WO2012133152A1 - Four de rétraction et procédé de fabrication d'un film étiré - Google Patents

Four de rétraction et procédé de fabrication d'un film étiré Download PDF

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Publication number
WO2012133152A1
WO2012133152A1 PCT/JP2012/057462 JP2012057462W WO2012133152A1 WO 2012133152 A1 WO2012133152 A1 WO 2012133152A1 JP 2012057462 W JP2012057462 W JP 2012057462W WO 2012133152 A1 WO2012133152 A1 WO 2012133152A1
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WO
WIPO (PCT)
Prior art keywords
film
nozzle
air
air blowing
tenter oven
Prior art date
Application number
PCT/JP2012/057462
Other languages
English (en)
Japanese (ja)
Inventor
道錫 李
拓也 川越
井上　博之
Original Assignee
東レ株式会社
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 東レ株式会社 filed Critical 東レ株式会社
Priority to JP2012523141A priority Critical patent/JP5949548B2/ja
Priority to CN201280015361.2A priority patent/CN103442879B/zh
Priority to EP12764064.7A priority patent/EP2692508B1/fr
Priority to KR1020137027161A priority patent/KR101879897B1/ko
Priority to US14/007,780 priority patent/US9522488B2/en
Publication of WO2012133152A1 publication Critical patent/WO2012133152A1/fr

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C35/00—Heating, cooling or curing, e.g. crosslinking or vulcanising; Apparatus therefor
    • B29C35/02—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould
    • B29C35/04—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using liquids, gas or steam
    • B29C35/045—Heating or curing, e.g. crosslinking or vulcanizing during moulding, e.g. in a mould using liquids, gas or steam using gas or flames
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/04—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique
    • B29C55/08—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets uniaxial, e.g. oblique transverse to the direction of feed
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/20—Edge clamps
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B13/00—Machines and apparatus for drying fabrics, fibres, yarns, or other materials in long lengths, with progressive movement
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F26—DRYING
    • F26B—DRYING SOLID MATERIALS OR OBJECTS BY REMOVING LIQUID THEREFROM
    • F26B21/00—Arrangements or duct systems, e.g. in combination with pallet boxes, for supplying and controlling air or gases for drying solid materials or objects
    • F26B21/004—Nozzle assemblies; Air knives; Air distributors; Blow boxes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
    • B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
    • B29C55/14—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial successively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C55/00—Shaping by stretching, e.g. drawing through a die; Apparatus therefor
    • B29C55/02—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets
    • B29C55/10—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial
    • B29C55/12—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial
    • B29C55/16—Shaping by stretching, e.g. drawing through a die; Apparatus therefor of plates or sheets multiaxial biaxial simultaneously

Definitions

  • the present invention relates to a tenter oven suitable for production of a stretched film made of a thermoplastic resin, and a method for producing a stretched film made of a thermoplastic resin using the tenter oven.
  • a method for producing a stretched film made of a thermoplastic resin after obtaining a uniaxially stretched film by stretching an unstretched film made of a thermoplastic resin in its longitudinal direction, the obtained uniaxially stretched film was introduced into a tenter oven.
  • a sequential biaxial stretching method that stretches in the width direction or an unstretched film made of a thermoplastic resin is introduced into a tenter oven, in which the lengthwise direction and the width direction are simultaneously stretched simultaneously.
  • a biaxial stretching method is known.
  • a stretched film made of a thermoplastic resin is widely used for various industrial material applications including packaging applications. Above all, sequential biaxially stretched films of polyester, polyolefin and polyamide resin are widely used for applications that cannot be used with unstretched films due to their excellent mechanical properties, thermal properties, electrical properties, etc. It has increased.
  • Patent Document 1 a method of reducing the temperature unevenness in the width direction of the film (Patent Document 1) and temperature by increasing the air volume of the blowing air at the end of the film compared to the center of the film
  • Patent Document 2 or Patent Document 3 a method of controlling the heat exchanger based on the temperature detected by the sensor, uniforms the heating in the width direction of the film, and reduces the temperature unevenness in the width direction of the film. It has been.
  • Patent Document 5 There is a method of suppressing sheet flutter by flowing parallel air to the sheet surface from a nozzle having a flat part and an inclined part provided subsequently. Thereby, it is known that the gap between the sheet and the nozzle can be narrowed, and there is an effect of suppressing the heat entering and exiting the entrance and exit of the heat treatment chamber (Patent Document 5).
  • the pattern of the air outlets is a number of round holes, and the number of round holes is arranged at intervals Py in each of the first row and the second row, and the arrangement of the air ejection holes in the first row and the second row Are arranged in a staggered arrangement, the first row and the second row are located at a distance Px, and the air ejection surface and the seat running surface are opposed to each other with a distance L.
  • the air ejection hole has a diameter D and satisfies the formula (1): 6 ⁇ (L / D) / (Px / Py) ⁇ 9 and the formula (2): 4 ⁇ L / D ⁇ 8 It is known that the unevenness of the heat transfer efficiency in the width direction of the film is made uniform by adopting this pattern (Patent Document 6).
  • Patent Documents 1 to 3 are effective when the circulation of air is completed in each room.
  • a certain room has a set temperature different from the set temperature of the room.
  • a temperature equalizing effect cannot be obtained with respect to temperature unevenness caused by part of the circulating air in the adjacent chamber flowing, or temperature unevenness caused by the outside air flowing into the tenter oven.
  • Patent Document 5 The invention described in Patent Document 5 is mainly intended to make the film run stably, and is not intended to have a function of heating, cooling, or drying the film. That is, in the tenter oven, it is used as an auxiliary means in order to sufficiently secure the capability of the film heating nozzle (or cooling and drying nozzle). The effect of reduction is small.
  • Patent Document 6 has the effect of making the blown air less susceptible to the influence of the MD flow flowing in the tenter oven, but the effect of fundamentally blocking the MD flow, as in the invention described in Patent Document 4. There is no. Therefore, there is a concern that the physical property unevenness in the width direction of the film occurs due to the MD flow, and there is a concern that the energy consumption of the tenter oven increases.
  • An object of the present invention is to suppress the MD flow generated in the tenter oven, thereby reducing the temperature unevenness of the film, and producing a stretched film made of a thermoplastic resin having uniform film width characteristics and thickness.
  • An object of the present invention is to provide a tenter oven that enables the reduction of energy consumption required to heat a film to a predetermined temperature and maintain the temperature.
  • the inventor has focused on the distance from the air blowing surface of the air blowing nozzle to the film passing surface and found a configuration of a tenter oven that can suppress the occurrence of MD flow.
  • the tenter oven of the present invention is as follows.
  • One end of the traveling film made of a thermoplastic resin film and the other end of the traveling film have an outlet, and the upper and lower surfaces of the traveling film formed between the inlet and the outlet are opposed to each other.
  • a plurality of air blowing nozzles for blowing warmed air to the running film, and an air blowing opening for blowing the heated air to an air blowing surface facing the film passage surface of the air blowing nozzle A tenter oven having a stretching zone extending between the inlet and the outlet in the width direction of the running film, wherein at least one of the plurality of air blowing nozzles is the air blowing surface.
