WO2013151012A1 - Élément de touret - Google Patents
Élément de touret Download PDFInfo
- Publication number
- WO2013151012A1 WO2013151012A1 PCT/JP2013/059948 JP2013059948W WO2013151012A1 WO 2013151012 A1 WO2013151012 A1 WO 2013151012A1 JP 2013059948 W JP2013059948 W JP 2013059948W WO 2013151012 A1 WO2013151012 A1 WO 2013151012A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- reel
- adhesive film
- elastic ring
- reel member
- elastic body
- Prior art date
Links
- 239000002313 adhesive film Substances 0.000 claims abstract description 116
- 238000004804 winding Methods 0.000 claims abstract description 74
- 230000002093 peripheral effect Effects 0.000 claims abstract description 19
- 230000000903 blocking effect Effects 0.000 abstract description 23
- 238000001125 extrusion Methods 0.000 abstract 1
- 229920005989 resin Polymers 0.000 description 27
- 239000011347 resin Substances 0.000 description 27
- 239000010408 film Substances 0.000 description 24
- 239000011230 binding agent Substances 0.000 description 22
- 239000000463 material Substances 0.000 description 21
- 239000003822 epoxy resin Substances 0.000 description 15
- 229920000647 polyepoxide Polymers 0.000 description 15
- 238000000034 method Methods 0.000 description 14
- 239000002245 particle Substances 0.000 description 14
- 230000000052 comparative effect Effects 0.000 description 13
- 238000005259 measurement Methods 0.000 description 13
- 238000001723 curing Methods 0.000 description 11
- 229920001971 elastomer Polymers 0.000 description 10
- 239000005060 rubber Substances 0.000 description 10
- 239000012790 adhesive layer Substances 0.000 description 9
- 239000003795 chemical substances by application Substances 0.000 description 9
- 229920005549 butyl rubber Polymers 0.000 description 8
- -1 Poly Ethylene Terephthalate Polymers 0.000 description 6
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 5
- 230000001105 regulatory effect Effects 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 238000011156 evaluation Methods 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000004925 Acrylic resin Substances 0.000 description 3
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 229920000459 Nitrile rubber Polymers 0.000 description 3
- 239000006087 Silane Coupling Agent Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000000853 adhesive Substances 0.000 description 2
- 230000001070 adhesive effect Effects 0.000 description 2
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical compound C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 230000001771 impaired effect Effects 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000003094 microcapsule Substances 0.000 description 2
- 230000003287 optical effect Effects 0.000 description 2
- 239000005026 oriented polypropylene Substances 0.000 description 2
- 239000013034 phenoxy resin Substances 0.000 description 2
- 229920006287 phenoxy resin Polymers 0.000 description 2
- 229920003023 plastic Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 2
- 239000004810 polytetrafluoroethylene Substances 0.000 description 2
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- YYJIYUNJTKCRHL-UHFFFAOYSA-N (2-hydroxy-3-prop-2-enoyloxypropyl) prop-2-enoate Chemical compound C=CC(=O)OCC(O)COC(=O)C=C YYJIYUNJTKCRHL-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- CFVWNXQPGQOHRJ-UHFFFAOYSA-N 2-methylpropyl prop-2-enoate Chemical compound CC(C)COC(=O)C=C CFVWNXQPGQOHRJ-UHFFFAOYSA-N 0.000 description 1
- GZVHEAJQGPRDLQ-UHFFFAOYSA-N 6-phenyl-1,3,5-triazine-2,4-diamine Chemical compound NC1=NC(N)=NC(C=2C=CC=CC=2)=N1 GZVHEAJQGPRDLQ-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 229930185605 Bisphenol Natural products 0.000 description 1
- XWUNIDGEMNBBAQ-UHFFFAOYSA-N Bisphenol A ethoxylate diacrylate Chemical compound C=1C=C(OCCOC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OCCOC(=O)C=C)C=C1 XWUNIDGEMNBBAQ-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- RIUQHCOQTXZANT-UHFFFAOYSA-N OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCCCCO Chemical compound OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OC(=O)C=C.OCCCCO RIUQHCOQTXZANT-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-VAWYXSNFSA-N Stilbene Natural products C=1C=CC=CC=1/C=C/C1=CC=CC=C1 PJANXHGTPQOBST-VAWYXSNFSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- 239000007983 Tris buffer Substances 0.000 description 1
- 238000003848 UV Light-Curing Methods 0.000 description 1
- 229920006311 Urethane elastomer Polymers 0.000 description 1
