DE69117479D1 - Verfahren zur umsetzung von methan zu höheren kohlenwasserstoffen - Google Patents

Verfahren zur umsetzung von methan zu höheren kohlenwasserstoffen

Info

Publication number
DE69117479D1
DE69117479D1 DE69117479T DE69117479T DE69117479D1 DE 69117479 D1 DE69117479 D1 DE 69117479D1 DE 69117479 T DE69117479 T DE 69117479T DE 69117479 T DE69117479 T DE 69117479T DE 69117479 D1 DE69117479 D1 DE 69117479D1
Authority
DE
Germany
Prior art keywords
higher hydrocarbons
comprised
converting methane
methane
contact time
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
DE69117479T
Other languages
English (en)
Other versions
DE69117479T2 (de
Inventor
Henri Amariglio
Just Jacques Saint
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Engie SA
Original Assignee
Gaz de France SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gaz de France SA filed Critical Gaz de France SA
Publication of DE69117479D1 publication Critical patent/DE69117479D1/de
Application granted granted Critical
Publication of DE69117479T2 publication Critical patent/DE69117479T2/de
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/76—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by condensation of hydrocarbons with partial elimination of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • C07C2521/08—Silica
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/10—Magnesium; Oxides or hydroxides thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/12—Silica and alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/18—Carbon
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/02—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the alkali- or alkaline earth metals or beryllium
    • C07C2523/04—Alkali metals
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/06—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of zinc, cadmium or mercury
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/26—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/24—Chromium, molybdenum or tungsten
    • C07C2523/30—Tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • C07C2523/32—Manganese, technetium or rhenium
    • C07C2523/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/42—Platinum
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/44—Palladium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals
    • C07C2523/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of noble metals of the platinum group metals
    • C07C2523/46—Ruthenium, rhodium, osmium or iridium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/755—Nickel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S585/00—Chemistry of hydrocarbon compounds
    • Y10S585/929—Special chemical considerations
    • Y10S585/943—Synthesis from methane or inorganic carbon source, e.g. coal

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Fats And Perfumes (AREA)
  • Hydrogen, Water And Hydrids (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
DE69117479T 1990-07-20 1991-07-17 Verfahren zur umsetzung von methan zu höheren kohlenwasserstoffen Expired - Fee Related DE69117479T2 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR9009340A FR2664891B1 (fr) 1990-07-20 1990-07-20 Procede de conversion du methane en hydrocarbures superieurs.
PCT/FR1991/000589 WO1992001656A1 (fr) 1990-07-20 1991-07-17 Procede de conversion du methane en hydrocarbures superieurs

Publications (2)

Publication Number Publication Date
DE69117479D1 true DE69117479D1 (de) 1996-04-04
DE69117479T2 DE69117479T2 (de) 1996-10-02

Family

ID=9398966

Family Applications (1)

Application Number Title Priority Date Filing Date
DE69117479T Expired - Fee Related DE69117479T2 (de) 1990-07-20 1991-07-17 Verfahren zur umsetzung von methan zu höheren kohlenwasserstoffen

Country Status (12)

Country Link
US (1) US5414176A (de)
EP (1) EP0493574B1 (de)
AT (1) ATE134602T1 (de)
CA (1) CA2066271C (de)
DE (1) DE69117479T2 (de)
DK (1) DK0493574T3 (de)
FR (1) FR2664891B1 (de)
GR (1) GR3020032T3 (de)
MY (1) MY106544A (de)
NO (1) NO300320B1 (de)
NZ (1) NZ239040A (de)
WO (1) WO1992001656A1 (de)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2759695B1 (fr) * 1997-02-18 1999-05-07 Total Raffinage Distribution Procede de conversion d'alcanes legers en hydrocarbures superieurs
FR2766835B1 (fr) * 1997-08-04 1999-10-22 Total Raffinage Distribution Procede de conversion d'hydrocarbures legers gazeux en hydrocarbures superieurs
EP1063011B1 (de) * 1999-05-22 2001-12-12 OMG AG & Co. KG Verwendung eines Katalysators für die Dampfreformierung von Methanol
IT1317757B1 (it) 2000-02-03 2003-07-15 Enitecnologie Spa Metodo per la preparazione di idrocarburi idrogenati.
US6500313B2 (en) 2001-03-12 2002-12-31 Steven P. Sherwood Method for production of hydrocarbons
FR2840607A1 (fr) * 2002-06-10 2003-12-12 Bp Lavera Procede de conversion du methane en ethane
US20050045467A1 (en) * 2003-09-03 2005-03-03 King Fahd University Of Petroleum And Minerals Method for the conversion of methane into hydrogen and higher hydrocarbons using UV laser
IT1392390B1 (it) 2008-12-19 2012-03-02 Eni Spa Procedimento per la conversione di metano, contenuto in correnti gassose, in idrocarburi liquidi idrogenati
US10183267B2 (en) 2014-10-23 2019-01-22 Ashley Day Gas-to-liquids conversion process using electron beam irradiation
US10472303B2 (en) * 2017-08-30 2019-11-12 Uchicago Argonne, Llc Alkane activation with single and bi-metallic catalysts

