CN110629546A - 一种天丝纤维织造用绿色环保型油剂及其制备方法 - Google Patents

一种天丝纤维织造用绿色环保型油剂及其制备方法 Download PDF

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CN110629546A
CN110629546A CN201911056668.7A CN201911056668A CN110629546A CN 110629546 A CN110629546 A CN 110629546A CN 201911056668 A CN201911056668 A CN 201911056668A CN 110629546 A CN110629546 A CN 110629546A
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张诗涵
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Rugao Yurun Fiber Technology Co Ltd
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Abstract

本发明公开了一种天丝纤维织造用绿色环保型油剂，包括如下成分组成：平滑剂、乳化剂、抗静电剂、集束剂、防腐剂、渗透剂、表面活性剂和去离子水，各成分质量分数为：平滑剂22～30%，乳化剂5～10%，抗静电剂5～10%，集束剂10～15%，防腐剂0.01～3%，渗透剂0.05～1%，表面活性剂15～30%，余量的去离子水。本发明中，生产出的油剂在上油天丝纤维后，可以将天丝纤维原纤之间很好的抱合集束在一起，增加了天丝纤维的集束性，从而避免了现有天丝纤维原纤集束差，受机械摩擦断裂的情况发生，且本油剂在生产制备以及使用后均不产生危害元素，是绿色环保型油剂。

