WO2016158790A1 - 樹脂用改質剤およびこれを用いた樹脂組成物 - Google Patents
樹脂用改質剤およびこれを用いた樹脂組成物 Download PDFInfo
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L5/00—Compositions of polysaccharides or of their derivatives not provided for in groups C08L1/00 or C08L3/00
- C08L5/10—Heparin; Derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
- C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/91—Polymers modified by chemical after-treatment
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/08—Cellulose derivatives
- C08L1/10—Esters of organic acids, i.e. acylates
- C08L1/14—Mixed esters, e.g. cellulose acetate-butyrate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K3/00—Materials not provided for elsewhere
- C09K3/10—Materials in mouldable or extrudable form for sealing or packing joints or covers
- C09K3/1006—Materials in mouldable or extrudable form for sealing or packing joints or covers characterised by the chemical nature of one of its constituents
- C09K3/1015—Polysaccharides or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
Definitions
- the present invention relates to a resin modifier (hereinafter, also simply referred to as “modifier”) and a resin composition using the same. Specifically, the resin has excellent moisture resistance, dimensional stability, optical properties, The present invention relates to a resin modifier capable of imparting water and a resin composition using the same.
- resin films such as cellulose acylate, polycarbonate, polyacrylate, and polyolefin have been used mainly for polarizing plate protective films for liquid crystal display devices and optical compensation films.
- cellulose acylate films are widely used because they have excellent bonding properties to polyvinyl alcohol used in polarizers, have high transparency, and have appropriate strength.
- the cellulose acylate film has high moisture permeability, there is a drawback in that peeling from the polarizer or deterioration of the polarizer itself is caused by transmission of external moisture. Further, under high temperature and high humidity, there were also problems with the shrinkage of the polarizing plate protective film and the optical compensation film due to moisture absorption (dimensional stability) and the phase difference fluctuation (optical characteristics) involved in visibility. In recent years, with the thinning of liquid crystal display devices, the polarizing plate protective film and the optical compensation film have been made thinner, and higher moisture resistance, dimensional stability, and optical characteristics have been demanded.
- Patent Document 1 a cellulose ester resin comprising a polyester composed of a divalent alcohol and a dibasic acid, which does not contain an aromatic ring, and gives a high retardation value to a film composed of a cellulose ester resin.
- Additives have been proposed.
- Patent Document 2 proposes an additive for cellulose ester resin, which is made of an ester compound that is excellent in bleed resistance under high temperature and high humidity and hardly volatilizes in the production process.
- Patent Document 1 discloses that it is desired that the water vapor transmission rate is low, but no specific improvement has been studied.
- Patent Document 2 dimensional stability has not been studied, and the moisture permeability has not been sufficiently satisfactory.
- the present condition is that the modifier which can satisfy all of moisture proof performance, dimensional stability, and an optical characteristic has not been found until now.
- an object of the present invention is to provide a modifier for a resin capable of imparting excellent moisture resistance, dimensional stability and optical properties to the resin, and a resin composition using the same.
- the resin modifier of the present invention has the following general formula (1), (In the formula (1), m represents an integer of 1 to 5, n represents an integer of 0 to 50, and R A , R B and R C represent a hydrocarbon group having 2 to 20 carbon atoms, oxygen atom, sulfur A hydrocarbon group having 2 to 20 carbon atoms having one or more atoms selected from the group consisting of an atom and a nitrogen atom).
- R A , R B and R C in the compound represented by the general formula (1) are a hydrocarbon group having 2 to 12 carbon atoms, an oxygen atom or a sulfur atom. And a hydrocarbon group having 2 to 12 carbon atoms having one or more atoms selected from the group consisting of nitrogen atoms.
- the modifier for resin of this invention is suitable for using for a thermoplastic resin, and is especially suitable for a cellulose resin.
- the resin composition of the present invention is characterized by containing the resin modifier of the present invention.
- the present invention it is possible to provide a resin modifier that can impart excellent moisture resistance, dimensional stability, and optical properties to a resin, and a resin composition using the same.
- the resin modifier of the present invention has the following general formula (1), It can contain the compound represented by these, and can provide the moisture-proof property, dimensional stability, and optical characteristic which were excellent with respect to resin.
- m is an integer of 1 to 5, preferably 1 to 3, and more preferably 1.
- m is 3, it is preferable to have hydroxyl groups at positions 3, 4 and 5 on the aromatic ring, and when m is 2, there should be hydroxyl groups at positions 3 and 5 on the aromatic ring.
- m is 1, it is more preferable that a hydroxyl group is present at the 4-position on the aromatic ring.
- n is an integer of 0 to 50, preferably 0 to 30, and more preferably 0 to 20.
- the method for producing the resin modifier of the present invention is not particularly limited.
- divalent acid components such as succinic acid and terephthalic acid, anhydrides of these acid components, and acid chlorides such as ethylene glycol and propylene glycol are used.