  • the air blowing opening provided in is formed by a slit extending in the width direction of the traveling film,
  • the distance L between the air blowing surface and the film passage surface and the slit width B of the slit in the running direction of the running film satisfy the relationship of the formula: (L / B) ⁇ 10, and the distance A tenter oven that is a proximity nozzle with L of 150 mm or less.
  • At least one of the plurality of proximity nozzles is provided to face the upper surface of the film passage surface, and at least one other faces the lower surface of the film passage surface. It is preferable to be provided.
  • an air spray angle formed by the film passage surface in the flow direction of air blown from the slit of the proximity nozzle toward the film passage surface is 85 to 95 degrees.
  • a preheating zone for preheating the traveling film is provided on the entrance side of the stretching zone, and the proximity nozzle is provided in at least a part of the preheating zone.
  • At least one of the proximity nozzles includes a casing, and the casing includes the heated air flow path supplied from a supply source therein, and one surface thereof.
  • a movable casing that is movable in the width direction of the traveling film with respect to the fixed casing at both ends of the fixed casing and the fixed casing. It is preferable to have.
  • left and right clip moving devices for moving a number of clips holding both ends of the traveling film from the inlet toward the outlet, and the left and right clip moving devices are guided in the tenter oven.
  • the left and right rails provided to be changeable in the width direction of the traveling film and the left and right rail covers that cover the left and right rails, and the respective movable housings are closer to each other.
  • the cover is coupled to the left and right rail covers via a coupling member, and the movable casing moves in the width direction of the traveling film according to a change in the distance between the left and right rails. It is preferable to be movable.
  • the rail cover is a general term for members that are installed so as to surround the rail and move in the width direction integrally with the rail.
  • At least one of the proximity nozzles has a protective cover for preventing the traveling film provided on one side or both sides of the slit from contacting the tip of the proximity nozzle.
  • the method for producing the stretched film of the present invention is as follows.
  • An unstretched film or a uniaxially stretched film made of a thermoplastic resin is introduced into the tenter oven from the entrance of any of the tenter ovens of the present invention as a running film, and the slits are formed in the tenter oven.
  • a method for producing a stretched film wherein the heated film is heated by the warmed air blown from a nozzle, and the travel film is stretched in the width direction during the heat treatment, and then is led out from the outlet.
  • thermoplastic resin that forms the thermoplastic resin film used in the tenter oven of the present invention examples include the following.
  • polyolefin resins such as polyethylene, polypropylene and polymethylpentene
  • polyamide resins such as nylon 6 and nylon 66
  • poly-1,4-cyclohexylenedimethylene terephthalate and copolymerization components include diol components such as diethylene glycol, neopentyl glycol, polyalkylene glycol, adipic acid, sebacic acid, phthalic acid, isophthalic acid, 2,6 -Polyester resins such as polyester copolymerized with dicarboxylic acid components such as naphthalene dicarboxylic acid, other polyacetal resins, polyphenylenes There is Fido resin.
  • a film made of polyolefin resin, polyamide resin, or polyester resin is preferable.
  • a film made of polyethylene-2,6-naphthalate resin or polyethylene terephthalate resin is preferable.
  • a film made of polyethylene terephthalate resin is inexpensive and can be used in a wide variety of applications, and the application effect of the present invention can be improved. high.
  • These thermoplastic resins may be homo-resins, copolymerized or blended.
  • the thermoplastic resin film may contain various known additives such as an antioxidant, an antistatic agent, a crystal nucleating agent, inorganic particles, a thinning agent, a thermal stabilizer, and a lubricant together with the above-described thermoplastic resin. good.
  • the tenter oven of the present invention since the uniformity of the temperature of the blowing air can be secured by suppressing the occurrence of MD flow in the tenter oven, the temperature unevenness in the width direction of the film generated in the tenter oven is reduced. This makes it possible to produce stretched films made of a thermoplastic resin with uniform film properties and thickness, improving product quality and reducing product tearing in the tenter oven. Is possible.
  • the temperature of the circulating air can be maintained at a temperature close to the set temperature of the chamber, the amount of steam consumed by the heat exchanger necessary for reheating the air can be reduced. Furthermore, since the heating efficiency of the air blowing nozzle is improved, the air volume of the heat exchanger can be reduced and the power consumption can also be reduced.
  • FIG. 1 is a schematic vertical cross-sectional view of one embodiment of the tenter oven of the present invention.
  • FIG. 2 is a schematic plan view in the direction of arrows A1-A1 shown in FIG.
  • FIG. 3a is a longitudinal sectional schematic view in the longitudinal direction of the proximity nozzle illustrating the flow direction of air blown from the slit in the air blowing surface of the proximity nozzle used as the air blowing nozzle of the tenter oven of the present invention toward the film passage surface. It is.
  • FIG. 3b is a schematic cross-sectional view of the proximity nozzle in the direction of arrows A2-A2 shown in FIG.
  • FIG. 3a for explaining the air blowing angle formed from the slit of the proximity nozzle to the film passage surface in the flow direction of air blown toward the film passage surface.
  • FIG. FIG. 4a is a schematic cross-sectional view of an example of a proximity nozzle used as an air blowing nozzle of the tenter oven of the present invention.
  • FIG. 4b is an enlarged schematic cross-sectional view of the air blowing opening T of the proximity nozzle shown in FIG. 4a.
  • FIG. 5 is a schematic cross-sectional view in the direction of arrows B1-B1 shown in FIG. 6 is a schematic cross-sectional view in the direction of arrows B1-B1 shown in FIG. 1 when a proximity nozzle including a fixed housing and a movable housing is used.
  • FIG. 7 is a schematic vertical cross-sectional view of one embodiment of the tenter oven of the present invention having a plurality of zones with different film processing conditions inside.
  • FIG. 8 is a schematic side view of a model test machine that models a chamber constituting the tenter oven of the present invention.
  • FIG. 9 is a schematic side view for explaining a method of evaluating the magnitude of the MD flow by generating the accompanying air flow in a simulated manner with the model test machine of FIG.
  • FIG. 10 is a schematic front schematic view in the direction of arrow C1-C1 shown in FIG. 9 for explaining the wind velocity measurement location of the MD flow.
  • FIG. 11a shows an air spray nozzle in the direction of arrows D1-D1 shown in FIG.
  • FIG. 11b is an enlarged schematic plan view of the connecting portion between the end of the proximity nozzle shown in FIG. 11a and the rail cover.
  • FIG. 12 is a plan view of a portion between one end and a substantially central portion of an example of a proximity nozzle that can change the length of the nozzle in the width direction of the running film used as the air blowing nozzle of the tenter oven of the present invention.
  • FIG. FIG. 12 is a plan view of a portion between one end and a substantially central portion of an example of a proximity nozzle that can change the length of the nozzle in the width direction of the running film used as the air blowing nozzle of the tenter oven of the present invention.
  • FIG. 13 shows a perforated plate type spray nozzle used as an air spray nozzle of a conventional tenter oven, and one end of the perforated plate type spray nozzle when the length of the nozzle in the width direction of the running film is variable. It is a plane schematic diagram of the part between a part and a substantially central part.
