WO2018052146A1 - 組成物及び製品 - Google Patents
組成物及び製品 Download PDFInfo
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- WO2018052146A1 WO2018052146A1 PCT/JP2017/033612 JP2017033612W WO2018052146A1 WO 2018052146 A1 WO2018052146 A1 WO 2018052146A1 JP 2017033612 W JP2017033612 W JP 2017033612W WO 2018052146 A1 WO2018052146 A1 WO 2018052146A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
- A61K8/466—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfonic acid derivatives; Salts
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
- A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/48—Thickener, Thickening system
Definitions
- composition relates to a composition.
- the present disclosure relates to a composition that can be applied to hair styling.
- the present disclosure also relates to a product comprising the composition.
- the present disclosure relates to cosmetic products.
- Patent Document 1 and Patent Document 2 disclose hair styling materials aimed at improving the feeling of use and hair styling power.
- Patent Document 1 contains (a) a wax, a hydrophobically modified polyether urethane represented by a specific structural formula, (c) an ionic vinyl polymer, and (d) an alcohol, and has a viscosity. Is 20,000 to 100,000 mPa ⁇ s. Patent Document 1 discloses an example using a nonionic surfactant.
- the emulsified hair styling described in Patent Document 2 includes: (a) component: a long-chain acyl sulfonate anionic surfactant represented by a specific structural formula; and (b) component: a higher aliphatic alcohol. (C) component: (c-1) 0.5 to 50% by mass of waxes, (c-2) 0.1 to 8% by mass of hairdressing resin, and (c-3) 0.1 to 8% of powder component. 1 type (s) or 2 or more types chosen from 8 mass%, and (d) component: Water is included.
- the hair cosmetic described in Patent Document 1 uses a nonionic surfactant and feels sticky when used. Moreover, the washing
- the emulsified hair styling described in Patent Document 2 has a problem of ease of hair styling because the drying time is fast and the hair styling time is short.
- composition having no stickiness during use and excellent cleaning properties. Further, for example, when the composition is used as a hair styling material, it is desired that the hair styling time can be sufficiently maintained while having hair styling power.
- composition containing an associative thickener, an anionic surfactant, and a higher alcohol is provided.
- a product including a container, and a first composition and a second composition present in the container is provided.
- the first composition and the second composition are disposed in the container at least partially in contact with each other.
- the first composition and the second composition contain an associative thickener, an anionic surfactant, and a higher alcohol.
- the user can be prevented from feeling sticky.
- the user can easily clean the compositions and products of the present disclosure.
- the hair styling material When the composition of the present disclosure is applied to a hair styling material, the hair styling material has high hair styling power. Moreover, the said hairdressing material can fully ensure the state in which a user can style hair.
- the schematic side view of the container in 3rd Embodiment. The schematic top view of the product in 3rd Embodiment.
- the schematic side view of the product in 3rd Embodiment. The schematic side view of the product in 3rd Embodiment.
- the schematic side view of the product in 3rd Embodiment. The schematic sectional drawing of the product in 3rd Embodiment.
- the schematic sectional drawing of the product in 3rd Embodiment. The schematic sectional drawing of the product in 3rd Embodiment.
- the schematic sectional drawing of the product in 3rd Embodiment. The schematic sectional drawing of the product in 3rd Embodiment.
- the schematic sectional drawing of the product in 3rd Embodiment. The graph which shows the result of the test example 1, the test example 2, and the test example 14.
- the content of the associative thickener is 0.1% by mass to 3% by mass with respect to the mass of the composition.
- the content of the anionic surfactant is 0.3% by mass to 4% by mass with respect to the mass of the composition.
- the content of higher alcohol is 0.2% by mass to 8% by mass with respect to the mass of the composition.
- the content of the oil component including the higher alcohol is 5% by mass to 55% by mass with respect to the mass of the composition.
- the anionic surfactant is N-stearoyl-N-methyltaurine salt.
- the composition further contains 0.1% by mass to 10% by mass of powder with respect to the mass of the composition.
- the associative thickener is a hydrophobically modified polyether urethane and / or a taurate-based synthetic polymer.
- the hydrophobically modified polyether urethane has the following structural formula (I).
- R 1 , R 2 and R 4 are each independently a hydrocarbon group having 2 to 4 carbon atoms
- R 3 is a hydrocarbon group having 1 to 10 carbon atoms which may have a urethane bond
- R 5 is a hydrocarbon group having 8 to 36 carbon atoms
- m is a number greater than or equal to 2
- h is a number greater than or equal to 1
- k is a number from 1 to 500
- n is a number from 1 to 200.
- the hydrophobically modified polyether urethane is a (PEG-240 / decyltetradeceth-20 / hexamethyl diisocyanate) copolymer.
- the taurate-based synthetic polymer is a polymer and / or copolymer (including a crosslinked polymer) having 2-acrylamido-2-propanesulfonic acid or a salt thereof as a structural unit. is there.
- the taurate-based synthetic polymer is a (acryloyldimethyltaurine ammonium / beheneth-25 methacrylate) crosspolymer.
- the viscosity is 10,000 mPa ⁇ s to 200,000 mPa ⁇ s.
- the composition further contains an ionic polymer.
- the ionic polymer is a (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer.
- the product uses a mixture obtained by kneading the first composition and the second composition taken out from the container as a cosmetic.
- the viscosity of the first composition and the second composition is 10,000 mPa ⁇ s to 200,000 mPa ⁇ s.
- the container has an opening.
- the opening overlaps with a part of the interface between the first composition and the second composition.
- the first composition and the second composition can be extruded simultaneously through the openings.
- the first composition further contains a first component.
- the second composition further contains a second component. The first component and the second component bind and / or associate when the first composition and the second composition are mixed.
- the first component and the second component are ionic polymers.
- the first component is an amphoteric polymer and / or an anionic polymer.
- the second component is an amphoteric polymer and / or a cationic polymer.
- the anionic polymer is at least one of urethane polymer and (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP.
- the amphoteric polymer is an acrylic polymer.
- the amphoteric polymer is a (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer.
- the cationic polymer is at least one of polyquaternium-11 and polyurethane-10.
- the second viewpoint is a hair styling product.
- composition according to the first embodiment of the present disclosure will be described.
- the composition of the present disclosure can be applied to, for example, a hair styling agent.
- the composition of the present disclosure may be an oil-in-water type or a water-in-oil type.
- composition of the present disclosure contains an associative thickener, an anionic surfactant, and a higher alcohol.
- the associative thickener usually has a hydrophobic part and a hydrophilic part.
- the associative thickener preferably has a hydrophobic portion at both ends.
- the associative thickener preferably has a hydrophilic portion between the hydrophobic portions at both ends.
- a certain associative thickener forms a network (network structure) by associating hydrophobic portions with each other, and develops a thickening action.
- hydrophobically modified polyether urethane and / or taurate-based synthetic polymer can be used. Even if the thickening mechanism of the thickener listed below is not associative, the thickener is not excluded from the thickener applicable to the composition of the present disclosure.
- hydrophobically modified polyether urethane for example, a polymer having the following structural formula (I) can be used.
- R 1 , R 2 and R 4 are each independently preferably a hydrocarbon group having 2 to 4 carbon atoms, and more preferably an alkylene group having 2 to 4 carbon atoms. .
- R 3 is preferably a hydrocarbon group having 1 to 10 carbon atoms which may have a urethane bond.
- R 5 is preferably a hydrocarbon group having 8 to 36 carbon atoms, and more preferably a hydrocarbon group having 12 to 24 carbon atoms.
- R 1 can be an ethylene group.
- R 2 can be an ethylene group.
- R 3 can be an alkylene group having 4 to 8 carbon atoms.
- R 4 can be an ethylene group.
- R 5 can be a branched alkyl group having 16 to 32 carbon atoms.
- m is preferably a number of 2 or more.
- h is preferably a number of 1 or more, and more preferably 1.
- k is preferably a number of 1 to 500, more preferably 100 to 300.
- n is preferably a number from 1 to 200, more preferably from 10 to 100.
- the polyether polyol compound represented by the above formula R 1 [(OR 2 ) k OH] m is an addition polymerization of m-valent polyol with alkylene oxide such as ethylene oxide, propylene oxide, butylene oxide, epichlorohydrin, styrene oxide, etc. Can be obtained.
- R 1 is determined by the m-valent polyol.
- R 2 is determined by alkylene oxide, styrene oxide or the like.
- the molecular weight of R 1 [(OR 2 ) k OH] m is preferably 500 to 100,000, more preferably 1,000 to 50,000.
- the polyol is preferably a divalent to octavalent one.
- a dihydric alcohol such as ethylene glycol, propylene glycol, butylene glycol, hexamethylene glycol, neopentyl glycol; glycerin, trioxyisobutane, 1,2,3-butanetriol, 1,2,3-pentatriol 2-methyl-1,2,3-propanetriol, 2-methyl-2,3,4-butanetriol, 2-ethyl-1,2,3-butanetriol, 2,3,4-pentanetriol, 2 , 3,4-hexanetriol, 4-propyl-3,4,5-heptanetriol, 2,4-dimethyl-2,3,4-pentanetriol, pentamethylglycerin, pentaglycerin, 1,2,4-butane Triol, 1,2,4-pentanetriol, trimethylolethane, Trihydric alcohols such as methylolpropane; pent
- alkylene oxide, styrene oxide and the like to be added are particularly easily available, and are preferably alkylene oxide or styrene oxide having 2 to 4 carbon atoms in order to exhibit an excellent effect.
- Alkylene oxide, styrene oxide and the like may be homopolymerization, two or more types of random polymerization, or block polymerization.
- the addition method may be a normal method.
- the degree of polymerization k is preferably 0 to 1000, more preferably 1 to 500, and even more preferably 10 to 200.
- Ratio of ethylene groups occupied in R 2 is preferably a 50 to 100% by weight based on the total R 2.
- the polyisocyanate represented by the formula R 3 (NCO) h + 1 is not particularly limited as long as it has two or more isocyanate groups in the molecule.
- Examples of the polyisocyanate include aliphatic diisocyanate, aromatic diisocyanate, alicyclic diisocyanate, biphenyl diisocyanate, and phenylmethane diisocyanate, triisocyanate, and tetraisocyanate.
- aliphatic diisocyanate examples include methylene diisocyanate, dimethylene diisocyanate, trimethylene diisocyanate, tetramethylene diisocyanate, pentamethylene diisocyanate, hexamethylene diisocyanate, dipropyl ether diisocyanate, 2,2-dimethylpentane diisocyanate, 3-methoxyhexane diisocyanate, Octamethylene diisocyanate, 2,2,4-trimethylpentane diisocyanate, nonamethylene diisocyanate, decamethylene diisocyanate, 3-butoxyhexane diisocyanate, 1,4-butylene glycol dipropyl ether diisocyanate, thiodihexyl diisocyanate, metaxylylene diisocyanate, paraxylylene Range isocyania Over DOO, tetramethylxylylene diisocyanate, and the like.
- aromatic diisocyanate examples include metaphenylene diisocyanate, paraphenylene diisocyanate, 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, dimethylbenzene diisocyanate, ethylbenzene diisocyanate, isopropylbenzene diisocyanate, tolidine diisocyanate, 1,4- Examples include naphthalene diisocyanate, 1,5-naphthalene diisocyanate, 2,6-naphthalene diisocyanate, and 2,7-naphthalene diisocyanate.
