WO2014042005A1 - 蓄電素子、及び蓄電素子の製造方法 - Google Patents
蓄電素子、及び蓄電素子の製造方法 Download PDFInfo
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- WO2014042005A1 WO2014042005A1 PCT/JP2013/072901 JP2013072901W WO2014042005A1 WO 2014042005 A1 WO2014042005 A1 WO 2014042005A1 JP 2013072901 W JP2013072901 W JP 2013072901W WO 2014042005 A1 WO2014042005 A1 WO 2014042005A1
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- electrode plate
- vibration
- current collector
- electrode
- electrode body
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/64—Carriers or collectors
- H01M4/66—Selection of materials
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K20/00—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating
- B23K20/10—Non-electric welding by applying impact or other pressure, with or without the application of heat, e.g. cladding or plating making use of vibrations, e.g. ultrasonic welding
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0431—Cells with wound or folded electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/533—Electrode connections inside a battery casing characterised by the shape of the leads or tabs
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/536—Electrode connections inside a battery casing characterised by the method of fixing the leads to the electrodes, e.g. by welding
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
- H01M50/538—Connection of several leads or tabs of wound or folded electrode stacks
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/547—Terminals characterised by the disposition of the terminals on the cells
- H01M50/55—Terminals characterised by the disposition of the terminals on the cells on the same side of the cell
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/552—Terminals characterised by their shape
- H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/564—Terminals characterised by their manufacturing process
- H01M50/567—Terminals characterised by their manufacturing process by fixing means, e.g. screws, rivets or bolts
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2224/00—Indexing scheme for arrangements for connecting or disconnecting semiconductor or solid-state bodies and methods related thereto as covered by H01L24/00
- H01L2224/01—Means for bonding being attached to, or being formed on, the surface to be connected, e.g. chip-to-package, die-attach, "first-level" interconnects; Manufacturing methods related thereto
- H01L2224/42—Wire connectors; Manufacturing methods related thereto
- H01L2224/47—Structure, shape, material or disposition of the wire connectors after the connecting process
- H01L2224/48—Structure, shape, material or disposition of the wire connectors after the connecting process of an individual wire connector
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L2924/00—Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
- H01L2924/0001—Technical content checked by a classifier
- H01L2924/00014—Technical content checked by a classifier the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49002—Electrical device making
- Y10T29/49108—Electric battery cell making
Definitions
- the present invention relates to a power storage device including an electrode body in which electrode plates are laminated, and a current collecting member joined to the electrode body, and a method for manufacturing the power storage device.
- chargeable / dischargeable storage elements such as batteries (lithium ion batteries, nickel metal hydride batteries, etc.), capacitors (electric double layer capacitors, etc.) are used in vehicles (automobiles, motorcycles, etc.), various devices (mobile terminals, laptop computers, etc.) ) And other power sources.
- An electric storage element generally includes an external terminal to which conductors such as cables and bus bars are connected, an electrode body in which electrode plates are laminated in multiple layers, and a current collecting member that electrically connects the external terminal and the electrode body.
- the electrode body includes a positive electrode plate and a negative electrode plate.
- the positive electrode plate and the negative electrode plate are laminated while being insulated from each other.
- the positive electrode plate and the negative electrode plate are arranged in a state of being displaced in the width direction.
- the protruding portion in which only the positive electrode plate is laminated is formed at one end portion in the width direction of the electrode body, and the protruding portion in which only the negative electrode plate is laminated is the other end portion in the width direction of the electrode body. Is formed.
- the electricity storage element includes a positive current collecting member joined to a positive electrode plate (projecting portion) and a negative current collecting member joined to a negative electrode plate (projecting portion). These current collecting members have the same basic configuration.
- the current collecting member has a connection portion welded to an electrode plate (a positive electrode plate or a negative electrode plate).
- the current collector is a current collector disposed along an electrode plate (positive electrode plate or negative electrode plate), and includes a current collector electrically connected to an external terminal. . And in this kind of current collection member, there exist some which were provided with the contact member or the clip member in addition to the electrical power collector.
- the contact member is disposed along the electrode plate (positive electrode plate or negative electrode plate) of the electrode body.
- the clip member has a pair of facing pieces that face each other with the electrode plate (positive electrode plate or negative electrode plate) interposed therebetween. The current collector is superimposed on one of the pair of facing pieces.
- a portion along the electrode plate of the current collector and the contact member are joined (welded) to the electrode plate as a connecting portion so as to be energized.
- the portion along the electrode plate of the current collector and the pair of opposing pieces are joined (welded) to the electrode plate as a connection portion so as to be energized.
- the electrode body and the current collecting member are welded by vibration welding.
- Vibration welding is a welding method in which welding objects are superposed and melted (welded) by applying vibration to the objects.
- Ultrasonic vibration welding is popular as one of vibration welding.
- Such ultrasonic vibration welding uses a horn to which ultrasonic vibration is applied and an anvil that sandwiches an object to be welded together with the horn.
- the electrode plate (projecting portion) and the connecting portion of the current collecting member are sandwiched between the horn and the anvil, and in this state, ultrasonic vibration is applied to the horn. Thereby, an electrode body (electrode plate) and a current collection member (connection part) are welded.
- the present invention is capable of eliminating a joint failure in vibration welding between an electrode body and a current collecting member, and ensuring an electrical and mechanical connection between the electrode body and the current collecting member, and the power storage element It is an object to provide a manufacturing method.
- the electricity storage device is: An external terminal, An electrode body in which electrode plates are laminated; A current collecting member for electrically connecting the external terminal and the electrode body, comprising a current collecting member having a connection portion welded to the electrode plate by vibration welding; At least the connecting portion of the current collecting member is made of a rolled material.
- the rolling direction of the connecting portion corresponds to the amplitude direction of vibration applied during vibration welding, You can do so.
- the rolling direction of the connection portion corresponds to the amplitude direction of vibration applied during vibration welding” means that the rolling direction of the connection portion matches the amplitude direction of vibration. This is a concept including a state in which the rolling direction of the connecting portion is inclined with respect to the amplitude direction of the vibration within a range in which the extension of the connecting portion does not significantly attenuate the vibration.
- Vibration welding is ultrasonic vibration welding that welds the electrode plate and the connection part by applying ultrasonic vibration to the horn of the horn and anvil sandwiching the electrode plate and the connection part,
- the connecting part is a part facing the horn during ultrasonic vibration welding. You can do so.
- the current collector is A current collector disposed along an electrode plate of the electrode body, the current collector electrically connected to an external terminal; A clip member having a pair of opposed pieces opposed to each other with the electrode plate interposed therebetween, and a clip member on which a current collector is superimposed on any one of the pair of opposed pieces,
- the connecting portion is a portion along the electrode plate of the current collector, or one of the pair of facing pieces. You can do so.
