WO2013100354A1 - 무방향성 전기강판의 절연 피막 조성물, 그 제조방법 및 절연 피막조성물이 적용된 무방향성 전기강판 - Google Patents
무방향성 전기강판의 절연 피막 조성물, 그 제조방법 및 절연 피막조성물이 적용된 무방향성 전기강판 Download PDFInfo
- Publication number
- WO2013100354A1 WO2013100354A1 PCT/KR2012/009662 KR2012009662W WO2013100354A1 WO 2013100354 A1 WO2013100354 A1 WO 2013100354A1 KR 2012009662 W KR2012009662 W KR 2012009662W WO 2013100354 A1 WO2013100354 A1 WO 2013100354A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- steel sheet
- electrical steel
- oriented electrical
- phosphate
- coating composition
- Prior art date
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/002—Inhomogeneous material in general
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B17/00—Insulators or insulating bodies characterised by their form
- H01B17/56—Insulating bodies
- H01B17/62—Insulating-layers or insulating-films on metal bodies
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/02—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of inorganic substances
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/40—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/325—Calcium, strontium or barium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/327—Aluminium phosphate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
- C08K2003/328—Phosphates of heavy metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/25—Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T428/259—Silicic material
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/31504—Composite [nonstructural laminate]
- Y10T428/31511—Of epoxy ether
- Y10T428/31529—Next to metal
Definitions
- Insulating coating composition of non-oriented electrical steel sheet, manufacturing method thereof and non-oriented electrical steel sheet to which insulating coating composition is applied is applied
- the present invention relates to a non-oriented electrical steel sheet, and more particularly to a non-oriented electrical steel sheet having an insulating coating composition excellent in insulating properties.
- Non-oriented electrical steel sheet is a steel plate with uniform magnetic properties in all directions on the rolled plate. It is widely used in motors, generator cores, electric motors and small transformers. Stress relief annealing (SRA) to improve magnetic properties after punching In case of loss of cost due to heat treatment than the effect of magnetic characteristics due to stress removal annealing, stress relief annealing is omitted. Doing.
- SRA Stress relief annealing
- Insulating film formation is a process of finishing production of products, and in addition to the electrical properties that usually suppress the generation of eddy currents, continuous punchability that suppresses abrasion of mold when forming a core by laminating a large number after punching into a predetermined shape. After removing the annealing process to recover the magnetic properties by removing the processing force of steel sheet and steel sheet, it requires the tacking and surface adhesion that does not adhere to the steel core steel plate. In addition to these basic characteristics, excellent coating workability of coating solution and solution stability that can be used for a long time after blending are required.
- the non-directional insulating film is mainly intended for the interlayer insulation between steel sheets to be laminated.
- the coating performance which is advantageous not only for insulation but also for workability, weldability, and corrosion resistance, has been evaluated as a major physical property. It demands excellent electrical steel.
- non-oriented electrical steel sheet is in the midst of advanced wave by developing high-efficiency motor in line with the government and low-carbon policy.
- non-oriented electrical steel sheet requires high functionality (high insulation, high heat resistance, high corrosion resistance). Will be done.
- the present invention has been made to solve the above problems, a mixed metal phosphate of aluminum phosphate and cobalt phosphate, sodium perborate (NaB0 3 ⁇ 43 ⁇ 40) as an oxidation promoter and Si3 ⁇ 4 in the basic composition of the emulsion resin of the epoxy-based Insulation coating solution prepared by mixing acid-type organic / inorganic composites in which the nanoparticles were modified by chemical reaction. Distribution is to provide non-oriented electrical steel sheet with excellent insulation characteristics before and after the SRA removal than conventional thin film products.
- the insulating film composition may comprise a "heunhap the metal phosphate 30 ⁇ 70wt3 ⁇ 4, 30 ⁇ 70% the organic-inorganic clothing laminated material (composite).
- the insulation coating composition may further include an oxidation promoter, and may include 0.1 to 1.0 wt% of the oxidation promoter.
- the size of the silica nanoparticles may be 5 ⁇ 50nm.
- the mixing bar ratio (aluminum phosphate / cobalt phosphate) of the aluminum phosphate and cobalt phosphate mixed in the mixed metal phosphate may be 0 ⁇ 05 ⁇ 0 ⁇ 2.
- the solid content of the organic-inorganic composite (composite) is 30 ⁇ 70wt3 ⁇ 4, the ratio of silica (Si0 2 ) / resin in the solid content may be 0.30.6.
- the oxidation promoter may be sodium perborate (NaB0 3 ⁇ 43 ⁇ 40).
- a method for preparing an insulating coating composition of an electrical non-oriented electrical steel sheet may include providing a mixed metal phosphate 30 to 70 3 ⁇ 4> composed of aluminum phosphate and cobalt phosphate, and replacing silica nanoparticles with a functional group of an epoxy resin.
- Providing 30 to 70% of an organic-inorganic composite, and said mixed metal phosphate provided Mixing the organic and inorganic composites followed by stirring.
- the mixture of the mixed metal phosphate and the inorganic inorganic compound (composi te) may further include 0.1 to 1.0% of an oxidation promoter.
- the aluminum phosphate is added 5 ⁇ 40g aluminum hydroxide (A1 (0H) 3 ) based on a water solution 100g consisting of 15wt water (3 ⁇ 40) and 85wt phosphoric acid (3 ⁇ 4P0 4 ) 6 ⁇ 10 at a temperature range of 80 ⁇ 90 ° C. It can be prepared by time reaction.
