WO2018133258A1 - 转移染色方法 - Google Patents

转移染色方法 Download PDF

Info

Publication number
WO2018133258A1
WO2018133258A1 PCT/CN2017/083967 CN2017083967W WO2018133258A1 WO 2018133258 A1 WO2018133258 A1 WO 2018133258A1 CN 2017083967 W CN2017083967 W CN 2017083967W WO 2018133258 A1 WO2018133258 A1 WO 2018133258A1
Authority
WO
WIPO (PCT)
Prior art keywords
transfer
dyeing
roller
roll
fabric
Prior art date
Application number
PCT/CN2017/083967
Other languages
English (en)
French (fr)
Inventor
钟博文
Original Assignee
长胜纺织科技发展(上海)有限公司
钟博文
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 长胜纺织科技发展(上海)有限公司, 钟博文 filed Critical 长胜纺织科技发展(上海)有限公司
Priority to EP17892141.7A priority Critical patent/EP3572232B1/en
Priority to US16/326,261 priority patent/US10618272B2/en
Priority to JP2019537144A priority patent/JP6865287B2/ja
Priority to ES17892141T priority patent/ES2952548T3/es
Publication of WO2018133258A1 publication Critical patent/WO2018133258A1/zh

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/002—Locally enhancing dye affinity of a textile material by chemical means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F16/00—Transfer printing apparatus
    • B41F16/02—Transfer printing apparatus for textile material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41F—PRINTING MACHINES OR PRESSES
    • B41F31/00—Inking arrangements or devices
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/46—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing natural macromolecular substances or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/003—Transfer printing
    • D06P5/007—Transfer printing using non-subliming dyes