- the current collecting member is A current collector disposed along an electrode plate of the electrode body, the current collector electrically connected to an external terminal;
- a contact member disposed along the electrode plate of the electrode body, The connecting portion is a portion along the electrode plate in either the current collector or the contact member. You can do so.
- a method for manufacturing a power storage device includes: An external terminal, An electrode body in which electrode plates are laminated; A method for manufacturing an electricity storage device having a connection part welded to an electrode plate by vibration welding and comprising a current collecting member that electrically connects an external terminal and an electrode body, At least the connecting portion of the current collecting member is made of a rolled material.
- connection portion is vibration welded to the electrode plate. You can do so.
- the state in which the rolling direction of the connecting portion corresponds to the amplitude direction of vibration in the vibration welding means that the rolling direction of the connecting portion matches the amplitude direction of vibration, as well as the connection.
- This is a concept including a state in which the rolling direction of the connecting portion is inclined with respect to the amplitude direction of the vibration within a range in which the stretching of the portion does not greatly attenuate the vibration.
- Vibration welding is ultrasonic vibration welding that welds the electrode plate and the connection part by applying ultrasonic vibration to the horn of the horn and anvil sandwiching the electrode plate and the connection part, The horn is opposed to the connection part during ultrasonic vibration welding. You can do so.
- the current collector is A current collector disposed along an electrode plate of the electrode body, the current collector electrically connected to an external terminal; A clip member having a pair of opposed pieces opposed to each other with the electrode plate interposed therebetween, and a clip member on which a current collector is superimposed on any one of the pair of opposed pieces,
- the connecting portion is a portion along the electrode plate of the current collector, or one of the pair of facing pieces. You can do so.
- the current collecting member is A current collector disposed along an electrode plate of the electrode body, the current collector electrically connected to an external terminal;
- a contact member disposed along the electrode plate of the electrode body, The connecting portion may be a portion along the electrode plate of either the current collector or the contact member.
- FIG. 1 shows a partially broken front view of a battery according to an embodiment of the present invention.
- FIG. 2 shows a perspective view of the structure in the case of the battery.
- FIG. 3 is an explanatory view of an electrode body in the battery, and shows a schematic cross-sectional view simply showing an electrode plate and a separator.
- FIG. 4 is an exploded perspective view of a current collecting member in the battery.
- FIG. 5 is a sectional view taken along line AA in FIG.
- FIG. 6 is a diagram of a method for manufacturing the battery (a method for welding the electrode body and the current collecting member), and shows a partial cross-sectional view including a part of the current collecting member and a part of the electrode body.
- FIG. 1 shows a partially broken front view of a battery according to an embodiment of the present invention.
- FIG. 2 shows a perspective view of the structure in the case of the battery.
- FIG. 3 is an explanatory view of an electrode body in the battery, and shows a schematic cross-section
- FIG. 7 is a diagram of a method for manufacturing the battery (a method for welding the electrode body and the current collecting member), and shows a partial front view including a part of the current collecting member and a part of the electrode body.
- FIG. 8 is a diagram of a battery (battery manufacturing method) according to another embodiment of the present invention, in which a stacked portion of electrode bodies is sandwiched between clip members and an electrode body of a pair of opposing pieces of the clip members.
- FIG. 2 shows a partial schematic cross-sectional view of a battery in which a current collector connection piece is superposed on a facing piece on the inside of the battery and vibration welded by applying a minute vibration to the connection piece.
- FIG. 9 is a diagram of a battery (battery manufacturing method) according to another embodiment of the present invention, in which the stacked portion of the electrode body is sandwiched between the clip members, and the electrode of the pair of opposed pieces of the clip members.
- FIG. 2 shows a partial schematic cross-sectional view of a battery in which a current collector connection piece is superimposed on an opposing piece on the outside of the body and vibration welded by applying a minute vibration to the connection piece.
- FIG. 10 is a diagram of the battery (the manufacturing method of the battery), in which the stacked portion of the electrode body is sandwiched between the clip members, and the opposing piece that is outside the electrode body of the pair of opposing pieces of the clip member FIG.
- FIG. 2 shows a partial schematic cross-sectional view of a battery in which the connection pieces of the current collector are superposed on each other and vibration-welded by applying minute vibrations to the opposing piece on the inner side (winding center side) of the electrode body.
- FIG. 11 is a diagram of a battery (battery manufacturing method) according to still another embodiment of the present invention, in which a laminated part of an electrode body and a connection piece of a current collector superimposed on the outside of the laminated part are clipped.
- the partial schematic cross-sectional view of the battery clamped by the member and vibration-welded by applying a minute vibration to the opposing piece outside the electrode body of the pair of opposing pieces of the clip member is shown.
- FIG. 12 is a diagram of the battery (the battery manufacturing method), in which a laminated portion of an electrode body and a connecting piece of a current collector superimposed on the outside of the laminated portion are sandwiched between clip members, The partial schematic cross-sectional view of the battery which was vibration-welded by applying a micro vibration to the opposing piece inside the electrode body (winding center side) of the pair of opposing pieces is shown.
- FIG. 13 is a diagram of a battery (battery manufacturing method) according to still another embodiment of the present invention, in which a laminated part of an electrode body and a connection piece of a current collector superimposed on the inside of the laminated part are clipped.
- FIG. 14 is a diagram of the battery (the manufacturing method of the battery), in which a laminated portion of an electrode body and a connecting piece of a current collector superimposed on the inside of the laminated portion are sandwiched between clip members,
- the partial schematic cross-sectional view of the battery which was vibration-welded by applying a micro vibration to the opposing piece inside the electrode body (winding center side) of the pair of opposing pieces is shown.
- FIG. 15 is a diagram of a battery (battery manufacturing method) according to still another embodiment of the present invention, in which the connection pieces of the current collector are superimposed on the inner side of the laminated part of the electrode body, and The plate-shaped contact member is piled up on the outer side, The partial schematic cross-sectional view of the battery which was vibration-welded by applying a micro vibration to a contact member is shown.
- FIG. 16 is a diagram of the battery (the method for manufacturing the battery), in which the connection pieces of the current collector are superimposed on the inner side of the stacked portion of the electrode body, and the plate-shaped contact member is stacked on the outer side of the stacked portion.
- FIG. 2 is a partial schematic cross-sectional view of a battery that is vibration-welded by applying microvibration to a connection piece.
- FIG. 17 is a diagram of a battery (battery manufacturing method) according to still another embodiment of the present invention, in which the connection pieces of the current collector are overlaid on the outer side of the stacked portion of the electrode body, The plate-shaped contact member is piled up inside and the partial schematic cross-sectional view of the battery which was vibration-welded by applying a micro vibration to a connection piece is shown.
- FIG. 17 is a diagram of a battery (battery manufacturing method) according to still another embodiment of the present invention, in which the connection pieces of the current collector are overlaid on the outer side of the stacked portion of the electrode body, The plate-shaped contact member is piled up inside and the partial schematic cross-sectional view of the battery which was vibration-welded by applying a micro vibration to a connection piece is shown.