- the amount of 3 PO 4 ) may be less than 40%.
- the cobalt phosphate is added to the cobalt hydroxide (Co (0H) 2 ) 2 ⁇ 5g based on the aqueous solution consisting of 15w «water (3 ⁇ 40) and 85wt% phosphoric acid (H 3 P0 4 ) 80 ⁇ 90 ° C in
- It can be prepared by reacting for 6 to 10 hours.
- the mixing ratio of the aluminum phosphate and cobalt phosphate may be 0.05 to 0.2.
- the solid content of the organic inorganic composite (composi te) is 30 to 70%, the ratio of silica (Si0 2 ) / resin in the solid content may be 0.3 ⁇ 0.6 '. '
- the additive organic and inorganic composites may be modified by modifying silica (Si0 2 ) particles having a particle size of 10 to 50 nra in an acidic epoxy resin.
- silica (Si0 2 ) particles having a particle size of 10 to 50 nra in an acidic epoxy resin.
- an insulating coating layer is formed, and the insulating coating layer includes aluminum phosphate (A1 (3 ⁇ 4P0 4 ) X ⁇ 3 ) and cobalt phosphate.
- the insulating coating composition may include 30 to 70 wtt of the mixed metal phosphate and 30 to 70 wort of the organic and inorganic composites.
- the insulating coating composition may further include an oxidation promoter, and may include the oxidation promoter 0.1 to 1.0 ⁇ 3 ⁇ 4) in the insulating coating composition.
- the size of the silica nanoparticles in the non-oriented electrical steel sheet may be 5 ⁇ 50nm.
- the mixing ratio (aluminum phosphate / cobalt phosphate) of the aluminum phosphate and cobalt phosphate mixed in the mixed metal phosphate may be 0.05 to 0.2.
- Solid content of the organic-inorganic composite (composite) is 30 ⁇ 70wt%, the ratio of silica (Si0 2 ) / resin in the solid content may be 0.3-0.6.
- the oxidation promoter may be sodium perborate (NaB0 3 ⁇ 4H 2 0).
- the ratio of the inorganic material in the insulating coating layer may be 0.55 ⁇ 0.95.
- the distribution area of silica (Si0 2 ) distributed in the insulating coating layer may be 5-30%.
- the electrical steel sheet method, the coating layer formed of the coating layer by the insulating coating composition, the thickness of the coating layer is less than I.
- MII may have an insulation resistance property of 10.0 ⁇ or more.
- the thickness of the coating layer is 1.0zm or less Insulation resistance may be 10.0 Qasf or more.
- silica (Si0 2 ) particles are uniformly distributed in the coating layer.
- a silica (Si0 2 ) nanocomposite can be applied to the production of the coating composition for non-oriented electrical steel sheet to provide a non-oriented electrical steel sheet having an excellent insulating coating.
- the present, invention is to provide a non-oriented electrical steel sheet having excellent insulation properties before and after the high-to uniformly distribute nanoparticles in the insulating coating of the electrical steel sheet, the stress-relief annealing by controlling the size and dose of nanoparticles
- FIG. 1 is a process flowchart of a method of manufacturing an insulating coating of an non-oriented electrical steel sheet according to an embodiment of the present invention.
- FIG. 2 is a diagram illustrating single and multiple bonds of aluminum phosphate with phosphoric acid in the mixed metal phosphate constituting the insulating coating composition of the electrical steel sheet according to the present invention.
- Figure 4 is a view showing a cross-sectional view before the spring removal annealing coating layer of the electrical steel sheet dried after coating the insulating coating composition according to the present invention on the surface.
- FIG. 5 is a view showing a cross-sectional view of the coating layer after the stress relief annealing of the electrical steel sheet dried after coating the insulating coating composition according to the present invention on the surface.
- FIG. 6 is a view showing a cross section of a coating layer (insulation film) to which the insulation coating composition of the electrical steel sheet according to the present invention is applied.
- An insulating film composition of the non-oriented electrical steel sheet according to ⁇ a preferred embodiment of the invention aluminum phosphate (Al (H 3 P0 4; - 3) and cobalt phosphate (heunhap metal phosphate consisting of Co (H 3 P0 4) 3 ) And organic / inorganic composites composed of epoxy resins and silica (Si0 2 ) nanoparticles substituted with functional groups of the epoxy resins.
- composition of the insulating film is aluminum phosphate (AKHsP ⁇ 3 ) and cobalt phosphate
- the insulating film composition further comprises 0.1 to 1.0% of an oxidation promoter.
- the organic-inorganic composite comprises an epoxy resin and silica (Si02) nanoparticles substituted in the functional group of the epoxy resin, the size of the silica nanoparticles is characterized in that 5 ⁇ 50nm.
- the mixing ratio (aluminum phosphate / cobalt phosphate) of the aluminum phosphate and cobalt phosphate mixed in the mixed metal phosphate is 0.05-0.2.
- the organic solid content of the inorganic composite material (composite) is 30 ⁇ 70wt%, in the solid component
- the ratio of silica (Si0 2 ) / resin is characterized by being 0 ⁇ 3 to 0.6.
