AR069820A2 - Un catalizador de oxidacion y un proceso para preparar un producto que comprende n-( fosfonometil)glicina o una sal del mismo - Google Patents
Un catalizador de oxidacion y un proceso para preparar un producto que comprende n-( fosfonometil)glicina o una sal del mismoInfo
- Publication number
- AR069820A2 AR069820A2 ARP080100812A ARP080100812A AR069820A2 AR 069820 A2 AR069820 A2 AR 069820A2 AR P080100812 A ARP080100812 A AR P080100812A AR P080100812 A ARP080100812 A AR P080100812A AR 069820 A2 AR069820 A2 AR 069820A2
- Authority
- AR
- Argentina
- Prior art keywords
- catalyst
- carbon
- noble metal
- promoter
- measured
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 title abstract 11
- 238000000034 method Methods 0.000 title abstract 4
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 title 2
- 239000004471 Glycine Substances 0.000 title 1
- 150000003839 salts Chemical class 0.000 title 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 10
- 229910052799 carbon Inorganic materials 0.000 abstract 10
- 229910000510 noble metal Inorganic materials 0.000 abstract 5
- 238000010438 heat treatment Methods 0.000 abstract 4
- 239000001257 hydrogen Substances 0.000 abstract 4
- 229910052739 hydrogen Inorganic materials 0.000 abstract 4
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 2
- 125000004432 carbon atom Chemical group C* 0.000 abstract 2
- 238000000151 deposition Methods 0.000 abstract 2
- 239000007800 oxidant agent Substances 0.000 abstract 2
- 230000001590 oxidative effect Effects 0.000 abstract 2
- 239000001301 oxygen Substances 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 125000004430 oxygen atom Chemical group O* 0.000 abstract 2
- 238000004611 spectroscopical analysis Methods 0.000 abstract 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 abstract 1
- 230000008021 deposition Effects 0.000 abstract 1
- 239000001307 helium Substances 0.000 abstract 1
- 229910052734 helium Inorganic materials 0.000 abstract 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 abstract 1
- 150000002431 hydrogen Chemical class 0.000 abstract 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
- B01J21/18—Carbon
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/40—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals of the platinum group metals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/582—Recycling of unreacted starting or intermediate materials
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Catalysts (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
Un catalizador de oxidacion que comprende un soporte de carbon, un metal noble y un promotor, en donde: a) el metal noble y el promotor están en una superficie del soporte de carbon, donde el catalizador produce menos de 0,5 mmol de monoxido de carbono por gramo de catalizador cuando se calienta una muestra seca del catalizador, después que ha sido calentado a una temperatura de aproximadamente 500sC durante aproximadamente 1 hora en una atmosfera de hidrogeno y antes de ser expuesto a un oxidante seguido de calentamiento en la atmosfera de hidrogeno, se calienta en una atmosfera de helio desde aproximadamente 20 a aproximadamente 900sC a una velocidad de aproximadamente 10sC por minuto, y luego a aproximadamente 900sC durante aproximadamente 30 minutos; el promotor constituye por lo menos 0,05% por peso del catalizador, y el soporte de carbon tiene un área de superficie específica de aproximadamente 10 a aproximadamente 3000 m2/g, como es medido por el método de Brunauer-Emmett-Teller; y/o b) él soporte de carbon