WO2016088505A1 - Pile rechargeable rectangulaire - Google Patents

Pile rechargeable rectangulaire Download PDF

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Publication number
WO2016088505A1
WO2016088505A1 PCT/JP2015/081243 JP2015081243W WO2016088505A1 WO 2016088505 A1 WO2016088505 A1 WO 2016088505A1 JP 2015081243 W JP2015081243 W JP 2015081243W WO 2016088505 A1 WO2016088505 A1 WO 2016088505A1
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WIPO (PCT)
Prior art keywords
electrode group
plate
battery
secondary battery
electrode
Prior art date
Application number
PCT/JP2015/081243
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English (en)
Japanese (ja)
Inventor
修 久保田
貴宏 相馬
明秀 田中
Original Assignee
日立オートモティブシステムズ株式会社
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Application filed by 日立オートモティブシステムズ株式会社 filed Critical 日立オートモティブシステムズ株式会社
Publication of WO2016088505A1 publication Critical patent/WO2016088505A1/fr

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/463—Separators, membranes or diaphragms characterised by their shape
    • H01M50/466—U-shaped, bag-shaped or folded
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention relates to a prismatic secondary battery used for, for example, in-vehicle use.
  • an in-vehicle power source that supplies power to an electric motor or the like mounted on a vehicle such as an electric vehicle or a hybrid electric vehicle, or a square shape such as a lithium ion secondary battery having a high energy density as a power source for other devices. Secondary batteries are used.
  • a nonaqueous electrolyte battery includes, for example, a container, an electrode group housed in the container, and spirally wound via a separator between a positive electrode and a negative electrode, and a non-aqueous electrolyte housed in the container.
  • a water electrolyte is provided (see Patent Document 1 below).
  • the non-aqueous electrolyte battery described in Patent Document 1 has a problem in that the porosity of the positive and negative electrodes and the separator is lowered to ensure the discharge capacity, and the impregnation of the non-aqueous electrolyte into the positive and negative electrodes and the separator is deteriorated.
  • the nonaqueous electrolyte battery includes a tab electrically connected to a positive electrode or a negative electrode of an electrode group, and the electrode group so as to include an end surface opposite to an end surface to which the tab is connected, and the opposite side
  • the insulator which has an adhesive layer other than the location which opposes the end surface of this is comprised.
  • an insulating spacer and an insulating tape are attached to the flat wound electrode body, the positive electrode tab and the negative electrode tab are bent into predetermined shapes, respectively, and then the flat wound electrode body. Is inserted into a rectangular metal battery outer body whose one end surface in the longitudinal direction is open and whose peripheral surface is closed (see Patent Document 2 below).
  • JP 2010-73580 A International Publication No. 2012/090726
  • the nonaqueous electrolyte battery described in Patent Document 1 is coated with an insulator so as to include an end surface opposite to the end surface to which the tab of the electrode group is connected, so that insulation between the electrode group and the container is provided.
  • an insulator so as to include an end surface opposite to the end surface to which the tab of the electrode group is connected, so that insulation between the electrode group and the container is provided.
  • the insertion direction of the electrode group when the spirally wound electrode group is inserted into the opening of the battery exterior body is a direction along the winding center axis. Therefore, when the electrode group is inserted into the battery outer package, or after the electrode group is inserted into the battery outer package, the positive and negative electrodes and the separator are unwound along the winding central axis, and the end surface in the winding central axis direction is There is a risk of protruding in a so-called bowl shape. Such winding deviation cannot be prevented even if the end face of the electrode group is covered with a thin and flexible sheet-like insulator having no rigidity.
  • the nonaqueous electrolyte secondary battery described in Patent Document 2 has insulating spacers attached to both ends of the flat wound electrode group in the direction of the central axis of the winding, but the nonaqueous electrolyte secondary battery has both ends of the nonaqueous electrolyte secondary battery. The whole is covered with an insulating spacer. Therefore, the volume increase in the thickness direction of the battery is caused.
  • the present invention has been made in view of the above problems, and an object of the present invention is to provide a prismatic secondary battery that prevents an electrode group from being unwound and does not cause an increase in volume in the thickness direction of the battery. .