  • FIG. 14a shows the proximity of the nozzle to the tip of the proximity nozzle in the vicinity of the air blowing opening (slit) of the proximity nozzle that can change the length of the nozzle in the width direction of the running film used as the air blowing nozzle of the tenter oven of the present invention.
  • FIG. 1 is a schematic vertical cross-sectional view of one embodiment of the tenter oven of the present invention.
  • FIG. 2 is a schematic plan view in the direction of arrows A1-A1 shown in FIG.
  • a tenter oven TO1 has a running film inlet 6 made of a thermoplastic resin film at one end and a running film outlet 7 at the other end.
  • the running film film is formed from the inlet 6 to the outlet 7. It has a passage surface 5.
  • the air blowing surface 8 of each air blowing nozzle NUn is opposed to the film passing surface 5 at a distance from the film passing surface 5.
  • the air blowing surface 8 of each air blowing nozzle NLn faces the film passing surface 5 at a distance from the film passing surface 5.
  • the air blowing nozzle is formed of a casing, and has a flow path of heated air supplied from a supply source inside thereof, and on one side thereof, the longitudinal direction of the casing (the width direction of the running film) ) Along the air blowing surface 8.
  • the air blowing surface 8 of the air blowing nozzles NUn and NLn is provided with an air blowing opening 8a for blowing out the heated air.
  • Each air blowing opening 8a is formed by a slit.
  • an air blowing nozzle having an air blowing opening formed by the slit 8a is referred to as a slit nozzle.
  • the interior of the tenter oven TO1 is preferably divided into a plurality of zones having different film processing purposes from the film inlet 6 to the film outlet 7, that is, in the film traveling direction.
  • Zones with different film processing purposes in a tenter oven are zones that correspond to the film processing steps for film preheating, stretching, heat treatment, or cooling. Each process is generally a preheating zone or stretching. It is called a zone, a heat treatment zone, a cooling zone, or the like. When the tenter oven is divided into a plurality of zones, it is preferable that the zone located closest to the inlet 6 is a preheating zone.
  • Each zone may be formed in one processing chamber without a partition separating each zone, but in general, from the entrance 6 of the running film to the exit 7 of the running film, that is, in the running direction of the film, It is divided into a plurality of processing chambers, and is configured so that the temperature setting can be changed for each processing chamber.
  • the processing chamber in the tenter oven is a wall other than the opening provided for passing the traveling film and the opening provided for supplying and discharging the heated air provided as necessary. It is a space partitioned by.
  • Slit nozzles NUn and NLn are nozzles for blowing hot air (heated air) to heat the film.
  • the film is heated or cooled by the heated air blown out from the slit nozzles NUn and NLn while traveling in the processing chamber from the inlet 6 toward the outlet 7.
  • the temperature of the film is higher than the temperature of the heated air, the film is cooled by the heated air.
  • the air suction part 2 is provided around the slit nozzles NUn and NLn.
  • the low-temperature air that bounces off the film is sucked by the air suction section 2 and reaches the heat exchanger 3 provided in the tenter oven TO1.
  • the heat exchanger 3 In the heat exchanger 3, the air is reheated to the set temperature, and the circulation fan 4 Is blown out from the slit nozzles NUn and NLn.
  • the flow of air from the slit nozzles NUn and NLn includes a region where the initial wind speed is maintained, that is, the potential core, a region where the surrounding static air is entrained away from the potential core, and the flow velocity decreases, that is, a turbulent region.
  • the air coming out of the air blowing opening (slit) 8a of the air blowing surface 8 of the slit nozzles NUn and NLn approaches the film passage surface 5, the air velocity in the potential core becomes weaker and a turbulent flow region develops.
  • the heating efficiency of the film by the slit nozzles NUn and NLn is likely to decrease.
  • the air blowing surface 8 is a surface from which air blows out at the slit nozzles NUn and NLn, and means the front end surface of the slit nozzles NUn and NLn.
  • the film passage surface 5 means a surface through which the traveling film surface passes.
  • Increasing the wind speed means that if the size of the air blowing opening (slit) 8a is constant, it means an increase in the air volume of the blown air, and the accompanying airflow flowing on the film surface increases, and MD flow tends to occur. Furthermore, the energy consumption (steam, electric power) of the tenter oven increases due to the increase in the air volume.
  • the straightness of the potential core of the blowing air is affected by the gap B (slit width B) (see FIG. 2) of the slit 8a of the air blowing surface 8 in the film running direction. Therefore, it is necessary that the distance L from the air blowing surface 8 to the film passage surface 5 and the slit width B satisfy the formula: (L / B) ⁇ 10. It is preferable that the distance L and the slit width B satisfy the formula: (L / B) ⁇ 5. When the distance L is 150 mm, the slit width B is preferably 15 mm or less. In this case, the distance L and the slit width B can satisfy the formula: (L / B) ⁇ 10.
  • the lower limit of the value of (L / B) is not particularly limited, but when the value of slit width B is about 15 mm or less, the practical range of distance L in consideration of maintainability and workability is about 30 mm. It is preferable that L and slit width B satisfy the formula: 2 ⁇ (L / B).
  • the slit width B refers to the length (width) in the running direction of the film when the air blowing surface 8 has a slit-shaped opening.
  • the distance L from the air blowing surface 8 of the slit nozzles NUn and NLn to the film passing surface 5 is 150 mm or less.
  • the distance L from the air blowing surface 8 to the film passing surface 5 is preferably 150 mm or less.
  • the slit nozzles NUn and NLn whose distance from the blowing surface 8 to the film passage surface 5 is 150 mm or less are referred to as proximity nozzles NUn and NLn.
  • This not only suppresses the MD flow but also improves the straightness or stability of the blowing air, thereby further improving the heating efficiency of the film by the proximity nozzles NUn and NLn. Further, by suppressing the MD flow, the temperature unevenness generated in the film can be further reduced, and the amount of steam consumed for heating the circulating air to the set temperature of each processing chamber can be further reduced.
  • the distance L from the air blowing surface 8 of the proximity nozzle to the film passing surface 5 is more preferably 75 mm or less.
  • the distance L from the air blowing surface 8 of the proximity nozzle to the film passage surface 5 is more preferably 50 mm or less. By making the distance L 50 mm or less, the heating efficiency of the film is further improved.
  • the distance from the air blowing surface to the film passage surface is 170 mm or more and 300 mm or less in the tenter oven of the thermoplastic resin film. It has been found that when this distance is reduced from, for example, 170 mm to 50 mm, the heating efficiency of the film is improved by 20 to 30%.
  • the power consumption can be reduced by lowering the air volume of the circulation fan as much as the heating efficiency of the film is improved by the proximity nozzle. At that time, when the proximity nozzle is applied, it is preferable to reduce the air flow rate of the circulation fan while confirming that there is no change in the characteristics and quality of the film when the proximity nozzle is applied.
  • the lower limit of the distance L from the air blowing surface 8 to the film passing surface 5 is preferably set in a range where the traveling film does not contact the air blowing surface 8 of the proximity nozzle.
  • the inventor has confirmed that a stretched film can be produced without the traveling film coming into contact with the proximity nozzle in the range of Examples described later.