- a glycol component and a monovalent acid component such as p-hydroxybenzoic acid are charged in a batch or divided in the presence or absence of a catalyst, and an esterification reaction or a transesterification reaction is performed.
- the compound represented by the general formula (1) can be obtained.
- the resulting compound has a molecular weight distribution.
- the modifier for resin of the present invention may be a mixture of compounds having a molecular weight distribution or a single product purified by distillation or the like, but a mixture of compounds having a molecular weight distribution is preferable from the viewpoint of economy. .
- the hydrocarbon group having 2 to 20 carbon atoms, preferably 2 to 12 carbon atoms represented by R A , R B and R C is, for example, carbon A linear or branched alkylene group having 2 to 20 atoms, a linear or branched alkenylene group, a cycloalkylene group which may have a linear or branched substituent, a linear or branched group
- a linear or branched alkylene group or an arylene group is preferable, a linear or branched alkylene group or an arylene group having 2 to 12 carbon atoms is more preferable, an ethylene group, an n-propylene group, Isopropylene group, n-butylene group, isobutylene group, n-pentylene group, isopentylene group, n-hexylene group, isohexylene group, n-heptylene group, isoheptylene group, n-octylene group, isooctylene group, n- Nonylene group, isononylene group, n-decylene group, isodecylene group, n-undecylene group, isoundecylene group, n-dodecylene group, isododecylene group, phenylene group, naphthylene group are more preferable, ethylene group,
- the hydrocarbon groups of R A , R B and R C are one or more selected from the group consisting of an oxygen atom, a sulfur atom and a nitrogen atom.
- the hydrocarbon group may be substituted with an atom, and as a hydrocarbon group having 2 to 20 carbon atoms, preferably 2 to 12 carbon atoms, one or more hydrogen atoms are substituted with a substituent having an oxygen atom, a sulfur atom, or a nitrogen atom. And the case where one or more carbon atoms are substituted with an oxygen atom, a sulfur atom, or a nitrogen atom.
- Examples of the case where one or more hydrogen atoms are substituted with a substituent having an oxygen atom, a sulfur atom, or a nitrogen atom include a hydroxy group, an alkoxy group, an aryloxy group, an acyl group, a carbonyl group, and a carboxy group. .
- R A and R C are preferably diethyl ether-1,1′-diyl.
- R B is preferably an ethylene group, an n-propylene group, or a phenylene group.
- n pieces is R A, R B and R C may be be the same or different.
- the molecular weight is not particularly limited, but from the viewpoint of compatibility with the resin and moisture-proof performance, the number average molecular weight is preferably 350 to 5,000, more preferably 350 to 2,000, More preferably, it is 350 to 1,500.
- the number average molecular weight can be measured using gel permeation chromatography (GPC).
- the blending amount of the resin modifier of the present invention is not particularly limited, but is preferably 0.1 to 100 parts by weight, preferably 0.5 to 80 parts by weight, and more preferably 1 to 50 parts by weight with respect to 100 parts by weight of the resin. 1 to 30 parts by mass is more preferable. If the amount is less than 0.1 parts by mass, performance such as moisture resistance, dimensional stability, optical characteristics (phase difference fluctuation value) may not be sufficiently exhibited, and if it exceeds 100 parts by mass, bleeding may occur.
- the modifier for resin represented by the general formula (1) of the present invention is exemplified, but the present invention is not limited thereto.
- the parentheses in the modifiers A to Q for resin indicate a molar ratio, and these compounds may be used alone or in combination of two or more.
- the resin composition of the present invention contains the resin modifier of the present invention and has excellent moisture resistance, dimensional stability, and optical properties.
- resin used for the resin composition of this invention is not specifically limited, For example, although a thermoplastic resin and a thermosetting resin are mentioned, it can use suitably for a thermoplastic resin.
- thermoplastic resin examples include polyvinyl chloride resin, polyethylene resin, polypropylene resin, polystyrene resin, polyvinyl acetate resin, polyurethane resin, cellulose resin, acrylic resin, AS (acrylonitrile-styrene) resin, ABS (acrylonitrile-butadiene).
- -Styrene) resin fluorine resin, thermoplastic elastomer, polyamide resin, polyacetal resin, polycarbonate resin, modified polyphenylene ether resin, polyethylene terephthalate resin, polybutylene terephthalate resin, polylactic acid resin, cyclic polyolefin resin, polyphenylene sulfide resin, etc. These resins may be used alone or in combination of two or more.
- polyvinyl chloride resin examples include homopolymers such as polyvinyl chloride and polyvinylidene chloride, and vinyl compound copolymers such as vinyl chloride or a copolymer of vinylidene chloride and vinyl acetate. These may be used alone or in combination of two or more.
- polyethylene resin examples include low density polyethylene, medium density polyethylene, and high density polyethylene. These may be used alone or in combination of two or more.
