ATE324941T1 - Katalytische oxidierung von alkanen zu zugehöriger säure - Google Patents

Katalytische oxidierung von alkanen zu zugehöriger säure

Info

Publication number
ATE324941T1
ATE324941T1 AT99972126T AT99972126T ATE324941T1 AT E324941 T1 ATE324941 T1 AT E324941T1 AT 99972126 T AT99972126 T AT 99972126T AT 99972126 T AT99972126 T AT 99972126T AT E324941 T1 ATE324941 T1 AT E324941T1
Authority
AT
Austria
Prior art keywords
alkanes
catalytic oxidation
associated acid
propane
acid
Prior art date
Application number
AT99972126T
Other languages
English (en)
Inventor
Khalid Karim
Yajnavalkya Subrai Bhat
Syed Irshad Zaheer
Abdullah Bin Nafisah
Assad Ahmed Khan
Original Assignee
Saudi Basic Ind Corp Sabic
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Ind Corp Sabic filed Critical Saudi Basic Ind Corp Sabic
Application granted granted Critical
Publication of ATE324941T1 publication Critical patent/ATE324941T1/de

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6482—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
AT99972126T 1998-11-16 1999-11-15 Katalytische oxidierung von alkanen zu zugehöriger säure ATE324941T1 (de)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US09/193,015 US6114278A (en) 1998-11-16 1998-11-16 Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same

Publications (1)

Publication Number Publication Date
ATE324941T1 true ATE324941T1 (de) 2006-06-15

Family

ID=22711946

Family Applications (1)

Application Number Title Priority Date Filing Date
AT99972126T ATE324941T1 (de) 1998-11-16 1999-11-15 Katalytische oxidierung von alkanen zu zugehöriger säure

Country Status (9)

Country Link
US (3) US6114278A (de)
EP (2) EP1156877B1 (de)
JP (1) JP4809531B2 (de)
CN (1) CN1145527C (de)
AT (1) ATE324941T1 (de)
DE (2) DE69931184T2 (de)
ES (2) ES2264284T3 (de)
SA (3) SA06260448B1 (de)
WO (2) WO2000029105A1 (de)