tiene un metal noble, el promotor, carbon y oxígeno en una superficie del mismo, el catalizador tiene una relacion de átomos de carbono respecto de los átomos de oxígeno de por lo menos aproximadamente 30:1 en la superficie, segun lo medido por espectroscopía fotoelectronica de rayos X, después de calentar el catalizador a una temperatura de aproximadamente 500sC durante aproximadamente 1 hora en una atmosfera de hidrogeno y antes de exponer el catalizador a un oxidante a continuacion del calentamiento en la atmosfera de hidrogeno, el promotor constituye por lo menos el 0,05% por peso del catalizador, y el soporte de carbon tiene un área de superficie específica de aproximadamente 10 a aproximadamente 3000 m2/g, como es medido por el método de Brunauer-Emmett-Teller; y/o c) el catalizador se prepara mediante un proceso que comprende depositar un metal noble en una superficie de un soporte de carbon y después calentar la superficie a una temperatura de por lo menos aproximadamente 400sC, antes de la deposicion del metal noble, el soporte de carbon tiene carbono y oxígeno en su superficie en cantidades tales que la proporcion de átomos de carbono respecto de los átomos de oxígeno de la superficie es de por lo menos aproximadamente 20:1, segun lo medido mediante espectroscopía fotoelectronica de rayos X.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US7598898P | 1998-02-25 | 1998-02-25 | |
| US09/248,655 US6417133B1 (en) | 1998-02-25 | 1999-02-11 | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| AR069820A2 true AR069820A2 (es) | 2010-02-24 |
Family
ID=26757505
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP990100768A AR013023A1 (es) | 1998-02-25 | 1999-02-24 | Un proceso para preparar n-(fosfonometil) glicina o una sal del mismo, |
| ARP040100336A AR043018A2 (es) | 1998-02-25 | 2004-02-03 | Un catalizador de oxidacion y un proceso para preparar un producto que comprende n-(fosfonometil) glicina o una sal del mismo |
| ARP080100812A AR069820A2 (es) | 1998-02-25 | 2008-02-27 | Un catalizador de oxidacion y un proceso para preparar un producto que comprende n-( fosfonometil)glicina o una sal del mismo |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ARP990100768A AR013023A1 (es) | 1998-02-25 | 1999-02-24 | Un proceso para preparar n-(fosfonometil) glicina o una sal del mismo, |
| ARP040100336A AR043018A2 (es) | 1998-02-25 | 2004-02-03 | Un catalizador de oxidacion y un proceso para preparar un producto que comprende n-(fosfonometil) glicina o una sal del mismo |
Country Status (20)
| Country | Link |
|---|---|
| US (4) | US6417133B1 (es) |
| EP (1) | EP1060017A1 (es) |
| JP (1) | JP2002504427A (es) |
| KR (1) | KR20010041349A (es) |
| CN (2) | CN1962673B (es) |
| AR (3) | AR013023A1 (es) |
| AU (1) | AU761345B2 (es) |
| BR (2) | BRPI9908252B1 (es) |
| CA (2) | CA2321923C (es) |
| CZ (1) | CZ20003020A3 (es) |
| EA (1) | EA200000869A1 (es) |
| HU (1) | HUP0101891A3 (es) |
| ID (1) | ID26942A (es) |
| IL (1) | IL138081A0 (es) |
| MX (2) | MX264644B (es) |
| PL (1) | PL342499A1 (es) |
| SK (1) | SK12562000A3 (es) |
| TR (1) | TR200002459T2 (es) |
| WO (1) | WO1999043430A1 (es) |
| ZA (1) | ZA991496B (es) |
Families Citing this family (67)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6232494B1 (en) * | 1998-02-12 | 2001-05-15 | Monsanto Company | Process for the preparation of N-(phosphonomethyl)glycine by oxidizing N-substituted N-(phosphonomethyl)glycine |
| US6417133B1 (en) | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
| WO2000001707A1 (en) * | 1998-07-06 | 2000-01-13 | Syngenta Participations Ag. | Preparation of n-phosphonomethylglycine salts |