  • the distance L can be further shortened by devising such as reducing the slack of the running film.
  • the front end surface of the proximity nozzle is processed smoothly, or alternatively, in the vicinity of the front end surface of the proximity nozzle, protection for film catching along the longitudinal direction (running film width direction) of the proximity nozzle A cover may be installed.
  • the shape of the protective cover include a rod shape and a plate shape. In the case of a plate shape, a single plate may be provided between adjacent nozzles.
  • the protective cover When the protective cover is formed of a single plate between adjacent nozzles, it is necessary that the single plate be provided with an air circulation hole through which exhaust air can flow. This is to secure a flow passage for air that passes through the air suction portion 2 formed between adjacent nozzles and is discharged to the heat exchanger 3 provided in the tenter oven.
  • FIG. 14a shows the proximity of the nozzle to the tip of the proximity nozzle in the vicinity of the air blowing opening (slit) of the proximity nozzle that can change the length of the nozzle in the width direction of the running film used as the air blowing nozzle of the tenter oven of the present invention. It is the longitudinal cross-sectional schematic diagram in the running direction of the film of an example of a proximity nozzle at the time of installing the protective cover for preventing catching of a running film.
  • each of the proximity nozzles NL1 and NL2 is a proximity nozzle in which the length of the nozzle in the width direction of the traveling film can be varied.
  • Each of the proximity nozzles NL1 and NL2 includes a fixed nozzle portion (fixed housing) 14 and a movable nozzle portion (movable housing) 15 that expands and contracts with respect to the fixed nozzle portion (fixed housing) 14.
  • a protective cover 42 for preventing the traveling film from being caught on the tip surface of the proximity nozzle is provided.
  • the front end 38 of the protective cover 42 is located closer to the film passing surface 5 than the air blowing surface 8 of the proximity nozzle NL1. In addition, it is preferable that there are no sharp parts by bending the tip of the protective cover 42.
  • the front end 38 of the protective cover 42 is positioned closer to the travel film (film passage surface 5) than the air blowing surface 8 of the proximity nozzle NL1, so that the travel film does not contact the front end surface of the proximity nozzle NL1, Since the protective cover 42 is contacted as necessary, the film is prevented from being broken due to the contact with the tip surface of the proximity nozzle.
  • the air blowing surface 8 of the upper proximity nozzle NUn located on the upper surface side of the film passage surface 5 is changed from the air blowing surface 8 to the film passage surface 5.
  • the distance to the air blowing surface 8 of the lower adjacent nozzle NLn located on the lower surface side should be 50 mm or more to ensure a work space. That is, the distance L from the air blowing surface 8 to the film passing surface 5 is preferably 25 mm or more.
  • the air blowing surface 8 is positioned opposite to the film passing surface 5.
  • the proximity nozzles are provided on the upper side and the lower side of the film passage surface 5, it is preferable that the air blowing surfaces 8 of the respective proximity nozzles face each other through the film passage surface 5.
  • the proximity nozzle is installed only on the upper side or the lower side with respect to the film passage surface 5, the MD flow easily flows on the side where the proximity nozzle is not installed, and the MD flow suppression effect of the proximity nozzle is obtained. To reduce.
  • thermoplastic resin film is unlikely to transmit air between the upper surface and the lower surface unlike materials such as cloth.
  • air is blown only from the upper surface side or the lower surface side of the film, the film blows up due to the wind pressure of the blowing air, and the fluttering of the film increases. This causes film breakage and the like.
  • it is difficult to uniformly heat, cool or dry both sides of the film, and uneven physical properties are likely to occur in the film.
  • a device for example, a pressing roll
  • a device for example, a pressing roll
  • the air blowing surfaces are opposed to each other when the air blowing surface of the adjacent nozzle on the upper surface side is projected on the film passing surface 5 and the air blowing surface of the lower nozzle on the lower nozzle side is projected on the film passing surface 5.
  • the projection plane it means a state in which both projection planes overlap at least partially. It is more preferable that both projection surfaces are completely overlapped.
  • n proximity nozzles are provided on the upper surface side of the film passage surface 5
  • n proximity nozzles are also provided on the lower surface side of the film passage surface 5
  • the air blowing surface of each proximity nozzle is the film passage surface 5. It is preferable that the air blowing surface of the proximity nozzle on the upper surface side and the air blowing surface of the proximity nozzle on the lower surface side face each other.
  • the upper limit of the number of adjacent nozzles n is not particularly limited as long as the value of n is an integer of 1 or more, but in general, the value of n may be selected within a range of 300 or less.
  • the air blowing angle formed by the flow direction of the air blown from the slit of the adjacent nozzle and the film passage surface 5 is vertical. Is preferred.
  • the air blowing angle is vertical means that the air blowing angle 22 formed by the flow direction 23 of air blown from the slit of the adjacent nozzle (see FIG. 3b) and the film passage surface 5 is within a range of 90 ⁇ 5 °. .
  • a preferable spraying angle 22 is in a range of 90 ⁇ 5 °.
  • the spray angle 22 is more preferably in the range of 90 ⁇ 2 °.
  • the spray angle includes an angle on the downstream side in the film running direction (angle 22 in FIG. 3b) and an angle on the upstream side in the film running direction.
  • the spray angle referred to here is on the downstream side in the film running direction. This refers to the angle (angle 22 in FIG. 3b).
  • the effect of suppressing the MD flow in the tenter oven can be obtained by forming a strong air curtain against the MD flow by bringing the potential core of the blowing air as close as possible to the film passing surface 5. Therefore, it is preferable that the wind pressure of the blowing air on the film surface is high. Therefore, it is preferable to apply the blowing air to the film passage surface 5 perpendicularly.
  • the spray air strikes the film surface (upper surface or lower surface) passing through the film passage surface 5 at an angle, and the straightness of the flow of the spray air with respect to the film surface is improved.
  • the film is lost due to the influence of disturbance such as an accompanying air current on the film surface, and an MD flow is formed. Therefore, problems such as uneven physical properties in the film width direction and increased energy consumption due to MD flow occur.
  • the cross section (longitudinal section) of the adjacent nozzles NUn, NLn in the film running direction that is, the direction perpendicular to the longitudinal direction of the nozzle
  • the shape of the air flow path in the cross section (transverse cross section) 24 is symmetrical with respect to the nozzle center line 25.
  • FIG. 4b is an enlarged schematic cross-sectional view of the air blowing opening T of the proximity nozzle shown in FIG. 4a.
  • the slit gap (slit width) B of the air blowing opening (slit) 8a on the air blowing surface 8 and the distance H in the bottom direction of the nozzle from the air blowing surface 8 are In the range where the formula: (H / B) ⁇ 10 is satisfied, it is more preferable that the cross-sectional shape of the air flow path in the nozzle is symmetrical.
  • the slit gap B is 10 mm
  • the cross-sectional shape of the air flow path in the nozzle is symmetrical in the range where the formula: H ⁇ 100 mm is satisfied.
  • FIG. 5 is a schematic cross-sectional view of the tenter oven shown in FIG. 1 in the direction of arrows BB in FIG.
  • FIG. 6 is a schematic cross-sectional view of a tenter oven when the proximity nozzle shown in FIG. 5 includes a fixed housing and a movable housing.
