WO2015074297A1 - Composition de résine abs résistante à la chaleur formée par moulage par soufflage et procédé de préparation correspondant - Google Patents
Composition de résine abs résistante à la chaleur formée par moulage par soufflage et procédé de préparation correspondant Download PDFInfo
- Publication number
- WO2015074297A1 WO2015074297A1 PCT/CN2013/088527 CN2013088527W WO2015074297A1 WO 2015074297 A1 WO2015074297 A1 WO 2015074297A1 CN 2013088527 W CN2013088527 W CN 2013088527W WO 2015074297 A1 WO2015074297 A1 WO 2015074297A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- weight
- parts
- resin composition
- heat
- graft copolymer
- Prior art date
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- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 title claims abstract description 73
- 239000011342 resin composition Substances 0.000 title claims abstract description 71
- 238000000071 blow moulding Methods 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 33
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 49
- 239000000203 mixture Substances 0.000 claims abstract description 46
- 238000000034 method Methods 0.000 claims abstract description 19
- 238000001125 extrusion Methods 0.000 claims abstract description 6
- 238000001816 cooling Methods 0.000 claims abstract description 3
- 238000001035 drying Methods 0.000 claims abstract description 3
- 229920000578 graft copolymer Polymers 0.000 claims description 77
- 239000003795 chemical substances by application Substances 0.000 claims description 44
- 229920001577 copolymer Polymers 0.000 claims description 38
- 239000000178 monomer Substances 0.000 claims description 33
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 25
- 229920001971 elastomer Polymers 0.000 claims description 23
- 239000005060 rubber Substances 0.000 claims description 23
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 21
- 229920002857 polybutadiene Polymers 0.000 claims description 19
- 230000009477 glass transition Effects 0.000 claims description 13
- 239000002245 particle Substances 0.000 claims description 13
- 230000000379 polymerizing effect Effects 0.000 claims description 13
- 229920000642 polymer Polymers 0.000 claims description 9
- 229920006029 tetra-polymer Polymers 0.000 claims description 8
- 229920001890 Novodur Polymers 0.000 claims description 6
- 238000012662 bulk polymerization Methods 0.000 claims description 6
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 claims description 4
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims description 4
- 229920000459 Nitrile rubber Polymers 0.000 claims description 4
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 4
- 229920001893 acrylonitrile styrene Polymers 0.000 claims description 2
- RPVQALVQDWBYJO-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione;prop-1-en-2-ylbenzene Chemical group CC(=C)C1=CC=CC=C1.O=C1C=CC(=O)N1C1=CC=CC=C1 RPVQALVQDWBYJO-UHFFFAOYSA-N 0.000 claims 1
- 238000005453 pelletization Methods 0.000 claims 1
- DXDLUSAGXYTADH-UHFFFAOYSA-N C=CC1=CC=CC=C1.CC(C#N)=CC=CC1=CC=CC=C1.C1(=CC=CC=C1)N1C(C=CC1=O)=O Chemical compound C=CC1=CC=CC=C1.CC(C#N)=CC=CC1=CC=CC=C1.C1(=CC=CC=C1)N1C(C=CC1=O)=O DXDLUSAGXYTADH-UHFFFAOYSA-N 0.000 abstract description 7
- 238000012805 post-processing Methods 0.000 abstract description 3
- 238000005303 weighing Methods 0.000 abstract description 2
- 238000002156 mixing Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 26
- 239000002994 raw material Substances 0.000 description 9
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 8
- 239000000155 melt Substances 0.000 description 8
- 229920002285 poly(styrene-co-acrylonitrile) Polymers 0.000 description 8
- 229920005989 resin Polymers 0.000 description 7
- 239000011347 resin Substances 0.000 description 7