- the organic inorganic composite (composite) is characterized in that the silica (Si3 ⁇ 4) particles having a particle size of 10 ⁇ 50nm in the acidic epoxy resin.
- the oxidation promoter is characterized in that sodium perborate (NaB0 3 ⁇ 43 ⁇ 40).
- FIG. 1 is a process flowchart showing a manufacturing process of the insulating coating composition according to the present invention.
- a method for preparing an insulating coating composition of an electrical non-oriented electrical steel sheet comprising providing 30 to 70 wt% of a mixed metal phosphate composed of aluminum phosphate and cobalt phosphate. and a substitution in which u ⁇ inorganic composite material (composite) step, and a step of stirring the common haphu heunhap metal phosphate and the organic-inorganic composite material is provided that provides 30 to 70%.
- insulating coating composition according to the present invention can solve the problem of the insulating properties before and after the removal of annealing (SRA) of the steel sheet and the tacky problem caused by the introduction of phosphate.
- SRA annealing
- the metal phosphate used in the present invention may be prepared by mixing a high concentration of aluminum phosphate (AKHsPO n ⁇ 3 ) and cobalt phosphate ((Co (H 3 P0 4 ) 3 ).
- Aluminum Phosphate (AKHgP rf ⁇ 3 ) is added at 10-40g of aluminum hydroxide (A1 (0H) 3 ) based on 100g of 15wt% water (3 ⁇ 40) and 85wt% free phosphoric acid (3 ⁇ 4P0 4 ) at 80 ⁇ 90 ° C.
- Cobalt phosphate ((Co (H 3 P0 4 ) 3 ) is 15wt% water (0)
- It can be prepared by adding 2-5 g of cobalt hydroxide (Co (0H) 2 ) to 100 g of an aqueous solution of 85 wt% phosphoric acid (H 3 P0 4 ) and reacting at 80-90 ° C. for 6-10 hours.
- Co (0H) 2 cobalt hydroxide
- H 3 P0 4 85 wt% phosphoric acid
- the amount of aluminum hydroxide (AK0H) 3 ) was adjusted to 5-40 g based on 100 g of 15 wt 3 water (H 2 0) and 85 wt% phosphoric acid (H 3 P0 4 ). If the amount of aluminum hydroxide (AK0H) 3 ) is less than 10 g, surface hygroscopicity and powder development may be caused by high free phosphoric acid in the coating composition. If it is more than 40 g, metal phosphate may be recrystallized, resulting in inferior solution stability. ⁇
- cobalt phosphate (Co (H 3 P0 4 ) 3
- cobalt hydroxide (Co (0H) 2 2-5g) is injected into free phosphoric acid (cobalt hydroxide (Co (0H) 2 ) It exists in the form dissolved in cobalt hydroxide (Co (0H) divalent free phosphoric acid) without reacting with free phosphoric acid, so that the ratio of cobalt phosphate / aluminum phosphate is 0.050.2 in order to improve the coating workability of the insulating coating composition. It was set as.
- the ratio of cobalt phosphate / shallow aluminum phosphate is less than 05, the coating workability is inferior, and if the ratio of cobalt phosphate / aluminum phosphate is greater than 0.2, hygroscopicity and powder development may occur.
- the mixed metal phosphate may improve stickyness and precipitation of free phosphoric acid due to adhesion inferiority of the insulating film (coating layer) and the material (steel plate) and introduction of phosphate, and improve the cross-sectional characteristics before and after deflection annealing (SRA). It can be improved.
- an organic / inorganic composite in which nanoparticles are replaced by chemical reactions is applied to a resin which is not a conventional colloidal sol form for uniform dispersion of nanoparticles in an insulating coating composition.
- the average particle size of Si3 ⁇ 4 particles of the organic / inorganic composite modified by the chemical reaction is 5-50 nm, and the solid content of the Si0 2 nanoparticles in the organic / inorganic composite is 10-50%.
- the average size of Si3 ⁇ 4 particles substituted in the Si0 2 nanocomposite is 5 nm or less, the overall surface area of the particles increases, so that the insulating properties are improved by maximizing the barrier effect, but the film composition and the price are expensive. have.
- the average particle size is 50 nm or more, the total surface area of Si0 2 is reduced, resulting in inferior insulation properties.
- the solid content of Si3 ⁇ 4 nanoparticles substituted in the epoxy resin is injected at 10% or less, the improvement of the insulating properties by the Si0 2 nanoparticles is not significant, and when the solid content is 50% or more, it is obtained by the high inorganic ratio in the coating layer. Inferiority problems may occur.
- the ratio of the inorganic material composed of the mixed metal phosphate and silica (Si02) nanoparticles in the insulating coating composition except water is characterized in that 0.55 ⁇ 0.95. If the inorganic material is less than 0.55, the degree of improvement of the insulation properties is not large and there is a problem of poor adhesion after SRA. On the other hand, when the inorganic content exceeds 0.95, there is a problem of inferior corrosion resistance and punchability.
- the presence or absence of modifying the silica (Si0 2 ) nanoparticles in the epoxy resin by chemical reaction The composite particles are applied.
- the silica (Si0 2 ) average particle size of organic / inorganic composites modified by the above chemical reaction is 5 ⁇ 50nm and the solid content of nanoparticles in organic / inorganic composites is
- the molecular weight of the epoxy resin contained in the organic / inorganic composite material is 1,000 ⁇ 4,000, Tg (glass transition temperature) is 40 ⁇ 60 ° C, solid content is 20-40%, the viscosity is 50 ⁇ 200cp.