- FIG. 18 is a diagram of the battery (the method for manufacturing the battery), in which a connecting piece of a current collector is superimposed on the outer side of the laminated part of the electrode body, and a plate-like contact member is provided on the inner side of the laminated part.
- the partial schematic cross-sectional view of the battery which was piled up and vibration-welded by applying a micro vibration to a contact member is shown.
- An electricity storage device is an external terminal, an electrode body in which electrode plates are laminated, and a current collecting member that electrically connects the external terminal and the electrode body, and is welded to the electrode plate by vibration welding.
- a current collecting member having a connecting portion, and at least the connecting portion of the current collecting member is made of a rolled material.
- connection portion welded to the electrode body by vibration welding is made of a rolled material in which vibration is easily propagated, the electrical and mechanical connection between the electrode body and the current collecting member is sufficient. Is secured. Specifically, it is as follows.
- Rolled material formed by rolling is easier to stretch in a specific direction and applied vibration compared to isotropic materials such as forged material formed by forging and cutting material formed by cutting. It has the characteristic that it is easy to propagate. For this reason, by forming at least the connecting portion of the current collecting member with a rolled material, vibration is efficiently transmitted to the electrode plate through the connecting portion when welding the current collecting member and the electrode plate by vibration welding during manufacturing. . As a result, in the electricity storage element, the electrical and mechanical connection between the electrode body and the current collecting member can be obtained sufficiently and reliably.
- the rolling direction of the connection portion corresponds to the amplitude direction of vibration applied during vibration welding.
- “the rolling direction of the connection portion corresponds to the amplitude direction of vibration applied during vibration welding” means that the rolling direction of the connection portion matches the amplitude direction of vibration. This is a concept including a state in which the rolling direction of the connecting portion is inclined with respect to the amplitude direction of the vibration within a range in which the extension of the connecting portion does not significantly attenuate the vibration.
- the connection portion extends in a direction corresponding to the amplitude direction of vibration of vibration welding during vibration welding at the time of manufacture. That is, since the connecting portion is made of a rolled material, the connecting portion has a characteristic that it is easily stretched in the rolling direction. For this reason, when performing vibration welding, the connecting portion is stretched in the rolling direction by pressurizing to apply a pressing force for bringing the electrode plate and the connecting portion into pressure contact. At this time, the connecting portion extends in a direction corresponding to the amplitude direction of vibration, and vibration energy during vibration welding is propagated to the connecting portion and the electrode plate without greatly decreasing.
- the connecting portion extends in a direction not corresponding to the amplitude direction of vibration
- the extension of the connecting portion attenuates vibration due to a mismatch between the extending direction of the connecting portion and the amplitude direction of vibration. For this reason, vibration energy is not efficiently propagated to the connecting portion and the electrode plate.
- the connecting portion extends in a direction corresponding to the amplitude direction of the vibration
- the extension of the connecting portion maintains or amplifies the vibration due to the coincidence between the extending direction of the connecting portion and the amplitude direction of the vibration. For this reason, vibration energy is efficiently propagated to the connecting portion and the electrode plate.
- the connecting portion and the electrode plate are efficiently fused and reliably joined.
- Vibration welding is ultrasonic vibration welding that welds the electrode plate and the connection part by applying ultrasonic vibration to the horn of the horn and anvil sandwiching the electrode plate and the connection part,
- the connecting part is a part facing the horn during ultrasonic vibration welding. You can do so.
- the electrode plate and the connecting part are sandwiched between the horn and the anvil, and the connecting part is pressurized.
- the electrode plate and the connection portion are drawn from the horn while the electrode plate and the connection portion are in pressure contact with each other while the connection portion extends in a direction corresponding to the amplitude direction of the ultrasonic vibration. Receive vibration. Therefore, due to the coincidence between the extending direction of the connecting portion and the amplitude direction of vibration, the extending of the connecting portion maintains or amplifies the vibration, and vibration energy is efficiently propagated to the connecting portion and the electrode plate. As a result, the connecting portion and the electrode plate are efficiently fused and reliably joined.
- the current collector is A current collector disposed along an electrode plate of the electrode body, the current collector electrically connected to an external terminal; A clip member having a pair of opposed pieces facing each other with the electrode plate interposed therebetween, and a clip member on which a current collector is superimposed on any one of the pair of opposed pieces,
- the connecting portion is a portion along the electrode plate of the current collector, or one of the pair of facing pieces. You can do so.
- the electrode plate can be prevented from being damaged (broken) due to the influence of vibration.
- the clip member surrounds the electrode plate of the electrode body. Therefore, the electrode plate of the electrode body can be protected.
- the current collecting member is A current collector disposed along an electrode plate of the electrode body, the current collector electrically connected to an external terminal;
- a contact member disposed along the electrode plate of the electrode body, The connecting portion is a portion along the electrode plate in either the current collector or the contact member. You can do so.
- a method for manufacturing a power storage device includes: An external terminal, An electrode body in which electrode plates are laminated; A method of manufacturing an electricity storage device having a connection part welded to an electrode plate by vibration welding and comprising a current collecting member for electrically connecting an external terminal and the electrode body, At least the connecting portion of the current collecting member is made of a rolled material.
- connection portion welded to the electrode body by vibration welding is made of a rolled material that easily propagates vibrations, the electrical connection between the electrode body and the current collecting member by vibration welding is achieved. A sufficient mechanical connection can be ensured. Specifically, it is as follows.
- the rolled material Compared to isotropic materials such as forging materials formed by forging and cutting materials formed by cutting, the rolled material has the property of being easily stretched in a specific direction and propagating applied vibrations. Have. For this reason, at least a connection part is comprised with a rolling material in a current collection member, and when a current collection member and an electrode plate are welded by vibration welding, a vibration is efficiently propagated to an electrode plate through a connection part. As a result, in the manufactured power storage element, an electrical and mechanical connection between the electrode body and the current collecting member can be obtained sufficiently and reliably.
- the connecting portion is vibration welded to the electrode plate in a state where the rolling direction of the connecting portion corresponds to the amplitude direction of vibration in vibration welding.
- the state in which the rolling direction of the connecting portion corresponds to the amplitude direction of vibration in vibration welding means that the rolling direction of the connecting portion coincides with the amplitude direction of vibration. This is a concept including a state in which the rolling direction of the connecting portion is inclined with respect to the amplitude direction of vibration within a range in which the stretching does not greatly attenuate the vibration.
- the connecting portion when vibration welding is performed, the connecting portion extends in a direction corresponding to the amplitude direction of the vibration. That is, since the connecting portion is made of a rolled material, the connecting portion has a characteristic that it is easily stretched in the rolling direction. Accordingly, when vibration welding is performed, the connecting portion is stretched in the rolling direction by pressurizing to apply a pressing force for bringing the electrode plate and the connecting portion into pressure contact. Accordingly, the connecting portion extends in a direction corresponding to the amplitude direction of vibration, and vibration energy during vibration welding is transmitted to the connecting portion and the electrode plate without being lowered.