Families Citing this family (66)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6432870B1 (en) * 1999-05-25 2002-08-13 Toagosei Co., Ltd. Process for preparing metal oxide catalyst for acrylic acid production
US6337424B1 (en) * 2000-04-28 2002-01-08 Saudi Basic Industries Corporation Catalysts oxidation of lower olefins to unsaturated aldehydes, methods of making and using the same
US7321058B2 (en) 2000-06-14 2008-01-22 Basf Aktiengesellschaft Method for producing acrolein and/or acrylic acid
DE10118814A1 (de) 2001-04-17 2002-10-24 Basf Ag Verfahren zur Herstellung von Acrylsäure durch heterogen katalysierte Gasphasenoxidation von Propen mit molekularem Sauerstoff in einer Reaktionszone
DE10051419A1 (de) * 2000-10-17 2002-04-18 Basf Ag Katalysator bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse
US6441227B1 (en) * 2000-06-23 2002-08-27 Saudi Basic Industries Corporation Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons
CZ301370B6 (cs) 2000-07-18 2010-02-03 Basf Aktiengesellschaft Zpusob prípravy kyseliny akrylové heterogenne katalyzovanou oxidací propanu v plynné fázi
US6461996B2 (en) 2000-09-28 2002-10-08 Rohm And Haas Company Halogen promoted multi-metal oxide catalyst
US6407031B1 (en) 2000-09-28 2002-06-18 Rohm And Haas Company Promoted multi-metal oxide catalyst
KR100814702B1 (ko) * 2000-09-28 2008-03-18 롬 앤드 하스 캄파니 불포화 니트릴 제조방법
US6407280B1 (en) 2000-09-28 2002-06-18 Rohm And Haas Company Promoted multi-metal oxide catalyst
US6734136B2 (en) 2000-09-28 2004-05-11 Rohm And Haas Company IR and/or SM promoted multi-metal oxide catalyst
US6589907B2 (en) 2000-09-28 2003-07-08 Rohm And Haas Company Zn and/or Ga promoted multi-metal oxide catalyst
US6403525B1 (en) 2000-09-28 2002-06-11 Rohm And Haas Company Promoted multi-metal oxide catalyst
TW548133B (en) 2001-04-12 2003-08-21 Rohm & Haas NOx treated mixed metal oxide catalyst
US6943135B2 (en) 2001-04-12 2005-09-13 Rohm And Haas Company NOx treated mixed metal oxide catalyst
US6841699B2 (en) * 2001-04-25 2005-01-11 Rohm And Haas Company Recalcined catalyst
EP1266688A3 (de) * 2001-06-14 2003-07-09 Rohm And Haas Company Mischoxidkatalysator, der durch Gasphasenabscheidung eines Metalls dotiert wurde, und Mischoxidkatalysator, der durch Aufbringen mehrerer Schichten verschiedener Elemente mittels Gasphasenabscheidung hergestellt wurde
EP1598112A3 (de) * 2001-06-14 2005-11-30 Rohm and Haas Company Verfahren zur Herstellung eines Mischoxidkatalysators durch Gasphasenabscheidung
ZA200208247B (en) * 2001-10-26 2003-05-14 Rohm & Haas Treatment of mixed metal oxide catalyst.
MXPA02011489A (es) 2001-12-04 2003-06-30 Rohm & Haas Procesos mejorados para la preparacion de olefinas, acidos carboxilicos insaturados y nitrilos insaturados, a partir de alcanos.
US6919472B2 (en) * 2001-12-21 2005-07-19 Saudi Basic Industries Corporation Catalyst compositions for the selective conversion of alkanes to unsaturated carboxylic acids, methods of making and methods of using thereof
US6919295B2 (en) 2002-05-01 2005-07-19 Rohm And Haas Company Supported mixed metal oxide catalyst
TW200400851A (en) 2002-06-25 2004-01-16 Rohm & Haas PVD supported mixed metal oxide catalyst
JP2005538173A (ja) * 2002-09-10 2005-12-15 アルケマ 分子酸素の存在下におけるプロパンからのアクリル酸の製造方法
FR2844262B1 (fr) * 2002-09-10 2004-10-15 Atofina Procede de fabrication d'acide acrylique a partir de propane, en l'absence d'oxygene moleculaire
EP1407819A3 (de) * 2002-10-01 2004-06-23 Rohm And Haas Company Durch hydrothermale Behandlung hergestellte Mo-V-M-Nb-X-oxid Katalysatoren für die selektive Oxidation von Kohlenwasserstoffen
US7038082B2 (en) 2002-10-17 2006-05-02 Basf Aktiengesellschaft Preparation of a multimetal oxide material
US7229946B2 (en) * 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
US7012157B2 (en) 2003-09-23 2006-03-14 Basf Aktiengesellschaft Preparation of (meth)acrylic acid
US7019169B2 (en) 2003-09-23 2006-03-28 Basf Aktiengesellschaft Preparation of (meth)acrylic acid
US20050137422A1 (en) * 2003-12-19 2005-06-23 Saudi Basic Industries Corporation Process for producing an unsaturated carboxylic acid from an alkane
US8193387B2 (en) * 2003-12-19 2012-06-05 Saudi Basic Industries Corporation Process for producing an unsaturated carboxylic acid from an alkane
