwest Research Institute | Metal oxide compositions composites thereof and method |
| US5372796A (en) * | 1993-04-13 | 1994-12-13 | Southwest Research Institute | Metal oxide-polymer composites |
| US6417244B1 (en) * | 1993-04-13 | 2002-07-09 | Southwest Research Institute | Metal oxide compositions and methods |
| US5883153A (en) * | 1993-04-15 | 1999-03-16 | Shofu Inc. | Fluoride ion sustained release preformed glass ionomer filler and dental compositions containing the same |
| JP3452379B2 (ja) | 1993-05-18 | 2003-09-29 | 大日本塗料株式会社 | 顆粒状歯科用セメントの調製方法 |
| US5530038A (en) * | 1993-08-02 | 1996-06-25 | Sun Medical Co., Ltd. | Primer composition and curable composition |
| TW289024B (enExample) | 1993-11-02 | 1996-10-21 | Hoechst Ag | |
| US5501727A (en) * | 1994-02-28 | 1996-03-26 | Minnesota Mining And Manufacturing Company | Color stability of dental compositions containing metal complexed ascorbic acid |
| EP0748201A1 (en) * | 1994-02-28 | 1996-12-18 | Minnesota Mining And Manufacturing Company | Paste:paste glass ionomer cement system and method |
| JP3214982B2 (ja) * | 1994-07-04 | 2001-10-02 | 株式会社トクヤマ | 無機組成物 |
| JP3471431B2 (ja) * | 1994-07-18 | 2003-12-02 | 株式会社ジーシー | 歯科用グラスアイオノマーセメント組成物 |
| EP0712622B1 (en) | 1994-11-21 | 1999-09-01 | Tokuyama Corporation | Dental composition and kit |
| US5694701A (en) * | 1996-09-04 | 1997-12-09 | Minnesota Mining And Manufacturing Company | Coated substrate drying system |
| BR9610657A (pt) * | 1995-09-18 | 1999-02-17 | Minnesota Mining & Mfg | Processo e aparelho para separar componentes de uma mistura e mecanismo de codensação para uso em um sistema de separação de componentes |
| US6391286B1 (en) * | 1995-11-17 | 2002-05-21 | 3M Innovative Properties Company | Use of metallofluorocomplexes for dental compositions |
| US6050815A (en) | 1996-03-15 | 2000-04-18 | 3M Innovative Properties Company | Precoated dental cement |
| IL118460A (en) | 1996-05-28 | 1999-09-22 | Dead Sea Works Ltd | Edible salt mixture |
| US6136885A (en) * | 1996-06-14 | 2000-10-24 | 3M Innovative Proprerties Company | Glass ionomer cement |
| US20030180414A1 (en) * | 1996-11-27 | 2003-09-25 | Gudas Victor V. | Method of controlling release of bitterness inhibitors in chewing gum and gum produced thereby |
| US5871360A (en) | 1996-12-31 | 1999-02-16 | Gc Corporation | Method for restoration of a cavity of a tooth using a resin reinforced type glass ionomer cement |
| JP4083257B2 (ja) | 1997-03-19 | 2008-04-30 | 株式会社ジーシー | 歯科充填用レジン組成物 |
| DE19711514B4 (de) | 1997-03-19 | 2006-09-14 | 3M Espe Ag | Triglyceride enthaltende Abformmassen |
| US6353040B1 (en) * | 1997-04-02 | 2002-03-05 | Dentsply Research & Development Corp. | Dental composite restorative material and method of restoring a tooth |
| US6262142B1 (en) * | 1997-04-02 | 2001-07-17 | Dentsply Research & Development | Translucent wear resistant dental enamel material and method |
| US5965632A (en) | 1997-06-20 | 1999-10-12 | Scientific Pharmaceuticals Inc. | Dental cement compositions |