Definitions

  • the invention relates to printing and dyeing technology in the textile industry, in particular to a transfer dyeing method.
  • Each type of dye is further divided into groups according to different dyeing properties and process conditions.
  • the same fiber can often be dyed with several dyes, and the same dye can often be used for dyeing and printing of several different fibers.
  • the dyeing mechanism and dyeing process applied in dyeing and printing are designed according to the actual situation.
  • a large number of regulations on printing and dyeing environmental protection regulations were introduced, which caused many dyeing factories to face the pressure of research and development.
  • the old dyeing and printing technology is gradually being eliminated.
  • the market and society need printing and dyeing enterprises to save energy, protect the environment, control costs, improve efficiency, improve quality and other topics closely related to society.
  • New science and technology, information technology and new processes are introduced into the production process of textile printing and dyeing.
  • Dyeing is a process in which the dye is physically or chemically combined with the fiber, or a chemical is used to form a pigment on the fiber to impart a certain color to the entire textile. Dyeing is carried out under conditions of temperature, time, pH and the desired dyeing aid. The dyed product should have a uniform color and good dye fastness.
  • the dyeing methods of the existing fabrics are mainly divided into dip dyeing and padding. Dip dyeing is a method of immersing a fabric in a dyeing liquid to gradually dye the dye, which is suitable for dyeing in small batches and varieties. Rope dyeing and dyeing all fall into this category.
  • Dyeing is a dyeing method in which the fabric is first immersed in the dyeing liquid, and then the fabric is passed through a roll to uniformly roll the dyeing liquid into the interior of the fabric, and then subjected to steaming or hot-melting treatment, which is suitable for dyeing large-volume fabrics.
  • the traditional dyeing process of dyeing fibers can be described as follows: first, the dye reaches the fiber around the dye bath; secondly, the dye diffuses by its own thermal motion, and the liquid layer around the fiber approaches the fiber surface; The action is absorbed by the fiber, and the dye around the fiber The bath concentration is then reduced; finally the dye diffuses into the fiber and is adsorbed in the amorphous region of the fiber.
  • the dye bath method is actually an extensive production method, and the water consumption in the production process is huge, and a large amount of dye-containing colored wastewater is generated after washing.
  • 1 ton of textiles per 100 tons of textiles consumes 100 to 200 tons of water, of which 80 to 90% become wastewater. It is one of the major emitters in various industries.
  • Printing and dyeing wastewater generally has the characteristics of high concentration of pollutants, various types, large alkalinity, large changes in water quality, high COD content, high toxic and harmful components and high chroma, and is one of the industrial wastewaters that are difficult to treat.
  • the quality of personal and family life has improved, people's demand for environmental protection and health has become stronger and stronger.
  • the polymer film layer prevents the dye from diffusing into the fiber, so that the dye adheres to the surface of the fiber, and finally realizes the dye by steaming, baking and the like. Fixed. Therefore, dyeing by printing is one of the directions to achieve energy saving and emission reduction.
  • the present invention provides a method of transfer dyeing, which can overcome the shortcomings of the existing dyeing process and improve the quality of dyeing.
  • the transfer dyeing method has the following steps:
  • step 2 According to the dyeing requirements of double-sided color or double-sided color, the same or different dye inks as in step 2 will pass the first Two full-page printing plate rolls are printed on the second transfer roller or the ink transfer blanket;
  • the pretreatment liquid formulation in the step 1 is based on the weight percentage of each component:
  • the binder is sodium alginate, or guar gum, or synthetic longan, or cellulose and its derivatives, or starch and its derivatives, or a multicomponent polymer of acrylic acid, crotonic acid and its derivatives;
  • the surfactant is polyvinylpyrrolidone, or polyoxyethylene alkylamine, or fatty alcohol polyoxyethylene ether, or polysiloxane;
  • the leveling agent is sodium alkyl sulfonate, or higher fatty acid sodium sulfate, or fatty alcohol polyoxyethylene;
  • the fixing agent, the fixing agent in the pretreatment liquid for reactive dye ink is sodium carbonate, or sodium hydrogencarbonate, or sodium hydroxide, or potassium carbonate, or potassium hydrogencarbonate, or potassium hydroxide, or a substitute base;
  • the fixing agent in the pretreatment liquid for acid dye ink is urea or dicyandiamide; the pretreatment liquid for disperse dye ink is not used to fix the toner;
  • the pH adjusting agent is citric acid, or acetic acid, or ammonium sulfate; or triethanolamine.
  • the anilox roll in the step 1 is a laser-engraved chrome-plated anilox roll or a ceramic anilox roll, and the number of lines is 60-200 lines/cm.
  • the dye ink is a dyed ink disclosed in the art.
  • the plate roll is a gravure roll, or a flexographic plate roll, or a rotary screen, or an offset plate roll.
  • the surface of the ink transfer roller or the ink transfer blanket is made of a rubber coating layer, the rubber coating layer has a thickness of 3-15 mm, and the rubber is urethane rubber, or nitrile rubber, or neoprene rubber, or chlorosulfonated.
  • Polyethylene rubber, or ethylene propylene rubber has a surface hardness of 45-90 degrees Shore.
  • the fixing color in the step 8 is cold stacking, or steaming fixing, or baking fixing.
  • the steps 2 and 3 may be performed in a dyeing unit of a dyeing apparatus comprising: a center roll mounted to the frame; and at least one dyeing set device, the at least one dyeing unit
  • the sleeve device is distributed around the circumference of the center roll, and the fabric to be dyed enters between the center roll and each dyeing set device for dyeing, wherein each dyeing set device comprises the full-length printing plate roll carrying the dyed ink of the bottom plate.
  • the steps 6 and 7 are also carried out in a dyeing unit of a dyeing apparatus comprising: a center roll mounted to the frame; and at least one dyeing set device, the at least one dyeing unit
  • the sleeve device is distributed around the circumference of the center roll, and the fabric to be dyed enters between the center roll and each dyeing set device for dyeing, wherein each dyeing set device comprises the full-length printing plate roll carrying the dyed ink of the bottom plate.
  • the outer diameter of the printing plate ⁇ the outer diameter of the transfer roller ⁇ the outer diameter of the printing plate roll +1 mm.
  • each dyeing jacket device further includes a pressure applying assembly for variably providing pressure of the ink transfer roller against the printing plate roller, wherein the pressure applying assembly enables the ink transfer roller Selectively moving to the pressing position and the rest position, in the pressing position, the transfer roller presses against the printing plate roller, thereby generating the pressure of the transfer roller against the printing plate roller; in the rest position, the transfer roller is not pressed Printing plate roll.
  • a pressure applying assembly for variably providing pressure of the ink transfer roller against the printing plate roller, wherein the pressure applying assembly enables the ink transfer roller Selectively moving to the pressing position and the rest position, in the pressing position, the transfer roller presses against the printing plate roller, thereby generating the pressure of the transfer roller against the printing plate roller; in the rest position, the transfer roller is not pressed Printing plate roll.
  • the pressing component comprises a rotatable eccentric bushing, and a shaft end of the ink transfer roller is rotatably mounted in the eccentric bushing, and the transfer roller and the printing plate roller can be adjusted by rotating the eccentric bushing The distance between them thereby adjusts the pressure of the resulting transfer roller against the printing plate roll.
  • the transfer roller can be selectively moved to a plurality of pressing positions by rotating the eccentric bushing.
  • the pressing assembly further includes a connecting rod for driving the rotation of the eccentric bushing and a swing arm for moving the connecting rod, one end of the connecting rod is connected to the eccentric bushing, The other end of the connecting rod is coupled to the swing arm, the swing arm being pivotable relative to the body of the dyeing jacket device by a swing arm pivot.
  • the pressure applying assembly further includes an actuator that drives the swing arm to pivot, and pivoting of the swing arm causes the link to drive the eccentric bushing to rotate, thereby moving the ink transfer roller to the pressure Location or rest position.
  • one of the pressure applying assemblies is provided on each of the two axial end sides of the transfer roller.
  • one of the pressure applying assemblies is provided on each of the two axial end sides of the transfer roller, and the swing arm on one axial end side and the swing arm on the other axial end side are pivoted by the same swing arm pivot. Pivot, thereby achieving two connecting rods, eccentric bushings Synchronous movement to maintain simultaneous pressure on the two shaft ends of the printing plate roll.
  • only one of the pressing members located on the two axial end sides of the transfer roller includes an actuator for driving the swing arm to pivot.
  • the swing arm includes a first arm and a second arm, each arm portion including a first end and a second end, the first end of the first arm being pivotally coupled to the a projecting end of the second arm, the first end of the second arm being pivotally coupled to the other end of the link by a pin, the second ends of the two arms being non-rotatably fixed to the swing arm On the end of the pivot.
  • the swing arm includes a first arm and a second arm, each arm portion including a first end and a second end, the first end of the first arm being pivotally coupled to the a projecting end of the second arm, the first end of the second arm being pivotally coupled to the other end of the link by a pin, the second ends of the two arms being non-rotatably fixed to the swing arm On the end of the pivot.
  • the center roll is a hard material roll whose surface is covered with rubber and is filled with oil, and the hard material roll heats the oil through an electric heating rod built in the cavity, thereby controlling the temperature of the center roll.
  • each of the dyeing jacket devices further includes a propulsion device for providing a propulsive force for advancing the ink transfer roller toward the center roller, the propulsion device being mounted on the frame of the dyeing jacket device.
  • each dyeing jacket device can be advanced or moved independently toward the center roller by means of a respective propulsion device.
  • the propulsion device also provides an independently adjustable pressure that causes the transfer roller to abut the fabric to be dyed on the center roll.
  • each of the dyeing jacket devices further includes a frame in which the mounting block is disposed, the transfer roller and the printing plate roller are rotatably mounted into the mounting block, and are mounted under the push of the propulsion device The block is movable within the frame towards the center roll.
  • a slide rail is disposed in the frame, and the mounting block can slide on the slide rail.
  • the axes of the transfer roller, printing plate roll, and center roll are parallel to each other but not coplanar.
  • each dyeing set device further includes a pressure lock for locking the pressure between the transfer roller and the printing plate roll.
  • the invention has the advantages that the dyeing method of transfer dyeing is adopted instead of the traditional dyeing or tie-dying method, so that only the surface of the fabric is dyed, and the inside of the fabric and the non-visible portion are not filled with dye, so the degree of the dye is greatly Saves the amount of dye and water consumption; on-demand dyeing, proper dyeing, and high fixing rate, so water consumption
  • the amount of waste is small, the generated waste water is less; the mode of treating with the pretreatment liquid and then dyeing and fixing, the pattern of the fixing agent for non-conventional dyeing and the dyeing of the dye to ensure the storage stability of the dye ink; It can be dyed on one side, dyed on both sides, can be dyed in a single color, or it can be dyed on both sides, which meets the market demand for dyed fabrics.
  • FIG. 1 is a flow chart of a transfer dyeing method in accordance with an embodiment of the present invention.
  • Fig. 2 is an overall schematic view of a transfer dyeing apparatus embodying this embodiment, which can perform double-sided dyeing.
  • Figure 3 is a schematic illustration of the dyeing unit of the transfer dyeing apparatus.
  • Figure 4 is a schematic illustration of a single dyeing set of the dyeing unit.
  • Figure 5 is a cross-sectional view of the single dyeing jacket of the dyeing unit taken along the axial direction of the actuator, swing arm, connecting rod, eccentric bushing, and the like.
  • Figure 6 is a schematic illustration of the force and positional relationship of a single dyeing jacket and center roll in accordance with the present invention.
  • Example 1 Double-sided heterochromatic transfer dyeing of cotton fabric.
  • Fabric specifications 100% cotton knit 150g/m 2 .
  • the double-sided heterochromatic transfer dyeing method of cotton fabric has the following steps:
  • FIG. 1 shows a flow chart of Embodiment 1.
  • the first anilox roll and the second anilox roll may be the same roll or two different rolls.
  • the pretreatment liquid formulation is based on the weight percentage of each component:
  • the binder is sodium alginate
  • the surfactant is a polyoxyethylene alkylamine
  • the leveling agent is a high-grade fatty alcohol sodium sulfate
  • the fixing agent is an alkali agent in which sodium hydrogencarbonate, sodium carbonate and potassium carbonate are mixed in a weight ratio of 1:4:2;
  • the anilox roll was a laser-engraved ceramic anilox roll having a line number of 60 lines/cm.
  • the dye ink is an active dye ink as disclosed in the art.
  • the full-plate printing plate roll is a gravure roll.
  • the surface of the transfer roller is made of a rubber coating layer having a thickness of 3 mm, and the rubber is a urethane rubber having a surface hardness of 90 degrees Shore.
  • the fixing color in the step 8 was cold stacking, 25 ° C, and cold stacking for 6 hours.
  • Nylon fabric double-sided color transfer dyeing method the steps are as follows:
  • step 6 printing the same dye ink as in step 2 on the other set of ink transfer blankets by the second full-page printing plate roll;
  • the reverse surface superficial nylon fabric in the step 5 and the ink transfer blanket in the step 6 are in close pressure contact, and the dye ink is transferred from the ink transfer blanket to the reverse side of the fabric, thereby realizing the color on the reverse side of the fabric;
  • the pretreatment liquid formulation is based on the weight percentage of each component:
  • the binder is sodium carboxymethyl cellulose
  • the surfactant is a fatty alcohol polyoxyethylene ether
  • the leveling agent is a fatty alcohol polyoxyethylene
  • the fixing agent is an alkali agent in which urea and dicyandiamide are mixed in a weight ratio of 2:1;
  • the pH adjusting agent is ammonium sulfate.
  • the anilox roll was a laser-engraved chrome-plated anilox roll having a line number of 120 lines/cm.
  • the dye ink is an acid dyed ink disclosed in the art.
  • the full-page printing plate roll is a flexographic plate roll.
  • the ink transfer blanket belt has a surface coated with a rubber coating layer, a rubber coating layer having a thickness of 8 mm, and the rubber is a nitrile rubber having a surface hardness of 75 degrees Shore.
  • the fixing color in the step 8 is steam-fixing, 103 ° C, and steaming for 20 min.
  • Fabric Polyester ramie; Fabric specifications: Raw material is polyester 111dtex (DTY) ⁇ 111dtex (DTY), density is 256 ⁇ 256 / 10cm, weight is 142g / m2.
  • the single-side transfer dyeing method of polyester fabric has the following steps:
  • the pretreatment liquid is uniformly coated on the front surface of the fabric to form a polyester fabric having a front surface wet state by means of an anilox roll coating;
  • the dye ink is printed on the transfer roller by a full-plate roll
  • the fabric in the front surface of the wet state in the step 1 is closely adhered to the transfer roller in the step 2, and the pressure ink is transferred from the transfer roller to the front side of the fabric to realize the front dyeing of the polyester fabric;
  • the fabric After the fabric is dried, it is solidified, washed with water, and shaped, which is the finished product.
  • the pretreatment liquid formulation in the step 1 is based on the weight percentage of each component:
  • the binder is methyl methacrylate, butyl acrylate, acrylic acid terpolymer
  • the surfactant is polyvinylpyrrolidone
  • the leveling agent is sodium alkyl sulfonate
  • the anilox roll in the step 1 was a laser-engraved chrome-plated anilox roll having a line number of 200 lines/cm.
  • the dye ink in step 2 is a dispersion dyed ink disclosed in the art.
  • the printing plate roller in the step 2 is an offset plate roller.
  • the surface of the transfer roller in the step 2 is made of a rubber coating layer having a thickness of 15 mm, and the rubber is a neoprene rubber having a surface hardness of 45 degrees Shore.
  • the fixing color in the step 8 is baking fixing, 180 ° C, fixing for 20 min.
  • FIG. 2 shows a transfer dyeing effect of the transfer dyeing method according to the above-described Embodiment 1 of the present invention.
  • Color equipment When dyeing, the fabric passes through the following parts of the transfer dyeing device in sequence: a compacting frame 201; a dust removing unit 300; a two-roller active expanding device 401; a centering device 601; a tension controller 603; an active traction device 602; a processor 1100; a first tension swing device 604; a first sizing pre-expansion device 402; a first sizing device 701 and a second dehumidifying device 702 for sizing the fabric prior to dyeing the first side of the fabric Dehumidification; a second tension swing device 604'; a first correcting unit 800; a first dyeing unit 100 for performing a dyeing operation on the first side of the fabric; a drying unit 1000; a second sizing pre-expansion device 402'; a second sizing device 701
  • the first dyeing unit 100 is used to implement steps 2 and 3 in the above embodiment 1.
  • the second dyeing unit 100' is used to implement steps 6 and 7.
  • the structure of the second dyeing unit 100' is similar to that of the first dyeing unit 100. For convenience of description, only the first dyeing unit 100 will be described below, and is simply referred to as the dyeing unit 100.
  • the dyeing unit is the core of the overall dyeing apparatus and comprises mainly at least one dyeing jacketing device 5 and a central roller 1, as will be described in more detail below.
  • Each dyeing set device includes a full-plate printing plate roll.
  • the full-length printing plate roll is a gravure roll, but is not limited thereto.
  • the full-length printing plate roll may be an anilox roll (full-page gravure printing roll), a full-plate flexographic printing roll, a full-bottom rotary screen printing roll or a full-surface offset printing plate roll.
  • the center roller and each dyeing unit are independently driven by an AC servo motor.
