ZA200503286B - Copolymer having at least one alkoxy-or hydroxy-p oly-alkylene glycol grafted function, and use thereof - Google Patents
Copolymer having at least one alkoxy-or hydroxy-p oly-alkylene glycol grafted function, and use thereof Download PDFInfo
- Publication number
- ZA200503286B ZA200503286B ZA200503286A ZA200503286A ZA200503286B ZA 200503286 B ZA200503286 B ZA 200503286B ZA 200503286 A ZA200503286 A ZA 200503286A ZA 200503286 A ZA200503286 A ZA 200503286A ZA 200503286 B ZA200503286 B ZA 200503286B
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- South Africa
- Prior art keywords
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- copolymer
- Prior art date
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- 229920001577 copolymer Polymers 0.000 title claims abstract description 116
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 title description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 title description 2
- 239000000178 monomer Substances 0.000 claims abstract description 98
- 239000012190 activator Substances 0.000 claims abstract description 95
- 229910052500 inorganic mineral Inorganic materials 0.000 claims abstract description 61
- 239000011707 mineral Substances 0.000 claims abstract description 61
- 238000000034 method Methods 0.000 claims abstract description 55
- 239000007900 aqueous suspension Substances 0.000 claims abstract description 46
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 125000003827 glycol group Chemical group 0.000 claims abstract description 12
- 238000004519 manufacturing process Methods 0.000 claims abstract description 12
- 229920001515 polyalkylene glycol Polymers 0.000 claims abstract description 12
- 239000000203 mixture Substances 0.000 claims description 63
- -1 hydrocarbon radical Chemical group 0.000 claims description 53
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 50
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 25
- 239000000945 filler Substances 0.000 claims description 24
- 150000002148 esters Chemical class 0.000 claims description 23
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 23
- 239000011248 coating agent Substances 0.000 claims description 22
- 238000000576 coating method Methods 0.000 claims description 22
- 239000000049 pigment Substances 0.000 claims description 20
- 230000004913 activation Effects 0.000 claims description 19
- 238000000227 grinding Methods 0.000 claims description 18
- 125000002947 alkylene group Chemical group 0.000 claims description 15
- 239000006185 dispersion Substances 0.000 claims description 14
- 239000005995 Aluminium silicate Substances 0.000 claims description 13
- 125000003545 alkoxy group Chemical group 0.000 claims description 11
- 125000004356 hydroxy functional group Chemical group O* 0.000 claims description 10
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 9
- 239000002253 acid Substances 0.000 claims description 9
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 9
- 235000012211 aluminium silicate Nutrition 0.000 claims description 9
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 9
- 229910052602 gypsum Inorganic materials 0.000 claims description 5
- 239000010440 gypsum Substances 0.000 claims description 5
- 239000000454 talc Substances 0.000 claims description 5
- 229910052623 talc Inorganic materials 0.000 claims description 5
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims description 5
- 229920002554 vinyl polymer Polymers 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 3
- 239000003973 paint Substances 0.000 claims description 3
- 239000004033 plastic Substances 0.000 claims description 3
