CN108239887B - 一种对版给液前处理方法 - Google Patents

一种对版给液前处理方法 Download PDF

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CN108239887B
CN108239887B CN201611223332.1A CN201611223332A CN108239887B CN 108239887 B CN108239887 B CN 108239887B CN 201611223332 A CN201611223332 A CN 201611223332A CN 108239887 B CN108239887 B CN 108239887B
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pretreatment
plate
fabric
transfer printing
liquid
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CN108239887A (zh
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钟博文
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NEWTECH TEXTILE TECHNOLOGY DEVELOPMENT (SHANGHAI) Co.,Ltd.
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Newtech Textile Technology Development Shanghai Co ltd
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Abstract

本发明涉及一种对版给液前处理方法，包括以下步骤：配制织物前处理液；以及使织物从第一前处理装置中通过，该第一前处理装置包括前处理版辊、承压辊、刮刀和前处理液槽，前处理版辊部分地浸在前处理液槽中，刮刀设在前处理版辊和承压辊之间的夹持部入口附近并且抵接前处理版辊，织物从前处理版辊和承压辊之间的夹持部通过，其中，前处理版辊上具有待转移印花图案的版型，从而将该前处理液仅通过前处理版辊的版型给液的方式定位上浆涂覆在织物一面的待印花部位。