- XBCFXELSWDAYIW-UHFFFAOYSA-N [4-[2-[4-(prop-2-enoyloxymethoxy)phenyl]propan-2-yl]phenoxy]methyl prop-2-enoate Chemical compound C=1C=C(OCOC(=O)C=C)C=CC=1C(C)(C)C1=CC=C(OCOC(=O)C=C)C=C1 XBCFXELSWDAYIW-UHFFFAOYSA-N 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000004305 biphenyl Substances 0.000 description 1
- 235000010290 biphenyl Nutrition 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 125000001951 carbamoylamino group Chemical group C(N)(=O)N* 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000011889 copper foil Substances 0.000 description 1
- 239000013039 cover film Substances 0.000 description 1
- 125000004386 diacrylate group Chemical group 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 238000010494 dissociation reaction Methods 0.000 description 1
- 208000018459 dissociative disease Diseases 0.000 description 1
- 239000013013 elastic material Substances 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002460 imidazoles Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000011147 inorganic material Substances 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 229920003049 isoprene rubber Polymers 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 239000011133 lead Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910001092 metal group alloy Inorganic materials 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- LUCXVPAZUDVVBT-UHFFFAOYSA-N methyl-[3-(2-methylphenoxy)-3-phenylpropyl]azanium;chloride Chemical compound Cl.C=1C=CC=CC=1C(CCNC)OC1=CC=CC=C1C LUCXVPAZUDVVBT-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920000768 polyamine Chemical class 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- LYBIZMNPXTXVMV-UHFFFAOYSA-N propan-2-yl prop-2-enoate Chemical compound CC(C)OC(=O)C=C LYBIZMNPXTXVMV-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229920002379 silicone rubber Polymers 0.000 description 1
- 239000004945 silicone rubber Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- AAAQKTZKLRYKHR-UHFFFAOYSA-N triphenylmethane Chemical compound C1=CC=CC=C1C(C=1C=CC=CC=1)C1=CC=CC=C1 AAAQKTZKLRYKHR-UHFFFAOYSA-N 0.000 description 1
- KBMBVTRWEAAZEY-UHFFFAOYSA-N trisulfane Chemical compound SSS KBMBVTRWEAAZEY-UHFFFAOYSA-N 0.000 description 1
- 230000003313 weakening effect Effects 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H75/00—Storing webs, tapes, or filamentary material, e.g. on reels
- B65H75/02—Cores, formers, supports, or holders for coiled, wound, or folded material, e.g. reels, spindles, bobbins, cop tubes, cans, mandrels or chucks
- B65H75/04—Kinds or types
- B65H75/08—Kinds or types of circular or polygonal cross-section
- B65H75/14—Kinds or types of circular or polygonal cross-section with two end flanges
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H75/00—Storing webs, tapes, or filamentary material, e.g. on reels
- B65H75/02—Cores, formers, supports, or holders for coiled, wound, or folded material, e.g. reels, spindles, bobbins, cop tubes, cans, mandrels or chucks
- B65H75/18—Constructional details
- B65H75/24—Constructional details adjustable in configuration, e.g. expansible
- B65H75/242—Expansible spindles, mandrels or chucks, e.g. for securing or releasing cores, holders or packages
- B65H75/245—Expansible spindles, mandrels or chucks, e.g. for securing or releasing cores, holders or packages by deformation of an elastic or flexible material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65H—HANDLING THIN OR FILAMENTARY MATERIAL, e.g. SHEETS, WEBS, CABLES
- B65H2701/00—Handled material; Storage means
- B65H2701/30—Handled filamentary material
- B65H2701/37—Tapes
- B65H2701/377—Adhesive tape
Definitions
- the present invention relates to a reel member around which a tape-like adhesive film is wound, and more particularly to a reel member in which an elastic body is mounted on a core and the adhesive film is wound around the elastic body.
- a mounting method has been used in which electronic components are mounted on a substrate using an adhesive film.
- COG Chip on Glass
- an IC chip as a liquid crystal driving circuit is mounted on a peripheral portion of a liquid crystal display panel (LCD panel) via a conductive adhesive film, or a tab serving as an interconnector in a solar battery cell
- the connection method which connects a line is mentioned.
- the conductive adhesive film is obtained by forming an adhesive layer in which conductive particles are dispersed in a binder resin on a base film serving as a support.
- a conductive adhesive film 50 is used, for example, in the form of a reel wound body wound around a core 53 of a reel member 51 having a reel flange 52 as shown in FIG. Reference 1).
