WO2015097882A1 - 熱間プレス鋼板部材、その製造方法及び熱間プレス用鋼板 - Google Patents
熱間プレス鋼板部材、その製造方法及び熱間プレス用鋼板 Download PDFInfo
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- WO2015097882A1 WO2015097882A1 PCT/JP2013/085167 JP2013085167W WO2015097882A1 WO 2015097882 A1 WO2015097882 A1 WO 2015097882A1 JP 2013085167 W JP2013085167 W JP 2013085167W WO 2015097882 A1 WO2015097882 A1 WO 2015097882A1
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/46—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for sheet metals
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/02—Stamping using rigid devices or tools
- B21D22/022—Stamping using rigid devices or tools by heating the blank or stamping associated with heat treatment
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D—WORKING OR PROCESSING OF SHEET METAL OR METAL TUBES, RODS OR PROFILES WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21D22/00—Shaping without cutting, by stamping, spinning, or deep-drawing
- B21D22/20—Deep-drawing
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
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- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
- C21D1/673—Quenching devices for die quenching
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D3/00—Diffusion processes for extraction of non-metals; Furnaces therefor
- C21D3/02—Extraction of non-metals
- C21D3/04—Decarburising
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0257—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment with diffusion of elements, e.g. decarburising, nitriding
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- C—CHEMISTRY; METALLURGY
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for drawing, e.g. for deep-drawing
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for drawing, e.g. for deep-drawing
- C21D8/0421—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for drawing, e.g. for deep-drawing characterised by the working steps
- C21D8/0436—Cold rolling
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- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/04—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for drawing, e.g. for deep-drawing
- C21D8/0447—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for drawing, e.g. for deep-drawing characterised by the heat treatment
- C21D8/0457—Modifying the physical properties of ferrous metals or ferrous alloys by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips to produce plates or strips for drawing, e.g. for deep-drawing characterised by the heat treatment with diffusion of elements, e.g. decarburising, nitriding
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/002—Ferrous alloys, e.g. steel alloys containing In, Mg, or other elements not provided for in one single group C22C38/001 - C22C38/60
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- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/005—Ferrous alloys, e.g. steel alloys containing rare earths, i.e. Sc, Y, Lanthanides
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- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/08—Ferrous alloys, e.g. steel alloys containing nickel
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/12—Ferrous alloys, e.g. steel alloys containing tungsten, tantalum, molybdenum, vanadium, or niobium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
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- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/16—Ferrous alloys, e.g. steel alloys containing copper
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/58—Ferrous alloys, e.g. steel alloys containing chromium with nickel with more than 1.5% by weight of manganese
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- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/005—Ferrite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2211/00—Microstructure comprising significant phases
- C21D2211/008—Martensite
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D2221/00—Treating localised areas of an article
Definitions
- the present invention relates to a hot-pressed steel sheet member used for machine structural parts and the like, a manufacturing method thereof, and a hot-press steel sheet.
- Patent Documents 1 and 2 describe a method called hot pressing for the purpose of obtaining high formability in a high-strength steel sheet. According to hot pressing, a high-strength hot-pressed steel plate member can be obtained by forming a high-strength steel plate with high accuracy.
- Patent Documents 3 to 5 describe high-strength hot-pressed steel sheets for the purpose of improving ductility. However, it is difficult to obtain sufficient impact characteristics with these conventional hot-pressed steel sheets. is there. Patent Documents 6 to 8 also describe techniques related to hot pressing, but it is difficult to obtain sufficient impact characteristics.
- An object of the present invention is to provide a hot-pressed steel sheet member that can obtain excellent impact characteristics while having high strength, a manufacturing method thereof, and a hot-press steel sheet.
- the inventor of the present application examined the cause of difficulty in obtaining excellent collision performance even with a conventional high-strength hot-pressed steel sheet member aimed at improving ductility. As a result, it became clear that not only the improvement of ductility but also the improvement of bendability is important for improving the impact performance. The bendability is also important because extreme plastic deformation occurs in the hot pressed steel sheet member at the time of collision, and the surface layer portion of the hot pressed steel sheet member may be subjected to severe bending deformation. It has also been clarified that the importance of bendability becomes apparent when the tensile strength is 980 MPa or more.
- the inventor of the present application has conducted extensive studies based on such knowledge, and as a result, has a chemical composition containing a predetermined amount of C and Mn and a relatively large amount of Si, and has a predetermined steel structure.
- the steel structure is a multiphase structure containing ferrite and martensite, and the area ratio of ferrite in the surface layer part is compared with the inner layer part
- an elevated hot pressed steel sheet member can be obtained.
- the present inventor has also found that the hot-pressed steel sheet member has a high tensile strength of 980 MPa or more and also has excellent ductility and bendability. And this inventor came up with the aspect of the invention shown below.
- the chemical composition is mass%, Ti: 0.003% to 0.20%, Nb: 0.003% to 0.20%, V: 0.003% to 0.20%, Cr: 0.005% to 1.0%, Mo: 0.005% to 1.0%, Cu: 0.005% to 1.0%, and Ni: 0.005% to 1.0%
- the hot-pressed steel sheet member according to (1) containing one or more selected from the group consisting of:
- the chemical composition is mass%, Ca: 0.0003% to 0.01%, Mg: 0.0003% to 0.01%, REM: 0.0003% to 0.01%, and Zr: 0.0003% to 0.01%
- the chemical composition is mass%, Ti: 0.003% to 0.20%, Nb: 0.003% to 0.20%, V: 0.003% to 0.20%, Cr: 0.005% to 1.0%, Mo: 0.005% to 1.0%, Cu: 0.005% to 1.0%, and Ni: 0.005% to 1.0%
- the hot-press steel plate according to (6) which contains one or more selected from the group consisting of:
- the chemical composition is mass%, Ca: 0.0003% to 0.01%, Mg: 0.0003% to 0.01%, REM: 0.0003% to 0.01%, and Zr: 0.0003% to 0.01%
- the manufacturing method of the hot press steel plate member characterized by having.
- the hot-pressed steel sheet member according to the present invention is used for a body structure part of an automobile, even if a collision that causes extreme plastic deformation occurs, the impact is absorbed along with the bending deformation of the surface layer portion. be able to.
- Embodiments of the present invention relate to a hot-pressed steel sheet member having a tensile strength of 980 MPa or more.
- % which is a unit of content of each element contained in a steel plate member or a hot-press steel plate, means “% by mass” unless otherwise specified.
- the chemical composition of the steel sheet member according to this embodiment is, in mass%, C: 0.10% to 0.34%, Si: 0.5% to 2.0%, Mn: 1.0% to 3.0%. %, Sol. Al: 0.001% to 1.0%, P: 0.05% or less, S: 0.01% or less, N: 0.01% or less, Ti: 0% to 0.20%, Nb: 0% ⁇ 0.20%, V: 0% ⁇ 0.20%, Cr: 0% ⁇ 1.0%, Mo: 0% ⁇ 1.0%, Cu: 0% ⁇ 1.0%, Ni: 0% -1.0%, Ca: 0% -0.01%, Mg: 0% -0.01%, REM: 0% -0.01%, Zr: 0% -0.01%, B: 0% -0.01%, Bi: 0% -0.01%, balance: Fe and impurities.
- the chemical composition of the steel sheet for hot pressing used for manufacturing the steel sheet member according to this embodiment is mass%, C: 0.11% to 0.35%, Si: 0.5% to 2.0%, Mn: 1.0% to 3.0%, sol. Al: 0.001% to 1.0%, P: 0.05% or less, S: 0.01% or less, N: 0.01% or less, Ti: 0% to 0.20%, Nb: 0% ⁇ 0.20%, V: 0% ⁇ 0.20%, Cr: 0% ⁇ 1.0%, Mo: 0% ⁇ 1.0%, Cu: 0% ⁇ 1.0%, Ni: 0% -1.0%, Ca: 0% -0.01%, Mg: 0% -0.01%, REM: 0% -0.01%, Zr: 0% -0.01%, B: 0% -0.01%, Bi: 0% -0.01%, balance: Fe and impurities.