- 229920003023 plastic Polymers 0.000 claims description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims 53
- 125000004432 carbon atom Chemical group C* 0.000 claims 46
- 239000004215 Carbon black (E152) Substances 0.000 claims 38
- 229930195733 hydrocarbon Natural products 0.000 claims 38
- 150000003254 radicals Chemical group 0.000 claims 36
- 229910052739 hydrogen Inorganic materials 0.000 claims 26
- 239000001257 hydrogen Substances 0.000 claims 26
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims 20
- QUPDWYMUPZLYJZ-UHFFFAOYSA-N ethyl Chemical compound C[CH2] QUPDWYMUPZLYJZ-UHFFFAOYSA-N 0.000 claims 20
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 20
- 229910021653 sulphate ion Inorganic materials 0.000 claims 20
- 239000001166 ammonium sulphate Substances 0.000 claims 19
- 235000011130 ammonium sulphate Nutrition 0.000 claims 19
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 18
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 18
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical class C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 claims 18
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims 18
- 150000001408 amides Chemical class 0.000 claims 18
- DOEXKUOGPAEBAD-UHFFFAOYSA-N ethyl n-(2-methylprop-2-enoyl)carbamate Chemical compound CCOC(=O)NC(=O)C(C)=C DOEXKUOGPAEBAD-UHFFFAOYSA-N 0.000 claims 18
- IPZIVCLZBFDXTA-UHFFFAOYSA-N ethyl n-prop-2-enoylcarbamate Chemical group CCOC(=O)NC(=O)C=C IPZIVCLZBFDXTA-UHFFFAOYSA-N 0.000 claims 18
- 150000003949 imides Chemical class 0.000 claims 18
- 125000005395 methacrylic acid group Chemical group 0.000 claims 18
- OCAAZRFBJBEVPS-UHFFFAOYSA-N prop-2-enyl carbamate Chemical compound NC(=O)OCC=C OCAAZRFBJBEVPS-UHFFFAOYSA-N 0.000 claims 18
- GYLZSBPASSUYIS-UHFFFAOYSA-N tert-butyl n-benzyl-n-prop-1-en-2-ylcarbamate Chemical compound CC(C)(C)OC(=O)N(C(=C)C)CC1=CC=CC=C1 GYLZSBPASSUYIS-UHFFFAOYSA-N 0.000 claims 18
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims 14
- 150000001768 cations Chemical class 0.000 claims 14
- 230000003472 neutralizing effect Effects 0.000 claims 14
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims 8
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 8
- 125000000217 alkyl group Chemical group 0.000 claims 8
- 125000003710 aryl alkyl group Chemical group 0.000 claims 8
- 125000003118 aryl group Chemical group 0.000 claims 8
- 125000002091 cationic group Chemical group 0.000 claims 8
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims 8
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 8
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 claims 8
- 125000001453 quaternary ammonium group Chemical group 0.000 claims 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims 6
- 125000002877 alkyl aryl group Chemical group 0.000 claims 6
- 239000011575 calcium Substances 0.000 claims 6
- 229910052791 calcium Inorganic materials 0.000 claims 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims 6
- 238000004132 cross linking Methods 0.000 claims 6
- TURITJIWSQEMDB-UHFFFAOYSA-N 2-methyl-n-[(2-methylprop-2-enoylamino)methyl]prop-2-enamide Chemical compound CC(=C)C(=O)NCNC(=O)C(C)=C TURITJIWSQEMDB-UHFFFAOYSA-N 0.000 claims 4
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical group FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 claims 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims 4
- 229910021532 Calcite Inorganic materials 0.000 claims 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 claims 4
- GDFCSMCGLZFNFY-UHFFFAOYSA-N Dimethylaminopropyl Methacrylamide Chemical compound CN(C)CCCNC(=O)C(C)=C GDFCSMCGLZFNFY-UHFFFAOYSA-N 0.000 claims 4
