WO2021200647A1 - 重合体粒子 - Google Patents

重合体粒子 Download PDF

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Publication number
WO2021200647A1
WO2021200647A1 PCT/JP2021/012847 JP2021012847W WO2021200647A1 WO 2021200647 A1 WO2021200647 A1 WO 2021200647A1 JP 2021012847 W JP2021012847 W JP 2021012847W WO 2021200647 A1 WO2021200647 A1 WO 2021200647A1
Authority
WO
WIPO (PCT)
Prior art keywords
polymer particles
meth
particles
monomer
less
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2021/012847
Other languages
English (en)
French (fr)
Japanese (ja)
Inventor
直樹 今津
佐藤　謙一
信康 甲斐
美月 杉浦
智幸 小田島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Toray Industries Inc
Original Assignee
Toray Industries Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Toray Industries Inc filed Critical Toray Industries Inc
Priority to JP2021517705A priority Critical patent/JPWO2021200647A1/ja
Priority to KR1020227014372A priority patent/KR20220162685A/ko
Priority to CN202180006607.9A priority patent/CN114729085A/zh
Publication of WO2021200647A1 publication Critical patent/WO2021200647A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/22—Esters containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/281—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing only one oxygen, e.g. furfuryl (meth)acrylate or 2-methoxyethyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/1006—Esters of polyhydric alcohols or polyhydric phenols
    • C08F222/102—Esters of polyhydric alcohols or polyhydric phenols of dialcohols, e.g. ethylene glycol di(meth)acrylate or 1,4-butanediol dimethacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F222/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical and containing at least one other carboxyl radical in the molecule; Salts, anhydrides, esters, amides, imides, or nitriles thereof
    • C08F222/10—Esters
    • C08F222/12—Esters of phenols or saturated alcohols
    • C08F222/18—Esters containing halogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F290/00—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
    • C08F290/02—Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups on to polymers modified by introduction of unsaturated end groups
    • C08F290/04—Polymers provided for in subclasses C08C or C08F
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Definitions

  • the lower limit of the elastic modulus of the particle film made of polymer particles is preferably 0.1 GPa or more, more preferably 0.5 GPa or more, and further preferably 0.7 GPa or more.
  • the upper limit of the elastic modulus of the particle film made of polymer particles is preferably less than 1.7 GPa, more preferably 1.4 GPa or less, and further preferably 1.2 GPa or less.
  • the amount of the (meth) acrylic acid ester monomer (B) is preferably 30% by mass or more of the total amount of the monomers.
  • the amount of the chain transfer agent used is preferably about 0 to 10 parts by mass per 100 parts by mass of the monomer mixture.
  • Example 2 Polymer particles were obtained in the same manner as in Example 1 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 1. The obtained polymer particles were as shown in Table 1.
  • Example 3 The cross-linking agent (D) was changed to polyalkylene glycol dimethacrylate PDE-600 (manufactured by NOF CORPORATION, Tg of a polymer obtained by polymerizing polyalkylene glycol dimethacrylate PDE-600: -34 ° C.), and a monomer mixture was prepared.
  • Polymer particles were obtained in the same manner as in Example 1 except that the composition ratio was changed to the composition shown in Table 1. The obtained polymer particles were as shown in Table 1.
  • Example 4 Polymer particles were obtained in the same manner as in Example 3 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 1. The obtained polymer particles were as shown in Table 1.
  • Example 6 Examples except that the cross-linking agent (D) was changed to polyalkylene glycol diacrylate ADP-400 (manufactured by NOF CORPORATION, Tg of a polymer obtained by polymerizing polyalkylene glycol diacrylate ADP-400: -9 ° C.). Polymer particles were obtained in the same manner as in 1. The obtained polymer particles were as shown in Table 1.
  • Example 8 Polymer particles were obtained in the same manner as in Example 3 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 1. The obtained polymer particles were as shown in Table 1.
  • Example 11 Polymer particles were obtained in the same manner as in Example 3 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 2. The obtained polymer particles were as shown in Table 2.
  • Example 12 Polymer particles were obtained in the same manner as in Example 3 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 2. The obtained polymer particles were as shown in Table 2.
  • Comparative Example 2 Polymer particles were obtained in the same manner as in Example 1 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 2. The obtained polymer particles were as shown in Table 2.
  • Comparative Example 3 Polymer particles were obtained in the same manner as in Comparative Example 1 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 2. The obtained polymer particles were as shown in Table 2.
  • Comparative Example 4 Polymer particles were obtained in the same manner as in Example 3 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 2. The obtained polymer particles were as shown in Table 2.
  • Comparative Example 5 Polymer particles were obtained in the same manner as in Example 9 except that the composition ratio of the monomer mixture was changed to the composition shown in Table 2. The obtained polymer particles were as shown in Table 2.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)
PCT/JP2021/012847 2020-03-31 2021-03-26 重合体粒子 Ceased WO2021200647A1 (ja)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP2021517705A JPWO2021200647A1 (https=) 2020-03-31 2021-03-26
KR1020227014372A KR20220162685A (ko) 2020-03-31 2021-03-26 중합체 입자
CN202180006607.9A CN114729085A (zh) 2020-03-31 2021-03-26 聚合物粒子