- the impurities include those contained in raw materials such as ore and scrap and those contained in the manufacturing process.
- C (C for steel sheet for hot pressing: 0.10% to 0.34%, C for steel sheet for hot pressing: 0.11% to 0.35%)
- C is a very important element that enhances the hardenability of the steel sheet for hot pressing and mainly determines the strength of the steel sheet member. If the C content of the steel sheet member is less than 0.10%, it is difficult to ensure a tensile strength of 980 MPa or more. Therefore, the C content of the steel plate member is set to 0.10% or more. When the C content of the steel plate member exceeds 0.34%, the bendability and weldability are significantly reduced. Therefore, the C content of the steel plate member is set to 0.34% or less.
- the C content of the steel sheet for hot pressing is preferably 0.30% or less, more preferably 0.25%. It is as follows. As will be described later, since the decarburization treatment of the hot press steel plate is performed during the production of the hot press steel plate member, the hot press steel plate contains a larger amount of C, and the C content is 0.11% or more and 0.35% or less.
- Si 0.5% to 2.0%
- Si is an element that is very effective in improving the ductility of the steel sheet member and ensuring the strength of the steel sheet member stably. If the Si content is less than 0.5%, it is difficult to obtain the above effect. Therefore, the Si content is 0.5% or more. When the Si content exceeds 2.0%, the effects of the above action are saturated and disadvantageous economically, and the plating wettability is significantly reduced, resulting in frequent non-plating. Therefore, the Si content is 2.0% or less. From the viewpoint of improving weldability, the Si content is preferably 0.7% or more. From the viewpoint of suppressing surface defects of the steel plate member, the Si content is preferably 1.8% or less.
- Mn is an element that is extremely effective in improving the hardenability of the steel sheet for hot pressing and ensuring the strength of the steel sheet member. If the Mn content is less than 1.0%, it is very difficult to secure a tensile strength of 980 MPa or more for the steel plate member. Therefore, the Mn content is 1.0% or more. In order to obtain the above action more reliably, the Mn content is preferably 1.1% or more. If the Mn content is more than 3.0%, the steel structure of the steel sheet member becomes a remarkable band shape, and the deterioration of bendability becomes remarkable. Therefore, the Mn content is 3.0% or less. From the viewpoint of productivity in hot rolling and cold rolling for obtaining a steel sheet for hot pressing, the Mn content is preferably 2.5% or less.
- Al is an element having an action of deoxidizing steel to make the steel material sound. sol. If the Al content is less than 0.001%, it is difficult to obtain the above effect. Therefore, sol. The Al content is 0.001% or more. In order to obtain the above action more reliably, sol. The Al content is preferably 0.015% or more. sol. If the Al content exceeds 1.0%, the weldability is significantly lowered, the oxide inclusions are increased, and the surface properties are remarkably deteriorated. Therefore, sol. Al content shall be 1.0% or less. In order to obtain better surface properties, sol. The Al content is preferably 0.080% or less.
- P is not an essential element but is contained as an impurity in steel, for example. From the viewpoint of weldability, the lower the P content, the better. In particular, when the P content exceeds 0.05%, the weldability is remarkably reduced. Therefore, the P content is 0.05% or less. In order to ensure better weldability, the P content is preferably 0.018% or less. On the other hand, P has the effect
- S is not an essential element but is contained as an impurity in steel, for example. From the viewpoint of weldability, the lower the S content, the better. In particular, when the S content exceeds 0.01%, the weldability is significantly reduced. Therefore, the S content is 0.01% or less. In order to ensure better weldability, the S content is preferably 0.003% or less, more preferably 0.0015% or less.
- N is not an essential element but is contained as an impurity in steel, for example. From the viewpoint of weldability, the lower the N content, the better. In particular, when the N content exceeds 0.01%, the weldability is significantly reduced. Therefore, the N content is 0.01% or less. In order to ensure better weldability, the N content is preferably 0.006% or less.
- Ti, Nb, V, Cr, Mo, Cu, Ni, Ca, Mg, REM, Zr, B, and Bi are not essential elements and are appropriately contained in steel plate members and hot-press steel plates up to a predetermined amount. It is an optional element that may be present.
- Ti, Nb, and V are all elements that are effective in ensuring a stable strength of the steel sheet member. Therefore, 1 type (s) or 2 or more types selected from the group which consists of these elements may contain.
- 1 type (s) or 2 or more types selected from the group which consists of these elements may contain.
- Ti, Nb, and V if any content exceeds 0.20%, not only hot rolling and cold rolling for obtaining a steel sheet for hot pressing become difficult, but also the reverse In addition, it is difficult to stably secure the strength.
- the Ti content, the Nb content, and the V content are all 0.20% or less.
- the Cu content and the Ni content are both 1.0% or less.
- the Ti content, the Nb content, and the V content are preferably 0.003% or more, and the Cr content, the Mo content, the Cu content,
- the Ni content is preferably 0.005% or more. That is, “Ti: 0.003% to 0.20%”, “Nb: 0.003% to 0.20%”, “V: 0.003% to 0.20%”, “Cr: 0.005” % To 1.0% “,” Mo: 0.005% to 1.0% “,” Cu: 0.005% to 1.0% “, and” Ni: 0.005% to 1.0% " Preferably at least one of the above is satisfied.
- Ca, Mg, REM, and Zr are all elements that contribute to the control of inclusions, in particular to fine dispersion of inclusions, and have an effect of increasing low-temperature toughness. Therefore, 1 type (s) or 2 or more types selected from the group which consists of these elements may contain. However, if the content of any of them is more than 0.01%, the deterioration of the surface properties may become obvious. Therefore, the Ca content, the Mg content, the REM content, and the Zr content are all 0.01% or less.
- the Ca content, the Mg content, the REM content, and the Zr content are all preferably 0.0003% or more. That is, “Ca: 0.0003% to 0.01%”, “Mg: 0.0003% to 0.01%”, “REM: 0.0003% to 0.01%”, and “Zr: 0.0. Preferably, at least one of “0003% to 0.01%” is satisfied.
- REM rare earth metal
- REM content means the total content of these 17 elements.
- Lanthanoids are added industrially, for example, in the form of misch metal.
- B is an element having an effect of increasing the low temperature toughness of the steel sheet. Therefore, B may be contained. However, if the B content is more than 0.01%, the hot workability is deteriorated, and hot rolling for obtaining a hot-press steel sheet becomes difficult. Therefore, the B content is 0.01% or less. In order to improve low temperature toughness, the B content is preferably 0.0003% or more. That is, the B content is preferably 0.0003% to 0.01%.
- Bi 0% to 0.01%
- Bi is an element having an effect of making the steel structure uniform and increasing the low temperature toughness of the steel sheet. Therefore, Bi may be contained. However, if the Bi content is more than 0.01%, the hot workability is deteriorated, and hot rolling for obtaining a hot-press steel sheet becomes difficult. Therefore, the Bi content is 0.01% or less. In order to improve low temperature toughness, the Bi content is preferably 0.0003% or more. That is, the Bi content is preferably 0.0003% to 0.01%.
- the area ratio of ferrite in the surface layer portion from the surface to a depth of 15 ⁇ m is more than 1.20 times the area ratio of ferrite in the inner layer portion which is a portion excluding the surface layer portion, and the inner layer portion has an area of %, Ferrite: 10% to 70%, martensite: 30% to 90%, and the total area ratio of ferrite and martensite: 90% to 100%.