- Examples of the alicyclic diisocyanate include hydrogenated xylylene diisocyanate and isophorone diisocyanate.
- biphenyl diisocyanate examples include biphenyl diisocyanate, 3,3′-dimethylbiphenyl diisocyanate, 3,3′-dimethoxybiphenyl diisocyanate, and the like.
- diisocyanate of phenylmethane examples include diphenylmethane-4,4′-diisocyanate, 2,2′-dimethyldiphenylmethane-4,4′-diisocyanate, diphenyldimethylmethane-4,4′-diisocyanate, 2,5,2 ′.
- triisocyanate of phenylmethane examples include 1-methylbenzene-2,4,6-triisocyanate, 1,3,5-trimethylbenzene-2,4,6-triisocyanate, and 1,3,7-naphthalenetriisocyanate.
- the polyisocyanate may be used as a dimer or trimer (isocyanurate bond) of these polyisocyanate compounds, or may be used as a biuret by reacting with an amine.
- polyisocyanate having a urethane bond obtained by reacting these polyisocyanate compounds with a polyol can also be used.
- the polyol those having 2 to 8 valences are preferable, and the above-mentioned polyols are preferable.
- polyisocyanate preferably has the urethane bond.
- the polyether monoalcohol represented by the above formula HO (R 4 O) n R 5 is not particularly limited as long as it is a monohydric alcohol polyether.
- the polyether monoalcohol can be obtained by addition polymerization of a monohydric alcohol with an alkylene oxide such as ethylene oxide, propylene oxide, butylene oxide, epichlorohydrin, styrene oxide, or the like.
- the monohydric alcohol here can be represented by, for example, the following formulas (II), (III) and (IV).
- R 5 may be a hydrocarbon group excluding the hydroxyl group in the above formulas (II) to (IV).
- R 5 is preferably R 6 , R 7 , R 8 , R 10 and R 11 , and examples thereof include an alkyl group, an alkenyl group, an alkylaryl group, a cycloalkyl group, and a cycloalkenyl group.
- R 5 has preferably 8 to 36 carbon atoms, more preferably 12 to 24 carbon atoms.
- alkyl group examples include methyl, ethyl, propyl, isopropyl, butyl, isobutyl, tertiary butyl, pentyl, isopentyl, neopentyl, tertiary pentyl, hexyl, heptyl, octyl, 2-ethylhexyl, nonyl, decyl, undecyl, dodecyl.
- Tridecyl isotridecyl, myristyl, palmityl, stearyl, isostearyl, icosyl, docosyl, tetracosyl, triacontyl, 2-octyldodecyl, 2-dodecylhexadecyl, 2-tetradecyloctadecyl, monomethyl branched-isostearyl and the like.
- alkenyl group examples include vinyl, allyl, propenyl, isopropenyl, butenyl, pentenyl, isopentenyl, hexenyl, heptenyl, octenyl, nonenyl, decenyl, undecenyl, dodecenyl, tetradecenyl, oleyl and the like.
- alkylaryl groups include phenyl, toluyl, xylyl, cumenyl, mesityl, benzyl, phenethyl, styryl, cinnamyl, benzhydryl, trityl, ethylphenyl, propylphenyl, butylphenyl, pentylphenyl, hexylphenyl, heptylphenyl, octylphenyl, nonyl Examples include phenyl, ⁇ -naphthyl, ⁇ -naphthyl group and the like.
- Examples of the cycloalkyl group and the cycloalkenyl group include a cyclopentyl, cyclohexyl, cycloheptyl, methylcyclopentyl, methylcyclohexyl, methylcycloheptyl, cyclopentenyl, cyclohexenyl, cycloheptenyl, methylcyclopentenyl, methylcyclohexenyl, methylcycloheptenyl group.
- R 9 is preferably a hydrocarbon group, and more preferably, for example, an alkylene group, an alkenylene group, an alkylarylene group, a cycloalkylene group, a cycloalkenylene group or the like.
- the alkylene oxide, styrene oxide and the like to be added may be homopolymerization, two or more kinds of random polymerization, or block polymerization.
- the addition method may be a normal method.
- the degree of polymerization n is preferably from 0 to 1000, more preferably from 1 to 200, and even more preferably from 10 to 200.
- the ratio of ethylene to total R 4 is preferably to be 50 wt% to 100 wt% of the total R 4, and more preferably to be 65 wt% to 100 wt%.
- a reaction between a normal polyether and an isocyanate can be used.
- the polyether and the isocyanate are reacted at 80 to 90 ° C. for 1 to 3 hours. It can be reacted by heating.
- PEG-240 / decyltetradeceth-20 / hexamethyldiisocyanate) copolymer (a copolymer represented by the above formula (I), wherein R 1 , R 2 , and R 4 are each An ethylene group, R 3 is a hexamethylene group, R 5 is a 2-dodecyldodecyl group, h is 1, m is 2, k is 120, and n is 20) (Adecanol® ) GT-700, ADEKA Corporation) can be used.
- associative thickeners include taurate-based synthetic polymers and / or acrylate-based synthetic polymers.
- a taurate polymer thickener a polymer and / or copolymer (crosslinking) having 2-acrylamido-2-propanesulfonic acid (acryloyldimethyltauric acid) or a salt thereof (AMPS structure) as a structural unit.
- AMPS structure 2-acrylamido-2-propanesulfonic acid
- AMPS structure a salt thereof
- a thickener for example, (acryloyldimethyltaurate ammonium / beheneth methacrylate-25) crosspolymer (Aristoflex (registered trademark) HMB, Clariant Japan) can be mentioned.
- the content of the associative thickener in the composition is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and 0.5% by mass or more with respect to the mass of the composition. Is more preferable. If the content of the associative thickener is less than 0.1% by mass, stickiness cannot be reduced.
- the content of the associative thickener in the composition is preferably 3.5% by mass or less, more preferably 3% by mass or less, and more preferably 2.5% by mass or less with respect to the mass of the composition. And more preferably 2% by mass or less. If the content of the associative thickener exceeds 3% by mass, the stickiness will be felt during use. Moreover, when the composition of this indication is used for a hairdressing material, the hairdressing ease will fall.
- thickening agent may be added as long as the effects of the present disclosure are not impaired.
- thickeners include, for example, gum arabic, carrageenan, gum karaya, gum tragacanth, carob gum, quince seed (malmello), casein, dextrin, gelatin, sodium pectate, sodium alginate, methylcellulose, ethylcellulose, carboxymethylcellulose (CMC).
- PVA polyvinyl alcohol
- PVM polyvinyl methyl ether
- PVP polyvinyl pyrrolidone
- sodium polyacrylate carboxyvinyl polymer
- locust bean gum locust bean gum
- guar gum tamarind gum
- dialkyldimethylammonium cellulose sulfate Xanthan gum
- magnesium aluminum silicate bentonite
- anionic surfactant examples include fatty acid soap (eg, sodium laurate, sodium palmitate, etc.); higher alkyl sulfates (eg, sodium lauryl sulfate, potassium lauryl sulfate); alkyl ether sulfates (eg, POE-lauryl sulfate triethanolamine, POE-sodium lauryl sulfate, etc.); N-acyl sarcosine acids (eg, sodium lauroyl sarcosine, etc.); higher fatty acid amide sulfonates (eg, sodium N-stearoyl-N-methyl taurate, N-myristoyl-N-methyl taurate sodium, coconut oil fatty acid methyl tauride sodium, lauryl methyl tauride sodium, etc .; phosphate ester salt (POE-oleyl ether sodium phosphate, POE- Sulfoaryl succinate (eg, sodium di
- an acyl taurine salt having 6 to 24 carbon atoms can be used.
- acyl taurine salts it is preferable to use sodium N-stearoyl-N-methyl taurate. By using this compound, stickiness during use can be suppressed.
- the composition of the present disclosure is applied to a hair styling material, the ease of hair styling can be improved.
- the content of the anionic surfactant is preferably 0.3% by mass or more with respect to the mass of the composition. When the anionic surfactant is less than 0.3% by mass, a stable emulsion cannot be obtained.
- the content rate of an anionic surfactant shall be 0.4 mass% or more, 0.5 mass% or more, 0.6 mass% or more, or 0.7 mass% or more with respect to the mass of a composition, for example. be able to.
- the content of the anionic surfactant is preferably 4% by mass or less and more preferably 3% by mass or less with respect to the mass of the composition. When the anionic surfactant exceeds 4% by mass, stickiness becomes strong and a stable emulsion cannot be obtained.
- the content of the anionic surfactant is, for example, 2.5% by mass or less, 2% by mass or less, 1.5% by mass or less, 1.2% by mass or less, or 1% by mass with respect to the mass of the composition. It can be as follows.
- higher alcohols include linear alcohols (eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol); branched chain alcohols (eg, monostearyl glycerin ether (batyl alcohol) ), 2-decyltetradecinol, lanolin alcohol, cholesterol, phytosterol, hexyl decanol, isostearyl alcohol, octyldodecanol, etc.) can be used.
- linear alcohols eg, lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol
- branched chain alcohols eg, monostearyl glycerin ether (batyl alcohol)
- 2-decyltetradecinol lanolin alcohol
- cholesterol phytosterol
- hexyl decanol
- the higher alcohol forms an ⁇ gel with the anionic surfactant.
- the content of the higher alcohol is preferably 0.2% by mass or more, more preferably 1% by mass or more, and more preferably 2% by mass or more based on the mass of the composition. If it is less than 0.2% by mass, the feeling of use becomes worse, for example, stickiness is felt.
- the content of the higher alcohol is preferably 8% by mass or less, more preferably 6% by mass or less, and still more preferably 4% by mass or less with respect to the mass of the composition. If it exceeds 8% by mass, cleanability and ease of hairdressing will decrease.
- composition of the present disclosure may further contain an oily component different from the higher alcohol.
- oil component for example, liquid fats, solid fats, waxes, hydrocarbons, higher fatty acids, higher alcohols, synthetic ester oils, silicone oils and the like can be used. The description above is used for higher alcohols.
- POE is an abbreviation for polyoxyethylene and POP is an abbreviation for polyoxypropylene, and the numbers in parentheses after POE or POP represent the average number of moles of POE groups or POP groups in the compound.
- liquid oils examples include avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, persic oil, wheat germ oil, southern castor oil, castor oil, linseed oil , Safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil, rice bran oil, cinnagiri oil, Japanese kiri oil, jojoba oil, germ oil, triglycerin and the like.
- solid fat examples include cacao butter, palm oil, horse fat, hydrogenated palm oil, palm oil, beef tallow, sheep fat, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, owl kernel oil, hydrogenated oil, cattle Leg fats, moles, hydrogenated castor oil and the like.
- waxes examples include beeswax, candelilla wax, cotton wax, carnauba wax, bayberry wax, ibota wax, whale wax, montan wax, nuka wax, lanolin, kapok wax, lanolin acetate, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, and reduced lanolin.
- hydrocarbon oil examples include liquid paraffin, ozokerite, squalane, pristane, paraffin, ceresin, squalene, petrolatum, and microcrystalline wax.