- JP 2001-171033 A JP 2010-257983 A JP 2011-58007 A
- an object of the present invention is to provide a reel member that can increase the length of an adhesive film, suppress protrusion and blocking due to concentration of winding pressure, and prevent winding deviation and the like.
- a reel member according to the present invention includes a winding core, an annular elastic body that is fitted to the outer peripheral surface of the winding core and on which a tape-like adhesive film is wound, and the winding described above.
- Reel flanges provided on both sides of the core, and the elastic body has a Shore A hardness of more than 30 ° and less than 90 °.
- the elastic body absorbs the winding pressure even when the adhesive film is wound and the winding body of the adhesive film is wound by being elastically deformable while the adhesive film is wound. Protruding and blocking can be prevented.
- FIG. 1 is a side view showing a reel member to which the present invention is applied.
- FIG. 2 is a cross-sectional view showing the reel member in which the wound state of the adhesive film is broken.
- FIG. 3 is a side view showing a reel member to which the present invention is applied.
- FIG. 4 is a side view showing another reel member to which the present invention is applied.
- FIG. 5 is a side view showing another reel member to which the present invention is applied.
- FIG. 6 is a side view showing another reel member to which the present invention is applied.
- FIG. 7 is a side view showing another reel member to which the present invention is applied.
- FIG. 8 is a cross-sectional view showing the configuration of the adhesive film.
- FIG. 9 is a perspective view illustrating a method of measuring the protrusion in the embodiment.
- FIG. 10 is a side view illustrating a method for measuring the tightening load strength in the embodiment.
- FIG. 11 is a perspective view showing a conventional reel member.
- FIG. 12 is a side view showing a state in which winding deviation or loosening occurs in a conventional reel member.
- FIG. 13 is a side view showing a state in which winding of the conventional reel member or dropping of the adhesive film from the wound body has occurred.
- a reel member 1 to which the present invention is applied includes a winding core 3, an elastic ring 4 that is fitted to the outer peripheral surface of the winding core 3 and on which a tape-like adhesive film 2 is wound, And reel flanges 5 provided on both sides of the core 3.
- the winding core 3 has a cylindrical shape, and is formed with an insertion port 3a through which a rotating device (not shown) that rotates the elastic ring 4 is inserted. Moreover, the core 3 has the width
- the elastic ring 4 is made of an elastic body such as rubber, has a cylindrical shape, and has substantially the same width as the adhesive film 2 or a width equal to or larger than the width of the adhesive film 2.
- the elastic ring 4 is integrated with the core 3 and the reel flange 5 by being fitted to the core 3.
- the elastic ring 4 absorbs the winding pressure even when winding of the wound body of the adhesive film 2 occurs, Blocking can be prevented.
- the reel member 1 can wind the adhesive film 2 with a large tension by providing the elastic ring 4.
- the elastic ring 4 has a Shore A hardness of 30 ° to 90 °. If the hardness of the elastic ring 4 is greater than 90 ° in Shore A hardness, the reel member 1 becomes too hard and cannot be formed into a cylindrical shape depending on the ring diameter. Occasionally, the winding pressure cannot be absorbed and there is a risk of protrusion and blocking. Further, in the reel member 1, when the hardness of the elastic ring 4 is less than 30 ° in Shore A hardness, the elastic ring 4 is crushed by the winding pressure when the adhesive film 2 is wound, and the wound body of the adhesive film 2 is deformed. And tightening load strength is reduced.
- the tightening load strength refers to the maximum load applied when the wound adhesive film 2 is pulled out while the rotation of the core 3 and the elastic ring 4 is restricted.
- the winding pressure is applied to the adhesive film winding body. Is generated, and the winding pressure is accumulated toward the inner circumferential side of the wound body. For this reason, the load applied to pulling out the adhesive film increases, but it suddenly decreases at a certain point and can be pulled out with a low load. As shown in FIG.
- the winding state collapses and accumulates due to the reel flange 52 not being able to support the film winding body and curving left and right due to an increase in the winding pressure applied to the adhesive film winding body. This is because the winding pressure is released, and the adhesive film 50 is not properly superimposed, and the winding pressure can no longer be accumulated and supported normally.
- the adhesive film winding body in which the winding pressure is accumulated until the winding state is broken the binder resin protrudes or blocks, the adhesive film falls off, and the adhesive film 2 cannot be normally unwound.
- the tightening load strength of the reel member means the maximum load strength that can maintain a normal winding state when a load due to tightening is applied to the wound body of the adhesive film.
