AR081778A1 - Derivados y los herbicidas de 6-acil-1,2,4-triazina-3,5-diona - Google Patents
Derivados y los herbicidas de 6-acil-1,2,4-triazina-3,5-dionaInfo
- Publication number
- AR081778A1 AR081778A1 ARP110102275A ARP110102275A AR081778A1 AR 081778 A1 AR081778 A1 AR 081778A1 AR P110102275 A ARP110102275 A AR P110102275A AR P110102275 A ARP110102275 A AR P110102275A AR 081778 A1 AR081778 A1 AR 081778A1
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- C07D253/02—Heterocyclic compounds containing six-membered rings having three nitrogen atoms as the only ring hetero atoms, not provided for by group C07D251/00 not condensed with other rings
- C07D253/06—1,2,4-Triazines
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- C07D401/14—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing three or more hetero rings
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- A—HUMAN NECESSITIES
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- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
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- A—HUMAN NECESSITIES
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- A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
- A01N43/66—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
- A01N43/68—1,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
- A01N43/70—Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
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- A01N43/707—1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
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- A01N43/74—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms five-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,3
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- A01N43/84—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with nitrogen atoms and oxygen or sulfur atoms as ring hetero atoms six-membered rings with one nitrogen atom and either one oxygen atom or one sulfur atom in positions 1,4
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- C07D253/06—1,2,4-Triazines
- C07D253/065—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members
- C07D253/07—1,2,4-Triazines having three double bonds between ring members or between ring members and non-ring members with hetero atoms, or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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- C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
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- C07D417/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings directly linked by a ring-member-to-ring-member bond
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- C07D417/08—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing alicyclic rings
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- C07D417/10—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a carbon chain containing aromatic rings
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- C07D417/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings
- C07D417/12—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing two hetero rings linked by a chain containing hetero atoms as chain links
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- C07D417/14—Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/00 containing three or more hetero rings
Abstract
Se revelan los compuestos que exhiben suficiente actividad herbicida en bajas dosis de aplicación, cuando se aplican al suelo y al follaje, y una composición agroquímica que utiliza los mismos, en particular los herbicidas.Reivindicación 1: Un derivado de la triazina o una sal de la misma representada por la fórmula [1] [en la fórmula, R1 representa un átomo de hidrógeno; un grupo alquilo C1-12; un grupo alquenilo C2-6; un grupo alquinilo C2-6; un grupo cicloalquilo C3-6; un grupo cicloalquenilo C3-6; un grupo cicloalquilo C3-6alquilo C1-6; un grupo halo-alquilo C1-6; un grupo halo-alquenilo C2-6; un grupo halo-alquinilo C2-6; un grupo halo-cicloalquilo C3-6; un grupo halocicloalquilo C3-6alquilo C1-6; un grupo aminoalquilo C1-6; un grupo nitroalquilo C1-6; un grupo alquilamino C1-6alquilo C1-6; un di(alquil C1-6)aminoalquilo C1-6; un grupo alquiltio C1-6alquilo C1-6; un grupo alquilsulfinilo C1-6alquilo C1-6; un grupo alquilsulfonilo C1-6alquilo C1-6; un grupo haloalquiltio C1-6alquilo C1-6; un grupo haloalquilsulfinilo C1-6alquilo C1-6; un grupo haloalquilsulfonilo C1-6alquilo C1-6; un grupo alcoxi C1-6alquilo C1-6; un grupo hidroxialquilo C1-6; un grupo fenilo-alcoxi C1-6alquilo C1-6 (el fenilo en el grupo puede ser substituido con un grupo substituyente seleccionado del Grupo substituyente a o los grupos 2 a 5 substituyentes que son los mismos o diferentes el uno del otro y seleccionados del Grupo substituyente a); un grupo alcoxi C1-6alcoxi C1-6alquilo C1-6; un grupo cicloalquiloxi C3-6alquilo C1-6; un grupo cicloalquilo C3-6alquiloxi C1-6alquilo C1-6; un grupo feniloxi-alquilo C1-6 (el fenilo en el grupo puede ser substituido con 1 a 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); un grupo feniltio-alquilo C1-6 (el fenilo en el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); un grupo fenilsulfinilo-alquilo C1-6 (el fenilo en el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); un grupo fenilsulfonilo-alquilo C1-6 (el fenilo en el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); un grupo haloalcoxi C1-6alquilo C1-6; el grupo fenilo, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilo-alquilo C1-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilo-alquenilo