  • the motion controller in the central control unit connects each AC servo motor through a high-speed field bus, thereby achieving high precision of the center roller and each dyeing unit. Synchronous control.
  • the dyeing unit adopts AC servo motor and motion controller, which can realize pre-registration function and greatly reduce material waste.
  • the dyeing unit 100 includes at least one dyeing jacket device.
  • the dyeing unit 100 mainly includes a center roll 1 and at least one dyeing jacket device 5.
  • the dyeing unit employs a satellite structure, and the at least one dyeing jacket device shares a center roller as a back pressure roller.
  • the center roll 1 is fixedly attached to the frame 12 by bearings.
  • the center roller 1 can be driven to rotate by the inverter motor 13.
  • the center roll 1 may be a hard material roll coated with rubber.
  • the surface rubber has a Shore hardness of 85 to 90 degrees, preferably 90 degrees.
  • the outer diameter of the center roll 1 may be 1600-2000 mm, preferably 1800 mm.
  • the center roll can be filled with oil by a cavity, and the oil is heated by an electric heating rod built in the cavity, so that the temperature of the center roll 1 can be raised to 30-150 °C.
  • those skilled in the art can control the temperature of the center roller by other heating methods according to actual needs.
  • the central roller can be heated and heated to stably transfer the dyeing temperature, avoiding a large temperature difference due to seasonal changes or day and night changes, resulting in unstable product quality between batches; and for some high-density and high-density fabrics, the heat to be further expanded by heating Fabric fibers, thereby increasing the dye uptake rate and dyeing speed.
  • At least one (for example, 2-8, 6 shown in Fig. 3) dyeing jacket means 5 is distributed around the circumference of the center roll 1.
  • Each dyeing jacket device 5 independently provides its propulsion force toward the center roller 1 by a respective propulsion device, such as a propulsion cylinder 506.
  • the push cylinder 506 is mounted on the body of each dyeing jacket device 5, for example, on the frame 501 of the body.
  • the transfer dyeing apparatus may further comprise a guide roller 4. More preferably, at least two guide rolls 4 are provided. At least one guide roller is disposed in the vicinity of the inlet and the outlet in contact with the center roll of the fabric to be dyed.
  • the guide roller 4 guides the fabric 2 into or out of a pressurized section between the center roll 1 and the dyeing jacket device 5.
  • each of the guide rolls 4 may be a hard material roll.
  • Each guide roller may have an outer diameter of 100-150 mm.
  • a drying box 7 may be disposed between each of the dyeing jacket devices 5 for ensuring drying of the ink after printing and preventing coloring of the color between the multiple registrations.
  • five drying boxes 7 are provided which are alternately distributed with the six dyeing jacket devices 5 on the periphery of the circumference of the center roller 1.
  • the transfer dyeing apparatus may further comprise an in-line center roll cleaning system 15 disposed in the non-pressurized section of the center roll 1 and the dyeing jacket apparatus 5.
  • the online center roller cleaning system 15 includes a cleaning device, a wiper blade and an oven. After the surface of the center roller 1 is cleaned by the cleaning device, the surface moisture of the center roller 1 is scraped off by a wiper blade, and then dried in an oven to realize continuous cycle application.
  • the cleaning device can include a showerhead and a brush.
  • the dyeing jacket device 5 can include the above-described propulsion device (e.g., propulsion cylinder 506), ink fountain assembly 510, anilox roller 511, ink transfer roller 512, and a pressure applying assembly.
  • the ink fountain assembly 510, the anilox roller 511, the transfer roller 512, and the pressing assembly are mounted in the frame 501.
  • the transfer roller 512 is located between the anilox roller 511 and the center roller 1, and is in contact with the anilox roller 511.
  • the respective axial ends of the transfer roller 512 and the anilox roller 511 can be mounted into a mounting block 502 in the frame 501.
  • the mounting block 502 can slide on a slide rail disposed in the frame 501, so that Under the advancing action of the inlet cylinder 506, the mounting block 502 is moved in the direction of the center roll 1 so that the transfer roller 512 reaches a position in contact with the fabric to be dyed on the center roll 1.
  • the push cylinder 506 can also provide a pressure that causes the transfer roller 512 to abut against the fabric to be dyed on the center roll 1.
  • the pressure provided by each of the push cylinders 506 to urge the transfer rollers 512 against the fabric to be dyed on the center roll 1 can be independently adjustable. The pressure is adjusted by the control system, and can be stepped up according to the program or gradually decreased according to the program.
  • the entire dyeing jacket device 5 is pushed by the propulsion cylinder 506 along the linear slide rail to achieve clutching with the center roller, and the clutch stroke can be 2-5 cm.
  • the outer diameter of the anilox roll 511 can be selected for use, and is usually 95-200 mm in outer diameter.
  • the anilox roller 511 is associated with an ink fountain assembly 510.
  • the ink supply system delivers ink into the ink chamber formed between the ink fountain assembly 510 and the anilox roller 511.
  • the anilox roller 511 can be driven by a servo motor and synchronized with the anilox roller 511 of the other dyeing jacket device 5 to ensure registration accuracy.
  • the transfer roller 512 may be a hard material roll coated with rubber.
  • the surface can be covered with a seamless rubber.
  • the rubber is natural rubber, styrene butadiene rubber, urethane rubber or other rubber having good affinity for aqueous ink.
  • the surface of the transfer roller 512 has a Shore Shore hardness of 85-90 degrees, more preferably 90 degrees.
  • each dyeing set device transfer roller 512 is a rubber-coated hard material roll
  • the outer diameter of the transfer roller 512 is slightly larger than the anilox roll 511, thus providing a certain capacity while ensuring the integrity of the transfer dye ink. Poor space.
  • the rubber transfer roller is in contact with the anilox roller, the rubber of the rubber transfer roller is deformed by a certain pressure under the action of the propelling device and the pressing force of the pressing component; When the current surface of the roller is turned away from the rubber surface of the rubber transfer roller, the rubber surface can be quickly restored to its original shape.
  • the dyeing device according to the invention has strong pressure bearing capability and high precision, and can completely carry the dyeing ink, thereby ensuring the registration precision of the dyed ink after transfer; in addition, the compression deformation of the rubber is small, so that it can withstand thousands of times per hour. Compression, no compression fatigue during the production cycle and permanent deformation.
  • the pressing assembly can be used to provide an adjustable pressure of the transfer roller 512 against the anilox roller 511.
  • the pressing component is used to adjust the amount of ink to control the chromatic aberration, and the pressure is mainly used to stick the amount of ink in the anilox roll cell.
  • the pressure applying assembly includes an actuator 509 and an eccentric bushing 503.
  • the actuator 509 includes a cylinder block and a piston rod.
  • the cylinder is pivotally coupled to the mounting block 502.
  • the actuator 509 can be of a hydraulic type, a pneumatic type, or an electric type. Where the actuator 509 is of the hydraulic or pneumatic type, the length of the piston rod extension can be adjusted by adjusting the fluid pressure within the chamber of the cylinder.
  • the actuator 509 can be a servo actuator, such as a servo electric cylinder.
  • the pressure applying assembly can also include a swing arm 508 and a link 516.
  • the swing arm 508 is pivotally coupled to the mounting block 502 by a swing arm pivot 504.
  • the swing arm 508 includes a first end and a second end.
  • the first end of the swing arm 508 is pivotally coupled to the extended end of the piston rod of the actuator 509 by a pin.
  • the second end of the swing arm 508 is pivotally coupled to one end of the link 516 by a pin.
  • the other end of the link 516 is pivotally coupled to the eccentric bushing 503.
  • a handle may be provided at the end of the swing arm pivot to manually adjust the rotation of the eccentric bushing 503 by the operator during the commissioning phase.
  • the swing arm 508 can include a first arm 5081 and a second arm 5082.
  • Each arm includes a first end and a second end.
  • the first end may be a small end and the second end may be a big end.
  • the first end of the first arm 5081 is pivotally coupled to the extended end of the piston rod of the actuator 509 by a pin.
  • the first end of the second arm 5082 is pivotally coupled to one end of the link 516 by a pin. Both the first arm 5081 and the second end of the second arm 5082 are non-pivotablely coupled to the swing arm pivot 504.
  • the second end may be provided with a pivot hole, and the swing arm pivot is fixed to the pivot hole of the second end by a keyway engagement, a positioning pin and a pin hole connection, or an interference fit.
  • the swing arm pivot 504 is pivotally mounted to the mounting block 502.
  • the swing arm pivot 504 extends axially outward from the mounting block 502 to form an extension.
  • the extension can be used to connect the second ends of the first arm 5081 and the second arm 5082.
  • the other end of the link 516 is pivotally coupled to the eccentric bushing 503 by a pin.
  • the eccentric bushing 503 is sleeve-like as a whole, but the central axis of the outer cylindrical surface is not collinear with the central axis of the inner cylindrical surface, that is, the two are offset by a certain distance.
  • the eccentric bushing 503 is rotatably mounted in a sleeve hole of the mounting block 502.
  • the outer diameter of the eccentric bushing 503 is slightly smaller than the inner diameter of the sleeve bore.
  • the eccentric bushing is rotatable relative to the mounting block 502 in the sleeve bore about a central axis of the outer cylindrical surface of the eccentric bushing.
  • the eccentric bushing 503 also has a portion of the axially extending mounting block 502 for connecting the other end of the link 516.
  • the eccentric bushing can be rotatable by a flange provided at the axially extending portion and an opposite stop block mounted at the other end of the eccentric bushing The ground is fitted on the mounting block to prevent axial movement in the sleeve hole to maintain the stability of its rotation.
  • One axial end of the transfer roller 512 is rotatably mounted in the eccentric bushing 503 by a bearing.
  • the central axis of the transfer roller 512 is collinear with the central axis of the inner cylindrical surface of the eccentric bushing 503. Since the central axis of the outer cylindrical surface of the eccentric bushing 503 is not collinear with the central axis of the inner cylindrical surface, thereby causing the central axis of the inner cylindrical surface of the eccentric bushing when the eccentric bushing is rotated in the bushing hole The position will change accordingly, thus making the eccentric bushing 503
  • the position of the axial end of the transfer roller 512 is also changed correspondingly, and the position of the central axis of the transfer roller 512 is changed, resulting in a change in the distance between the transfer roller 512 and the anilox roller 511, thereby causing a change
  • the pressure between the two has also changed.
  • the eccentric bushing rotates to move the transfer roller 512 to a pressing position, the distance between the transfer roller 512 and the anilox roller 511 is reduced, and the two are pressed together, thereby generating the transfer roller 512.
  • the pressure of the anilox roller 511 is pressed.
  • the eccentric sleeve rotates to move the transfer roller 512 to the rest position, the distance between the transfer roller 512 and the anilox roller 511 increases, and the two are separated from the pressure (can be contacted or not contacted), the transfer roller 512 does not provide pressure to the anilox roller 511.
  • the transfer roller 512 can be moved to a different pressing position by rotating the eccentric bushing by the pressing member as needed.
  • the eccentric bushing 503 By rotating the eccentric bushing 503 to move the ink transfer roller to different pressing positions, due to the eccentric configuration of the eccentric bushing, the distance between the transfer roller 512 and the anilox roller 511 can be adjusted, thereby adjusting the generated transmission.
  • the ink roller 512 presses against the pressure of the anilox roller 511. And because the rubber has the characteristics of flexibility, resilience, small hardness, etc., the deformation of the transfer roller 512 can be finely controlled by adjusting the pressure generated, so that the registration of the dye can be further improved by adjusting the pressure of the pressing. Registration accuracy.
  • the other axial end side of the transfer roller 512 is provided with the same other pressing member.
  • the actuator on the other axial end side of the transfer roller 512 can be omitted, and only the swing arm, the link and the eccentric bushing are provided, that is, the two pressing members share one actuator 509.
  • the two swing arms on the two axial end sides of the transfer roller 512 are non-rotatably fixed to the swing arm pivot 504, whereby the two swing arms are pivoted synchronously by means of the swing arm pivot 504, thereby realizing two links and eccentricity Synchronous movement of the sleeve.
  • the eccentric bushing can be set to initially rest in the rest position.
  • the actuator 509 is actuated to extend the piston rod, and the swing arm 508 is pivoted about the central axis of the swing arm pivot 504 to drive the link 516 connected to the swing arm 508 to move.
  • the movement of 516 in turn drives the eccentric bushing to rotate, and the eccentric bushing 503 rotates to move the transfer roller 512 to a pressing position (refer to FIG. 4), and the distance between the transfer roller 512 and the anilox roller 511 is reduced. Both of them are pressed, thereby providing the pressure of the transfer roller 512 against the anilox roller 511.
  • the actuator 509 is actuated to retract the piston rod, and the swing arm 508 is pivoted about the central axis of the swing arm pivot 504 to drive the link 516 coupled to the swing arm 504.
  • the movement of the connecting rod 516 in turn drives the eccentric bushing 503 to rotate, the eccentric bushing 503 rotates to move the transfer roller 512 to the rest position, and the distance between the transfer roller 512 and the anilox roller 511 increases.
  • the pressure is released, whereby the transfer roller 512 no longer applies pressure to the anilox roller 511.
  • the stroke of the piston rod of the actuator 509 can be set to 80-200 mm, preferably 100 mm.
  • the center roller 1, the transfer roller 512 and the axis of the anilox roller 511 are parallel.
  • the axes of the three can be Not coplanar.
  • the axes of the three are not collinear.
  • the axial connection of the three forms an included angle ranging from 130 to 170 degrees, which is preferably 146 degrees or 147 degrees.
  • the swing arm pivot 504 is disposed substantially on the side of the anilox roll 511 opposite the transfer roller side. That is, the axes of the anilox roll 511, the transfer roller 512, and the swing arm pivot 504 are arranged in a triangular shape.
  • the advantage of such an arrangement is that the size of the dyeing jacket device in the direction perpendicular to the axis of the center roller 1 can be reduced, so that the frame and the mounting block are compact in structure; in addition, the parts are easily maintained and replaced.
  • the direction in which the transfer roller 512 presses the pressing force F1 of the center roller 1 is parallel to the length of the slide rail.
  • the direction is parallel to the longitudinal centerline of the dyeing set.
  • the pushing force F1 can be decomposed into two components, vertical and tangential.
  • the vertical component refers to the actual dyeing pressure F2 perpendicular to the outer peripheral surface of the center roll, that is, toward the center of the center roll, which is expressed by the amount of rubber deformation of the rubber roll.
  • the tangential component is a tangential component force F3 that is tangential to the outer circumferential surface of the center roll.
  • the tangential component force F3 has a certain influence on the tangential deformation of the rubber roller cladding layer, but has little effect on the deformation of the dyeing pattern.
  • the required dyeing pressure F2 should remain the same, so in the case where the angle ⁇ between the center line of the transfer roller and the center roller and the horizontal line is determined, the pressing force F1 and the cut are made.
  • the magnitude of the component force F3 is related to the angle ⁇ between the longitudinal centerline and the horizontal line of the dyeing device, and the smaller the angle ⁇ , the larger the pressing force F1 and the tangential component F3; The larger ⁇ , the smaller the pushing force F1 and the tangential component F3.
  • the angle ⁇ between the longitudinal centerline and the horizontal line of the dyeing jacket device may be 0-90 degrees, preferably 15 degrees.
  • the angle between the anilox roller-ink transfer center line and the longitudinal centerline of the dyeing jacket can be from 4 to 35 degrees, preferably 23 degrees.
  • the dyeing jacket device may further include a pressure locker 517 for locking the pressure between the ink transfer roller 512 and the anilox roller 511, thereby avoiding pressure values due to unevenness of the surface of the fabric 2 during production.
  • the pressure locker can include a variable length member that is pivotally coupled to the eccentric bushing 503 at one end and pivotally secured to the mounting block 502 at the other end. The length of the component changes as the eccentric bushing 503 rotates.
  • the operator can lock the pressure locker 517 by any suitable means, thereby making the length variable.
  • the length of the member is constant, thereby keeping the pressure of the transfer roller 512 against the anilox roller 511 constant.
  • the transfer dyeing apparatus achieves good results in production and application of transfer dyeing products in terms of productivity and product quality.
  • Each dyeing jacket device can be independently pressure contacted or disengaged by means of a respective propulsion device
  • the center roll so that the other dyeing set devices continue to transfer the dye, and the pressure against the center roll can be independently adjusted.
  • the transfer roller is used as the transfer temporary carrier, and the consumption of paper-free consumables not only reduces the running cost, but also is environmentally friendly, economical and practical.
  • the transfer dyeing apparatus of the present invention can realize high-speed transfer dyeing production with a dyeing speed of up to 30-60 m/min.
  • Double-sided dyeing can share one drying unit 1000 or two separate drying units.
  • the dyeing unit 100 that dyes the first side and the dyeing unit 100' that dyes the opposite second side may be of different colors, so that double-sided heterochromatic dyeing can be achieved. This is not possible with traditional dyeing processes.
  • the pressing assembly provided in the two dyeing units can adjustably provide the pressure of the transfer roller against the anilox roller, thereby being able to adapt to different fabric properties and fabric thickness, and effectively control the dyeing effect.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Coloring (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