US7553986B2 (en) * 2003-12-23 2009-06-30 Rohm And Haas Company Process for the selective (amm)oxidation of lower molecular weight alkanes and alkenes
BRPI0500615B1 (pt) 2004-03-10 2015-07-14 Rohm & Haas Catalisador modificado, e, sistema de catalisador modificado
TWI303584B (en) * 2004-04-08 2008-12-01 Rohm & Haas Improved catalytic (amm)oxidation process for conversion of lower alkanes
EP1593663A1 (de) * 2004-05-05 2005-11-09 Haldor Topsoe A/S Verfahren zur Herstellung von Acrolein und/oder Acrylsäure
US20060020142A1 (en) * 2004-07-23 2006-01-26 Pessoa Cavalcanti Fernando A Catalytic (AMM)oxidation process for conversion of lower alkanes to carboxylic acids and nitriles
JP4635571B2 (ja) * 2004-11-09 2011-02-23 住友化学株式会社 脂肪族環式炭化水素類の酸化反応に用いる触媒及びそれを用いる酸化方法
US20060122055A1 (en) * 2004-12-06 2006-06-08 Gaffney Anne M (Amm)oxidation catalyst and catalytic (amm)oxidation process for conversion of lower alkanes
FR2880346B1 (fr) * 2004-12-30 2007-02-23 Arkema Sa Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau
SG137840A1 (en) * 2005-02-18 2007-12-28 Mitsubishi Rayon Co PALLADIUM-CONTAINING CATALYST, METHOD FOR PRODUCING THE SAME, AND METHOD FOR PRODUCING α, β-UNSATURATED CARBOXYLIC ACID
US20090023952A1 (en) 2005-02-18 2009-01-22 Mitsubishi Rayon Co., Ltd. Palladium-containing catalyst, method for producing same, and method for producing alpha, beta-unsaturated carboxylic acid
WO2007001649A2 (en) * 2005-06-22 2007-01-04 Exxonmobil Chemical Patents Inc. Oxidation of alkanes
KR100807972B1 (ko) * 2005-08-10 2008-02-28 주식회사 엘지화학 아크릴산 선택성이 높은 복합 금속 산화물 촉매
US7365217B2 (en) * 2006-01-25 2008-04-29 Lyondell Chemical Technology, L.P. Oxidation process
TWI311498B (en) * 2006-07-19 2009-07-01 Lg Chemical Ltd Catalyst for partial oxidation of methylbenzenes, method for preparing the same, and method for producing aromatic aldehydes using the same
JP5094459B2 (ja) * 2007-03-09 2012-12-12 ローム アンド ハース カンパニー アルカンを不飽和カルボン酸に変換するための改良法
WO2008136857A1 (en) * 2007-05-04 2008-11-13 Bp Corporation North America Inc. Process for the production of non-aromatic carboxylic acids
WO2009012040A1 (en) * 2007-07-16 2009-01-22 Exxonmobil Chemical Patents Inc. Manganese oxides and their use in the oxidation of alkanes
JP4822559B2 (ja) * 2007-09-19 2011-11-24 ローム アンド ハース カンパニー （メタ）アクリル酸生成物流からのプロピオン酸の選択的減少のための改良された方法
US7820854B2 (en) * 2008-03-19 2010-10-26 Rohm And Haas Company Process for converting alkanes to unsaturated carboxylic acids
SG10201602362XA (en) * 2011-03-25 2016-05-30 Rohm & Haas Steam Re-Calcination Of Mixed Metal Oxide Catalysts
US8921257B2 (en) * 2011-12-02 2014-12-30 Saudi Basic Industries Corporation Dual function partial oxidation catalyst for propane to acrylic acid conversion
JP6068617B2 (ja) * 2012-03-28 2017-01-25 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ エチレン及び酢酸の製造工程
WO2014167482A1 (en) * 2013-04-08 2014-10-16 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety
CN105143157B (zh) * 2013-04-24 2018-11-13 沙特基础工业公司 从天然资源产生产物
EP2988866B1 (de) 2013-04-24 2017-05-31 Saudi Basic Industries Corporation Katalysator zur selektiven synthese von niederen kohlenwasserstoffen aus syngas
US9636663B2 (en) 2013-04-24 2017-05-02 Saudi Basic Industries Corporation High productivity catalyst for alkane oxidation to unsaturated carboxylic acids and alkenes
WO2014174371A2 (en) 2013-04-24 2014-10-30 Saudi Basic Industries Corporation Supported catalyst for production of unsaturated carboxylic acids from alkanes
JP2016520096A (ja) 2013-05-20 2016-07-11 サウディ ベーシック インダストリーズ コーポレイション 酢酸及びアクリル酸の精製方法
CN103691457B (zh) * 2013-12-24 2016-04-27 济南开发区星火科学技术研究院 一种丙烷选择性氧化制备丙烯酸的催化剂及其制备方法
EP3178805B1 (de) * 2014-10-07 2021-09-29 LG Chem, Ltd. Verfahren und vorrichtung zur kontinuierlichen herstellung von acrylsäure mittels propanteiloxidierung
CN107866251B (zh) * 2016-09-23 2019-12-10 中国石油化工股份有限公司 用于均酐制备的催化剂
RU2644158C1 (ru) * 2016-12-19 2018-02-08 Федеральное государственное автономное образовательное учреждение высшего образования "Национальный исследовательский технологический университет "МИСиС" Способ получения акриловой кислоты
EP4342873A1 (de) 2022-09-26 2024-03-27 Linde GmbH Verfahren und anlage zur herstellung von ethylen und essigsäure, verfahren und anlage zur herstellung einer zielverbindung unter verwendung von ethylen und essigsäure

