AR034254A1 - Ester de hidroxilamina; composicion; procedimiento para preparar un oligomero, un cooligomero, un polimero o un copolimero; procedimiento para reducir el peso molecular de polipropileno, copolimeros de propileno o mezclas de polipropileno; y un procedimiento para el aumento controlado del peso molec - Google Patents

Ester de hidroxilamina; composicion; procedimiento para preparar un oligomero, un cooligomero, un polimero o un copolimero; procedimiento para reducir el peso molecular de polipropileno, copolimeros de propileno o mezclas de polipropileno; y un procedimiento para el aumento controlado del peso molec

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AR034254A1
AR034254A1 ARP010102349A ARP010102349A AR034254A1 AR 034254 A1 AR034254 A1 AR 034254A1 AR P010102349 A ARP010102349 A AR P010102349A AR P010102349 A ARP010102349 A AR P010102349A AR 034254 A1 AR034254 A1 AR 034254A1
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Argentina
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alkyl
aryl
alkenyl
hydrogen
group
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Ciba Sc Holding Ag
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    • C07D491/02—Heterocyclic compounds containing in the condensed ring system both one or more rings having oxygen atoms as the only ring hetero atoms and one or more rings having nitrogen atoms as the only ring hetero atoms, not provided for by groups C07D451/00 - C07D459/00, C07D463/00, C07D477/00 or C07D489/00 in which the condensed system contains two hetero rings
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    • C07C239/22—Hydroxylamino compounds or their ethers or esters having oxygen atoms of hydroxylamino groups esterified
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    • C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
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    • C07D233/28—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having one double bond between ring members or between a ring member and a non-ring member with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
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    • C07D241/08—Heterocyclic compounds containing 1,4-diazine or hydrogenated 1,4-diazine rings not condensed with other rings having one or two double bonds between ring members or between ring members and non-ring members with oxygen atoms directly attached to ring carbon atoms
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    • C07D295/22—Heterocyclic compounds containing polymethylene-imine rings with at least five ring members, 3-azabicyclo [3.2.2] nonane, piperazine, morpholine or thiomorpholine rings, having only hydrogen atoms directly attached to the ring carbon atoms with hetero atoms directly attached to ring nitrogen atoms
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    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
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    • C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
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    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
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    • C08K5/16—Nitrogen-containing compounds
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    • C08K5/3412—Heterocyclic compounds having nitrogen in the ring having one nitrogen atom in the ring
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Abstract