- the winding tightening load strength shows the resistance to maintain the winding state and support the winding pressure with respect to the winding tightening of the wound body of the adhesive film.
- the elastic ring 4 preferably has a Shore A hardness of 30 ° to 90 °.
- the elastic ring 4 has a Shore A hardness of 80 ° or more, so that the maximum load applied when the wound adhesive film 2 is pulled out in a state where the rotation of the core 3 and the elastic ring 4 is restricted. That is, the tightening load strength can be 5 N or more.
- the elastic ring 4 is formed using rubber such as buty rubber, nitrile rubber, NE, or urethane. Moreover, the winding quality of the adhesive film 2 improves by using a material with high impact resilience. Examples of the material of the elastic ring 4 include urethane, NR, butadiene rubber, isoprene rubber, and silicone rubber.
- the elastic ring 4 cannot obtain a desired hardness when a material with volume shrinkage with respect to the winding pressure such as a foam is used, and easily deforms due to the tightness of the adhesive film 2. The winding state cannot be maintained. Therefore, the elastic ring 4 is preferably made of a material having a desired hardness such as rubber.
- foamed elastic materials such as olefin-based foams and foamed urethane have an elastic modulus (Young's modulus) of 0.005 to 0.06 GPa, whereas rubber systems have 0.01 to 0.1 GPa. It is numerically superior.
- the elastic ring 4 can be appropriately adjusted in thickness according to the rubber hardness and the length of the wound adhesive film 2.
- the length of the wound adhesive film 2 is 200 to 500 m.
- the thickness is preferably in the range of 0.5 to 10 mm.
- Reel flanges 5 are provided on both sides of the core 3 and the elastic ring 4.
- the reel flange 5 supports the adhesive film 2 wound around the elastic ring 4, and is formed in a disk shape using a transparent plastic material, for example. Further, the reel flange 5 may be subjected to electrostatic treatment on the surface in contact with the adhesive film 2. Examples of the method for applying electrostatic treatment include a method of applying a compound such as polythiophene.
- the reel flange 5 is provided with a retreat space 10 in which a part of the elastic ring 4 is retreated when the elastic ring 4 is compressed and deformed by the accumulated winding pressure.
- the elastic ring 4 is formed of a material such as rubber, and when compressed by applying a winding pressure, the elastic ring 4 is deformed without contracting to absorb the winding pressure.
- the retreat space 10 is a space in which a part of the deformed elastic ring 4 is retreated, and is recessed on the inner peripheral surface of the reel flange 5, for example, as shown in FIG.
- the retreat space 10 is provided on the inner peripheral surface of the reel flange 5 at a position facing the side surface of the elastic ring 4.
- the retreat space 10 is formed with an annular concave groove 11 having the same shape at a position facing the side surface of the elastic ring 4 of the pair of left and right reel flanges 5 a and 5 b.
- the retreat space 10 has a depth A of the concave groove 11a on the one reel flange 5a side, a depth C of the concave groove 11b on the other reel flange 5b side, and a concave groove 11a, 11b on both reel flanges 5a, 5b.
- the width D is the same as the thickness of the elastic ring 4.
- the sectional area of the retracting space 10 (A ⁇ D + C ⁇ D) / the sectional area of the elastic ring 4 (B ⁇ D) is 3.5 to 20%. It is preferable. If the cross-sectional area ratio between the retracting space 10 and the elastic ring 4 is less than 3.5%, that is, if the retracting space 10 is too narrow, the elastic ring 4 is compressed and retracted according to the winding pressure when the adhesive film 2 is wound. Can not absorb the winding pressure. On the other hand, if the cross-sectional area ratio between the retracting space 10 and the elastic ring 4 is larger than 20%, the compression deformation becomes unstable, and the function as an elastic body is lowered, and the adhesive film 2 is collapsed.
- the retreat space 10 has a size that supports the elastic ring 4 in contact with the elastic ring 4 when the elastic ring 4 is deformed to the maximum extent. Thereby, the evacuation space 10 supports the elastic ring 4 that has been compressed and deformed, and can stably absorb the winding pressure.
- the retreat space 10 is provided with a plurality of ridge ribs 12 radially on the inner peripheral surface of the reel flange 5 as shown in FIG. 4.
- a clearance may be provided between the convex rib 12 and the elastic ring 4 to adjust the distance between the elastic ring 4 and the reel flange 5 and the distance between the elastic ring 4 and the convex rib 12. Good.
- the retreat space 10 is provided between the elastic ring 4 and the convex rib 12 and between the elastic ring 4 and the reel. It is formed between the flange 5.