| WO2001046208A2 (en) | 1999-12-21 | 2001-06-28 | Monsanto Technology Llc | Use of a supplemental promoter in conjunction with a carbon-supported, noble-metal-containing catalyst in liquid phase oxidation reactions |
| US6376708B1 (en) | 2000-04-11 | 2002-04-23 | Monsanto Technology Llc | Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts |
| WO2001087827A1 (en) | 2000-05-15 | 2001-11-22 | Monsanto Technology Llc | Preparation of iminodiacetic acid compounds from monoethanolamine substrates |
| US6927304B2 (en) | 2000-05-22 | 2005-08-09 | Monsanto Technology Llc | De-oxygenation treatment for noble metal on carbon catalysts used in liquid phase oxidation reactions |
| DK1283841T3 (da) * | 2000-05-22 | 2006-04-10 | Monsanto Technology Llc | Reaktionssystem til fremstilling af N-(phosphonomethyl)glycinforbindelser |
| US6818450B2 (en) | 2001-05-22 | 2004-11-16 | Monsanto Technology Llc | Use of infrared spectroscopy for on-line process control and endpoint detection |
| JP4069242B2 (ja) * | 2001-06-04 | 2008-04-02 | 株式会社日本触媒 | 金属粒子担持体及びカルボン酸エステルの製造方法 |
| DE10226073B8 (de) * | 2001-06-13 | 2007-10-18 | Honda Giken Kogyo K.K. | Elektrode für eine ein Festpolymerelektrolyt aufweisende Brennstoffzelle und Herstellungsverfahren dafür |
| US20030217967A1 (en) * | 2001-08-23 | 2003-11-27 | The Procter & Gamble Company | Processes for manufacturing water filter materials and water filters |
| AU2002362929B2 (en) | 2001-10-18 | 2007-08-09 | Monsanto Technology Llc | Process and catalyst for dehydrogenating primary alcohols to make carboxylic acid salts |
| ES2294075T3 (es) * | 2001-12-07 | 2008-04-01 | Basf Se | Procedimiento para la obtencion de catalizadores de rutenio/hierro sobre soportes de carbono. |
| US6706658B2 (en) * | 2001-12-21 | 2004-03-16 | Engelhard Corporation | Catalyst for purification of aromatic acids |
| US6720283B2 (en) * | 2002-01-03 | 2004-04-13 | Dalian Institute Of Chemical Physics | Activated carbon supported cobalt based catalyst for direct conversion of synthesis gas to diesel fuels |
| WO2003068387A1 (en) * | 2002-02-14 | 2003-08-21 | Monsanto Technology Llc | Oxidation catalyst and process for its preparation and process for oxidation using it |
| US7390920B2 (en) * | 2002-02-14 | 2008-06-24 | Monsanto Technology Llc | Oxidation catalyst and process |
| JP4202047B2 (ja) * | 2002-05-24 | 2008-12-24 | 富士通株式会社 | ヘッド位置制御方法及びデイスク記憶装置 |
| CN1674986A (zh) * | 2002-06-28 | 2005-09-28 | 孟山都技术公司 | 碲在液相氧化反应用碳担载的含贵金属催化剂中的应用 |
| US7312174B2 (en) * | 2002-09-09 | 2007-12-25 | The Board Of Trustees Of The University Of Illinois | Method for preparing highly loaded, highly dispersed platinum metal on a carbon substrate |
| US20040101718A1 (en) * | 2002-11-26 | 2004-05-27 | Lixin Cao | Metal alloy for electrochemical oxidation reactions and method of production thereof |
| JP2006518665A (ja) * | 2003-02-13 | 2006-08-17 | イー・アイ・デュポン・ドウ・ヌムール・アンド・カンパニー | 電極触媒および製造方法 |
| US20040192546A1 (en) * | 2003-03-27 | 2004-09-30 | Zhongyuan Dang | Catalyst for the low temperature oxidation of methane |
| EP1491253A1 (en) * | 2003-06-26 | 2004-12-29 | Urea Casale S.A. | Fluid bed granulation process and apparatus |
| WO2005009509A2 (en) * | 2003-07-22 | 2005-02-03 | Georgia Tech Research Corporation | Needle insertion systems and methods |
| WO2005016519A1 (en) | 2003-08-14 | 2005-02-24 | Monsanto Technology Llc | Transition metal-carbide and nitride containing catalysts , their preparation and use as oxidation and dehydrogenation catalysts |