Esteres de hidroxilamina cíclicos y de cadena abierta que tienen: (a) la fórmula (1) donde: Ra es un radical acilo seleccionado del grupo que consiste en -C(=O)-H, -C(=O)-alquilo C1-19, -C(=O)-alquenilo C2-19, -C(=O)-alquenilo C2-19-arilo C6-10, -C(=O)-arilo C6-10, -C(=O)-O-alquilo C1-6, -C(=O)-O-arilo C6-10, -C(=O)-NH-arilo C6-10, y -C(=O)-N(alquilo C1-6)2; R1 - R4 son cada uno alquilo C1-6; R5 y R6 son cada uno, independientemente uno del otro, hidrógeno, alquilo C1-6 o arilo C6-10; o R5 y R6 son conjuntamente oxígeno; Q es un enlace directo o un radical divalente -(CR7R8)- ó -(CR7R8-CR9R10)-, donde R7, R8, R9 y R10 son cada uno, independientemente uno del otro, hidrógeno, ó alquilo C1-6; y Z1 es oxígeno o un radical divalente -NR11-, donde R11 es hidrógeno, alquilo C1-6, arilo C6-10 o el radical acilo Ra que tiene uno de los significados antes mencionados; o (b) la fórmula (1) donde: Ra es un radical acilo seleccionado del grupo consistente en -P(=O)-alquilo C1-19, -P(=O)2-alquilo C1-19, -P(=O)-arilo C6-10, -P=O(-alquilo C1-19)2, -P=O(-arilo C6-10)2, -P(=O)-O-alquilo C1-6, -P(=O)-O-arilo C6-10, -P=O(-O-alquilo C1-6)2, -P=O(-O-arilo C6-10)2, -P(-O-alquilo C1-6)2, y -P(-O-arilo C6-10)2; R1 - R4 son cada uno alquilo C1-6; R5 y R6 son cada uno, independientemente uno del otro, hidrógeno, alquilo C1-6, o arilo C6-10; o R5 y R6 son conjuntamente oxígeno; Q es un enlace directo o un radical divalente -(CR7R8)- ó -(CR7R(-CR9R10)-, donde R7, R8, R9 y R10 son cada uno, independientemente uno del otro, hidrógeno, o alquilo C1-6; Z1 es oxígeno o un radical divalente -NR11- o -(CR12R13)-, donde R11 es hidrógeno, alquilo C1-6, arilo C6-10 o independientemente uno del otro uno de los radicales R12 y R13 es hidrógeno o alquilo C1-6 y el otro es alquilo C1-6, alcoxi C1-6, ariloxi C6-10, aciloxi seleccionado del grupo que consiste en -O-C-(=O)-H, -O-C(=O)-alquilo C1-16, -O-C(=O)-alquenilo C1-54, -O-C(=O)-arilo C6-10, -O-C(=O)-alquenilo C1-36-arilo C6-10, -O-C(=O)-O-alquilo C1-19, -O-C(=O)-O-arilo C6-10, -O-C(=O)-NH-alquilo C1-6, -O-C(=O)-NH-arilo C6-10, y -O-C(=O)-N(alquilo C1-6)2, alquilamino C1-6, dialquilamino C1-6, arilamino C6-10, acilamino seleccionado del grupo que consiste en -NH-C(=O)-alquilo C1-19, -NH-C(=O)-alquenilo C1-54, -NH-C(=O)-arilo C6-10, -NH-C(=O)-alquenilo C1-36-arilo C6-10, -NH-C(=O)-O-alquilo C1-19, -NH-C(=O)-O-arilo C6-10, -NH-C(=O)-NH-alquilo C1-6, -NH-C(=O)-NH-arilo C6-10 y -NH-C(=O)-N(alquilo C1-6)2, diacilamino seleccionado del grupo consistente en -N[-C(=O)-alquilo C1-19]2 y -N[-C(=O)-arilo C6-10]2, ó N-acil-N-alquilamino C1-6; o los dos radicales R12 y R13 son conjuntamente oxo; o (c) la fórmula (2) donde: Ra es un radical acilo seleccionado del grupo que consiste en -C(=O)-H, -C(=O)-alquilo C1-19, -C(=O)-alquenilo C2-19, -C(=O)-alquenilo C2-4-arilo C6-10, -C(=O)-arilo C6-10, -C(=O)-O-alquilo C1-6, -C(=O)-O-arilo C6-10, -C(=O)-NH-arilo C6-10, y -C(=O)-N(alquilo C1-6)2; R1 - R4 son cada uno alquilo C1-6; A es un sustituyente en los anillos fenilo; y m es 0 ó un número entero de 1 a 4; o (d) la fórmula (3) donde: Ra es un radical acilo seleccionado del grupo que consiste en -C(=O)-H, -C(=O)-alquilo C1-19, -C(=O)-alquenilo C2-19, -C(=O)-alquenilo C2-4-arilo C6-10, -C(=O)-arilo C6-10, -C(=O)-O-alquilo C1-6, -C(=O)-O-arilo C6-10, -C(=O)-NH-alquilo C1-6, -C(=O)-NH-arilo C6-10, -C(=O)-N(alquilo C1-6)2, -P(=O)-alquilo C1-19, -P(=O)2-alquilo C1-19, -P(=O)-arilo C6-10, -P=O(alquilo C1-19)2, -P=O(arilo C6-10)2, -P-(=O)-O-alquilo C1-6, -P-(=O)-O-arilo C6-10, -P=O(-O-alquilo C1-6)2, -P=O(-O-arilo C6-10)2, -P(-O-alquilo C1-6)2, y -P(-O-arilo C6-10)2; Rb es tal como se ha definido para Ra o es carbamoilo, alquilcarbamoilo C1-6, o di-alquilcarbamoilo C1-6; Rc y Rd son cada uno, independientemente uno del otro, hidrógeno, alquilo C1-6, o arilo C6-10; y R1 a R3 son cada uno, independientemente uno del otro, alquilo C1-6 o arilo C6-10. Composiciones polimerizables que comprenden estos ésteres de hidroxilamina y un monómero u oligómero etilénicamente insaturado. Uso de los ésteres de hidroxilamina como iniciadores de polimerización. Uso de los ésteres de hidroxilamina conocidos seleccionados del grupo que consiste en compuestos HALS y de los nuevos ésteres de hidroxilamina para la degradación controlada de polipropileno y para lograr un aumento controlado del peso molecular del polietileno. Se describe también un procedimiento para preparar un oligómero, cooligómero, un polímero o un copolímero; un procedimiento para reducir el peso molecular de polipropileno, copolímeros de propileno o mezclas de polipropileno; y un procedimiento para el aumento controlado del peso molecular de polietilenos o mezclas de polietileno.