- the surface layer portion of the steel plate member means a surface portion from the surface to a depth of 15 ⁇ m
- the inner layer portion means a portion excluding this surface layer portion. That is, the inner layer portion is a portion other than the surface layer portion of the steel plate member.
- the numerical value related to the steel structure of the inner layer portion is, for example, the average value in the entire thickness direction of the inner layer portion, but the point where the depth from the surface of the steel plate member is 1/4 of the thickness of the steel plate member (hereinafter, this point) Can be represented by numerical values related to the steel structure at “1/4 depth position”. For example, if the thickness of the steel plate member is 2.0 mm, it can be represented by a numerical value at a point where the depth from the surface is 0.50 mm. This is because the steel structure at the 1/4 depth position shows an average steel structure in the thickness direction of the steel plate member. Therefore, in the present invention, the area ratio of ferrite and the area ratio of martensite measured at the 1/4 depth position are defined as the area ratio of ferrite and the area ratio of martensite in the inner layer portion, respectively.
- the surface layer portion becomes rich in ductility, and even when it has a high tensile strength of 980 MPa or more, excellent ductility and bendability Can be obtained.
- the area ratio of ferrite in the surface layer portion is 1.20 times or less than the area ratio of ferrite in the inner layer portion, minute cracks are likely to occur in the surface layer portion, and sufficient bendability cannot be obtained. Therefore, the area ratio of the ferrite in the surface layer portion is more than 1.20 times the area ratio of the ferrite in the inner layer portion.
- the area ratio of ferrite in the inner layer portion is set to 10% or more.
- the area ratio of ferrite in the inner layer portion is set to 70% or less.
- the inner layer portion of the hot-pressed steel sheet member according to the present embodiment is preferably made of ferrite and martensite, that is, the total area ratio of ferrite and martensite is preferably 100%.
- the phase or structure other than ferrite and martensite may include one or more selected from the group consisting of bainite, retained austenite, cementite, and pearlite.
- the area ratio of the phase or structure other than ferrite and martensite in the inner layer portion is set to 10% or less. That is, the total area ratio of ferrite and martensite in the inner layer portion is 90% or more.
- Such a steel plate member can be manufactured by processing a predetermined hot-press steel plate under predetermined conditions.
- This steel sheet for hot pressing has an internal oxide layer with a thickness of 30 ⁇ m or less, the area ratio of ferrite in the region from the surface to a depth of 100 ⁇ m is 30% to 90%, and the region from the surface to a depth of 100 ⁇ m. It has a steel structure in which the area ratio of pearlite having an average particle size of 5 ⁇ m or more in the excluded region is 10% to 70%.
- the thickness of the internal oxide layer is set to 30 ⁇ m or less.
- the internal oxide layer can be observed with an electron microscope, and the thickness of the internal oxide layer can be measured with an electron microscope.
- Ferrite in the region from the surface to a depth of 100 ⁇ m contributes to securing ferrite in the surface layer portion of the steel plate member. If the area ratio of ferrite in this region is less than 30%, it is difficult to make the area ratio of ferrite in the surface layer portion of the steel plate member more than 1.20 times the area ratio in the inner layer portion. Therefore, the area ratio of ferrite in the region from the surface to a depth of 100 ⁇ m is 30% or more. If the area ratio of ferrite in this region exceeds 90%, it is difficult to make the area ratio of ferrite in the inner layer portion of the steel plate member 70% or less. Therefore, the area ratio of ferrite in the region from the surface to a depth of 100 ⁇ m is 90% or less.
- Perlite having an average particle diameter of 5 ⁇ m or more in the region excluding the region from the surface to a depth of 100 ⁇ m contributes to the formation of martensite in the inner layer portion of the steel plate member.
- the area ratio of pearlite having an average particle diameter of 5 ⁇ m or more in this region is less than 10%, it is difficult to set the martensite area ratio in the inner layer portion of the steel sheet member to 30% or more. Therefore, the area ratio of this pearlite is 10% or more.
- the area ratio of pearlite having an average particle diameter of 5 ⁇ m or more in this region is more than 70%, it is difficult to make the martensite area ratio in the inner layer portion of the steel plate member 90% or less. Therefore, the area ratio of this pearlite is 70% or less.
- the area ratio of this pearlite is easily affected by the C content of the steel sheet for hot pressing.
- the C content of the hot pressing steel sheet used for the production is 0. Often over 35%.
- the average particle diameter of pearlite means the average value of the diameter of the pearlite grains in the rolling direction and the diameter in the sheet width direction (direction perpendicular to the rolling direction).
- a hot-rolled steel plate for example, a hot-rolled steel plate, a cold-rolled steel plate, a hot-dip galvanized cold-rolled steel plate and the like can be used.
- a hot-rolled steel sheet having the steel structure described above is hot-rolled by completing finish rolling at 850 ° C. or higher, holding it in the range of 720 ° C. to 650 ° C. for 10 seconds or more, and then winding in a temperature range of 600 ° C. or higher.
- a cold-rolled steel sheet and a hot-dip galvanized cold-rolled steel sheet having the above steel structure are 720 ° C. or higher and 850 ° C. or lower in a mixed gas atmosphere of nitrogen and hydrogen having a dew point of ⁇ 10 ° C. or higher after cold rolling. It can manufacture through the annealing heated to a temperature range.
- the manufacturing method of the steel plate member which concerns on this embodiment ie, the method of processing the steel plate for hot presses.
- the hot press steel plate is heated to a temperature range of 720 ° C. or higher and Ac 3 points or lower, and after this heating, the C content on the surface of the hot press steel plate is set to 0.
- a decarburization process is performed to reduce the mass by 0005 mass% to 0.015 mass%, and after this decarburization process, hot pressing is performed to cool to the Ms point at an average cooling rate of 10 ° C./second to 500 ° C./second.
- Heating temperature of steel sheet for hot pressing Temperature range of 720 ° C or more and Ac 3 points or less
- Heating of the steel sheet to be subjected to hot pressing that is, the steel sheet for hot pressing is performed in a temperature range of 720 ° C. or more and Ac 3 points or less.
- Ac 3 point is the temperature (unit: ° C.) at which the austenite single phase is defined by the following empirical formula (i).
- the heating temperature is 720 ° C. or higher.
- the heating temperature is set to Ac 3 points or less.
- the heating rate up to a temperature range of 720 ° C. or more and Ac 3 points or less and the heating time held in the temperature range are not particularly limited, but are preferably in the following ranges, respectively.
- the average heating rate in the heating up to a temperature range of 720 ° C. or more and Ac 3 points or less is 0.2 ° C./second or more and 100 ° C./second or less.
- the average heating rate is 0.2 ° C./second or more, higher productivity can be secured.
- the heating temperature can be easily controlled in the case of heating using a normal furnace.
- the heating time in the temperature range of 720 ° C. or more and Ac 3 points or less is preferably 1 minute or more and 10 minutes or less.
- the heating time is the time from when the temperature of the steel sheet reaches 720 ° C. until the end of heating.
- the end of heating is when the steel plate is taken out of the heating furnace in the case of furnace heating, and when the energization or the like is ended in the case of energization heating or induction heating.
- the heating time is more preferably 4 minutes or more.
- the steel structure of the steel plate member can be made finer, so that the low temperature toughness of the steel plate member is further improved.
- Decarburization amount in decarburization treatment 0.0005 mass% to 0.015 mass%
- ferrite is more easily formed in the portion that becomes the surface layer portion of the steel plate member than in the portion that becomes the inner layer portion.
- the amount of decarburization is less than 0.0005% by mass, the above effect cannot be obtained sufficiently, and it is difficult to make the area ratio of ferrite in the surface layer portion more than 1.20 times the area ratio of ferrite in the inner layer portion. It is. Therefore, the amount of decarburization is 0.0005 mass% or more.