| TW200524949A (en) * | 2003-09-17 | 2005-08-01 | Monsanto Technology Llc | Process for recovering a crystalline product from solution |
| CA2560069C (en) * | 2004-03-15 | 2012-10-30 | Cabot Corporation | Modified carbon products, their use in fuel cells and similar devices and methods relating to the same |
| CN100372857C (zh) * | 2004-05-12 | 2008-03-05 | 江苏好收成韦恩农药化工有限公司 | N-膦酰基甲基甘氨酸的生产方法 |
| WO2006031938A2 (en) * | 2004-09-15 | 2006-03-23 | Monsanto Technology Llc | Oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
| AR054096A1 (es) * | 2004-11-12 | 2007-06-06 | Monsanto Technology Llc | Recuperacion de metales nobles de corrientes de proceso acuosas y proceso de preparacion de n-(fosfonometil)-glicina |
| CN101583425A (zh) * | 2005-02-17 | 2009-11-18 | 孟山都技术公司 | 含过渡金属的催化剂、包含含过渡金属的催化剂的催化剂组合物、它们的制备方法和作为氧化催化剂的用途 |
| US8198479B2 (en) * | 2005-02-17 | 2012-06-12 | Monsanto Technology Llc | Transition metal-containing catalysts and catalyst combinations including transition metal-containing catalysts and processes for their preparation and use as oxidation catalysts |
| EP1852180A4 (en) * | 2005-02-21 | 2010-10-13 | Nissan Motor | ELECTRODE CATALYST AND METHOD FOR MANUFACTURING THE SAME |
| CN102792969B (zh) * | 2005-03-04 | 2015-01-21 | 孟山都技术公司 | 减轻用除草剂草甘膦制剂处理的草甘膦耐受性转基因棉花植物内的坏死 |
| BRPI0607713A2 (pt) * | 2005-04-01 | 2009-09-22 | Monsanto Technology Llc | métodos para monitorar ou detectar a conversão do ácido n-(fosfonometil) iminodiacético para n-(fosfonometil)glicina ou outro intermediário para n-(fosfonometil)glicina no curso da oxidação catalìtica de ácido n-(fosfonometil)iminodiacético em um meio aquoso |
| US7390471B2 (en) * | 2005-11-17 | 2008-06-24 | Siemens Power Generation, Inc. | Apparatus and method for catalytic treatment of exhaust gases |
| CA2642226A1 (en) * | 2006-02-17 | 2007-08-30 | Monsanto Technology Llc | Transition metal-containing catalysts and processes for their preparation and use as fuel cell catalysts |
| US7842639B2 (en) * | 2006-05-19 | 2010-11-30 | The United States Of America As Represented By The Administrator Of The National Aeronautics And Space Administration | Mechanical alloying of a hydrogenation catalyst used for the remediation of contaminated compounds |
| US20090215615A1 (en) * | 2006-07-11 | 2009-08-27 | 3M Innovative Properties Company | Method of forming supported nanoparticle catalysts |
| US9193613B2 (en) | 2006-10-03 | 2015-11-24 | Siemens Energy, Inc. | pH control to enable homogeneous catalytic wet air oxidation |
| WO2008085571A2 (en) * | 2006-10-11 | 2008-07-17 | Applied Technology Limited Partnership | Carbon black monolith, carbon black monolith catalyst, methods for making same, and uses thereof |
| US9315401B2 (en) | 2007-01-22 | 2016-04-19 | Siemens Energy, Inc. | Wet air oxidation process using recycled copper catalyst |
| US7771494B2 (en) * | 2007-01-31 | 2010-08-10 | Monsanto Technology Llc | Process for selective removal of water and impurities from N-(phosphonomethyl)glycine |
| US20090264277A1 (en) * | 2007-04-17 | 2009-10-22 | Dr. Rishi Raj | Picoscale catalysts for hydrogen catalysis |
| WO2009029539A1 (en) * | 2007-08-24 | 2009-03-05 | Monsanto Technology Llc | Mixtures and catalyst systems including transition metal-containing catalysts and noble metal-containing catalysts, processes for their preparation, and processes for their use in oxidation reactions |
| CA2720348A1 (en) * | 2008-04-03 | 2009-10-08 | Siemens Water Technologies Corp. | Catalytic wet oxidation systems and methods |
| US8252953B2 (en) | 2008-05-01 | 2012-08-28 | Monsanto Technology Llc | Metal utilization in supported, metal-containing catalysts |
