AR026287A1 - Anodo inerte de cerametal que contiene fases de oxido y metales utiles para la produccion electrolitica de metales - Google Patents
Anodo inerte de cerametal que contiene fases de oxido y metales utiles para la produccion electrolitica de metalesInfo
- Publication number
- AR026287A1 AR026287A1 ARP000105704A ARP000105704A AR026287A1 AR 026287 A1 AR026287 A1 AR 026287A1 AR P000105704 A ARP000105704 A AR P000105704A AR P000105704 A ARP000105704 A AR P000105704A AR 026287 A1 AR026287 A1 AR 026287A1
- Authority
- AR
- Argentina
- Prior art keywords
- cerametal
- inert
- anode
- containing oxide
- metal production
- Prior art date
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/17—Metallic particles coated with metal
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/12—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on oxides
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C7/00—Constructional parts, or assemblies thereof, of cells; Servicing or operating of cells
- C25C7/02—Electrodes; Connections thereof
- C25C7/025—Electrodes; Connections thereof used in cells for the electrolysis of melts
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Oxide Ceramics (AREA)
- Electrolytic Production Of Metals (AREA)
- Electrodes For Compound Or Non-Metal Manufacture (AREA)
Abstract
Se describe un ánodo inerte de cerametal para la produccion electrolítica de metales tales como aluminio. El ánodo inerte comprende una fase de cerámicaque tiene la formula: NixFe2yMzO(3y+x+z)+gamma, donde M es por lo menos un metal seleccionado de Z n, Co, Al, Li, Cu, Ti, V, Cr, Zr, Nb, Ta, W, Mb, Hf y tierrasraras, preferiblemente Zn y/o Cu; x es desde 0,1 hasta 0,99; y es desde 0,0001 hasta 0,9; z es desde 0,0001 hasta 0,5; y gamma es desde 0 hasta aproximadamente0,3. Las composiciones cerámic as preferidas comprenden Fe2O3, NiO y ZnO o CoO. El ánodo de cerametal comprende también una fase metálica tal como Cu, Ag, Pd,Pt, Au, Rh, Ru, Ir y/o Os. La fase de metal preferida comprende Cu y Ag. Los ánodos inertes a cerametal pueden usarse para células de reduccion electrolíticapara la produccion de aluminio de pureza comercial, así como también otros metales.
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US09/428,004 US6162334A (en) | 1997-06-26 | 1999-10-27 | Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum |
US09/431,756 US6217739B1 (en) | 1997-06-26 | 1999-11-01 | Electrolytic production of high purity aluminum using inert anodes |
US09/629,332 US6423204B1 (en) | 1997-06-26 | 2000-08-01 | For cermet inert anode containing oxide and metal phases useful for the electrolytic production of metals |
Publications (1)
Publication Number | Publication Date |
---|---|
AR026287A1 true AR026287A1 (es) | 2003-02-05 |
Family
ID=27411574
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
ARP000105704A AR026287A1 (es) | 1999-10-27 | 2000-10-27 | Anodo inerte de cerametal que contiene fases de oxido y metales utiles para la produccion electrolitica de metales |
Country Status (14)
Country | Link |
---|---|
US (1) | US6423204B1 (es) |
EP (2) | EP1226287B1 (es) |
KR (1) | KR20020091046A (es) |
CN (3) | CN1289713C (es) |
AR (1) | AR026287A1 (es) |
AT (1) | ATE356230T1 (es) |
AU (1) | AU774817B2 (es) |
BR (1) | BR0015087A (es) |
CA (1) | CA2385776C (es) |
DE (1) | DE60033837T2 (es) |
ES (1) | ES2283328T3 (es) |
MX (1) | MXPA02004141A (es) |
RU (1) | RU2251591C2 (es) |
WO (1) | WO2001031090A1 (es) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20030209426A1 (en) * | 2000-12-08 | 2003-11-13 | Slaugenhaupt Michael L. | Insulating lid for aluminum production cells |
