WO2017024424A1 - 高效渗透性、防飞溅的锦纶dty油剂及其制造方法 - Google Patents

高效渗透性、防飞溅的锦纶dty油剂及其制造方法 Download PDF

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WO2017024424A1
WO2017024424A1 PCT/CN2015/000740 CN2015000740W WO2017024424A1 WO 2017024424 A1 WO2017024424 A1 WO 2017024424A1 CN 2015000740 W CN2015000740 W CN 2015000740W WO 2017024424 A1 WO2017024424 A1 WO 2017024424A1
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agent
splash
permeability
oil
emulsifier
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PCT/CN2015/000740
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French (fr)
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赵国良
朱坚毅
陆蕴菊
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太仓市隆纺油剂有限公司
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/368—Hydroxyalkylamines; Derivatives thereof, e.g. Kritchevsky bases
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • D06M13/51—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond
    • D06M13/513—Compounds with at least one carbon-metal or carbon-boron, carbon-silicon, carbon-selenium, or carbon-tellurium bond with at least one carbon-silicon bond
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    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain

Definitions

  • the invention relates to the technical field of nylon DTY fiber processing, and more particularly to a high-permeability, anti-splash nylon DTY oil agent and a manufacturing method thereof.
  • nylon DTY fiber technology in China, in order to increase the output, the speed of nylon DTY fiber is increasing.
  • nylon DTY oil agent can not adapt to the high-speed elastic process, and often does not oil or oil. Uneven, or oil on the fibers, tends to run out at high speeds, sticking to the machine and the ground, causing unstable fiber quality and environmental pollution.
  • the object of the present invention is to provide a nylon DTY oil agent which can meet the following requirements and a manufacturing method thereof: the requirements for high-speed elastic-stretching process of nylon DTY fiber; good spinnability; oiling It is quick and even; it will not be splashed on the machine table and the ground by the high-speed machine; the fiber is evenly coated with an appropriate amount of oil to ensure good winding and post-processing, thus ensuring fiber Super qulity.
  • a high-permeability, anti-splash nylon DTY oil agent is composed of an emulsifier, a sizing agent, an antistatic agent, a high-efficiency penetrating agent, an anti-splashing agent and a smoothing agent, wherein the weight percentage of each component is: emulsifier 6- 12%, concentrating agent 3-8%, antistatic agent 2-5%, high-efficiency penetrant 0.5-1.5%, anti-splash agent 0.5-1.5%, smoothing agent 72-88%.
  • the weight percentage of each component is: 6% emulsifier, 3% of the sizing agent, 2% of the antistatic agent, 0.5% of the high-efficiency penetrant, 0.5% of the anti-splashing agent, and 88% of the smoothing agent.
  • the weight percentage of each component is: emulsifier 12%, concentrating agent 8%, antistatic 5% agent, 1.5% high-efficiency penetrant, 1.5% anti-splash agent, 72% smoothing agent.
  • the weight percentage of each component is: 8% emulsifier, 6% sizing agent, 3.5% antistatic agent, 1.5% high-efficiency penetrant, 1% anti-splash agent, and 80% smoothing agent.
  • the weight percentage of each component is: 7% emulsifier, 4% sizing agent, 3% antistatic agent, 1% high-efficiency penetrant, 1% anti-splash agent, and 84% smoothing agent.
  • the emulsifier is one or a mixture of oleic acid polyoxyethylene ester, castor oil polyoxyethylene ether, trimethylolpropane polyoxyethylene ether, and dodecanol polyoxyethylene ether.
  • the function of the emulsifier is to balance the components in the oil agent, in particular the smoothing agent to be emulsified, by a physicochemical process, so that the oil agent becomes a uniform, transparent and stable oily solution;
  • the sizing agent is one or a mixture of one or more of sorbitan oleate polyoxyethylene ether, dodecyl lauric acid diethanolamine salt, and lauryl ethoxylate ether triethanolamine salt.
