DE69931184D1 - Katalytische oxidierung von alkanen zu zugehöriger säure - Google Patents

Katalytische oxidierung von alkanen zu zugehöriger säure

Info

Publication number
DE69931184D1
DE69931184D1 DE69931184T DE69931184T DE69931184D1 DE 69931184 D1 DE69931184 D1 DE 69931184D1 DE 69931184 T DE69931184 T DE 69931184T DE 69931184 T DE69931184 T DE 69931184T DE 69931184 D1 DE69931184 D1 DE 69931184D1
Authority
DE
Germany
Prior art keywords
alkanes
catalytic oxidation
subsequent acid
propane
acrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
DE69931184T
Other languages
English (en)
Other versions
DE69931184T2 (de
Inventor
Khalid Karim
Subrai Bhat
Irshad Zaheer
Bin Nafisah
Ahmed Khan
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Saudi Basic Industries Corp
Original Assignee
Saudi Basic Industries Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Saudi Basic Industries Corp filed Critical Saudi Basic Industries Corp
Publication of DE69931184D1 publication Critical patent/DE69931184D1/de
Application granted granted Critical
Publication of DE69931184T2 publication Critical patent/DE69931184T2/de
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6482—Vanadium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/648—Vanadium, niobium or tantalum or polonium
    • B01J23/6484—Niobium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/652—Chromium, molybdenum or tungsten
    • B01J23/6525—Molybdenum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/215—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of saturated hydrocarbyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
DE69931184T 1998-11-16 1999-11-15 Katalytische oxidierung von alkanen zu zugehöriger säure Expired - Lifetime DE69931184T2 (de)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US193015 1998-11-16
US09/193,015 US6114278A (en) 1998-11-16 1998-11-16 Catalysts for catalytic oxidation of propane to acrylic acid, methods of making and using the same
PCT/EP1999/009037 WO2000029105A1 (en) 1998-11-16 1999-11-15 Catalytic oxidation of alkanes to corresponding acids

Publications (2)

Publication Number Publication Date
DE69931184D1 true DE69931184D1 (de) 2006-06-08
DE69931184T2 DE69931184T2 (de) 2007-02-08

Family

ID=22711946

Family Applications (2)

Application Number Title Priority Date Filing Date
DE69931184T Expired - Lifetime DE69931184T2 (de) 1998-11-16 1999-11-15 Katalytische oxidierung von alkanen zu zugehöriger säure
DE69935809T Expired - Lifetime DE69935809T2 (de) 1998-11-16 1999-11-15 Katalysatoren für die katalytische oxidation von propan zu acrylsäure

Family Applications After (1)

Application Number Title Priority Date Filing Date
DE69935809T Expired - Lifetime DE69935809T2 (de) 1998-11-16 1999-11-15 Katalysatoren für die katalytische oxidation von propan zu acrylsäure

Country Status (9)

Country Link
US (3) US6114278A (de)
EP (2) EP1156877B1 (de)
JP (1) JP4809531B2 (de)
CN (1) CN1145527C (de)
AT (1) ATE324941T1 (de)
DE (2) DE69931184T2 (de)
ES (2) ES2264284T3 (de)
SA (3) SA99200360B1 (de)
WO (2) WO2000029105A1 (de)