  • a prismatic secondary battery comprises a flat rectangular battery container, and positive and negative electrodes wound around a winding axis that is accommodated in the battery container and perpendicular to the bottom surface of the battery container. And a flat electrode group, wherein the electrode group is disposed between the bottom surface of the battery container and an end portion of the electrode group facing the bottom surface in the winding axis direction.
  • a plate-like member having rigidity whose dimension in the thickness direction is smaller than the thickness is disposed.
  • the displacement of the electrode group is prevented by the rigidity of the plate-like member between the bottom surface of the battery container and the end portion of the electrode group facing the bottom surface in the winding axis direction. be able to. Moreover, since the dimension of the plate-shaped member in the thickness direction of the electrode group is smaller than the thickness of the electrode group, the volume in the thickness direction of the battery is not increased.
  • FIG. 1 is an external perspective view showing Embodiment 1 of a prismatic secondary battery of the present invention.
  • the disassembled perspective view of the electrode group shown in FIG. FIG. 3 is a perspective view of an electrode group and a plate member shown in FIG. 2.
  • the enlarged side view which shows an example of the fixing method of the electrode group and plate-shaped member which are shown in FIG.
  • the enlarged side view which shows an example of the fixing method of the electrode group and plate-shaped member which are shown in FIG.
  • Sectional drawing which follows the longitudinal direction which shows the modification 1 of the plate-shaped member shown in FIG. It is sectional drawing which shows the modification 2 of the plate-shaped member shown in FIG.
  • FIG. 4 (a) is sectional drawing which follows a longitudinal direction, (b) is sectional drawing which follows a transversal direction.
  • the perspective view which shows the modification 3 of the plate-shaped member shown in FIG. FIG. 6 is a cross-sectional view taken along the line XX shown in FIG. 1 showing Embodiment 2 of the prismatic secondary battery of the present invention.
  • FIG. 1 is an external perspective view of a prismatic secondary battery 100 of the present embodiment.
  • FIG. 2 is an exploded perspective view of the prismatic secondary battery 100 shown in FIG.
  • the prismatic secondary battery 100 of the present embodiment is, for example, a prismatic lithium ion secondary battery including a flat rectangular battery container 10.
  • the battery container 10 includes a bottomed rectangular tube-shaped battery can 11 having an opening 11d at the top, and a rectangular plate-shaped battery lid 12 that seals the opening 11d of the battery can 11.
  • the battery can 11 has a wide side wall 11a having a maximum area along the width direction, a narrow side wall 11b having a small area along the thickness direction, and a bottom wall 11c facing the upper opening 11d.
  • the battery can 11 and the battery lid 12 are made of a metal material such as aluminum or an aluminum alloy, for example.
  • positive and negative external terminals 20A and 20B are arranged outside the battery lid 12.
  • the positive external terminal 20A is made of, for example, aluminum or an aluminum alloy
  • the negative external terminal 20B is made of, for example, copper or a copper alloy.
  • the external terminals 20A and 20B of the positive electrode and the negative electrode are collectively referred to as the external terminal 20.
  • the battery lid 12 has through holes 12a at both ends where the external terminals 20 are disposed.
  • the gasket 2 is disposed between the external terminal 20 and the battery lid 12 around the through hole 12a.
  • the gasket 2 electrically insulates the external terminal 20 and the battery cover 12 and is compressed between the external terminal 20 and the battery cover 12 so as to be in close contact therewith, thereby sealing the through hole 12a of the battery cover 12. ing.
  • the gasket 2 is made of an insulating resin material such as polybutylene terephthalate, polyphenylene sulfide, or perfluoroalkoxy fluororesin.
  • the gas discharge valve 13 is provided, for example, by thinning the battery lid 12 to form a groove 13a, and is cleaved to release the internal gas when the internal pressure of the battery container 10 exceeds a predetermined value. As a result, the pressure inside the battery container 10 is reduced.
  • the liquid injection port 14 is used for injecting an electrolytic solution into the battery container 10, and the liquid injection plug 15 is welded and sealed by laser welding, for example.
  • the external terminal 20 has a weld joint 21 that is welded to a bus bar or the like.
  • the welded joint portion 21 is formed in a block shape having a substantially rectangular parallelepiped shape, the lower end surface faces the upper surface of the battery lid 12, and the upper end surface is parallel to the upper surface of the battery lid 12.