ARP010102349A 2000-05-19 2001-05-17 Ester de hidroxilamina; composicion; procedimiento para preparar un oligomero, un cooligomero, un polimero o un copolimero; procedimiento para reducir el peso molecular de polipropileno, copolimeros de propileno o mezclas de polipropileno; y un procedimiento para el aumento controlado del peso molec AR034254A1 (es)

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ARP100104779A AR079557A2 (es) 2000-05-19 2010-12-20 Ester de hidroxilamina

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EP1513893B1 (en) * 2002-04-17 2009-01-07 Ciba Holding Inc. Flame retardant polymer compositions containing hydroxylamine esters
CA2494682A1 (en) * 2002-09-23 2004-04-01 Ciba Specialty Chemicals Holding Inc. Polymeric alkoxyamines prepared by atom transfer radical addition (atra)
DE602004001517T2 (de) * 2003-03-12 2006-12-28 Ciba Speciality Chemicals Holding Inc. Hydroxylaminester enthaltende beschichtungszusammensetzung
US20100210800A1 (en) 2004-03-24 2010-08-19 Ciba Corporation Method of preparing ethylene polymers by controlled high pressure polymerization
CA2558370C (en) * 2004-03-24 2012-11-20 Ciba Specialty Chemicals Holding Inc. Method of preparing ethylene polymers by controlled high pressure polymerization
ATE420137T1 (de) * 2004-09-09 2009-01-15 Ciba Holding Inc Abbau von polypropylen mit hydroxylamin-ester- zusammensetzungen
FR2877003B1 (fr) * 2004-10-26 2007-01-05 Arkema Sa Procede ameliore de fabrication d'anhydride (meth) acrylique
WO2006106059A1 (en) * 2005-04-06 2006-10-12 Ciba Specialty Chemicals Holding Inc. Azo compounds for polypropylene degradation
US20090209158A1 (en) * 2006-04-26 2009-08-20 Richeson Galen C Pelletized Polymer Product And Process For Making The Same
FR2908864B1 (fr) * 2006-11-22 2013-04-26 Cedric Brochier Soieries Complexe eclairant verrier
AU2008340442B2 (en) * 2007-12-21 2013-09-26 Basf Se Flame retardant compositions comprising sterically hindered amines
CN102341370B (zh) * 2009-01-08 2014-12-24 巴斯夫欧洲公司 聚合引发剂
JP5642150B2 (ja) 2009-03-23 2014-12-17 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ フォトレジスト組成物
US8940806B2 (en) 2009-03-30 2015-01-27 Basf Se Polymerizable compositions
CA2759289C (en) * 2009-04-21 2019-01-15 Basf Corporation Rotomolding process for polyethylene articles
WO2010128062A1 (en) 2009-05-07 2010-11-11 Basf Se O-imino-iso-urea compounds and polymerizable compositions thereof
US20120108712A1 (en) 2009-07-06 2012-05-03 Basf Se Phenylphosphonate flame retardant compositions
CN102010519B (zh) * 2009-09-07 2012-09-12 中国石油化工股份有限公司 一种聚丙烯降解用粉体组合物母料
KR200458226Y1 (ko) * 2009-09-30 2012-01-30 주식회사 바스존 돌출 무늬를 갖는 욕실용 슬리퍼
US8653196B2 (en) 2010-01-11 2014-02-18 Dow Global Technologies, Llc Method for preparing polyethylene with high melt strength
JP5631414B2 (ja) 2010-01-15 2014-11-26 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ ホスホ置換アルコキシアミン化合物
EP2550321A1 (en) 2010-03-25 2013-01-30 Basf Se Flame retardant compositions of phosphinic acid salts and nitroxyl derivatives
CA2804228A1 (en) 2010-07-28 2012-02-02 Basf Se Phosphinic acid hydrazide flame retardant compositions