| CA2725434C (en) * | 2008-05-01 | 2017-02-28 | Monsanto Technology Llc | Metal utilization in supported, metal-containing catalysts |
| US20100055422A1 (en) * | 2008-08-28 | 2010-03-04 | Bob Kong | Electroless Deposition of Platinum on Copper |
| JP2010247079A (ja) * | 2009-04-16 | 2010-11-04 | Denso Corp | 排ガス浄化触媒の製造方法 |
| US8669396B2 (en) | 2009-05-18 | 2014-03-11 | Monsanto Technology Llc | Recovery of phosphorus values and salt impurities from aqueous waste streams |
| US8211821B2 (en) | 2010-02-01 | 2012-07-03 | Celanese International Corporation | Processes for making tin-containing catalysts |
| CN102416322A (zh) * | 2010-11-23 | 2012-04-18 | 郴州高鑫铂业有限公司 | 氧化合成草甘膦Pd-M/C三元合金催化剂及制备方法 |
| CN103562126A (zh) | 2011-02-18 | 2014-02-05 | 西门子能量股份有限公司 | 使用再生碘溶液将硫化氢转化为硫 |
| SG11201607687WA (en) * | 2014-04-29 | 2016-10-28 | Rennovia Inc | Carbon black based shaped porous products |
| WO2015167667A1 (en) * | 2014-04-30 | 2015-11-05 | Exxonmobil Chemical Patents Inc. | Method of improving metal-impregnated catalyst performance |
| EP3235564A4 (en) * | 2014-12-18 | 2018-07-25 | Kao Corporation | Method for preparing catalyst |
| US10562841B2 (en) | 2015-10-01 | 2020-02-18 | Monsanto Technology Llc | Process for catalytic hydrogenation of halonitroaromatics |
| BR112019027682A2 (pt) | 2017-06-26 | 2020-09-15 | Monsanto Technology Llc | controle de fósforo para fluxos de resíduos provenientes de processos de produção de glifosato |
| CN108837822A (zh) * | 2018-06-20 | 2018-11-20 | 江苏龙净科杰环保技术有限公司 | 以泡沫钛为载体的板式脱硝催化剂及其制备方法 |
| CN109046337B (zh) * | 2018-08-01 | 2021-08-17 | 西安凯立新材料股份有限公司 | 一种亚胺培南用钯炭催化剂的制备方法 |
| CN109796491A (zh) * | 2018-12-24 | 2019-05-24 | 荆州鸿翔化工有限公司 | 一种制备草甘膦的方法 |
| US11648328B2 (en) | 2020-03-28 | 2023-05-16 | Ecocatalytic Inc. | Disinfecting device |
| KR20220091754A (ko) * | 2020-12-24 | 2022-07-01 | 현대자동차주식회사 | 인터메탈릭 촉매 및 이의 제조 방법 |
| CN112619641A (zh) * | 2020-12-30 | 2021-04-09 | 珠海格力电器股份有限公司 | 一种贵金属催化剂及其制备工艺 |
Family Cites Families (65)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3340097A (en) | 1964-01-22 | 1967-09-05 | Air Prod & Chem | Fuel cell electrode having surface co-deposit of platinum, tin and ruthenium |
| US3799758A (en) | 1971-08-09 | 1974-03-26 | Monsanto Co | N-phosphonomethyl-glycine phytotoxicant compositions |
| US3950402A (en) | 1972-05-31 | 1976-04-13 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
| US3954848A (en) | 1972-05-31 | 1976-05-04 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
| GB1436843A (en) | 1972-07-21 | 1976-05-26 | Ici Ltd | Preparation of n-phosphonomethyl-glycine |
| US3835000A (en) | 1972-12-21 | 1974-09-10 | Monsanto Co | Electrolytic process for producing n-phosphonomethyl glycine |
| US3969398A (en) | 1974-05-01 | 1976-07-13 | Monsanto Company | Process for producing N-phosphonomethyl glycine |
| US3927080A (en) | 1974-09-03 | 1975-12-16 | Monsanto Co | Process for producing N-phosphonomethyl glycine |
| FR2305420A1 (fr) | 1975-03-28 | 1976-10-22 | Rhone Poulenc Ind | Procede de preparation d'hydroxybenzaldehydes |
| US4264776A (en) | 1976-01-02 | 1981-04-28 | Monsanto Company | Production of secondary amines |
| ES465139A1 (es) | 1976-12-20 | 1978-10-01 | Monsanto Co | Un procedimiento para preparar una mono-o disal de n-fosfo- nometilglicina. |
| GB1601715A (en) | 1977-03-03 | 1981-11-04 | Engelhard Min & Chem | Method of preparing activated graphite and catalysts based thereon |
| US4190605A (en) | 1978-06-30 | 1980-02-26 | The Dow Chemical Company | Catalyst activation in oxidation process |