- the amount of decarburization exceeds 0.015% by mass, it is difficult to secure a sufficient amount of martensite in the steel plate member due to bainite transformation during the decarburization process, that is, to obtain a tensile strength of 980 MPa or more. is there. Therefore, the amount of decarburization is 0.015 mass% or less.
- the amount of decarburization can be measured using, for example, a glow discharge emission spectrometer (GDS) or an electron probe micro analyzer (EPMA). That is, the amount of decarburization can be obtained by analyzing the surface of the steel sheet for hot pressing before and after the decarburization treatment and comparing the results.
- GDS glow discharge emission spectrometer
- EPMA electron probe micro analyzer
- the method of decarburization treatment is not particularly limited, and can be performed by air cooling, for example.
- decarburization treatment is performed by performing air cooling with appropriately controlled atmosphere, temperature, time, etc., from extraction from a heating device such as a heating furnace used for the above heating to charging into a hot press device. It can be performed. More specifically, air cooling can be performed, for example, at the time of extraction from the heating device, at the time of conveyance from the heating device to the hot press device, and at the time of charging into the hot press device.
- the air cooling time from the end of heating to the start of hot pressing is 5 seconds or more and 50 seconds or less.
- the air cooling time is preferably 30 seconds or shorter, more preferably 20 seconds or shorter.
- the air cooling time can be adjusted, for example, by adjusting the transport time from extraction from the heating device to the press die of the heating press device.
- the average cooling rate is set to 10 ° C./second or more. If the average cooling rate exceeds 500 ° C./second, it becomes extremely difficult to keep the members soaking, and the strength becomes unstable. Accordingly, the average cooling rate is set to 500 ° C./second or less.
- the cooling in the hot press is performed by previously setting a steel mold used for forming a heated steel sheet to room temperature or a temperature of about several tens of degrees Celsius, and the steel sheet comes into contact with the mold. . Therefore, the average cooling rate can be controlled by, for example, a change in heat capacity accompanying a change in the dimensions of the mold.
- the average cooling rate can also be controlled by changing the material of the mold to a different metal (such as Cu).
- the average cooling rate can also be controlled by using a water-cooled mold and changing the amount of cooling water flowing through the mold.
- the average cooling rate can also be controlled by forming a plurality of grooves in the mold in advance and passing water through the grooves during hot pressing.
- the average cooling rate can also be controlled by raising the hot press machine in the middle of hot pressing and flowing water during that time.
- the average cooling rate can also be controlled by adjusting the mold clearance and changing the contact area of the mold with the steel plate.
- the following three types can be mentioned.
- the cooling rate may be increased by increasing the amount of water according to the temperature.
- the form of molding in the hot press in this embodiment is not particularly limited.
- Examples of the form of molding include bending, drawing, overhang molding, hole expansion molding, and flange molding. What is necessary is just to select the form of shaping
- molding suitably with the kind of target steel plate member.
- Representative examples of the steel plate member include a door guard bar and a bumper reinforcement which are reinforcing parts for automobiles.
- hot forming is not limited to hot pressing as long as the steel sheet can be cooled simultaneously with or immediately after forming. For example, roll forming may be performed as hot forming.
- the steel sheet member according to the present embodiment can be manufactured by performing such a series of treatments on the predetermined hot-press steel sheet. That is, a hot-pressed steel sheet member having a desired steel structure and a tensile strength of 980 MPa and having excellent ductility and bendability can be obtained.
- ductility can be evaluated by the total elongation (EL) of the tensile test, and in this embodiment, the total elongation of the tensile test is preferably 12% or more. The total elongation is more preferably 14% or more.
- the bendability can be evaluated by the limit bending radius of a V-bending test with a tip angle of 90 °. In this embodiment, when the thickness of a hot-pressed steel sheet member is expressed as t, this limit bending radius is It is preferably 5 ⁇ t or less.
- ⁇ Shot blasting may be performed after hot pressing and cooling.
- the scale can be removed by shot blasting. Shot blasting also has the effect of introducing compressive stress into the surface of the steel sheet member, so that delayed fracture is suppressed and fatigue strength is improved.
- the hot press steel sheet is heated to a temperature range of 720 ° C. or more and Ac 3 points or less to cause austenite transformation to some extent. Molding is performed. Therefore, the mechanical properties of the steel sheet for hot pressing at room temperature before heating are not important.
- the steel plate member according to the present embodiment can also be manufactured through hot pressing with pre-forming.
- the hot-press steel plate is pre-formed by pressing it with a mold having a predetermined shape, and is put into the same mold and pressed.
- a hot-pressed steel sheet member may be produced by applying pressure and quenching.
- the type of steel sheet for hot pressing and its steel structure are not limited, but it is preferable to use a steel sheet having as low strength and ductility as possible in order to facilitate pre-forming.
- the tensile strength is preferably 700 MPa or less.
- the full hard steel plate used in this experiment is a steel plate obtained by cold rolling a hot rolled steel plate having a thickness of 3.6 mm, and is not annealed after cold rolling.
- the numerical value (unit:%) in the column of “Ferrite area ratio” in Table 2 indicates the ferrite area ratio in the region from the surface of the steel sheet to 100 ⁇ m.
- the numerical value (unit:%) in the column of “perlite area ratio” in Table 2 indicates the area ratio of pearlite having an average particle diameter of 5 ⁇ m or more in a region excluding the region from the surface to a depth of 100 ⁇ m.
- These area ratios are average values of values calculated by performing an image analysis of an electron microscope observation image of a cross section orthogonal to the rolling direction and a cross section orthogonal to the sheet width direction (direction orthogonal to the rolling direction). .
- the steel sheet After producing the steel sheet to be subjected to heat treatment, the steel sheet was heated under the conditions shown in Table 2 in a gas heating furnace with an air-fuel ratio of 0.9.
- Heating time indicates the time from when the temperature of the steel sheet reaches 720 ° C. after the steel sheet is inserted into the gas heating furnace until the steel sheet is removed from the gas heating furnace.
- heating temperature indicates not the temperature of the steel sheet but the temperature in the gas heating furnace.
- the steel plate was taken out from the gas heating furnace, the steel plate was decarburized by air cooling, the steel plate was hot pressed, and the steel plate was cooled. In the hot press, a flat steel mold was used. That is, no molding was performed.
- test steel plates 28 kinds of test materials (test steel plates) were produced.
- test material steel plate for test
- hot-pressed steel plate the test material (steel plate for test) may be referred to as “hot-pressed steel plate”.
- the area ratio of ferrite in the surface layer part, the area ratio of ferrite in the inner layer part, and the area ratio of martensite in the inner layer part were determined for each of these steel sheets. These area ratios are average values of values calculated by performing an image analysis of an electron microscope observation image of a cross section orthogonal to the rolling direction and a cross section orthogonal to the sheet width direction (direction orthogonal to the rolling direction). .
- the region from the surface of the steel plate to a depth of 15 ⁇ m was observed.
- the observation was performed at a 1/4 depth position.
- Table 3 shows the ratio of the area ratio of ferrite in the surface layer portion to the area ratio of ferrite in the inner layer portion, and the area ratio of ferrite and martensite in the inner layer portion.
- TS tensile strength
- EL total elongation
- evaluation of bendability were performed.
- a JIS No. 5 tensile test piece was taken from each steel plate in a direction perpendicular to the rolling direction and subjected to a tensile test.
- a test piece (30 mm ⁇ 60 mm) was sampled from each steel plate so that the bending ridge line was in the rolling direction, and a V-bending test was performed with a tip angle of 90 ° and a tip radius of 10 mm.