一种转移染色方法，包括步骤：1)将前处理液通过第一网纹辊涂布的方式均匀涂覆在织物正面；2)使染料墨水通过第一满底版印刷版辊印刷在第一传墨辊或传墨毯带上；3)将染料墨水从第一传墨辊或传墨毯带转移到织物正面，从而实现织物正面上色；4)在织物烘干后，使织物反面面对第二网纹辊；5)再将前处理液通过所述第二网纹辊涂布的方式均匀涂覆在织物反面；6)将与步骤2)相同或不同的染料墨水通过第二满底版印刷版辊印刷在第二传墨辊或传墨毯带上；7)染料墨水从第二传墨辊或传墨毯带转移到织物反面，从而实现织物反面上色；8)织物烘干后，经固色，水洗，定型，即为染色成品。

Description

转移染色方法 技术领域
本发明涉及纺织工业中的印染技术，具体是指一种转移染色方法。
背景技术
人类在发明纺织的同时，也发展了染色技术，早在1.5万年以前原始人就开始应用红色氧化铁矿物颜料对织物进行了染色，公元1450年欧洲的染色工业已略有规模，掌握了染色工艺和染料的应用。1471年欧洲各国的染色从业者齐集英国伦敦，讨论了染色工艺相关课题，通过了第一个会章，成立染色业者协会。第二次世界大战后，随着纺织工业的持续发展，带动了染料工业的发展。到二十世纪八十年代达到高峰，合成染料根据化学结构可细分为三十二类，根据应用分类亦可分为十八类，染料品种多达数万种。每一大类的染料又根据不同的染色性能和工艺条件又分成许多组别。同一种纤维常常可以用几种染料进行染色，而同一种染料也往往可以用于几种不同纤维的染色和印花。在染色和印花中所应用的染色机理和染色工艺则根据实际情况加以设计。在上个世纪九十年代，随着世界各国对环保和健康的重视，出台了大量关于印染环保条例的实施，使许多染厂面临研究与发展的压力。近年在染料的使用上，陈旧的染色、印花技术工艺正在逐渐被淘汰，而市场和社会需要印染企业从节省能源、环境保护、控制成本、提高效益、提高质量等与社会密切相关的主题出发以新的科学技术、信息工艺技术以及新的工艺引入纺织印染的生产程序中。
染色是借染料与纤维发生物理或化学的结合，或用化学方法在纤维上生成颜料，使整个纺织品具有一定色泽的加工过程。染色是在一定温度、时间、pH值和所需染色助剂等条件下进行的。染色产品应色泽均匀，还需要具有良好的染色牢度。现有织物的染色方法主要分浸染和轧染。浸染是将织物浸渍于染液中，而使染料逐渐上染织物的方法，它适用于小批量多品种染色。绳状染色、卷染都属于此范畴。轧染是先把织物浸渍于染液中，然后使织物通过轧辊，把染液均匀轧入织物内部，再经汽蒸或热熔等处理的染色方法，它适用于大批量织物的染色。传统染色上染纤维的过程可描述为：首先染料随着染浴的流动到达纤维周围；其次染料依靠本身的热运动扩散，通过纤维周围液层接近纤维表面；再次染料因分子间各种力的作用被纤维吸附，纤维周围的染 浴浓度随之降低；最后染料在纤维无定形区向纤维内部扩散并被吸附。而染浴的方式实际上是粗放型的生产方法，其生产过程中的耗水量巨大，且水洗后造成大量含染料有色废水的产生。我国每印染加工1吨纺织品耗水100～200吨，其中80～90％成为废水。是各行业中的排污大户之一。印染废水一般具有污染物浓度高，种类多，碱性大，水质变化大，COD含量高，含有毒有害成分及色度高等特点，属难处理的工业废水之一。随着社会的发展，个人、家庭生活品质提升，人们对于环保和健康的需求越来越强烈，粗放型的传统的染色方法已进入了被淘汰的落后产能的目录，例如2016年浙江绍兴近半的印染厂已关停，但是织物染色产品的需求仍然巨大，因此市场急需环保，低好水，低排放、高品质的织物染色工艺方法的开发和推广应用。相对而言，印花的耗水量远低于传统染色，实际上印花是一种局部的染色，染色时(特别是浸染)，织物在染浴中有较长的作用时间，这使染料能较充分地扩散、渗透到纤维中去完成染着过程。而印花时，色浆中所加的糊料待烘干成膜后，高分子膜层阻止了染料向纤维内部扩散，使得染料附着在纤维表面，经汽蒸、焙烘等手段最终实现染料的固着。因此，采用印花的方式进行染色是实现节能减排的方向之一。
发明内容
针对浸染和轧染等染色工艺耗水高，废水量大的缺陷，本发明提供了一种转移染色的方法，可以克服现有染色工艺的缺点，并使染色的质量得到提升。
所述转移染色方法，其步骤如下：
1)将前处理液通过第一前处理网纹辊涂布的方式均匀涂覆在织物正面以形成正面表层湿态的织物，便于后续工序固色；
2)使染料墨水通过第一满底版印刷版辊印刷在第一传墨辊或传墨毯带上；
3)使所述步骤1中的正面表层湿态的织物和步骤2中的第一传墨辊或传墨毯带密合，压力接触，将染料墨水从第一传墨辊\传墨毯带转移到织物正面，从而实现织物正面上色；
4)在织物烘干后，使织物反面面对第二前处理网纹辊；
5)再将前处理液通过所述第二前处理网纹辊涂布的方式均匀涂覆在织物反面以形成反面表层湿态的织物；
6)根据双面同色或双面异色的染色需求，将与步骤2相同或不同染料墨水通过第 二满底版印刷版辊印刷在第二传墨辊或传墨毯带上；
7)所述步骤5中的反面表层湿态的织物和步骤6中的第二传墨辊或传墨毯带密合，压力接触，促使染料墨水从第二传墨辊\传墨毯带转移到织物反面，从而实现织物反面上色；
8)织物烘干后，经固色，水洗，定型，即为染色成品。
所述步骤1中的前处理液配方，按各组分的重量百分比为：
Figure PCTCN2017083967-appb-000001
所述连接料为海藻酸钠，或瓜尔胶，或合成龙胶，或纤维素及其衍生物，或淀粉及其衍生物，或丙烯酸、丁烯酸及其衍生物的多元聚合体；
所述表面活性剂为聚乙烯吡咯烷酮，或聚氧乙烯烷基胺，或脂肪醇聚氧乙烯醚，或聚硅醚；
所述匀染剂为烷基磺酸钠，或高级脂肪醇硫酸钠，或脂肪醇聚氧乙烯；
所述固色剂，活性染料墨水用前处理液中的固色剂为碳酸钠，或碳酸氢钠，或氢氧化钠，或碳酸钾，或碳酸氢钾，或氢氧化钾，或代用碱；酸性染料墨水用前处理液中的固色剂为尿素，或双氰胺；分散染料墨水用前处理液中不加固色剂；
所述pH调节剂为柠檬酸，或醋酸，或硫酸铵；或三乙醇胺。
所述步骤1中的网纹辊为激光雕刻的镀铬网纹辊或陶瓷网纹辊，线数为60-200线/cm。
所述染料墨水为本领域公开的染色墨水。
所述版辊为凹版版辊，或柔版版辊，或圆网，或胶版版辊。
所述传墨辊或传墨毯带的表面材质为橡胶涂覆层，橡胶涂覆层厚度为3-15mm，所述橡胶为聚氨酯橡胶，或丁腈橡胶，或氯丁橡胶，或氯磺化聚乙烯橡胶，或乙丙橡胶，其表面硬度为邵氏45-90度。
所述步骤8中的固色为冷堆固色，或汽蒸固色，或烘焙固色。
可以在一染色设备的染色单元中执行所述步骤2和3，所述染色单元包括：中心辊，所述中心辊安装到机架上；和至少一个染色部套装置，所述至少一个染色部套装置分布在中心辊圆周外围，待染色的织物进入中心辊与各个染色部套装置之间进行染色，其中，每个染色部套装置包括承载满底版的染色墨水的所述满底版印刷版辊和用于将所述满底版印刷版辊上的染色墨水转移至织物的所述传墨辊，所述传墨辊位于所述满底版印刷版辊与中心辊之间。
也在一染色设备的染色单元中执行所述步骤6和7，所述染色单元包括：中心辊，所述中心辊安装到机架上；和至少一个染色部套装置，所述至少一个染色部套装置分布在中心辊圆周外围，待染色的织物进入中心辊与各个染色部套装置之间进行染色，其中，每个染色部套装置包括承载满底版的染色墨水的所述满底版印刷版辊和用于将所述满底版印刷版辊上的染色墨水转移至织物的所述传墨辊，所述传墨辊位于所述满底版印刷版辊与中心辊之间。
可选地，印刷版辊的外径＜传墨辊的外径≤印刷版辊的外径+1mm。
可选地，每个染色部套装置还包括施压组件，所述施压组件用于可调地提供传墨辊抵压印刷版辊的压力，其中，所述施压组件能够使传墨辊选择性地运动至抵压位置和休止位置，在抵压位置，传墨辊抵压印刷版辊，由此产生传墨辊抵压印刷版辊的压力；在休止位置，传墨辊不抵压印刷版辊。
可选地，所述施压组件包括可转动的偏心轴套，传墨辊的轴端可旋转地安装在所述偏心轴套内，通过转动偏心轴套，能够调节传墨辊与印刷版辊之间的距离，由此调节所产生的传墨辊抵压印刷版辊的压力。
可选地，通过转动所述偏心轴套能够使传墨辊选择性地运动至多个抵压位置。
可选地，所述施压组件还包括用于驱动偏心轴套转动的连杆和用于使所述连杆运动的摆臂，所述连杆的一端连接至所述偏心轴套，所述连杆的另一端连接至所述摆臂，所述摆臂能够通过摆臂枢轴相对于染色部套装置的本体枢转。
可选地，所述施压组件还包括致动器，所述致动器驱动摆臂枢转，摆臂的枢转致使连杆驱动偏心轴套转动，由此使传墨辊运动至抵压位置或休止位置。
可选地，在传墨辊的两个轴端侧各设有一个所述施压组件。
可选地，在传墨辊的两个轴端侧各设有一个所述施压组件，在一个轴端侧的摆臂与在另一轴端侧的摆臂借助于同一摆臂枢轴同步枢转，由此实现两个连杆、偏心轴套 的同步运动，从而对印刷版辊的两个轴端保持同步施压。
可选地，位于传墨辊的两个轴端侧的施压组件中只有一个包括用于驱动摆臂枢转的致动器。
可选地，所述摆臂包括第一臂部和第二臂部，每个臂部包括第一端和第二端，第一臂部的第一端通过销轴可枢转地连接至致动器的伸出端，第二臂部的第一端通过销轴可枢转地连接至连杆的所述另一端，两个臂部的第二端都不可旋转地固定在所述摆臂枢轴的端部上。
可选地，所述摆臂包括第一臂部和第二臂部，每个臂部包括第一端和第二端，第一臂部的第一端通过销轴可枢转地连接至致动器的伸出端，第二臂部的第一端通过销轴可枢转地连接至连杆的所述另一端，两个臂部的第二端都不可旋转地固定在所述摆臂枢轴的端部上。
可选地，所述中心辊为表面包覆橡胶且空腔注油的硬质材料辊，硬质材料辊通过内置于空腔的电热棒加热油液，从而控制中心辊温度。
可选地，每个染色部套装置还包括用于提供使传墨辊朝向中心辊前进的推进力的推进装置，所述推进装置安装在染色部套装置的框架上。
可选地，每个染色部套装置能够借助于各自的推进装置独立地朝向中心辊前进或离开。
可选地，推进装置还提供使传墨辊抵靠中心辊上的待染色的织物的独立可调节压力。
可选地，每个染色部套装置还包括框架，框架内设置有安装块，所述传墨辊和印刷版辊可旋转地安装至所述安装块中，在推进装置的推进作用下，安装块能够在框架内朝向中心辊运动。
可选地，框架内设置有滑轨，安装块能够在滑轨上滑动。
可选地，所述传墨辊、印刷版辊、中心辊的轴线相互平行、但不共面。
可选地，每个染色部套装置还包括用于将传墨辊和印刷版辊之间的压力锁定的压力锁定器。
本发明的有益效果在于，采用转移染色的上染方式，而非传统的浸染或扎染的方式，从而仅在织物表层上染，织物内部，非可见部分均无需染料填充，因此极大程度地节约了染料用量以及耗水量；按需上染，上染量恰当，且固色率高，因此水洗耗水 量少，产生的废水少；采用前处理液处理再上染再固色的模式，非传统染色用的固色剂和染料同浆上染的模式，保证了染料墨水的存储稳定性；本发明可以单面上染，双面上染，可单色上染，也可双面异色上染，符合市场对染色面料差异化的需求。