Description

一种对版给液前处理方法
技术领域
本发明涉及纺织工业中的印染技术，特别是涉及一种新型的冷转移印花前处理方法。
背景技术
转移印花是纺织品印花方法之一，始于20世纪60年代末。早期的转移印花主要采用热转移印花工艺，即先将某种染料印在纸等其他材料上，然后再用热压等方式，使花纹转移到织物上的一种印花方法。对于棉织物等天然纤维由于没有比较明确的玻璃化温度，在高温下不能像涤纶那样出现液层现象，与热转移印花所用的染料之间没有亲和力，因此热转移方法主要适用于涤纶织物上印花，后期虽然通过架桥剂等方式实现了天然纤维上的热转移印花，但架桥剂工艺操作复杂，至今未得到大规模生产应用。
近年来，冷转移印花技术发展迅速，该工艺生产的冷转移印花面料已大量进入市场，并广受欢迎。冷转移印花基本流程是先将水溶性或水分散性的染料色浆印刷制成转移印花花纸，然后织物经预处理后与转移印花纸相密合，并施加以一定的压力。织物所带前处理液使转移印花纸上的色浆溶解。在一定的压力下，由于染料对织物的亲和力比对转移纸的亲和力大，染料转移到织物上，并进入到织物间隙中。经固色后对织物进行水洗，洗去微量的浆料和水解染料等，并将织物洗至中性，烘干定型即为成品。
冷转移印花的关键技术环节之一就在于织物的前处理。前处理的作用在于冷转移印花过程中，提供染料的转移需要的湿态环境，其次往往通过前处理工序中前处理液对织物的上浆，提升上染率和固色率，很好地控制印花图案在布面的渗透率及精细线条的扩散性。传统的冷转移印花前处理方法，如CN104928864A“冷转移印花三辊式前处理装置”，CN2844175Y“冷转移印花机的前处理装置”，CN201380632Y“冷转移印花机的调节式前处理装置”，CN201350725Y“转移印花机的定量给液装置”等资料所公开的技术方案均是对织物整体或表面进行全面的上浆给液，而众所周知，印花不同于染色，印花仅是在织物面料上根据花型部位进行上染，是一种局部染色，因此传统前处理方法中对于未上染部位的前处理就造成了前处理液的浪费，进而增加了后道水洗的负担。因此，从进一步节能减排的需求目标出发，冷转移印花需要开发一种更为精确给液的方法。
发明内容
为了发展经济节约的生产工艺，进一步在冷转移印花产线上实现节能减排的目标，本发明提供了一种对版给液的前处理方法。
根据本发明的对版给液前处理方法，包括以下步骤：配制织物前处理液；以及使织物从第一前处理装置中通过，该第一前处理装置包括前处理版辊、承压辊、刮刀和前处理液槽，前处理版辊部分地浸在前处理液槽中，刮刀设在前处理版辊和承压辊之间的夹持部入口附近并且抵接前处理版辊，织物从前处理版辊和承压辊之间的夹持部通过，其中，前处理版辊上具有待转移印花图案的版型，从而将该前处理液仅通过前处理版辊的版型给液的方式定位上浆涂覆在织物一面的待印花部位。
根据本发明，在织物一面进行了上述前处理后，将前处理后的织物送入转移印花机，与同步送入的转移印花暂载体对版，该转移印花暂载体上具有待转移印花到织物上的染料图案且该染料图案与前处理版辊上的版型图案相同，以实现转移印花暂载体染料图案与织物前处理液涂覆位置重合一致，从而实现转移印花。
根据本发明，在织物一面转移印花之后，使织物从第二前处理装置中通过，该第二前处理装置与第一前处理装置的结构组成相同，以将织物反面前处理液通过第二前处理装置的前处理版辊的版型给液的方式定位上浆涂覆在织物反面的待印花部位。
根据本发明，在对织物反面进行上述前处理后，将反面前处理后的织物送入转移印花机，与同步送入的转移印花暂载体对版，该转移印花暂载体上具有待转移印花到织物反面上的染料图案且该染料图案与第二前处理装置中前处理版辊上的版型图案相同，以实现转移印花暂载体染料图案与织物反面前处理液涂覆位置重合一致，从而实现转移印花。
所述对版给液前处理液的配方，按各组分的重量百分比可以为：
Figure BDA0001193107430000031
所述连接料可以为多糖类高聚物及其衍生物，或合成龙胶，或聚乙烯醇；根据本申请，选用这样水溶性的连接料可以在后续水洗工序中洗去，从而与现有技术相比能够改善手感；
所述表面活性剂可以为聚乙烯吡咯烷酮，或聚氧乙烯烷基胺，或脂肪醇聚氧乙烯醚，或聚硅醚；
螯合剂可以为六偏磷酸钠SHMP，或乙二胺四乙酸EDTA，或羟基乙叉二膦酸HEDP，或2-羟基膦酸基乙酸HPAA，或己二胺四甲叉膦酸HDTMPA，或羟乙基替乙二胺三乙酸HEEDTA；
所述保湿剂可以为甘油，或二甘醇；
所述固色剂，活性染料印花用对版给液前处理液中的固色剂可以为碳酸钠，或碳酸氢钠，或氢氧化钠，或碳酸钾，或碳酸氢钾，或氢氧化钾，或代用碱；酸性染料印花用对版给液前处理液中的固色剂可以为尿素，或双氰胺；分散染料印花用对版给液前处理液中不加固色剂；
所述pH调节剂可以为柠檬酸，或醋酸，或硫酸铵；或三乙醇胺。
前处理版辊可以为凹版版辊，或柔版版辊，或圆网版辊，或胶版版辊。
本发明的有益效果在于，采用对版给液前处理方法，仅对织物面料上待印花部位进行上浆前处理，避免了传统前处理方法中对于织物所有部位进行上浆前处理所造成的前处理液的浪费，进而减少了后道水洗的负担。因此，能够进一步满足节能减排的需要，给冷转移印花工艺的绿色标签更增添其绿色要素。此外，采用本发明前处理液配方并利用前处理版辊上浆的方式，由于在前处理时织物的非印花部位不给液，为干态，而织物干态区域无毛细效应等导致的渗化现象，从而能够进一步提升印花图案的精度。
附图说明
下面结合附图和实施例对本发明进一步的说明。
图1本发明所述对版给液前处理方法示意图。
图2对版给液前处理后织物转移印花流程示意图。
具体实施方式
下面结合图1和图2以非限制性实施例来进一步说明本发明，但应注意的是，这些实施例不应视为是对本发明的限制。
实施例1：全棉织物，双面对版给液前处理，双面转移印花。
织物规格:100％棉针织150g/m2。