  • the function of the agent is to improve the adhesion of the oil agent, so that the fibers and the fibers can be properly bonded together, and are not loosened or scattered during the processing, and the yarn breakage is reduced, so that the winding is well formed;
  • the antistatic agent is one or a mixture of one or more of dodecanol polyoxyethylene phosphate methyl salt, cetyl sulfate methyl salt, and octadecyl dihydroxyethyl betaine.
  • the role of the agent is to increase the hygroscopicity of the fiber during the high-speed elastic process of the fiber, improve the electrical conductivity of the fiber, reduce the generation and accumulation of static electricity, and ensure the smooth processing of the fiber;
  • the high-efficiency penetrant is a mixture of one or more of dimethylcyclosiloxane, hexamethyldisiloxane, low-viscosity dimethicone, and the effect of the high-efficiency penetrant is to reduce the oil agent.
  • the surface tension and the penetration of the oil enhance the oil agent to spread rapidly on the surface of the fiber and quickly penetrate into each fiber of the fiber, so that the oil is quickly applied, the oil is evenly distributed, and a uniform oil is formed on the surface of the fiber.
  • Layer which is conducive to high-speed bombing to ensure fiber quality;
  • the anti-splashing agent is a high molecular weight polyisobutylene.
  • the anti-splashing agent acts to increase the shearing force between the oil molecules, and the intermolecular attraction increases.
  • the mechanical high-speed operation generates an outward force. Because of the anti-splash, the attraction between the oil molecules is greatly increased, and the outward force of the mechanical operation is overcome, the oil agent will not splash out, the oil quantity on the fiber is ensured, and the pollution on the machine platform and the workshop floor is reduced. Reduce waste and ensure fiber quality;
  • the smoothing agent is one of a primary hydrogenated mineral oil, a national standard mechanical oil, and dioctyl sebacate. Or more than one mixture, the smoothing agent acts to provide a suitable coefficient of friction between the fibers and the fibers, and between the fibers and other components, which helps to reduce friction between the fibers and between the fibers and other components. The force reduces the breakage of the filament during the processing and makes the winding forming good.
  • a method for manufacturing a high-permeability, anti-splash nylon DTY oil agent comprising the following steps:
  • the metered emulsifier, sizing agent and antistatic agent are first added to the reaction equipment, heated to 40-50 degrees Celsius, and uniformly stirred to fuse;
  • the invention has the following remarkable features and positive effects:
  • the oil agent is transparent, stable and spinnable
  • the oil has a large intermolecular attraction and will not be splashed by the high-speed mechanical machine;
  • the amount of oil on the surface of the fiber is guaranteed, which is conducive to the high-speed bombing and ensures the quality of the fiber.
  • the high-permeability and anti-splash nylon DTY oil agent of the invention is suitable for the elasticizing process of the highest speed texturing machine in China, has good spinnability, and the oil is quickly and evenly distributed, and the fiber oil layer ensures that the processing process is interrupted less. The winding is well formed and the superior product rate is high to meet the needs of users.
  • a high-permeability, anti-splash nylon DTY oil agent mainly consists of an emulsifier, a sizing agent, An antistatic agent, a high-efficiency penetrant, an anti-splashing agent and a smoothing agent, wherein the weight percentage of each component is as follows:
  • sizing agent sorbitan oleate polyoxyethylene ether
  • high permeability agent which is dimethylcyclosiloxane
  • the anti-splash agent is 0.5% and is a polyisobutylene having a molecular weight of 1.5 million.
  • a high-permeability, anti-splash nylon DTY oil agent is mainly composed of an emulsifier, a sizing agent, an antistatic agent, a high-efficiency penetrating agent, an anti-splashing agent and a smoothing agent, wherein the weight percentage of each component is as follows:
  • emulsifier of which 5% oleic acid polyoxyethylene ester, castor oil polyoxyethylene ether 2%, trimethylolpropane polyoxyethylene ether 3%, dodecanol polyoxyethylene ether 2%;
  • Antistatic agent 5% wherein dodecanol polyoxyethylene phosphate methyl salt 2%, cetyl sulfate methyl salt 2%, octadecyl dihydroxyethyl betaine 1%;
  • smoothing agent including 50% primary hydrogenated mineral oil, 10% national standard mechanical oil, 12% dioctyl sebacate;
  • the anti-splash agent is 1.5% and is a polyisobutylene having a molecular weight of 1.5 million.