- the polymerization method is not particularly limited, and examples thereof include homopolymers, random polymers, block polymers and the like, and these may be used alone or in combination of two or more.
- cellulose resins include cellophane, celluloid, cellulose acetate, cellulose diacetate, cellulose triacetate, cellulose propionate, cellulose acetate propionate, cellulose acetate butyrate, methyl acetate, ethyl cellulose, carboxymethyl cellulose, hydroxyethyl cellulose, hydroxy Examples thereof include propylcellulose, ethylhydroxyethylcellulose, carboxymethylethylrose and the like. These may be used alone or in combination of two or more.
- acrylic resin examples include polymethyl acrylate and polymethyl methacrylate. These may be used alone or in combination of two or more.
- polyamide resin examples include aliphatic polyamides such as nylon-6, nylon-66, nylon-10, nylon-12, and nylon-46, and aromatic polyamides produced from aromatic dicarboxylic acids and aliphatic diamines. It is done. These may be used alone or in combination of two or more.
- polyacetal resin examples include polyformaldehyde, polyacetaldehyde, polypropionaldehyde, polybutyraldehyde, and the like. These may be used alone or in combination of two or more.
- a cellulose resin is more preferable, and a lower fatty acid ester of cellulose is more preferable.
- the lower fatty acid in the lower fatty acid ester of cellulose means a fatty acid having 6 or less carbon atoms.
- Examples of the lower fatty acid ester of cellulose include, for example, cellulose acetate, cellulose propionate, cellulose butyrate and the like, JP-A-10-45804, JP-A-8-231761, and US Pat. No. 2,319,052.
- Examples thereof include mixed fatty acid esters such as cellulose acetate propionate and cellulose acetate butyrate as described in the literature.
- plasticizers and various other additives such as phenol-based or sulfur-based antioxidants, ultraviolet absorbers, hindered amine light Stabilizers, polyols, other inorganic compounds, and the like can also be blended. These plasticizers and various additives may be used alone or in combination of two or more.
- plasticizer examples include dibutyl phthalate, butyl hexyl phthalate, diheptyl phthalate, di- (2-ethylhexyl) phthalate, diisononyl phthalate, diisodecyl phthalate, dilauryl phthalate, dicyclohexyl phthalate, dioctyl terephthalate and the like; Adipate plasticizers such as adipate, diisononyl adipate, diisodecyl adipate, di (butyl diglycol) adipate; triphenyl phosphate, tricresyl phosphate, trixylenyl phosphate, tri (isopropylphenyl) phosphate, triethyl phosphate, tributyl phosphate, tri Octyl phosphate, tri (butoxyethyl) phosphate, octyl diphenyl phosphate P
- polyester plasticizer other than the resin modifier according to the present invention are exemplified by the plasticizers 1 to 13, but are not limited thereto, and these compounds may be used alone. Well, two or more types may be used as a mixture.
- polyester plasticizers 1 to 4 the molar ratio is shown, and these polyester plasticizers may be used alone or in combination of two or more.
- Plasticizer-5 the following general formula (3), A compound in which all of the substituents Q A in FIG.
- Plasticizer-6 A compound of the above general formula (3) in which all the substituents Q A are methoxy groups.
- the content of these plasticizers can be blended within a range that does not impair the effects of the present invention, but is preferably 1 to 90 parts by weight, and more preferably 10 to 80 parts by weight with respect to 100 parts by weight of the resin.
- phenolic antioxidants examples include 2,6-ditert-butyl-p-cresol, 2,6-diphenyl-4-octadecyloxyphenol, stearyl (3,5-ditert-butyl-4-hydroxy). Phenyl) propionate, distearyl (3,5-ditert-butyl-4-hydroxybenzyl) phosphonate, tridecyl 3,5-ditert-butyl-4-hydroxybenzylthioacetate, thiodiethylenebis [(3,5- Di-tert-butyl-4-hydroxyphenyl) propionate], 4,4′-thiobis (6-tert-butyl-m-cresol), 2-octylthio-4,6-di (3,5-di-tert-butyl- 4-hydroxyphenoxy) -s-triazine, 2,2′-methylenebis (4-methyl-6-tert-butylphenol), bis [3,3-bi (4-Hydroxy-3-ter
- the content of these phenolic antioxidants can be blended within a range that does not impair the effects of the present invention, but is preferably 0.01 to 1 part by weight, preferably 0.03 to 0 parts by weight based on 100 parts by weight of the resin. More preferably, 8 parts by mass.
- sulfur-based antioxidants examples include dialkylthiodipropionates such as dilauryl, dimyristyl, myristylstearyl, and distearyl esters of thiodipropionic acid, and polyols such as pentaerythritol tetra ( ⁇ -dodecylmercaptopropionate). and ⁇ -alkyl mercaptopropionic acid esters.