| US5859089A (en) * | 1997-07-01 | 1999-01-12 | The Kerr Corporation | Dental restorative compositions |
| DE19740234B4 (de) | 1997-09-12 | 2008-07-10 | 3M Espe Ag | Verwendung von Dentalmassen auf Polyetherbasis zur Abformung im zahnmedizinischen oder zahntechnischen Bereich |
| US6693143B2 (en) * | 1997-10-03 | 2004-02-17 | Dentsply Detrey Gmbh | Dental materials having a nanoscale filler |
| DE19753456B4 (de) | 1997-12-02 | 2007-01-11 | 3M Espe Ag | Zweikomponente, kationisch aushärtende Zubereitungen auf der Basis von Aziridinopolyethern und deren Verwendung |
| JPH11228327A (ja) * | 1998-02-18 | 1999-08-24 | Gc Corp | 歯科用ペースト系グラスアイオノマーセメント組成物 |
| IT1299563B1 (it) | 1998-07-17 | 2000-03-16 | Giovanni Dolci | Uso odontostomatologico di materiali a base apatitica nanostrutturati |
| EP1017354B1 (en) | 1998-07-20 | 2005-07-06 | Dentsply International, Inc. | Translucent wear resistant dental enamel material and method |
| DE19832965A1 (de) * | 1998-07-22 | 2000-02-03 | Fraunhofer Ges Forschung | Sphärische Ionomerpartikel und deren Herstellung |
| US6669927B2 (en) | 1998-11-12 | 2003-12-30 | 3M Innovative Properties Company | Dental compositions |
| US6312667B1 (en) | 1998-11-12 | 2001-11-06 | 3M Innovative Properties Company | Methods of etching hard tissue in the oral environment |
| US6312666B1 (en) | 1998-11-12 | 2001-11-06 | 3M Innovative Properties Company | Methods of whitening teeth |
| SE9904080D0 (sv) * | 1998-12-03 | 1999-11-11 | Ciba Sc Holding Ag | Fotoinitiatorberedning |
| AU2378600A (en) * | 1998-12-23 | 2000-07-31 | Mount Sinai School Of Medicine Of The City University Of New York, The | Inhibitors of the bitter taste response |
| DE19860364C2 (de) | 1998-12-24 | 2001-12-13 | 3M Espe Ag | Polymerisierbare Dentalmassen auf der Basis von zur Aushärtung befähigten Siloxanverbindungen, deren Verwendung und Herstellung |
| DE19860361A1 (de) | 1998-12-24 | 2000-06-29 | Espe Dental Ag | Vernetzbare Monomere auf Cyclosiloxanbasis, deren Herstellung und deren Verwendung in polymerisierbaren Massen |
| JP2000217547A (ja) | 1999-01-27 | 2000-08-08 | Ajinomoto Co Inc | 苦味が低減されたアミノ酸類含有組成物 |
| ATE255116T1 (de) * | 1999-03-31 | 2003-12-15 | Kuraray Co | Organophosphor-verbindungen für dentale polymerisierbare zusammensetzungen |
| TWI284540B (en) | 1999-05-13 | 2007-08-01 | Kuraray Co | Bonding composition suitable to tooth tissue |
| US6194481B1 (en) * | 1999-05-19 | 2001-02-27 | Board Of Regents Of The University Of Texas System | Mechanically strong and transparent or translucent composites made using zirconium oxide nanoparticles |
| JP4636656B2 (ja) | 1999-07-08 | 2011-02-23 | 株式会社松風 | 歯科用接着剤組成物 |
| DE19934407A1 (de) | 1999-07-22 | 2001-01-25 | Espe Dental Ag | Hydrolysierbare und polymerisierbare Silane mit geringer Viskosität und deren Verwendung |
| US6472454B1 (en) | 1999-10-22 | 2002-10-29 | Kerr Corporation | Endodontic dental compositions |
| US6730156B1 (en) | 1999-10-28 | 2004-05-04 | 3M Innovative Properties Company | Clustered particle dental fillers |