- the hot-pressed steel sheet is hot-pressed using a flat steel mold, but not hot-pressed.
- the mechanical properties of the hot-pressed steel sheet reflect the mechanical properties of the hot-pressed steel sheet member produced by receiving a thermal history similar to that of the hot press of this experiment during forming. That is, regardless of the presence or absence of forming during hot pressing, if the thermal history is substantially the same, the subsequent mechanical properties are also substantially the same.
- the test sample No. 2, no. 6, no. 8-No. 10, no. 12-No. 14, no. 16, no. 18, no. 22, no. 23, no. 26, and no. No. 27 showed excellent ductility and bendability. From this, it can be seen that the present invention exhibits an excellent effect regardless of whether the steel sheet for hot pressing is a full hard steel sheet, a cold-rolled steel sheet, a hot-rolled steel sheet, or a hot-dip galvanized cold-rolled steel sheet.
- specimen No. No. 1 had poor ductility because the chemical composition was outside the scope of the present invention.
- Specimen No. In No. 4 since the manufacturing conditions were outside the scope of the present invention and the steel structure after hot pressing was also outside the scope of the present invention, the bendability was poor.
- Specimen No. 21 had a chemical composition outside the range of the present invention, and thus a tensile strength of 980 MPa or more was not obtained after cooling (after quenching).
- Specimen No. 24 the manufacturing conditions were outside the scope of the present invention, and the steel structure after hot pressing was also outside the scope of the present invention, so the ductility was poor.
- Specimen No. 25 had poor bendability because the chemical composition was outside the scope of the present invention.
- Specimen No. In No. 28 the chemical composition was outside the scope of the present invention, and the steel structure after hot pressing was also outside the scope of the present invention, so the ductility was poor.
- sample No. which is a comparative example. 17 the ratio of the area ratio of the ferrite in the surface layer portion to the area ratio of the ferrite in the inner layer portion was less than 1.20, but the bendability was good, but this had a tensile strength (TS) of 591 MPa. This is because it is very low.
- TS tensile strength
- the present invention can be used, for example, in the manufacturing industry and the use industry of body structure parts of automobiles in which excellent collision characteristics are regarded as important.
- the present invention can also be used in other industries such as manufacturing and using industries of machine structural parts.
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Abstract
Description
質量%で、
C :0.10%~0.34%、
Si:0.5%~2.0%、
Mn:1.0%~3.0%、
sol.Al:0.001%~1.0%、
P :0.05%以下、
S :0.01%以下、
N :0.01%以下、
Ti:0%~0.20%、
Nb:0%~0.20%、
V :0%~0.20%、
Cr:0%~1.0%、
Mo:0%~1.0%、
Cu:0%~1.0%、
Ni:0%~1.0%、
Ca:0%~0.01%、
Mg:0%~0.01%、
REM:0%~0.01%、
Zr:0%~0.01%、
B :0%~0.01%、
Bi:0%~0.01%、
残部:Fe及び不純物
で表される化学組成を有し、
表面から深さ15μmまでの表層部におけるフェライトの面積率が、前記表層部を除いた部位である内層部におけるフェライトの面積率の1.20倍超であり、前記内層部が、面積%で、フェライト:10%~70%、マルテンサイト:30%~90%、フェライト及びマルテンサイトの合計面積率:90%~100%である鋼組織を有し、
引張強度が980MPa以上であることを特徴とする熱間プレス鋼板部材。
前記化学組成が、質量%で、
Ti:0.003%~0.20%、
Nb:0.003%~0.20%、
V :0.003%~0.20%、
Cr:0.005%~1.0%、
Mo:0.005%~1.0%、
Cu:0.005%~1.0%、及び
Ni:0.005%~1.0%
からなる群から選択された1種又は2種以上を含有することを特徴とする(1)に記載の熱間プレス鋼板部材。
前記化学組成が、質量%で、
Ca:0.0003%~0.01%、
Mg:0.0003%~0.01%、
REM:0.0003%~0.01%、及び
Zr:0.0003%~0.01%
からなる群から選択された1種又は2種以上を含有することを特徴とする(1)又は(2)に記載の熱間プレス鋼板部材。
前記化学組成が、質量%で、B:0.0003%~0.01%を含有することを特徴とする(1)~(3)のいずれかに記載の熱間プレス鋼板部材。
前記化学組成が、質量%で、Bi:0.0003%~0.01%を含有することを特徴とする(1)~(4)のいずれかに記載の熱間プレス鋼板部材。
質量%で、
C :0.11%~0.35%、
Si:0.5%~2.0%、
Mn:1.0%~3.0%、
sol.Al:0.001%~1.0%、
P :0.05%以下、
S :0.01%以下、
N :0.01%以下、
Ti:0%~0.20%、
Nb:0%~0.20%、
V :0%~0.20%、
Cr:0%~1.0%、
Mo:0%~1.0%、
Cu:0%~1.0%、
Ni:0%~1.0%、
Ca:0%~0.01%、
Mg:0%~0.01%、
REM:0%~0.01%、
Zr:0%~0.01%、
B :0%~0.01%、
Bi:0%~0.01%、
残部:Fe及び不純物
で表される化学組成を有し、
厚さが30μm以下の内部酸化層を有し、