- the method for producing an insulating coating composition of the non-oriented electrical steel ⁇ is the mixed metal phosphate and oil. It is characterized by further mixing 0.1 to 1.0% of the oxidation promoter to the mixture of inorganic composites.
- the introduction of phosphate may cause problems with hygroscopicity or adhesion during annealing due to trace amounts of free phosphoric acid remaining in the insulation coating.
- the present invention focuses on the fact that sodium (Na) cation promotes reaction of free phosphoric acid remaining in the iron (Fe) -based oxide and coating solution.
- the oxidation promoter may include sodium-based materials including sodium carbonate .
- NaB0 cracks (NaB0 3 ⁇ 43 ⁇ 40) are easily dissociated in aqueous solution and do not adversely affect the solution stability when added to the insulating coating composition, and do not harm surface properties including corrosion resistance.
- FIG. 3 is a view showing that sodium perborate used as an oxidation promoter is dissociated in an aqueous solution to promote reaction of free phosphoric acid and iron oxide.
- the sodium (Na) cation dissociated in the aqueous solution serves as an oxidation promoter to induce a chemical bond with iron oxide at a high temperature (above 250 ° C.) of free phosphoric acid remaining in the coating layer. .
- the injection amount of sodium perborate (NaB0 3 ⁇ 43 ⁇ 40) is based on 100 g of the insulating coating composition. Below lg, hygroscopicity and powder development occurred on the surface despite high drying temperature. Above Og, corrosion resistance and weather resistance are inferior.
- the aluminum phosphate was added to 5 g of aluminum hydroxide (AK0H) 3 ) in 100 g of an aqueous solution consisting of 15 wt% water (3 ⁇ 40) and 85 wt% phosphoric acid (H 3 P0 4 ), and the temperature range was 80 to 90 ° C. It is characterized by the fact that it is prepared by reaction.
- the cobalt phosphate is added to the cobalt hydroxide (Co (0H) 2 ) 2-5g in 100g aqueous solution consisting of 15wt% water (3 ⁇ 40) and 85wt% phosphoric acid (P0 4 ) 6 ⁇ in the temperature range 80 ⁇ 90 ° C It is characterized in that the reaction is prepared for 10 hours.
- the mixing ratio of the aluminum phosphate and cobalt phosphate is characterized in that 0.05 ⁇ 0.2.
- the solid content of the organic-inorganic composite (composite) is 30 ⁇ 70wt%, characterized in that the ratio of silica (Si0 2 ) / resin in the solid content is 0.3-0.6.
- the organic / inorganic composite is characterized in that the silica (Si02) particles having a particle size of 10 to 50nm in the acidic epoxy resin.
- the non-oriented electrical steel sheet is characterized in that the ratio of the inorganic in the insulating coating layer is 0.55 ⁇ 0.95.
- the distribution area of silica (Si0 2 ) distributed in the insulating coating layer is characterized in that 5 ⁇ 30%.
- the coating solution composition containing the nanoparticles on the test specimen 0.5 ⁇ 1.0 coating thickness per side, 30 (750 ° C. heat treatment for 10-30 seconds in the basic range of non-oriented electrical steel sheet It can provide non-oriented electrical steel sheet with excellent corrosion resistance, weather resistance, heat resistance and adhesion before and after SRA as well as excellent insulation.
- a test specimen containing silicon (Si) in a weight ratio of 3.15 wt> and a sheet thickness of 0.35 mm high quality non-oriented electrical steel sheet (150 * 50 mm) was prepared, and the solution prepared as shown in Table 1 on the bar coater ( Each prepared disclosure using a bar coater and a roll coater After applying to a certain thickness (0.6 ⁇ 0.8 ⁇ ) on the piece and kept in a drying furnace of temperature range 300 ⁇ 750 ° C for 10-30 seconds and then cooled slowly in the air.
- Table 1 15wt% water (0) and 85wt% free phosphoric acid (H 3 P0 4) aqueous solution 100g hydroxide, aluminum (A1 (0H) 3) aluminum to the amount of remaining free acid Al after the solution stability and the reaction according to the injection amount of the
- the binding amounts of (A1) and phosphorus (P) are shown.
- an injection amount of aluminum hydroxide (AI (0H) 3) it is preferable to select an injection amount of aluminum hydroxide (AI (0H) 3) to 10 to 40 g.
- AI (0H) 3 aluminum hydroxide
- 30-4OT which minimizes the amount of free phosphoric acid after reaction and excellent solution stability is preferable.
- Table 2 shows cobalt phosphate ((Co (3 ⁇ 4P0 4 ) 3 ) and aluminum phosphate (A1 (H 3 ) substituted with 30 g of cobalt hydroxide (Co (0H) 2 and 30 g of aluminum hydroxide (AK0H) 3 ) based on 100 g of free phosphoric acid, respectively.
- P0 4 ) X 3 fixed the mixing ratio of cobalt phosphate / aluminum phosphate to 0.1
- the solution stability, coating workability, surface condition, corrosion resistance, and insulation properties of the mixed metal phosphate and silica (Si0 2 ) nanocomposites were shown.