附图说明
下面结合附图和实施例对本发明进一步的说明。
图1是根据本发明一实施例的转移染色方法的流程图。
图2是实现该实施例的转移染色设备的整体示意图，该转移染色设备可进行双面染色。
图3是该转移染色设备的染色单元的示意图。
图4是该染色单元的单个染色部套装置的示意图。
图5是该染色单元的单个染色部套装置沿着致动器、摆臂、连杆、偏心轴套等部件的轴向方向截取的截面图。
图6是依照本发明的单个染色部套装置与中心辊的受力和位置关系示意图。
具体实施方式
下述以非限制性实施例来进一步说明本发明，但应注意的是，这些实施例不应视为是对本发明的限制。
实施例1：全棉织物双面异色转移染色。
织物规格：100％棉针织150g/m2。
全棉织物双面异色转移染色方法，其步骤如下：
1)将前处理液通过第一网纹辊涂布的方式均匀涂覆在织物正面形成正面表层湿态的全棉织物；
2)正面色染料墨水通过第一满底版印刷版辊印刷在传墨辊上；
3)所述步骤1中的正面表层湿态的织物和步骤2中的传墨辊密合，压力接触，染料墨水从传墨辊带转移到全棉织物正面，从而实现全棉织物正面上色；
4)全棉织物烘干后，使全棉织物反面面对前处理第二网纹辊；
5)再将前处理液通过第二网纹辊涂布的方式均匀涂覆在全棉织物反面形成反面表层湿态的全棉织物；
6)将反面色染料墨水通过第二满底版印刷版辊印刷在另一组传墨辊上；
7)所述步骤5中的反面表层湿态的全棉织物和步骤6中的传墨辊密合，压力接触，染料墨水从传墨辊转移到织物反面，从而实现全棉织物反面上色；
8)织物烘干后，经固色，水洗，定型，即为染色成品。
图1示出了实施例1的流程图。
所述第一网纹辊和所述第二网纹辊可以是同一个辊，也可是不同的两个辊。
所述前处理液配方，按各组分的重量百分比为：
Figure PCTCN2017083967-appb-000002
所述连接料为海藻酸钠；
所述表面活性剂为聚氧乙烯烷基胺；
所述匀染剂为高级脂肪醇硫酸钠；
所述固色剂为碳酸氢钠、碳酸钠和碳酸钾以重量比1∶4∶2混合配置的碱剂；
所述网纹辊为激光雕刻的陶瓷网纹辊，线数为60线/cm。
所述染料墨水为本领域公开的活性染色墨水。
所述满底版印刷版辊为凹版版辊。
所述传墨辊的表面材质为橡胶涂覆层，橡胶涂覆层厚度为3mm，所述橡胶为聚氨酯橡胶，其表面硬度为邵氏90度。
所述步骤8中的固色为冷堆固色，25℃，冷堆6小时。
实施例2：尼龙织物双面同色转移染色
织物规格：塔丝隆；原料：100％尼龙，规格：70D×160D
尼龙织物双面同色转移染色方法，其步骤如下：
1)将前处理液通过第一网纹辊涂布的方式均匀涂覆在织物正面形成正面表层湿态的尼龙织物；
2)染料墨水通过第一满底版印刷版辊印刷在传墨毯带上；
3)所述步骤1中的正面表层湿态的尼龙织物和步骤2中的传墨毯带密合压力接触，染料墨水从传墨毯带转移到尼龙织物正面，从而实现尼龙织物正面上色；
4)织物烘干后，使尼龙织物反面面对前处理第二网纹辊；
5)再将前处理液通过第二网纹辊涂布的方式均匀涂覆在尼龙织物反面形成反面表层湿态的尼龙织物；
6)将与步骤2相同的染料墨水通过第二满底版印刷版辊印刷在另一组传墨毯带上；
7)所述步骤5中的反面表层湿态的尼龙织物和步骤6中的传墨毯带密合压力接触，染料墨水从传墨毯带转移到织物反面，从而实现织物反面上色；
8)织物烘干后，经固色，水洗，定型，即为染色成品。
所述前处理液配方按各组分的重量百分比为：
Figure PCTCN2017083967-appb-000003
所述连接料为羧甲基纤维素钠；
所述表面活性剂为脂肪醇聚氧乙烯醚；
所述匀染剂为脂肪醇聚氧乙烯；
所述固色剂为尿素和双氰胺以重量比2∶1混合配置的碱剂；
所述pH调节剂为硫酸铵。
所述网纹辊为激光雕刻的镀铬网纹辊，线数为120线/cm。
所述染料墨水为本领域公开的酸性染色墨水。
所述满底版印刷版辊为柔版版辊。
所述传墨毯带，其表面材质为橡胶涂覆层，橡胶涂覆层厚度为8mm，所述橡胶为丁腈橡胶，其表面硬度为邵氏75度。
所述步骤8中的固色为汽蒸固色，103℃，汽蒸20min固色。
实施例3：涤纶织物单面转移染色
织物：涤纶绉麻；织物规格：原料为涤纶111dtex(DTY)×111dtex(DTY)，密度为256×256根/10cm，重量为142g/m2。
涤纶织物单面转移染色方法，其步骤如下：
将前处理液通过网纹辊涂布的方式均匀涂覆在织物正面形成正面表层湿态的涤纶织物；
染料墨水通过满底版版辊印刷在传墨辊上；
所述步骤1中的正面表层湿态的织物和步骤2中的传墨辊密合，压力接触，染料墨水从传墨辊转移到织物正面，从而实现涤纶织物正面上染；
织物烘干后，经固色，水洗，定型，即为染色成品。
所述步骤1中的前处理液配方，按各组分的重量百分比为：
Figure PCTCN2017083967-appb-000004
所述连接料为甲基丙烯酸甲酯、丙烯酸丁酯、丙烯酸三元共聚物；
所述表面活性剂为聚乙烯吡咯烷酮；
所述匀染剂为烷基磺酸钠；
所述步骤1中的网纹辊为激光雕刻的镀铬网纹辊，线数为200线/cm。
所述步骤2中的染料墨水为本领域公开的分散染色墨水。
所述步骤2中的印刷版辊为胶版版辊。
所述步骤2中的传墨辊，其表面材质为橡胶涂覆层，橡胶涂覆层厚度为15mm，所述橡胶为氯丁橡胶，其表面硬度为邵氏45度。
所述步骤8中的固色为烘焙固色，180℃，20min固色。
作为示例，图2示出了实现根据本发明的上述实施例1的转移染色方法的转移染 色设备。在进行染色时，织物依次经过该转移染色设备的如下部位：紧布架201；除尘单元300；双辊主动扩幅装置401；对中装置601；张力控制器603；主动牵引装置602；电晕处理器1100；第一张力摆杆装置604；第一上浆前扩幅装置402；第一上浆装置701和第二除湿装置702，用于在对织物的第一面进行染色之前对织物进行上浆和除湿；第二张力摆杆装置604’；第一纠偏单元800；第一染色单元100，用于对织物的第一面进行染色操作；烘干单元1000；第二上浆前扩幅装置402’；第二上浆装置701’和第二除湿装置702’，用于在对织物的与第一面相反的第二面进行染色之前对织物进行上浆和除湿；第三张力摆杆装置604”；第二纠偏单元800’；第二染色单元100’，用于对织物的所述第二面进行染色操作；烘干单元1000；张力摆臂装置605；和落布牵引装置202。
第一染色单元100用来实现上述实施例1中的步骤2和3。第二染色单元100’用来实现步骤6和7。第二染色单元100’的结构与第一染色单元100类似。为了方便描述，下面只对第一染色单元100进行描述，并简称为染色单元100。
染色单元是整个染色设备的核心，主要包括至少一个染色部套装置5和中心辊1，将在下面更详细地描述。每个染色部套装置包括满底版印刷版辊。在实施例1中该满底版印刷版辊为凹版版辊，但不限于此。该满底版印刷版辊可以是网纹辊(满底版凹版印刷版辊)、满底版柔版印刷版辊、满底版圆网印刷版辊或满底版胶版印刷版辊。中心辊和每一个染色部套装置都采用交流伺服电机独立驱动，中央控制单元中的运动控制器通过高速现场总线连接每一个交流伺服电机，从而实现中心辊和每一个染色部套装置的高精度同步控制。染色单元采用了交流伺服电机和运动控制器，可以实现预套准功能，大大减少材料浪费。所述染色单元100包括至少一个染色部套装置，使用多个颜色相同的染色部套装置进行染色操作的情况下，多次相同颜色的满底叠加可保证染色的均匀性；织物经过的运转中的染色部套装置的个数越多，染色颜色越深，通过对运转中的染色部套装置的个数进行控制，可实现对颜色深度的选择控制；对于需要染料具有渗透性的厚布或绒布染色，通过多次压合，或者不同压力梯度的多次压合，能够实现染料的充分渗透，保证染色效果。
参照图3-5，下面将更详细地描述染色单元100。如上所述，染色单元100主要包括中心辊1和至少一个染色部套装置5。该染色单元采用卫星式结构，所述至少一个染色部套装置共用一个中心辊作为背压辊。
在机架12上通过轴承固定连接中心辊1。中心辊1可以由变频电机13驱动旋转。中心辊1可以为表面包覆橡胶的硬质材料辊。表面橡胶邵氏硬度为85-90度，优选为90度。中心辊1的外径可以为1600-2000mm，优选为1800mm。可选地，该中心辊可以空腔注油，通过内置于空腔的电热棒加热油液，从而可将中心辊1温度升温到30-150℃。显然，本领域技术人员可以根据实际需要，采用其它升温方式控制中心辊的温度。中心辊可加热升温，能够稳定转移染色温度，避免由于季节变化或昼夜变化形成较大温差，导致批次间产品质量的不稳定；并且针对一些高支高密织物，通过加热可进一步膨胀待染色的织物纤维，从而增加染料上染率和上染速度。
中心辊1圆周外围分布有至少一个(例如2-8个，图3中示出了6个)染色部套装置5。每个染色部套装置5由各自的推进装置、例如推进缸506独立地提供其朝向中心辊1前进的推进力。推进缸506安装在各个染色部套装置5的的本体上，例如安装在本体的框架501上。
可选地，该转移染色设备还可以包括导辊4。更优选地，设置有至少两个导辊4。在待染色的织物与中心辊接触的入口和出口附近分别设置至少一个导辊。导辊4引导织物2进入或导出处于中心辊1和染色部套装置5之间的加压区间。优选地，每个导辊4可以为硬质材料辊。每个导辊的外径可以为100-150mm。
可选地，在各个染色部套装置5之间可以设置有烘燥箱7，用于确保墨水印后干燥，防止多次套准之间沾色串色的现象。特别地，参见图3，设置有五个烘燥箱7，其与六个染色部套装置5交替分布在中心辊1圆周外围。
可选地，依照本发明的转移染色设备还可以包括布置在中心辊1和染色部套装置5的非加压区间的在线中心辊清洗系统15。该在线中心辊清洗系统15包括清洗装置、刮水刀和烘箱，中心辊1表面经清洗装置清洗后，通过刮水刀刮除中心辊1表面水分，再经烘箱干燥后，即实现连续循环应用。清洗装置可以包括喷淋头和毛刷。
图4和图5显示了依照本发明的该实施例的转移染色设备的染色部套装置5。在所示的实施例中，染色部套装置5可以包括上述的推进装置(例如推进缸506)、墨斗组件510、网纹辊511、传墨辊512以及施压组件。墨斗组件510、网纹辊511、传墨辊512以及施压组件安装在框架501内。传墨辊512位于网纹辊511和中心辊1之间，可以与网纹辊511接触。传墨辊512与网纹辊511各自的轴端可以安装至框架501内的一安装块502内。该安装块502可在设置于框架501中的滑轨上滑动，这样，在推 进缸506的推进作用下，安装块502朝着中心辊1的方向运动，使得传墨辊512到达与中心辊1上的待染色的织物相接触的位置。在这里，推进缸506还可以提供使传墨辊512抵靠中心辊1上的待染色的织物的压力。根据本发明的实施例，各个推进缸506所提供的使传墨辊512抵靠中心辊1上的待染色的织物的压力可以为独立可调的。该压力通过控制系统调节设定，亦可以按照程序渐升，或按照程序渐降。整个染色部套装置5被推进缸506沿直线滑轨推动而实现与中心辊的离合，离合行程可达2-5cm。