  • a columnar connection portion 22 extending in a direction perpendicular to the upper surface of the battery lid 12 is provided on the lower end surface of the weld joint portion 21.
  • the positive and negative current collecting plates 30 ⁇ / b> A and 30 ⁇ / b> B are respectively bent at the rectangular plate-like base portion 31 disposed opposite to the lower surface of the battery lid 12 and the side end of the base portion 31, and are formed on the wide side wall 11 a of the battery can 11. And a terminal portion 32 extending toward the bottom wall 11c.
  • the positive and negative current collecting plates 30A and 30B are electrically connected to the electrode group 40 by joining the terminal portions 32 to the tab portions 41c and 42c of the electrode group 40 by, for example, ultrasonic welding or resistance welding.
  • the electrode group 40 is supported in the battery container 10 while being connected.
  • the positive current collecting plate 30A is made of, for example, aluminum or an aluminum alloy
  • the negative current collecting plate 30B is made of, for example, copper or a copper alloy.
  • the positive and negative current collecting plates 30A and 30B are collectively referred to as the current collecting plate 30.
  • the insulating plate 3 is disposed between the base 31 of the current collecting plate 30 and the battery lid 12, and the battery lid 12 and the current collecting plate 30 are electrically insulated.
  • the insulating plate 3 is made of, for example, a resin material having insulation similar to that of the gasket 2.
  • External terminal 20, gasket 2, insulating plate 3, and current collector plate 30 are caulked and fixed to battery lid 12.
  • the connecting portion 22 of the external terminal 20 is inserted into the through hole 2 a of the gasket 2, the through hole 12 a of the battery cover 12, the through hole 3 a of the insulating plate 3, and the through hole 31 a of the base 31 of the current collector plate 30.
  • the tip of the connecting portion 22 is plastically deformed to expand the diameter, thereby forming the caulking portion 22c.
  • the external terminal 20, the gasket 2, the insulating plate 3, and the current collecting plate 30 are caulked and fixed to the battery lid 12, and the positive and negative external terminals 20A and 20B are connected to the positive and negative current collecting plates 30A and 30B, respectively.
  • FIG. 3 is an exploded perspective view in which a part of the electrode group 40 shown in FIG. 2 is developed.
  • the electrode group 40 is a flat wound electrode group in which positive and negative electrodes 41 and 42 are wound around a central axis of winding, that is, a winding axis A. More specifically, the electrode group 40 is formed into a flat shape by winding the positive and negative electrodes 41 and 42 laminated with the separators 43 and 44 interposed therebetween around an axis parallel to the winding axis A. This is a wound electrode group.
  • the separators 43 and 44 are, for example, porous resin sheets manufactured by stretching a polyethylene resin or a polypropylene resin, and insulate the positive electrode 41 and the negative electrode 42 from each other.
  • the electrode group 40 can be manufactured by the following procedure, for example. First, the winding start ends of the separators 43 and 44 are welded to a shaft core (not shown), and the separators 43 and 44 and the positive and negative electrodes 41 and 42 are alternately overlapped and wound. At this time, the starting end portion of the positive electrode 41 is arranged closer to the axial center side than the starting end portion of the negative electrode 42 and wound. Thereby, in the electrode group 40 after winding, the winding start end portion of the positive electrode 41 is positioned closer to the axial center side than the winding start end portion of the negative electrode 42.
  • the separator 44 is wound around the electrode group 40 more than once around the electrode group 40 after the negative electrode 42 has been wound.
  • the wound end is fixed by, for example, an adhesive tape for preventing winding looseness.
  • the width, length, and thickness of the adhesive tape are not particularly limited, and for example, the entire outer periphery of the electrode group may be covered.
  • the positive electrode 41 has a positive electrode foil 41a that is a positive electrode current collector, and a positive electrode mixture layer 41b made of a positive electrode active material mixture applied to both surfaces of the positive electrode foil 41a.
  • One side in the width direction of the elongated positive electrode 41 is a current collector exposed portion where the positive electrode mixture layer 41b is not formed and the positive foil 41a is exposed, and the current collector exposed portion is cut out to form a plurality.
  • the tab portion 41c is formed.
  • the tab portion 41 c protrudes in the width direction of the positive electrode 41 and protrudes from end portions in the width direction of the separators 43 and 44.