- higher fatty acid examples include lauric acid, myristic acid, palmitic acid, stearic acid, behenic acid, oleic acid, undecylenic acid, toluic acid, isostearic acid, linoleic acid, linolenic acid, eicosapentaenoic acid (EPA), docosahexaenoic acid ( DHA) and the like.
- Synthetic ester oils include isopropyl myristate, cetyl octanoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyl decyl dimethyloctanoate, cetyl lactate, myristyl lactate Lanolin acetate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexanoate, dipentaerythritol fatty acid ester, N-alkyl glycol monoisostearate, neopentyl glycol dicaprate, apple Acid diisostearyl, di-2-heptylundecanoic acid glycerin, tri-2-ethylhexanoic acid
- Silicone oils include dimethylpolysiloxane, methylhydrogenpolysiloxane, methylphenylpolysiloxane, stearoxymethylpolysiloxane, polyether-modified organopolysiloxane, fluoroalkyl / polyoxyalkylene co-modified organopolysiloxane, and alkyl-modified organopolysiloxane.
- silicone compounds such as non-terminally modified organopolysiloxane, fluorine-modified organopolysiloxane, amino-modified organopolysiloxane, silicone gel, acrylic silicone, trimethylsiloxysilicic acid, and silicone RTV rubber.
- the content of the oil component (including higher alcohol) is preferably 55% by mass or less, and more preferably 50% by mass or less, based on the mass of the composition. This is because if the amount exceeds 55% by mass, the sticky feeling increases and the cleaning performance decreases. Moreover, when the composition of this indication is used for a hairdressing material, it is because hairdressing power will fall.
- the content of the oil component is preferably 10% by mass or more, more preferably 20% by mass or more, and even more preferably 25% by mass or more with respect to the mass of the composition. This is because if it is less than 10% by mass, a sufficient hair styling effect cannot be obtained.
- composition of the present disclosure may further contain a powder.
- the hair styling power can be increased by adding powder.
- the powder examples include inorganic powders (for example, talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, safmica, biotite, lithia mica, calcined mica, calcined talc, permiculite.
- inorganic powders for example, talc, kaolin, mica, sericite (sericite), muscovite, phlogopite, synthetic mica, safmica, biotite, lithia mica, calcined mica, calcined talc, permiculite.
- the content of the powder is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and further preferably 0.5% by mass or more with respect to the mass of the composition.
- the hair styling effect can be improved by adding 0.1% by mass or more of the powder.
- the content of the powder is preferably 10% by mass or less and more preferably 8% by mass or less with respect to the mass of the composition. If the powder is added in an amount exceeding 10% by mass, stickiness is caused.
- the composition of the present disclosure may further contain a hair styling resin.
- the hair styling resin is a polymer that enhances the hair styling power when the composition of the present disclosure is used as a hair styling agent.
- the hair styling resin can be a polymer having film-forming properties.
- an ionic polymer and / or a nonionic polymer can be used.
- the ionic polymer can be at least one of an anionic polymer, a cationic polymer, and an amphoteric polymer. Although it does not limit as hairdressing resin, the following polymers can be illustrated.
- Betaine anionic polymers such as methacryloyloxyethylcarboxybetaine / alkyl methacrylate copolymer (Yukaformer (registered trademark) 301 of Mitsubishi Chemical Corporation), (2) Vinylpyrrolidone-based polymer compounds such as polyvinylpyrrolidone and polyvinylpyrrolidone-vinyl acetate copolymer (such as Rubiscol K-90 and VA73 from BASF), (3) Vinyl alcohol polymer compounds such as polyvinyl alcohol and polyvinyl butyral (Gosenol (registered trademark) of Nippon Synthetic Chemical Company, Denkapoval (registered trademark) of Denki Kagaku Kogyo Co., Ltd.), (4) Acid vinyl ether polymer compounds such as vinyl methyl ether / butyl maleate (Agro BEM-42S from Osaka Organic Chemical Co., Gantrez ES-225 from ISP, etc.) (5) Acrylic polymer such as acrylic acid alkyl ester /
- Amphoteric acrylic polymer compounds (Yukaformer (registered trademark) AM-75 of Mitsubishi Chemical Corporation, Anformer 28-4910 of NSC of Japan, etc.), (7) Hydroxyethylcellulose dimethyldiallylammonium chloride copolymer, hydroxyethylcellulose hydroxypropyltrimethylammonium chloride, vinylpyrrolidone / N, N'-dimethylaminoethylmethacrylic acid copolymer diethyl sulfate solution, homopolymer of dimethyldiallylammonium chloride, Nitrogen-containing cationic high molecular compounds such as dimethyldiallylammonium chloride / acrylamide copolymer (Amercor polymer JR-125, Lion's Leoguard (registered trademark) GP, Japan NSC's Cellcoat L-200, ISP's Guff Coat 734, HC Polymer 1N from Osaka Organic Chemical Co., Ltd., Marcote 550 from Nal
- the content of the hairdressing resin is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and further preferably 0.5% by mass or more with respect to the mass of the composition. If it is less than 0.1% by mass, sufficient hair styling power cannot be obtained. Further, the content of the hairdressing resin is preferably 8% by mass or less, more preferably 5% by mass or less, and further preferably 3% by mass or less with respect to the mass of the composition. If the hair-styling resin is added in excess of 8% by mass, stickiness is caused.
- anionic polymers and amphoteric polymers are insoluble in water as they are, and if necessary, some or all of the functional groups are neutralized with an inorganic or organic alkaline agent to change to water solubility. You may let them.
- the alkali agent used for the purpose of neutralization includes alkali metal hydroxides such as sodium hydroxide and potassium hydroxide as inorganic alkali agents.
- volatile alkaline agents such as ammonia and morpholine, triethanolamine, diethanolamine, isopropanolamine, monoethanolamine, diisopropanolamine, 2-amino-2-methyl-1-propanol, 2-amino-2-methyl-1, Examples include alkanolamines such as 3-propanediol, and amino acids such as L-arginine and lysine.
- composition of the present disclosure has other components such as an aqueous solvent, an oily component, an anionic surfactant, a cationic surfactant, an amphoteric surfactant, a nonionic surfactant, as long as the effects of the present disclosure are not impaired.
- Powders, water-soluble polymers, film agents, UV absorbers, sequestering agents, amino acids, organic amines, polymer emulsions, pH adjusters, skin nutrients, vitamins, antioxidants, antioxidant aids, fragrances, etc. Can be appropriately contained as required.
- aqueous solvent examples include water, alcohol, and a mixture thereof.
- water used for cosmetics, quasi-drugs and the like can be used.
- purified water, ion-exchanged water, tap water and the like can be used.
- the aqueous phase can further contain a water-soluble alcohol depending on the purpose.
- water-soluble alcohols include lower alcohols, polyhydric alcohols, polyhydric alcohol polymers, divalent alcohol alkyl ethers, dihydric alcohol alkyl ethers, dihydric alcohol ether esters, glycerin monoalkyl ethers, sugar alcohols, Examples thereof include at least one selected from monosaccharides, oligosaccharides, polysaccharides and derivatives thereof.
- lower alcohols examples include ethanol, propanol, isopropanol, isobutyl alcohol, t-butyl alcohol and the like.
- polyhydric alcohol examples include divalent alcohols (for example, ethylene glycol, propylene glycol, trimethylene glycol, 1,2-butylene glycol, 1,3-butylene glycol, tetramethylene glycol, 2,3-butylene glycol, Pentamethylene glycol, 2-butene-1,4-diol, hexylene glycol, octylene glycol, etc.); trivalent alcohol (eg, glycerin, trimethylolpropane, etc.); tetravalent alcohol (eg, 1, 2, 6) Pentaerythritol, such as hexanetriol, etc .; pentavalent alcohol (eg, xylitol, etc.); hexavalent alcohol (eg, sorbitol, mannitol, etc.); polyhydric alcohol polymer (eg, diethylene glycol, dipropylene glycol, Ethylene glycol, polypropylene glycol, tetraethylene glycol,
- monosaccharides include tricarbon sugars (for example, D-glyceryl aldehyde, dihydroxyacetone, etc.), tetracarbon sugars (for example, D-erythrose, D-erythrose, D-threoose, erythritol, etc.), Pentose sugars (for example, L-arabinose, D-xylos, L-lyxose, D-arabinose, D-ribose, D-ribose, D-xylulose, L- Xylose, etc.), hexose (eg D-glucose, D-talose, D-bucikose, D-galactose, D-fructose, L-galactose, L- Mannose, D-tagatose, etc.), heptose sugar (eg, aldoheptose, heproose, etc.), octose sugar (eg
- oligosaccharide for example, at least one selected from sucrose, gnocyanose, umbelliferose, lactose, planteose, isoliquinoses, ⁇ , ⁇ -trehalose, raffinose, lycnose, umbilicin, stachyose berbasose, etc. Can be mentioned.
- polysaccharide examples include cellulose, quince seed, chondroitin sulfate, starch, galactan, dermatan sulfate, glycogen, gum arabic, heparan sulfate, hyaluronic acid, tragacanth gum, keratan sulfate, chondroitin, xanthan gum, mucoitin sulfate, guar gum, dextran, kerato sulfate. And at least one selected from locust bean gum, succinoglucan, and caronic acid.
- Examples of other polyols include at least one selected from polyoxyethylene methyl glucoside (Glucam E-10), polyoxypropylene methyl glucoside (Glucam P-10) and the like.
- Examples of the cationic surfactant include alkyltrimethylammonium salts (eg, stearyltrimethylammonium chloride, lauryltrimethylammonium chloride, etc.); alkylpyridinium salts (eg, cetylpyridinium chloride, etc.); distearyldimethylammonium dialkyldimethylammonium chloride; Poly (N, N′-dimethyl-3,5-methylenepiperidinium chloride); alkyl quaternary ammonium salt; alkyldimethylbenzylammonium salt; alkylisoquinolinium salt; dialkyl morpholinium salt; POE-alkylamine; Examples include alkylamine salts; polyamine fatty acid derivatives; amyl alcohol fatty acid derivatives; benzalkonium chloride; benzethonium chloride and the like.
- alkyltrimethylammonium salts eg, stearyltrimethylammonium chloride, lauryltrimethyl
- amphoteric surfactants examples include imidazoline-based amphoteric surfactants (eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide). Side-1-carboxyethyloxy disodium salt, etc.); betaine surfactants (for example, 2-heptadecyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine, lauryldimethylaminoacetic acid betaine, alkylbetaine, amide betaine) , Sulfobetaine, etc.).
- imidazoline-based amphoteric surfactants eg, 2-undecyl-N, N, N- (hydroxyethylcarboxymethyl) -2-imidazoline sodium, 2-cocoyl-2-imidazolinium hydroxide).