  • a high-permeability, anti-splash nylon DTY oil agent is mainly composed of an emulsifier, a sizing agent, an antistatic agent, a high-efficiency penetrating agent, an anti-splashing agent and a smoothing agent, wherein the weight of each component is 100
  • the score is as follows:
  • Emulsifier 8% of which 5% oleic acid polyoxyethylene ester, trimethylolpropane polyoxyethylene ether 3%;
  • Antistatic agent 3.5%, wherein cetyl sulfate methyl salt 2%, octadecyl dihydroxyethyl betaine 1.5%;
  • the anti-splashing agent is 1% and is a polyisobutylene having a molecular weight of 1.5 million.
  • a high-permeability, anti-splash nylon DTY oil agent is mainly composed of an emulsifier, a sizing agent, an antistatic agent, a high-efficiency penetrating agent, an anti-splashing agent and a smoothing agent, wherein the weight percentage of each component is as follows:
  • Emulsifier 7% of which castor oil polyoxyethylene ether 2%, dodecyl polyoxyethylene ether 5%;
  • Antistatic agent 3% wherein octadecyl dihydroxyethyl betaine 2%, dodecanol polyoxyethylene phosphate methyl salt 1%;
  • the anti-splashing agent is 1% and is a polyisobutylene having a molecular weight of 1.5 million.
  • the method of manufacturing the high-permeability, splash-proof nylon DTY oil agent in the above embodiment comprises the following steps:
  • the quality parameters of the high-permeability, splash-proof nylon DTY oil agent in the above embodiments of the present invention are as follows:
  • Emulsifying (5% aqueous solution) is a uniform milky white liquid
  • Table 1 shows the case where the high-permeability, splash-proof nylon DTY oil agent in the above-described embodiment of the present invention and the existing nylon DTY oil agent splash oil on the machine table and the ground at different times.
  • Table 1 The situation of splashing oil on the machine and the ground in different oil agents at different times
  • the existing nylon DTY oil agent has more machine and ground oil after 72 hours, and must be cleaned, otherwise it will affect the operation.
  • the nylon DTY oil of the invention has strong anti-splash ability. After 72 hours, there is almost no oil on the machine table and the bottom surface, which ensures the amount of oil on the fiber, so that the processing is smoothly carried out, and the quality is achieved on the basis of ensuring the quality.
  • the purpose of fuel economy has reduced pollution to the machine and the ground.
  • Table 2 shows the high-permeability, splash-proof nylon DTY in the above embodiment of the present invention.
  • the permeability test is to use a nylon round plant of the same diameter (1.5 cm), placed in a high 10 cm oil, and note the time when the nylon fabric falls to the end.
  • the surface tension of the nylon DTY oil of the present invention is in the range of 20-23 mN ⁇ m -1 , which is smaller than the surface tension of the existing nylon DTY oil agent, and the nylon DTY of the present invention.
  • the permeability of the oil agent is better than that of the existing nylon DTY oil.