  • the spacing between the tab portions 41c is adjusted so that the plurality of tab portions 41c of the positive electrode 41 are bundled together at a position corresponding to the terminal portion 32 of the positive current collector plate 30A after the electrode group 40 is wound. ing.
  • the positive electrode 41 for example, a positive electrode active material mixture kneaded by adding a conductive material, a binder and a dispersion solvent to the positive electrode active material, is applied to both surfaces of the positive electrode foil 41a except for one side in the width direction, It can be produced by drying, pressing and cutting.
  • As the positive electrode foil 41a for example, an aluminum foil having a thickness of about 15 ⁇ m can be used.
  • the thickness of the positive electrode mixture layer 41b not including the thickness of the positive electrode foil 41a is, for example, about 70 ⁇ m.
  • the positive electrode active material mixture for example, 100 parts by weight of lithium manganate (chemical formula LiMn 2 O 4 ) is used as the positive electrode active material, 10 parts by weight of flaky graphite as the conductive material, and 10% by weight as the binder.
  • Part of polyvinylidene fluoride (hereinafter referred to as PVDF) and N-methylpyrrolidone (hereinafter referred to as NMP) can be used as a dispersion solvent.
  • the positive electrode active material is not limited to the above-described lithium manganate.
  • another lithium manganate having a spinel crystal structure, or a lithium manganese composite oxide partially substituted or doped with a metal element may be used.
  • lithium cobalt oxide or lithium titanate having a layered crystal structure, or a lithium-metal composite oxide in which a part thereof is substituted or doped with a metal element may be used.
  • the negative electrode 42 has a negative electrode foil 42a which is a negative electrode current collector, and a negative electrode mixture layer 42b made of a negative electrode active material mixture coated on both surfaces of the negative electrode foil 42a.
  • the negative electrode mixture layer 42b is not formed on one side in the width direction of the negative electrode 42, and a current collector exposed portion where the negative electrode foil 42a is exposed is formed, and the current collector exposed portion is cut away to form a tab portion 42c.
  • the tab portion 42 c protrudes in the width direction of the negative electrode 42 and protrudes from the end portions in the width direction of the separators 43 and 44.
  • the spacing between the tab portions 42c is adjusted so that the plurality of tab portions 42c of the negative electrode 42 are bundled together at a position corresponding to the terminal portion 32 of the negative electrode current collector plate 30B after the electrode group 40 is wound. ing.
  • the negative electrode 42 is prepared by applying a negative electrode active material mixture kneaded by adding a binder and a dispersion solvent to the negative electrode active material on both sides of the negative electrode foil 42a except for one side in the width direction, drying, pressing, It can be produced by cutting.
  • a negative electrode foil 42a for example, a copper foil having a thickness of about 10 ⁇ m can be used.
  • the thickness of the negative electrode mixture layer 42b not including the thickness of the negative electrode foil 42a is, for example, about 40 ⁇ m.
  • the negative electrode active material mixture for example, 100 parts by weight of amorphous carbon powder as the negative electrode active material, 10 parts by weight of PVDF as the binder, and NMP as the dispersion solvent can be used.
  • the negative electrode active material is not limited to the above-mentioned amorphous carbon, and natural graphite capable of inserting and removing lithium ions, various artificial graphite materials, carbonaceous materials such as coke, and compounds such as Si and Sn (for example, , SiO, TiSi 2 or the like), or a composite material thereof.
  • the particle shape of the negative electrode active material is not particularly limited, and a particle shape such as a scale shape, a spherical shape, a fiber shape, or a lump shape can be appropriately selected.
  • the binder used for the positive electrode and negative electrode mixture layers 41b and 42b is not limited to PVDF.
  • the binder include polytetrafluoroethylene (PTFE), polyethylene, polystyrene, polybutadiene, butyl rubber, nitrile rubber, styrene butadiene rubber, polysulfide rubber, nitrocellulose, cyanoethyl cellulose, various latexes, acrylonitrile, and vinyl fluoride.
  • Polymers such as vinylidene fluoride, propylene fluoride, chloroprene fluoride, and acrylic resins, and mixtures thereof may be used.
  • the axial core when winding the positive electrode 41 and the negative electrode 42 with the separators 43 and 44 interposed therebetween is, for example, more flexible than the positive foil 41a, the negative foil 42a, and the separators 43 and 44.