- lipophilic nonionic surfactant examples include sorbitan fatty acid esters (for example, sorbitan monooleate, sorbitan monoisostearate, sorbitan monolaurate, sorbitan monopalmitate, sorbitan monostearate, sorbitan sesquioleate, sorbitan Trioleate, penta-2-ethylhexyl diglycerol sorbitan, tetra-2-ethylhexyl diglycerol sorbitan, etc.); glycerin polyglycerin fatty acid (eg mono cottonseed oil fatty acid glycerin, monoerucic acid glycerin, sesquioleate glycerin, glyceryl monostearate) , ⁇ , ⁇ '-oleic acid pyroglutamate glycerin, monostearate glycerin malate, etc.); propylene glycol fatty acid esters (eg mono
- hydrophilic nonionic surfactants include POE-sorbitan fatty acid esters (eg, POE-sorbitan monooleate, POE-sorbitan monostearate, POE-sorbitan monooleate, POE-sorbitan tetraoleate, etc.); POE-sorbite fatty acid ester (eg POE-sorbite monolaurate, POE-sorbite monooleate, POE-sorbite pentaoleate, POE-sorbite monostearate, etc.); POE-glycerin fatty acid ester (eg POE-glycerin monoester) POE-monooleate such as stearate, POE-glycerin monoisostearate, POE-glycerin triisostearate, etc .; POE-fatty acid esters (eg POE-distearate, POE) Monodiolates, ethylene glycol distearate, etc.); POE-alkyl
- humectant examples include polyethylene glycol, propylene glycol, glycerin, 1,3-butylene glycol, xylitol, sorbitol, maltitol, chondroitin sulfate, hyaluronic acid, mucoitin sulfate, caronic acid, atelocollagen, cholesteryl-12-hydroxystearate Sodium lactate, bile salt, dl-pyrrolidone carboxylate, alkylene oxide derivative, short-chain soluble collagen, diglycerin (EO) PO adduct, Izayoi rose extract, yarrow extract, merirot extract and the like.
- EO diglycerin
- natural water-soluble polymers include plant-based polymers (for example, gum arabic, tragacanth gum, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid); microbial polymers (eg, xanthan gum, dextran, succinoglucan, bullulan, etc.); animal polymers (eg, collagen, casein, albumin, gelatin, etc.), etc. Is mentioned.
- plant-based polymers for example, gum arabic, tragacanth gum, galactan, guar gum, carob gum, caraya gum, carrageenan, pectin, agar, quince seed (malmello), alge colloid (guckweed extract), starch (Rice, corn, potato, wheat), glycyrrhizic acid);
- Semi-synthetic water-soluble polymers include, for example, starch polymers (eg, carboxymethyl starch, methylhydroxypropyl starch, etc.); cellulose polymers (methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate) Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like); alginic acid polymers (for example, sodium alginate, propylene glycol alginate, etc.) and the like.
- starch polymers eg, carboxymethyl starch, methylhydroxypropyl starch, etc.
- cellulose polymers methylcellulose, ethylcellulose, methylhydroxypropylcellulose, hydroxyethylcellulose, sodium cellulose sulfate Hydroxypropylcellulose, carboxymethylcellulose, sodium carboxymethylcellulose, crystalline cellulose, cellulose powder and the like
- alginic acid polymers for example, sodium
- Synthetic water-soluble polymers include, for example, vinyl polymers (eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer); polyoxyethylene polymers (eg, polyethylene glycol 20,000, 40). , 000, 60,0000 polyoxyethylene polyoxypropylene copolymer, etc.); acrylic polymers (for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.); polyethyleneimine; cationic polymers and the like.
- vinyl polymers eg, polyvinyl alcohol, polyvinyl methyl ether, polyvinyl pyrrolidone, carboxyvinyl polymer
- polyoxyethylene polymers eg, polyethylene glycol 20,000, 40. , 000, 60,0000 polyoxyethylene polyoxypropylene copolymer, etc.
- acrylic polymers for example, sodium polyacrylate, polyethyl acrylate, polyacrylamide, etc.
- polyethyleneimine
- the coating agent examples include an anionic coating agent (for example, (meth) acrylic acid / (meth) acrylic acid ester copolymer, methyl vinyl ether / maleic anhydride polymer), and a cationic coating agent (for example, cation Cellulose, dimethyldiallylammonium chloride polymer, dimethyldiallylammonium chloride / acrylamide copolymer, etc.), nonionic coating agent (eg, polyvinyl alcohol, polyvinylpyrrolidone, polyvinyl acetate, polyacrylate copolymer, (meth) Acrylamide, polymer silicone, silicone resin, trimethylsiloxysilicate, etc.).
- an anionic coating agent for example, (meth) acrylic acid / (meth) acrylic acid ester copolymer, methyl vinyl ether / maleic anhydride polymer
- a cationic coating agent for example, cation Cellulose, dimethyldiallylammonium chloride polymer, dimethyldially
- ultraviolet absorber examples include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester.
- PABA paraaminobenzoic acid
- PABA monoglycerin ester N, N-dipropoxy PABA ethyl ester
- N, N-diethoxy PABA ethyl ester examples include benzoic acid-based ultraviolet absorbers (for example, paraaminobenzoic acid (hereinafter abbreviated as PABA), PABA monoglycerin ester, N, N-dipropoxy PABA ethyl ester, N, N-diethoxy PABA ethyl ester.
- PABA paraaminobenzoic acid
- sequestering agent examples include 1-hydroxyethane-1,1-diphosphonic acid, 1-hydroxyethane-1,1-diphosphonic acid tetrasodium salt, disodium edetate, trisodium edetate, and tetrasodium edetate.
- amino acids examples include neutral amino acids (eg, threonine, cysteine, etc.); basic amino acids (eg, hydroxylysine, etc.), and the like.
- amino acid derivatives include acyl sarcosine sodium (lauroyl sarcosine sodium), acyl glutamate, acyl ⁇ -alanine sodium, glutathione, and pyrrolidone carboxylic acid.
- organic amines examples include monoethanolamine, diethanolamine, triethanolamine, morpholine, triisopropanolamine, 2-amino-2-methyl-1,3-propanediol, and 2-amino-2-methyl-1-propanol. Is mentioned.
- polymer emulsion examples include acrylic resin emulsion, polyethyl acrylate emulsion, acrylic resin liquid, polyacryl alkyl ester emulsion, polyvinyl acetate resin emulsion, natural rubber latex, and the like.
- pH adjuster examples include buffers such as lactic acid-sodium lactate, citric acid-sodium citrate, and succinic acid-sodium succinate.
- vitamins examples include vitamins A, B1, B2, B6, C, E and derivatives thereof, pantothenic acid and derivatives thereof, and biotin.
- antioxidants examples include tocopherols, dibutylhydroxytoluene, butylhydroxyanisole, gallic acid esters and the like.
- antioxidant assistant examples include phosphoric acid, citric acid, ascorbic acid, maleic acid, malonic acid, succinic acid, fumaric acid, kephalin, hexametaphosphate, phytic acid, ethylenediaminetetraacetic acid and the like.
- ingredients that can be blended include, for example, preservatives (ethyl paraben, butyl paraben, chlorphenesin, phenoxyethanol, etc.); anti-inflammatory agents (eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.
- preservatives ethyl paraben, butyl paraben, chlorphenesin, phenoxyethanol, etc.
- anti-inflammatory agents eg, glycyrrhizic acid derivatives, glycyrrhetinic acid derivatives, salicylic acid derivatives, hinokitiol, zinc oxide, allantoin, etc.
- Whitening agent eg, placenta extract, saxifrage extract, arbutin, etc.
- various extracts eg, buckwheat, auren, shikon, peonies, assembly, birch, sage, loquat, carrot, aloe, mallow, iris, grape , Yokuinin, Loofah, Lily, Saffron, Senkyu, Pepper, Hypericum, Onionis, Garlic, Pepper, Chimpi, Toki, Seaweed, etc.
- Activator eg, Royal Jelly, Photosensitive Element, Cholesterol Derivative, etc.
- composition of the present disclosure includes caffeine, tannin, verapamil, tranexamic acid and derivatives thereof, various herbal extracts such as licorice, karin, and yew, etc., tocopherol acetate, glycyrrhizic acid, glycyrrhizic acid and derivatives or salts thereof, etc.
- Drugs, vitamin C, magnesium ascorbate phosphate, glucoside ascorbate, whitening agents such as arbutin and kojic acid, amino acids such as arginine and lysine, and derivatives thereof can also be contained as appropriate.
- the viscosity of the composition of the present disclosure is preferably 10,000 mPa ⁇ s or more. If it is less than 10,000 mPa ⁇ s, there is a concern of falling off from the container. Moreover, in the product described later, the compositions having different compositions are easily mixed in the container.
- the viscosity of the composition of the present disclosure is preferably 200,000 mPa ⁇ s or less. When it exceeds 200,000 mPa ⁇ s, the elongation becomes worse and the user feels stickiness.
- the viscosity can be measured with a Brookfield viscometer (spindle number 7, rotation speed 10 rpm) at 30 ° C.
- composition of the present disclosure stickiness felt by the user when the composition of the present disclosure is applied can be suppressed.
- the composition of the present disclosure also has emulsion stability. Furthermore, the composition of the present disclosure can easily wash the composition remaining in the hand after use with water.
- ⁇ / RTI> When the composition of the present disclosure is applied to a hair styling product, the time during which the hairstyle can be adjusted can be maintained for a long time even after application to the hair. Thereby, hairdressing can be performed easily. Nevertheless, the hair styling has a strong hair styling power. Furthermore, even after solidifying on the hair, the hair styling material can be easily washed with a shampoo.
- the cosmetic composition according to the second embodiment can be a hairdressing composition, for example.
- Cosmetics that are used by mixing two agents when used are known (for example, see Japanese Patent Application Laid-Open Nos. 11-279031 and 2011-73991). When such two agents are filled in separate containers, the manufacturing cost is high. Moreover, a user will have a trouble at the time of use in a separate container. Therefore, there is a demand for a cosmetic that can fill two containers to be mixed in one container.
- the cosmetic composition according to the second embodiment has a first composition containing a first component and a second composition containing a second component.
- a mixture obtained by kneading the first composition and the second composition can be used as a cosmetic, for example, a hair styling agent.
- the mixture of the first composition and the second composition has a higher hairstyle keeping power than the first composition alone and the second composition alone.
- the first component and the second component can have increased adhesion or increased viscosity when mixed.
- the first component and the second component are a mixture of the first composition and the second composition mixed and applied to the hair when the cosmetic composition is applied to a hairdressing composition.
- the combination is preferably such that when the hair is solidified or dried, the keeping power of the hairstyle can be increased.
- first component and the second component are bonded and / or associated when mixed with the first composition and the second composition.
- first component and the second component should be associated with each other by ionic bonds and / or interactions due to opposite charges, interactions between hydrophilic portions, interactions between hydrophobic portions, and the like. Can do.
- the above-described hair styling resin can also be used.
- the first component and the second component can be ionic polymers.
- the first component can be an amphoteric polymer and / or an anionic polymer
- the second component can be an amphoteric polymer and / or a cationic polymer.
- the anionic polymer for example, an anionic urethane polymer can be used.
- the amphoteric polymer for example, an amphoteric acrylic polymer can be used.
- anionic polymer examples include (acrylates / alkyl acrylate (C1-18) / alkyl (C1-8) acrylamide) copolymer AMP (plus size (registered trademark) L9909B Kyoyo Chemical Industry Co., Ltd.), (octyl acrylamide / acrylic acid). Hydroxypropyl / butylaminoethyl methacrylate) copolymer (AMPHOMER (registered trademark) LV-71 Akzo Nobel) can be used.
- polyquaternium-11 (PDM polymer, Osaka Organic Chemical Co., Ltd.), polyurethane-10 (Yodosol Akzo Nobel), etc. can be used.