  • Table 2 fully demonstrates that the nylon DTY oil agent of the invention has small surface tension and good permeability, and the oil agent is easy to spread on the surface of the fiber and penetrate into the middle of the fiber layer, and the oil is quickly and evenly distributed.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

本发明提供了一种高效渗透性、防飞溅的锦纶DTY油剂，其由乳化剂、集束剂、抗静电剂、高效渗透剂、防飞溅剂和平滑剂组成，其中，各组分的重量百分比为：乳化剂6-12％，集束剂3-8％，抗静电剂2-5％，高效渗透剂0.5-1.5％，防飞溅剂0.5-1.5％、平滑剂72-88％。本发明提供的高效渗透性、防飞溅的锦纶DTY油剂透明，稳定，可纺性好；油剂表面张力小，铺展性好，渗透率强，上油迅速均匀；油剂分子间引力大，不会被高速运转的机械甩出而飞溅；纤维表面上油量有保证，有利于高速加弹的进行，保证纤维的质量。

Description

高效渗透性、防飞溅的锦纶DTY油剂及其制造方法 技术领域
本发明涉及锦纶DTY纤维加工技术领域，并且更具体地涉及一种高效渗透性、防飞溅的锦纶DTY油剂及其制造方法。
背景技术
当前，由于我国锦纶DTY纤维工艺飞速发展，为提高产量，锦纶DTY纤维加弹的速度不断提高，先前使用的锦纶DTY油剂已不能适应高速的加弹工艺，常常出现上不上油或上油不匀，或上在纤维上的油也往往会被高速地运转甩出，粘在机台上和地面上，从而造成纤维质量不稳定并产生环境污染。
发明内容
针对以上现有技术中存在的问题，本发明的目的是提供一种能满足以下要求的锦纶DTY油剂及其制造方法：适应锦纶DTY纤维高速加弹工艺的要求；可纺性好；上油迅速均匀；并且不会被高速运转的机械甩出而飞溅在机台上和地面上；使纤维上均匀涂有一层适量的油剂，保证卷绕成型良好和后加工的顺利进行，从而保证纤维优良的品质。
为了实现上述发明目的，本发明采用的技术方案如下：
一种高效渗透性、防飞溅的锦纶DTY油剂由乳化剂、集束剂、抗静电剂、高效渗透剂、防飞溅剂和平滑剂组成，其中，各组分的重量百分比为：乳化剂6-12％，集束剂3-8％，抗静电剂2-5％，高效渗透剂0.5-1.5％，防飞溅剂0.5-1.5％，平滑剂72-88％。
优选地，各组分的重量百分比为：乳化剂6％，集束剂3％，抗静电剂2％，高效渗透剂0.5％，防飞溅剂0.5％、平滑剂88％。
优选地，各组分的重量百分比为：乳化剂12％，集束剂8％，抗静电 剂5％，高效渗透剂1.5％，防飞溅剂1.5％、平滑剂72％。
优选地，各组分的重量百分比为：乳化剂8％，集束剂6％，抗静电剂3.5％，高效渗透剂1.5％，防飞溅剂1％、平滑剂80％。
优选地，各组分的重量百分比为：乳化剂7％，集束剂4％，抗静电剂3％，高效渗透剂1％，防飞溅剂1％、平滑剂84％。
进一步地，所述乳化剂为油酸聚氧乙烯酯、蓖麻油聚氧乙烯醚、三羟甲基丙烷聚氧乙烯醚、十二醇聚氧乙烯醚中的一种或一种以上的混合物，所述乳化剂的作用是将油剂中的各组分，特别是被乳化对象平滑剂通过物理化学过程达到平衡，使油剂成为均匀、透明、稳定的油状溶液；