- 238000000465 moulding Methods 0.000 description 5
- -1 polyethylene Polymers 0.000 description 5
- 239000003963 antioxidant agent Substances 0.000 description 4
- 230000003078 antioxidant effect Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000001746 injection moulding Methods 0.000 description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920000098 polyolefin Polymers 0.000 description 4
- 230000008569 process Effects 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- 230000035945 sensitivity Effects 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- 229920000147 Styrene maleic anhydride Polymers 0.000 description 3
- 238000009826 distribution Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000004048 modification Effects 0.000 description 3
- 238000012986 modification Methods 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 description 2
- JDCCCHBBXRQRGU-UHFFFAOYSA-N 5-phenylpenta-2,4-dienenitrile Chemical compound N#CC=CC=CC1=CC=CC=C1 JDCCCHBBXRQRGU-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 238000007591 painting process Methods 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 238000007665 sagging Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 229920000638 styrene acrylonitrile Polymers 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- QDOXQIRWYQMOKT-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione;styrene Chemical compound C=CC1=CC=CC=C1.O=C1C=CC(=O)N1C1=CC=CC=C1 QDOXQIRWYQMOKT-UHFFFAOYSA-N 0.000 description 1
- 150000003923 2,5-pyrrolediones Chemical class 0.000 description 1
- JCJIZBQZPSZIBI-UHFFFAOYSA-N 2-[2,6-di(propan-2-yl)phenyl]benzo[de]isoquinoline-1,3-dione Chemical compound CC(C)C1=CC=CC(C(C)C)=C1N(C1=O)C(=O)C2=C3C1=CC=CC3=CC=C2 JCJIZBQZPSZIBI-UHFFFAOYSA-N 0.000 description 1
- IYMZEPRSPLASMS-UHFFFAOYSA-N 3-phenylpyrrole-2,5-dione Chemical compound O=C1NC(=O)C(C=2C=CC=CC=2)=C1 IYMZEPRSPLASMS-UHFFFAOYSA-N 0.000 description 1
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 238000007664 blowing Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000000701 coagulant Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000007720 emulsion polymerization reaction Methods 0.000 description 1
- 229920006351 engineering plastic Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000010528 free radical solution polymerization reaction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000000265 homogenisation Methods 0.000 description 1
- 150000003949 imides Chemical class 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 150000008442 polyphenolic compounds Chemical class 0.000 description 1
- 235000013824 polyphenols Nutrition 0.000 description 1
- 238000005086 pumping Methods 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 229920006027 ternary co-polymer Polymers 0.000 description 1
- 229920001897 terpolymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/03—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
- B29C48/04—Particle-shaped
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/16—Homopolymers or copolymers of alkyl-substituted styrenes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/08—Copolymers of styrene
- C08L25/12—Copolymers of styrene with unsaturated nitriles
Definitions
- the components and parts by weight of the monomer mixture are as follows, in terms of 100 parts by weight: 10 30 parts by weight of acrylonitrile and 70 parts by weight of a styrene component;
- Blow molded article surface quality A cylindrical blow molded article having a diameter of 100 ⁇ m and a length of 5 mm and a thickness of 5 mm was prepared using a blow molding machine.
- the blow molding conditions were a parison temperature of 240 ° C, a screw rotation speed of 50 rpm, and a mold temperature of 70 ° C.