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 claims 4
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims 4
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 claims 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 claims 4
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims 4
- 229930006000 Sucrose Natural products 0.000 claims 4
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 claims 4
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims 4
- 125000005250 alkyl acrylate group Chemical group 0.000 claims 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims 4
- 150000008064 anhydrides Chemical class 0.000 claims 4
- 125000000129 anionic group Chemical group 0.000 claims 4
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical compound NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 claims 4
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 claims 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims 4
- 239000004579 marble Substances 0.000 claims 4
- 150000002734 metacrylic acid derivatives Chemical class 0.000 claims 4
- 239000010445 mica Substances 0.000 claims 4
- 229910052618 mica group Inorganic materials 0.000 claims 4
- ZIUHHBKFKCYYJD-UHFFFAOYSA-N n,n'-methylenebisacrylamide Chemical compound C=CC(=O)NCNC(=O)C=C ZIUHHBKFKCYYJD-UHFFFAOYSA-N 0.000 claims 4
- ADTJPOBHAXXXFS-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]prop-2-enamide Chemical group CN(C)CCCNC(=O)C=C ADTJPOBHAXXXFS-UHFFFAOYSA-N 0.000 claims 4
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims 4
- 229920005862 polyol Polymers 0.000 claims 4
- 150000003077 polyols Chemical class 0.000 claims 4
- QTECDUFMBMSHKR-UHFFFAOYSA-N prop-2-enyl prop-2-enoate Chemical compound C=CCOC(=O)C=C QTECDUFMBMSHKR-UHFFFAOYSA-N 0.000 claims 4
- 239000000600 sorbitol Substances 0.000 claims 4
- 239000005720 sucrose Substances 0.000 claims 4
- 239000004408 titanium dioxide Substances 0.000 claims 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims 4
- FZGFBJMPSHGTRQ-UHFFFAOYSA-M trimethyl(2-prop-2-enoyloxyethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCOC(=O)C=C FZGFBJMPSHGTRQ-UHFFFAOYSA-M 0.000 claims 4
- RRHXZLALVWBDKH-UHFFFAOYSA-M trimethyl-[2-(2-methylprop-2-enoyloxy)ethyl]azanium;chloride Chemical group [Cl-].CC(=C)C(=O)OCC[N+](C)(C)C RRHXZLALVWBDKH-UHFFFAOYSA-M 0.000 claims 4
- UZNHKBFIBYXPDV-UHFFFAOYSA-N trimethyl-[3-(2-methylprop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].CC(=C)C(=O)NCCC[N+](C)(C)C UZNHKBFIBYXPDV-UHFFFAOYSA-N 0.000 claims 4
- OEIXGLMQZVLOQX-UHFFFAOYSA-N trimethyl-[3-(prop-2-enoylamino)propyl]azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCNC(=O)C=C OEIXGLMQZVLOQX-UHFFFAOYSA-N 0.000 claims 4
- 229940096522 trimethylolpropane triacrylate Drugs 0.000 claims 4
- GQOKIYDTHHZSCJ-UHFFFAOYSA-M dimethyl-bis(prop-2-enyl)azanium;chloride Chemical compound [Cl-].C=CC[N+](C)(C)CC=C GQOKIYDTHHZSCJ-UHFFFAOYSA-M 0.000 claims 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 claims 2
- XHZPRMZZQOIPDS-UHFFFAOYSA-N 2-Methyl-2-[(1-oxo-2-propenyl)amino]-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(C)(C)NC(=O)C=C XHZPRMZZQOIPDS-UHFFFAOYSA-N 0.000 claims 2
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 claims 2
- SEILKFZTLVMHRR-UHFFFAOYSA-N 2-phosphonooxyethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOP(O)(O)=O SEILKFZTLVMHRR-UHFFFAOYSA-N 0.000 claims 2
- UDXXYUDJOHIIDZ-UHFFFAOYSA-N 2-phosphonooxyethyl prop-2-enoate Chemical compound OP(O)(=O)OCCOC(=O)C=C UDXXYUDJOHIIDZ-UHFFFAOYSA-N 0.000 claims 2