- the particle size of the silica nanocomposite used here was 10 nm, and the solid content of silica was 30%. Solution stability and coating workability were very good in the ratio of composites and metal phosphates from 8: 2 to 4: 6. Surface state was also obtained when the ratio of composites and metal phosphates was 8: 2 to 3: 7.
- the corrosion resistance was very good when the ratio of composite to metal phosphate was 7: 3 to 4: 6.
- Insulation measurement method is to place one test specimen on the plate to make contact with the electrode contact and pressurize to 300psi (20.4atm) by pressurizing device. When the test pressure is reached, adjust the sliding resistor and read the ammeter reading under a voltage of 0.5V.
- the injection ratio of cobalt phosphate / aluminum phosphate does not affect the insulation properties, but the higher the cobalt phosphate / aluminum phosphate ratio, the better the improvement in waterability of the coating composition.
- Corrosion resistance is evaluated by 5 3 ⁇ 4>, 35 ° C, NaCl solution for 8 hours. It is very excellent when the rust area is below 2%, excellent when below 5%, and below 20%. If good, less than 3OT usually, 50% or more was marked as bad.
- the SRA pre-adhesiveness is shown by the minimum arc diameter without film peeling when the test specimen is bent 180 ° in contact with an arc of 5, 10, 20, 30-100 mmf.
- the minimum arc diameter was 5 ⁇ or less, which is very good, 10 ⁇ or less, which is excellent, and 20 ⁇ or less.
- the adhesiveness after SRA was heat treated at 80CTC for 2 hours in dry 100% nitrogen gas made a scratch on the surface with Cross Cut Tester, and the adhesion of the film peeling powder appeared when the adhesive tape of a certain size was attached and detached.
- the degree of contamination was quantified.
- the cross cut tester made 100 scratches in the horizontal and vertical direction at intervals of 1 ⁇ , and then stuck a certain size of adhesive tape.
- the presence and absence of tape contamination was quantified (3 ⁇ 4).
- 0 means that there is no film peeling from the surface of the film after SRA
- 100 means that the entire tape area is contaminated with film peeling.
- Film hardness was measured by the semi-automatic pencil hardness tester. The test was carried out by applying a pencil core defined in KSG 2603 (pencil) at about 45 degrees with respect to the drawings, and scraping the surface of the material with a load of about lkgf (9.8N) to measure the surface change of the material (ASTM D2197). ). When pencil hardness is 9H, very good, 8H is excellent, 6 ⁇ 7H is usually, 4 ⁇ 5H is very inferior.
- FIGS. 4 and 5 are photographs observed by scanning electron microscopy (SEM) of the cross-section of the coating layer before and after the stress relief annealing (SRA) of the electrical steel sheet by processing with a focused ion beam (RIB). As can be seen from the picture, it can be seen that there is no bubble or crack in the coating layer.
- FIG. 6 is a photograph of TEM and EPMA mapping after processing Si0 2 nanoparticles distribution in FIB on the cross section of the coating layer. As can be seen in Figure 6 Si0 2 nanoparticles in the coating layer is uniformly distributed on the surface, Si3 ⁇ 4 nanoparticles in the coating layer is bonded in the coating layer
- the silica nanoindenters distributed in the coating layer in FIG. 6 have an average particle size of lOnra, and those represented by light (white) color represent nanoparticles.
- the uniform distribution of these particles induces a series of electrostatic series micro-dielectric effects, improving the insulation resistance.