  • a roll of a high resin sheet can be used.
  • the width of the negative electrode mixture layer 42b of the negative electrode 42 is wider than the width of the positive electrode mixture layer 41b of the positive electrode 41.
  • a negative electrode 42 is wound around the innermost and outermost circumferences of the electrode group 40.
  • the positive electrode mixture layer 41b is sandwiched between the negative electrode mixture layer 42b from the innermost periphery to the outermost periphery of the electrode group 40.
  • the end portion of the negative electrode 42 is at the end portion 40d facing the bottom wall 11c of the battery can 11 opposite to the end portion 40c where the tab portions 41c and 42c are formed. Is arranged on the outermost side. Furthermore, in the winding axis A direction of the electrode group 40, the end portions of the separators 43 and 44 are arranged inside the end portion of the negative electrode 42 with an interval of 2 mm or less, for example. The end of the positive electrode 41 is disposed on the inner side with an interval of, for example, 2 mm or more and 4 mm or less.
  • the end wall of the negative electrode 42 wound on the end portion 40 d facing the bottom wall 11 c of the battery can 11 has the bottom wall of the battery can 11. An end surface facing 11c is formed.
  • FIG. 4 is a perspective view of the electrode group 40 and the plate-like member 50 shown in FIG.
  • the plate-like member 50 is an insulating plate-like member made of, for example, a resin material such as polyethylene, PTFE, or vinyl chloride, or a fiber reinforced plastic resin such as FRP or GFRP.
  • the plate-like member 50 has rigidity capable of supporting or pressing the end face formed by the end portion 40 d of the electrode group 40, that is, the end portion of the negative electrode 42.
  • the plate-like member 50 of the present embodiment has an end of the electrode group 40 when the electrode group 40 is inserted into the battery can 11 or when the electrode group 40 repeatedly expands and contracts in the battery container 10. Resisting against the force acting from the portion 40d, the shape of the end portion 40d of the electrode group 40 can be maintained to prevent the loosening of the winding.
  • the rigidity of the plate-like member 50 described above can be obtained by setting the thickness T 50 of the plate-like member 50 made of the above material to, for example, 0.8 mm or more. Note that the deflection of the plate-like member 50 varies depending on the Young's modulus, the secondary moment of section, and the load acting from the end 40 d of the electrode group 40. Therefore, the thickness T 50 of the plate-like member 50 can be appropriately changed within the range having the above-described rigidity in consideration of the deflection of the plate-like member 50.
  • the plate-like member 50 is disposed between the bottom wall 11c of the battery can 11, that is, the bottom surface of the battery case 10, and the end 40d in the winding axis A direction of the electrode group 40 facing the bottom surface.
  • the plate-like member 50 has a flat upper surface 50 a that contacts the end portion 40 d of the electrode group 40 and a flat lower surface 50 b that faces the bottom wall 11 c of the battery can 11.
  • Dimension W 50 of the plate-like member 50 in the width W 40 direction of the electrode group 40 is the width W 40 of the electrode assembly 40 or less, it is preferably smaller than the width W 40 of the electrode assembly 40.
  • Both end portions in the longitudinal direction of the plate-like member 50 are formed in curved shapes corresponding to the shapes of the curved portions 40 b formed at both end portions in the width W 40 direction of the electrode group 40.
  • the dimensional D 50 of the plate-like member 50 in the thickness T 40 direction of the flat electrode group 40 is smaller than the thickness T 40 of the electrode group 40.
  • the thickness T40 of the electrode group 40 is the distance between the surfaces P1 and P2 when the electrode group 40 is compressed between a pair of parallel surfaces P1 and P2, for example, with a compressive force of 50N or more and 100N or less. Can be defined.
  • the areas of the surfaces P1 and P2 are assumed to be larger than the area of the flat portion 40a of the electrode group 40.
  • FIG. 5 and 6 are enlarged side views showing an example of a method for fixing the plate-like member 50 to the end portion 40d of the electrode group 40.
  • FIG. 5 and 6 are enlarged side views showing an example of a method for fixing the plate-like member 50 to the end portion 40d of the electrode group 40.
  • the plate-like member 50 can be fixed to the end portion 40 d of the electrode group 40 via the adhesive layer 60.