全棉织物的双面对版给液前处理以及双面转移印花方法，主要包括以下步骤：
配制织物正面印前处理液；使织物4从前处理版辊1和承压辊2之间的夹持部通过，前处理版辊部分地浸在前处理液槽5中，版辊上具有待转移印花图案的版型，在前处理版辊1和承压辊2之间夹持部入口附近设有刮刀，刮刀相对于前处理版辊旋转方向以逆向地抵接前处理版辊，以把前处理版辊上除版型之外部位的前处理液刮除，从而将该前处理液通过前处理版辊的版型部给液的方式定位上浆(或称对版给液)涂覆在织物正面的待印花部位；将前处理后的织物送入转移印花机，与同步送入的转移印花暂载体(例如转移印花纸)对版压合，该转移印花暂载体上具有待转移印花到织物上的染料图案且该染料图案与前处理版辊上的版型相同，以实现转移印花暂载体染料图案与织物前处理液涂覆位置重合一致，从而实现正面转移印花，即把转移印花暂载体染料图案转移印花到织物正面。在对织物反面进行前处理以及转移印花时，步骤与以上相似：配制织物反面印前处理液；使织物通过第二前处理装置，该第二前处理装置与正面前处理时的第一前处理装置组成结构相同(但第一、二前处理装置中前处理版辊的版型图案可相同，也可不同，这根据织物正反面转移印花图案是相同或不同而定)，将该前处理液通过前处理版辊的版型部给液的方式定位上浆(或称对版给液)涂覆在织物反面的待印花部位；将反面前处理后的织物送入转移印花机，与同步送入的转移印花暂载体(例如转移印花纸)对版压合，该转移印花暂载体上具有待转移印花到织物反面上的染料图案且该染料图案与反面前处理版辊上的版型相同，以实现转移印花暂载体染料图案与织物反面前处理液涂覆位置重合一致，从而实现反面转移印花，即把转移印花暂载体染料图案转移印花到织物反面。最后，把织物固色水洗定型后即为转移印花成品。
所述正面印前处理液的配方，按各组分的重量百分比为：
Figure BDA0001193107430000051
其中，连接料为醚化淀粉；表面活性剂为聚乙烯吡咯烷酮；螯合剂为六偏磷酸钠SHMP；保湿剂为甘油；固色剂为代用碱。
所述反面印前处理液的配方，按各组分的重量百分比为：
Figure BDA0001193107430000061
其中，连接料为合成龙胶；表面活性剂为聚乙烯吡咯烷酮；螯合剂为乙二胺四乙酸EDTA；保湿剂为甘油；固色剂为代用碱。
前处理版辊为圆网版辊，160目。
实施例2：尼龙织物，单面对版给液前处理以及转移印花
织物规格:塔丝隆；原料：100％尼龙，规格：70D×160D
配制织物正面印前处理液；使织物4从前处理版辊1和承压辊2之间的夹持部通过，前处理版辊部分地浸在前处理液槽5中，版辊上具有待转移印花图案的版型，在前处理版辊1和承压辊2之间夹持部入口附近设有刮刀，刮刀相对于前处理版辊旋转方向以逆向地抵接前处理版辊，以把前处理版辊上除版型之外部位的前处理液刮除，从而将该前处理液通过前处理版辊的版型部给液的方式定位上浆(或称对版给液)涂覆在织物正面的待印花部位；将前处理后的织物送入转移印花机，与同步送入的转移印花暂载体(例如转移印花纸)对版压合，该转移印花暂载体上具有待转移印花到织物上的染料图案且该染料图案与前处理版辊上的版型相同，以实现转移印花暂载体染料图案与织物前处理液涂覆位置重合一致，从而实现正面转移印花，即把转移印花暂载体染料图案转移印花到织物正面。最后，固色水洗定型后即为转移印花成品。
所述前处理液的配方，按各组分的重量百分比为：
Figure BDA0001193107430000062
Figure BDA0001193107430000071
其中，所述连接料为醚化淀粉；所述表面活性剂为聚硅醚；螯合剂为羟基乙叉二膦酸HEDP；所述保湿剂为二甘醇；所述固色剂为双氰胺；所述pH调节剂为硫酸铵。
所述前处理版辊为凹版版辊，80目。
实施例3：涤纶织物，单面对版给液前处理以及转移印花
织物：涤纶绉麻；织物规格：原料为涤纶111dtex(DTY)×111dtex(DTY)，密度为256×256根/10cm,重量为142g/m2。
配制织物正面印前处理液；使织物4从前处理版辊1和承压辊2之间的夹持部通过，前处理版辊部分地浸在前处理液槽5中，版辊上具有待转移印花图案的版型，在前处理版辊1和承压辊2之间夹持部入口附近设有刮刀，刮刀相对于前处理版辊旋转方向以逆向地抵接前处理版辊，以把前处理版辊上除版型之外部位的前处理液刮除，从而将该前处理液通过前处理版辊的版型部给液的方式定位上浆(或称对版给液)涂覆在织物正面的待印花部位；将前处理后的织物送入转移印花机，与同步送入的转移印花暂载体(例如转移印花纸)对版压合，该转移印花暂载体上具有待转移印花到织物上的染料图案且该染料图案与前处理版辊上的版型相同，以实现转移印花暂载体染料图案与织物前处理液涂覆位置重合一致，从而实现正面转移印花，即把转移印花暂载体染料图案转移印花到织物正面。最后，固色水洗定型后即为转移印花成品。
所述前处理液的配方，按各组分的重量百分比为：
Figure BDA0001193107430000072
Figure BDA0001193107430000081
其中，所述连接料为聚乙烯醇；所述表面活性剂为脂肪醇聚氧乙烯醚；螯合剂为己二胺四甲叉膦酸HDTMPA；所述保湿剂为二甘醇。
前处理版辊为柔版版辊，60线。
以上虽然描述了三种具体实施例，但本领域技术人员应该理解，在本发明的构思下，各实施例的一些细节可以适当地结合、变更或替换。例如，尽管仅在实施例1中描述了双面前处理和双面转移印花，但实施例2和实施例3中也可进行双面前处理和双面转移印花。此外，视前处理上浆量的需要，实施例1、实施例2和实施例3中的前处理版辊可互换，或者可以采用其它型式。此外，关于前处理后的织物进入转移印花机与转移印花暂载体对版，可以采用在织物边缘和/或暂载体边缘做标记(例如打孔、打标等)并且通过识别标记(例如传感器等)的方式来进行。此外，织物的类型不限于实施例1、2、3中所描述的。