表面から深さ100μmまでの領域におけるフェライトの面積率が30%~90%、表面から深さ100μmまでの領域を除く領域における平均粒径が5μm以上のパーライトの面積率が10%~70%の鋼組織を有することを特徴とする熱間プレス用鋼板。
前記化学組成が、質量%で、
Ti:0.003%~0.20%、
Nb:0.003%~0.20%、
V :0.003%~0.20%、
Cr:0.005%~1.0%、
Mo:0.005%~1.0%、
Cu:0.005%~1.0%、及び
Ni:0.005%~1.0%
からなる群から選択された1種又は2種以上を含有することを特徴とする(6)に記載の熱間プレス用鋼板。
前記化学組成が、質量%で、
Ca:0.0003%~0.01%、
Mg:0.0003%~0.01%、
REM:0.0003%~0.01%、及び
Zr:0.0003%~0.01%
からなる群から選択された1種又は2種以上を含有することを特徴とする(6)又は(7)に記載の熱間プレス用鋼板。
前記化学組成が、質量%で、B:0.0003%~0.01%を含有することを特徴とする(6)~(8)のいずれかに記載の熱間プレス用鋼板。
前記化学組成が、質量%で、Bi:0.0003%~0.01%を含有することを特徴とする(6)~(9)のいずれかに記載の熱間プレス用鋼板。
(6)~(10)のいずれかに記載の熱間プレス用鋼板を、720℃以上Ac3点以下の温度域に加熱する工程と、
前記加熱の後に、前記熱間プレス用鋼板の表面におけるC含有量を0.0005質量%~0.015質量%減じる脱炭処理を行う工程と、
前記脱炭処理の後に、熱間プレスを行い、10℃/秒~500℃/秒の平均冷却速度でMs点まで冷却する工程と、
を有することを特徴とする熱間プレス鋼板部材の製造方法。
前記脱炭処理を行う工程は、5秒間~50秒間の空冷を行う工程を有することを特徴とする(11)に記載の熱間プレス鋼板部材の製造方法。
Cは、熱間プレス用鋼板の焼入れ性を高め、かつ鋼板部材の強度を主に決定する非常に重要な元素である。鋼板部材のC含有量が0.10%未満では、980MPa以上の引張強度を確保することが困難である。従って、鋼板部材のC含有量は0.10%以上とする。鋼板部材のC含有量が0.34%超では、曲げ性及び溶接性の低下が顕著である。従って、鋼板部材のC含有量は0.34%以下とする。熱間プレス用鋼板を得るための熱間圧延及び冷間圧延における生産性の観点から、熱間プレス用鋼板のC含有量は好ましくは0.30%以下であり、より好ましくは0.25%以下である。後述のように、熱間プレス鋼板部材の製造の際に熱間プレス用鋼板の脱炭処理が行われるため、熱間プレス用鋼板にはその分だけ多くCが含有され、そのC含有量は0.11%以上0.35%以下とする。
Siは、鋼板部材の延性の向上及び鋼板部材の強度の安定した確保に非常に効果のある元素である。Si含有量が0.5%未満では、上記作用を得ることが困難である。従って、Si含有量は0.5%以上とする。Si含有量が2.0%超では、上記作用による効果は飽和して経済的に不利となるうえに、めっき濡れ性の低下が著しくなり、不めっきが多発する。従って、Si含有量は2.0%以下とする。溶接性を向上させる観点から、Si含有量は好ましくは0.7%以上である。鋼板部材の表面欠陥を抑える観点から、Si含有量は好ましくは1.8%以下である。
Mnは、熱間プレス用鋼板の焼入れ性の向上及び鋼板部材の強度の確保に非常に効果のある元素である。Mn含有量が1.0%未満では、鋼板部材に980MPa以上の引張強度を確保することが非常に困難である。従って、Mn含有量は1.0%以上とする。上記作用をより確実に得るために、Mn含有量は好ましくは1.1%以上である。Mn含有量が3.0%超では、鋼板部材の鋼組織が顕著なバンド状になり、曲げ性の劣化が顕著になる。従って、Mn含有量は3.0%以下とする。熱間プレス用鋼板を得るための熱間圧延及び冷間圧延における生産性の観点から、Mn含有量は好ましくは2.5%以下である。
Alは、鋼を脱酸して鋼材を健全化する作用を有する元素である。sol.Al含有量が0.001%未満では、上記作用を得ることが困難である。従って、sol.Al含有量は0.001%以上とする。上記作用をより確実に得るために、sol.Al含有量は好ましくは0.015%以上である。sol.Al含有量が1.0%超では、溶接性の低下が著しくなるとともに、酸化物系介在物が増加し、表面性状の劣化が著しくなる。従って、sol.Al含有量は1.0%以下とする。より良好な表面性状を得るために、sol.Al含有量は好ましくは0.080%以下である。
Pは、必須元素ではなく、例えば鋼中に不純物として含有される。溶接性の観点から、P含有量は低ければ低いほどよい。特にP含有量が0.05%超で、溶接性の低下が著しい。従って、P含有量は0.05%以下とする。より良好な溶接性を確保するために、P含有量は好ましくは0.018%以下である。その一方で、Pは、固溶強化により鋼の強度を高める作用を有する。この作用を得るために、0.003%以上のPが含有されていてもよい。
Sは、必須元素ではなく、例えば鋼中に不純物として含有される。溶接性の観点から、S含有量は低ければ低いほどよい。特にS含有量が0.01%超で、溶接性の低下が著しい。従って、S含有量は0.01%以下とする。より良好な溶接性を確保するために、S含有量は好ましくは0.003%以下であり、より好ましくは0.0015%以下である。
Nは、必須元素ではなく、例えば鋼中に不純物として含有される。溶接性の観点から、N含有量は低ければ低いほどよい。特にN含有量が0.01%超で、溶接性の低下が著しい。従って、N含有量は0.01%以下とする。より良好な溶接性を確保するために、N含有量は好ましくは0.006%以下である。
Ti、Nb、V、Cr、Mo、Cu、及びNiは、いずれも鋼板部材の強度の安定した確保に効果のある元素である。従って、これらの元素からなる群から選択された1種又は2種以上が含有されていてもよい。しかし、Ti、Nb及びVについては、いずれかの含有量が0.20%超であると、熱間プレス用鋼板を得るための熱間圧延及び冷間圧延が困難になるだけでなく、逆に、強度を安定して確保することが困難になる。従って、Ti含有量、Nb含有量、及びV含有量は、いずれも0.20%以下とする。Cr及びMoについては、いずれかの含有量が1.0%超であると、熱間プレス用鋼板を得るための熱間圧延及び冷間圧延が困難になる。従って、Cr含有量及びMo含有量は、いずれも1.0%以下とする。Cu及びNiについては、いずれかの含有量が1.0%であると、上記作用による効果は飽和して経済的に不利となるうえに、熱間プレス用鋼板を得るための熱間圧延及び冷間圧延が困難になる。従って、Cu含有量及びNi含有量は、いずれも1.0%以下とする。鋼板部材の強度の安定した確保のために、Ti含有量、Nb含有量、及びV含有量は、いずれも好ましくは0.003%以上であり、Cr含有量、Mo含有量、Cu含有量、及びNi含有量は、いずれも好ましくは0.005%以上である。つまり、「Ti:0.003%~0.20%」、「Nb:0.003%~0.20%」、「V:0.003%~0.20%」、「Cr:0.005%~1.0%」、「Mo:0.005%~1.0%」、「Cu:0.005%~1.0%」、及び「Ni:0.005%~1.0%」のうちの少なくとも一つが満たされることが好ましい。
Ca、Mg、REM、及びZrは、いずれも介在物の制御、特に、介在物の微細分散化に寄与し、低温靭性を高める作用を有する元素である。従って、これらの元素からなる群から選択された1種又は2種以上が含有されていてもよい。しかし、いずれかの含有量が0.01%超であると、表面性状の劣化が顕在化する場合がある。従って、Ca含有量、Mg含有量、REM含有量、及びZr含有量は、いずれも0.01%以下とする。低温靭性の向上のために、Ca含有量、Mg含有量、REM含有量、及びZr含有量は、いずれも好ましくは0.0003%以上である。つまり、「Ca:0.0003%~0.01%」、「Mg:0.0003%~0.01%」、「REM:0.0003%~0.01%」、及び「Zr:0.0003%~0.01%」のうちの少なくとも一つが満たされることが好ましい。
Bは、鋼板の低温靭性を高める作用を有する元素である。従って、Bが含有されていてもよい。しかし、B含有量が0.01%超であると、熱間加工性が劣化して、熱間プレス用鋼板を得るための熱間圧延が困難になる。従って、B含有量は0.01%以下とする。低温靭性の向上のために、B含有量は好ましくは0.0003%以上である。つまり、B含有量は0.0003%~0.01%であることが好ましい。
Biは、鋼組織を均一にし、鋼板の低温靭性を高める作用を有する元素である。従って、Biが含有されていてもよい。しかし、Bi含有量が0.01%超であると、熱間加工性が劣化して、熱間プレス用鋼板を得るための熱間圧延が困難になる。従って、Bi含有量は0.01%以下とする。低温靭性の向上のために、Bi含有量は好ましくは0.0003%以上である。つまり、Bi含有量は0.0003%~0.01%であることが好ましい。
内層部におけるフェライトの面積率よりも表層部におけるフェライトの面積率を高めることにより、表層部が延性に富むようになり、980MPa以上という高い引張強度を有する場合であっても、優れた延性及び曲げ性を得ることができる。表層部におけるフェライトの面積率が内層部におけるフェライトの面積率の1.20倍以下では、微小なクラックが表層部に発生しやすくなり、十分な曲げ性を得ることができない。従って、表層部におけるフェライトの面積率は内層部におけるフェライトの面積率の1.20倍超とする。