Description

一种天丝纤维织造用绿色环保型油剂及其制备方法
技术领域
本发明属于纺织油剂制备技术领域，具体为一种天丝纤维织造用绿色环保型油剂及其制备方法。
背景技术
天丝是一种木浆纤维，原料为天然材质，经过物理处理过程。保留了棉的透气、化纤的强度、真丝的光泽。具有柔软悬垂、触感独特、飘逸动感、透气透湿、素雅光泽，防螨抗静电、耐用性强、弹性好、不易起皱、便于打理洗涤等优点。适宜春夏秋多雨季节选用，它有棉的舒适性、涤纶的“强度”、毛织物的“豪华美感”和真丝的“独特触感”及“柔软垂坠”，无论在干或湿的状态下，均极具韧性，迎合了现代消费者的需求。但天丝纤维仍存在原纤之间结合较弱，受到机械摩擦时，纤维外层会发生断裂产生毛茸，严重时会缠结成棉粒，影响使用。
发明内容
本发明的目的在于：为了解决现有天丝纤维油剂对天丝结合能力弱、受机械摩擦出现断裂，保护天丝纤维效果不足的问题，提供一种天丝纤维织造用绿色环保型油剂及其制备方法。
本发明采用的技术方案如下：
一种天丝纤维织造用绿色环保型油剂，包括如下成分组成：平滑剂、乳化剂、抗静电剂、集束剂、防腐剂、渗透剂、表面活性剂和去离子水，各成分质量分数为：平滑剂22～30%，乳化剂5～10%，抗静电剂5～10%，集束剂10～15%，防腐剂0.01～3%，渗透剂0.05～1%，表面活性剂15～30%，余量的去离子水。
其中,所述平滑剂包括矿物油、油酸脂、动物脂肪酸酯、植物脂肪酸酯中的任意一种或几种。
其中,所述乳化剂包括聚丙烯酰胺、脂肪胺盐、聚甘油酯中的任意一种或几种。
其中,所述抗静电剂为十八烷基二甲基羟乙基季铵硝酸盐、烷基胺与环氧乙烷浓缩物中的任意一种与β-烷基磺酸盐、高碳醇聚氧乙烯醚磷酸酯钾盐、异构醇聚氧乙烯醚磷酸酯钾盐中任意一种的混合。
其中,所述表面活性剂包括非离子表面活性剂与阴离子表面活性剂，非离子表面活性剂选用Tween 80，阴离子表面活性剂选用烷基苯磺酸盐。
其中,所述的一种天丝纤维织造用绿色环保型油剂的制备方法，其特征在于,包括如下步骤：
步骤1：将平滑剂、抗静电剂、表面活性剂和渗透剂以及三分之二分量的去离子水加入反应釜中，升温至50～60℃，加压20～26Pa，进行搅拌30～42min；
步骤2：将步骤1产物进行泄压降温至室温后，加入乳化剂、集束剂和防腐剂以及剩余分量的去离子水，常压状态下，降温至5～8℃，搅拌混合，混合后静置10～13min，匀速增压至30～32Pa，再搅拌，搅拌速度180～220r/min，搅拌时间35～45min，静置12～15min，然后再降温搅拌和增压搅拌循环两次；
步骤3：测试步骤2产物的pH值，并使用pH调节剂，调节至5～7，然后检查油剂是否合格；
步骤4：油剂冷却后，灌装油桶内即完成制备。
其中,所述检查油剂是否合格，具体为，加热油剂至80～90℃，轻微搅拌，查看是否有泡沫产生以及是否油剂变稠，是则为不合格，空冷后降温至-2～-3℃，轻微搅拌，查看油剂是否有凝结现象以及是否有析出物，有则为不合格。
综上所述，由于采用了上述技术方案，本发明的有益效果是：
1、本发明中，生产出的油剂在上油天丝纤维后，可以将天丝纤维原纤之间很好的抱合集束在一起，增加了天丝纤维的集束性，从而避免了现有天丝纤维原纤集束差，受机械摩擦断裂的情况发生，且本油剂在生产制备以及使用后均不产生危害元素，是绿色环保型油剂。
2、本发明中，提供的纺丝油剂各项性能较好，与现有的纺丝油剂相比断裂伸长率增大，断裂伸长率变异系数降低，弹性回复率升高， 沸水收缩率降低，性能与现有纺丝油剂相比有了明显提高。
3、本发明中，油剂的制备方法工艺简单易操作，原料易得，生产过程安全可靠，生产过程中挥发损失少，适合工业化大量生产。
具体实施方式
为了使本发明的目的、技术方案及优点更加清楚明白，以下结合实施例，对本发明进行进一步详细说明。应当理解，此处所描述的具体实施例仅用以解释本发明，并不用于限定本发明。
实施例一，一种天丝纤维织造用绿色环保型油剂，包括如下成分组成：平滑剂、乳化剂、抗静电剂、集束剂、防腐剂、渗透剂、表面活性剂和去离子水。各成分质量分数为：平滑剂22%，乳化剂10%，抗静电剂5%，集束剂15%，防腐剂0.01%，渗透剂1%，表面活性剂15%，余量的去离子水；
所述平滑剂选用矿物油；所述乳化剂选用聚丙烯酰胺；所述抗静电剂为十八烷基二甲基羟乙基季铵硝酸盐与β-烷基磺酸盐的混合物；所述表面活性剂包括非离子表面活性剂与阴离子表面活性剂，非离子表面活性剂选用Tween 80，阴离子表面活性剂选用烷基苯磺酸盐。
所述的一种天丝纤维织造用绿色环保型油剂的制备方法，包括如下步骤：
步骤1：将平滑剂、抗静电剂、表面活性剂和渗透剂以及三分之二分量的去离子水加入反应釜中，升温至50℃，加压26Pa，进行搅拌30min；
步骤2：将步骤1产物进行泄压降温至室温后，加入乳化剂、集束剂和防腐剂以及剩余分量的去离子水，常压状态下，降温至8℃，搅拌混合，混合后静置10min，匀速增压至32Pa，再搅拌，搅拌速度180r/min，搅拌时间45min，静置12min，然后再降温搅拌和增压搅拌循环两次；
步骤3：测试步骤2产物的pH值，并使用pH调节剂，调节至7，然后检查油剂是否合格；
步骤4：油剂冷却后，灌装油桶内即完成制备。
检查油剂是否合格，具体为，加热油剂至80℃，轻微搅拌，查看是否有泡沫产生以及是否油剂变稠，是则为不合格，空冷后降温至-3℃，轻微搅拌，查看油剂是否有凝结现象以及是否有析出物，有则为不合格。
实施例二，一种天丝纤维织造用绿色环保型油剂，包括如下成分组成：平滑剂、乳化剂、抗静电剂、集束剂、防腐剂、渗透剂、表面活性剂和去离子水。各成分质量分数为：平滑剂30%，乳化剂5%，抗静电剂10%，集束剂10%，防腐剂3%，渗透剂0.05%，表面活性剂30%，余量的去离子水；
所述平滑剂选用油酸脂；所述乳化剂选用脂肪胺盐；所述抗静电剂为烷基胺与高碳醇聚氧乙烯醚磷酸酯钾盐的混合物；所述表面活性剂包括非离子表面活性剂与阴离子表面活性剂，非离子表面活性剂选用Tween 80，阴离子表面活性剂选用烷基苯磺酸盐。
所述的一种天丝纤维织造用绿色环保型油剂的制备方法，包括如下步骤：
步骤1：将平滑剂、抗静电剂、表面活性剂和渗透剂以及三分之二分量的去离子水加入反应釜中，升温至60℃，加压20Pa，进行搅拌42min；
步骤2：将步骤1产物进行泄压降温至室温后，加入乳化剂、集束剂和防腐剂以及剩余分量的去离子水，常压状态下，降温至5℃，搅拌混合，混合后静置13min，匀速增压至30Pa，再搅拌，搅拌速度220r/min，搅拌时间35min，静置15min，然后再降温搅拌和增压搅拌循环两次；
步骤3：测试步骤2产物的pH值，并使用pH调节剂，调节至5，然后检查油剂是否合格；
步骤4：油剂冷却后，灌装油桶内即完成制备。
检查油剂是否合格，具体为，加热油剂至90℃，轻微搅拌，查看是否有泡沫产生以及是否油剂变稠，是则为不合格，空冷后降温至-2℃，轻微搅拌，查看油剂是否有凝结现象以及是否有析出物，有则为不合格。
实施例三，一种天丝纤维织造用绿色环保型油剂，包括如下成分组成：平滑剂、乳化剂、抗静电剂、集束剂、防腐剂、渗透剂、表面活性剂和去离子水。各成分质量分数为：平滑剂25%，乳化剂7%，抗静电剂6%，集束剂12%，防腐剂1.8%，渗透剂0.7%，表面活性剂22%，余量的去离子水；
所述平滑剂选用脂肪酸酯；所述乳化剂选用聚甘油酯；所述抗静电剂为环氧乙烷浓缩物与异构醇聚氧乙烯醚磷酸酯钾盐的混合物；所述表面活性剂包括非离子表面活性剂与阴离子表面活性剂，非离子表面活性剂选用Tween 80，阴离子表面活性剂选用烷基苯磺酸盐。
所述的一种天丝纤维织造用绿色环保型油剂的制备方法，包括如下步骤：
步骤1：将平滑剂、抗静电剂、表面活性剂和渗透剂以及三分之二分量的去离子水加入反应釜中，升温至55℃，加压23Pa，进行搅拌37min；
步骤2：将步骤1产物进行泄压降温至室温后，加入乳化剂、集束剂和防腐剂以及剩余分量的去离子水，常压状态下，降温至6℃，搅拌混合，混合后静置12min，匀速增压至31Pa，再搅拌，搅拌速度190r/min，搅拌时间39min，静置13min，然后再降温搅拌和增压搅拌循环两次；
步骤3：测试步骤2产物的pH值，并使用pH调节剂，调节至7，然后检查油剂是否合格；
步骤4：油剂冷却后，灌装油桶内即完成制备。
检查油剂是否合格，具体为，加热油剂至87℃，轻微搅拌，查看是否有泡沫产生以及是否油剂变稠，是则为不合格，空冷后降温至-2℃，轻微搅拌，查看油剂是否有凝结现象以及是否有析出物，有则为不合格。
以上所述仅为本发明的较佳实施例而已，并不用以限制本发明，凡在本发明的精神和原则之内所作的任何修改、等同替换和改进等，均应包含在本发明的保护范围之内。