所述集束剂为山梨醇酐油酸酯聚氧乙烯醚、十二烷基月桂酸二乙醇胺盐、月桂醇聚氧乙烯醚硫酸三乙醇胺盐中的一种或一种以上的混合物，所述集束剂的作用是提高油剂的粘合力，使纤维与纤维之间能适当的粘合在一起，在加工过程中不松开、不散乱，减少毛丝断头，使卷绕成型良好；
所述抗静电剂为十二醇聚氧乙烯磷酸酯甲盐、十六醇硫酸酯甲盐、十八烷基二羟乙基甜菜碱中的一种或一种以上的混合物，所述抗静电剂的作用是在纤维高速加弹过程中，增加纤维的吸湿性，提高纤维的电导率，减少静电的产生和积聚，保证纤维顺利进行加工；
所述高效渗透剂为二甲基环硅氧烷、六甲基二硅氧烷、低粘度二甲基硅油中的一种或一种以上的混合物，所述高效渗透剂的作用是降低油剂的表面张力和提高油剂的渗透力，使油剂能在纤维表面迅速铺展和快速渗透到纤维的每根纤维中，使上油迅速，上油均匀，在纤维表面形成一层均匀的油剂层，有利于高速加弹进行，保证纤维质量；
所述防飞溅剂为高分子量的聚异丁烯，所述防飞溅剂的作用是提高油剂分子间的剪切力，分子间引力增加，当高速加弹时，机械高速运转产生向外的甩力，由于防飞溅的存在，油剂分子间的引力大大增加，克服机械运转的向外甩力，油剂不会飞溅出去，保证纤维上的上油量，减少机台上和车间地面的污染，减少了浪费，保证纤维质量；
所述平滑剂为一次加氢矿物油、国标机械油、癸二酸二辛酯中的一种 或一种以上的混合物，所述平滑剂的作用是使纤维与纤维之间，纤维与其他部件之间有一个合适的摩擦系数范围，有利于减少纤维之间、纤维与其他部件之间的摩擦力，减少加工过程中的毛丝断头，使卷绕成型良好。
一种高效渗透性、防飞溅的锦纶DTY油剂的制造方法，包括以下步骤：
(1)按各组分的重量百分比，先将计量好的乳化剂、集束剂、抗静电剂加入反应设备中，加热至40-50摄氏度，均匀搅拌使之融合；
(2)再将计量好的平滑剂加入到反应设备中，搅拌20分钟；
(3)再将计量好的高效渗透剂和防飞溅剂加入到反应设备中，搅拌60-90分钟；
(4)将所得的混合物冷却，过滤，包装，得到高效渗透性、防飞溅的锦纶DTY油剂。
本发明与原有技术相比，具有以下显著的特点和积极作用：
A.油剂透明，稳定，可纺性好；
B.油剂表面张力小，铺展性好，渗透率强，上油迅速均匀；
C.油剂分子间引力大，不会被高速运转的机械甩出而飞溅；
D.纤维表面上油量有保证，有利于高速加弹的进行，保证了纤维的质量。
本发明所述的高渗透性、防飞溅的锦纶DTY油剂，适用于国内最高速加弹机的加弹工艺，可纺性好，上油迅速均匀，纤维上油层保证加工过程中断头少，卷绕成型良好，优等品率高，满足用户需求。
具体实施方式
以下结合实施例对本发明作进一步说明，但并非限制本发明的应用范围。
实施例1
一种高效渗透性、防飞溅的锦纶DTY油剂主要由乳化剂、集束剂、 抗静电剂、高效渗透剂、防飞溅剂和平滑剂组成，其中，各组分的重量百分比如下：
乳化剂6％，为油酸聚氧乙烯酯；
集束剂3％，为山梨醇酐油酸酯聚氧乙烯醚；
抗静电剂2％，为十二醇聚氧乙烯磷酸酯甲盐；
平滑剂88％，为一次加氢矿物油；
高渗透剂0.5％，为二甲基环硅氧烷；
防飞溅剂0.5％，为分子量150万的聚异丁烯。
实施例2
一种高效渗透性、防飞溅的锦纶DTY油剂主要由乳化剂、集束剂、抗静电剂、高效渗透剂、防飞溅剂和平滑剂组成，其中，各组分的重量百分比如下：
乳化剂12％，其中油酸聚氧乙烯酯5％，蓖麻油聚氧乙烯醚2％，三羟甲基丙烷聚氧乙烯醚3％，十二醇聚氧乙烯醚2％；
集束剂8％，其中山梨醇酐油酸酯聚氧乙烯醚3％，十二烷基月桂酸二乙醇胺盐2％，月桂醇聚氧乙烯醚硫酸三乙醇胺盐3％；