  • the adhesive layer 60 for example, an epoxy resin or an acrylic resin can be used.
  • the plate-like member 50 can be fixed to the end portion 40 d of the electrode group 40 using an adhesive tape 70.
  • the adhesive tape 70 protrudes in the direction of the thickness T 40 of the electrode group 40, but the thickness of the adhesive tape 70 is very thin compared to the thickness T 50 of the plate-like member 50, so There is almost no effect on capacity reduction.
  • the tab portions 41c and 42c of the positive and negative electrodes 41 and 42 are connected to the terminal portions of the positive and negative current collector plates 30A and 30B, respectively, by ultrasonic welding or resistance welding, for example. 32.
  • the electrode group 40 is electrically connected to the external terminal 20 via the current collector plate 30 and is fixed to the battery lid 12 via the insulating plate 3.
  • the width of the separators 43 and 44 is wider than the width of the negative electrode mixture layer 42b, but the tab portions 41c and 42c of the positive electrode 41 and the negative electrode 42 are respectively separated from the separator 43. , 44 protrudes outward in the width direction from the end in the width direction. Therefore, the separators 43 and 44 do not hinder the tab portions 41c and 42c from being bundled and welded.
  • the electrode group 40 and the plate-like member 50 are covered and covered with an insulating protective film 4 made of synthetic resin such as polypropylene, for example, in a state where the electrode group 40 and the plate-like member 50 are joined and supported by a current collector plate 30 that is caulked and fixed to the battery lid 12.
  • the battery can 11 is electrically insulated from the battery can 11 and inserted into the battery can 11 through the opening 11 d of the battery can 11.
  • the lower surface 50 b of the plate-like member 50 may not be covered with the insulating protective film 4.
  • the battery lid 12 is welded over the entire circumference of the opening 11d of the battery can 11 by laser welding, and the opening 11d of the battery can 11 is sealed with the battery lid 12, so that the battery container 10 is Composed.
  • a non-aqueous electrolyte is injected into the battery container 10 through the liquid injection port 14 of the battery lid 12 and, for example, the liquid injection plug 15 is joined to the liquid injection port 14 by laser welding and sealed.
  • the battery container 10 is sealed.
  • the non-aqueous electrolyte to be injected into the electrolyte for example, lithium hexafluorophosphate (LiPF 6 ) is mixed in a mixed solution in which ethylene carbonate and dimethyl carbonate are mixed at a volume ratio of 1: 2. Those dissolved at a concentration of 1 mol / liter can be used.
  • the prismatic secondary battery 100 of the present embodiment accumulates the power supplied from the generator or the like in the electrode group 40 via the external terminal 20 and the current collector plate 30 and accumulates in the electrode group 40. Electric power is supplied to an external motor or the like via the current collector plate 30 and the external terminal 20.
  • the prismatic secondary battery 100 of the present embodiment has rigidity between the bottom wall 11c of the battery can 11, that is, the bottom surface of the battery container 10, and the end portion 40d of the electrode group 40 facing the bottom surface in the winding axis A direction.
  • a plate-like member 50 is disposed.
  • the electrode group 40 when the electrode group 40 is inserted into the opening 11 d of the battery can 11, the end 40 d of the electrode group 40 is supported by the plate-like member 50, thereby preventing the electrode group 40 from being unwound. be able to.
  • the electrode group 40 repeatedly expands and contracts as the prismatic secondary battery 100 is charged and discharged, the end portion 40d of the electrode group 40 is supported by the plate-like member 50, and the electrode group 40 is unwound. It can be prevented from occurring.
  • the plate-like member 50 has a dimension D 50 in the thickness T 40 direction smaller than the thickness T 40 of the electrode group 40. Thereby, the volume increase in the thickness direction of the prismatic secondary battery 100 is not caused. Accordingly, it is possible to prevent a useless space from being generated between the wide side wall 11a of the battery can 11 and the flat portion 40a of the electrode group 40, and to increase the number and thickness of the positive and negative electrodes 41 and 42 of the electrode group 40. The capacity of the square secondary battery 100 can be increased.
  • the plate member 50 When the plate member 50 is fixed to the end portion 40 d of the electrode group 40 via the adhesive layer 60, the plate member 50 is inserted when the electrode group 40 is inserted into the opening portion 11 d of the battery can 11. And displacement of the electrode group 40 can be prevented. In addition, the impact between the plate-like member 50 and the end portion of the electrode group 40 can be reduced by the adhesive layer 60.