- the connecting portion extends in a direction not corresponding to the amplitude direction of vibration
- the extension of the connecting portion attenuates vibration due to a mismatch between the extending direction of the connecting portion and the amplitude direction of vibration. For this reason, vibration energy is not efficiently propagated to the connecting portion and the electrode plate.
- the connecting portion extends in a direction corresponding to the amplitude direction of the vibration
- the extension of the connecting portion maintains or amplifies the vibration due to the coincidence between the extending direction of the connecting portion and the amplitude direction of the vibration. For this reason, vibration energy is efficiently propagated to the connecting portion and the electrode plate.
- the connecting portion and the electrode plate are efficiently fused and reliably joined.
- Vibration welding is ultrasonic vibration welding that welds the electrode plate and the connection part by applying ultrasonic vibration to the horn of the horn and anvil sandwiching the electrode plate and the connection part, The horn is opposed to the connection part during ultrasonic vibration welding. You can do so.
- the connection portion receives vibration from the horn while extending in a direction corresponding to the amplitude direction of ultrasonic vibration in a state where the electrode plate and the connection portion are in pressure contact. Therefore, the extension of the connecting portion maintains or amplifies the vibration, by matching the extension direction of the connecting portion with the amplitude direction of the vibration. For this reason, vibration energy is efficiently propagated to the connecting portion and the electrode plate. As a result, the connection portion and the electrode plate are efficiently fused and securely joined without being damaged.
- the current collector is A current collector disposed along an electrode plate of the electrode body, the current collector electrically connected to an external terminal; A clip member having a pair of opposed pieces opposed to each other with the electrode plate interposed therebetween, and a clip member on which a current collector is superimposed on any one of the pair of opposed pieces,
- the connecting portion is a portion along the electrode plate of the current collector, or one of the pair of facing pieces. You can do so.
- the electrode plate can be prevented from being damaged (broken) due to the influence of vibration.
- the clip member surrounds the electrode plate of the electrode body. Therefore, the electrode plate of the electrode body can be protected.
- the current collecting member is A current collector disposed along an electrode plate of the electrode body, the current collector electrically connected to an external terminal;
- a contact member disposed along the electrode plate of the electrode body, The connecting portion is a portion along the electrode plate in either the current collector or the contact member. You can do so.
- a power storage device As an example of a storage element, a chargeable / dischargeable secondary battery (hereinafter, referred to as a power source) for vehicles (automobiles, motorcycles, etc.), various devices (mobile terminals, laptop computers, etc.), etc. This will be simply referred to as “battery”.
- a power source a chargeable / dischargeable secondary battery for vehicles (automobiles, motorcycles, etc.), various devices (mobile terminals, laptop computers, etc.), etc. This will be simply referred to as “battery”.
- the battery according to the present embodiment is a lithium ion secondary battery. As shown in FIGS. 1 and 2, the battery includes a metal case 10, an electrode body 20 accommodated inside the case 10, external terminals 30 and 30 disposed outside the case 10, and an external terminal 30. , 30 and the electrode body 20 are provided with current collecting members 40, 40.
- the case 10 includes a bottomed rectangular tube-shaped case main body 11 having an opening, and a lid 12 that closes the opening of the case main body 11.
- the case body 11 and the lid body 12 are integrated by welding the peripheral edges in a state of being combined with each other. Thereby, the case 10 is configured to be airtight and liquidtight.
- External terminals 30 and 30 are parts to which conductors (not shown) such as cables and bus bars are connected.
- the battery according to this embodiment is provided with an external terminal 30 for a positive electrode and an external terminal 30 for a negative electrode.
- the external terminal 30 for positive electrode and the external terminal 30 for negative electrode have a common configuration.
- the external terminal 30 for positive electrode and the external terminal 30 for negative electrode are electrically connected to the electrode body 20 while being fixed to the case 10 while being insulated from the case 10.
- the external terminals 30 and 30 of this embodiment are being fixed to the case 10 via the rivet 13 which penetrated the case 10 (lid body 12).
- the rivet 13 fixes the external terminals 30 and 30 to the case 10.
- the rivet 13 has a function of connecting the current collecting members 40, 40 and the external terminals 30, 30 in a conductive manner while fixing the current collecting members 40, 40 to the case 10.
- the electrode body 20 is laminated with electrode plates. Specifically, as shown in FIG. 3, the electrode body 20 includes a positive electrode plate 21 and a negative electrode plate 22. More specifically, the electrode body 20 includes a positive electrode plate 21, a negative electrode plate 22, and a separator 23. The positive electrode plate 21 and the negative electrode plate 22 are stacked with a separator 23 interposed therebetween. The positive electrode plate 21 and the negative electrode plate 22 of the present embodiment each have a strip shape. The positive electrode plate 21 and the negative electrode plate 22 are stacked in a state of sandwiching the separator 23 and wound in a flat shape.
- the positive electrode plate 21 and the negative electrode plate 22 are arranged so as to be displaced from each other in the width direction (direction perpendicular to the longitudinal direction).
- the electrode body 20 has a protruding portion 24 formed by protruding only the positive electrode plate 21 at one end in the width direction, and only the negative electrode plate 22 protruded at the other end in the width direction.
- a projecting portion 25 configured by doing so. That is, in the electrode body 20 according to the present embodiment, the protrusion 24 in which only the positive electrode plate 21 is laminated is formed at one end in the width direction, and only the negative electrode plate 22 is laminated. The part 25 is formed at the other end in the width direction.
- the electrode body 20 is accommodated in the case 10 so that the winding center CL is parallel to the surface through which the rivet 13 is inserted in the case 10 (inner surface of the lid body 12).
- the battery includes a current collecting member 40 for a positive electrode and a current collecting member 40 for a negative electrode.
- the positive electrode current collecting member 40 connects the positive electrode plate 21 and the positive electrode external terminal 30 to each other.
- the negative electrode current collecting member 40 connects the negative electrode plate 22 and the negative electrode external terminal 30 to each other.
- the positive current collecting member 40 and the negative current collecting member 40 are formed in the same shape.
- These current collecting members 40, 40 have a connecting portion 41 welded to the electrode plates 21, 22 by vibration welding.
- the connection portion 41 is made of a rolled material.
- the rolling direction of the connecting portion 41 corresponds to the amplitude direction of vibration applied during vibration welding.
- the current collecting members 40, 40 include a current collector 42 and clip members 43, 43.
- the current collector 42 is disposed along the electrode plates 21 and 22 of the electrode body 20 and is electrically connected to the external terminals 30 and 30.
- the current collector 42 includes an internal connection portion 420 connected to the external terminals 30 and 30, and an electrode attachment portion 421 that is directly or indirectly joined to the protruding portions 24 and 25 of the electrode body 20. And an intermediate part 422 for connecting the internal connection part 420 and the electrode attachment part 421.