| US6376590B2 (en) * | 1999-10-28 | 2002-04-23 | 3M Innovative Properties Company | Zirconia sol, process of making and composite material |
| US6387981B1 (en) | 1999-10-28 | 2002-05-14 | 3M Innovative Properties Company | Radiopaque dental materials with nano-sized particles |
| US6572693B1 (en) * | 1999-10-28 | 2003-06-03 | 3M Innovative Properties Company | Aesthetic dental materials |
| DE60032858T2 (de) * | 1999-11-17 | 2007-09-06 | Kabushiki Kaisha Shofu | Dentales Füllungsmaterial |
| DE10026432A1 (de) | 2000-05-29 | 2002-02-14 | 3M Espe Ag | Präpolymere (Meth)acrylate mit polycyclischen oder aromatischen Segmenten |
| US6565873B1 (en) | 2000-10-25 | 2003-05-20 | Salvona Llc | Biodegradable bioadhesive controlled release system of nano-particles for oral care products |
| DE10124028B4 (de) | 2001-05-16 | 2010-02-18 | 3M Espe Ag | Selbstadhäsive Dentalmaterialien |
| US6593395B2 (en) * | 2001-05-16 | 2003-07-15 | Kerr Corporation | Dental composition containing discrete nanoparticles |
| US6942874B2 (en) | 2001-05-25 | 2005-09-13 | Linguagen Corp. | Nucleotide compounds that block the bitter taste of oral compositions |
| JP4822617B2 (ja) | 2001-06-28 | 2011-11-24 | クラレメディカル株式会社 | 歯科用セメント組成物 |
| US6765038B2 (en) * | 2001-07-27 | 2004-07-20 | 3M Innovative Properties Company | Glass ionomer cement |
| US6620405B2 (en) | 2001-11-01 | 2003-09-16 | 3M Innovative Properties Company | Delivery of hydrogel compositions as a fine mist |
| US7173074B2 (en) * | 2001-12-29 | 2007-02-06 | 3M Innovative Properties Company | Composition containing a polymerizable reducing agent, kit, and method |
| US6765036B2 (en) * | 2002-01-15 | 2004-07-20 | 3M Innovative Properties Company | Ternary photoinitiator system for cationically polymerizable resins |
| JP4748938B2 (ja) | 2002-01-31 | 2011-08-17 | スリーエム イノベイティブ プロパティズ カンパニー | 歯科ペースト、歯科物品、および方法 |
| US7129281B2 (en) | 2002-03-19 | 2006-10-31 | Dentsply-Sankin K.K. | One-bottle dental bonding composition |
| US20040197401A1 (en) | 2002-06-14 | 2004-10-07 | Calton Gary J | Modifying undesirable tastes |
| JP2004067597A (ja) | 2002-08-07 | 2004-03-04 | Gc Corp | 歯科用組成物 |
| US6689343B1 (en) | 2002-11-05 | 2004-02-10 | Ultradent Products, Inc. | Hemostatic and acid etch compositions containing sucralose |
| US20040120901A1 (en) | 2002-12-20 | 2004-06-24 | Dong Wu | Dental compositions including enzymes and methods |
| US20040206932A1 (en) | 2002-12-30 | 2004-10-21 | Abuelyaman Ahmed S. | Compositions including polymerizable bisphosphonic acids and methods |
| US20040185013A1 (en) | 2003-01-30 | 2004-09-23 | Burgio Paul A. | Dental whitening compositions and methods |
| US7223826B2 (en) | 2003-01-30 | 2007-05-29 | 3M Innovative Properties Company | Amide-functional polymers, compositions, and methods |
| US20040151691A1 (en) | 2003-01-30 | 2004-08-05 | Oxman Joel D. | Hardenable thermally responsive compositions |
| WO2005072683A1 (en) | 2004-01-21 | 2005-08-11 | 3M Innovative Properties Company | Dental compositions and kits containing bitterness inhibitors, and related methods |