  • the plate-like member 50 when the plate-like member 50 is fixed to the end 40 d of the electrode group 40 by the adhesive tape 70, the plate-like member is similarly inserted when the electrode group 40 is inserted into the opening 11 d of the battery can 11. 50 and the electrode group 40 can be prevented from being displaced.
  • the flow of the electrolytic solution between the plate member 50 and the electrode group 40 is not hindered, and the electrolytic solution can be easily impregnated from the end portion 40 d of the electrode group 40.
  • the prismatic secondary battery 100 of the present embodiment it is possible to prevent winding deviation of the electrode group 40 and to prevent an increase in volume in the thickness direction.
  • the structure of the plate-shaped member 50 is the structure demonstrated by this embodiment. It is not limited.
  • Modification 1 to Modification 3 of the plate-like member 50 of the present embodiment will be described.
  • FIG. 7 is a cross-sectional view along the longitudinal direction showing Modification 1 of the plate-like member 50 of Embodiment 1 shown in FIG.
  • the plate-like member 50 ⁇ / b> A of the present modification includes a porous layer 51 that faces the end 40 d of the electrode group 40.
  • the porous layer 51 can impregnate the electrolytic solution in the battery container 10 and impregnate the electrolytic solution from the end portion 40 d of the electrode group 40. Therefore, according to the prismatic secondary battery including the plate-like member 50A of the present modification, not only the same effects as those of the prismatic secondary battery 100 of the first embodiment can be obtained, but also the electrolyte solution impregnation with respect to the electrode group 40. Can be improved.
  • (Modification 2) 8 is a cross-sectional view showing a second modification of the plate-like member 50 of the first embodiment shown in FIG. 4, where FIG. 8 (a) is a cross-sectional view in the longitudinal direction, and FIG. 8 (b) is a cross-section in the short direction.
  • FIG. The plate-like member 50B of this modification has an area of the upper surface 50a facing the end portion 40d of the electrode group 40 larger than the area of the bottom wall 11c of the battery can 11, that is, the lower surface 50b facing the bottom surface of the battery container 10, The surface 50 c is inclined with respect to the winding axis A of the electrode group 40.
  • the plate-like member fixed to the end portion 40 d of the electrode group 40 when the electrode group 40 is inserted into the opening 11 d of the battery can 11.
  • the electrode group 40 can be easily inserted by the outer peripheral surface 50c of the 50.
  • FIG. 9 is a perspective view showing a third modification of the plate-like member 50 of the first embodiment shown in FIG.
  • the plate-like member 50C of this modification is formed in a mesh shape with the same material as the plate-like member 50 of the first embodiment.
  • the electrolytic solution in the battery container 10 reaches the end 40d of the electrode group 40 by the mesh of the plate-like member 50C, and electrolysis with respect to the electrode group 40 is performed. Impregnation of the liquid can be further improved.
  • FIG. 10 is a cross-sectional view of the rectangular secondary battery 100A of the present embodiment corresponding to the XX cross section shown in FIG.
  • the rectangular secondary battery 100 ⁇ / b> A of the present embodiment is attached between the plate member 50 and the bottom wall 11 c of the battery can 11, that is, the bottom surface of the battery container 10, with the plate member 50 facing the end 40 d of the electrode group 40.
  • This is different from the prismatic secondary battery 100 of the first embodiment described above in that the elastic member 80 is provided. Since the other points of the prismatic secondary battery 100 of the present embodiment are the same as those of the prismatic secondary battery 100 of the first embodiment described above, the same portions are denoted by the same reference numerals and description thereof is omitted.
  • the elastic member 80 for example, a spring member such as a leaf spring, a coil spring, and a disc spring, or an elastic body such as styrene butadiene rubber, ethylene propylene rubber, polyethylene sponge, and rubber sponge can be used.
  • the plate-like member 50 is attached to the end 40d of the electrode group 40 by the elastic member 80.
  • the end 40d of the electrode group 40 can be pressed by the plate-like member 50 by being biased toward the plate. Accordingly, it is possible to effectively prevent the winding deviation of the electrode group 40 when the prismatic secondary battery 100A is repeatedly charged and discharged.