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2941007A (en) * 1957-06-10 1960-06-14 Standard Oil Co Process for the oxidation of olefins
CA1066686A (en) * 1974-04-25 1979-11-20 Alan Lauder Metal oxide catalytic compositions
US4049583A (en) * 1974-04-25 1977-09-20 E. I. Du Pont De Nemours And Company Metal oxide catalytic compositions having perovskite crystal structures and containing metals of the platinum group
US4182694A (en) * 1974-04-25 1980-01-08 E. I. Du Pont De Nemours & Company Ruthenium-containing perovskite catalysts
US4499301A (en) * 1979-04-20 1985-02-12 National Distillers And Chemical Corporation Process for the preparation of unsaturated aldehydes and carboxylic acids
US5162578A (en) * 1987-06-12 1992-11-10 Union Carbide Chemicals & Plastics Technology Corporation Acetic acid from ethane, ethylene and oxygen
US5198580A (en) * 1991-11-18 1993-03-30 The Standard Oil Company Process for oxidation of propane
KR960003792B1 (ko) * 1992-12-31 1996-03-22 한국과학기술원 신규한 다성분계 혼합산화물 촉매 조성물 및 그의 제조방법
JP3334296B2 (ja) * 1993-01-28 2002-10-15 三菱化学株式会社 不飽和カルボン酸の製造方法
EP0608838B1 (de) * 1993-01-28 1997-04-16 Mitsubishi Chemical Corporation Methode zur Herstellung einer ungesättigten Carbonsäure
TW295579B (de) * 1993-04-06 1997-01-11 Showa Denko Kk
DE19622331A1 (de) * 1996-06-04 1997-12-11 Basf Ag Verfahren der heterogen katalysierten Gasphasenoxidation von Propan zu Acrolein
JPH1017523A (ja) * 1996-07-01 1998-01-20 Mitsubishi Chem Corp 酢酸の製造方法
DE19630832A1 (de) 1996-07-31 1998-02-05 Hoechst Ag Verfahren zur selektiven Herstellung von Essigsäure
DE19717076A1 (de) 1997-04-23 1998-10-29 Hoechst Ag Katalysator und Verfahren zur katalytischen Oxidation von Ethan zu Essigsäure
JP3938225B2 (ja) * 1997-08-05 2007-06-27 旭化成ケミカルズ株式会社 触媒の調製方法
DE19745902A1 (de) * 1997-10-17 1999-04-22 Hoechst Ag Verfahren zur selektiven Herstellung von Essigsäure durch katalytische Oxidation von Ethan
GB9807142D0 (en) * 1998-04-02 1998-06-03 Bp Chem Int Ltd Catalyst and process utilising the catalyst
JP4166334B2 (ja) * 1998-07-24 2008-10-15 旭化成ケミカルズ株式会社 酸化用触媒の調製方法