- the content of these sulfur-based antioxidants can be blended within a range that does not impair the effects of the present invention, but is preferably 0.01 to 1 part by weight, preferably 0.03 to 0 parts per 100 parts by weight of the resin. More preferably, 8 parts by mass.
- Examples of the ultraviolet absorber include 2,4-dihydroxybenzophenone, 2-hydroxy-4-methoxybenzophenone, 2-hydroxy-4-octoxybenzophenone, 2-hydroxy-4-tert-butyl-4 ′-(2- 2-hydroxybenzophenones such as methacryloyloxyethoxyethoxy) benzophenone and 5,5′-methylenebis (2-hydroxy-4-methoxybenzophenone); 2- (2-hydroxy-5-methylphenyl) benzotriazole, 2- (2 -Hydroxy-5-tert-octylphenyl) benzotriazole, 2- (2-hydroxy-3,5-ditert-butylphenyl) -5-chlorobenzotriazole, 2- (2-hydroxy-3-tert-butyl- 5-methylphenyl) -5-chlorobenzotriazole, 2 (2-hydroxy-3-dodecyl-5-methylphenyl) benzotriazole, 2- (2-hydroxy-3-tert-butyl-5-
- hindered amine light stabilizer examples include 2,2,6,6-tetramethyl-4-piperidyl stearate, 1,2,2,6,6-pentamethyl-4-piperidyl stearate, 2,2,6. , 6-tetramethyl-4-piperidylbenzoate, bis (2,2,6,6-tetramethyl-4-piperidyl) sebacate, bis (1,2,2,6,6-pentamethyl-4-piperidyl) sebacate, Bis (1-octoxy-2,2,6,6-tetramethyl-4-piperidyl) sebacate, tetrakis (2,2,6,6-tetramethyl-4-piperidyl) -1,2,3,4-butane Tetracarboxylate, tetrakis (1,2,2,6,6-pentamethyl-4-piperidyl) -1,2,3,4-butanetetracarboxylate, bis (2,2, , 6-tetramethyl-4-piperidyl) .bis (tridecyl
- the content of these hindered amine light stabilizers can be blended within a range that does not impair the effects of the present invention, but is preferably 0.01 to 1 part by weight, preferably 0.03 to 0 parts per 100 parts by weight of the resin. More preferably, 8 parts by mass.
- polyols examples include trimethylolpropane, ditrimethylolpropane, pentaerythritol, dipentaerythritol, polypentaerythritol, pentaerythritol or dipentaerythritol stearic acid half ester, bis (dipentaerythritol) adipate, glycerin, tris ( 2-hydroxyethyl) isocyanurate, sorbitol, mannitol, lactitol and the like.
- the content of these polyols can be blended within a range that does not impair the effects of the present invention, but is preferably 0.01 to 2 parts by weight, and 0.01 to 1 part by weight with respect to 100 parts by weight of the resin. More preferred.
- Examples of other inorganic compounds include calcium silicate, calcium phosphate, calcium oxide, calcium hydroxide, magnesium silicate, magnesium phosphate, magnesium oxide, and magnesium hydroxide.
- the content of other inorganic compounds can be blended within a range not impairing the effects of the present invention, but is preferably 0.01 to 5 parts by weight, and 0.03 to 3 parts by weight with respect to 100 parts by weight of the resin. Is more preferable.
- the resin composition of the present invention may further include other additives as necessary, for example, fillers, colorants, crosslinking agents, antistatic agents, antifogging agents, plate-out preventing agents, surface treatment agents, lubricants. , Flame retardant, Fluorescent agent, Antifungal agent, Bactericidal agent, Metal deactivator, Release agent, Pigment, Processing aid, Foaming agent, Organic acid metal salt, Hydrotalcite compound, Zinc-modified hydrotalcite, Zeolite A compound etc. can also be mix
- the resin composition of the present invention is characterized by containing a resin modifier represented by the above general formula (1), and its blending method and molding method are not particularly limited. Examples include a method of mixing with a blender, a mixer, etc., a method of melt-kneading with an extruder, etc., a method of mixing with a solvent and casting a solution, and the molding methods include extrusion molding, injection molding, stretched film molding, blow molding. Etc.
- the shape of the molded body obtained by molding the resin composition of the present invention is not particularly limited, and examples thereof include a sheet shape, a film shape, and a special shape.
- the use of the obtained molded body is not particularly limited.
- Examples 1 to 17 and Comparative Examples 1 to 14> Using the resin modifiers shown in Tables 1 and 2 below, moisture resistance (moisture permeability), optical properties (phase difference variation), and dimensional stability were evaluated according to the following procedures. The obtained results are also shown in the table. The number average molecular weight was measured according to the following procedure.
- Resin modifiers A to Q of the present invention or Comparative compounds 1 to 14 are dissolved in tetrahydrofuran (THF) to prepare a 0.5 mass% sample solution, and the following using gel permeation chromatography (GPC). The number average molecular weight was measured under the conditions.