Claims (7)

1.一种天丝纤维织造用绿色环保型油剂，其特征在于,包括如下成分组成：平滑剂、乳化剂、抗静电剂、集束剂、防腐剂、渗透剂、表面活性剂和去离子水，各成分质量分数为：平滑剂22～30%，乳化剂5～10%，抗静电剂5～10%，集束剂10～15%，防腐剂0.01～3%，渗透剂0.05～1%，表面活性剂15～30%，余量的去离子水。
2.如权利要求1所述的一种天丝纤维织造用绿色环保型油剂，其特征在于,所述平滑剂包括矿物油、油酸脂、动物脂肪酸酯、植物脂肪酸酯中的任意一种或几种。
3.如权利要求1所述的一种天丝纤维织造用绿色环保型油剂，其特征在于,所述乳化剂包括聚丙烯酰胺、脂肪胺盐、聚甘油酯中的任意一种或几种。
4.如权利要求1所述的一种天丝纤维织造用绿色环保型油剂，其特征在于,所述抗静电剂为十八烷基二甲基羟乙基季铵硝酸盐、烷基胺与环氧乙烷浓缩物中的任意一种与β-烷基磺酸盐、高碳醇聚氧乙烯醚磷酸酯钾盐、异构醇聚氧乙烯醚磷酸酯钾盐中任意一种的混合。
5.如权利要求1所述的一种天丝纤维织造用绿色环保型油剂，其特征在于,所述表面活性剂包括非离子表面活性剂与阴离子表面活性剂，非离子表面活性剂选用Tween 80，阴离子表面活性剂选用烷基苯磺酸盐。
6.如权利要求1～5任一所述的一种天丝纤维织造用绿色环保型油剂的制备方法，其特征在于,包括如下步骤：
步骤1：将平滑剂、抗静电剂、表面活性剂和渗透剂以及三分之二分量的去离子水加入反应釜中，升温至50～60℃，加压20～26Pa，进行搅拌30～42min；
步骤2：将步骤1产物进行泄压降温至室温后，加入乳化剂、集束剂和防腐剂以及剩余分量的去离子水，常压状态下，降温至5～8℃，搅拌混合，混合后静置10～13min，匀速增压至30～32Pa，再搅拌，搅拌速度180～220r/min，搅拌时间35～45min，静置12～15min，然后再降温搅拌和增压搅拌循环两次；
步骤3：测试步骤2产物的pH值，并使用pH调节剂，调节至5～7，然后检查油剂是否合格；
步骤4：油剂冷却后，灌装油桶内即完成制备。
7.如权利要求6所述的一种天丝纤维织造用绿色环保型油剂的制备方法，其特征在于,所述检查油剂是否合格，具体为，加热油剂至80～90℃，轻微搅拌，查看是否有泡沫产生以及是否油剂变稠，是则为不合格，空冷后降温至-2～-3℃，轻微搅拌，查看油剂是否有凝结现象以及是否有析出物，有则为不合格。
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