- the current collector 42 is formed into a deformed L-shape in front view by bending a plate-shaped metal material cut into a predetermined shape.
- the metal material of the positive electrode current collector 42 for example, aluminum or an aluminum alloy is employed.
- a metal material of the current collector 42 for the negative electrode for example, copper or a copper alloy is employed.
- the current collector 42 is bent at the intermediate portion 422.
- the internal connection part 420 has faced the orthogonal
- the internal connection portion 420 is disposed along the inner surface of the case 10 in a state of being insulated from the inner surface of the case 10.
- a through hole 423 through which the rivet 13 (see FIGS. 1 and 2) connecting the external terminals 30 and 30 is inserted is provided at the tip of the internal connection portion 420.
- the electrode attachment portion 421 is disposed between the protruding portions 24 and 25 of the electrode body 20 and the inner surface of the case 10 (see FIG. 1).
- the electrode attachment portion 421 includes an opening 424.
- Two connection pieces 425 and 425 extending in the same direction as the internal connection portion 420 are provided on both sides of the opening 424.
- the electrode body 20 is formed by winding a positive electrode plate 21 and a negative electrode plate 22 in a flat shape as shown in FIG. For this reason, the electrode body 20 has a minor axis and a major axis when viewed from the winding center CL. And the protrusion parts 24 and 25 of the electrode body 20 have the two laminated parts 26 and 26 formed so that the winding center CL of the electrode body 20 might be pinched
- connection pieces 425 and 425 extends along the major axis direction of the electrode body 20 and extends in the direction in which the winding center CL of the electrode body 20 extends.
- the two connection pieces 425 and 425 of the present embodiment are overlapped with the corresponding stacked portions 26 and 26 in a state where they are inserted into the central portions of the protruding portions 24 and 25 of the electrode body 20.
- the opening 424 and the connecting pieces 425 and 425 are formed, for example, by making a cut in the length direction in the state of the strip before forming the electrode attachment portion 421 and twisting both sides of the cut.
- the clip member 43 sandwiches the electrode plates 21 and 22 of the electrode body 20 and connects the current collector 42 and the electrode body 20.
- the clip member 43 includes a pair of facing pieces 430 and 430 that face each other with the electrode plates 21 and 22 (projecting portions 24 and 25) of the electrode body 20 interposed therebetween. This will be described more specifically.
- the clip member 43 includes a pair of facing pieces 430 and 430 that face each other with a space therebetween, and a connecting portion 431 that connects corresponding ends of the pair of facing pieces 430 and 430.
- the pair of opposed pieces 430 and 430 are the connection portions 41 that are joined to the electrode plates 21 and 22 of the electrode body 20.
- each of the positive electrode current collecting member 40 and the negative electrode current collecting member 40 has a connection piece so that one laminated portion 26 and one connecting piece 425 corresponding to the laminated portion 26 can be electrically connected.
- two clip members 43 and 43 are provided.
- the clip member 43 is formed in a U-shaped cross section by bending a plate-shaped metal material.
- the metal material forming the clip member 43 is a rolled material that is rolled in one direction and stretched.
- the current collecting member 40 (the connecting piece 425 of the clip member 43 and the current collector 42) is vibration welded to the electrode plates 21 and 22 (projecting portions 24 and 25) of the electrode body 20. Is done. Accordingly, the clip members 43 and 43 are formed by bending the metal material so that the rolling direction of the metal material corresponds to the amplitude direction of vibration during vibration welding. The clip members 43, 43 of this embodiment are formed so that the rolling direction of the metal material coincides with the amplitude direction of vibration.
- Each of the pair of opposed pieces 430 and 430 of the present embodiment is formed so as to be longitudinal in the major axis direction of the electrode body 20.
- the opposing pieces 430, 430 are electrode plates 21, 22 so as to form a welded area WA extending in the major axis direction of the electrode body 20 (longitudinal direction of the opposing pieces 430, 430). And vibration welded to the connection pieces 425 and 425.
- the clip members 43 and 43 are bent so that the rolling direction of the facing pieces 430 and 430 corresponds to the amplitude direction of the vibration welding. That is, the clip members 43 and 43 (the pair of opposed pieces 430 and 430 and the connecting portion 431) are formed by bending a rolled material having a plate shape or a sheet shape in a direction perpendicular to the rolling direction. Thereby, the boundary line (imaginary line) of the opposing piece 430 and the connection part 431 corresponds with the rolling direction of a rolling material.
- the clip members 43 and 43 according to the present embodiment are formed by bending a single rolled material as described above. For this reason, in the clip members 43 and 43, the rolling direction is the same in each of the pair of opposed pieces 430 and 430 and the connecting portion 431. That is, the rolling direction of the pair of opposed pieces 430 and 430 and the connecting portion 431 is coincident with or substantially coincides with a direction orthogonal or substantially orthogonal to the bending direction of the metal material.
- the clip member 43 for the positive electrode is made of, for example, aluminum or an aluminum alloy like the current collector 42 for the positive electrode
- the clip member 43 for the negative electrode is made of, for example, copper or copper like the current collector 42 for the negative electrode. It is composed of an alloy or the like.
- the battery according to this embodiment is as described above. Next, a method for manufacturing such a battery will be described.
- the current collector 42 and the external terminals 30 and 30 are connected to the case 10 and the case 10 is assembled by a general method. Below, only joining of current collection members 40 and 40 and electrode body 20 is explained. As shown in FIG. 6, first, the clip members 43, 43 are attached to the projecting portions 24, 25 of the electrode body 20, and then the connection piece 425 of the current collector 42 is welded to the clip member 43.
- Each of the clip members 43 and 43 is attached to a pair of laminated portions 26 and 26 constituting the protruding portions 24 and 25.
- the opposing pieces 430 and 430 of the clip members 43 and 43 are in a state of sandwiching the corresponding laminated portions 26 and 26 (electrode plates 21 and 22).
- the pair of connection pieces 425 and 425 of the current collector 42 are inserted into the central portions (between the pair of stacked portions 26 and 26) of the protruding portions 24 and 25 of the electrode body 20.
- one connection piece 425 is along one opposing piece 430 in one clip member 43
- the other connection piece 425 is along one opposing piece 430 in the other clip member 43.
- the opposing of the clip member 43 is caused by pressurizing to apply a pressure contact force for bringing the electrode plates 21 and 22 and the facing pieces 430 and 430 (connecting portion 41) of the clip member 43 into pressure contact with each other.
- Pieces 430 and 430 (connection portion 41) extend in the rolling direction.
- the connection portion 41 and the electrode plate 21 do not decrease vibration energy during vibration welding. , 22.
- the extension direction of the opposing piece 430 (connecting portion 41) of the clip member 43 does not match the amplitude direction of vibration.
- the extension of the facing piece 430 (connecting portion 41) of the clip member 43 attenuates the vibration. Thereby, vibration energy is not efficiently propagated to the facing piece 430 (connecting portion 41) and the electrode plates 21 and 22 of the clip member 43.