- a calibration curve was prepared using polystyrene (molecular weight standard manufactured by GL Sciences: molecular weight 162, 370, 580, 1000, 2000, 3000, 5000).
- SHODEX KF-802 manufactured by Showa Denko KK was used as the column temperature was 40 ° C.
- THF was used as an eluent
- the flow rate was 1 ml / min
- a refractometer (RI) was used as a detector.
- ⁇ Moisture resistance 85 parts by mass of cellulose triacetate (degree of acetylation 61%, degree of polymerization 260) and 15 parts by mass of a modifier were dissolved uniformly in a mixed solvent consisting of 900 parts by mass of methylene chloride and 100 parts by mass of methyl alcohol while stirring.
- Various dope solutions for evaluation and film preparation were prepared. Next, the obtained dope solution was cast on a glass plate so as to have a thickness of about 80 ⁇ m, dried at room temperature for 16 hours, dried at 50 ° C. for 1 hour, further dried at 120 ° C. for 1 hour, and various evaluations. A film was obtained. The film thicknesses of the obtained films were all about 80 ⁇ m.
- the moisture permeability of the obtained film was measured according to the method described in JIS Z 0208.
- the measurement conditions are 40 ° C. and relative humidity 80%.
- the moisture permeability indicates that the smaller the numerical value, the better the moisture resistance.
- the moisture proof performance indicates that the moisture permeability is not more than 360 g / m 2 / day as the performance.
- the obtained evaluation results are shown in Table 1 and Table 2 below.
- Various dope solutions for evaluation and film preparation were prepared.
- the obtained dope solution was cast on a glass plate so as to have a thickness of about 80 ⁇ m, dried at room temperature for 16 hours, dried at 50 ° C. for 1 hour, further dried at 120 ° C. for 1 hour, and various evaluations.
- a film was obtained. The film thicknesses of the obtained films were all about 80 ⁇ m.
- phase difference fluctuation value Phase difference at drying-Phase difference at high temperature and high humidity
- Various dope solutions for evaluation and film preparation were prepared.
- the obtained dope solution was cast on a glass plate so as to have a thickness of about 80 ⁇ m, dried at room temperature for 16 hours, dried at 50 ° C. for 1 hour, further dried at 120 ° C. for 1 hour, and various evaluations.
- a film was obtained. The film thicknesses of the obtained films were all about 80 ⁇ m.
- the obtained film was allowed to stand for 24 hours in an environment of 40 ° C. and a relative humidity of 80%, visually confirmed, and evaluated in three stages according to the following criteria. Excellent: No distortion of the film is confirmed. Good: The film is confirmed to be slightly distorted. No: The dimensional stability performance in which the film is confirmed to be largely distorted is excellent. It shows that.
- the obtained evaluation results are shown in Table 1 and Table 2 below.
- the retardation in the thickness direction of the film was measured using an automatic birefringence meter RETS-100 (manufactured by Otsuka Electronics Co., Ltd.) according to the following formula at 25 ° C. and a relative humidity of 60% at a wavelength of 590 nm.
- Thickness direction retardation ⁇ (nx + ny) / 2 ⁇ nz ⁇ ⁇ d
- nx is the refractive index in the direction with the largest refractive index in the film plane
- ny is the refractive index in the film plane in the direction perpendicular to nx
- nz is the refractive index in the thickness direction of the film
- d It represents the thickness (nm) of the film.
- Table 1 and Table 2 The obtained evaluation results are shown in Table 1 and Table 2 below.
- Comparative compound 1 Triphenyl phosphate Comparative compound 2: Unblocked product at both ends of a condensate consisting of succinic acid (50) / terephthalic acid (50) / ethylene glycol (100) (number average molecular weight: 670) Comparative compound 3: Condensate obtained by substituting 1,2-propylene glycol for ethylene glycol of comparative compound 2 (number average molecular weight: 1000) Comparative compound 4: Condensate of comparative compound 2 (number average molecular weight: 1400) Comparative compound 5: benzoic acid ester at both ends of a condensate consisting of succinic acid (50) / terephthalic acid (50) / ethylene glycol (100) (number average molecular weight: 450) Comparative compound 6: benzoic acid ester at both ends of a condensate consisting of succinic acid (50) / terephthalic acid (50) / 1,2-propylene glycol (
- the modifier of the present invention satisfies all of moisture resistance (moisture permeability), dimensional stability, and optical characteristics (phase difference fluctuation value), whereas the comparative compound is moisture proof.
- the optical properties are poor even if the properties are good, and in some cases the moisture resistance and the optical properties are poor even if the dimensional stability is good. Therefore, it is clear that the present invention is an excellent resin modifier that balances moisture resistance, dimensional stability, and optical properties.