Claims (7)

1.一种对版给液前处理方法，包括以下步骤：
配制织物前处理液；以及
使织物从第一前处理装置中通过，该第一前处理装置包括前处理版辊、承压辊、刮刀和前处理液槽，前处理版辊部分地浸在前处理液槽中，刮刀设在前处理版辊和承压辊之间的夹持部入口附近并且抵接前处理版辊以把前处理版辊上除版型之外部位的前处理液刮除，织物从前处理版辊和承压辊之间的夹持部通过，其中，前处理版辊上具有待转移印花图案的版型，从而将该前处理液仅通过前处理版辊的版型给液的方式定位上浆涂覆在织物一面的待印花部位；
其中，前处理液的配方，按各组分的重量百分比可以为：连接料5-10％；表面活性剂1-3％；螯合剂0.8-1.6％；保湿剂2-5％；固色剂0-5％；pH调节剂0-2％；用去离子水调到100％。
2.根据权利要求1所述的对版给液前处理方法，其中，将前处理后的织物送入转移印花机，与同步送入的转移印花暂载体对版压合，该转移印花暂载体上具有待转移印花到织物上的染料图案且该染料图案与前处理版辊上的版型图案相同，以实现转移印花暂载体染料图案与织物前处理液涂覆位置重合一致，从而实现转移印花。
3.根据权利要求2所述的对版给液前处理方法，其中，使织物从第二前处理装置中通过，该第二前处理装置与第一前处理装置的结构组成相同，以将织物反面前处理液通过第二前处理装置的前处理版辊的版型给液的方式定位上浆涂覆在织物反面的待印花部位。
4.根据权利要求3所述的对版给液前处理方法，其中，将反面前处理后的织物送入转移印花机，与同步送入的转移印花暂载体对版压合，该转移印花暂载体上具有待转移印花到织物反面上的染料图案且该染料图案与第二前处理装置中前处理版辊上的版型图案相同，以实现转移印花暂载体染料图案与织物反面前处理液涂覆位置重合一致，从而实现转移印花。
5.根据权利要求3或4所述的对版给液前处理方法，其中，第一前处理装置中前处理版辊的版型与第二前处理装置中前处理版辊的版型相同或不同。
6.根据权利要求1所述的对版给液前处理方法，其中，连接料为多糖类高聚物及其衍生物，或合成龙胶，或聚乙烯醇；表面活性剂为聚乙烯吡咯烷酮、聚氧乙烯烷基胺、脂肪醇聚氧乙烯醚或聚硅醚；螯合剂为六偏磷酸钠SHMP、乙二胺四乙酸EDTA、羟基乙叉二膦酸HEDP、2-羟基膦酸基乙酸HPAA、己二胺四甲叉膦酸HDTMPA或羟乙基替乙二胺三乙酸HEEDTA；保湿剂为甘油或二甘醇；活性染料转移印花用前处理液中的固色剂为碳酸钠、碳酸氢钠、氢氧化钠、碳酸钾、碳酸氢钾、氢氧化钾或代用碱；酸性染料转移印花用前处理液中的固色剂为尿素或双氰胺；分散染料转移印花用前处理液中不加固色剂；pH调节剂为柠檬酸、醋酸、硫酸铵或三乙醇胺。
7.根据权利要求1或3所述的对版给液前处理方法，其中，第一前处理装置和第二前处理装置中的前处理版辊为凹版版辊、柔版版辊、圆网版辊或胶版版辊。
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