- the facing piece 430 (connecting portion 41) of the clip member 43 extends in a direction corresponding to the amplitude direction of vibration, the extending direction of the facing piece 430 (connecting portion 41) of the clip member 43 and the amplitude direction of vibration
- the extension of the connecting portion 41 maintains or amplifies the vibration due to the agreement.
- vibration energy is efficiently propagated to the facing piece 430 (connection portion 41) and the electrode plates 21 and 22 of the clip member 43.
- the opposing piece 430 (connecting portion 41) of the clip member 43 and the electrode plates 21 and 22 are efficiently fused and reliably joined.
- a large stress does not act directly on the electrode plates 21 and 22. For this reason, damage to the electrode plates 21 and 22 is also prevented.
- ultrasonic vibration welding in which an object is welded by applying ultrasonic vibration to the horn P ⁇ b> 1 is employed as vibration welding. Accordingly, at the time of ultrasonic vibration welding, the horn P1 is made to face the facing piece 430 of the clip member 43 that is the connecting portion 41. More specifically, the anvil P ⁇ b> 2 is pressed against the connection piece 425, and the horn P ⁇ b> 1 (ultrasonic vibrator) is pressed against the facing piece 430 opposite to the facing piece 430 on which the connection piece 425 is superimposed. .
- connection piece 425, the pair of opposing pieces 430 and 430, and the electrode plates 21 and 22 of the protrusions 24 and 25 are sandwiched between the horn P1 and the anvil P2.
- frictional heat is generated by applying ultrasonic vibration to the horn P1.
- the connection pieces 425 and 425, the clip member 43 (opposing pieces 430 and 430), and the electrode plates 21 and 22 are integrally welded.
- the electrode plates 21 and 22 are affected by the addition of vibration. Damage (breakage) can be prevented.
- the clip member 43 surrounds the protruding portions 24 and 25 (electrode plates 21 and 22) of the electrode body 20, the electrode plates 21 and 22 of the electrode body 20 can be protected.
- the wound electrode body 20 in which the electrode plate 21 for the positive electrode, the electrode plate 22 for the negative electrode, and the separator 23 are wound is used.
- the electrode body 20 may be a laminate of a positive electrode plate 21, a negative electrode plate 22, and a separator 23 each having a sheet shape.
- the entire clip member 43 constituting the current collecting member 40 is made of a rolled material, but is not limited thereto.
- the connection part 41 joined to the electrode body 20 is made of a material in which only vibration parts (opposing pieces 430 and 430) to which vibration is applied during vibration welding are made of a rolled material, and other parts are made of a material that is not rolled. May be. That is, only the connection part 41 welded to the electrode body 20 (electrode plates 21 and 22) by applying vibration during vibration welding may be formed of a rolled material. Also in this case, it is preferable that the current collecting member 40 is arranged so that the rolling direction of the connecting portion 41 corresponds to the amplitude direction of vibration during vibration welding.
- connection portion 41 of current collecting member 40, electrode plates 21 and 22 are made of a rolled material, and all these welded objects are arranged in a state in which the rolling directions correspond to each other. The And these rolling directions are made to correspond to the amplitude direction of vibration at the time of vibration welding. If it does in this way, the connection part 41 and the electrode plates 21 and 22 will be extended
- ultrasonic vibration welding is adopted as an example of vibration welding, but the present invention is not limited to this.
- a minute vibration is mechanically applied to the outermost welding object among the plurality of superimposed welding objects, thereby generating friction between the overlapping welding objects and welding. It may be a method.
- the connection portion 41 welded to the projecting portions 24 and 25 of the electrode body 20 by the application of vibration is constituted by a rolled material, and the rolling direction corresponds to the direction of the amplitude of vibration, Actions and effects similar to those of the above embodiment can be obtained.
- connection piece 425 of the current collector 42 is overlapped on one facing piece 430 of the clip member 43 in a state of sandwiching the protruding parts 24 and 25 (lamination parts 26 and 26). And the vibration is provided to the other opposing piece 430 (opposing piece 430 located outside) of the clip member 43 which is the connecting portion 41 (the ultrasonic vibration is applied by the horn P1).
- the connection piece 425 is used as the connection portion 41 to vibrate the connection piece 425 (directly pressing the horn P1 against the connection piece 425).
- the anvil P2 may be pressed against the other facing piece 430 to apply vibration).
- the connecting piece 425 of the current collector 42 is connected to the other facing piece 430 (outside of the clip member 43). Of the opposing piece 430). And you may make it provide a vibration with respect to either the connection piece 425 in the outer side as the connection part 41, and one opposing piece 430 (connection part 41) in an inner side. That is, the horn P1 is pressed against one of the outer connecting piece 425 and the inner facing piece 430, and the anvil P2 is pressed against either the outer connecting piece 425 or the inner facing piece 430 to apply vibration. You may do it.
- connection piece 425 which is the connection portion 41 or one of the opposing pieces 430.
- connection part 41 (connection piece 425 or one opposing piece 430) is comprised with a rolling material, and material is taken so that the rolling direction of the connection part 41 may correspond to the amplitude direction of the vibration at the time of vibration welding.
- the current collecting member 40 (the current collector 42 and the clip member 43) is formed.
- the connection part 41 in the current collection members 40 and 40 welded to the electrode plates 21 and 22 of the electrode body 20 is extended in a direction corresponding to the amplitude of the vibration by being given vibration during vibration welding.
- the connecting portion 41 to which vibration is applied is made of a rolled material, and the rolling direction of the rolling member corresponds to the amplitude of vibration in vibration welding, the connecting portion 41 is rolled in the rolling direction (vibration amplitude). Direction).
- connection piece 425 of the current collector 42 is connected to the outer surface or the inner surface of the laminated portion 26 of the electrode body 20 as shown in FIGS.
- the connecting piece 425 and the protruding portions 24 and 25 of the electrode body 20 may be sandwiched between the clip members 43.
- the pair of opposed pieces 430 and 430 of the clip member 43 are located on the outermost side.
- any one of the opposing pieces 430 may be used as the connection portion 41 to apply vibration to the opposing piece 430. That is, the horn P1 may be pressed against one of the opposing pieces 430 and the anvil P2 may be pressed against either of the opposing pieces 430 to apply vibration to the horn P1.
- the current collecting member 40 includes the current collector 42 and the clip member 43, but is not limited thereto.
- the current collecting member 40 is a current collector 42 disposed along the electrode plates 21 and 22 of the electrode body 20, and is electrically connected to the external terminal 30.
- the current collector 42 and the contact member 44 disposed along the electrode plates 21 and 22 of the electrode body 20 may be provided.
- the current collector 42 may be the same as in the above embodiment.
- the current collector has a basic configuration in common with the current collector 42 of the above-described embodiment, and the connection piece 425 is overlapped on the outer surface of the protruding portions 24 and 25 (laminated portion 26) of the electrode body 20. May be.