WO2012013565A1 (en) 2010-07-29 2012-02-02 Basf Se Phosphinic acid hydrazide flame retardant compositions
WO2013006409A1 (en) * 2011-07-06 2013-01-10 Dow Global Technologies Llc Polyethylene with high melt strength for use in extrusion coating
WO2013006748A1 (en) * 2011-07-07 2013-01-10 Dow Global Technologies Llc Ethylene-based polymers compositions
WO2013036581A1 (en) * 2011-09-09 2013-03-14 Chevron Phillips Chemical Company Lp Polyethylene additive compositions and articles made from same
EP2912023B1 (en) 2012-10-23 2017-01-11 Basf Se Iminoxytriazines as radical generators
US10301434B2 (en) 2013-01-18 2019-05-28 Basf Se Block copolymers having a polydimethylsiloxane block
CN105531260B (zh) 2013-09-10 2019-05-31 巴斯夫欧洲公司 肟酯光引发剂
JP2017507237A (ja) * 2014-03-07 2017-03-16 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 制御されたラジカル重合
JP6323151B2 (ja) * 2014-05-09 2018-05-16 三菱ケミカル株式会社 Ｎ−オキシル化合物の製造方法
CN104201164B (zh) * 2014-08-27 2019-01-15 佳禾智能科技股份有限公司 一种三维集成电路组件及其制备方法
DE102014218811A1 (de) 2014-09-18 2016-03-24 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Verwendung von phosphorhaltigen organischen Oxyimiden als Flammschutzmittel, Radikalgeneratoren und/oder als Stabilisatoren für Kunststoffe, flammgeschützte Kunststoffzusammensetzung, Verfahren zu deren Herstellung sowie Formteile, Lacke und Beschichtungen
DK3034552T4 (da) * 2014-12-15 2024-09-16 Borealis Ag Synergistic visbreaking-sammensætning af peroxid og hydroxylaminester til øgning af visbreaking-effektivitet
EP3492499A1 (en) 2014-12-15 2019-06-05 Borealis AG Melt-blown webs without shots and with improved barrier properties
KR101859813B1 (ko) * 2016-03-14 2018-05-18 한국화학연구원 이중 경화가 가능한 저온가교형 블록이소시아네이트 및 이를 포함하는 조성물
MX2018014917A (es) * 2016-05-31 2019-08-29 Basf Se Telas no tejidas elaboradas de fibras bicomponentes.
KR102285438B1 (ko) * 2018-11-27 2021-08-02 주식회사 엘지화학 아크릴산 에스테르 화합물 제조 방법
US20220121113A1 (en) 2019-01-23 2022-04-21 Basf Se Oxime ester photoinitiators having a special aroyl chromophore
WO2021110814A1 (en) 2019-12-04 2021-06-10 Borealis Ag Filtration media made from melt-blown fibers with improved filtration properties
US20230025875A1 (en) 2019-12-04 2023-01-26 Borealis Ag Light weight melt blown webs with improved barrier properties
AU2021225338A1 (en) * 2020-02-26 2022-09-08 Basf Se Additive mixtures for rheology modification of polymers
EP4114825A1 (en) 2020-03-04 2023-01-11 Basf Se Oxime ester photoinitiators
EP3925986A1 (en) 2020-06-15 2021-12-22 Borealis AG Production of polypropylene with low volatiles
RU2748797C1 (ru) * 2020-09-10 2021-05-31 Общество с ограниченной ответственностью "Радуга" Способ модификации полипропилена
WO2022069414A1 (en) 2020-09-30 2022-04-07 Borealis Ag Process for recycling propylene-ethylene copolymers
US20230383043A1 (en) 2020-11-30 2023-11-30 Basf Se Process of producing polymer dispersions
WO2024133667A1 (en) 2022-12-21 2024-06-27 Basf Se A method for improving the processing of polyethylene

Family Cites Families (55)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH521997A (de) * 1969-04-02 1972-04-30 Ciba Geigy Ag Verfahren zur Herstellung von Phosphorsäure- und Phosphonsäure-Estern