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE505319C (de) * 1926-05-22 1900-01-01
US2537688A (en) * 1946-12-20 1951-01-09 Standard Oil Dev Co Method for synthesizing hydrocarbons and oxygenated compounds
US4009219A (en) * 1975-04-28 1977-02-22 Tamers Murry A Total synthesis of benzene from non-hydrocarbon materials
US4450310A (en) * 1983-03-04 1984-05-22 The Standard Oil Company Conversion of methane to olefins and hydrogen
US4599474A (en) * 1983-10-31 1986-07-08 Chevron Research Company Conversions of low molecular weight hydrocarbons to higher molecular weight hydrocarbons using a metal-containing catalyst
US4634800A (en) * 1984-04-16 1987-01-06 Atlantic Richfield Company Methane conversion process
US4801762A (en) * 1987-02-13 1989-01-31 Atlantic Richfield Company Methane conversion process
GB8724373D0 (en) * 1987-10-17 1987-11-18 British Petroleum Co Plc Chemical process
GB2213828A (en) * 1987-12-18 1989-08-23 Shell Int Research Process for the preparation of ethylene
US4962261A (en) * 1988-06-20 1990-10-09 Uop Process for upgrading methane to higher carbon number hydrocarbons
US4879427A (en) * 1988-12-29 1989-11-07 Atlantic Richfield Company Methane conversion
NZ234289A (en) * 1989-06-30 1992-03-26 Broken Hill Pty Co Ltd Catalyst for oxidative coupling of methane, containing clay and an oxide or carbonate of an alkaline earth metal

Also Published As

Publication number Publication date
NO300320B1 (no) 1997-05-12
NO920873D0 (no) 1992-03-05
CA2066271A1 (fr) 1992-01-21
DK0493574T3 (da) 1996-07-01
NZ239040A (en) 1992-12-23
GR3020032T3 (en) 1996-08-31
WO1992001656A1 (fr) 1992-02-06
FR2664891B1 (fr) 1992-11-06
CA2066271C (fr) 1997-11-25
US5414176A (en) 1995-05-09
MY106544A (en) 1995-06-30
FR2664891A1 (fr) 1992-01-24
NO920873L (no) 1992-03-05
ATE134602T1 (de) 1996-03-15
DE69117479T2 (de) 1996-10-02
EP0493574B1 (de) 1996-02-28
EP0493574A1 (de) 1992-07-08

Similar Documents

Publication Publication Date Title
DE3764844D1 (de) Mittel zur verhinderung von ablagerungen bei thermischen crackprozessen.
ES2188969T3 (es) Catalizadores homogeneos de oxidacion y de larga duracion.
DE69117479D1 (de) Verfahren zur umsetzung von methan zu höheren kohlenwasserstoffen
ATE324941T1 (de) Katalytische oxidierung von alkanen zu zugehöriger säure
IT1139029B (it) Procedimento per convertire carbone e,oppure frazioni petrolio pesanti ad idrogeno o gas di sintesi ammoniaca
BG101815A (en) Method for nitrogen oxides-containing waste gas scrubbing
DE3667795D1 (de) Mittel zur verhinderung von ablagerungen bei thermischen crackprozessen.
DE69417416D1 (de) Neuer katalysator und verfahren zum dehydrieren von dehydrierbaren kohlenwasserstoffen
ATE30334T1 (de) Mittel zur verhinderung von ablagerungen bei thermischen crackprozessen.
ES542240A0 (es) Un metodo de reducir la formacion de coque sobre las super- ficies metalicas en contacto con una corriente gaseosa que contiene hidrocarburos en un procedimiento de craqueo termi-co
ZA835538B (en) Process for the reaction of carbon monoxide with steam,with formation of carbon dioxide and hydrogen and use of a catalyst for this purpose
HUP9902411A2 (hu) Oxidációs katalizátor
ATE241576T1 (de) Carbid-nanofibrillen und verfahren zum herstellen derselben
ATE154764T1 (de) Oxidationskatalysator
AR246691A1 (es) Regeneracion o activacion de catalizadores de metales nobles empleando fluorhalocarburos o fluorhalohidrocarburos.
DE60005014D1 (de) Verfahren zur herstellung von kohlenwasserstoffen mit verwendung von methan
TR200000452T2 (tr) Aromatik aminler üretilmesine yönelik işlem.
DE3764521D1 (de) Mittel zur verhinderung von ablagerungen bei thermischen crackprozessen.
ATE81606T1 (de) Traegerkatalysatoren und ihre verwendung zur umwandlung von methan und zur dehydrogenierung von kohlenwasserstoffen.
GB1509100A (en) Metallic catalyst support
DK118494A (da) Fremgangsmåde til dekomponering af ammoniak i en ammoniakholdig gas
AR246757A1 (es) Un proceso para el craqueo catalitico de hidrocarburos.
IT1252302B (it) Procedimento per la combustione catalitica del metano
Stanford Yttrium Gives Ferritic Steel Exceptional Properties
DK583085A (da) Konvertering af methan

Legal Events

Date Code Title Description
8364 No opposition during term of opposition
8339 Ceased/non-payment of the annual fee