- the free volume is not affected by the increase in pressure at the interface, so porosity inside the coating layer as in the existing coating layer. If it is included, the phenomenon such as the reduction of free volume does not occur, so the insulation is not affected by free volume reduction.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Soft Magnetic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Manufacturing Of Steel Electrode Plates (AREA)
- Inorganic Insulating Materials (AREA)
- Organic Insulating Materials (AREA)
Abstract
Description
Claims
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201280065218.4A CN104025207B (zh) | 2011-12-28 | 2012-11-15 | 无取向电工钢板的绝缘覆膜组合物、其制造方法及施用绝缘覆膜组合物的无取向电工钢板 |
US14/369,248 US9455062B2 (en) | 2011-12-28 | 2012-11-15 | Insulation coating composition for non-oriented electrical sheet, method for manufacturing the same, and non-oriented electrical sheet to which insulation coating composition is applied |
JP2014549959A JP5877252B2 (ja) | 2011-12-28 | 2012-11-15 | 無方向性電磁鋼板の絶縁被膜組成物、その製造方法および絶縁被膜組成物が適用された無方向性電磁鋼板 |
EP12862247.9A EP2800103B1 (en) | 2011-12-28 | 2012-11-15 | Insulation coating composition for non-oriented electrical steel sheet, method for manufacturing same, and non-oriented electrical steel sheet upon which the insulation coating composition is applied |
PL12862247T PL2800103T3 (pl) | 2011-12-28 | 2012-11-15 | Kompozycja powłoki izolacyjnej do blachy cienkiej z niezorientowanej stali elektrotechnicznej, sposób jej wytwarzania oraz blacha cienka z niezorientowanej stali elektrotechnicznej, na którą nakłada się tę kompozycję powłoki izolacyjnej |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR10-2011-0145306 | 2011-12-28 | ||
KR1020110145306A KR101324260B1 (ko) | 2011-12-28 | 2011-12-28 | 무방향성 전기강판의 절연 피막 조성물, 그 제조방법 및 절연 피막조성물이 적용된 무방향성 전기강판 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2013100354A1 true WO2013100354A1 (ko) | 2013-07-04 |
Family
ID=48697770
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/KR2012/009662 WO2013100354A1 (ko) | 2011-12-28 | 2012-11-15 | 무방향성 전기강판의 절연 피막 조성물, 그 제조방법 및 절연 피막조성물이 적용된 무방향성 전기강판 |
Country Status (7)
Country | Link |
---|---|
US (1) | US9455062B2 (ko) |
EP (1) | EP2800103B1 (ko) |
JP (1) | JP5877252B2 (ko) |
KR (1) | KR101324260B1 (ko) |
CN (1) | CN104025207B (ko) |
PL (1) | PL2800103T3 (ko) |
WO (1) | WO2013100354A1 (ko) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105765106A (zh) * | 2013-11-27 | 2016-07-13 | Posco公司 | 无取向性电工钢板组合物、无取向性电工钢板产品及其制造方法 |
CN105980584A (zh) * | 2014-01-30 | 2016-09-28 | 蒂森克虏伯电工钢有限公司 | 含绝缘涂层的晶粒取向电工钢扁平材 |
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102177038B1 (ko) * | 2014-11-14 | 2020-11-10 | 주식회사 포스코 | 방향성 전기강판용 절연피막 조성물, 이를 이용하여 표면에 절연피막이 형성된 방향성 전기강판 및 이의 제조방법 |
EP3072936A1 (de) * | 2015-03-24 | 2016-09-28 | Voestalpine Stahl GmbH | Coil und Elektroband oder -blech |
US10526672B2 (en) | 2015-04-07 | 2020-01-07 | Jfe Steel Corporation | Electrical steel sheet with insulating coating |
KR101797129B1 (ko) | 2015-12-21 | 2017-11-13 | 주식회사 포스코 | 무방향성 전기강판 접착 코팅 조성물, 무방향성 전기강판 제품, 및 이의 제조 방법 |
KR101796234B1 (ko) * | 2015-12-22 | 2017-11-09 | 주식회사 포스코 | 방향성 전기강판용 절연피막 조성물, 이를 이용한 방향성 전기강판의 절연피막 형성방법, 및 방향성 전기강판 |
KR102444224B1 (ko) * | 2015-12-23 | 2022-09-16 | 주식회사 포스코 | 무방향성 전기강판 접착 코팅 조성물, 무방향성 전기강판 제품, 및 이의 제조 방법 |
CN109563626B (zh) * | 2016-09-13 | 2021-04-13 | 杰富意钢铁株式会社 | 带无铬绝缘张力被膜的取向性电磁钢板及其制造方法 |
WO2018117670A2 (ko) * | 2016-12-23 | 2018-06-28 | 주식회사 포스코 | 전기강판 접착 코팅 조성물, 전기강판 제품, 및 이의 제조 방법 |
KR101904306B1 (ko) * | 2016-12-23 | 2018-10-04 | 주식회사 포스코 | 무방향성 전기강판 접착 코팅 조성물 및 무방향성 전기강판 제품의 제조 방법 |