- the surface condition of the entire cylindrical blow molded article was visually observed, and the number of uneven positions of the surface, that is, the number of pockmarks (the size of the pitting point was 0.02 mm or more) was counted. Evaluation based on the following criteria: O : the number of pittings is less than 10;
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Blow-Moulding Or Thermoforming Of Plastics Or The Like (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
La présente invention concerne une composition de résine ABS résistante à la chaleur formée par moulage par soufflage et un procédé de préparation correspondant. La composition comprend 100 parties en masse d'une composition A de résine de styrène et 20 à 40 parties en masse d'un agent B résistant à la chaleur, ledit agent B résistant à la chaleur étant un quadripolymère N-phénylmaléimide-α-méthylstyrène-acrylonitrile-styrène. Le procédé de préparation de la composition de résine ABS comprend les étapes suivantes : pesée des composants en parties en masse; mélange poussé des composants dans un mélangeur haute vitesse, afin d'obtenir un mélange ; introduction du mélange dans une extrudeuse à double vis via un orifice d'alimentation principal et extrusion à l'état fondu, refroidissement, séchage et découpage en cubes pour obtenir la composition de résine ABS. Un produit élaboré par moulage par soufflage selon la présente invention présente une qualité de surface souhaitable et des performances de résistance à la chaleur, la température de ramollissement Vicat est supérieure à 110 °C et par conséquent, le produit peut répondre aux exigences de résistance à la chaleur de la technique de post-traitement de peinture par pulvérisation des pièces pour l'automobile et être employé dans des environnements agressifs. En outre, le produit préparé par moulage par soufflage possède une résistance élevée aux chocs.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2016533619A JP6364490B2 (ja) | 2013-11-20 | 2013-12-04 | ブロー成形に適する高耐熱ａｂｓ樹脂組成物及びその調製方法 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310590377.2A CN103613877B (zh) | 2013-11-20 | 2013-11-20 | 适于吹塑成型的高耐热abs树脂组合物及其制备方法 |
| CN201310590377.2 | 2013-11-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2015074297A1 true WO2015074297A1 (fr) | 2015-05-28 |
Family
ID=50164599
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/CN2013/088527 WO2015074297A1 (fr) | 2013-11-20 | 2013-12-04 | Composition de résine abs résistante à la chaleur formée par moulage par soufflage et procédé de préparation correspondant |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP6364490B2 (fr) |
| CN (1) | CN103613877B (fr) |
| WO (1) | WO2015074297A1 (fr) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019121647A1 (fr) * | 2017-12-19 | 2019-06-27 | Ineos Styrolution Group Gmbh | Composition de moulage thermoplastique abs pour moulage par soufflage |
| CN115044165A (zh) * | 2022-08-17 | 2022-09-13 | 山东东临新材料股份有限公司 | 一种abs树脂组合物及其制备方法 |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9527833B2 (en) * | 2013-06-17 | 2016-12-27 | Taiho Pharmaceutical Co., Ltd. | Stable crystal form of tipiracil hydrochloride and crystallization method for the same |
| KR101811485B1 (ko) * | 2014-11-28 | 2017-12-21 | 주식회사 엘지화학 | 열가소성 수지 조성물 및 이를 적용한 성형품 |
| TWI573710B (zh) * | 2016-05-18 | 2017-03-11 | Vehicle rear fender guardrail | |
| JP6218347B1 (ja) * | 2017-07-21 | 2017-10-25 | ユーエムジー・エービーエス株式会社 | めっき用熱可塑性樹脂組成物、樹脂成形品およびめっき加工品 |
| KR102210030B1 (ko) | 2017-12-11 | 2021-02-01 | 주식회사 엘지화학 | 내열 수지 조성물 |
| CN108285609B (zh) * | 2018-01-09 | 2020-10-02 | 佳易容聚合物(上海)有限公司 | 高熔体强度苯乙烯类树脂组合物及其制备方法 |
| CN110498890A (zh) * | 2019-08-26 | 2019-11-26 | 江苏宝源高新电工有限公司 | 一种具有耐候耐老化性丁腈橡胶接枝聚合物及其制备方法 |
| KR102493671B1 (ko) * | 2019-10-23 | 2023-02-06 | 주식회사 엘지화학 | 열가소성 수지 조성물 |
| EP3916049B1 (fr) | 2019-10-23 | 2024-06-05 | Lg Chem, Ltd. | Composition de résine thermoplastique |
| KR102639153B1 (ko) * | 2021-12-01 | 2024-02-21 | 금호석유화학 주식회사 | 항균성이 우수한 저취 abs계 수지 조성물 |
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Also Published As
| Publication number | Publication date |
|---|---|
| CN103613877B (zh) | 2017-09-19 |
| JP2017502106A (ja) | 2017-01-19 |
| CN103613877A (zh) | 2014-03-05 |
| JP6364490B2 (ja) | 2018-07-25 |
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