  • the prismatic secondary battery of the present invention can be used not only for an in-vehicle battery system applied to a hybrid vehicle using a motor as a drive source, a zero emission electric vehicle, etc., but also for a wider range of uses.
  • a battery system equipped with the prismatic secondary battery of the present invention is a power storage system that charges and stores a battery with electric power generated by solar power generation, wind power generation, etc. regardless of whether it is for home use, business use, or industrial use.
  • the battery system equipped with the rectangular secondary battery of the present invention is used as a power storage system for charging and storing a battery by using nighttime midnight power, or other than on the ground such as a space station, a spacecraft, a space base, etc. It can also be used as a possible power storage system.
  • the battery system equipped with the square secondary battery of the present invention is used for industrial purposes such as medical equipment, construction machinery, power storage systems, elevators, unmanned mobile vehicles, and for mobile objects such as golf carts and turret cars. can do.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Secondary Cells (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Cell Separators (AREA)

Abstract

L'invention concerne une pile rechargeable rectangulaire pour laquelle un déplacement d'enroulement d'un groupe d'électrodes est empêché sans augmenter le volume de la pile dans le sens de l'épaisseur. Une pile rechargeable rectangulaire comprend un récipient de pile rectangulaire plat et un groupe d'électrodes plates logées dans le récipient de pile, le groupe d'électrodes plates ayant des électrodes positive et négative enroulées autour d'un arbre d'enroulement qui est perpendiculaire à la surface inférieure du récipient de pile. Un élément en forme de plaque rigide présentant une dimension dans le sens de l'épaisseur qui est inférieure à l'épaisseur du groupe d'électrodes, est disposé entre la surface inférieure du récipient de pile et la partie d'extrémité dans la direction de l'arbre d'enroulement du groupe d'électrodes faisant face à la surface inférieure.
PCT/JP2015/081243 2014-12-04 2015-11-06 Pile rechargeable rectangulaire WO2016088505A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2014-245955 2014-12-04
JP2014245955A JP2016110787A (ja) 2014-12-04 2014-12-04 角形二次電池

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WO2016088505A1 true WO2016088505A1 (fr) 2016-06-09

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6878914B2 (ja) * 2017-01-26 2021-06-02 株式会社豊田自動織機 蓄電装置
JP6915491B2 (ja) * 2017-10-04 2021-08-04 トヨタ自動車株式会社 二次電池
WO2019104720A1 (fr) * 2017-12-01 2019-06-06 宁德新能源科技有限公司 Élément de batterie enroulé

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0192071U (fr) * 1987-12-08 1989-06-16
JPH0574424A (ja) * 1991-09-13 1993-03-26 Asahi Chem Ind Co Ltd 高容量の二次電池
JPH10340712A (ja) * 1997-06-06 1998-12-22 Toshiba Battery Co Ltd 角型非水電解液電池およびその製造方法
JP2008097882A (ja) * 2006-10-06 2008-04-24 Sumitomo Electric Fine Polymer Inc ガスケット、密閉型二次電池および電解コンデンサ
JP2009110751A (ja) * 2007-10-29 2009-05-21 Panasonic Corp 二次電池
JP2009295489A (ja) * 2008-06-06 2009-12-17 Panasonic Corp 電池
JP2011082162A (ja) * 2009-10-07 2011-04-21 Sb Limotive Co Ltd 二次電池

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0192071U (fr) * 1987-12-08 1989-06-16
JPH0574424A (ja) * 1991-09-13 1993-03-26 Asahi Chem Ind Co Ltd 高容量の二次電池
JPH10340712A (ja) * 1997-06-06 1998-12-22 Toshiba Battery Co Ltd 角型非水電解液電池およびその製造方法
JP2008097882A (ja) * 2006-10-06 2008-04-24 Sumitomo Electric Fine Polymer Inc ガスケット、密閉型二次電池および電解コンデンサ
JP2009110751A (ja) * 2007-10-29 2009-05-21 Panasonic Corp 二次電池
JP2009295489A (ja) * 2008-06-06 2009-12-17 Panasonic Corp 電池
JP2011082162A (ja) * 2009-10-07 2011-04-21 Sb Limotive Co Ltd 二次電池

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