- BRWBXCPVJZQRHJ-UHFFFAOYSA-N 2-phosphonooxypropyl 2-methylprop-2-enoate Chemical compound OP(=O)(O)OC(C)COC(=O)C(C)=C BRWBXCPVJZQRHJ-UHFFFAOYSA-N 0.000 claims 2
- ZWJWOOXWVLIPPX-UHFFFAOYSA-N 2-phosphonooxypropyl prop-2-enoate Chemical compound OP(=O)(O)OC(C)COC(=O)C=C ZWJWOOXWVLIPPX-UHFFFAOYSA-N 0.000 claims 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 2
- QUSNBJAOOMFDIB-UHFFFAOYSA-N Ethylamine Chemical compound CCN QUSNBJAOOMFDIB-UHFFFAOYSA-N 0.000 claims 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 claims 2
- XTUVJUMINZSXGF-UHFFFAOYSA-N N-methylcyclohexylamine Chemical compound CNC1CCCCC1 XTUVJUMINZSXGF-UHFFFAOYSA-N 0.000 claims 2
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 2
- 125000001931 aliphatic group Chemical group 0.000 claims 2
- 239000004411 aluminium Substances 0.000 claims 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims 2
- 229910052782 aluminium Inorganic materials 0.000 claims 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 claims 2
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 claims 2
- 150000002169 ethanolamines Chemical class 0.000 claims 2
- 229910052744 lithium Inorganic materials 0.000 claims 2
- 239000011777 magnesium Substances 0.000 claims 2
- 229910052749 magnesium Inorganic materials 0.000 claims 2
- 239000011976 maleic acid Substances 0.000 claims 2
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 claims 2
- 239000011591 potassium Substances 0.000 claims 2
- 229910052700 potassium Inorganic materials 0.000 claims 2
- 239000011734 sodium Substances 0.000 claims 2
- 229910052708 sodium Inorganic materials 0.000 claims 2
- SZHIIIPPJJXYRY-UHFFFAOYSA-M sodium;2-methylprop-2-ene-1-sulfonate Chemical compound [Na+].CC(=C)CS([O-])(=O)=O SZHIIIPPJJXYRY-UHFFFAOYSA-M 0.000 claims 2
- NLVXSWCKKBEXTG-UHFFFAOYSA-N vinylsulfonic acid Chemical compound OS(=O)(=O)C=C NLVXSWCKKBEXTG-UHFFFAOYSA-N 0.000 claims 2
- 239000011701 zinc Substances 0.000 claims 2
- 229910052725 zinc Inorganic materials 0.000 claims 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims 1
- 229910018557 Si O Inorganic materials 0.000 claims 1
- YIOJGTBNHQAVBO-UHFFFAOYSA-N dimethyl-bis(prop-2-enyl)azanium Chemical compound C=CC[N+](C)(C)CC=C YIOJGTBNHQAVBO-UHFFFAOYSA-N 0.000 claims 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 claims 1
- 239000006255 coating slurry Substances 0.000 abstract 2
- 230000003213 activating effect Effects 0.000 abstract 1
- 238000003801 milling Methods 0.000 abstract 1
- 239000003086 colorant Substances 0.000 description 9
- 239000012764 mineral filler Substances 0.000 description 9
- 239000000725 suspension Substances 0.000 description 6
- 239000000047 product Substances 0.000 description 5
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000002708 enhancing effect Effects 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical class OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 239000004568 cement Substances 0.000 description 1
- 239000008199 coating composition Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000007334 copolymerization reaction Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 239000001023 inorganic pigment Substances 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/32—Esters containing oxygen in addition to the carboxy oxygen containing epoxy radicals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
- C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
- C08F220/285—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety
- C08F220/286—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing a polyether chain in the alcohol moiety and containing polyethylene oxide in the alcohol moiety, e.g. methoxy polyethylene glycol (meth)acrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