- amphoteric polymer a (methacryloyloxyethylcarboxybetaine / alkyl methacrylate) copolymer (SM polymer, Mitsubishi Chemical Corporation) or the like can be used.
- SM polymer methacryloyloxyethylcarboxybetaine / alkyl methacrylate copolymer
- the mixture of the first composition and the second composition preferably contains the composition according to the first embodiment. That is, it is preferable that the first composition and the second composition contain at least one of an associative thickener, an anionic surfactant, and a higher alcohol.
- the first composition and the second composition may each include an associative thickener, an anionic surfactant, and a higher alcohol.
- the first composition and / or the second composition can include an oily component and / or a powder. About the composition which concerns on 1st Embodiment, the above-mentioned description is used.
- the viscosity of the first composition and the second composition is preferably 30,000 mPa ⁇ s or more, and more preferably 50,000 mPa ⁇ s or more.
- the viscosities of the first composition and the second composition are preferably 150,000 mPa ⁇ s or less and more preferably 100,000 mPa ⁇ s or less so that the user can easily knead.
- the first composition and the second composition have different colors so that the user can recognize the kneaded state of the first composition and the second composition.
- At least one of the first composition and the second composition can contain a colorant (pigment).
- the cosmetic composition of the present disclosure may be used by kneading three or more compositions.
- the user kneads the first composition and the second composition by a predetermined amount by hand.
- the kneading is preferably performed immediately before use.
- the user can then apply the kneaded mixture to the hair to set the desired hairstyle.
- a desired hairstyle can be set on the hair or after kneading the first composition and the second composition together with the hair or while kneading.
- the first composition and the second composition can be filled in one container. Thereby, the increase in manufacturing cost can be suppressed. In addition, user convenience can be achieved.
- the hairdressing material can have a higher hairstyle keeping power.
- the product according to the third embodiment includes a container and at least two compositions existing in the container as contents.
- the same elements are denoted by the same reference numerals.
- FIG. 1 is a top view of the container. 2 and 3 are side views of the container. 1 to 3 show a state where the composition is not present in the container.
- the container 1 has at least one opening 1a.
- the container 1 preferably has a longitudinal direction.
- the opening 1a is preferably arranged at one end in the longitudinal direction or the lateral direction.
- a longitudinal axis X shown in FIG. 1 is an axis along the longitudinal direction of the container 1.
- the opening 1a is arranged at one end in the longitudinal direction.
- the opening 1a is preferably arranged at the center in the lateral direction (left-right direction) in the side view.
- the opening 1a is preferably arranged at the center in the vertical direction (vertical direction) in the side view.
- the container 1 is preferably flexible. It is preferable that the container 1 can easily reduce the volume (volume) of the container 1 by hand so that the contents can be pushed out from the opening 1a.
- the container 1 preferably has a cross-sectional area (volume portion) perpendicular to the longitudinal axis X that tends to shrink toward the other end of the longitudinal direction opposite to the opening 1a. This is because it is easy for the user to push out the contents from the other end toward one end (opening 1a).
- the container 1 can have a cap (not shown) that allows the opening 1a to be opened and closed in order to prevent leakage of the contents.
- the cap may be removable.
- the container 1 does not have a partition or a partition for separating the contents inside.
- the inner wall of the container 1 preferably does not react with the contents.
- the shape of the space for storing contents in the container 1 is not particularly limited.
- the dimension of the container 1 is not specifically limited.
- the shape and size of the opening 1a are not particularly limited.
- the container 1 can take the form generally called a tube, for example.
- FIGS. 4 to 6 are schematic views showing a state in which the container is filled with the composition. 4 to 6, the container is assumed to be transparent. Alternatively, FIGS. 4 to 6 may be viewed as perspective views. 4 to 6 correspond to FIGS. 1 to 3, respectively.
- FIG. 7 is a schematic cross-sectional view taken along the line VII-VII of FIG. 7 to 11 show a circular cross section, the cross section of the container 1 and the contents is not limited to a circular shape, and may be, for example, an elliptical shape, a polygonal shape such as a quadrangle, an indefinite shape, or the like. Also good.
- the product 10 has a first composition 2 a and a second composition 2 b as the contents of the container 1.
- the first composition 2a and the second composition 2b are preferably arranged in parallel along the longitudinal axis X. It is preferable that the first composition 2a and the second composition 2b are arranged in the container 1 without using a partition or a partition wall. It is preferable that at least a part of the first composition 2a and the second composition 2b are in direct contact with each other.
- the interface 3 between the first composition 2a and the second composition 2b it is preferable that mixing of the first composition 2a and the second composition 2b is suppressed.
- the interface 3 preferably extends along the longitudinal axis X.
- the first composition 2a and the second composition 2b are arranged so that they can be discharged simultaneously from the opening 1a.
- the opening 1a and a part of the interface 3 overlap each other.
- one volume is preferably within ⁇ 20% of the other volume, more preferably within ⁇ 10%, and even more preferably substantially the same volume.
- the first composition 2a and the second composition 2b are arranged in the same volume in the container 1, and the total volume of the first composition 2a and the second composition 2b is 80% or more of the volume of the container 1, preferably 90% or more of the first composition 2a and the second composition 2b exiting from the opening 1a when the first composition 2a and the second composition 2b are extruded from the container 1 in the occupied state.
- one volume is preferably within ⁇ 20% of the other volume, more preferably within ⁇ 10%, and even more preferably substantially the same volume.
- the first composition 2a and the second composition 2b are alternately arranged.
- the cross section of the 1st composition 2a and the 2nd composition 2b can have a fan shape, for example.
- the first composition 2a and the second composition 2b can be arranged radially.
- the inside of the container 1 is divided into four sections in a fan shape by the first composition 2a and the second composition 2b, preferably divided into four equal parts, and the first composition 2a and the first composition 2a.
- the two compositions 2b are arranged in opposing sections. The area of each section in the cross section as shown in FIG.
- the shape formed by the first composition 2a and the second composition 2b can be line symmetric and / or point symmetric.
- FIG. 8 shows a schematic cross-sectional view of a different form from FIG. In the product 11 shown in FIG. 8, the first composition 2 a and the second composition 2 b extend in parallel along the longitudinal axis X without being divided. That is, in the cross section as shown in FIG. 8, the inside of the container 1 is divided into two sections by the first composition 2a and the second composition, and preferably is divided into two equal parts.
- the other forms of the form shown in FIG. 8 can be the same as the forms shown in FIGS.
- FIG. 9 shows a schematic cross-sectional view of a form different from those shown in FIGS.
- the first composition 2a and the second composition 2b are arranged in a fan shape or a radial shape in a cross section as shown in FIGS.
- the first composition 2a and the second composition 2b are arranged concentrically. That is, the first composition 2 a is arranged in a cylindrical shape along the longitudinal axis X in the container 1.
- the second composition 2b is arranged in a cylindrical shape around the first composition 2a (along the outer periphery of the first composition 2a) along the longitudinal axis X in the container 1.
- the other forms of the form shown in FIG. 9 can be the same as the forms shown in FIGS.
- FIGS. 4 to 9 a product having two compositions is shown, but the product may have three or more compositions.
- 10 and 11 show schematic cross-sectional views of a product having three compositions.
- the products 13 and 14 shown in FIGS. 10 and 11 have a third composition 2c in addition to the first composition 2a and the second composition 2b.
- the compositions 2a to 2c are arranged in a fan shape or a radial shape in the same manner as shown in FIGS.
- the compositions 2a to 2c are arranged concentrically in the same manner as in the form shown in FIG.
- Other forms than the forms shown in FIGS. 10 and 11 can be the same as the forms shown in FIGS. Even if there are four or more types of compositions, they can be similarly arranged.
- the space in the flexible container 1 can be reduced, and a plurality of compositions can be simultaneously extruded from the openings.
- the user can easily take a plurality of compositions.
- the increase in product cost can be suppressed.
- the contents of the container 1 can be the composition according to the first embodiment and / or the cosmetic composition according to the second embodiment.
- the first composition 2a and the second composition 2b in the third embodiment can be the first composition and the second composition in the second embodiment.
- the above description is used for the composition according to the first embodiment and the cosmetic composition according to the second embodiment.
- the user can change the volume of the container 1 by deforming the container 1 or press the container 1 from the outside to move the contents in the direction of the opening 1a, thereby moving the first through the opening 1a of the container 1.
- the 2nd composition 2a and the 2nd composition 2b are taken out. At this time, the 1st composition 2a and the 2nd composition 2b can be taken out in a desired ratio.
- the subsequent steps can be the same as the method for using the cosmetic composition according to the second embodiment.
- the cosmetic composition according to the second embodiment can be used with a simple configuration. That is, the same effect as that of the second embodiment can be obtained with a simple configuration. Moreover, since the 1st composition and the 2nd composition are filled into one simple container, while being able to suppress the rise in manufacturing cost, a user's convenience can be aimed at.
- composition of this indication can be manufactured by mixing each component by a usual method.
- compositions and products of the present disclosure will be described in detail using examples.
- the compositions and products of the present disclosure are not limited to the following examples.
- composition of the present disclosure will be described below with examples. However, the composition of the present disclosure is not limited to the following examples. Moreover, although the following example demonstrates the example which applied the composition of each test example to the hairdressing composition, the composition of this indication is not limited to a hairdressing composition.
- the unit of the content rate shown in each table is mass%.
- Test Examples 1 and 2 The compositions according to Test Examples 1 and 2 are shown in Table 1.
- Table 1 For the compositions according to Test Examples 1 and 2 and Test Example 14 described later, the change in stickiness was measured by a rolling friction test. The sample of each test example is placed on a horizontal movable plate, and the plate is intermittently reciprocated so that the sample and the probe rub against each other. At this time, by measuring the rolling force acting on the probe, the change in the frictional force applied between the sample and the probe was measured as the change in stickiness.
- FIG. 12 shows the measurement results of the rolling friction test of the compositions according to Test Examples 1, 2, and 14. The compositions according to Test Examples 1, 2, and 14 contain a higher alcohol.
- composition according to Test Example 1 contains an anionic surfactant and an associative thickener.
- composition according to Test Example 2 contains an anionic surfactant but does not contain an associative thickener.
- composition according to Test Example 14 contains an associative thickener, but contains a nonionic surfactant instead of the anionic surfactant.
- the composition according to Test Example 2 has a very high degree of stickiness immediately after the start of the test as compared with the compositions according to Test Examples 1 and 14. This is considered to be because in Test Examples 1 and 14, the elongation, that is, the slip of the composition was improved by the presence of the associative thickener. From this, it is considered that the stickiness of the composition can be reduced by adding an associative thickener.
- the composition according to Test Example 2 has a drastic reduction in stickiness. This means that the sample has dried and solidified.
- the composition according to Test Example 2 when used as a hair styling material, it means that hair styling becomes difficult as soon as the user starts hair styling.
- a sharp decrease in stickiness as in Test Example 2 was not measured. This is considered because the associative thickener suppressed the solidification of the composition.
- Comparison of Test Example 1 and Test Example 14 shows that the composition according to Test Example 14 increases in stickiness after the start of the test and then decreases to form a peak of stickiness. This means that, for example, when the composition according to Test Example 14 is used as a hairdressing material, the user feels sticky during use of the hairdressing material, and then the hairstyling power decreases. On the other hand, in the composition according to Test Example 1, the stickiness degree is almost constant. This means that, for example, when the composition according to Test Example 1 is used as a hairdressing material, the user hardly feels stickiness and the hairstyling power is maintained constant.