抗静电剂5％，其中十二醇聚氧乙烯磷酸酯甲盐2％，十六醇硫酸酯甲盐2％，十八烷基二羟乙基甜菜碱1％；
平滑剂72％，其中一次加氢矿物油50％，国标机械油10％，癸二酸二辛酯12％；
高渗透剂1.5％，其中二甲基环硅氧烷0.5，六甲基二硅氧烷0.5％，低粘度二甲基硅油0.5％；
防飞溅剂1.5％，为分子量150万的聚异丁烯。
实施例3
一种高效渗透性、防飞溅的锦纶DTY油剂主要由乳化剂、集束剂、抗静电剂、高效渗透剂、防飞溅剂和平滑剂组成，其中，各组分的重量百 分比如下：
乳化剂8％，其中油酸聚氧乙烯酯5％，三羟甲基丙烷聚氧乙烯醚3％；
集束剂6％，其中山梨醇酐油酸酯聚氧乙烯醚4％，十二烷基月桂酸二乙醇胺盐2％；
抗静电剂3.5％，其中十六醇硫酸酯甲盐2％，十八烷基二羟乙基甜菜碱1.5％；
平滑剂80％，其中一次加氢矿物油70％，国标机械油10％；
高渗透剂1.5％，其中六甲基二硅氧烷1％，低粘度二甲基硅油0.5％；
防飞溅剂1％，为分子量150万的聚异丁烯。
实施例4
一种高效渗透性、防飞溅的锦纶DTY油剂主要由乳化剂、集束剂、抗静电剂、高效渗透剂、防飞溅剂和平滑剂组成，其中，各组分的重量百分比如下：
乳化剂7％，其中蓖麻油聚氧乙烯醚2％，十二醇聚氧乙烯醚5％；
集束剂4％，其中山梨醇酐油酸酯聚氧乙烯醚2.5％，月桂醇聚氧乙烯醚硫酸三乙醇胺盐1.5％；
抗静电剂3％，其中十八烷基二羟乙基甜菜碱2％，十二醇聚氧乙烯磷酸酯甲盐1％；
平滑剂84％，其中一次加氢矿物油64％，国标机械油20％；
高渗透剂1％，其中二甲基环硅氧烷0.5％，低粘度二甲基硅油0.5％；
防飞溅剂1％，为分子量150万的聚异丁烯。
制造上述实施例中的高效渗透性、防飞溅的锦纶DTY油剂的方法包括以下步骤：
(1)按上述各组分的重量百分比，先将计量好的乳化剂、集束剂、抗静电剂加入反应釜中，加热至40-50摄氏度，均匀搅拌使之融合；
(2)再将计量好的平滑剂加入到反应釜中，搅拌20分钟；
(3)再将计量好的高效渗透剂和防飞溅剂加入到反应釜中，搅拌60-90分钟；
(4)将所得的混合物冷却，过滤，包装，得到高效渗透性、防飞溅的锦纶DTY油剂。
本发明的上述实施例中的高效渗透性、防飞溅的锦纶DTY油剂的质量参数如下：
1.外观：微黄色透明油状液
2.PH:5％水溶液7.0-9.0
3.旋转指数(40℃)mpa·s 11-13
4.有效浓度≥99％
5.乳化性(5％水溶液)呈均匀乳白色液体
6.表面张力mN·m-120-23
表1示出了本发明的上述实施例中的高效渗透性、防飞溅的锦纶DTY油剂与现有的锦纶DTY油剂不同时间内在机台和地面上飞溅油剂的情况。
表1不同油剂不同时间内机台和地面上飞溅油剂的情况
Figure PCTCN2015000740-appb-000001
由表1可知，现有的锦纶DTY油剂72小时后机台和地面油剂较多，必须清洁，否则影响操作。而本发明的锦纶DTY油剂防飞溅能力较强，在72小时之后，在机台和底面上几乎没有油剂，保证了纤维上上油的量，使得加工顺利进行，在保证质量基础上达到了省油的目的，减少了对机台和地面的污染。
表2示出了本发明的上述实施例中的高效渗透性、防飞溅的锦纶DTY 油剂与现有的锦纶DTY油剂的表面张力和渗透率的测试结果。
表2不同DTY油剂的表面张力和渗透率
Figure PCTCN2015000740-appb-000002
注：渗透率测试是用相同直径(1.5cm)的锦纶圆形植物，放在高10cm油剂中，记下锦纶织物落到底的时间。