  • the air blowing surfaces 8 of the proximity nozzles NUn and NLn are positioned facing the film passage surface 5 on the upper surface side and the lower surface side of the film passage surface 5.
  • the left and right clip moving devices that move a large number of clips 11 for gripping both ends of the film from the inlet 6 toward the outlet 7 and the left and right clip moving devices are guided inside the tenter oven, and
  • the left and right rails 12 are provided so that the distance in the width direction of the traveling film can be changed, and the left and right rail covers 13 are provided to cover the left and right rails.
  • the width of the running film of the proximity nozzles NUn and NLn may be made shorter than the distance between the two rail covers 13 so that the proximity nozzles NUn and NLn are accommodated between the two rail covers 13.
  • FIG. 6 is a schematic cross-sectional view of the tenter oven when the air blowing surfaces 8 of the proximity nozzles NUn and NLn are positioned opposite to the film passing surface 5 on the upper surface side and the lower surface side of the film passing surface 5.
  • the proximity nozzles NUn and NLn shown in FIG. 6 are proximity nozzles whose length can be varied (stretched and contracted) in the width direction of the running film following the change in the width of the rail interval 26.
  • An example of the proximity nozzles NUn and NLn whose lengths are variable following the change in the width of the rail interval 26 includes a fixed nozzle portion 14 and a movable nozzle portion 15 that is slidable in and out of the fixed nozzle portion 14. It is configured.
  • the movable nozzle portion may be formed from a plurality of movable portions.
  • the number of fixed nozzle portions and the number of movable nozzle portions forming the proximity nozzle may be selected according to the change width of the rail interval 26.
  • the width change of the rail interval 26 can be followed.
  • the protective cover 42 (see FIG. 14a) is the width of the rail gap as in the proximity nozzle.
  • the protective cover 42 is composed of a fixed cover portion 40 and a movable cover portion 39 that slides in and out of the fixed cover portion 40, because the change must be followed. It is preferable. By connecting the end of the movable cover portion 39 to the rail cover 13, it is possible to follow the change in the width of the rail gap.
  • the protection cover 42 When the protective cover 42 is provided across the air suction part 2 between the adjacent nozzles NUn and NLn adjacent to the film running direction, the protection cover 42 is protected so as not to hinder the flow of air flowing through the air suction part 2. It is necessary to provide the cover 42 with the opening 41 of the protective cover. Thereby, the flow path (air suction part 2) of the air which bounces off from the film surface is ensured.
  • the shape of the opening 41 of the protective cover is not limited to a large number of circular holes shown in FIG. 14b, and the shape of the opening 41 of the protective cover, taking into account the strength and manufacturing accuracy of the protective cover 42, Design the size, arrangement, etc.
  • the pattern of the air blowing opening on the air blowing surface of the nozzle whose length in the width direction of the running film is variable needs to be a slit. This is because, as shown in FIG. 13, when an air blowing nozzle having a perforated plate type air blowing surface is used and this air blowing nozzle is formed of a fixed nozzle portion 14 and a movable nozzle portion 15, the air blowing nozzle When the width of the nozzle is changed, a portion of the fixed nozzle portion 14 and the movable nozzle portion 15 where the hole is blocked is formed, thereby changing the pitch 35 between adjacent holes and reducing the substantial opening area 36. This is because there is a portion 37 in which the distribution of the blown air in the width direction becomes non-uniform, and it becomes difficult to make the physical property unevenness in the film width direction uniform.
  • This problem can be solved by making the air blowing opening pattern on the air blowing surface into a slit. That is, even when the length of the nozzle (the length in the direction perpendicular to the traveling direction of the nozzle film) changes, the size of the slit gap (slit width) of the slit 8a provided in the nozzle length direction is This is because since the opening area of the slit is constant in the length direction of the nozzle, it is avoided that the opening area of the slit becomes uneven at the entrance and exit of the fixed nozzle portion and the movable nozzle portion. Thereby, even if the length of a nozzle changes, manufacture of the stretched film which has a desired uniform physical property is realizable.
  • the connecting portion between the movable nozzle portion 15 and the rail cover 13 can absorb the movement of the rail 12 (or the rail cover 13) in the film traveling direction, and the film traveling direction and It is preferably formed of a connecting member that can freely rotate with respect to the width direction of the film.
  • the tenter oven has a stretching process of stretching the film in the width direction and imparting predetermined physical properties to the film, as shown in FIG. 11a. That is, the change in the width between the left and right rails is necessary not only at the time of switching products having different product widths, but also when giving various stretching ratios to the film in the stretching process. For example, when the width between the left and right rails is changed from a rail RPA in a certain pattern A state to a rail RPB in another pattern B state in order to change the stretch ratio, the rail RPA in the pattern A state In the rail RPB in the pattern B state, the position of the connecting portion 27 between the rail cover 13 and the movable nozzle portion 15 moves to the position of the connecting portion 28.
  • the connecting portion 27 moves in the film running direction (MD direction), and the rail cover 13 rotates relative to the proximity nozzle. Therefore, if the movable nozzle portion 15 and the rail cover 13 are simply fixed, the proximity nozzle may be damaged by the movement of the rail cover 13.
  • the stretch ratio of the film may vary within a range of about 3 to 7 times depending on the required quality, and the amount of movement of the rail in the MD direction may also increase.
  • the connecting portions 27 and 28 absorb the movement amount 30 in the MD direction due to the change in the rail width, while the connecting portions 27 and 28 are in the film running direction. It is preferable to have a structure that can freely rotate in the width direction. This is because simply changing the length of the nozzle in the width direction of the film may fail to follow the change in the draw ratio.
  • a long hole corresponding to the amount of rail movement is provided in the connecting member forming the connecting portion 27 of the rail cover 13 and the movable nozzle portion 15, and the pin mechanism 31 (FIG. 11b) is provided in this long hole.
  • This connecting member is, for example, in the long hole 27a provided in the connecting part 27 attached to the rail side end of the movable nozzle part at the end of the proximity nozzle, and to the tip of the arm 31a attached to the rail cover 13. It is formed by fitting the provided pin 31b so as to be movable.
  • the width 33 of the connecting rib 32 is preferably 2 mm or less, and the distance 34 between two adjacent ribs is preferably 10 mm or more.
  • each slit gap between the fixed nozzle part and the movable nozzle part has a structure that can keep constant. As shown in FIG. 12, this can be realized by providing connecting ribs 32 (reinforcing members that hold the slit gap) at regular intervals in the nozzle width direction in the slit of the air blowing surface.
  • the connecting rib 32 Due to the presence of the connecting rib 32, the air flow passing through the vicinity of the connecting rib 32 may be disturbed, which may cause uneven heating efficiency. However, according to the inventor's investigation, this concern is eliminated by setting the width 33 of the connecting rib 32 to 2 mm or less and the thickness of the connecting rib 32 in the vertical direction to 2 mm or less. If it exceeds this range, the unevenness of the heating efficiency becomes large, and there is a concern of causing film quality problems such as unevenness of thickness.