- compositions according to Test Examples 1, 2, and 14 are used for hair styling
- the user is strongly sticky when taking the hair styling in hand and applying it to the hair. You have to feel and make a haircut quickly and quickly.
- the composition according to Test Example 14 has a sticky feeling and a reduction in hair styling power.
- an appropriate degree of stickiness is kept constant for a long time immediately after the start of use. In other words, the user is less likely to feel stickiness even during hair styling, and it is possible to set the hairstyle over time.
- composition according to Test Example 13 containing no surfactant and associative thickener did not become a stable oil-in-water emulsion. Therefore, compared with other test examples, at least a surfactant is required for emulsion stability.
- Test Examples 8 to 12 a thickener having another thickening mechanism was used instead of a thickener having an associative thickening mechanism.
- the component (11) of Test Example 8, the component (12) of Test Example 9, and the component (14) of Test Example 11 are considered to have a thickening action due to entanglement.
- the component (13) of Test Example 10 is considered to have a thickening action due to electrostatic repulsion.
- the component (15) of Test Example 12 is considered to have a thickening action due to the card house structure.
- the user did not feel stickiness and could not obtain easy hair styling. Further, the cleaning properties of Test Examples 3 to 7 were higher than those of Test Examples 8 to 12. Therefore, comparing Test Examples 3 to 7 and Test Examples 8 to 12, by using an associative thickener, stickiness can be suppressed, hair styling ease can be improved, and cleanability can be improved. it is conceivable that.
- test Example 5 an associative thickener different from the associative thickener used in Test Examples 3, 4, 6 and 7 was used. However, in Test Examples 3 to 7, equivalent test results could be obtained. Accordingly, associative thickeners are considered useful for the compositions of the present disclosure.
- Test Examples 3 to 7 containing associative thickeners in an amount of 0.2 to 2% by mass, good results were obtained for all items. However, in Test Example 15 in which 4% by mass of the associative thickener was added, the viscosity was too high, so that the suitability to hair decreased and the stickiness increased. In addition, the hair styling ability and cleanability were generally lower than those of Test Examples 3 to 7. From this, it is considered that the content of the associative thickener is preferably 0.1% by mass or more, and more preferably 0.2% by mass or more. Further, the content of the associative thickener is preferably 3.5% by mass or less, more preferably 3% by mass or less, and further preferably 2% by mass or less.
- the content of the anionic surfactant is preferably 0.2% by mass or more, and more preferably 0.3% by mass or more.
- the content of the anionic surfactant is preferably 4% by mass or less, and more preferably 3% by mass or less.
- Test Examples 3 to 7 containing 1.3% by mass to 5% by mass of higher alcohol good results were obtained for all items. However, in Test Example 16 containing no higher alcohol, the user felt strongly sticky. This is thought to be due to the absence of ⁇ -gel formation. In addition, hair styling ease and hair styling power have been reduced. In Test Examples 3 to 6 containing 1.3% by mass and 2.5% by mass of higher alcohol, the stickiness decreased, and the ease of styling and styling power were improved. Accordingly, the content of the higher alcohol is preferably 0.2% by mass or more, more preferably 1% by mass or more, and more preferably 2% by mass or more. Further, in Test Example 17 containing 10% by mass of higher alcohol, the hair styling ease was low and the cleanability was poor.
- Test Example 7 containing 5% by mass of higher alcohol, both hair styling ease and cleanability were improved. Accordingly, the content of higher alcohol is preferably 8% by mass or less, more preferably 6% by mass or less, and further preferably 4% by mass or less.
- Test Examples 3 to 7 containing 26 mass% to 50 mass% of the oil component (including higher alcohol) good results were obtained for all items.
- Test Example 18 containing 57.5% by mass of an oil component the stickiness increased and the hair styling ease also decreased. Furthermore, the detergency decreased. From this, it is considered that the content of the oil component is preferably 55% by mass or less, and more preferably 50% by mass or less. Further, the content of the oil component is preferably 20% by mass or more, and more preferably 25% by mass or more.
- the hair styling power could be increased as compared with Test Example 3.
- the content of the powder is preferably 0.1% by mass or more, more preferably 0.3% by mass or more, and further preferably 0.5% by mass or more. Further, the content of the powder is preferably at least 10% by mass or less, and more preferably 8% by mass or less.
- Test Example 5 the hair styling power could be increased as compared with Test Example 3 by adding the component (15) which is a hair styling resin. From this, it was found that the addition of a hair styling resin is also effective in increasing the hair styling power.
- a product was produced by injecting the cosmetic composition according to the second embodiment of the present disclosure into a container.
- Two types of compositions a first composition and a second composition, were injected into a flexible container (tube) as shown in FIGS.
- the two compositions were injected into the container so as to extend along the longitudinal axis direction so that the two kinds of compositions could be led out simultaneously from the opening.
- the two types of compositions were alternately arranged in four fan-shaped sections in a cross section perpendicular to the longitudinal axis direction.
- Table 5 shows the compositions of the two types of compositions.
- a coloring material was added to at least one of the compositions so that the colors of the first composition and the second composition were different.
- test Example 19 the amphoteric polymer was added to the first composition, and the amphoteric polymer was added to the second composition.
- test Example 20 an amphoteric polymer was added to the first composition, and an anionic polymer was added to the second composition.
- test Example 21 an amphoteric polymer was added to the first composition, and a cationic polymer was added to the second composition.
- the viscosities of the first composition and the second composition were about 100,000 mPa ⁇ s, respectively.
- [Appearance stability and hair mixing resin mixing effect] The appearance stability in the container and the interaction when the two compositions were mixed were determined according to the following evaluation criteria.
- [Appearance stability] The stability in the container in the state where the first composition and the second composition were in direct contact with each other was evaluated.
- C The boundary between the first composition and the second composition in the container was unclear.
- the first composition and the second composition were taken out of the container at the same time, and kneaded with a palm to prepare a mixture.
- the mixture was evaluated for non-stickiness, ease of hair styling, hair styling power, cleanability (hand) and cleanability (hair).
- the evaluation criteria are the same as in Test Examples 1-18.
- compositions, cosmetic composition and product of the present invention, and methods for using them have been described based on the above embodiments and examples, but the present invention is not limited to the above embodiments and examples.
- various disclosed elements including elements described in the claims, the description, and the drawings) can include various modifications, changes, and improvements. .
- various combinations, substitutions, or selections of the disclosed elements are possible within the scope of the claims of the present invention.
- [Appendix 4] The cosmetic composition according to the supplementary note, wherein the viscosity of the first composition and the second composition is 10,000 mPa ⁇ s to 200,000 mPa ⁇ s.
- the first component is the amphoteric polymer and / or anionic polymer
- the cosmetic composition according to appendix, wherein the second component is the amphoteric polymer and / or the cationic polymer.
- the anionic polymer is a urethane polymer.
- Appendix 11 The cosmetic composition according to the supplementary note, which is a hair styling agent.
- Appendix 12 A container, The cosmetic composition according to the supplementary note, disposed in the container, The product in which the first composition and the second composition are arranged in the container at least partially in contact with each other.
- [Appendix 14] The product according to the supplementary note, wherein the mixture has a higher keeping power than the first composition alone and the second composition alone.
- [Appendix 15] The product according to the supplementary note, wherein the first composition and the second composition are arranged in the container in parallel along a longitudinal direction of the container.
- [Appendix 16] The product according to the supplementary note, wherein an interface between the first composition and the second composition extends in a longitudinal direction of the container.
- the container has an opening; The product according to the supplementary note, wherein the opening overlaps a part of an interface between the first composition and the second composition on a projection surface facing the opening.
- composition of the present disclosure is shown below.
- the composition of the present disclosure is not limited to the following formulation examples. All the compounding ratio of a component means the mass%.
- composition of the present disclosure can be suitably used for cosmetics and skin external preparations directly used by hand.
- composition of the present disclosure can be suitably used in cosmetics and skin external preparations that are applied to or rubbed into the skin and hair.
- the cosmetic composition include foundations (for example, O / W gel foundation), balms (for example, highly perfumed balm and body balm), and the like.