| US4186110A (en) * | 1978-07-03 | 1980-01-29 | United Technologies Corporation | Noble metal-refractory metal alloys as catalysts and method for making |
| HU184168B (en) | 1979-05-11 | 1984-07-30 | Mta Koezponti Kemiai Kutato In | Process for producing n-bracket-phosphono-methyl-bracket closed-glycine |
| EP0055695A1 (de) | 1980-12-30 | 1982-07-07 | Ciba-Geigy Ag | Verfahren zur Herstellung von N-phosphonomethylglycin |
| US4415479A (en) | 1981-10-29 | 1983-11-15 | Standard Oil Company (Indiana) | Palladium on carbon catalyst for purification of crude terephthalic acid |
| US4525294A (en) | 1981-11-13 | 1985-06-25 | Exxon Research And Engineering Co. | Amino acid mixtures, their alkali metal salts and process for preparing same |
| US4551657A (en) | 1981-12-10 | 1985-11-05 | General Electric Company | Format reconfigurable CRT display |
| IL66824A0 (en) | 1982-06-25 | 1982-12-31 | Geshuri Lab Ltd | Process for producing n-phosphonomethylglycine derivatives and herbicidal compounds and compositions prepared thereby |
| IL68716A (en) | 1983-05-17 | 1987-03-31 | Geshuri Lab Ltd | Process for producing n-phosphonomethylglycine |
| US4654429A (en) | 1983-12-02 | 1987-03-31 | Monsanto Company | Process for the preparation of a glyphosate product |
| US4624937A (en) | 1984-05-10 | 1986-11-25 | Monsanto Company | Process for removing surface oxides from activated carbon catalyst |
| US5079107A (en) | 1984-06-07 | 1992-01-07 | Giner, Inc. | Cathode alloy electrocatalysts |
| US4775498A (en) | 1984-12-05 | 1988-10-04 | Monsanto Company | Process for preparing N,N-diacetic acid aminomethylenephosphonic acid |
| US4579689A (en) * | 1985-02-11 | 1986-04-01 | Monsanto Company | Oxidation with coated catalyst |
| US4582650A (en) | 1985-02-11 | 1986-04-15 | Monsanto Company | Oxidation with encapsulated co-catalyst |
| US4921991A (en) | 1985-02-22 | 1990-05-01 | Guy Lacroix | Preparation of esters of the N-phosphonomethylglycine and the N-phosphonomethyl glycines |
| US4696772A (en) | 1985-02-28 | 1987-09-29 | Monsanto Company | Amine oxidation using carbon catalyst having oxides removed from surface |
| US4810426A (en) | 1986-01-28 | 1989-03-07 | Monsanto Company | Process for making glyphosate from n-phosphonomethyl-2-oxazolidone |
| US4853159A (en) | 1987-10-26 | 1989-08-01 | Monsanto Company | Process for producing N-phosphonomethylglycine |
| US4851131A (en) | 1987-12-31 | 1989-07-25 | Monsanto Company | Process for treating glyphosate process waste streams |
| SU1706690A1 (ru) | 1988-04-19 | 1992-01-23 | Всесоюзный Научно-Исследовательский Институт Технического Углерода | Пористый углеродный материал |
| JPH0697614B2 (ja) | 1988-08-26 | 1994-11-30 | エヌ・イーケムキャット株式会社 | 担持白金合金電極触媒 |
| JPH0697615B2 (ja) | 1989-03-09 | 1994-11-30 | エヌ・イーケムキャット株式会社 | 白金合金電極触媒 |
| JP2806391B2 (ja) | 1989-07-11 | 1998-09-30 | 田中貴金属工業株式会社 | 有害気体酸化触媒 |
| US5087740A (en) | 1989-08-17 | 1992-02-11 | Monsanto Company | Process for purifying N-phosphonomethylglycine |
| ES2021229A6 (es) | 1990-03-12 | 1991-10-16 | Ercros Sa | Perfeccionamientos introducidos en un procedimiento de obtencion de n-fosfonometilglicina por oxidacion de n-fosfonometiliminodiacetico. |
| US5095140A (en) | 1990-06-25 | 1992-03-10 | Monsanto Company | Peroxide process for producing N-phosphonomethylglycine |
| US5077431A (en) | 1990-06-25 | 1991-12-31 | Monsanto Company | Peroxide process for producing n-phosphonomethylglycine |
| US5023369A (en) | 1990-06-25 | 1991-06-11 | Monsanto Company | Process for producing N-phosphonomethylglycine |
| JP2909166B2 (ja) | 1990-07-31 | 1999-06-23 | エヌ・イーケムキヤツト株式会社 | 担持白金四元系合金電極触媒 |