Also Published As

Publication number Publication date
EP1140355B1 (de) 2006-05-03
EP1156877A1 (de) 2001-11-28
WO2000029105A1 (en) 2000-05-25
US6646158B1 (en) 2003-11-11
SA06260448B1 (ar) 2006-10-31
SA99626044B1 (ar) 2006-10-31
JP4809531B2 (ja) 2011-11-09
DE69931184D1 (de) 2006-06-08
ES2264284T3 (es) 2006-12-16
DE69935809T2 (de) 2007-12-27
EP1140355A1 (de) 2001-10-10
DE69931184T2 (de) 2007-02-08
US6160162A (en) 2000-12-12
SA99200360B1 (ar) 2006-10-11
CN1326378A (zh) 2001-12-12
DE69935809D1 (de) 2007-05-24
ES2284288T3 (es) 2007-11-01
JP2003511344A (ja) 2003-03-25
CN1145527C (zh) 2004-04-14
US6114278A (en) 2000-09-05
WO2000029106A1 (en) 2000-05-25
EP1156877B1 (de) 2007-04-11

Similar Documents

Publication Publication Date Title
ATE324941T1 (de) Katalytische oxidierung von alkanen zu zugehöriger säure
DK0705136T3 (da) Ny katalysator og fremgangsmåde til dehydrogenering af dehydrogenerbare carbonhydrider
AU2001240085A1 (en) Multi-zoned catalytic trap and methods of making and using the same
IT1318550B1 (it) Catalizzatore e processo per la sintesi diretta di acqua ossigenata.
DE69916078D1 (de) Molybdän-vanadin enthaltender katalysator für die selektive niedrig temperatur oxidation von propylen, seine herstellung und seine verwendung
ATE231516T1 (de) Herstellung von azithromycin
DE69924288D1 (de) Verfahren zur oxidation von in wasserstoff enthaltenem co
BG103001A (en) Oxidation catalyst
DE69932806D1 (de) Katalysator zur oxidation von ethan zu essigsäure
DE69403953D1 (de) Oxidationskatalysator
ES2161531T3 (es) Catalizador que comprende paladio y oro depositados sobre un vehiculo que contiene cobre para la produccion de acetato de vinilo.
AR015201A1 (es) Proceso para preparar acetato de vinilo.
TW429163B (en) Oxidazing catalyst system and an oxidation process by using the same
ATE81606T1 (de) Traegerkatalysatoren und ihre verwendung zur umwandlung von methan und zur dehydrogenierung von kohlenwasserstoffen.
BR9813104A (pt) Catalisador de acetato de vinila compreendendo paládio metálico e ouro, e acetato cúprico
DE69919545D1 (de) Katalysatorsysteme zur einstufigen gasphasenherstellung von essigsäure aus ethylen
DE69117479D1 (de) Verfahren zur umsetzung von methan zu höheren kohlenwasserstoffen
BR9813560A (pt) Catalisador à base de paládio, cádmio, metal alcalino e lantanóides e processo para preparação de acetato de vinila
SE9603323D0 (sv) Catalytic method and structure
DE50100315D1 (de) Verfahren zur Herstellung von 2,3,5-Trimethyl-p-benzochinon
ATE496122T1 (de) Thermostabile polymerase aus i thermococcus pacificus /i
Pescovitz Bioagent Chip.
DE3763197D1 (de) (meth)acrylsaeureestermodifizierte organopolysiloxane, verfahren zu ihrer herstellung und ihre verwendung als abhaesive beschichtungsmassen.
Ruscoe Bright ideas.
Fitzgerald Register kills column critical of Overholser.

Legal Events

Date Code Title Description
RER Ceased as to paragraph 5 lit. 3 law introducing patent treaties