US3697520A (en) 1970-04-30 1972-10-10 Ciba Geigy Ag Triazine carboxylic acids and esters
CH576495A5 (es) 1973-03-27 1976-06-15 Ciba Geigy Ag
CH597274A5 (es) 1974-07-30 1978-03-31 Ciba Geigy Ag
GB1478261A (en) 1975-05-28 1977-06-29 Ciba Geigy Ag Derivatives of 4-oxopiperidines
GB1496844A (en) 1975-05-28 1978-01-05 Ciba Geigy Ag Stabilization of polymers
JPS5266551A (en) * 1975-12-01 1977-06-02 Adeka Argus Chem Co Ltd Stabilizer for plastics
US4118369A (en) * 1976-07-28 1978-10-03 Argus Chemical Corporation 2,2,6,6-Tetrasubstituted-4-piperidyl carboxy heterocyclic compounds as stabilizers for synthetic polymers
GB2042562B (en) 1979-02-05 1983-05-11 Sandoz Ltd Stabilising polymers
EP0227640B1 (de) 1982-09-30 1993-05-26 Ciba-Geigy Ag Mit Bis-(polyalkylpiperidinyl-amino)-1,3,5-triazinen stabilisierte Polyolefine
AU571240B2 (en) * 1983-07-11 1988-04-14 Commonwealth Scientific And Industrial Research Organisation Alkoxy-amines, useful as initiators
FR2562546B1 (fr) * 1984-04-09 1987-01-23 Bp Chimie Sa Procede de traitement de polyethylene de basse densite lineaire destine a la fabrication par extrusion de corps creux, tubes et gaines
US4680325A (en) 1985-01-17 1987-07-14 Mallinckrodt, Inc. Anti-oxidant isocyanurate ester of thioamidophenol and polyolefins stabilized therewith
US4619956A (en) 1985-05-03 1986-10-28 American Cyanamid Co. Stabilization of high solids coatings with synergistic combinations
EP0365481A1 (en) * 1988-10-19 1990-04-25 Ciba-Geigy Ag Polymeric substrates stabilized with N-substituted hindered amines
US5004770A (en) * 1988-10-19 1991-04-02 Ciba-Geigy Corporation Polymeric substrates stabilized with N-substituted hindered amines
US5175312A (en) 1989-08-31 1992-12-29 Ciba-Geigy Corporation 3-phenylbenzofuran-2-ones
DE69030362T2 (de) 1989-12-05 1997-10-23 Ciba Geigy Ag Stabilisiertes organisches Material
US5198498A (en) 1990-02-06 1993-03-30 Ciba-Geigy Corporation Light-stabilized binders for coating compositions
DE59106390D1 (de) 1990-02-16 1995-10-12 Ciba Geigy Ag Gegen Schädigung durch Licht, Wärme und Sauerstoff stabilisierte Ueberzugsmittel.
EP0458741B1 (de) 1990-05-10 1996-01-24 Ciba-Geigy Ag Strahlenhärtbare lichtstabilisierte Zusammensetzungen
KR100187320B1 (ko) 1991-02-21 1999-04-01 월터 클리웨인 광, 산소 및 열에 대해 안정화된 도료
US5252643A (en) 1991-07-01 1993-10-12 Ciba-Geigy Corporation Thiomethylated benzofuran-2-ones
TW206220B (es) 1991-07-01 1993-05-21 Ciba Geigy Ag
NL9300801A (nl) 1992-05-22 1993-12-16 Ciba Geigy 3-(acyloxyfenyl)benzofuran-2-on als stabilisatoren.
TW260686B (es) 1992-05-22 1995-10-21 Ciba Geigy
GB2267490B (en) 1992-05-22 1995-08-09 Ciba Geigy Ag 3-(Carboxymethoxyphenyl)benzofuran-2-one stabilisers
DE4219459A1 (de) 1992-06-13 1993-12-16 Huels Chemische Werke Ag Verfahren zur Herstellung von 2,2,6,6-Tetramethylpiperidin-N-oxyl und seinen in 4-Stellung substituierten Derivaten
DE4219471A1 (de) 1992-06-13 1993-12-16 Huels Chemische Werke Ag N-Oxyl-Derivate des 2,2,6,6-Tetramethylpiperidins und deren Herstellung
MX9305489A (es) 1992-09-23 1994-03-31 Ciba Geigy Ag 3-(dihidrobenzofuran-5-il)benzofuran-2-onas, estabilizadores.