- the retreat space 10 may be formed by adjusting the height of the convex rib 12 by bringing the convex rib 12 and the elastic ring 4 into contact with each other.
- the retreat space 10 is between the elastic ring 4 and the reel flange 5.
- the reel flange 5 is not provided with the protruding rib 12 at a position facing the elastic ring 4 but is provided facing the adhesive film 2 wound around the elastic ring 4. Thereby, the reel flange 5 can support the winding body side surface of the adhesive film 2 by the protruding ribs 12, reduce the contact area with the binder resin, and suppress blocking.
- the retreat space 10 has the height of the protruding rib rib 12a on the one reel flange 5a side as A, the height of the protruding rib rib 12b on the other reel flange 5b side as C, and the thickness of the elastic ring 4
- the sectional area of the retreat space 10 (A ⁇ D + C ⁇ D) / the cross section of the elastic ring 4 (B ⁇ D) is preferably 3.5 to 20%.
- the retreat space 10 may be formed by projecting an annular rib 13 on the inner peripheral surface of the reel flange 5 as shown in FIG.
- the annular rib 13 serves as a retreat space for the elastic ring 4 whose inside is compressed and deformed, is formed concentrically with the reel flange 5, and abuts on the outer peripheral side surface of the elastic ring 4.
- the adhesive film 2 wound around the reel member 1 will be described.
- the adhesive film 2 includes an adhesive layer 20 and a base film 21 serving as a support that supports the adhesive layer 20.
- the adhesive layer 20 can be an anisotropic conductive film (ACF: Anisotropic Conductive Film) containing conductive particles 22 in a binder (insulating adhesive composition) 20a, but is not limited thereto.
- ACF Anisotropic Conductive Film
- NCF Non-Conductive Film
- the binder 20a of the adhesive film for example, a normal binder containing a film forming resin, a thermosetting resin, a latent curing agent, a silane coupling agent, or the like can be used.
- a normal binder containing a film forming resin, a thermosetting resin, a latent curing agent, a silane coupling agent, or the like can be used.
- an anisotropic conductive composition in which the conductive particles 22 are dispersed in the binder 20 a or an insulating adhesive composition that does not contain the conductive particles 22 in the binder 20 a is applied on the base film 21.
- the film is formed on the base film 21.
- the base film 21 supports the binder 20a in the form of a film.
- PET Poly Ethylene Terephthalate
- OPP Oriented Polypropylene
- PMP Poly-4-methlpentene-1
- PTFE Polytetrafluoroethylene
- the film-forming resin contained in the binder 20a is preferably a resin having an average molecular weight of about 10,000 to 80,000.
- the film forming resin include various resins such as an epoxy resin, a modified epoxy resin, a urethane resin, and a phenoxy resin. Among these, phenoxy resin is particularly preferable from the viewpoint of film formation state, connection reliability, and the like.
- thermosetting resin is not particularly limited as long as it has fluidity at room temperature, and examples thereof include commercially available epoxy resins and acrylic resins.
- the epoxy resin is not particularly limited.
- naphthalene type epoxy resin biphenyl type epoxy resin, phenol novolac type epoxy resin, bisphenol type epoxy resin, stilbene type epoxy resin, triphenolmethane type epoxy resin, phenol aralkyl type epoxy resin.
- an acrylic compound, liquid acrylate, etc. can be selected suitably.
- what made acrylate the methacrylate can also be selected from methyl acrylate, ethyl acrylate, isopropy
- the latent curing agent is not particularly limited, and examples thereof include various curing agents such as a heat curing type and a UV curing type.
- the latent curing agent does not normally react, but is activated by various triggers selected according to applications such as heat, light, and pressure, and starts the reaction.
- the activation method of the thermally activated latent curing agent includes a method of generating active species (cations and anions) by a dissociation reaction by heating, and the like.
- Thermally active latent curing agents include imidazole series, hydrazide series, boron trifluoride-amine complex, sulfonium salt, amine imide, polyamine salt, dicyandiamide, and modified products thereof. The above mixture may be sufficient. Among these, a microcapsule type imidazole-based latent curing agent is preferable.
- the silane coupling agent is not particularly limited, and examples thereof include an epoxy type, an amino type, a mercapto sulfide type, and a ureido type. By adding the silane coupling agent, the adhesion at the interface between the organic material and the inorganic material is improved.
- Examples of the conductive particles 22 include any known conductive particles used in anisotropic conductive films.