- the contact member 44 may be disposed so as to sandwich the electrode plates 21 and 22 of the projecting portions 24 and 25 together with the connection piece 425 of the current collector 42.
- the contact member 44 only needs to be arranged along the protruding portions 24 and 25 (laminated portions 26 and 26) of the electrode body 20.
- the abutting member 44 may be formed in a plate shape, or may be press-molded into a shape corresponding to the shape of the protruding portions 24 and 25 of the electrode body 20.
- connection piece 425 or the contact member 44 that is the connection portion 41 are formed of a rolled material, and the connection pieces 425 or the contact members 44 are arranged so that the rolling direction corresponds to the amplitude direction of vibration during vibration welding. Be placed. Therefore, as in the above embodiment, when the current collecting member 40 and the electrode body 20 are subjected to ultrasonic vibration welding, the connection piece 425 or the contact member 44 that contacts the horn P1 to which ultrasonic vibration is applied is rolled. It is made of a material, and is formed by removing the material so that its rolling direction corresponds to the amplitude direction of ultrasonic vibration during vibration welding.
- the current collecting member 40 includes the current collector 42 and the clip member 43, but is not limited thereto.
- the current collecting member 40 may be configured by only the current collector 42 connected to the external terminal 30.
- the connection piece 425 as the connection portion 41 is made of a rolled material, and the rolling direction of the rolled material is the same as that during vibration welding.
- the current collector 42 (current collecting member 40) may be disposed so as to correspond to the amplitude direction of vibration (the material may be removed).
- the connecting pieces 425 and 425 of the current collector 42 are joined to the stacked portions 26 and 26 on the assumption that the protruding portions 24 and 25 of the electrode body 20 have two stacked portions 26 and 26.
- the protruding portions 24 and 25 of the electrode body 20 may be vibration-welded to the current collector 42 (current collector 40) in a state where the protrusions 24 and 25 are bundled together.
- the current collector 42 has a configuration in which an opening 424 is provided in the electrode attachment portion 421 and a pair of connection pieces 425 and 425 having both ends connected to each other are provided on both sides of the opening 424.
- the electrode attachment portion 421 of the current collector 42 may include a pair of connection pieces 425 and 425 that are divided into two forks from the intermediate portion 422 (only one end of each other is connected).
- the current collector 42 (electrode attachment portion 421) may be one in which one connection piece 425 is configured.
- the current collector 42 (electrode attachment portion 421) may be anything provided with the electrode attachment portion 421 that can be disposed so as to overlap the protruding portions 24 and 25 of the electrode body 20.
- the rolling direction of the connecting portion 41 and the amplitude direction of vibration in vibration welding completely coincide, but the present invention is not limited to this.
- the rolling direction of the connecting portion 41 may correspond to the amplitude direction of vibration during vibration welding. That is, in the case of vibration welding, the rolling direction of the connecting portion 41 is not only in a state where it completely coincides with the vibration amplitude direction in vibration welding.
- the rolling direction of the connection portion 41 may be inclined with respect to the vibration amplitude direction in a range in which the extension of the connection portion 41 does not significantly attenuate the vibration amplitude.
- the current collecting member 40 (connecting portion) so that the rolling direction of the connecting portion 41 and the amplitude direction of vibration in vibration welding are inclined with respect to each other within a range of 0 ° to 45 °, for example. 41) may be formed.
- the current collection is performed so that the rolling direction of the connecting portion 41 and the amplitude direction of vibration in vibration welding are substantially coincident (for example, in a state where they are inclined with respect to each other within a range of 0 ° to 10 °). More preferably, the member 40 (connection portion 41) is formed.
- the secondary battery (lithium ion secondary battery) that can be charged and discharged has been described, but the type and size (capacity) of the battery are arbitrary.
- the lithium ion secondary battery was demonstrated as an example of an electrical storage element, it is not limited to this.