NO326214B1 (no) * | 2001-10-25 | 2008-10-20 | Norsk Hydro As | Anode for elektrolyse av aluminium |
CN1301344C (zh) * | 2002-06-28 | 2007-02-21 | 东北大学 | 尖晶石型铝酸镍基金属陶瓷惰性电极 |
US6866766B2 (en) * | 2002-08-05 | 2005-03-15 | Alcoa Inc. | Methods and apparatus for reducing sulfur impurities and improving current efficiencies of inert anode aluminum production cells |
WO2004018734A2 (en) * | 2002-08-21 | 2004-03-04 | Pel Technologies Llc | Cast ceramic anode for metal oxide electrolytic reduction |
NO20024049D0 (no) * | 2002-08-23 | 2002-08-23 | Norsk Hydro As | Materiale for bruk i en elektrolysecelle |
US6758991B2 (en) | 2002-11-08 | 2004-07-06 | Alcoa Inc. | Stable inert anodes including a single-phase oxide of nickel and iron |
US7033469B2 (en) * | 2002-11-08 | 2006-04-25 | Alcoa Inc. | Stable inert anodes including an oxide of nickel, iron and aluminum |
US20040163967A1 (en) * | 2003-02-20 | 2004-08-26 | Lacamera Alfred F. | Inert anode designs for reduced operating voltage of aluminum production cells |
FR2852331B1 (fr) * | 2003-03-12 | 2005-04-15 | Procede de fabrication d'une anode inerte pour la production d'aluminium par electrolyse ignee | |
US6830605B2 (en) * | 2003-03-14 | 2004-12-14 | World Resources Company | Recovery of metal values from cermet |
US6805777B1 (en) | 2003-04-02 | 2004-10-19 | Alcoa Inc. | Mechanical attachment of electrical current conductor to inert anodes |
US6855234B2 (en) * | 2003-04-02 | 2005-02-15 | Alcoa Inc. | Sinter-bonded direct pin connections for inert anodes |
FR2860520B1 (fr) * | 2003-10-07 | 2006-01-13 | Pechiney Aluminium | Anode inerte destinee a la production d'aluminium par electrolyse ignee et procede d'obtention de cette anode |
CN1295379C (zh) * | 2003-11-04 | 2007-01-17 | 中南大学 | 一种铝电解用惰性阳极 |
US7235161B2 (en) * | 2003-11-19 | 2007-06-26 | Alcoa Inc. | Stable anodes including iron oxide and use of such anodes in metal production cells |
US7169270B2 (en) | 2004-03-09 | 2007-01-30 | Alcoa, Inc. | Inert anode electrical connection |
KR20110060926A (ko) * | 2008-09-08 | 2011-06-08 | 리오 틴토 알칸 인터내셔널 리미티드 | 알루미늄 환원 셀용의 고전류 밀도에서 작동하는 산소 발생 금속 애노드 |
CN102206837B (zh) * | 2010-03-31 | 2014-03-19 | 比亚迪股份有限公司 | 一种惰性阳极及其制备方法 |
CN102489700B (zh) * | 2011-12-23 | 2013-06-19 | 长沙理工大学 | Cu-Ni-Al合金粉末及其制备方法 |
WO2013122693A1 (en) * | 2012-02-14 | 2013-08-22 | Wisconsin Alumni Research Foundation | Electrocatalysts having mixed metal oxides |
CN103820816B (zh) * | 2013-12-11 | 2016-11-02 | 中国铝业股份有限公司 | 一种铝电解惰性阳极的表面处理方法 |
FR3022917B1 (fr) * | 2014-06-26 | 2016-06-24 | Rio Tinto Alcan Int Ltd | Materiau d'electrode et son utilisation pour la fabrication d'anode inerte |
KR20160065277A (ko) | 2014-11-28 | 2016-06-09 | 한국원자력연구원 | 전도성 산화물 세라믹 양극을 이용하는 금속산화물의 전해환원 장치 및 전해환원 방법 |
FR3034433B1 (fr) * | 2015-04-03 | 2019-06-07 | Rio Tinto Alcan International Limited | Materiau cermet d'electrode |
KR101723919B1 (ko) | 2016-08-08 | 2017-04-06 | 한국원자력연구원 | 전도성 산화물 세라믹 양극을 이용하는 금속산화물의 전해환원 장치 및 전해환원 방법 |
CN113174615B (zh) * | 2021-04-30 | 2024-02-13 | 中南大学 | 一种铝电解惰性阳极用金属陶瓷材料及其制备方法 |
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IT978528B (it) | 1973-01-26 | 1974-09-20 | Oronzio De Nora Impianti | Elettrodi metallici e procedimen to per la loro attivazione |
US3996117A (en) | 1974-03-27 | 1976-12-07 | Aluminum Company Of America | Process for producing aluminum |
JPS6047352B2 (ja) | 1977-06-27 | 1985-10-21 | 株式会社トクヤマ | 陰極の製造法 |
JPS54112785A (en) | 1978-02-24 | 1979-09-03 | Asahi Glass Co Ltd | Electrode and manufacture thereof |