  • the distance 34 between two adjacent connecting ribs is preferably at least 10 mm. By setting the distance 34 to 10 mm or more, the influence due to the decrease in the flow rate of the air flowing in the vicinity of the connecting rib 32 is reduced, and the actual harm to the quality of the film is almost eliminated.
  • the upper limit of the distance 34 is not particularly limited because it depends on the rigidity of the air blowing surface of the nozzle, but is preferably 500 mm or less, more preferably 100 mm or less.
  • the width 33 of the connecting rib 32 is the width of the connecting rib 32 in the longitudinal direction of the slit, and the thickness of the connecting rib 32 is a dimension in the vertical direction.
  • the distance 34 between two adjacent ribs refers to the distance between the central positions of the widths of adjacent ribs.
  • the shape of the connecting rib 32 may be a rectangular parallelepiped shape or a round bar shape. However, it is desirable to examine optimum specifications for the shape of the connecting rib 32, the pitch in the nozzle width direction, and the like according to the allowable level of unevenness of the film to be produced.
  • a sliding mechanism is provided at a position where the movable nozzle portion 15 moves relative to the fixed nozzle portion 14.
  • the movable nozzle portion 15 can be adjusted to a predetermined nozzle width by moving with a low sliding resistance while maintaining a constant gap between both nozzles without colliding with the fixed nozzle portion 14 in the film width direction.
  • a sliding mechanism on the movable nozzle portion 15.
  • a wheel is provided on the movable nozzle portion 15, and a wheel provided on the movable nozzle portion 15 is provided on the fixed nozzle portion 14.
  • a sliding mechanism provided with a traveling rail is conceivable.
  • the type and structure of the sliding mechanism is not limited to the wheel type exemplified above, and various methods such as sliding with a linear guide and sliding with contact between metal plates infiltrated with a lubricant can be considered. It should be selected in consideration of maintainability (lubricant replenishment, nozzle repair, inspection), cost, sliding resistance, heat resistance, etc.
  • the proximity nozzle is provided at least in a part of the preheating zone when the zone before the stretching step is a preheating zone. .
  • the reason is as follows.
  • FIG. 7 is a schematic longitudinal sectional view of an example of a tenter oven composed of a plurality of zones.
  • the tenter oven TO2 is surrounded by an oven outer wall 21 except for the inlet 6 and the outlet 7.
  • the inside of the tenter oven TO2 is divided into, for example, a preheating zone ZPH, a stretching zone ZD, a heat setting zone ZHS, and a cooling zone ZC according to functions required for the tenter oven TO2.
  • Each zone is provided with a plurality of air blowing nozzles that are heated by the running film and blown air, facing the upper and lower surfaces of the film passage surface.
  • the preheating zone ZPH refers to the zone of the process before stretching the film.
  • the thermoplastic resin film is a polyester sequential biaxially stretched film, it is a zone where the film is heated to a temperature at which the crystallization of the film does not proceed and to a temperature at which the film can be stretched.
  • the MD flow is generated in the preheating zone ZPH which is the zone closest to the inlet 6 of the tenter oven TO2, so that air having different set temperatures (for example, outside air in the oven, circulating air in the stretching zone, etc.) When flowing, mixing of the blowing air and MD flow causes problems such as uneven thickness of the film, poor stretchability, or coating unevenness when the film is preheated. Occur.
  • the proximity nozzle in the preheating zone, there is no fear of nozzle failure, and the effect of suppressing MD flow and the effect of improving energy efficiency can be exhibited greatly.
  • the proximity nozzle it is more preferable that all the air blowing nozzles in the preheating zone are proximity nozzles. Since all the spray nozzles in the preheating zone are adjacent nozzles, the effect of suppressing MD flow and the effect of reducing energy are increased.
  • an air supply duct and an exhaust duct may be provided in the room.
  • the ratio of the total supply amount and the total exhaust amount is set to 1 in the room or zone in which the proximity nozzle is installed, and balanced. This is because an air flow is generated in the running direction of the film due to an imbalance in the supply / exhaust amount, and the flow acts as a disturbance. Therefore, when a proximity nozzle is used in the preheating zone and there are an air supply duct and an exhaust duct in the preheating zone, it is preferable that the ratio of the total air supply amount and the total exhaust amount in the preheating zone is 1.
  • An air inflow prevention shutter is installed at the entrance and exit of the chamber or zone where the proximity nozzle is applied, and at a distance of 20 to 50 mm away from the upper and lower surfaces of the film passage surface in the direction of the air blowing surface (vertical direction). Then, as a synergistic effect with the proximity nozzle, a large suppression effect of MD flow is obtained.
  • proximity nozzles may be applied to all zones of the tenter oven. At that time, it is preferable that the ratio of the supply / discharge amount and the exhaust amount of the entire zone is 1.
  • the proximity nozzle when the proximity nozzle is applied to all zones of the tenter oven, the proximity nozzle whose length in the longitudinal direction (direction perpendicular to the traveling direction of the film) as shown in FIG. In comparison, the manufacturing cost is high, and weak wind speed unevenness of the blown air due to the structure tends to occur. Therefore, it is preferable to determine the application range of the proximity nozzle whose length in the longitudinal direction can be adjusted by sufficiently considering cost-effectiveness and influence on the quality of the stretched film to be produced.
  • an unstretched film is obtained by extruding a thermoplastic resin from a die onto a cooling drum, and if necessary, this unstretched film is stretched in the longitudinal direction (running direction) to obtain a uniaxially stretched film.
  • a biaxially stretched thermoplastic resin film can be obtained by a method of stretching a uniaxially stretched film in the width direction in a tenter oven (sequential biaxial stretching method), or the unstretched film can be traveled in a tenter oven. It is widely performed to obtain a biaxially stretched thermoplastic resin film by a method of stretching simultaneously in the width direction and the width direction (simultaneous biaxial stretching method).
  • the tenter oven of the present invention is preferably used as a tenter oven used in such a production process.
  • the method for producing a stretched film of the present invention is obtained by introducing an unstretched film obtained by extruding a thermoplastic resin from a die onto a cooling drum or a uniaxially stretched film already obtained by introducing it into the tenter oven of the present invention.
  • An axially stretched stretched film is produced.
  • the biaxially stretched stretched film made of a thermoplastic resin produced by the stretched film production method of the present invention has uniform width characteristics and thickness. Moreover, the energy consumption required for the temperature rise of the film in the manufacturing process can be significantly reduced as compared with the conventional case.
  • FIG. 8 is a schematic vertical sectional view of this model test machine.
  • the length of the running direction of the film is 2.0 m and the width of the running film is 1.8 m at the position of the film passing surface 5.
  • a transparent acrylic plate 17 was fixed.
  • the internal dimensions of the model test machine chamber were 1.8 m for the length in the running direction of the film, 1.8 m for the width in the width direction of the running film, and 1.5 m for the height.
  • the opening 6 corresponding to the film inlet 6 was provided on the left outer wall 18 in FIG. 8 of the model test machine, and the opening 7 corresponding to the film outlet 7 was provided on the right outer wall 18.
  • the air blowing opening 8a in the air blowing surface 8 of the proximity nozzle NLn is a slit having a width (gap) in the running direction of the film of 0.016 m and a length in the width direction of the running film of 1.2 m.