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Abstract
Description
(式(1)中、mは1~5の整数、nは0~50の整数を表し、RA、RBおよびRCは炭素原子数2~20の炭化水素基または、酸素原子、硫黄原子、窒素原子からなる群より選択される1つ以上の原子を有する炭素原子数2~20の炭化水素基を表す)で表される化合物を含有することを特徴とするものである。
本発明の樹脂用改質剤は、下記一般式(1)、
で表される化合物を含有するものであり、樹脂に対して優れた防湿性、寸法安定性、光学特性、を付与することができる。ここで、上記式(1)中、mは1~5の整数であり、1~3が好ましく、1がより好ましい。mが3の場合は、芳香環上の3位、4位、5位にヒドロキシル基があることが好ましく、mが2の場合は、芳香環上の3位、5位にヒドロキシル基があることが好ましく、mが1の場合は、芳香環上の4位にヒドロキシル基があることがより好ましい。
改質剤B:コハク酸(50)/テレフタル酸(50)/1,2-プロピレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:880、nが0の化合物の割合:15質量%)
改質剤C:コハク酸(50)/テレフタル酸(50)/1,2-プロピレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:650、nが0の化合物の割合:20質量%)
改質剤D:コハク酸(50)/テレフタル酸(50)/エチレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:570、nが0の化合物の割合:23質量%)
改質剤E:コハク酸(30)/テレフタル酸(70)/1,2-プロピレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:740、nが0の化合物の割合:17質量%)
改質剤F:コハク酸(30)/テレフタル酸(70)/1,3-ブチレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:660、nが0の化合物の割合:20質量%)
改質剤G:コハク酸(5)/テレフタル酸(95)/1,2-プロピレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:1190、nが0の化合物の割合:10質量%)
改質剤H:コハク酸(100)/1,2-プロピレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:650、nが0の化合物の割合:29質量%)
改質剤I:テレフタル酸(100)/1,3-ブチレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:700、nが0の化合物の割合:23質量%)
改質剤J:コハク酸(50)/テレフタル酸(50)/エチレングリコール(50)/1,2-プロピレングリコール(50)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:550、nが0の化合物の割合:24質量%)
改質剤K:コハク酸(50)/テレフタル酸(50)/1,3-ブチレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:670、nが0の化合物の割合:27質量%)
改質剤L:フタル酸(100)/1,2-プロピレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:640、nが0の化合物の割合:30質量%)
改質剤M:テレフタル酸(100)/1,2-プロピレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:640、nが0の化合物の割合:24質量%)
改質剤N:コハク酸(50)/テレフタル酸(50)/1,2-プロピレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:490、nが0の化合物の割合:39質量%)
改質剤O:コハク酸(50)/テレフタル酸(50)/エチレングリコール(10)/ジエチレングリコール(90)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:410、nが0の化合物の割合:51質量%)
改質剤P:テレフタル酸(100)/エチレングリコール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:370、nが0の化合物の割合:39質量%)
改質剤Q:コハク酸(50)/テレフタル酸(50)/1,6-ヘキサンジオール(100)からなる縮合物の両末端p-ヒドロキシ安息香酸エステル体(数平均分子量:390、nが0の化合物の割合:54質量%)
の、多価アルコール成分Gとして、エチレングリコール(50)および1,2-プロピレングリコール(50)と、多価カルボン酸成分Aとして、コハク酸(50)およびテレフタル酸(50)、末端Eがアセチル基からなるn=5の化合物。
可塑剤-2:上記一般式(2)の、多価アルコール成分Gとして、1,2-プロピレングリコールと、多価カルボン酸成分Aとして、2,6-ナフタレンジカルボン酸、末端Eが水素からなるn=2の化合物。
可塑剤-3:上記一般式(2)の、多価アルコール成分Gとして、エチレングリコールと、多価カルボン酸成分Aとして、アジピン酸、末端Eがアセチル基からなるn=10の化合物。