从表2中可以看出，本发明的锦纶DTY油剂的表面张力在20-23mN·m-1的范围内，比现有的锦纶DTY油剂的表面张力要小，并且本发明的锦纶DTY油剂的渗透率比现有的锦纶DTY油剂的渗透率好。
表2充分说明了本发明的锦纶DTY油剂表面张力小，渗透率好，油剂易在纤维表面铺展和渗透到纤维层中间，上油迅速均匀。
以上所述仅为本发明的较佳实施例，并非用来限定本发明的实施范围；如果不脱离本发明的精神和范围，对本发明进行修改或者等同替换，均应涵盖在本发明权利要求的保护范围当中。

Claims (7)

  1. 一种高效渗透性、防飞溅的锦纶DTY油剂，其特征在于，由乳化剂、集束剂、抗静电剂、高效渗透剂、防飞溅剂和平滑剂组成，各组分的重量百分比为：乳化剂6-12％，集束剂3-8％，抗静电剂2-5％，高效渗透剂0.5-1.5％，防飞溅剂0.5-1.5％、平滑剂72-88％。
  2. 根据权利要求1所述的高效渗透性、防飞溅的锦纶DTY油剂，其特征在于，各组分的重量百分比为：乳化剂6％，集束剂3％，抗静电剂2％，高效渗透剂0.5％，防飞溅剂0.5％、平滑剂88％。
  3. 根据权利要求1所述的高效渗透性、防飞溅的锦纶DTY油剂，其特征在于，各组分的重量百分比为：乳化剂12％，集束剂8％，抗静电剂5％，高效渗透剂1.5％，防飞溅剂1.5％、平滑剂72％。
  4. 根据权利要求1所述的高效渗透性、防飞溅的锦纶DTY油剂，其特征在于，各组分的重量百分比为：乳化剂8％，集束剂6％，抗静电剂3.5％，高效渗透剂1.5％，防飞溅剂1％、平滑剂80％。
  5. 根据权利要求1所述的高效渗透性、防飞溅的锦纶DTY油剂，其特征在于，各组分的重量百分比为：乳化剂7％，集束剂4％，抗静电剂3％，高效渗透剂1％，防飞溅剂1％、平滑剂84％。
  6. 根据权利要求1-5中任意一项所述的高效渗透性、防飞溅的锦纶DTY油剂，其特征在于，所述乳化剂为油酸聚氧乙烯酯、蓖麻油聚氧乙烯醚、三羟甲基丙烷聚氧乙烯醚、十二醇聚氧乙烯醚中的一种或一种以上的混合物；
    所述集束剂为山梨醇酐油酸酯聚氧乙烯醚、十二烷基月桂酸二乙醇胺盐、月桂醇聚氧乙烯醚硫酸三乙醇胺盐中的一种或一种以上的混合物；
    所述抗静电剂为十二醇聚氧乙烯磷酸酯甲盐、十六醇硫酸酯甲盐、十八烷基二羟乙基甜菜碱中的一种或一种以上的混合物；
    所述高效渗透剂为二甲基环硅氧烷、六甲基二硅氧烷、低粘度二甲基 硅油中的一种或一种以上的混合物；
    所述防飞溅剂为高分子量的聚异丁烯；
    所述平滑剂为一次加氢矿物油、国标机械油、癸二酸二辛酯中的一种或一种以上的混合物。
  7. 一种如权利要求1-6中任意一项所述的高效渗透性、防飞溅的锦纶DTY油剂的制造方法，其特征在于，包括以下步骤：
    (1)按各组分的重量百分比，先将计量好的乳化剂、集束剂、抗静电剂加入反应设备中，加热至40-50摄氏度，均匀搅拌使之融合；
    (2)再将计量好的平滑剂加入到反应设备中，搅拌20分钟；
    (3)再将计量好的高效渗透剂和防飞溅剂加入到反应设备中，搅拌60-90分钟；
    (4)将所得的混合物冷却，过滤，包装，得到高效渗透性、防飞溅的锦纶DTY油剂。
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CN112663336A (zh) * 2020-12-22 2021-04-16 太仓市隆纺油剂有限公司 一种高渗透性的dty纺织油剂及其制备方法
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