内層部に適量のフェライトを存在させることにより、良好な延性を得ることができる。内層部におけるフェライトの面積率が10%未満では、フェライトの殆どが孤立し、良好な延性を得ることができない。従って、内層部におけるフェライトの面積率は10%以上とする。内層部におけるフェライトの面積率が70%超では、強化相であるマルテンサイトを十分に確保できなくなり、980MPa以上の引張強度を確保することが困難である。従って、内層部におけるフェライトの面積率は70%以下とする。
内層部に適量のマルテンサイトを存在させることにより、高い強度を得ることができる。内層部におけるマルテンサイトの面積率が30%未満では、980MPa以上の引張強度を確保することが困難である。従って、内層部におけるマルテンサイトの面積率は30%以上とする。内層部におけるマルテンサイトの面積率が90%超では、フェライトの面積率が10%未満となり、上述したように、良好な延性を得ることができない。従って、内層部におけるマルテンサイトの面積率は90%以下とする。
本実施形態に係る熱間プレス鋼板部材の内層部は、フェライト及びマルテンサイトからなること、つまり、フェライト及びマルテンサイトの合計面積率が100%であることが好ましい。しかし、製造条件によっては、フェライト及びマルテンサイト以外の相又は組織として、ベイナイト、残留オーステナイト、セメンタイト、及びパーライトからなる群から選択された1種又は2種以上が含まれることもある。この場合、フェライト及びマルテンサイト以外の相又は組織の面積率が10%超であると、これらの相又は組織の影響により、目的とする特性が得られないことがある。従って、内層部におけるフェライト及びマルテンサイト以外の相又は組織の面積率は10%以下とする。すなわち、内層部におけるフェライト及びマルテンサイトの合計面積率は90%以上とする。
内部酸化層が厚いほど鋼板部材の曲げ性が低下し、内部酸化層の厚さが30μm超でこの曲げ性の低下が顕著である。従って、内部酸化層の厚さは30μm以下とする。例えば、内部酸化層は電子顕微鏡で観察することができ、内部酸化層の厚さは電子顕微鏡で測定することができる。
表面から深さ100μmまでの領域におけるフェライトは、鋼板部材の表層部におけるフェライトの確保に寄与する。この領域におけるフェライトの面積率が30%未満では、鋼板部材の表層部におけるフェライトの面積率を内層部における面積率の1.20倍超とすることが困難である。従って、表面から深さ100μmまでの領域におけるフェライトの面積率は30%以上とする。この領域におけるフェライトの面積率が90%超では、鋼板部材の内層部におけるフェライトの面積率を70%以下とすることが困難である。従って、表面から深さ100μmまでの領域におけるフェライトの面積率は90%以下とする。
表面から深さ100μmまでの領域を除く領域における平均粒径が5μm以上のパーライトは、鋼板部材の内層部におけるマルテンサイトの生成に寄与する。この領域における平均粒径が5μm以上のパーライトの面積率が10%未満では、鋼板部材の内層部におけるマルテンサイトの面積率を30%以上とすることが困難である。従って、このパーライトの面積率は10%以上とする。この領域における平均粒径が5μm以上のパーライトの面積率が70%超では、鋼板部材の内層部におけるマルテンサイトの面積率を90%以下とすることが困難である。従って、このパーライトの面積率は70%以下とする。なお、このパーライトの面積率は熱間プレス用鋼板のC含有量の影響を受けやすく、パーライトの面積率が70%超の場合、その製造に用いた熱間プレス用鋼板のC含有量が0.35%超となっていることが多い。従って、表面から深さ100μmまでの領域を除く領域における平均粒径が5μm以上のパーライトの面積率を70%以下とするためには、例えばC含有量が0.35%以下の熱間プレス用鋼板を用いることが効果的である。ここで、パーライトの平均粒径とは、パーライト粒の圧延方向の直径と板幅方向(圧延方向に直交する方向)の直径との平均値を意味する。
熱間プレスに供する鋼板、つまり熱間プレス用鋼板の加熱は、720℃以上Ac3点以下の温度域において行う。Ac3点は、下記実験式(i)により規定されるオーステナイト単相になる温度(単位:℃)である。
-11×Cr-20×Cu+700×P+400×Al+50×Ti ・・・ (i)
ここで、上記式中における元素記号は、鋼板の化学組成における各元素の含有量(単位:質量%)を示す。
脱炭処理により、鋼板部材の表層部となる部分に内層部となる部分よりもフェライトが形成されやすくなる。脱炭の量が0.0005質量%未満では、上記作用を十分に得ることができず、表層部におけるフェライトの面積率を内層部におけるフェライトの面積率の1.20倍超とすることが困難である。従って、脱炭の量は0.0005質量%以上とする。脱炭の量が0.015質量%超では、脱炭処理中にベイナイト変態が生じて鋼板部材に十分な量のマルテンサイトを確保すること、つまり、980MPa以上の引張強度を得ることが困難である。従って、脱炭の量は0.015質量%以下とする。脱炭の量は、例えば、グロー放電発光分光分析装置(GDS:glow discharge spectroscope)又は電子線マイクロ分析装置(EPMA:electron probe micro analyzer)を用いて測定することができる。つまり、脱炭処理の前後で熱間プレス用鋼板の表面の分析を行い、その結果を比較すれば脱炭の量を求めることができる。
空冷後には、熱間プレスを行い、10℃/秒以上500℃/秒以下の平均冷却速度でMs点まで冷却する。平均冷却速度が10℃/秒未満では、ベイナイト変態等の拡散型変態が過度に進行してしまい、強化相であるマルテンサイトの面積率を確保できなくなり、鋼板部材の引張強度を980MPa以上とすることが困難である。従って、この平均冷却速度は10℃/秒以上とする。平均冷却速度が500℃/秒超では、部材の均熱を保つことが極めて困難となり、強度が安定しなくなる。従って、この平均冷却速度は500℃/秒以下とする。
(a)400℃到達直後に、熱容量の異なる金型又は室温状態の金型に鋼板を移動させる。
(b)水冷金型を用い、400℃到達直後に金型中の流水量を増加させる。
(c)400℃到達直後に、金型と鋼板との間に水を流す。この方法では、温度に応じて水量を増加させることでより冷却速度を高めてもよい。
Claims (12)
- 質量%で、
C :0.10%~0.34%、
Si:0.5%~2.0%、
Mn:1.0%~3.0%、
sol.Al:0.001%~1.0%、
P :0.05%以下、
S :0.01%以下、
N :0.01%以下、
Ti:0%~0.20%、
Nb:0%~0.20%、
V :0%~0.20%、
Cr:0%~1.0%、
Mo:0%~1.0%、
Cu:0%~1.0%、
Ni:0%~1.0%、
Ca:0%~0.01%、
Mg:0%~0.01%、
REM:0%~0.01%、
Zr:0%~0.01%、
B :0%~0.01%、
Bi:0%~0.01%、
残部:Fe及び不純物
で表される化学組成を有し、
表面から深さ15μmまでの表層部におけるフェライトの面積率が、前記表層部を除いた部位である内層部におけるフェライトの面積率の1.20倍超であり、前記内層部が、面積%で、フェライト:10%~70%、マルテンサイト:30%~90%、フェライト及びマルテンサイトの合計面積率:90%~100%である鋼組織を有し、
引張強度が980MPa以上であることを特徴とする熱間プレス鋼板部材。 - 前記化学組成が、質量%で、
Ti:0.003%~0.20%、
Nb:0.003%~0.20%、
V :0.003%~0.20%、
Cr:0.005%~1.0%、
Mo:0.005%~1.0%、
Cu:0.005%~1.0%、及び
Ni:0.005%~1.0%
からなる群から選択された1種又は2種以上を含有することを特徴とする請求項1に記載の熱間プレス鋼板部材。 - 前記化学組成が、質量%で、
Ca:0.0003%~0.01%、
Mg:0.0003%~0.01%、
REM:0.0003%~0.01%、及び
Zr:0.0003%~0.01%
からなる群から選択された1種又は2種以上を含有することを特徴とする請求項1又は2に記載の熱間プレス鋼板部材。 - 前記化学組成が、質量%で、B:0.0003%~0.01%を含有することを特徴とする請求項1乃至3のいずれか1項に記載の熱間プレス鋼板部材。
- 前記化学組成が、質量%で、Bi:0.0003%~0.01%を含有することを特徴とする請求項1乃至4のいずれか1項に記載の熱間プレス鋼板部材。
- 質量%で、
C :0.11%~0.35%、
Si:0.5%~2.0%、
Mn:1.0%~3.0%、
sol.Al:0.001%~1.0%、
P :0.05%以下、
S :0.01%以下、
N :0.01%以下、
Ti:0%~0.20%、
Nb:0%~0.20%、
V :0%~0.20%、
Cr:0%~1.0%、
Mo:0%~1.0%、
Cu:0%~1.0%、
Ni:0%~1.0%、
Ca:0%~0.01%、
Mg:0%~0.01%、
REM:0%~0.01%、
Zr:0%~0.01%、
B :0%~0.01%、
Bi:0%~0.01%、
残部:Fe及び不純物
で表される化学組成を有し、