KR102112171B1 (ko) * | 2017-12-26 | 2020-05-18 | 주식회사 포스코 | 전기강판 접착 코팅 조성물, 전기강판 제품, 및 이의 제조 방법 |
KR102114810B1 (ko) * | 2017-12-26 | 2020-05-25 | 주식회사 포스코 | 전기강판 접착 코팅 조성물, 전기강판 적층체 및 전기강판 제품의 제조 방법 |
CN112204170B (zh) * | 2018-05-30 | 2022-04-19 | 杰富意钢铁株式会社 | 带有绝缘被膜的电磁钢板及其制造方法 |
KR102176342B1 (ko) * | 2018-09-28 | 2020-11-09 | 주식회사 포스코 | 전기강판 제품의 제조 방법 |
US20220106689A1 (en) | 2019-02-14 | 2022-04-07 | Jfe Steel Corporation | Electrical steel sheet having insulating coating |
JP7156579B2 (ja) * | 2020-06-17 | 2022-10-19 | 日本製鉄株式会社 | 電磁鋼板、積層コア、及び積層コア製造方法 |
KR20230092608A (ko) * | 2021-12-17 | 2023-06-26 | 주식회사 포스코 | 전기강판용 절연 피막 조성물, 전기강판, 및 이의 제조 방법 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100762466B1 (ko) * | 2006-08-02 | 2007-10-04 | 주식회사 포스코 | 크롬이 배제된 응력제거소둔 전후 피막밀착성 및피막강도가 우수한 절연피막 형성용 피복조성물 및 이를이용한 무방향성 전기강판의 절연피막 형성방법 |
JP2009545674A (ja) * | 2006-08-02 | 2009-12-24 | ポスコ | 耐食性、皮膜密着性および皮膜強度に優れた絶縁皮膜形成用クロムを含まない被覆液、並びにこれを用いて無方向性電気鋼板に絶縁皮膜を形成する方法 |
KR20110072848A (ko) * | 2009-12-23 | 2011-06-29 | 주식회사 포스코 | 절연성이 우수한 절연피막 형성용 피복조성물, 이를 이용한 무방향성 전기강판 및 무방향성 전기강판의 절연피막 형성방법 |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP3370235B2 (ja) | 1996-07-30 | 2003-01-27 | 川崎製鉄株式会社 | 耐食性に優れた歪取り焼鈍が可能なクロム化合物を含まない絶縁被膜を電磁鋼板の表面に形成する方法 |
JP2000169973A (ja) | 1998-12-04 | 2000-06-20 | Nippon Steel Corp | クロムを含まない方向性電磁鋼板用表面処理剤及びそれを用いた方向性電磁鋼板の製造方法 |
JP4264362B2 (ja) * | 2004-01-15 | 2009-05-13 | 新日本製鐵株式会社 | クロムを含まない方向性電磁鋼板用絶縁皮膜剤及びクロムを含まない絶縁皮膜を有する方向性電磁鋼板 |
KR100625116B1 (ko) * | 2004-09-23 | 2006-09-20 | 주식회사 대하맨텍 | 올리고머/실리카 나노복합체를 포함하여 이루어지는난반사 코팅제 |
KR100762465B1 (ko) | 2006-08-02 | 2007-10-04 | 주식회사 포스코 | 크롬이 배제된 내식성과 응력제거소둔후 피막밀착성이우수한 절연피막 형성용 피복조성물 및 이를 이용한무방향성 전기강판의 절연피막 형성방법 |
CN103923510A (zh) * | 2006-08-11 | 2014-07-16 | 鲍吉肥料公司 | 磷酸铝或多聚磷酸铝颗粒的制备 |
TWI457433B (zh) * | 2008-01-30 | 2014-10-21 | Chemetall Gmbh | 將金屬表面施以一磷酸鹽層然後施以一潤滑劑層的方法 |
KR100991012B1 (ko) * | 2008-07-14 | 2010-10-29 | 한국화학연구원 | 저온영역에서 탄소섬유 제조가 가능한코발트/알루미늄포스페이트 촉매 및 이의 제조방법 |
KR100966819B1 (ko) | 2008-08-08 | 2010-06-29 | 주식회사 포스코 | 방향성 전기강판용 비크롬계 코팅제와 그 제조방법 및 이를이용한 전기강판과 그 제조방법 |
CN102459696B (zh) * | 2009-06-17 | 2013-10-16 | 新日铁住金株式会社 | 具有绝缘覆盖膜的电磁钢板及其制造方法 |
JP5494240B2 (ja) * | 2010-05-28 | 2014-05-14 | Jfeスチール株式会社 | 無機質絶縁被膜付き電磁鋼板 |
-
2011
- 2011-12-28 KR KR1020110145306A patent/KR101324260B1/ko active IP Right Grant
-
2012
- 2012-11-15 CN CN201280065218.4A patent/CN104025207B/zh active Active
- 2012-11-15 US US14/369,248 patent/US9455062B2/en active Active
- 2012-11-15 WO PCT/KR2012/009662 patent/WO2013100354A1/ko active Application Filing
- 2012-11-15 PL PL12862247T patent/PL2800103T3/pl unknown
- 2012-11-15 JP JP2014549959A patent/JP5877252B2/ja active Active
- 2012-11-15 EP EP12862247.9A patent/EP2800103B1/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR100762466B1 (ko) * | 2006-08-02 | 2007-10-04 | 주식회사 포스코 | 크롬이 배제된 응력제거소둔 전후 피막밀착성 및피막강도가 우수한 절연피막 형성용 피복조성물 및 이를이용한 무방향성 전기강판의 절연피막 형성방법 |
JP2009545674A (ja) * | 2006-08-02 | 2009-12-24 | ポスコ | 耐食性、皮膜密着性および皮膜強度に優れた絶縁皮膜形成用クロムを含まない被覆液、並びにこれを用いて無方向性電気鋼板に絶縁皮膜を形成する方法 |
KR20110072848A (ko) * | 2009-12-23 | 2011-06-29 | 주식회사 포스코 | 절연성이 우수한 절연피막 형성용 피복조성물, 이를 이용한 무방향성 전기강판 및 무방향성 전기강판의 절연피막 형성방법 |
Non-Patent Citations (1)
Title |
---|
See also references of EP2800103A4 * |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105765106A (zh) * | 2013-11-27 | 2016-07-13 | Posco公司 | 无取向性电工钢板组合物、无取向性电工钢板产品及其制造方法 |
JP2016540901A (ja) * | 2013-11-27 | 2016-12-28 | ポスコPosco | 無方向性電磁鋼板組成物、無方向性電磁鋼板製品の製造方法および無方向性電磁鋼板製品 |
US20160375658A1 (en) * | 2013-11-27 | 2016-12-29 | Posco | Composition for non-oriented electrical steel sheet, method of manufacturing non-oriented electrical steel sheet product, and non-oriented electrical steel sheet product |