- Examples of the conductive particles 22 include particles of various metals and metal alloys such as nickel, iron, copper, aluminum, tin, lead, chromium, cobalt, silver, gold, metal oxide, carbon, graphite, glass, ceramic, Examples thereof include those in which the surface of particles such as plastic is coated with metal, or those in which the surface of these particles is further coated with an insulating thin film.
- examples of the resin particle include an epoxy resin, a phenol resin, an acrylic resin, an acrylonitrile / styrene (AS) resin, a benzoguanamine resin, a divinylbenzene resin, a styrene resin, and the like. Can be mentioned.
- the adhesive film 2 in which the adhesive film 2 made of ACF or NCF is laminated on the base film 21 is used.
- the present invention is not limited to this example.
- the film laminate may be an anisotropic conductive film having two or more layers in which ACF and NCF are laminated.
- the adhesive film 2 may have a configuration in which a cover film is provided on the surface opposite to the surface on which the base film 21 of the adhesive film 2 is laminated.
- a cover film is provided on the surface opposite to the surface on which the base film 21 of the adhesive film 2 is laminated.
- it is good also as an adhesive film with copper foil for electrically connecting the electrodes of a plurality of photovoltaic cells.
- reel members were prepared in which the type of elastic ring 4 to be fitted to the core 3 was changed, and an adhesive film having a length of 300 m was wound around each reel member. Then, the presence or absence of blocking of the binder resin when the adhesive film was unwound while the winding core and the elastic ring rotated as usual from each reel member and the presence or absence of blocking were confirmed. Further, the tightening load strength when the adhesive film was pulled out in a state where the rotation of the winding core and the elastic ring of each reel member was regulated and the presence or absence of protrusion after the measurement was evaluated.
- the reel member used in each example and comparative example is provided with a retracting space 10 for the elastic ring 4 formed of a concave groove 11 on the inner peripheral surface of the reel flange 5.
- a retracting space 10 for the elastic ring 4 formed of a concave groove 11 on the inner peripheral surface of the reel flange 5.
- Sony Chemical & Information Device Co., Ltd. ACF was used for the adhesive film wound around each reel member.
- the thickness of the adhesive layer of the adhesive film is 10 to 25 ⁇ m, and the minimum melt viscosity of the binder is 3.0 ⁇ 10 ⁇ 4 Pa ⁇ S.
- Example 1 butyl rubber having a Shore A hardness of 40 ° was used as an elastic ring material.
- the thickness D of the elastic ring is 2 mm, and the ratio of the cross-sectional area between the retreat space 10 and the elastic ring 4 is: the cross-sectional area of the retreat space 10 (A ⁇ D + C ⁇ D) / the cross-sectional area of the elastic ring 4 (B ⁇ D) 5%.
- tensile_strength at the time of winding of an adhesive film is 0.75N.
- Example 2 the same conditions as in Example 1 were used except that butyl rubber having a Shore A hardness of 80 ° was used as the material of the elastic ring.
- Example 3 the conditions were the same as in Example 1 except that nitrile rubber with a Shore A hardness of 40 ° was used as the material for the elastic ring.
- Example 4 the conditions were the same as in Example 1 except that nitrile rubber with a Shore A hardness of 80 ° was used as the material for the elastic ring.
- Example 5 the conditions were the same as in Example 1 except that NE with a Shore A hardness of 40 ° was used as the elastic ring material.
- Example 6 the conditions were the same as in Example 1 except that NE with a Shore A hardness of 80 ° was used as the material for the elastic ring.
- Example 7 the conditions were the same as in Example 1 except that urethane having a Shore A hardness of 40 ° was used as the material of the elastic ring.
- Example 7 the conditions were the same as in Example 1 except that urethane with a Shore A hardness of 80 ° was used as the material for the elastic ring.
- Comparative Example 1 the conditions were the same as in Example 1 except that the adhesive film was wound using a conventional reel member in which the elastic ring 4 was not provided.
- Comparative Example 2 the same conditions as in Example 1 were used except that butyl rubber having a Shore A hardness of 30 ° was used as the material of the elastic ring.
- Comparative Example 3 the conditions were the same as in Example 1 except that butyl rubber having a Shore A hardness of 90 ° was used as the material of the elastic ring.
- each reel member is set on a measurement jig for the presence or absence of the binder resin protruding or blocking when the adhesive film is unwound from the reel member according to the example and the comparative example as usual.