  • the air blowing surface 8 is located in parallel with the lower surface of the acrylic plate 17.
  • the model test machine is provided with a mechanism for adjusting the distance L from the air blowing surface 8 to the lower surface of the acrylic plate 17. This distance L corresponds to the distance L from the air blowing surface 8 of the proximity nozzle NLn to the film passing surface 5.
  • the acrylic plate 17 is used as a substitute for the thermoplastic resin film, the flicker of the film seen in an actual tenter oven cannot be observed, and the air blowing surface 8 to the lower surface of the acrylic plate 17 can be observed.
  • the distance up to is maintained at the set distance regardless of the wind speed of the blowing air, the air volume, changes with time, and the like.
  • the adjacent nozzles NLn are numbered No. 1 to No. 4 in order from the inlet 6 (opening 6) to the outlet 7 (opening 7).
  • One circulation fan 4 (circulation fan 4 located on the left side in FIG. 8) is adjacent to two adjacent nozzles No1 and No2, and another circulation is performed to two adjacent nozzles No3 and No4.
  • a fan 4 (circulation fan 4 located on the right side in FIG. 8) was provided so that the air blown against the acrylic plate 17 was circulated through the nozzles.
  • the air volume of each circulation fan 4 was adjusted so that the wind speed of the blowing air was about 20 m / s on average.
  • the heat exchanger was not installed and the air whose temperature is room temperature was circulated.
  • the spray angle 22 (see FIG. 3b) was set to 90 ⁇ 5 ° for all the adjacent nozzles NLn.
  • FIG. 9 is a schematic longitudinal sectional view for explaining a method for evaluating the magnitude of the MD flow by generating the accompanying air flow in a simulated manner with the model test machine of FIG.
  • an air generator 20 was installed at the inlet 6 of the model test machine.
  • the air generator 20 runs along the lower surface of the acrylic plate 17 from the inlet 6 to the outlet 7 of the model test machine. Air was blown.
  • FIG. 10 is a schematic cross-sectional view in the direction of arrow C1-C1 shown in FIG.
  • Five anemometers 19 were provided at the outlet 7 of the model test machine at almost equal intervals in the width direction of the film.
  • the wind speed of the air flowing out from the outlet 7 was measured by the anemometer 19, and the measured wind speed value was taken as the MD flow magnitude.
  • the wind speed of the air flowing from the air generator 20 was adjusted to an accuracy of about 3 m / s and ⁇ 0.5 m / s in the film width direction at the inlet 6 of the model test machine.
  • the MD flow is P1, P2, P3, P4, using five anemometers 19 provided at approximately equal intervals in the width direction of the film at the outlet 7 of the model test machine and immediately below the acrylic plate 17. Measured at 5 points of P5.
  • an 80 mm vane type anemometer was used as the anemometer 19. The observation surface of the vane anemometer was faced in the film traveling direction, and the wind velocity of air flowing in the film traveling direction at the outlet 7 was measured. Since the wind speed of MD flow fluctuates with time, the sampling period is set to 1 second, and the average value when measured continuously for 15 seconds is defined as the wind speed of MD flow.
  • the acrylic plate 17 was provided with an opening having a width of 150 mm and a length of 150 mm at the position of the central portion directly above the location of the proximity nozzle No. 2 of the acrylic plate 17 of the model test machine.
  • a sheet-like rubber heater having a width of 150 mm and a length of 150 mm was installed in the opening.
  • an infrared thermography was installed at a position 0.7 m upward from the upper surface of the acrylic plate 17, and the measurement field of the infrared thermography was adjusted so that the temperature distribution on the surface of the sheet-like rubber heater could be photographed simultaneously.
  • the rubber heater was heated to 100 ° C., and air flow was generated by the air generator 20 installed at the inlet 6 of the model test machine while blowing air at room temperature from the proximity nozzle toward the rubber heater. At that time, the temperature distribution of the surface of the rubber heater was photographed by infrared thermography, and the temperature unevenness of the rubber heater caused by the MD flow in the model test machine was measured with the dedicated thermal analysis software.
  • Heating efficiency measurement method The heating efficiency of the proximity nozzle is the same as the temperature unevenness measurement method described above. While the air is blown to the heated rubber heater by the proximity nozzle, the heat consumption of the rubber heater, The temperature and the rubber heater temperature after air blowing were substituted into the following formula to determine the heat transfer coefficient of the proximity nozzle, which was defined as the heating efficiency. Note that when the heating efficiency was measured, the air generator 20 was inactivated, and the heating efficiency of the proximity nozzle alone was measured.
  • Heat transfer coefficient [W / m 2 K] Heat consumption of rubber heater / [(Rubber heater temperature after air blowing) ⁇ (Blowing air temperature)]
  • the MD flow wind speed [m / s] except that the distance L from the air blowing surface 8 to the lower surface of the acrylic plate 17 is 100 mm and the value of L / B is 6.3. Heating efficiency [W / m 2 K] and temperature unevenness [° C.] were determined. The results are shown in Table 1.
  • the wind speed [m / s] of the MD flow is the same as in Example 1 except that the distance L from the air blowing surface 8 to the lower surface of the acrylic plate 17 is 150 mm and the value of L / B is 9.4. Heating efficiency [W / m 2 K] and temperature unevenness [° C.] were determined. The results are shown in Table 1.
  • Polyethylene terephthalate resin manufactured by Toray Industries, Inc., F20S
  • F20S Polyethylene terephthalate resin
  • the obtained sheet was brought into close contact with the surface of a cooling drum having a diameter of 1600 mm maintained at a surface temperature of 20 ° C. by an electrostatic application method and cooled and solidified to obtain a thermoplastic resin film having a thickness of 2100 ⁇ m.
  • thermoplastic resin film was heated with a heated roll group and an infrared heater, and then stretched 3.2 times in the running direction with a roll group having a difference in peripheral speed to obtain a uniaxially stretched film.
  • the obtained uniaxially stretched film was introduced into a tenter oven composed of a preheating zone, a stretching zone, a heat setting zone, and a cooling zone.
  • Each zone was formed by a plurality of chambers shown in FIG. That is, two preheating zones, four stretching zones, four heat setting zones, and two cooling zones were used.
  • Each chamber had a height of 3 m, a length of 3 m, and a width of 2 m.
  • five slit nozzles NUn were installed on the upper surface side of the film passage surface 5
  • five slit nozzles NLn were also installed on the lower surface side of the film passage surface.
  • the angle formed by the direction of the blowing air and the film passage surface was set to 90 ⁇ 5 °.
  • All slit nozzles in the preheating zone were close nozzles having a distance L from the air blowing surface to the film passage surface of 50 mm. In other zones, a slit nozzle having a distance L from the air blowing surface to the film passing surface of 170 mm was used.
  • each chamber hot air heated to a predetermined set temperature was blown out from the slit nozzle or the adjacent nozzle toward the film by a circulation fan, and a desired heat treatment of the film was performed.
  • the end of the uniaxially stretched film was held with a clip, passed through a preheating zone at a temperature of 100 ° C., led to a stretching zone at a temperature of 130 ° C., and the uniaxially stretched film was stretched 3.5 times in the width direction.