| JPH05208135A (ja) | 1991-02-23 | 1993-08-20 | Tanaka Kikinzoku Kogyo Kk | 負極用電極触媒 |
| US5189005A (en) | 1992-04-03 | 1993-02-23 | Tanaka Kikinzoku Kogyo K.K. | Electrocatalyst and process of preparing same |
| DE4236203A1 (de) | 1992-10-27 | 1994-04-28 | Bayer Ag | Verfahren zur Herstellung von chlorsubstituierten aromatischen Aminen und von Katalysatoren |
| US5356849A (en) | 1993-01-21 | 1994-10-18 | Calgon Carbon Corporation | Catalytic carbon |
| US5292936A (en) | 1993-04-12 | 1994-03-08 | Monsanto Company | Process to prepare amino carboxylic acid salts |
| US5759944A (en) | 1993-04-20 | 1998-06-02 | Johnson Matthey Public Limited Company | Catalyst material |
| GB9410524D0 (en) | 1993-06-21 | 1994-07-13 | Zeneca Ltd | Manufacture of n- phosphonomethylglycine and its salts |
| US5416052A (en) | 1994-01-21 | 1995-05-16 | Intevep, S.A. | Catalyst for use in the dehydrogenation and isomerization of paraffins and method for preparing the catalyst |
| DE4415312A1 (de) | 1994-05-02 | 1995-11-09 | Hoechst Ag | Verfahren zur Herstellung von N-Acylglycinderivaten |
| PL182347B1 (pl) | 1994-07-01 | 2001-12-31 | Monsanto Co | Sposób wytwarzania kwasu N-hydroksyalkiloaminometylofosfonowego lub jego soli, sposób wytwarzania kwasu N-fosfonometyloaminokarboksylowego lub jego soli, sposób wytwarzania N-fosfonometyloglicyny lub jej soli PL PL PL PL PL |
| US5689000A (en) | 1994-07-01 | 1997-11-18 | Monsanto Company | Process for preparing carboxylic acid salts and catalysts useful in such process |
| SI9400449A (en) | 1994-12-20 | 1996-06-30 | Pinus D D | Process for preparing N-phosphonomethyl glycin |
| US5585083A (en) | 1995-03-30 | 1996-12-17 | The United States As Represented By The Administrator Of The National Aeronautics And Space Administration | Catalytic process for formaldehyde oxidation |
| KR100266127B1 (ko) | 1995-06-07 | 2000-09-15 | 죤 에이치. 뷰센 | N-포스포노메틸이미노디아세트산의 제조방법 |
| US5606107A (en) | 1995-06-07 | 1997-02-25 | Monsanto Company | Formic acid and formaldehyde destruction in waste streams |
| ATE439185T1 (de) * | 1995-10-02 | 2009-08-15 | Osaka Gas Co Ltd | Verfahren zur entstickung von abgasen mittels hitzebehandeltem aktiven kohlenstoff |
| DE19544403A1 (de) * | 1995-11-29 | 1997-06-05 | Basf Ag | Herstellung eines Hydrierungskatalysators unter Verwendung von M(OR)¶m¶X¶n¶ |
| JP3874380B2 (ja) * | 1996-08-26 | 2007-01-31 | エヌ・イーケムキャット株式会社 | 空格子点型格子欠陥を有するカーボン担持白金スケルトン合金電極触媒 |
| CN1239473A (zh) * | 1997-02-13 | 1999-12-22 | 孟山都公司 | 制备氨基羧酸的方法 |
| EP1062221B1 (en) | 1998-02-12 | 2006-05-10 | Monsanto Technology LLC | Process for making glyphosate by oxidizing n-substituted glyphosates |
| US6417133B1 (en) | 1998-02-25 | 2002-07-09 | Monsanto Technology Llc | Deeply reduced oxidation catalyst and its use for catalyzing liquid phase oxidation reactions |
| WO2000001707A1 (en) | 1998-07-06 | 2000-01-13 | Syngenta Participations Ag. | Preparation of n-phosphonomethylglycine salts |
| WO2000031266A1 (en) * | 1998-11-25 | 2000-06-02 | The General Hospital Corporation | Human parathyroid hormone modifications, preparation and use |
-
1999
- 1999-02-11 US US09/248,655 patent/US6417133B1/en not_active Expired - Lifetime
- 1999-02-17 KR KR1020007009463A patent/KR20010041349A/ko not_active Application Discontinuation
- 1999-02-17 AU AU27707/99A patent/AU761345B2/en not_active Expired
- 1999-02-17 BR BRPI9908252-7A patent/BRPI9908252B1/pt active IP Right Grant
- 1999-02-17 CN CN2006101288026A patent/CN1962673B/zh not_active Expired - Lifetime
- 1999-02-17 TR TR2000/02459T patent/TR200002459T2/xx unknown