- the adhesive film is unwound and left at room temperature for 24 hours with a 50 g weight W suspended from the tip. Then, the side surface of the reel flange was observed with an optical microscope, and the presence or absence of protrusion was confirmed. Subsequently, the adhesive film was unwound as usual and checked for the presence or absence of blocking. A case where no protrusion was observed was indicated by ⁇ , a case where protrusion was observed but no problem in practical use was indicated by ⁇ , and a case where blocking occurred and the wire was not normally unwound was indicated by ⁇ .
- the measurement of the tightening load strength according to the example and the comparative example is performed by setting each reel member on a measuring jig and restricting the rotation of the winding core and the elastic ring.
- the adhesive film was pulled out with G, and the load peak was measured. Further, the side surface of the reel flange was observed with an optical microscope, and the presence or absence of protrusion was confirmed.
- the measurement results are shown in Table 1.
- Comparative Example 1 in which no elastic ring was provided, when the adhesive film was unwound as usual, blocking due to protrusion occurred, making it difficult to use.
- Comparative Example 2 using an elastic ring with a Shore A hardness of 30 °, the winding tightening load strength when the adhesive film was pulled out was as low as 0.5 N, and the protrusion was pulled out after the drawing, making it difficult to use.
- Comparative Example 3 using an elastic ring with a Shore A hardness of 90 °, when the adhesive film was unwound as usual, blocking due to protrusion occurred, making it practically difficult to use.
- the elastic ring material preferably has a Shore A hardness of more than 30 ° and less than 90 °.
- Example 2 in the reel member provided with the retraction space 10 having the same shape as that of Example 1, the cross-sectional area ratio between the retraction space 10 and the elastic ring 4: cross-sectional area of the retraction space 10 (A ⁇ D + C ⁇ D) / A reel member having an elastic ring 4 cross-sectional area (B ⁇ D) of 2% was prepared. Then, an adhesive film having a length of 300 m was wound around the reel member, and the presence or absence of blocking of the binder resin when the adhesive film was unwound from each reel member as usual was checked. Further, the tightening load strength when the adhesive film was pulled out in a state in which the rotation of each reel member was regulated was measured and the presence or absence of protrusion after the measurement was evaluated.
- Example 9 butyl rubber having a Shore A hardness of 40 ° was used as an elastic ring material.
- the thickness D of the elastic ring is 2 mm, and the tension when the adhesive film is wound is 0.75N.
- Example 10 butyl rubber having a Shore A hardness of 80 ° was used as an elastic ring material.
- the thickness D of the elastic ring is 2 mm, and the tension when the adhesive film is wound is 0.75N.
- Example 9 As shown in Table 2, in Example 9 and Example 10, blocking was not generated to the extent that both of the protrusions were found to have no practical problem. Further, the winding tightening load strength was as good as 1 N or more, and no unusable protrusion was observed even after the adhesive film was pulled out.
- Example 3 a reel member in which no evacuation space 10 was provided was prepared. That is, in the reel member according to Example 3, the ratio of the cross-sectional area between the retracting space 10 and the elastic ring 4 is 0% of the cross-sectional area of the retracting space 10 (A ⁇ D + C ⁇ D) / the cross-sectional area of the elastic ring 4 (B ⁇ D). It was. Then, an adhesive film having a length of 300 m was wound around the reel member, and the presence or absence of blocking of the binder resin when the adhesive film was unwound from each reel member as usual was checked. Further, the tightening load strength when the adhesive film was pulled out in a state in which the rotation of each reel member was regulated was measured and the presence or absence of protrusion after the measurement was evaluated.
- Comparative Example 4 butyl rubber having a Shore A hardness of 40 ° was used as an elastic ring material.
- the thickness D of the elastic ring is 2 mm, and the tension when the adhesive film is wound is 0.75N.
- Example 4 a reel member provided with an elastic ring made of urethane rubber was prepared.
- the ratio of the sectional area between the retracting space 10 and the elastic ring 4: the sectional area of the retracting space 10 (A ⁇ D + C ⁇ D) / the sectional area of the elastic ring 4 (B ⁇ D) is 5%.
- an adhesive film having a length of 300 m was wound around the reel member with a tension of 0.75 N, and the presence or absence of blocking of the binder resin when the adhesive film was unwound from each reel member as usual was checked. Further, the tightening load strength when the adhesive film was pulled out in a state in which the rotation of each reel member was regulated was measured and the presence or absence of protrusion after the measurement was evaluated.
- Example 11 an elastic ring having a Shore A hardness of 40 ° and a thickness of 1 mm was used.