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GB2069529A (en) | 1980-01-17 | 1981-08-26 | Diamond Shamrock Corp | Cermet anode for electrowinning metals from fused salts |
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US4584172A (en) | 1982-09-27 | 1986-04-22 | Aluminum Company Of America | Method of making composition suitable for use as inert electrode having good electrical conductivity and mechanical properties |
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US6030518A (en) | 1997-06-26 | 2000-02-29 | Aluminum Company Of America | Reduced temperature aluminum production in an electrolytic cell having an inert anode |
US6162334A (en) | 1997-06-26 | 2000-12-19 | Alcoa Inc. | Inert anode containing base metal and noble metal useful for the electrolytic production of aluminum |
US5865980A (en) * | 1997-06-26 | 1999-02-02 | Aluminum Company Of America | Electrolysis with a inert electrode containing a ferrite, copper and silver |
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US6077415A (en) | 1998-07-30 | 2000-06-20 | Moltech Invent S.A. | Multi-layer non-carbon metal-based anodes for aluminum production cells and method |
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-
2000
- 2000-08-01 US US09/629,332 patent/US6423204B1/en not_active Expired - Fee Related
- 2000-10-27 ES ES00975472T patent/ES2283328T3/es not_active Expired - Lifetime
- 2000-10-27 WO PCT/US2000/029826 patent/WO2001031090A1/en active IP Right Grant
- 2000-10-27 CN CNB008148821A patent/CN1289713C/zh not_active Expired - Fee Related
- 2000-10-27 CN CNA2006100735836A patent/CN1865511A/zh active Pending
- 2000-10-27 CN CNA2006100735821A patent/CN1865510A/zh active Pending
- 2000-10-27 MX MXPA02004141A patent/MXPA02004141A/es unknown
- 2000-10-27 CA CA002385776A patent/CA2385776C/en not_active Expired - Fee Related
- 2000-10-27 AR ARP000105704A patent/AR026287A1/es not_active Application Discontinuation
- 2000-10-27 BR BR0015087-8A patent/BR0015087A/pt not_active Application Discontinuation
- 2000-10-27 AU AU13520/01A patent/AU774817B2/en not_active Ceased
- 2000-10-27 EP EP00975472A patent/EP1226287B1/en not_active Expired - Lifetime
- 2000-10-27 AT AT00975472T patent/ATE356230T1/de not_active IP Right Cessation
- 2000-10-27 EP EP05027198A patent/EP1666640A3/en not_active Withdrawn
- 2000-10-27 KR KR1020027004505A patent/KR20020091046A/ko not_active Application Discontinuation
- 2000-10-27 DE DE60033837T patent/DE60033837T2/de not_active Expired - Fee Related
- 2000-10-27 RU RU2002113645/02A patent/RU2251591C2/ru not_active IP Right Cessation
Also Published As
Publication number | Publication date |
---|---|
MXPA02004141A (es) | 2003-04-10 |
DE60033837D1 (de) | 2007-04-19 |
CN1865511A (zh) | 2006-11-22 |
EP1666640A3 (en) | 2006-06-28 |
RU2251591C2 (ru) | 2005-05-10 |
WO2001031090A1 (en) | 2001-05-03 |
BR0015087A (pt) | 2002-07-16 |
KR20020091046A (ko) | 2002-12-05 |
US6423204B1 (en) | 2002-07-23 |
EP1226287B1 (en) | 2007-03-07 |
DE60033837T2 (de) | 2007-11-22 |
CA2385776A1 (en) | 2001-05-03 |
EP1226287A1 (en) | 2002-07-31 |
AU1352001A (en) | 2001-05-08 |
ES2283328T3 (es) | 2007-11-01 |
CA2385776C (en) | 2006-10-17 |
ATE356230T1 (de) | 2007-03-15 |
CN1384891A (zh) | 2002-12-11 |
AU774817B2 (en) | 2004-07-08 |
CN1289713C (zh) | 2006-12-13 |
CN1865510A (zh) | 2006-11-22 |
EP1666640A2 (en) | 2006-06-07 |
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Legal Events
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FA | Abandonment or withdrawal |