| US7090721B2 (en) * | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Use of nanoparticles to adjust refractive index of dental compositions |
| US7156911B2 (en) * | 2004-05-17 | 2007-01-02 | 3M Innovative Properties Company | Dental compositions containing nanofillers and related methods |
| US7090722B2 (en) * | 2004-05-17 | 2006-08-15 | 3M Innovative Properties Company | Acid-reactive dental fillers, compositions, and methods |
| US7649029B2 (en) | 2004-05-17 | 2010-01-19 | 3M Innovative Properties Company | Dental compositions containing nanozirconia fillers |
-
2004
- 2004-05-17 US US10/847,781 patent/US7156911B2/en not_active Expired - Lifetime
-
2005
- 2005-03-25 DE DE602005021777T patent/DE602005021777D1/de not_active Expired - Lifetime
- 2005-03-25 EP EP05746281A patent/EP1746967B1/en not_active Expired - Lifetime
- 2005-03-25 EP EP09178848A patent/EP2172184A1/en not_active Withdrawn
- 2005-03-25 WO PCT/US2005/010119 patent/WO2005117805A1/en not_active Ceased
- 2005-03-25 EP EP09178835A patent/EP2181689B1/en not_active Expired - Lifetime
- 2005-03-25 JP JP2007527210A patent/JP4851452B2/ja not_active Expired - Fee Related
- 2005-03-25 CN CN2005800239399A patent/CN1984631B/zh not_active Expired - Fee Related
- 2005-03-25 CA CA2567044A patent/CA2567044C/en not_active Expired - Fee Related
- 2005-03-25 KR KR1020067026536A patent/KR101166941B1/ko not_active Expired - Fee Related
- 2005-03-25 EP EP09178843A patent/EP2172183A1/en not_active Withdrawn
- 2005-03-25 AU AU2005249351A patent/AU2005249351B2/en not_active Ceased
- 2005-03-25 AT AT05746281T patent/ATE470423T1/de not_active IP Right Cessation
-
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- 2006-10-27 US US11/588,764 patent/US7361216B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5063257A (en) * | 1988-12-16 | 1991-11-05 | G-C Dental Industrial Corp. | Dental glass ionomer cement compositions |
| WO2001030307A1 (en) * | 1999-10-28 | 2001-05-03 | 3M Innovative Properties Company | Dental materials with nano-sized silica particles |
| WO2003086328A1 (en) * | 2002-04-12 | 2003-10-23 | 3M Innovative Properties Company | Medical compositions containing an ionic salt |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1984631B (zh) | 2013-05-08 |
| CA2567044C (en) | 2014-01-21 |
| US7361216B2 (en) | 2008-04-22 |
| EP2172184A1 (en) | 2010-04-07 |
| KR20070013332A (ko) | 2007-01-30 |
| JP2007538071A (ja) | 2007-12-27 |
| AU2005249351A1 (en) | 2005-12-15 |
| CN1984631A (zh) | 2007-06-20 |
| EP2181689B1 (en) | 2012-06-20 |
| CA2567044A1 (en) | 2005-12-15 |
| US20070039519A1 (en) | 2007-02-22 |
| US7156911B2 (en) | 2007-01-02 |
| US20050252413A1 (en) | 2005-11-17 |
| DE602005021777D1 (de) | 2010-07-22 |
| EP2181689A1 (en) | 2010-05-05 |
| JP4851452B2 (ja) | 2012-01-11 |
| ATE470423T1 (de) | 2010-06-15 |
| EP2172183A1 (en) | 2010-04-07 |
| EP1746967B1 (en) | 2010-06-09 |
| KR101166941B1 (ko) | 2012-07-19 |
| WO2005117805A1 (en) | 2005-12-15 |
| EP1746967A1 (en) | 2007-01-31 |
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