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DE10051419A1 (de) * 2000-10-17 2002-04-18 Basf Ag Katalysator bestehend aus einem Trägerkörper und einer auf der Oberfläche des Trägerkörpers aufgebrachten katalytisch aktiven Oxidmasse
DE10118814A1 (de) 2001-04-17 2002-10-24 Basf Ag Verfahren zur Herstellung von Acrylsäure durch heterogen katalysierte Gasphasenoxidation von Propen mit molekularem Sauerstoff in einer Reaktionszone
KR100740728B1 (ko) 2000-06-14 2007-07-19 바스프 악티엔게젤샤프트 아크롤레인 및(또는) 아크릴산의 제조 방법
US6441227B1 (en) * 2000-06-23 2002-08-27 Saudi Basic Industries Corporation Two stage process for the production of unsaturated carboxylic acids by oxidation of lower unsaturated hydrocarbons
AU2001287622A1 (en) 2000-07-18 2002-01-30 Basf Aktiengesellschaft Method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane
US6403525B1 (en) 2000-09-28 2002-06-11 Rohm And Haas Company Promoted multi-metal oxide catalyst
KR100814702B1 (ko) 2000-09-28 2008-03-18 롬 앤드 하스 캄파니 불포화 니트릴 제조방법
US6407031B1 (en) 2000-09-28 2002-06-18 Rohm And Haas Company Promoted multi-metal oxide catalyst
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US6407280B1 (en) 2000-09-28 2002-06-18 Rohm And Haas Company Promoted multi-metal oxide catalyst
US6589907B2 (en) 2000-09-28 2003-07-08 Rohm And Haas Company Zn and/or Ga promoted multi-metal oxide catalyst
US6461996B2 (en) 2000-09-28 2002-10-08 Rohm And Haas Company Halogen promoted multi-metal oxide catalyst
US6943135B2 (en) 2001-04-12 2005-09-13 Rohm And Haas Company NOx treated mixed metal oxide catalyst
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US7229946B2 (en) * 2003-03-24 2007-06-12 Saudi Basic Industries Corporation Catalyst composition for the selective conversion of alkanes to unsaturated carboxylic acids, method of making and method of using thereof
US7019169B2 (en) 2003-09-23 2006-03-28 Basf Aktiengesellschaft Preparation of (meth)acrylic acid
US7012157B2 (en) 2003-09-23 2006-03-14 Basf Aktiengesellschaft Preparation of (meth)acrylic acid
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US20060020142A1 (en) * 2004-07-23 2006-01-26 Pessoa Cavalcanti Fernando A Catalytic (AMM)oxidation process for conversion of lower alkanes to carboxylic acids and nitriles
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FR2880346B1 (fr) * 2004-12-30 2007-02-23 Arkema Sa Procede de preparation d'acide acrylique a partir du propane en absence de vapeur d'eau
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JP4822559B2 (ja) * 2007-09-19 2011-11-24 ローム アンド ハース カンパニー （メタ）アクリル酸生成物流からのプロピオン酸の選択的減少のための改良された方法
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WO2012134898A2 (en) * 2011-03-25 2012-10-04 Rohm And Haas Company Steam re-calcination of mixed metal oxide catalysts
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US9492814B2 (en) * 2013-04-08 2016-11-15 Saudi Basic Industries Corporation Catalyst for conversion of propylene to product comprising a carboxylic acid moiety
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CN103691457B (zh) * 2013-12-24 2016-04-27 济南开发区星火科学技术研究院 一种丙烷选择性氧化制备丙烯酸的催化剂及其制备方法
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Also Published As

Publication number Publication date
EP1156877A1 (de) 2001-11-28
US6646158B1 (en) 2003-11-11
CN1326378A (zh) 2001-12-12
DE69935809T2 (de) 2007-12-27
ATE324941T1 (de) 2006-06-15
JP4809531B2 (ja) 2011-11-09
EP1156877B1 (de) 2007-04-11
EP1140355B1 (de) 2006-05-03
US6114278A (en) 2000-09-05
SA99200360B1 (ar) 2006-10-11
SA99626044B1 (ar) 2006-10-31
ES2284288T3 (es) 2007-11-01
WO2000029106A1 (en) 2000-05-25
WO2000029105A1 (en) 2000-05-25
DE69931184T2 (de) 2007-02-08
CN1145527C (zh) 2004-04-14
US6160162A (en) 2000-12-12
SA06260448B1 (ar) 2006-10-31
DE69935809D1 (de) 2007-05-24
EP1140355A1 (de) 2001-10-10
JP2003511344A (ja) 2003-03-25
ES2264284T3 (es) 2006-12-16

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