- C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
- C08F290/06—Polymers provided for in subclass C08G
- C08F290/062—Polyethers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F297/00—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer
- C08F297/02—Macromolecular compounds obtained by successively polymerising different monomer systems using a catalyst of the ionic or coordination type without deactivating the intermediate polymer using a catalyst of the anionic type
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/02—Making solutions, dispersions, lattices or gels by other methods than by solution, emulsion or suspension polymerisation techniques
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- C—CHEMISTRY; METALLURGY
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/45—Anti-settling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/36—Coatings with pigments
- D21H19/44—Coatings with pigments characterised by the other ingredients, e.g. the binder or dispersing agent
- D21H19/62—Macromolecular organic compounds or oligomers thereof obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
- C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
- C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
- C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2438/00—Living radical polymerisation
- C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/14—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Inorganic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Dispersion Chemistry (AREA)
- Paper (AREA)
- Macromonomer-Based Addition Polymer (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polyethers (AREA)
- Paints Or Removers (AREA)
- Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)
- Materials For Medical Uses (AREA)
- Medicinal Preparation (AREA)
- Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
- Ink Jet Recording Methods And Recording Media Thereof (AREA)
- Graft Or Block Polymers (AREA)
- Polyesters Or Polycarbonates (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Polymerisation Methods In General (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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FR0213999A FR2846971B1 (fr) | 2002-11-08 | 2002-11-08 | Utilisation d'un copolymere disposant d'au moins une fonction greffee alkoxy ou hydroxy polyalkylene glycol, comme agent ameliorant la brillance du papier et produits obtenus |
Publications (1)
Publication Number | Publication Date |
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ZA200503286B true ZA200503286B (en) | 2006-09-27 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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ZA200503286A ZA200503286B (en) | 2002-11-08 | 2003-11-07 | Copolymer having at least one alkoxy-or hydroxy-p oly-alkylene glycol grafted function, and use thereof |
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Country | Link |
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US (1) | US7825192B2 (es) |
EP (2) | EP1569970B1 (es) |
JP (2) | JP4741239B2 (es) |
KR (2) | KR101200632B1 (es) |
CN (1) | CN100558771C (es) |
AT (1) | ATE531740T1 (es) |
AU (1) | AU2003278489B2 (es) |
BR (1) | BR0316093B1 (es) |
CA (1) | CA2505074C (es) |
CO (1) | CO5650169A2 (es) |
DK (2) | DK1569970T3 (es) |
EA (1) | EA012405B1 (es) |
ES (2) | ES2422581T3 (es) |
FR (1) | FR2846971B1 (es) |
HR (2) | HRP20050507B1 (es) |
MX (1) | MXPA05004760A (es) |
MY (1) | MY139769A (es) |
NO (1) | NO335886B1 (es) |
NZ (1) | NZ565212A (es) |
PL (3) | PL211432B1 (es) |
PT (2) | PT1569970E (es) |