- 1999-02-17 HU HU0101891A patent/HUP0101891A3/hu unknown
- 1999-02-17 CN CNB998054593A patent/CN1279048C/zh not_active Expired - Lifetime
- 1999-02-17 EA EA200000869A patent/EA200000869A1/ru unknown
- 1999-02-17 IL IL13808199A patent/IL138081A0/xx unknown
- 1999-02-17 CA CA002321923A patent/CA2321923C/en not_active Expired - Lifetime
- 1999-02-17 PL PL99342499A patent/PL342499A1/xx unknown
- 1999-02-17 BR BRPI9917783-8A patent/BR9917783B1/pt not_active IP Right Cessation
- 1999-02-17 JP JP2000533219A patent/JP2002504427A/ja not_active Withdrawn
- 1999-02-17 CZ CZ20003020A patent/CZ20003020A3/cs unknown
- 1999-02-17 CA CA2610653A patent/CA2610653C/en not_active Expired - Lifetime
- 1999-02-17 WO PCT/US1999/003402 patent/WO1999043430A1/en not_active Application Discontinuation
- 1999-02-17 EP EP99908217A patent/EP1060017A1/en not_active Ceased
- 1999-02-17 ID IDW20001910A patent/ID26942A/id unknown
- 1999-02-17 SK SK1256-2000A patent/SK12562000A3/sk unknown
- 1999-02-24 AR ARP990100768A patent/AR013023A1/es active IP Right Grant
- 1999-02-24 ZA ZA9901496A patent/ZA991496B/xx unknown
- 1999-09-29 US US09/408,323 patent/US7067693B1/en not_active Expired - Lifetime
- 1999-09-29 US US09/408,296 patent/US6603039B1/en not_active Expired - Lifetime
-
2000
- 2000-08-25 MX MXPA/A/2000/008441 patent/MX264644B/es active IP Right Grant
- 2000-08-25 MX MXPA03002768 patent/MX270262B/es unknown
-
2004
- 2004-02-03 AR ARP040100336A patent/AR043018A2/es active IP Right Grant
-
2006
- 2006-06-05 US US11/447,236 patent/US8143441B2/en not_active Expired - Fee Related
-
2008
- 2008-02-27 AR ARP080100812A patent/AR069820A2/es active IP Right Grant
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| AR069820A2 (es) | Un catalizador de oxidacion y un proceso para preparar un producto que comprende n-( fosfonometil)glicina o una sal del mismo | |
| Ferris et al. | Ammonia photolysis and the role of ammonia in chemical revolution | |
| JPS5231995A (en) | Gas generator | |
| GB1469930A (en) | Carbon filaments | |
| EP0089183A3 (en) | Process for the removal of hydrogen from gases | |
| Krasna et al. | The inhibition of hydrogenase by nitric oxide | |
| NO915083L (no) | Hydrogenbehandlingskatalysator | |
| NO892377D0 (no) | Fremgangsmaate for aa konvertere brennstoff til elektrisitet | |
| GB985601A (en) | Improvements in titanium alloy articles | |
| DE3889702D1 (de) | Eisen-Citrat-Komplex, Verfahren für seine Herstellung und seine pharmazeutische Verwendung. | |
| GB951665A (en) | Treatment of gases | |
| JPS5510473A (en) | Production of activated carbon fiber | |
| ES2163507T3 (es) | Procedimiento para reactivar catalizadores de carbon tratados con nitrogeno. | |
| Bugaev et al. | Interaction and Distribution of Atoms in Fe--Mn--C BCC-Alloy | |
| JPS5648239A (en) | Adsorbent | |
| GB1552573A (en) | Process for the oxidation of harmful material in aqueous solution | |
| JPS5573344A (en) | Catalyst for oxidation of carbon monoxide | |
| ES8303347A1 (es) | "procedimiento para la preparacion de amino-pridinas". | |
| JPS57131729A (en) | Selective preparation of 1-butene by hydroisomerization of 2-butene | |
| JPS57183302A (en) | Decomposition of water | |
| Huyton et al. | The effect of electron scavengers on the γ-radiolysis of gaseous H2S | |
| Paschen | Hydrogen Metallurgy | |
| Spedding | Some investigations into hydrogen sulphide adsorption by lead | |
| Main Jr | Generating Heat Treat Atmospheres From Alcohol | |
| Hoffmann et al. | Hydrogen intake during gas carburizing |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| FG | Grant, registration |