- Example 12 an elastic ring having a Shore A hardness of 40 ° and a thickness of 2 mm was used.
- Example 13 an elastic ring having a Shore A hardness of 40 ° and a thickness of 5 mm was used.
- Example 14 an elastic ring having a Shore A hardness of 80 ° and a thickness of 1 mm was used.
- Example 15 an elastic ring having a Shore A hardness of 80 ° and a thickness of 2 mm was used.
- Example 16 an elastic ring having a Shore A hardness of 80 ° and a thickness of 5 mm was used.
- any of Examples 11 to 16 has no practical problem.
- Examples 11 to 13 where the rubber hardness was 40 ° no protrusion was observed when the adhesive film was normally unwound, but the tightening load strength when the adhesive film was pulled out tended to decrease as the thickness increased. There is.
- Examples 14 to 16 where the rubber hardness was 80 ° when the adhesive film was unwound as usual in Example 14 having a thickness of 1 mm, a slight protrusion was observed. The tightening load strength when pulling out the film tends to increase.
- the protruding evaluation when unwinding the adhesive film while the winding core and the elastic ring rotate as usual, and the tightening load strength when pulling out the adhesive film in a state where the rotation of the winding core and the elastic ring is regulated May conflict with the rubber hardness and thickness of the elastic ring.
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Abstract
L'invention fournit un élément de touret qui tout en allongeant un film adhésif, empêche un blocage ou une protubérance du fait d'une concentration de pression d'enroulement, et permet de prévenir un décalage d'enroulement, ou similaire. L'élément de touret de l'invention est équipé : d'un noyau d'enroulement (3) ; d'un corps élastique (4) de forme annulaire qui est mis en prise avec la face périphérique externe du noyau d'enroulement (3), et sur lequel est enroulé le film adhésif (2) en forme de bande ; et de rebords de touret (5) agencés des deux côtés du noyau d'enroulement (3). Le corps élastique (4) présente une dureté Shore A supérieure à 30° et inférieure à 90°.
Priority Applications (2)
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CN201380017778.7A CN104185600B (zh) | 2012-04-06 | 2013-04-01 | 卷盘部件 |
KR1020147030862A KR102028518B1 (ko) | 2012-04-06 | 2013-04-01 | 릴 부재 |
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JP2012-087757 | 2012-04-06 | ||
JP2012087757A JP5982158B2 (ja) | 2012-04-06 | 2012-04-06 | リール部材 |
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PCT/JP2013/059948 WO2013151012A1 (fr) | 2012-04-06 | 2013-04-01 | Élément de touret |
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JP (1) | JP5982158B2 (fr) |
KR (1) | KR102028518B1 (fr) |
CN (1) | CN104185600B (fr) |
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WO (1) | WO2013151012A1 (fr) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103625987A (zh) * | 2013-12-02 | 2014-03-12 | 苏州市欧博锐自动化科技有限公司 | 一种带静电吸附板的卷膜滚筒 |
EP3459887B1 (fr) * | 2017-09-21 | 2023-03-15 | Bundesdruckerei GmbH | Bobine et procédé de fabrication d'une bobine |
Families Citing this family (1)
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CN107414943B (zh) * | 2017-08-03 | 2022-11-29 | 深圳市旭然电子有限公司 | 隔膜摆动控制机构的纠偏装置及其纠偏方法 |
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CN102161452B (zh) * | 2011-03-02 | 2013-04-10 | 梅县金象铜箔有限公司 | 电解铜箔生产用收卷轴及其使用方法 |
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- 2013-04-01 WO PCT/JP2013/059948 patent/WO2013151012A1/fr active Application Filing
- 2013-04-01 CN CN201380017778.7A patent/CN104185600B/zh active Active
- 2013-04-01 KR KR1020147030862A patent/KR102028518B1/ko active IP Right Grant
- 2013-04-08 TW TW102112454A patent/TWI567016B/zh active
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EP3459887B1 (fr) * | 2017-09-21 | 2023-03-15 | Bundesdruckerei GmbH | Bobine et procédé de fabrication d'une bobine |
Also Published As
Publication number | Publication date |
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CN104185600A (zh) | 2014-12-03 |
CN104185600B (zh) | 2017-07-28 |
TW201348109A (zh) | 2013-12-01 |
TWI567016B (zh) | 2017-01-21 |
JP5982158B2 (ja) | 2016-08-31 |
JP2013216435A (ja) | 2013-10-24 |
KR20140144265A (ko) | 2014-12-18 |
KR102028518B1 (ko) | 2019-10-04 |
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