SI (2) | SI1569970T1 (es) |
TW (1) | TWI387606B (es) |
UA (1) | UA83353C2 (es) |
UY (1) | UY28066A1 (es) |
WO (1) | WO2004041883A1 (es) |
ZA (1) | ZA200503286B (es) |
Families Citing this family (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2846971B1 (fr) * | 2002-11-08 | 2006-09-29 | Omya Ag | Utilisation d'un copolymere disposant d'au moins une fonction greffee alkoxy ou hydroxy polyalkylene glycol, comme agent ameliorant la brillance du papier et produits obtenus |
FR2846978B1 (fr) * | 2002-11-08 | 2007-05-18 | Coatex Sas | Utilisation d'un copolymere disposant d'au moins une fonction greffee alkoxy ou hydroxy polyalkylene glycol, comme agent ameliorant l'activation de l'azurage optique et produits obtenus |
FR2885906A1 (fr) * | 2005-05-20 | 2006-11-24 | Coatex Soc Par Actions Simplif | Utilisation de polymeres hydrosolubles obtenus par polymerisation radicalaire controlee comme agent ameliorant l'opacite et/ou la brillance de produits secs les contenant |
EP1752499A1 (en) | 2005-07-25 | 2007-02-14 | Omya Development AG | Process to disperse and/or grind and/or concentrate calcium carbonate in aqueous media using an aqueous solution containing zirconium compounds |
FR2893031B1 (fr) * | 2005-11-04 | 2008-02-08 | Coatex Sas | Procede de fabrication d'une resine thermoplastique avec une resistance a l'impact amelioree mettant en oeuvre un polymere peigne avec au moins une fonction greffee oxyde de polyalkylene et resines obtenues. |
FR2894998A1 (fr) | 2005-12-16 | 2007-06-22 | Coatex Sas | Procede de fabrication de sauces de couchage a la retention d'eau et a la viscosite brookfield ameliorees mettant en oeuvre un polymere peigne avec au moins une fonction greffee oxyde de polyalkylene. |
FR2896171B1 (fr) | 2006-01-19 | 2010-12-17 | Omya Development Ag | Procede de fabrication de particules a base de carbonate de calcium naturel et de sels d'acide ethylene acrylique, suspensions et pigments secs obtenus, leurs utilisations. |
FR2913427B1 (fr) * | 2007-03-05 | 2011-10-07 | Omya Development Ag | Procede de broyage a sec d'un ou plusieurs materiaux comprenant au moins un carbonate de calcium |
FR2917091B1 (fr) * | 2007-06-08 | 2009-08-28 | Coatex S A S Soc Par Actions S | Procede de fabrication d'une formulation aqueuse a base de solution d'un polymere peigne acrylique et d'emulsion epaississante acrylique, formulation obtenue et ses utilisations dans le couchage papetier |
EP2075374A1 (fr) | 2007-12-17 | 2009-07-01 | Omya Development AG | Procédé de fabrication d'une sauce de couchage avec mise en oeuvre d'un epaississant acrylique à chaine hydrophobe ramifiée et sauce obtenue |
EP2208761B1 (en) | 2009-01-16 | 2012-10-10 | Omya Development AG | Process to prepare self-binding pigment particles implementing acrylic comb copolymers with hydrophobic groups as coupling agents, self binding pigment particles and uses thereof |
IT1393466B1 (it) | 2009-03-16 | 2012-04-20 | Lamberti Spa | Composizioni per la patinatura della carta |
IT1393465B1 (it) | 2009-03-16 | 2012-04-20 | Lamberti Spa | Poliuretano idrofilico a pettine |
FR2945964B1 (fr) * | 2009-05-28 | 2012-02-17 | Coatex Sas | Utilisation d'un polymere peigne (meth)acrylique contenant un ester (meth)acrylique comme agent dispersant et anti-demoussant dans une suspension aqueuse de sulfate de calcium hemihydrate |
SI2281853T1 (sl) | 2009-08-05 | 2012-09-28 | Omya Development Ag | Uporaba 2-amino-2-metil-1-propanola kot aditiva v vodnih suspenzijah materialov, ki obsegajo kalcijev karbonat |
FR2961211B1 (fr) | 2010-06-10 | 2012-07-27 | Coatex Sas | Polymeres peignes (meth)acryliques a fonction hydroxy polyalkylene glycol, leur utilisation comme agent rheofluidifiant dans des sauces de couchage et sauces les contenant. |