TW255902B (es) 1992-09-23 1995-09-01 Ciba Geigy
US5322912A (en) 1992-11-16 1994-06-21 Xerox Corporation Polymerization processes and toner compositions therefrom
US5354794A (en) 1993-02-03 1994-10-11 Ciba-Geigy Corporation Electro coat/base coat/clear coat finishes stabilized with S-triazine UV absorbers
US5556973A (en) 1994-07-27 1996-09-17 Ciba-Geigy Corporation Red-shifted tris-aryl-s-triazines and compositions stabilized therewith
TW308601B (es) 1995-01-18 1997-06-21 Ciba Sc Holding Ag
DE69637916D1 (de) 1995-03-15 2009-06-10 Ciba Holding Inc Biphenyl-substituierte Triazine als Lichtschutzmittel
IT1273607B (it) 1995-04-26 1997-07-08 Ciba Geigy Spa Combinazione di stabilizzanti per polimeri sintetici organici
EP0909280B1 (de) * 1996-06-26 2000-08-23 Ciba SC Holding AG Abbau von polymeren durch nor-hals-verbindungen
US5910549A (en) 1996-08-22 1999-06-08 Carnegie-Mellon University Method for preparation of alkoxyamines from nitroxyl radicals
EP0928296B1 (en) * 1996-09-25 2001-12-05 Akzo Nobel N.V. No-compounds for pseudo-living radical polymerization
AUPO460797A0 (en) * 1997-01-15 1997-02-06 University Of Melbourne, The Polymerisation process
US6281311B1 (en) 1997-03-31 2001-08-28 Pmd Holdings Corp. Controlled free radical polymerization process
DE19727502A1 (de) * 1997-06-27 1999-01-07 Basf Ag Verfahren der radikalisch initiierten wäßrigen Emulsionspolymerisation zur Herstellung einer wäßrigen Polymerisatdispersion
CA2295631A1 (en) 1997-07-23 1999-02-04 Ciba Specialty Chemicals Holding Inc. Inhibition of pulp and paper yellowing using nitroxides and other coadditives
SG82601A1 (en) 1998-03-09 2001-08-21 Ciba Sc Holding Ag 1-alkoxy-polyalkyl-piperidine derivatives and their use as polymerization regulators
TWI246519B (en) 1998-06-25 2006-01-01 Ciba Sc Holding Ag Use of 2,2,6,6 tetraalkylpiperidine-N-oxyl radicals having long alkyl chains as polymerization regulators
KR20010106405A (ko) 1998-07-14 2001-11-29 시바 스폐셜티 케미칼스 홀딩 인코포레이티드 (메타)아크릴레이트 모노머용 중합방지제로서의1-옥실-4-히드록시- 또는4-아미노-2,2,6,6-테트라메틸피페리딘 유도체
EP1100772B1 (en) * 1998-07-31 2004-04-14 Ciba SC Holding AG Open chain alkoxyamine compounds and their use as polymerization regulators
JP2000053126A (ja) 1998-08-05 2000-02-22 Nihon Tetra Pak Kk 包装容器
JP5000038B2 (ja) * 1998-10-06 2012-08-15 トタル ペトロケミカルス フランス 開始／制御剤の存在下でエチレンを高圧フリーラジカル重合または共重合する方法
TWI225483B (en) 1998-10-16 2004-12-21 Ciba Sc Holding Ag Heterocyclic alkoxyamines as regulators in controlled radical polymerization process
US6797375B1 (en) 1998-11-12 2004-09-28 3M Innovative Properties Company Oriented polypropylene films for adhesive tape
ES2216610T3 (es) 1998-12-23 2004-10-16 Ciba Specialty Chemicals Holding Inc. Estabilizadores polimeros que tienen baja polidispersidad.
FR2792321B1 (fr) * 1999-04-19 2003-12-12 Atochem Elf Sa Procede de fabrication d'une resine de polypropylene a rheologie controlee
AU777318B2 (en) * 1999-09-15 2004-10-14 Ciba Specialty Chemicals Holding Inc. Chlorohydrin and cationic compounds having high affinity for pulp or paper

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