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2020062392 2020-03-31
JP2020-062392 2020-03-31

Publications (1)

Publication Number Publication Date
WO2021200647A1 true WO2021200647A1 (ja) 2021-10-07

Family

ID=77929403

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2021/012847 Ceased WO2021200647A1 (ja) 2020-03-31 2021-03-26 重合体粒子

Country Status (4)

Country Link
JP (1) JPWO2021200647A1 (https=)
KR (1) KR20220162685A (https=)
CN (1) CN114729085A (https=)
WO (1) WO2021200647A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023053956A1 (ja) * 2021-09-30 2023-04-06 東レ株式会社 重合体粒子

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000355603A (ja) * 1999-06-14 2000-12-26 Nippon Shokubai Co Ltd 水性樹脂分散体の製造方法
JP2008056900A (ja) * 2006-07-31 2008-03-13 Dainippon Ink & Chem Inc 紙製畳表加工用水性樹脂分散体、及びそれを被覆加工してなる紙製畳表
JP2012201862A (ja) * 2011-03-28 2012-10-22 Sekisui Plastics Co Ltd 重合体粒子およびその用途

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS6011608B2 (ja) 1978-09-29 1985-03-27 日精樹脂工業株式会社 射出成形機のパ−ジング方法
JPS577829A (en) 1980-06-18 1982-01-16 Toshiba Ceramics Co Ltd Colored quartz glass tube as heating element for heating
FR2725721B1 (fr) * 1994-10-18 1998-12-04 Atochem Elf Sa Latex et melanges de latex acryliques et methacyliques fluores, leurs procedes de fabrication et leurs applications dans le domaine des revetements hydrophobes
EP2297215B1 (en) 2008-07-07 2016-07-27 Arkema Inc. Fluoropolymer aqueous hybrid compositions with improved film formation
KR20160104613A (ko) * 2013-12-27 2016-09-05 세키스이가가쿠 고교가부시키가이샤 광학용 점착제, 광학용 점착 테이프 및 적층체
WO2019230956A1 (ja) * 2018-06-01 2019-12-05 積水化学工業株式会社 粘着シート
JP6773922B1 (ja) * 2018-11-22 2020-10-21 東レ・ファインケミカル株式会社 フッ素含有重合体粒子
KR20240109316A (ko) * 2023-01-03 2024-07-11 삼성디스플레이 주식회사 수지 조성물, 접착 부재, 및 접착 부재를 포함하는 표시 장치
JP2024143794A (ja) * 2023-03-30 2024-10-11 株式会社カネカ 水系塗料

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2000355603A (ja) * 1999-06-14 2000-12-26 Nippon Shokubai Co Ltd 水性樹脂分散体の製造方法
JP2008056900A (ja) * 2006-07-31 2008-03-13 Dainippon Ink & Chem Inc 紙製畳表加工用水性樹脂分散体、及びそれを被覆加工してなる紙製畳表
JP2012201862A (ja) * 2011-03-28 2012-10-22 Sekisui Plastics Co Ltd 重合体粒子およびその用途

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2023053956A1 (ja) * 2021-09-30 2023-04-06 東レ株式会社 重合体粒子

Also Published As

Publication number Publication date
JPWO2021200647A1 (https=) 2021-10-07
CN114729085A (zh) 2022-07-08
KR20220162685A (ko) 2022-12-08

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