FR2963939B1 (fr) | 2010-08-19 | 2013-11-15 | Coatex Sas | Utilisation en sauces de couchage papetieres de polymeres (meth)acryliques peignes amphiphiles et non hydrosolubles |
FR2963934B1 (fr) | 2010-08-19 | 2013-10-25 | Coatex Sas | Polymeres (meth)acryliques peignes amphiphiles et non hydrosolubles |
IT1402689B1 (it) | 2010-09-15 | 2013-09-13 | Lamberti Spa | Poliuretani a pettine utili per la patinatura della carta |
IT1402349B1 (it) | 2010-09-15 | 2013-08-30 | Lamberti Spa | Composizioni per la patinatura della carta |
AU2012262405B2 (en) * | 2011-06-02 | 2016-02-25 | Dow Global Technologies Llc | Amphoteric polymer composition |
CN102432752B (zh) * | 2011-08-18 | 2013-08-07 | 江苏科技大学 | 苯乙烯马来酸酐共聚物酰亚胺化材料及其制备方法 |
ES2528746T3 (es) | 2011-11-11 | 2015-02-12 | Omya International Ag | Suspensiones acuosas de materiales que comprenden carbonato de calcio con baja formación de depósitos |
ITVA20110030A1 (it) | 2011-11-11 | 2013-05-12 | Lamberti Spa | Composizione acquosa di polimeri per la patinatura della carta |
FR2982887B1 (fr) * | 2011-11-18 | 2014-01-31 | Coatex Sas | Polymeres faiblement anioniques pour sauces de couchage destinees a des papiers pour impression de type jet d'encre |
DK2684999T3 (en) | 2012-07-13 | 2015-03-23 | Omya Int Ag | High solids and low viskøse- aqueous suspensions of calcium carbonate-comprising materials with improved rheological stability under elevated temperature |
US9126866B2 (en) * | 2013-03-06 | 2015-09-08 | Construction Research & Technology Gmbh | Polycarboxylate ethers with branched side chains |
ES2672208T3 (es) | 2014-11-07 | 2018-06-13 | Omya International Ag | Método de fabricación de una suspensión que comprende un material que comprende carbonato de calcio |
Family Cites Families (20)
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JPS58109700A (ja) * | 1981-12-22 | 1983-06-30 | サンノプコ株式会社 | 紙の表面処理剤および表面処理法 |
JPS6335899A (ja) * | 1986-07-30 | 1988-02-16 | 新王子製紙株式会社 | 分散剤 |
CN1092430A (zh) * | 1989-10-25 | 1994-09-21 | 陶氏化学公司 | 纸张涂料组合物用的胶乳共聚物 |
WO1994024202A1 (en) | 1992-04-07 | 1994-10-27 | The Dow Chemical Company | Latex copolymers for paper coating compositions |
CA2086047C (en) | 1992-12-22 | 1999-11-09 | Clint W. Carpenter | A process for the preparation of a modified copolymer as a pigment dispersant for aqueous coating compositions |
FR2707182B1 (fr) | 1993-07-09 | 1995-09-29 | Protex Manuf Prod Chimiq | Composition dispersante/fluidifiante à base de sel d'acide polyacrylique et de sel d'acide phosphonique pour suspensions concentrées de matières minérales. |
JPH0853522A (ja) * | 1994-08-11 | 1996-02-27 | Sanyo Chem Ind Ltd | 水系スラリー用分散剤 |
JPH0853354A (ja) | 1994-08-11 | 1996-02-27 | Hisamitsu Pharmaceut Co Inc | 皮膚疾患用水性貼付剤 |
JPH1030010A (ja) * | 1996-07-15 | 1998-02-03 | Toyo Ink Mfg Co Ltd | ノニオン系高分子界面活性剤、その製造方法、及びその顔料分散体 |
FR2766107B1 (fr) * | 1997-07-18 | 1999-08-20 | Pluss Stauffer Ag | Suspensions aqueuses de matieres minerales et leurs utilisations |
FR2766106B1 (fr) * | 1997-07-18 | 2001-09-07 | Coatex Sa | Utilisation d'un copolymere a structure tensio-active comme agent dispersant et/ou d'aide au broyage |
PL200670B1 (pl) * | 1998-12-28 | 2009-01-30 | Chugoku Marine Paints | Kopolimer sililo(met)akrylanowy, sposób jego wytwarzania, przeciwporostowa kompozycja do malowania zawierająca kopolimer sililo(met)akrylanowy oraz jej zastosowanie |
JP2000229233A (ja) * | 1999-02-09 | 2000-08-22 | Denki Kagaku Kogyo Kk | 無機粉末用分散剤 |