网纹辊511的外径可选择使用，通常外径为95-200mm。网纹辊511配套一墨斗组件510。供墨系统将墨水输送到墨斗组件510与网纹辊511之间所形成的墨腔中。网纹辊511可以由伺服电机驱动，并与其它染色部套装置5的网纹辊511保持同步，从而保证套准精度。
优选地，传墨辊512可以为表面包覆橡胶的硬质材料辊。其表面可以包覆无缝橡胶。橡胶为天然橡胶、丁苯橡胶、聚氨酯橡胶或对水性墨水亲和性好的其它橡胶。优选地，传墨辊512的表面橡胶邵氏硬度为85-90度，更优选为90度。
由于每个染色部套装置传墨辊512为包覆橡胶的硬质材料辊，传墨辊512的外径略大于网纹辊511，如此在保证转移染色墨水完整的同时，提供了一定的容差空间。在转移染色过程中，当橡胶传墨辊与网纹辊接触时，橡胶传墨辊的橡胶在推进装置的推进作用下以及施压组件的施压作用下受到某一压力而发生变形；当网纹辊的当前表面转离橡胶传墨辊的橡胶表面时，橡胶表面能够迅速恢复原状。优选地，网纹辊511的外径＜传墨辊512的外径≤网纹辊511的外径+1mm，也就是说传墨辊512的外径比网纹辊511的外径大，但两者的差在1mm以下。依照本发明的染色设备承压能力强，精度高，能够完整承载染色墨水，从而确保了转移后的染色墨水套准精度；此外，橡胶的压缩变形很小，从而能够承受每小时千万次的压缩，在生产周期内不会产生压缩疲劳而带来永久变形。
施压组件可以用于提供传墨辊512抵压网纹辊511的可调节压力。该施压组件用于调整墨量，以控制色差，压力主要用于把网纹辊网穴中的墨量粘出。在所示的实施例中，该施压组件包括致动器509和偏心轴套503。致动器509包括缸体和活塞杆。缸体可枢转地连接至安装块502。致动器509可以为液压类型、气动类型或电动类型。在致动器509为液压或气动类型的情况下，可以通过调节缸体的腔室内的流体压力，调节活塞杆伸出的长度。优选地，致动器509可以为伺服致动器，例如伺服电动缸。
该施压组件还可以包括摆臂508和连杆516。在所示的实施例中，摆臂508通过摆臂枢轴504可枢转地连接至该安装块502。摆臂508包括第一端部和第二端部。摆臂508的第一端部通过销轴可枢转地连接至致动器509的活塞杆的伸出端。摆臂508的第二端部通过销轴可枢转地连接至连杆516的一端。连杆516的另一端可枢转地连接至偏心轴套503。当然，对于本领域技术人员来说，除了在此所述的摆臂-连杆方式外，可以使用任何其它传动方式实现致动器509对偏心轴套503的转动操作。可选地，在摆臂枢轴的端部处可以设置手柄，以便在调试阶段由操作人员手动调节偏心轴套503的转动。
在根据本发明的另一实施例中，摆臂508可以包括第一臂部5081和第二臂部5082。每个臂部都包括第一端和第二端。所述第一端可以是小端，所述第二端可以是大端。第一臂部5081的第一端通过销轴可枢转地连接至致动器509的活塞杆的伸出端。第二臂部5082的第一端通过销轴可枢转地连接至连杆516的一端。第一臂部5081和第二臂部5082的第二端都不可枢转地连接至摆臂枢轴504。例如第二端可以设置有枢轴孔，摆臂枢轴通过键槽配合、定位销与销孔连接、或过盈配合等方式固定至第二端的该枢轴孔内。摆臂枢轴504可枢转地安装至安装块502。优选地，摆臂枢轴504从安装块502轴向向外延伸，形成伸出部。该伸出部可用于连接第一臂部5081和第二臂部5082的第二端。连杆516的另一端通过销轴可枢转地连接至偏心轴套503。
偏心轴套503整体上为套筒状的，但其外圆柱面的中心轴线与内圆柱面的中心轴线不共线，即两者偏移一定距离。偏心轴套503可转动地安装在安装块502的一轴套孔中。在所示的实施例中，偏心轴套503的外径略小于轴套孔的内径。偏心轴套可以围绕偏心轴套的外圆柱面的中心轴线相对于安装块502在该轴套孔中转动。可选地，偏心轴套503也有一部分轴向伸出安装块502，用于连接连杆516的所述另一端。参照图4，在根据本发明的一实施例中，偏心轴套可以通过在该轴向伸出的部分处设置的凸缘和安装在偏心轴套的另一端处的相对的限位块可转动地配合在安装块上，防止其在轴套孔中轴向运动，以保持其转动的稳定性。
传墨辊512的一个轴端通过轴承可旋转地安装在偏心轴套503内。传墨辊512的中心轴线与偏心轴套503的内圆柱面的中心轴线共线。由于偏心轴套503的外圆柱面的中心轴线与内圆柱面的中心轴线不共线，由此使得当偏心轴套在该轴套孔中转动时，偏心轴套的内圆柱面的中心轴线的位置会相应地发生变化，因此使得偏心轴套503内 的传墨辊512的轴端的位置也会相应地发生变化，并使得传墨辊512的中心轴线的位置发生变化，导致传墨辊512与网纹辊511之间的距离发生变化，由此引起两者之间的压力也发生变化。当偏心轴套转动而使传墨辊512运动至一抵压位置时，传墨辊512与网纹辊511之间的距离减小，两者抵压在一起，由此产生传墨辊512抵压网纹辊511的压力。而当偏心轴套转动而使传墨辊512运动至休止位置时，传墨辊512与网纹辊511之间的距离增大，两者脱离抵压(可以接触或者不接触)，传墨辊512不向网纹辊511提供压力。
在工作时，根据需要可以通过施压组件转动偏心轴套而使传墨辊512运动至不同的抵压位置。通过转动偏心轴套503使传墨辊运动至不同的抵压位置，由于偏心轴套的上述偏心构造，可以调节传墨辊512与网纹辊511之间的距离，由此调节所产生的传墨辊512抵压网纹辊511的压力。并且由于橡胶具有柔性、回弹性、硬度小等特点，可以通过调节所产生的压力，精细地控制传墨辊512的形变，从而对于染色的套准而言，能够通过调节施压压力，进一步提升套准精度。
优选地，为了使整个传墨辊512在长度方向上均匀地对网纹辊511施加压力，传墨辊512的另一轴端侧设置有同样的另一施压组件。更优选地，传墨辊512的另一轴端侧的致动器可以省略，仅设置有摆臂、连杆和偏心轴套，即两个施压组件共用一个致动器509。传墨辊512两轴端侧的两个摆臂不可转动地固定至摆臂枢轴504，由此这两个摆臂借助于摆臂枢轴504同步枢转，从而实现两个连杆、偏心轴套的同步运动。
偏心轴套可以设定为初始位于休止位置。当施压时，致动器509致动而使活塞杆伸出，驱动摆臂508围绕摆臂枢轴504的中心轴线枢转，从而带动与摆臂508相连的连杆516运动，而连杆516的运动转而带动偏心轴套转动，偏心轴套503转动而使传墨辊512运动至一抵压位置(参照图4)，传墨辊512与网纹辊511之间的距离减小，两者抵压，由此提供传墨辊512抵压网纹辊511的压力。相反，当不需要施压时，致动器509致动而使活塞杆缩回，驱动摆臂508围绕摆臂枢轴504的中心轴线枢转，从而带动与摆臂504相连的连杆516运动，而连杆516的运动转而带动偏心轴套503转动，偏心轴套503转动而使传墨辊512运动至休止位置，传墨辊512与网纹辊511之间的距离增大，两者脱离抵压，由此传墨辊512不再向网纹辊511施加压力。致动器509的活塞杆的行程可设置为80-200mm，优选100mm。
中心辊1、传墨辊512与网纹辊511的轴线是平行的。优选地，三者的轴线可以 不共面。从图3和4所示的示意图中可以看到，三者的轴心不共线。优选地，三者的轴心连线形成从130到170度范围内的夹角，该夹角优选为146度或147度。另外，从图4的示意图中还可以看到，摆臂枢轴504大体上布置在网纹辊511的与传墨辊侧相对的一侧上。即，网纹辊511、传墨辊512、摆臂枢轴504三者的轴心成三角形布置。这样布置的优点在于，能够减小染色部套装置在与中心辊1的轴线垂直的方向上的尺寸，使框架以及安装块结构紧凑；另外，零件维护、更换方便。
而且，在推进缸506的推进作用下安装块502朝着中心辊1的方向运动时，如图6所示，传墨辊512抵压中心辊1的推压力F1的方向平行于滑轨的长度方向，即平行于染色部套装置的纵向中心线。该推压力F1可以分解为垂直和切向两个分量。垂直分量是指垂直于中心辊外周表面、即向着中心辊的中心的实际染色压力F2，此染色压力的大小体现为橡胶辊的橡胶变形量。切向分量是切向于中心辊外周表面的切向分力F3，该切向分力F3对橡胶辊包胶层的切向变形有一定影响，但对染色图案的变形影响很小。对于同一批次的染色作业而言，所需的染色压力F2应当保持不变，因此在传墨辊-中心辊中心连线与水平线之间的夹角β确定的情况下，推压力F1和切向分力F3的大小与染色部套装置的纵向中心线和水平线之间的夹角α的大小有关，夹角α越小，推压力F1和切向分力F3就越大；反之，夹角α越大，推压力F1和切向分力F3就越小。通过提供切向分力F3，可以控制橡胶辊包胶层的切向变形。
在一实施例中，染色部套装置的纵向中心线和水平线之间的夹角α可为0-90度，优选为15度。网纹辊-传墨辊中心连线与染色部套装置的纵向中心线的夹角角度可以为4-35度，优选为23度。
优选地，染色部套装置还可以包括用于将传墨辊512和网纹辊511之间的压力锁定的压力锁定器517，从而避免生产过程中，由于织物2表面不平整导致的压力值的微跳动。所述压力锁定器可以包括长度可变的部件，该部件的一端可枢转地连接至偏心轴套503，另一端可枢转地固定至安装块502。该部件的长度随着偏心轴套503的转动而发生变化。当传墨辊512抵压网纹辊511的压力根据需要通过致动器509调节至所需值时，操作人员可以通过任何适合的手段使该压力锁定器517锁定，从而使该长度可变的部件的长度恒定，借此保持传墨辊512抵压网纹辊511的压力恒定。
依照本发明的转移染色设备经转移染色产品的生产应用，产能和产品质量方面取得较好效果。各个染色部套装置可以借助于各自的推进装置而独立地压力接触或脱离 中心辊，以便其它染色部套装置继续转移染色，并且能够独立地调节抵靠中心辊的压力。采用传墨辊为转移暂载体，无纸张耗材的消耗，不仅降低运行成本，且绿色环保，经济实用。此外，本发明的转移染色设备可实现高速转移染色生产，染色速度可高达30-60m/min。
双面染色可以共用一个烘干单元1000，也可以设置两个单独的烘干单元。
对第一面进行染色的染色单元100和对相反的第二面进行染色的染色单元100’可以为不同的颜色，从而可实现双面异色染色。这是传统染色工艺所不能实现的。
此外，在两个染色单元中设置的施压组件，能够可调地提供传墨辊抵压网纹辊的压力，从而能够适应不同的织物属性和织物厚度，有效控制染色效果。
虽然已经参照特定的示例性实施例展示和描述了本发明，但是本发明不受这些示例性实施例的限制。应该认识到的是，本领域的技术人员能够在不脱离本发明的由权利要求书或者其等同内容所限定的范围和精神的情况下对这些示例性实施例进行变化和变型。