C2-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilo-alquinilo C2-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo alcoxiimino C1-6alquilo C1-6; un grupo fenoxiimino-alquilo C1-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo di(alcoxi C1-6)alquilo C1-6; un grupo (R31R32N-C=O)alquilo C1-6; un grupo alcoxicarbonilo C1-6alquilo C1-6; un grupo alquilcarbonilo C1-6alquilo C1-6; un grupo alquilcarboniloxi C1-6alquilo C1-6; un grupo alquilideno C1-6aminooxi-alquilo C1-6; un grupo formilo-alquilo C1-6; un grupo alquiltio C1-6alcoxi C1-6alquilo C1-6; un grupo alquilsulfinilo C1-6alcoxi C1-6alquilo C1-6; un grupo alquilsulfonilo C1-6alcoxi C1-6alquilo C1-6; un grupo ciano-alcoxi C1-6alquilo C1-6; un grupo ciano-alquilo C1-6; un grupo alquilideno C2-6amino; un grupo di(alquil C1-10)amino-alquiliden C1-6amino; un grupo NR31R32; un grupo alcoxi C1-6; un grupo alqueniloxi C2-6; un grupo alqueniloxi C2-6; un grupo cicloalquiloxi C3-6; un grupo cicloalquilo C3-6alquiloxi C1-6; un grupo haloalcoxi C1-6; un grupo heterocíclico que contiene de 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno [el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a, y cuando el heteroátomo en el grupo heterocíclico es un átomo de azufre, el átomo de azufre puede ser oxidado al sulfóxido o la sulfona]; un grupo alquilo C1-6 substituido con un grupo heterocíclico que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno [el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a]; un grupo alcoxi C1-6alquilo C1-6 substituido con un grupo heterocíclico que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno [el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a]; o un grupo alcoxi C1-6alquilo C1-6 substituido con un grupo heterocíclico-oxi en el cual el grupo heterocíclico en el grupo heterocíclico-oxi que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno [el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a]; R2 representa un átomo de hidrógeno; un grupo alquilo C1-6; un grupo alquenilo C2-6; un grupo alquinilo C2-6; un grupo cicloalquilo C3-6; un grupo haloalquilo C1-6; un grupo haloalquenilo C2-6; un grupo haloalquinilo C2-6; un grupo alcoxi C1-6alquilo C1-6; un grupo cicloalquiloxi C3-6alquilo C1-6; un grupo di(alcoxi C1-6)alquilo C1-6; un grupo heterocíclico que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo de nitrógeno (el grupo puede ser substituido con 1 hasta 5 substituyentes idénticos o diferentes seleccionados del grupo substituyente a); el grupo fenilo, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenil-alquilo C1-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenil-alquenilo C2-6 el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; o un grupo fenil-alquinilo C2-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; Y y Z representan un átomo de oxígeno o un átomo de azufre; A representa cualquiera de las fórmulas (A-1) a la (A-5); R4 representa un grupo hidroxilo; O-M+ (M+ representa un catión de metal alcali o un catión de amoniaco); un grupo amino; un átomo de halógeno; un grupo ciano; un grupo isotiocianato; un grupo isocianato; un grupo hidroxicarboniloxi; un grupo alcoxicarboniloxi C1-6; un grupo benciloxicarboniloxi, el cual puede ser substituido con un substituyente del grupo seleccionado desde el grupo substituyente a; un grupo alcoxi C1-6; un grupo alqueniloxi C2-6; un grupo alqueniloxi C2-6; un grupo cicloalquiloxi C3-6; un grupo cianometilenoxi; un grupo cicloalquilo C3-6alquiloxi C1-6; un grupo alquilcarbonil C1-6oxi; un grupo haloalquilcarboniloxi C1-6; un grupo alquenilcarboniloxi C2-6; un grupo haloalquenilcarboniloxi C2-6; un grupo alquinilocarboniloxi C2-6; un grupo haloalquinilocarboniloxi C2-6; un grupo alcoxicarbonilo C1-6alcoxi C1-6; un grupo feniloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo benciloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilcarboniloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo bencil carboniloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo fenilcarbonil-alquiloxi C1-6, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo alquilsulfoniloxi C1-10; un grupo haloalquilsulfoniloxi C1-6; un grupo fenilsulfoniloxi el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo bencilsulfoniloxi, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo alquiltio C1-10; un grupo alquilsulfinilo C1-10; un grupo alquilsulfonilo C1-10; un grupo haloalquiltio C1-6; un grupo haloalquilsulfinilo C1-6; un grupo haloalquilsulfonilo C1-6; un grupo alqueniltio C2-6; un grupo alquenilsulfinilo C2-6; un grupo alquenilsulfonilo C2-6; un grupo alquinilotio C2-6; un grupo alquinilsulfinilo C2-6; un grupo alquinilsulfonilo C2-6; un grupo feniltio, el cual puede ser substituido con uno o más substituyentes seleccionados del grupo substituyente a; un grupo benciltio, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo fenilsulfinilo, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo bencilsulfinilo, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo fenilsulfonilo, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo bencilsulfonilo, el cual puede ser substituido con uno o más substituyentes seleccionados desde el grupo substituyente a; un grupo alquilamino C1-10; un grupo di(alquil C1-10)amino; un grupo alcoxicarbonil C1-6amino; un grupo alcoxi C1-6 substituido con un grupo heterocíclico que contiene desde 3 hasta 10 átomos de carbono y uno o más heteroátomos idénticos o diferentes seleccionados desde un átomo de oxígeno, un átomo de azufre, y un átomo d
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