厚さが30μm以下の内部酸化層を有し、
表面から深さ100μmまでの領域におけるフェライトの面積率が30%~90%、表面から深さ100μmまでの領域を除く領域における平均粒径が5μm以上のパーライトの面積率が10%~70%の鋼組織を有することを特徴とする熱間プレス用鋼板。 - 前記化学組成が、質量%で、
Ti:0.003%~0.20%、
Nb:0.003%~0.20%、
V :0.003%~0.20%、
Cr:0.005%~1.0%、
Mo:0.005%~1.0%、
Cu:0.005%~1.0%、及び
Ni:0.005%~1.0%
からなる群から選択された1種又は2種以上を含有することを特徴とする請求項6に記載の熱間プレス用鋼板。 - 前記化学組成が、質量%で、
Ca:0.0003%~0.01%、
Mg:0.0003%~0.01%、
REM:0.0003%~0.01%、及び
Zr:0.0003%~0.01%
からなる群から選択された1種又は2種以上を含有することを特徴とする請求項6又は7に記載の熱間プレス用鋼板。 - 前記化学組成が、質量%で、B:0.0003%~0.01%を含有することを特徴とする請求項6乃至8のいずれか1項に記載の熱間プレス用鋼板。
- 前記化学組成が、質量%で、Bi:0.0003%~0.01%を含有することを特徴とする請求項6乃至9のいずれか1項に記載の熱間プレス用鋼板。
- 請求項6乃至10のいずれか1項に記載の熱間プレス用鋼板を、720℃以上Ac3点以下の温度域に加熱する工程と、
前記加熱の後に、前記熱間プレス用鋼板の表面におけるC含有量を0.0005質量%~0.015質量%減じる脱炭処理を行う工程と、
前記脱炭処理の後に、熱間プレスを行い、10℃/秒~500℃/秒の平均冷却速度でMs点まで冷却する工程と、
を有することを特徴とする熱間プレス鋼板部材の製造方法。 - 前記脱炭処理を行う工程は、5秒間~50秒間の空冷を行う工程を有することを特徴とする請求項11に記載の熱間プレス鋼板部材の製造方法。
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| KR1020167017162A KR101833655B1 (ko) | 2013-12-27 | 2013-12-27 | 열간 프레스 강판 부재, 그 제조 방법 및 열간 프레스용 강판 |
| JP2015554460A JPWO2015097882A1 (ja) | 2013-12-27 | 2013-12-27 | 熱間プレス鋼板部材、その製造方法及び熱間プレス用鋼板 |
| MX2016008169A MX2016008169A (es) | 2013-12-27 | 2013-12-27 | Miembro de lamina de acero prensada en caliente, metodo de fabricacion del mismo, y lamina de acero para prensado en caliente. |
| CA2934597A CA2934597C (en) | 2013-12-27 | 2013-12-27 | Hot-pressed steel sheet member, method of manufacturing the same, and steel sheet for hot pressing |
| PCT/JP2013/085167 WO2015097882A1 (ja) | 2013-12-27 | 2013-12-27 | 熱間プレス鋼板部材、その製造方法及び熱間プレス用鋼板 |
| US15/101,772 US10273555B2 (en) | 2013-12-27 | 2013-12-27 | Hot-pressed steel sheet member |
| RU2016129618A RU2631216C1 (ru) | 2013-12-27 | 2013-12-27 | Горячепрессованная стальная листовая деталь, способ ее изготовления и стальной лист для горячего прессования |
| EP13900077.2A EP3088544A4 (en) | 2013-12-27 | 2013-12-27 | Hot-pressed steel sheet member, production method for same, and steel sheet for hot pressing |
| CN201380081705.4A CN105829561B (zh) | 2013-12-27 | 2013-12-27 | 热压钢板构件、其制造方法以及热压用钢板 |
| US16/263,497 US20190161821A1 (en) | 2013-12-27 | 2019-01-31 | Steel sheet for hot pressing, and method of manufacturing the hot-pressed steel sheet member |
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| US16/263,497 Division US20190161821A1 (en) | 2013-12-27 | 2019-01-31 | Steel sheet for hot pressing, and method of manufacturing the hot-pressed steel sheet member |
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| US12129526B2 (en) | 2018-12-28 | 2024-10-29 | Baoshan Iron & Steel Co., Ltd. | Gradient steel material having surface layer with ferrite and inner layer with ferrite + pearlite and manufacturing method |
| JP2022513499A (ja) * | 2018-12-28 | 2022-02-08 | バオシャン アイアン アンド スティール カンパニー リミテッド | フェライトの表層とフェライト+パーライトの内層を有する勾配鉄鋼材料及びその製造方法 |
| JP7239704B2 (ja) | 2018-12-28 | 2023-03-14 | バオシャン アイアン アンド スティール カンパニー リミテッド | フェライトの表層とフェライト+パーライトの内層を有する勾配鉄鋼材料及びその製造方法 |
| KR20240037287A (ko) | 2021-08-27 | 2024-03-21 | 닛폰세이테츠 가부시키가이샤 | 강판 및 프레스 성형품 |
| WO2023026468A1 (ja) | 2021-08-27 | 2023-03-02 | 日本製鉄株式会社 | 鋼板およびプレス成形品 |
| WO2024122124A1 (ja) * | 2022-12-09 | 2024-06-13 | 日本製鉄株式会社 | ホットスタンプ成形体 |
| WO2024122122A1 (ja) * | 2022-12-09 | 2024-06-13 | 日本製鉄株式会社 | 鋼板及びホットスタンプ成形体 |
| WO2024122118A1 (ja) * | 2022-12-09 | 2024-06-13 | 日本製鉄株式会社 | めっき鋼板 |
| JPWO2024122118A1 (ja) * | 2022-12-09 | 2024-06-13 | ||
| JP7804239B2 (ja) | 2022-12-09 | 2026-01-22 | 日本製鉄株式会社 | めっき鋼板 |
Also Published As
| Publication number | Publication date |
|---|---|
| CA2934597C (en) | 2019-01-15 |
| KR101833655B1 (ko) | 2018-02-28 |
| RU2631216C1 (ru) | 2017-09-19 |
| CN105829561A (zh) | 2016-08-03 |
| CN105829561B (zh) | 2019-06-28 |
| CA2934597A1 (en) | 2015-07-02 |
| JPWO2015097882A1 (ja) | 2017-03-23 |
| US10273555B2 (en) | 2019-04-30 |
| KR20160091399A (ko) | 2016-08-02 |
| US20170029915A1 (en) | 2017-02-02 |
| US20190161821A1 (en) | 2019-05-30 |
| EP3088544A4 (en) | 2017-07-19 |
| MX2016008169A (es) | 2016-09-29 |
| EP3088544A1 (en) | 2016-11-02 |
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