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Abstract
Description
R1-{(O-R2)k-OCONH-R3[-NHCOO-(R4-O)n-R5]h}m (I)
[式(I)中、
R1、R2およびR4は、それぞれ独立に炭素原子数2~4の炭化水素基であり;
R3はウレタン結合を有していてもよい炭素原子数1~10の炭化水素基であり;
R5は炭素原子数8~36の炭化水素基であり;
mは2以上の数であり;
hは1以上の数であり;
kは1~500の数であり;
nは1~200の数である。]
会合性増粘剤は、通常、疎水部と親水部を有する。会合性増粘剤は、両端に疎水部を有すると好ましい。また、会合性増粘剤は、両端の疎水部の間に親水部を有すると好ましい。例えば、ある会合性増粘剤は、疎水部同士が会合することによってネットワーク(網目構造)を形成し、増粘作用を発現させると考えられている。
R1-{(O-R2)k-OCONH-R3[-NHCOO-(R4-O)n-R5]h}m (I)
R6-OH (II)
R7-CR8H-R9-OH (III)
R10-CR11H-OH (IV)
アニオン性界面活性剤としては、例えば、脂肪酸セッケン(例えば、ラウリン酸ナトリウム、パルミチン酸ナトリウム等);高級アルキル硫酸エステル塩(例えば、ラウリル硫酸ナトリウム、ラウリル硫酸カリウム等);アルキルエーテル硫酸エステル塩(例えば、POE-ラウリル硫酸トリエタノールアミン、POE-ラウリル硫酸ナトリウム等);N-アシルサルコシン酸(例えば、ラウロイルサルコシンナトリウム等);高級脂肪酸アミドスルホン酸塩(例えば、N‐ステアロイル‐N‐メチルタウリンナトリウム、N-ミリストイル-N-メチルタウリンナトリウム、ヤシ油脂肪酸メチルタウリッドナトリウム、ラウリルメチルタウリッドナトリウム等);リン酸エステル塩(POE-オレイルエーテルリン酸ナトリウム、POE-ステアリルエーテルリン酸等);スルホコハク酸塩(例えば、ジ-2-エチルヘキシルスルホコハク酸ナトリウム、モノラウロイルモノエタノールアミドポリオキシエチレンスルホコハク酸ナトリウム、ラウリルポリプロピレングリコールスルホコハク酸ナトリウム等);アルキルベンゼンスルホン酸塩(例えば、リニアドデシルベンゼンスルホン酸ナトリウム、リニアドデシルベンゼンスルホン酸トリエタノールアミン、リニアドデシルベンゼンスルホン酸等);高級脂肪酸エステル硫酸エステル塩(例えば、硬化ヤシ油脂肪酸グリセリン硫酸ナトリウム等);N-アシルグルタミン酸塩(例えば、N-ラウロイルグルタミン酸モノナトリウム、N-ステアロイルグルタミン酸ジナトリウム、N-ミリストイル-L-グルタミン酸モノナトリウム等);硫酸化油(例えば、ロート油等);POE-アルキルエーテルカルボン酸;POE-アルキルアリルエーテルカルボン酸塩;α-オレフィンスルホン酸塩;高級脂肪酸エステルスルホン酸塩;二級アルコール硫酸エステル塩;高級脂肪酸アルキロールアミド硫酸エステル塩;ラウロイルモノエタノールアミドコハク酸ナトリウム;N-パルミトイルアスパラギン酸ジトリエタノールアミン;カゼインナトリウム等を使用することができる。
高級アルコールとしては、例えば、直鎖アルコール(例えば、ラウリルアルコール、セチルアルコール、ステアリルアルコール、ベヘニルアルコール、ミリスチルアルコール、オレイルアルコール、セトステアリルアルコール等);分枝鎖アルコール(例えば、モノステアリルグリセリンエーテル(バチルアルコール)、2-デシルテトラデシノール、ラノリンアルコール、コレステロール、フィトステロール、ヘキシルドデカノール、イソステアリルアルコール、オクチルドデカノール等)等を使用することができる。
本開示の組成物は、高級アルコールとは別の油性成分をさらに含有することができる。
本開示の組成物は、粉体をさらに含有することができる。本開示の組成物を整髪料に用いる場合、粉体を添加することによって整髪力を高めることができる。
本開示の組成物は、整髪樹脂をさらに含有することができる。整髪樹脂は、本開示の組成物を整髪料として使用した場合に、整髪力をより高めるポリマーである。例えば、整髪樹脂は、成膜性を有するポリマーとすることができる。
(2)ポリビニルピロリドンや、ポリビニルピロリドン-酢酸ビニル共重合体等のビニルピロリドン系高分子化合物(BASF社のルビスコールK-90,VA73等)、
(3)ポリビニルアルコールや、ポリビニルブチラール等のビニルアルコール系高分子化合物(日本合成化学社のゴーセノール(登録商標)、電気化学工業社のデンカポバール(登録商標)等)、
(4)ビニルメチルエーテル/マレイン酸ブチル等の酸性ビニルエーテル系高分子化合物(大阪有機化学社のアニエールBEM-42S、ISP社のガントレッツES-225等)、
(5)アクリル酸アルキルエステル・メタクリル酸アルキルエステル・ジアセトンアクリルアミド・メタクリル酸共重合体、アクリル酸アルキル共重合体、アクリル酸・アクリル酸アミド・アクリル酸エチル共重合体等のアクリル酸系高分子化合物(BASF社のルビマー100P、ウルトラホールドストロング、三菱化学社のダイヤホールド(登録商標)HR-200、互応化学社のプラスサイズ(登録商標)L-53P等)、
(6)N-メタクリロイルオキシエチル-N,N-ジメチルアンモニウム-α-N-メチルカルボキシベタイン・メタクリル酸アルキル共重合体、アクリル酸オクチルアミド・アクリル酸ヒドロキシプロピル・メタクリル酸ブチルアミノエチル共重合体等の両性アクリル酸系高分子化合物(三菱化学社のユカフォーマー(登録商標)AM-75、日本NSC社のアンフォマー28-4910等)、
(7)ヒドロキシエチルセルロースジメチルジアリルアンモニウムクロリド共重合体、ヒドロキシエチルセルロースヒドロキシプロピルトリメチルアンモニウムクロリド、ビニルピロリドン・N,N'-ジメチルアミノエチルメタクリル酸共重合体ジエチル硫酸塩液、ジメチルジアリルアンモニウムクロリドのホモポリマー、ジメチルジアリルアンモニウムクロリド・アクリルアミド共重合体等の含窒素陽イオン性高分子化合物(アマコール社のポリマーJR-125、ライオン社のレオガード(登録商標)GP、日本NSC社のセルコートL-200、ISP社のガフコート734、大阪有機化学社のH.C.ポリマー1N、ナルコ社のマーコート550等)。
本開示の組成物は、本開示の効果を阻害しない範囲において、他の成分、例えば、水性溶媒、油性成分、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、非イオン界面活性剤、粉体、水溶性高分子、皮膜剤、紫外線吸収剤、金属イオン封鎖剤、アミノ酸、有機アミン、高分子エマルジョン、pH調整剤、皮膚栄養剤、ビタミン、酸化防止剤、酸化防止助剤、香料等を必要に応じて適宜含有することができる。
試験例1及び2に係る組成を表1に示す。試験例1及び2、並びに後述の試験例14に係る組成物について、転がり摩擦試験によってべたつき感の変化を測定した。各試験例の試料を水平可動プレート上に載せ、試料とプローブとが擦り合うようにプレートを断続的に往復運動させる。このとき、プローブに作用する転動力を測定することによって、試料とプローブ間に掛かる摩擦力の変化をべたつき度の変化として測定した。図12に、試験例1、2及び14に係る組成物の転がり摩擦試験の測定結果を示す。試験例1、2及び14に係る組成物は、高級アルコールを含有している。試験例1に係る組成物はアニオン性界面活性剤及び会合性増粘剤を含有している。一方、試験例2に係る組成物は、アニオン性界面活性剤を含有するが、会合性増粘剤を含有していない。試験例14に係る組成物は、会合性増粘剤を含有するが、アニオン性界面活性剤に代えて非イオン性界面活性剤を含有する。
3名の評価者が各試験例に係る組成物を整髪料として使用し、べたつきのなさ、整髪容易性、整髪力、手についた組成物の洗浄性、及び髪についた組成物の洗浄性について評価した。各評価項目について、評価者は以下の基準に基づいて点数をつけ、平均点を算出した。表に、各評価項目の評価を示す。
[評価基準]
5点:非常に良い
4点:良い
3点:普通
2点:悪い
1点:非常に悪い
[評価]
A:4点以上
B:3点
C:2点
D:1点
評価者が組成物を手で髪に塗布して整髪している間に感じるべたつきのなさを評価した。
整髪料が髪になじみやすいか、及び、評価者が組成物を髪につけた後、例えばすぐに髪が固まらない等、アレンジ可能な状態が適度に持続するかを評価した。
髪を自然な流れを有する髪形にセットでき、その髪形を維持できるかを評価した。
整髪料を使用後、手についた組成物を水で洗い流すことが容易にできるかを評価した。
髪に付着した乾燥後の整髪料がお湯とシャンプーで容易に洗浄可能かを評価した。具体的には、組成物を塗布して乾燥させたストランド(15cm、2gの人毛)をお湯で濡らし、シャンプーを0.1gつけて揉みこんだときに泡立つかを評価した。
容器内に本開示の第2実施形態に係る化粧料組成物を注入した製品を作製した。図1~図3に示すような可撓性容器(チューブ)に、第1の組成物及び第2の組成物の2種類の組成物を注入した。2つの組成物は、図4~図6に示すように、長手軸方向に沿って延在するように容器内に注入し、2種類の組成物が開口から同時に導出できるようにした。また、2種類の組成物は、図7に示すように、長手軸方向に垂直な方向の断面において、扇形の4区画に互い違いに配した。表5に、2種類の組成物の組成を示す。容器内における混合の有無を確認できるように、少なくとも一方の組成物には色材を入れて、第1の組成物と第2の組成物の色を異ならせた。
容器内における外観安定性及び2つの組成物を混合したときの相互作用について以下の評価基準で判定した。
[外観安定性]
第1の組成物と第2の組成物が直接接した状態における容器内の安定性について評価した。
A:容器内において、第1の組成物と第2の組成物の境界が明確であった。
B:容器内において、第1の組成物と第2の組成物の境界は全般的に明確であるが、一部境界のぼやけや色の混合が存在した。
C:容器内において、第1の組成物と第2の組成物の境界が不明確であった。
[整髪樹脂の混合作用]
各試験例に添加されている成分(15)~(18)のうちの2つ(例えば、試験例19においては成分(15)と成分(16))を質量比1:1で混練した際の相互作用について評価した。
A:髪形のキープ力が大きく向上した。
B:髪形のキープ力が向上した。
C:髪形のキープ力の向上はなかった。
容器から第1の組成物及び第2の組成物を同時に出し、手のひらで混練して混合物を作製した。その混合物について、べたつきのなさ、整髪容易性、整髪力、洗浄性(手)及び洗浄性(髪)について評価した。評価基準は試験例1~18と同じである。
[付記1]
第1の成分を含有する第1の組成物と、
第2の成分を含有する第2の組成物と、を含有し、
前記第1の成分と前記第2の成分とは、前記第1の組成物と前記第2の組成物を混合したときに結合及び/又は会合する、化粧料組成物。
[付記2]
第1の成分及び第2の成分はイオン性ポリマーである、付記に記載の化粧料組成物。
[付記3]
前記第1の組成物と前記第2の組成物を混練した混合物を化粧料として使用する、付記に記載の化粧料組成物。
[付記4]
前記第1の組成物及び前記第2の組成物の粘度は、10,000mPa・s~200,000mPa・sである、付記に記載の化粧料組成物。
[付記5]
前記第1の成分は、前記両性ポリマー及び/又はアニオン性ポリマーであり、
前記第2の成分は、前記両性ポリマー及び/又はカチオン性ポリマーである、付記に記載の化粧料組成物。
[付記6]
前記アニオン性ポリマーはウレタンポリマーである、付記に記載の化粧料組成物。
[付記7]
前記アニオン性ポリマーは(アクリレーツ/アクリル酸アルキル(C1-18)/アルキル(C1-8)アクリルアミド)コポリマーAMPである、付記に記載の化粧料組成物。
[付記8]
前記両性ポリマーはアクリルポリマーである、付記に記載の化粧料組成物。
[付記9]
前記両性ポリマーは、(メタクリロイルオキシエチルカルボキシベタイン/メタクリル酸アルキル)コポリマーである、付記に記載の化粧料組成物。
[付記10]
前記カチオン性ポリマーは、ポリクオタニウム-11及びポリウレタン-10のうちの少なくとも1つである、付記に記載の化粧料組成物。
[付記11]
整髪料である、付記に記載の化粧料組成物。
[付記12]
容器と、
前記容器内に配された、付記に記載の化粧料組成物と、を備え、
前記第1の組成物と前記第2の組成物とは少なくとも一部が接して前記容器中に配されている、製品。
[付記13]
前記容器から取り出した前記第1の組成物と前記第2の組成物を混練した混合物を化粧料として使用する、付記に記載の製品。
[付記14]
前記混合物は、前記第1の組成物単独及び前記第2の組成物単独よりも高いキープ力を有する、付記に記載の製品。
[付記15]
前記第1の組成物及び前記第2の組成物は、前記容器の長手方向に沿って並列的に前記容器内に配されている、付記に記載の製品。
[付記16]
前記第1の組成物と前記第2の組成物との界面は、前記容器の長手方向に延在している、付記に記載の製品。
[付記17]
前記容器は開口を有し、
前記開口に対向する投影面において、前記開口は、前記第1の組成物と前記第2の組成物との界面の一部と重複する、付記に記載の製品。
[付記18]
前記第1の組成物及び前記第2の組成物は、前記開口から同時に押出可能である、付記に記載の製品。
[付記19]