可塑剤-4:上記一般式(2)の、多価アルコール成分Gとして、1,2-プロピレングリコールと、多価カルボン酸成分Aとして、テレフタル酸、末端Eがトルイル基からなるn=5の化合物。
可塑剤-5:下記一般式(3)、
の置換基QAが全て水素原子である化合物。
可塑剤-6:上記一般式(3)の、置換基QAが全てメトキシ基である化合物。
可塑剤-7:
可塑剤-8:
可塑剤-9:
可塑剤-10:
可塑剤-11:
可塑剤-12:
可塑剤-13:
下記表1および2に示す樹脂用改質剤を用い、下記の手順にしたがって防湿性(透湿度)、光学特性(位相差変動値)および寸法安定性について評価を行った。得られた結果を、同表に併記する。なお、数平均分子量の測定は下記の手順で行った。
本発明の樹脂用改質剤A~Q、若しくは比較化合物1~14をテトラヒドロフラン(THF)に溶解し0.5質量%のサンプル溶液を調製し、ゲルパーミエーションクロマトグラフィー(GPC)を用いて下記条件で数平均分子量を測定した。なお、検量線はポリスチレン(ジーエルサイエンス製分子量スタンダード:分子量162、370、580、1000、2000、3000、5000)を用いて作成した。カラムは、昭和電工(株)製 SHODEX KF-802を用いた。カラム温度は40℃とし、溶離液としてTHFを用い、流量を1ml/分とし、検出器として屈折率計(RI)を用いて測定した。
セルローストリアセテート85質量部(酢化度61%、重合度260)、および改質剤15質量部を、メチレンクロライド900質量部とメチルアルコール100質量部とからなる混合溶剤に撹拌しながら均一に溶解させ、各種評価用およびフィルム作成用ドープ液を調製した。次いで、得られたドープ液をガラス板上に約80μmになるように流延し、室温で16時間乾燥させた後、50℃で1時間乾燥させ、さらに120℃で1時間乾燥させ、各種評価フィルムを得た。得られたフィルムの膜厚はいずれも約80μmであった。得られたフィルムを、JIS Z 0208に記載の方法に従い、透湿度を測定した。測定条件は40℃、相対湿度80%である。透湿度は、数値が小さい方が防湿性に優れていることを表す。防湿性能は、透湿度が360g/m2/day以下であることが性能として優れていることを示している。得られた評価結果を下記の表1および表2に併記する。
セルローストリアセテート90質量部(酢化度61%、重合度260)、および改質剤10質量部を、メチレンクロライド900質量部とメチルアルコール100質量部とからなる混合溶剤に撹拌しながら均一に溶解させ、各種評価用およびフィルム作成用ドープ液を調製した。次いで、得られたドープ液をガラス板上に約80μmになるように流延し、室温で16時間乾燥させた後、50℃で1時間乾燥させ、さらに120℃で1時間乾燥させ、各種評価フィルムを得た。得られたフィルムの膜厚はいずれも約80μmであった。得られたフィルムを、25℃、相対湿度15%環境下で48時間乾燥させ、乾燥後のフィルムの厚み方向の位相差を「乾燥時位相差」、その後同じフィルムを40℃、相対湿度80%、72時間置いた後のフィルムの厚み方向の位相差を「高温高湿時位相差」とし、「位相差変動値」を下記式から算出し、位相差変動値は絶対値で表す。位相差変動値は、数値が小さい程性能がよく、30以下であれば優れていることを示している。
|位相差変動値| = 乾燥時位相差-高温高湿時位相差
セルローストリアセテート85質量部(酢化度61%、重合度260)、および改質剤15質量部を、メチレンクロライド900質量部とメチルアルコール100質量部とからなる混合溶剤に撹拌しながら均一に溶解させ、各種評価用およびフィルム作成用ドープ液を調製した。次いで、得られたドープ液をガラス板上に約80μmになるように流延し、室温で16時間乾燥させた後、50℃で1時間乾燥させ、さらに120℃で1時間乾燥させ、各種評価フィルムを得た。得られたフィルムの膜厚はいずれも約80μmであった。得られたフィルムを、40℃相対湿度80%の環境下に24時間静置後、目視で確認し、下記基準で3段階評価を行なった。
優 :フィルムの歪みが確認されない
良 :フィルムが少し歪んでいることが確認された
不可:フィルムが大きく歪んでいることが確認された
寸法安定性能は、優および良であることが性能として優れていることを示している。得られた評価結果を下記の表1および表2に併記する。
厚み方向の位相差={(nx+ny)/2-nz}×d
ここで、式中、nxはフィルム面内の屈折率が最も大きい方向の屈折率、nyはnxに直角な方向でのフィルム面内の屈折率、nzはフィルムの厚み方向の屈折率、dはフィルムの厚み(nm)を表す。得られた評価結果を下記の表1および表2に併記する。
比較化合物2:コハク酸(50)/テレフタル酸(50)/エチレングリコール(100)からなる縮合物の両末端未封止体(数平均分子量:670)
比較化合物3:比較化合物2のエチレングリコールを1,2-プロピレングリコールに代替した縮合物(数平均分子量:1000)
比較化合物4:比較化合物2の縮合物(数平均分子量:1400)
比較化合物5:コハク酸(50)/テレフタル酸(50)/エチレングリコール(100)からなる縮合物の両末端安息香酸エステル体(数平均分子量:450)
比較化合物6:コハク酸(50)/テレフタル酸(50)/1,2-プロピレングリコール(100)からなる縮合物の両末端安息香酸エステル体(数平均分子量:450)
比較化合物7:比較化合物5の縮合物(数平均分子量:1050)
比較化合物8:コハク酸(30)/テレフタル酸(70)/1,2-プロピレングリコール(100)からなる縮合物の両末端安息香酸エステル体(数平均分子量:1050)
比較化合物9:コハク酸(50)/テレフタル酸(50)/エチレングリコール(100)からなる縮合物の両末端n-オクチル酸エステル体(数平均分子量:500)