EP3075882A4 (en) * | 2013-11-27 | 2017-06-28 | Posco | Composition for non-oriented electrical steel sheet, method of manufacturing non-oriented electrical steel sheet product, and non-oriented electrical steel sheet product |
CN105765106B (zh) * | 2013-11-27 | 2018-05-15 | Posco公司 | 无取向性电工钢板组合物、无取向性电工钢板产品及其制造方法 |
US10556404B2 (en) | 2013-11-27 | 2020-02-11 | Posco | Composition for non-oriented electrical steel sheet, method of manufacturing non-oriented electrical steel sheet product, and non-oriented electrical steel sheet product |
CN105980584A (zh) * | 2014-01-30 | 2016-09-28 | 蒂森克虏伯电工钢有限公司 | 含绝缘涂层的晶粒取向电工钢扁平材 |
Also Published As
Publication number | Publication date |
---|---|
KR101324260B1 (ko) | 2013-11-01 |
US20150017428A1 (en) | 2015-01-15 |
JP5877252B2 (ja) | 2016-03-02 |
CN104025207B (zh) | 2016-09-21 |
US9455062B2 (en) | 2016-09-27 |
EP2800103A1 (en) | 2014-11-05 |
EP2800103B1 (en) | 2022-02-16 |
EP2800103A4 (en) | 2015-07-29 |
KR20130076642A (ko) | 2013-07-08 |
JP2015509994A (ja) | 2015-04-02 |
PL2800103T3 (pl) | 2022-05-09 |
CN104025207A (zh) | 2014-09-03 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2013100354A1 (ko) | 무방향성 전기강판의 절연 피막 조성물, 그 제조방법 및 절연 피막조성물이 적용된 무방향성 전기강판 | |
JP5236077B2 (ja) | 方向性電気鋼板用非クロム系コーティング剤およびこれを用いた電気鋼板とその製造方法 | |
KR101264231B1 (ko) | 절연성이 우수한 절연피막 형성용 피복조성물, 이를 이용한 무방향성 전기강판 및 무방향성 전기강판의 절연피막 형성방법 | |
EP3395923B1 (en) | Adhesive coating composition for non-oriented electrical steel sheet, non-oriented electrical steel sheet product, and manufacturing method therefor | |
JP2009545674A (ja) | 耐食性、皮膜密着性および皮膜強度に優れた絶縁皮膜形成用クロムを含まない被覆液、並びにこれを用いて無方向性電気鋼板に絶縁皮膜を形成する方法 | |
KR20180074438A (ko) | 무방향성 전기강판 접착 코팅 조성물 및 무방향성 전기강판 제품의 제조 방법 | |
KR101448598B1 (ko) | 절연피막 조성물, 이를 이용한 무방향성 전기강판의 절연피막 형성방법 및 무방향성 전기강판 | |
JP5232246B2 (ja) | 無方向性電気鋼板用のコーティング溶液,これを用いた無方向性電気鋼板のコーティング方法及び無方向性電気鋼板のコーティング層 | |
KR101286248B1 (ko) | 방향성 전기강판의 절연피막 조성물 및 그 제조방법, 절연피막 조성물을 이용한 방향성 전기강판의 절연피막 형성방법 및 이에 의해 절연피막이 형성된 방향성 전기강판 | |
KR20140060717A (ko) | 절연피막 조성물, 이를 이용한 무방향성 전기강판의 절연피막 형성방법 및 무방향성 전기강판 | |
KR101481127B1 (ko) | 절연피막 조성물, 이를 이용한 무방향성 전기강판의 절연피막 형성방법 및 무방향성 전기강판 | |
KR100817157B1 (ko) | 용액 안정성이 우수한 무방향성 전기강판용 Cr-free코팅제 제조방법 | |
KR101110255B1 (ko) | 피막특성이 우수한 전기강판 절연피막 형성용 피복조성물과 이를 이용한 방향성 전기강판의 절연피막 형성방법 및 피복조성물로 절연피막이 형성된 방향성 전기강판 | |
KR101419473B1 (ko) | 절연피막 조성물, 이를 이용한 무방향성 전기강판의 절연피막 형성방법 및 무방향성 전기강판 | |
KR101448599B1 (ko) | 절연피막 조성물, 이를 이용한 무방향성 전기강판의 절연피막 형성방법 및 무방향성 전기강판 | |
KR101448600B1 (ko) | 절연피막 조성물, 이를 이용한 무방향성 전기강판의 절연피막 형성방법 및 무방향성 전기강판 | |
KR101308731B1 (ko) | 장력부여가 우수하며 타발성 및 가공성이 우수한 비크롬계 방향성 전기강판용 장력코팅제 조성물 및 이를 이용한 절연피막 형성방법, 그 방법에 의해 형성된 절연피막을 갖는 방향성 전기강판 | |
KR102371375B1 (ko) | 전기강판 절연 피막 조성물, 전기강판, 및 이의 제조 방법 | |
KR100779575B1 (ko) | 크롬이 배제된 무방향성 칼라강판용 절연피막 조성물 및 그제조방법 | |
KR100762466B1 (ko) | 크롬이 배제된 응력제거소둔 전후 피막밀착성 및피막강도가 우수한 절연피막 형성용 피복조성물 및 이를이용한 무방향성 전기강판의 절연피막 형성방법 | |
KR101507941B1 (ko) | 전기강판의 절연피막 조성물, 이를 이용한 절연피막 형성방법 및 이에 의해 제조되는 방향성 전기강판 | |
KR20230095279A (ko) | 전기강판 절연 피막 조성물, 전기강판, 및 이의 제조 방법 | |
KR20230094868A (ko) | 전기강판 절연 피막 조성물, 전기강판, 및 이의 제조 방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 12862247 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 14369248 Country of ref document: US |
|
ENP | Entry into the national phase |
Ref document number: 2014549959 Country of ref document: JP Kind code of ref document: A |
|
NENP | Non-entry into the national phase |
Ref country code: DE |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2012862247 Country of ref document: EP |