DE19926611A1 (de) | 1999-06-11 | 2000-12-14 | Sueddeutsche Kalkstickstoff | Copolymere auf Basis von ungesättigten Mono- oder Dicarbonsäure-Derivaten und Oxyalkylenglykol-Alkenylethern, Verfahren zu deren Herstellung und ihre Verwendung |
FR2810261B1 (fr) | 2000-06-15 | 2002-08-30 | Coatex Sa | Utilisation de copolymeres faiblement anioniques comme agent dispersant et/ou d'aide au broyage de suspension aqueuse de matieres minerales, suspensions aqueuses obtenues et leurs utilisations |
JP2002011338A (ja) | 2000-06-30 | 2002-01-15 | Lion Corp | 乳化剤及び乳化組成物 |
US6599973B1 (en) * | 2000-09-27 | 2003-07-29 | E. I. Du Pont De Nemours And Company | Aqueous graft copolymer pigment dispersants |
FR2846972B1 (fr) * | 2002-11-08 | 2005-02-18 | Omya Ag | Suspensions aqueuses de matieres minerales broyees, faiblement chargees ioniquement et leurs utilisations |
FR2846971B1 (fr) * | 2002-11-08 | 2006-09-29 | Omya Ag | Utilisation d'un copolymere disposant d'au moins une fonction greffee alkoxy ou hydroxy polyalkylene glycol, comme agent ameliorant la brillance du papier et produits obtenus |
FR2846978B1 (fr) * | 2002-11-08 | 2007-05-18 | Coatex Sas | Utilisation d'un copolymere disposant d'au moins une fonction greffee alkoxy ou hydroxy polyalkylene glycol, comme agent ameliorant l'activation de l'azurage optique et produits obtenus |
-
2002
- 2002-11-08 FR FR0213999A patent/FR2846971B1/fr not_active Expired - Lifetime
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2003
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- 2003-11-06 UY UY28066A patent/UY28066A1/es active IP Right Grant
- 2003-11-06 TW TW092131050A patent/TWI387606B/zh not_active IP Right Cessation
- 2003-11-07 ES ES10011527T patent/ES2422581T3/es not_active Expired - Lifetime
- 2003-11-07 WO PCT/IB2003/005082 patent/WO2004041883A1/fr active Application Filing
- 2003-11-07 AT AT03769789T patent/ATE531740T1/de active
- 2003-11-07 KR KR1020117022710A patent/KR101200632B1/ko not_active IP Right Cessation
- 2003-11-07 SI SI200332103T patent/SI1569970T1/sl unknown
- 2003-11-07 DK DK03769789.3T patent/DK1569970T3/da active
- 2003-11-07 MX MXPA05004760A patent/MXPA05004760A/es active IP Right Grant
- 2003-11-07 PT PT03769789T patent/PT1569970E/pt unknown
- 2003-11-07 NZ NZ565212A patent/NZ565212A/en not_active IP Right Cessation
- 2003-11-07 PL PL390344A patent/PL211432B1/pl unknown
- 2003-11-07 EA EA200500790A patent/EA012405B1/ru not_active IP Right Cessation
- 2003-11-07 PL PL380996A patent/PL211460B1/pl unknown
- 2003-11-07 ES ES03769789T patent/ES2377398T3/es not_active Expired - Lifetime
- 2003-11-07 CN CNB2003801041649A patent/CN100558771C/zh not_active Expired - Fee Related
- 2003-11-07 KR KR1020057008189A patent/KR101091313B1/ko not_active IP Right Cessation
- 2003-11-07 US US10/532,475 patent/US7825192B2/en active Active
- 2003-11-07 JP JP2004549498A patent/JP4741239B2/ja not_active Expired - Fee Related
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- 2003-11-07 PT PT100115278T patent/PT2275462E/pt unknown
- 2003-11-07 EP EP03769789A patent/EP1569970B1/fr not_active Expired - Lifetime
- 2003-11-07 EP EP10011527.8A patent/EP2275462B1/fr not_active Expired - Lifetime
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- 2003-11-07 PL PL390343A patent/PL211433B1/pl unknown
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- 2003-11-07 CA CA2505074A patent/CA2505074C/fr not_active Expired - Fee Related
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2005
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2010
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2014
- 2014-01-07 HR HRP20140008AA patent/HRP20140008A2/hr not_active Application Discontinuation
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