比較化合物10:コハク酸(50)/テレフタル酸(50)/エチレングリコール(100)からなる縮合物の両末端酢酸エステル体(数平均分子量:1130)
比較化合物11:アジピン酸(100)/エチレングリコール(100)からなる縮合物の両末端安息香酸エステル体(数平均分子量:1300)
比較化合物12:テレフタル酸(100)/1,2-プロピレングリコール(100)からなる縮合物の両末端安息香酸エステル体(数平均分子量:480)
比較化合物13:テレフタル酸(100)/エチレングリコール(50)/1,2-プロピレングリコール(50)からなる縮合物の両末端p-tertブチル安息香酸エステル体(数平均分子量:500)
Claims (7)
- 前記一般式(1)で表される化合物の、RA、RBおよびRCは炭素原子数2~12の炭化水素基または、酸素原子、硫黄原子、窒素原子からなる群より選択される1つ以上の原子を有する炭素原子数2~12の炭化水素基である請求項1記載の樹脂用改質剤。
- 熱可塑性樹脂に用いられる請求項1項記載の樹脂用改質剤。
- 熱可塑性樹脂に用いられる請求項2項記載の樹脂用改質剤。
- 前記熱可塑性樹脂が、セルロース系樹脂である請求項3記載の樹脂用改質剤。
- 前記熱可塑性樹脂が、セルロース系樹脂である請求項4記載の樹脂用改質剤。
- 請求項1記載の樹脂用改質剤を含有することを特徴とする樹脂組成物。
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2016
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Cited By (12)
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JP2016204495A (ja) * | 2015-04-21 | 2016-12-08 | Dic株式会社 | セルロースエステル樹脂用改質剤、セルロースエステル樹脂組成物、光学フィルム及び液晶表示装置 |
JP2018507918A (ja) * | 2015-07-01 | 2018-03-22 | エルジー・ケム・リミテッド | コポリカーボネート樹脂及びその製造方法 |
WO2017098831A1 (ja) * | 2015-12-11 | 2017-06-15 | Dic株式会社 | セルロースエステル樹脂用改質剤、セルロースエステル樹脂組成物、光学フィルム及び液晶表示装置 |
JPWO2017098831A1 (ja) * | 2015-12-11 | 2018-09-27 | Dic株式会社 | セルロースエステル樹脂用改質剤、セルロースエステル樹脂組成物、光学フィルム及び液晶表示装置 |
WO2018061773A1 (ja) * | 2016-09-28 | 2018-04-05 | 株式会社Adeka | 樹脂用改質剤およびこれを用いた樹脂組成物 |
JP2018053049A (ja) * | 2016-09-28 | 2018-04-05 | 株式会社Adeka | 樹脂用改質剤およびこれを用いた樹脂組成物 |
WO2018230122A1 (ja) * | 2017-06-14 | 2018-12-20 | Dic株式会社 | エステル樹脂、反可塑化剤、セルロースエステル樹脂組成物、光学フィルム及び液晶表示装置 |
WO2018230123A1 (ja) * | 2017-06-14 | 2018-12-20 | Dic株式会社 | エステル樹脂、反可塑化剤、セルロースエステル樹脂組成物、光学フィルム及び液晶表示装置 |
JPWO2018230122A1 (ja) * | 2017-06-14 | 2019-11-07 | Dic株式会社 | エステル樹脂、反可塑化剤、セルロースエステル樹脂組成物、光学フィルム及び液晶表示装置 |
CN110753681A (zh) * | 2017-06-14 | 2020-02-04 | Dic株式会社 | 酯树脂、反增塑剂、纤维素酯树脂组合物、光学薄膜和液晶显示装置 |
CN110753681B (zh) * | 2017-06-14 | 2022-05-10 | Dic株式会社 | 酯树脂、反增塑剂、纤维素酯树脂组合物、光学薄膜和液晶显示装置 |
JPWO2020049947A1 (ja) * | 2018-09-03 | 2021-02-15 | Dic株式会社 | セルロースエステル樹脂用添加剤及びセルロースエステル組成物 |
Also Published As
Publication number | Publication date |
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CN107428923B (zh) | 2020-03-03 |
JPWO2016158790A1 (ja) | 2018-02-01 |
CN107428923A (zh) | 2017-12-01 |
US20180066105A1 (en) | 2018-03-08 |
EP3279233A4 (en) | 2018-09-26 |
TWI687472B (zh) | 2020-03-11 |
TW201700571A (zh) | 2017-01-01 |
US10208161B2 (en) | 2019-02-19 |
JP6692348B2 (ja) | 2020-05-13 |
KR20170133436A (ko) | 2017-12-05 |
EP3279233B1 (en) | 2020-07-08 |
EP3279233A1 (en) | 2018-02-07 |
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