前記容器の長手方向に垂直な断面において、前記第1の組成物と前記第2の組成物とは放射状に配されている、付記に記載の製品。
[付記20]
前記容器の長手方向に垂直な断面において、前記第1の組成物と前記第2の組成物とは同心円状に配されている、付記に記載の製品。
[付記21]
前記容器の少なくとも一部は可撓性である、付記に記載の製品。
1a 開口
2a 第1の組成物
2b 第2の組成物
2c 第3の組成物
3 界面
10,11,12,13,14 製品
X 長手軸
Claims (26)
- 会合性増粘剤と、
アニオン性界面活性剤と、
高級アルコールと、を含有する組成物。 - 前記会合性増粘剤の含有率が前記組成物の質量に対して0.1質量%~3質量%であり、
前記アニオン性界面活性剤の含有率が前記組成物の質量に対して0.3質量%~4質量%である、請求項1に記載の組成物。 - 前記高級アルコールの含有率が前記組成物の質量に対して0.2質量%~8質量%である、請求項1又は2に記載の組成物。
- 前記高級アルコールを含む油性成分の含有率は、前記組成物の質量に対して5質量%~55質量%である、請求項1~3のいずれか一項に記載の組成物。
- 前記アニオン性界面活性剤は、N-ステアロイル-N-メチルタウリン塩である、請求項1~4のいずれか一項に記載の組成物。
- 前記組成物の質量に対して0.1質量%~10質量%の粉末をさらに含有する、請求項1~5のいずれか一項に記載の組成物。
- 前記会合性増粘剤は、疎水性変性ポリエーテルウレタン及び/又はタウレート系合成高分子である、請求項1~6のいずれか一項に記載の組成物。
- 前記疎水変性ポリエーテルウレタンは以下の構造式(I)を有する、請求項7に記載の組成物。
R1-{(O-R2)k-OCONH-R3[-NHCOO-(R4-O)n-R5]h}m (I)
[式(I)中、
R1、R2およびR4は、それぞれ独立に炭素原子数2~4の炭化水素基であり;
R3はウレタン結合を有していてもよい炭素原子数1~10の炭化水素基であり;
R5は炭素原子数8~36の炭化水素基であり;
mは2以上の数であり;
hは1以上の数であり;
kは1~500の数であり;
nは1~200の数である。] - 前記疎水変性ポリエーテルウレタンは(PEG-240/デシルテトラデセス-20/ヘキサメチルジイソシアネート)コポリマーである、請求項7又は8に記載の組成物。
- 前記タウレート系合成高分子は、2-アクリルアミド-2-プロパンスルホン酸又はその塩を構成単位として有する重合体及び/又は共重合体(架橋重合体含む)である、請求項7に記載の組成物。
- 前記タウレート系合成高分子は、(アクリロイルジメチルタウリンアンモニウム/メタクリル酸ベヘネス-25)クロスポリマーである、請求項7又は10に記載の組成物。
- 粘度が10,000mPa・s~200,000mPa・sである、請求項1~11のいずれか一項に記載の組成物。
- イオン性ポリマーをさらに含有する、請求項1~12のいずれか一項に記載の組成物。
- 前記イオン性ポリマーは、(メタクリロイルオキシエチルカルボキシベタイン/メタクリル酸アルキル)コポリマーである、請求項13に記載の組成物。
- 容器と、
前記容器中に存在する第1の組成物及び第2の組成物と、を備え、
前記第1の組成物と前記第2の組成物とは少なくとも一部が接して前記容器中に配され、
前記第1の組成物及び前記第2の組成物は、
会合性増粘剤と、
アニオン性界面活性剤と、
高級アルコールと、を含有する、製品。 - 前記容器から取り出した前記第1の組成物と前記第2の組成物を混練した混合物を化粧料として使用する、請求項15に記載の製品。
- 前記第1の組成物及び前記第2の組成物の粘度は、10,000mPa・s~200,000mPa・sである、請求項15又は16に記載の化粧料組成物。
- 前記容器は開口を有し、
前記開口に対向する投影面において、前記開口は、前記第1の組成物と前記第2の組成物との界面の一部と重複し、前記第1の組成物及び前記第2の組成物を前記開口から同時に押出可能である、請求項15~17のいずれか一項に記載の製品。 - 前記第1の組成物は、第1の成分をさらに含有し、
前記第2の組成物は、第2の成分をさらに含有し、
前記第1の成分と前記第2の成分とは、前記第1の組成物と前記第2の組成物を混合したときに結合及び/又は会合する、請求項15~18のいずれか一項に記載の製品。 - 前記第1の成分及び前記第2の成分はイオン性ポリマーである、請求項19に記載の製品。
- 前記第1の成分は、前記両性ポリマー及び/又はアニオン性ポリマーであり、
前記第2の成分は、前記両性ポリマー及び/又はカチオン性ポリマーである、請求項19又は20に記載の製品。 - 前記アニオン性ポリマーはウレタンポリマー及び(アクリレーツ/アクリル酸アルキル(C1-18)/アルキル(C1-8)アクリルアミド)コポリマーAMPのうち少なくとも1つである、請求項21に記載の製品。
- 前記両性ポリマーはアクリルポリマーである、請求項21又は22に記載の製品。
- 前記両性ポリマーは、(メタクリロイルオキシエチルカルボキシベタイン/メタクリル酸アルキル)コポリマーである、請求項21~23のいずれか一項に記載の製品。
- 前記カチオン性ポリマーは、ポリクオタニウム-11及びポリウレタン-10のうちの少なくとも1つである、請求項21~24のいずれか一項に記載の製品。
- 整髪料である、請求項15~25のいずれか一項に記載の製品。
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2021512848A (ja) * | 2017-12-22 | 2021-05-20 | エルブイエムエイチ レシェルシェ | 水中油型乳化化粧料 |
CN113171311A (zh) * | 2020-01-27 | 2021-07-27 | 富士胶片株式会社 | 透明凝胶状组合物 |
Families Citing this family (4)
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JP7133418B2 (ja) | 2018-09-28 | 2022-09-08 | 株式会社Subaru | エアバッグ装置 |
KR102276289B1 (ko) * | 2020-10-26 | 2021-07-12 | 주식회사 엔베코코스메틱 | 모발용 조성물 |
KR20240059685A (ko) * | 2022-10-25 | 2024-05-08 | 코스맥스 주식회사 | 포타슘알룸 및 폴리우레탄-10을 포함하는 염모제 조성물 |
CN117582377B (zh) * | 2023-11-01 | 2024-05-14 | 完美(广东)日用品有限公司 | 一种可形成稳定α-凝胶的乳化剂组合物 |
Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002193761A (ja) * | 2000-12-27 | 2002-07-10 | Hoyu Co Ltd | 毛髪処理剤組成物及びその使用方法 |
JP2002255740A (ja) * | 2001-03-05 | 2002-09-11 | Kose Corp | 多色状化粧料 |
JP2005213266A (ja) * | 2004-01-29 | 2005-08-11 | L'oreal Sa | 加圧流体、セラミド、ワックス及び/又はシリコーンを用いた、化粧処置用組成物の製法 |
JP2007291026A (ja) * | 2006-04-26 | 2007-11-08 | Shiseido Co Ltd | 増粘組成物及び化粧料 |
JP2008523110A (ja) * | 2005-03-21 | 2008-07-03 | ザ プロクター アンド ギャンブル カンパニー | 視覚的に区別できる相を含む多相パーソナルケア組成物 |
JP2009501210A (ja) * | 2005-07-12 | 2009-01-15 | ザ プロクター アンド ギャンブル カンパニー | 異なる相に類似レオロジー特性を有する組成物含有多相パーソナルケア組成物 |
JP2010070492A (ja) * | 2008-09-18 | 2010-04-02 | Nippon Fine Chem Co Ltd | 化粧料 |
JP2013018751A (ja) * | 2011-07-13 | 2013-01-31 | Shiseido Co Ltd | 水中油型乳化化粧料 |
JP2013537921A (ja) * | 2010-09-01 | 2013-10-07 | ビーエイエスエフ・ソシエタス・エウロパエア | 水性組成物用会合性増粘剤 |
JP2016088868A (ja) * | 2014-10-31 | 2016-05-23 | 株式会社 資生堂 | 弾力ジェル状組成物 |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP4133017B2 (ja) * | 2002-06-20 | 2008-08-13 | 株式会社資生堂 | 毛髪処理用組成物 |
JP4819332B2 (ja) | 2004-08-25 | 2011-11-24 | 株式会社 資生堂 | 毛髪化粧料 |
JP5761838B2 (ja) | 2008-01-25 | 2015-08-12 | 株式会社 資生堂 | 水中油型乳化型整髪料 |
-
2017
- 2017-09-15 JP JP2018539207A patent/JP7042743B2/ja active Active
- 2017-09-15 WO PCT/JP2017/033612 patent/WO2018052146A1/ja active Application Filing
- 2017-09-15 KR KR1020197007937A patent/KR20190051994A/ko unknown
- 2017-09-15 CN CN201780057008.3A patent/CN109689019B/zh active Active
- 2017-09-18 TW TW106131934A patent/TW201813623A/zh unknown
Patent Citations (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002193761A (ja) * | 2000-12-27 | 2002-07-10 | Hoyu Co Ltd | 毛髪処理剤組成物及びその使用方法 |
JP2002255740A (ja) * | 2001-03-05 | 2002-09-11 | Kose Corp | 多色状化粧料 |
JP2005213266A (ja) * | 2004-01-29 | 2005-08-11 | L'oreal Sa | 加圧流体、セラミド、ワックス及び/又はシリコーンを用いた、化粧処置用組成物の製法 |
JP2008523110A (ja) * | 2005-03-21 | 2008-07-03 | ザ プロクター アンド ギャンブル カンパニー | 視覚的に区別できる相を含む多相パーソナルケア組成物 |
JP2009501210A (ja) * | 2005-07-12 | 2009-01-15 | ザ プロクター アンド ギャンブル カンパニー | 異なる相に類似レオロジー特性を有する組成物含有多相パーソナルケア組成物 |
JP2007291026A (ja) * | 2006-04-26 | 2007-11-08 | Shiseido Co Ltd | 増粘組成物及び化粧料 |
JP2010070492A (ja) * | 2008-09-18 | 2010-04-02 | Nippon Fine Chem Co Ltd | 化粧料 |
JP2013537921A (ja) * | 2010-09-01 | 2013-10-07 | ビーエイエスエフ・ソシエタス・エウロパエア | 水性組成物用会合性増粘剤 |
JP2013018751A (ja) * | 2011-07-13 | 2013-01-31 | Shiseido Co Ltd | 水中油型乳化化粧料 |
JP2016088868A (ja) * | 2014-10-31 | 2016-05-23 | 株式会社 資生堂 | 弾力ジェル状組成物 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2021512848A (ja) * | 2017-12-22 | 2021-05-20 | エルブイエムエイチ レシェルシェ | 水中油型乳化化粧料 |
JP7211666B2 (ja) | 2017-12-22 | 2023-01-24 | エルブイエムエイチ レシェルシェ | 水中油型乳化化粧料 |
CN113171311A (zh) * | 2020-01-27 | 2021-07-27 | 富士胶片株式会社 | 透明凝胶状组合物 |
JP2021116262A (ja) * | 2020-01-27 | 2021-08-10 | 富士フイルム株式会社 | 透明ゲル状組成物 |
JP7220682B2 (ja) | 2020-01-27 | 2023-02-10 | 富士フイルム株式会社 | 透明ゲル状組成物 |
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