Claims (28)

  1. 一种转移染色方法，其包括如下步骤：
    1)将前处理液通过第一前处理网纹辊涂布的方式均匀涂覆在织物正面以形成正面表层湿态的织物；
    2)使染料墨水通过第一满底版印刷版辊印刷在第一传墨辊或传墨毯带上；
    3)使所述步骤1中的正面表层湿态的织物和步骤2中的第一传墨辊或传墨毯带密合，压力接触，将染料墨水从第一传墨辊\传墨毯带转移到织物正面，从而实现织物正面上色；
    4)在织物烘干后，使织物反面面对第二前处理网纹辊；
    5)再将前处理液通过所述第二前处理网纹辊涂布的方式均匀涂覆在织物反面以形成反面表层湿态的织物；
    6)根据双面同色或双面异色的染色需求，将与步骤2相同或不同染料墨水通过第二满底版印刷版辊印刷在第二传墨辊或传墨毯带上；
    7)所述步骤5中的反面表层湿态的织物和步骤6中的第二传墨辊或传墨毯带密合，压力接触，染料墨水从第二传墨辊\传墨毯带转移到织物反面，从而实现织物反面上色；
    8)织物烘干后，经固色，水洗，定型，即为染色成品。
  2. 如权利要求1所述转移染色方法，其特征在于，所述前处理液配方按各组分的重量百分比为：
    Figure PCTCN2017083967-appb-100001
    所述连接料为海藻酸钠，或瓜尔胶，或合成龙胶，或纤维素及其衍生物，或淀粉及其衍生物，或丙烯酸、丁烯酸及其衍生物的多元聚合体；
    所述表面活性剂为聚乙烯吡咯烷酮，或聚氧乙烯烷基胺，或脂肪醇聚氧乙烯醚， 或聚硅醚；
    所述匀染剂为烷基磺酸钠，或高级脂肪醇硫酸钠，或脂肪醇聚氧乙烯；
    所述固色剂，活性染料墨水用前处理液中的固色剂为碳酸钠，或碳酸氢钠，或氢氧化钠，或碳酸钾，或碳酸氢钾，或氢氧化钾，或代用碱；酸性染料墨水用前处理液中的固色剂为尿素，或双氰胺；分散染料墨水用前处理液中不加固色剂；
    所述pH调节剂为柠檬酸，或醋酸，或硫酸铵；或三乙醇胺。
  3. 如权利要求1所述转移染色方法，其特征在于，所述第一网纹辊和第二网纹辊为激光雕刻的镀铬网纹辊或陶瓷网纹辊，线数为60-200线/cm。
  4. 如权利要求1所述转移染色方法，其特征在于，所述第一满底版印刷版辊和第二满底版印刷版辊选自由凹版版辊、柔版版辊、圆网和胶版版辊组成的组。
  5. 如权利要求1所述转移染色方法，其特征在于，所述第一传墨辊或传墨毯带和所述第二传墨辊或传墨毯带的表面材质为橡胶涂覆层，橡胶涂覆层厚度为3-15mm；所述橡胶为聚氨酯橡胶，或丁腈橡胶，或氯丁橡胶，或氯磺化聚乙烯橡胶，或乙丙橡胶，其表面硬度为邵氏45-90度。
  6. 如权利要求1所述转移染色方法，其特征在于，所述步骤8中的固色为冷堆固色，或汽蒸固色，或烘焙固色。
  7. 如权利要求1所述转移染色方法，其特征在于，所述第一前处理网纹辊和第二前处理网纹辊是同一个前处理网纹辊。
  8. 如权利要求1所述转移染色方法，其特征在于，在一染色设备的染色单元中执行所述步骤2和3，所述染色单元包括：中心辊，所述中心辊安装到机架上；和至少一个染色部套装置，所述至少一个染色部套装置分布在中心辊圆周外围，待染色的织物进入中心辊与各个染色部套装置之间进行染色，其中，每个染色部套装置包括承载满底版的染色墨水的所述满底版印刷版辊和用于将所述满底版印刷版辊上的染色墨水转移至织物的所述传墨辊，所述传墨辊位于所述满底版印刷版辊与中心辊之间。
  9. 如权利要求1所述转移染色方法，其特征在于，在一染色设备的染色单元中执行所述步骤6和7，所述染色单元包括：中心辊，所述中心辊安装到机架上；和至少一个染色部套装置，所述至少一个染色部套装置分布在中心辊圆周外围，待染色的织物进入中心辊与各个染色部套装置之间进行染色，其中，每个染色部套装置包括承载满底版的染色墨水的所述满底版印刷版辊和用于将所述满底版印刷版辊上的染色墨水 转移至织物的所述传墨辊，所述传墨辊位于所述满底版印刷版辊与中心辊之间。
  10. 如权利要求8或9所述的转移染色方法，其特征在于，印刷版辊的外径<传墨辊的外径≤印刷版辊的外径+1mm。
  11. 如权利要求8或9所述的转移染色方法，其特征在于，每个染色部套装置还包括施压组件，所述施压组件用于可调地提供传墨辊抵压印刷版辊的压力，其中，所述施压组件能够使传墨辊选择性地运动至抵压位置和休止位置，在抵压位置，传墨辊抵压印刷版辊，由此产生传墨辊抵压印刷版辊的压力；在休止位置，传墨辊不抵压印刷版辊。
  12. 如权利要求11所述的转移染色方法，其特征在于，所述施压组件包括可转动的偏心轴套，传墨辊的轴端可旋转地安装在所述偏心轴套内，通过转动偏心轴套，能够调节传墨辊与印刷版辊之间的距离，由此调节所产生的传墨辊抵压印刷版辊的压力。
  13. 如权利要求12所述的转移染色方法，其特征在于，通过转动所述偏心轴套能够使传墨辊选择性地运动至多个抵压位置。
  14. 如权利要求12所述的转移染色方法，其特征在于，所述施压组件还包括用于驱动偏心轴套转动的连杆和用于使所述连杆运动的摆臂，所述连杆的一端连接至所述偏心轴套，所述连杆的另一端连接至所述摆臂，所述摆臂能够通过摆臂枢轴相对于染色部套装置的本体枢转。
  15. 如权利要求14所述的转移染色方法，其特征在于，所述施压组件还包括致动器，所述致动器驱动摆臂枢转，摆臂的枢转致使连杆驱动偏心轴套转动，由此使传墨辊运动至抵压位置或休止位置。
  16. 如权利要求11所述的转移染色方法，其特征在于，在传墨辊的两个轴端侧各设有一个所述施压组件。
  17. 如权利要求14所述的转移染色方法，其特征在于，在传墨辊的两个轴端侧各设有一个所述施压组件，在一个轴端侧的摆臂与在另一轴端侧的摆臂借助于同一摆臂枢轴同步枢转，由此实现两个连杆、偏心轴套的同步运动，从而对印刷版辊的两个轴端保持同步施压。
  18. 如权利要求17所述的转移染色方法，其特征在于，位于传墨辊的两个轴端侧的施压组件中只有一个包括用于驱动摆臂枢转的致动器。
  19. 如权利要求14、15、17和18中任一项所述的转移染色方法，其特征在于， 所述摆臂包括第一臂部和第二臂部，每个臂部包括第一端和第二端，第一臂部的第一端通过销轴可枢转地连接至致动器的伸出端，第二臂部的第一端通过销轴可枢转地连接至连杆的所述另一端，两个臂部的第二端都不可旋转地固定在所述摆臂枢轴的端部上。
  20. 如权利要求16所述的转移染色方法，其特征在于，所述摆臂包括第一臂部和第二臂部，每个臂部包括第一端和第二端，第一臂部的第一端通过销轴可枢转地连接至致动器的伸出端，第二臂部的第一端通过销轴可枢转地连接至连杆的所述另一端，两个臂部的第二端都不可旋转地固定在所述摆臂枢轴的端部上。
  21. 如权利要求8或9所述的转移染色方法，其特征在于，所述中心辊为表面包覆橡胶且空腔注油的硬质材料辊，硬质材料辊通过内置于空腔的电热棒加热油液，从而控制中心辊温度。
  22. 如权利要求8或9所述的转移染色方法，其特征在于，每个染色部套装置还包括用于提供使传墨辊朝向中心辊前进的推进力的推进装置，所述推进装置安装在染色部套装置的框架上。
  23. 如权利要求22所述的转移染色方法，其特征在于，每个染色部套装置能够借助于各自的推进装置独立地朝向中心辊前进或离开。
  24. 如权利要求23所述的转移染色方法，其特征在于，推进装置还提供使传墨辊抵靠中心辊上的待染色的织物的独立可调节压力。
  25. 如权利要求22所述的转移染色方法，其特征在于，每个染色部套装置还包括框架，框架内设置有安装块，所述传墨辊和印刷版辊可旋转地安装至所述安装块中，在推进装置的推进作用下，安装块能够在框架内朝向中心辊运动。
  26. 如权利要求25所述的转移染色方法，其特征在于，框架内设置有滑轨，安装块能够在滑轨上滑动。
  27. 如权利要求8或9所述的转移染色方法，其特征在于，所述传墨辊、印刷版辊、中心辊的轴线相互平行、但不共面。
  28. 如权利要求8或9所述的转移染色方法，其特征在于，每个染色部套装置还包括用于将传墨辊和印刷版辊之间的压力锁定的压力锁定器。
PCT/CN2017/083967 2017-01-23 2017-05-11 转移染色方法 WO2018133258A1 (zh)