- the present invention can be applied to various secondary batteries, other primary batteries, and power storage elements of capacitors such as electric double layer capacitors.
- Experimental Example 1 The rolling direction of the clip member and the ultrasonic vibration direction are both the vertical direction in FIG.
- Experimental Example 2 The rolling direction of the clip member is a direction orthogonal to the vertical direction in FIG. 7 (left-right direction), and the ultrasonic vibration direction is the vertical direction in FIG.
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Abstract
Description
外部端子と、
極板が積層された電極体と、
外部端子と電極体とを電気的に接続する集電部材であって、振動溶接によって極板に溶着された接続部を有する集電部材とを備え、
集電部材のうちの少なくとも接続部が圧延材で構成されている。
接続部の圧延方向は、振動溶接時に付与される振動の振幅方向と対応する、
ようにし得る。
振動溶接は、極板及び接続部を挟み込むホーン及びアンビルのうちのホーンに超音波振動を付与することで、極板及び接続部を溶着させる超音波振動溶接であり、
接続部は、超音波振動溶接時にホーンと対向する部位である、
ようにし得る。
電極体の極板に沿って配置された集電体であって、外部端子に電気的に接続された集電体と、
極板を挟んで対向する一対の対向片を有するクリップ部材であって、一対の対向片のうちの何れか一方の対向片に集電体が重ね合わされるクリップ部材とを備え、
接続部は、集電体の極板に沿った部分、又は一対の対向片のうちの何れか一方の対向片である、
ようにし得る。
電極体の極板に沿って配置された集電体であって、外部端子に電気的に接続された集電体と、
電極体の極板に沿って配置された当て部材とを備え、
接続部は、集電体又は当て部材の何れか一方における極板に沿った部分である、
ようにし得る。
外部端子と、
極板が積層された電極体と、
振動溶接によって極板に溶着された接続部を有し、外部端子と電極体とを電気的に接続する集電部材とを備えた蓄電素子の製造方法であって、
集電部材のうちの少なくとも接続部が圧延材で構成される。
接続部の圧延方向を振動溶接における振動の振幅方向と対応させた状態で、接続部を極板に振動溶接する、
ようにし得る。
振動溶接は、極板及び接続部を挟み込むホーン及びアンビルのうちのホーンに超音波振動を付与することで、極板及び接続部を溶着させる超音波振動溶接であり、
超音波振動溶接時にホーンを接続部に対向させる、
ようにし得る。
電極体の極板に沿って配置された集電体であって、外部端子に電気的に接続された集電体と、
極板を挟んで対向する一対の対向片を有するクリップ部材であって、一対の対向片のうちの何れか一方の対向片に集電体が重ね合わされるクリップ部材とを備え、
接続部は、集電体の極板に沿った部分、又は一対の対向片のうちの何れか一方の対向片である、
ようにし得る。
電極体の極板に沿って配置された集電体であって、外部端子に電気的に接続された集電体と、
電極体の極板に沿って配置された当て部材とを備え、
接続部は、集電体又は当て部材の何れか一方における極板に沿った部分である、ようにし得る。
振動溶接は、極板及び接続部を挟み込むホーン及びアンビルのうちのホーンに超音波振動を付与することで、極板及び接続部を溶着させる超音波振動溶接であり、
接続部は、超音波振動溶接時にホーンと対向する部位である、
ようにし得る。
電極体の極板に沿って配置された集電体であって、外部端子に電気的に接続された集電体と、
極板を挟んで対向する一対の対向片を有するクリップ部材であって、前記一対の対向片のうちの何れか一方の対向片に集電体が重ね合わされるクリップ部材とを備え、
接続部は、集電体の極板に沿った部分、又は一対の対向片のうちの何れか一方の対向片である、
ようにし得る。
電極体の極板に沿って配置された集電体であって、外部端子に電気的に接続された集電体と、
電極体の極板に沿って配置された当て部材とを備え、
接続部は、集電体又は当て部材の何れか一方における極板に沿った部分である、
ようにし得る。
外部端子と、
極板が積層された電極体と、
振動溶接によって極板に溶着された接続部を有し、外部端子と前記電極体とを電気的に接続する集電部材とを備えた蓄電素子の製造方法であって、
集電部材のうちの少なくとも接続部が圧延材で構成される。
振動溶接は、極板及び接続部を挟み込むホーン及びアンビルのうちのホーンに超音波振動を付与することで、極板及び接続部を溶着させる超音波振動溶接であり、
超音波振動溶接時にホーンを接続部に対向させる、
ようにし得る。
電極体の極板に沿って配置された集電体であって、外部端子に電気的に接続された集電体と、
極板を挟んで対向する一対の対向片を有するクリップ部材であって、一対の対向片のうちの何れか一方の対向片に集電体が重ね合わされるクリップ部材とを備え、
接続部は、集電体の極板に沿った部分、又は一対の対向片のうちの何れか一方の対向片である、
ようにし得る。
電極体の極板に沿って配置された集電体であって、外部端子に電気的に接続された集電体と、
電極体の極板に沿って配置された当て部材とを備え、
接続部は、集電体又は当て部材の何れか一方における極板に沿った部分である、
ようにし得る。
厚みが15μmの集電箔(上記実施形態の極板に相当)を30枚重ね、この重ねられた集電箔を厚みが0.1mmのクリップ部材によって挟み込む。その後、厚みが1.5mmの集電体を外側から前記クリップ部材に重ね合わせる。この重ね合わせた状態のクリップ部材と集電体とに対し、集電体側にアンビル、クリップ部材側にローレット形状(詳しくは、正四角錐形状の複数の凸部が配列された形状)のホーンをそれぞれ配置して挟み込み、超音波溶接を行う。ここで、集電箔、クリップ部材、集電体の材料は、いずれもアルミニウム合金である。
・実験例1:クリップ部材の圧延方向及び超音波の振動方向は、いずれも図7における上下方向とする。
・実験例2:クリップ部材の圧延方向は、図7の上下方向と直交する方向(左右方向)、超音波の振動方向は、図7の上下方向とする。
・実験例1では、超音波溶接時の最大出力が760Wであり、溶接後のクリップ部材と集電箔との間の引っ張り強度が1259Nであった。
・実験例2では、超音波溶接時の最大出力が640Wであり、溶接後のクリップ部材と集電箔との間の引っ張り強度が700Nであった。
Claims (10)
- 外部端子と、
極板が積層された電極体と、
前記外部端子と前記電極体とを電気的に接続する集電部材であって、振動溶接によって前記極板に溶着された接続部を有する集電部材とを備え、
前記集電部材のうちの少なくとも前記接続部が圧延材で構成される
蓄電素子。 - 前記接続部の圧延方向は、前記振動溶接時に付与される振動の振幅方向と対応している
請求項1に記載の蓄電素子。 - 前記振動溶接は、前記極板及び前記接続部を挟み込むホーン及びアンビルのうちの前記ホーンに超音波振動を付与することで、前記極板及び前記接続部を溶着させる超音波振動溶接であり、
前記接続部は、超音波振動溶接時に前記ホーンと対向する部位である
請求項1又は2に記載の蓄電素子。 - 前記集電部材は、
前記電極体の極板に沿って配置された集電体であって、前記外部端子に電気的に接続された集電体と、
前記極板を挟んで対向する一対の対向片を有するクリップ部材であって、前記一対の対向片のうちの何れか一方の対向片に集電体が重ね合わされるクリップ部材とを備え、
前記接続部は、前記集電体の前記極板に沿った部分、又は前記一対の対向片のうちの何れか一方の対向片である
請求項1~3のいずれか1項に記載の蓄電素子。 - 前記集電部材は、
前記電極体の極板に沿って配置された集電体であって、前記外部端子に電気的に接続された集電体と、
前記電極体の極板に沿って配置された当て部材とを備え、
前記接続部は、前記集電体又は前記当て部材の何れか一方における前記極板に沿った部分である
請求項1~3のいずれか1項に記載の蓄電素子。 - 外部端子と、
極板が積層された電極体と、
振動溶接によって前記極板に溶着された接続部を有し、前記外部端子と前記電極体とを電気的に接続する集電部材とを備えた蓄電素子の製造方法であって、
前記集電部材のうちの少なくとも前記接続部が圧延材で構成される
蓄電素子の製造方法。 - 前記接続部の圧延方向を前記振動溶接における振動の振幅方向と対応させた状態で、前記接続部を前記極板に振動溶接する
請求項6に記載の蓄電素子の製造方法。 - 前記振動溶接は、前記極板及び前記接続部を挟み込むホーン及びアンビルのうちの前記ホーンに超音波振動を付与することで、前記極板及び前記接続部を溶着させる超音波振動溶接であり、
超音波振動溶接時に前記ホーンを前記接続部に対向させる
請求項6又は7に記載の蓄電素子の製造方法。 - 前記集電部材は、
前記電極体の極板に沿って配置された集電体であって、前記外部端子に電気的に接続された集電体と、
前記極板を挟んで対向する一対の対向片を有するクリップ部材であって、前記一対の対向片のうちの何れか一方の対向片に集電体が重ね合わされるクリップ部材とを備え、
前記接続部は、前記集電体の前記極板に沿った部分、又は前記一対の対向片のうちの何れか一方の対向片である
請求項6~8のいずれか1項に記載の蓄電素子の製造方法。 - 前記集電部材は、
前記電極体の極板に沿って配置された集電体であって、前記外部端子に電気的に接続された集電体と、
前記電極体の極板に沿って配置された当て部材とを備え、
前記接続部は、前記集電体又は前記当て部材の何れか一方における前記極板に沿った部分である
請求項6~8のいずれか1項に記載の蓄電素子の製造方法。
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US10003067B2 (en) | 2018-06-19 |
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US20150221926A1 (en) | 2015-08-06 |
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CN104584271B (zh) | 2018-04-17 |
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