Priority Applications (4)

Application Number Priority Date Filing Date Title
EP17892141.7A EP3572232B1 (en) 2017-01-23 2017-05-11 Transfer dyeing method
US16/326,261 US10618272B2 (en) 2017-01-23 2017-05-11 Transfer dyeing method
JP2019537144A JP6865287B2 (ja) 2017-01-23 2017-05-11 転写染色方法
ES17892141T ES2952548T3 (es) 2017-01-23 2017-05-11 Método de teñido por transferencia

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
CN201710048417.9 2017-01-23
CN201710048417.9A CN108342914B (zh) 2017-01-23 2017-01-23 转移染色方法

Publications (1)

Publication Number Publication Date
WO2018133258A1 true WO2018133258A1 (zh) 2018-07-26

Family

ID=62907750

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/CN2017/083967 WO2018133258A1 (zh) 2017-01-23 2017-05-11 转移染色方法

Country Status (7)

Country Link
US (1) US10618272B2 (zh)
EP (1) EP3572232B1 (zh)
JP (1) JP6865287B2 (zh)
CN (1) CN108342914B (zh)
ES (1) ES2952548T3 (zh)
TW (1) TWI650462B (zh)
WO (1) WO2018133258A1 (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111923578A (zh) * 2020-07-01 2020-11-13 沈阳飞行船数码喷印设备有限公司 一种双面喷印转印一体装置

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109808322B (zh) * 2019-02-26 2021-02-26 浙江金晨纺织科技有限公司 一种热转纸张的凹版印刷方法
CN110485085B (zh) * 2019-08-12 2022-06-17 林金标 一种平幅卧式双涂层染色设备
JP6814365B1 (ja) * 2019-12-09 2021-01-20 東洋インキＳｃホールディングス株式会社 前処理液、インキセット、及び印刷物
CN111074457A (zh) * 2019-12-09 2020-04-28 高斯图文印刷系统（中国）有限公司 一种染色布的双面印染设备
TWI791968B (zh) * 2020-03-27 2023-02-11 財團法人紡織產業綜合研究所 使織物均勻染色的方法
CN112647320B (zh) * 2020-12-17 2022-04-19 长胜纺织科技发展(上海)有限公司 一种用于牛仔布的活性染料转移染色方法
CN112832042A (zh) * 2020-12-30 2021-05-25 长胜纺织科技发展(上海)有限公司 一种用于牛仔布的悬浮体染料转移染色的方法
CN113262969A (zh) * 2021-04-02 2021-08-17 福建华峰运动用品科技有限公司 高精度3d柔软涂层及其激光雕刻工艺和纺织面料
CN113265804B (zh) * 2021-05-12 2023-04-07 福州华冠针纺织品有限公司 一种转移扎染方法及其制得的锦棉花边蕾丝面料
TWI817136B (zh) * 2021-06-10 2023-10-01 富泰企業股份有限公司 環保無溶劑重磅織物之結構及其製程
CN113584752A (zh) * 2021-08-06 2021-11-02 长胜纺织科技发展(上海)有限公司 场射流织物染色方法和场射流织物染色系统

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2250940A1 (de) * 1972-10-18 1974-05-02 Vepa Ag Verfahren und vorrichtung zum bedrucken textiler waren
US4138945A (en) * 1975-07-21 1979-02-13 Thomas Rejto Simultaneous heat transfer printing and embossing method
JPH06206305A (ja) * 1991-12-03 1994-07-26 Crown Cork & Seal Co Inc 単一パスにおいて多色容器本体ブランクを印刷するための装置と方法
CN1915682A (zh) * 2005-11-29 2007-02-21 李智 一种升华印刷的工艺方法及卫星式升华印刷机
CN102505525A (zh) * 2011-10-13 2012-06-20 上海长胜纺织制品有限公司 冷转移数码喷墨印花前处理液及其使用方法
CN102785495A (zh) * 2012-07-26 2012-11-21 浙江亿得化工有限公司 一种用于纺织物染料多套色辊筒凹版印刷印花生产方法
CN105058968A (zh) * 2015-07-21 2015-11-18 长胜纺织科技发展(上海)有限公司 一种转印和直印两用印花设备
CN105150673A (zh) * 2015-08-17 2015-12-16 长胜纺织科技发展(上海)有限公司 印转联合一体转移印花设备

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1594629A (en) * 1976-12-21 1981-08-05 Ciba Geigy Ag Wet transfer process
CN100339237C (zh) * 2005-06-10 2007-09-26 上海迪纺纺织科技有限公司 用凹版印刷机印制全棉转移印花纸的生产工艺
CN100463805C (zh) * 2005-11-23 2009-02-25 上海迪纺纺织科技有限公司 柔版转移印花纸的生产方法
ES2403133T3 (es) * 2010-11-05 2013-05-14 Neopack, S.L. Máquina impresora offset de formato variable dotada de un cilindro central de impresión
CN102561074A (zh) * 2011-12-16 2012-07-11 上海长胜纺织制品有限公司 一种转移印花新的前处理方法
CN102838898B (zh) * 2012-09-26 2014-10-15 长胜纺织科技发展(上海)有限公司 一种冷转移印花用酸性染料墨水及其应用方法
CN205112630U (zh) * 2015-07-21 2016-03-30 长胜纺织科技发展(上海)有限公司 一种转印和直印两用印花设备
CN205112632U (zh) * 2015-08-17 2016-03-30 长胜纺织科技发展(上海)有限公司 印转联合一体转移印花设备
CN105479933B (zh) * 2015-11-23 2017-09-12 浙江美格机械股份有限公司 双面直接染色印花机

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2250940A1 (de) * 1972-10-18 1974-05-02 Vepa Ag Verfahren und vorrichtung zum bedrucken textiler waren
US4138945A (en) * 1975-07-21 1979-02-13 Thomas Rejto Simultaneous heat transfer printing and embossing method
JPH06206305A (ja) * 1991-12-03 1994-07-26 Crown Cork & Seal Co Inc 単一パスにおいて多色容器本体ブランクを印刷するための装置と方法
CN1915682A (zh) * 2005-11-29 2007-02-21 李智 一种升华印刷的工艺方法及卫星式升华印刷机
CN102505525A (zh) * 2011-10-13 2012-06-20 上海长胜纺织制品有限公司 冷转移数码喷墨印花前处理液及其使用方法
CN102785495A (zh) * 2012-07-26 2012-11-21 浙江亿得化工有限公司 一种用于纺织物染料多套色辊筒凹版印刷印花生产方法
CN105058968A (zh) * 2015-07-21 2015-11-18 长胜纺织科技发展(上海)有限公司 一种转印和直印两用印花设备
CN105150673A (zh) * 2015-08-17 2015-12-16 长胜纺织科技发展(上海)有限公司 印转联合一体转移印花设备

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111923578A (zh) * 2020-07-01 2020-11-13 沈阳飞行船数码喷印设备有限公司 一种双面喷印转印一体装置

Also Published As

Publication number Publication date
JP6865287B2 (ja) 2021-04-28
CN108342914B (zh) 2020-07-14
TW201827669A (zh) 2018-08-01
EP3572232B1 (en) 2023-07-19
EP3572232A1 (en) 2019-11-27
ES2952548T3 (es) 2023-11-02
US10618272B2 (en) 2020-04-14
CN108342914A (zh) 2018-07-31
TWI650462B (zh) 2019-02-11
EP3572232A4 (en) 2020-10-28
US20190217600A1 (en) 2019-07-18
JP2020505221A (ja) 2020-02-20
EP3572232C0 (en) 2023-07-19

Similar Documents

Publication Publication Date Title
WO2018133258A1 (zh) 转移染色方法
CN205112630U (zh) 一种转印和直印两用印花设备
CN105058968A (zh) 一种转印和直印两用印花设备
CN102877363B (zh) 浸染式纸张染色方法
CN103898778B (zh) 一种天然织物或人棉的升华转移印花工艺
CN102785466B (zh) 一种柔版滚筒式转移印花系统及印花方法
CN102561074A (zh) 一种转移印花新的前处理方法
WO2018133257A1 (zh) 印花部套装置
CN108340667B (zh) 转移染色设备
CN106436460A (zh) 一种纸张涂布装置
CN107672289B (zh) 一种印染作业免蒸洗的凹凸版直印装置及使用方法
CN105172365A (zh) 纺织品转移印花时的雕印工艺应用装置
CN206605893U (zh) 一种台布印刷机
CN102321959A (zh) 一种面料上浆机
US20080168915A1 (en) Roller transfer printing apparatus for cold transfer printing
CN202247330U (zh) 一种面料上浆机
CN108340663B (zh) 无纸化转移印花机
CN109894327A (zh) 一种加工热升华数码转印印花纸的涂布机及其加工方法
CN202727551U (zh) 一种柔版滚筒式转移印花系统
WO2022142063A1 (zh) 一种用于牛仔布的悬浮体染料转移染色的方法
CN205112631U (zh) 纺织品转移印花时的雕印工艺应用装置
CN2837351Y (zh) 节能型烫金、复膜、压花机
CN208346469U (zh) 针织彩色仿旧面料的高环保生产线
CN113400781A (zh) 一种双面冷转移印花设备
CN108239887B (zh) 一种对版给液前处理方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 17892141

Country of ref document: EP

Kind code of ref document: A1

ENP Entry into the national phase

Ref document number: 2019537144

Country of ref document: JP

Kind code of ref document: A

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2017892141

Country of ref document: EP