  • the film is heat set in a heat setting zone at a temperature of 220 ° C., and further, after cooling the film in a cooling zone at a temperature of 100 ° C., Both ends of the film were trimmed and further wound up by a winding device to obtain a biaxially stretched film having a thickness of 188 ⁇ m and a width of 3450 mm.
  • the temperature of each zone is the temperature of hot air blown from the slit nozzle or the adjacent nozzle.
  • the traveling speed of the film was 25 m / min.
  • the obtained biaxially stretched film was removed from each end by 225 mm, and divided into 1000 mm widths and slitted to obtain three biaxially stretched film rolls having a width of 1000 mm and a length of 2000 m. Of these three films, a roll obtained from the film at the center of the obtained biaxially stretched film was used to prepare a film roll sample necessary for measuring the thickness unevenness of the film.
  • the measurement of the thickness unevenness of the film is carried out from a film sample having a length of 1 m and a width of 600 mm, with a thickness measurement sample having a width of 40 mm being set so that the center of the film sample is 100 mm from the center in the width direction and the end. Cut out from three places. Thereafter, using a contact-type thickness gauge (KG60 / A manufactured by Anritsu Co., Ltd.), the thickness in the running direction of the film of each thickness measurement sample was continuously measured and output to a chart recorder.
  • KG60 / A manufactured by Anritsu Co., Ltd. the thickness in the running direction of the film of each thickness measurement sample was continuously measured and output to a chart recorder.
  • the maximum and minimum values ⁇ m and ⁇ m of the thickness in the running direction of the film, and the arithmetic average value ⁇ m (hereinafter simply referred to as the average value ⁇ m) of the continuous distribution obtained from the thickness profile are obtained. It was. And the percentage with respect to the average value of the difference of the maximum value and the minimum value was calculated
  • the thickness nonuniformity R in an Example is an average value of the thickness nonuniformity R of the sample for a measurement of three places.
  • the MD flow was measured at the outlet of the tenter oven, as shown in FIG. 10, by measuring the wind speed at five locations at equal intervals in the width direction of the film, and calculating the average value.
  • the power reduction rate [%] and the steam reduction rate [%] of the tenter oven with respect to before the proximity nozzle was applied were calculated. “Before applying the proximity nozzle” means that the distance L from the air blowing surface to the film passing surface is 170 mm in all the nozzles of the tenter oven.
  • the power consumption [kWh] of the circulation fan in each room before and after applying the proximity nozzle is calculated by the following formula, and the total power consumption of each room (power consumption of the entire tenter oven) It was obtained by calculating.
  • Power reduction rate [%] [(Decrease in total power consumption before and after applying proximity nozzle) / (Total power consumption before applying proximity nozzle)].
  • Power consumption [kWh] [Rated capacity of circulating fan [kWh] ⁇ (Circulating fan operating frequency [Hz] / Circulating fan rated frequency [Hz]) 3 / Inverter efficiency].
  • the steam reduction rate [%] is calculated by calculating the steam consumption [t / year] of each room heat exchanger before and after applying the proximity nozzle with the following formula, and the total steam consumption of each room (the entire tenter oven) The amount of steam consumed) was calculated.
  • Table 2 shows various conditions and various measured values in Example 6.
  • a tenter oven was used in the same manner as in Example 6 except that the proximity nozzle was applied to all slit nozzles in the preheating zone and the stretching zone, and the ratio of the preheating and the total supply amount of the stretching zone to the total exhaust amount was set to 1.
  • the thickness direction thickness unevenness [%] of the film that came out, and the wind speed of the MD flow at the tenter oven outlet were measured. Further, the power reduction rate [%] and the steam reduction rate [%] of the tenter oven with respect to before the proximity nozzle was applied were calculated. Table 2 shows various conditions and various measured values in Example 7.
  • the proximity nozzle is applied to all slit nozzles in the preheating zone, the stretching zone, and the heat setting zone, and the ratio of the total amount of supply air and the total displacement in the heat setting zone and the heat setting zone is set to 1.
  • the thickness direction unevenness [%] of the film exiting the tenter oven and the wind speed of the MD flow at the exit of the tenter oven were measured. Further, the power reduction rate [%] and the steam reduction rate [%] of the tenter oven with respect to before the proximity nozzle was applied were calculated. Table 2 shows various conditions and various measured values in Example 8.
  • the proximity nozzle is applied to slit nozzles in all zones of the tenter oven (all zones from the preheating zone to the cooling zone), and the ratio of the total supply amount and the total exhaust amount in all zones is set to 1.
  • the thickness direction unevenness [%] of the film exiting the tenter oven and the wind speed of the MD flow at the exit of the tenter oven were measured. Further, the power reduction rate [%] and the steam reduction rate [%] of the tenter oven with respect to before the proximity nozzle was applied were calculated. Table 2 shows various conditions and various measured values in Example 9.
  • tenters were installed in the same manner as in Example 6 except that five proximity nozzles were installed in each chamber only on the lower side of the film passage surface.
  • the thickness unevenness [%] of the film exiting the oven was measured, and the wind speed of the MD flow at the tenter oven outlet was measured. Further, the power reduction rate [%] and the steam reduction rate [%] of the tenter oven with respect to before the proximity nozzle was applied were calculated. Table 2 shows various conditions and various measured values in Example 10.
  • ⁇ Proximity nozzles were installed in all zones of the tenter oven (all zones from the preheating zone to the cooling zone). At that time, the spray angle was set to 110 ⁇ 5 °. Other than that was carried out similarly to Example 6, and measured the thickness nonuniformity [%] of the film which went out of the tenter oven, and the wind speed of MD flow at the tenter oven exit. Further, the power reduction rate [%] and the steam reduction rate [%] of the tenter oven with respect to before the proximity nozzle was applied were calculated. Table 2 shows various conditions and various measured values in Example 11.
  • the distance L from the air blowing surface to the film passage surface is 170 mm, and the ratio of the total supply amount and the total discharge amount of all zones is 0.76.
  • the thickness unevenness [%] of the film exiting the tenter oven and the wind speed of the MD flow at the tenter oven outlet were measured. Further, the power reduction rate [%] and the steam reduction rate [%] of the tenter oven with respect to before the proximity nozzle was applied were calculated. Table 2 shows various conditions and various measured values in Comparative Example 4.
  • the distance L from the air blowing surface to the film passing surface is 150 mm or less, it is possible to reduce the temperature unevenness of the film and reduce the heating unevenness of the spray nozzle.
  • a proximity nozzle having a distance L from the air blowing surface to the film passage surface of 150 mm or less in at least the preheating zone of the tenter oven MD flow can be suppressed and film thickness unevenness can be improved.
  • the proximity nozzle can also be said to be an effective means for reducing the power of the tenter oven and the energy consumption of the steam.
  • At least one air blowing nozzle of a plurality of air blowing nozzles used therein has a slit-shaped opening provided on the air blowing surface of the nozzle, and from the air blowing surface to the film passing surface.
  • the tenter oven is characterized in that the distance L and the width B of the slit gap satisfy the relationship of the formula: (L / B) ⁇ 10, and the distance L is 150 mm or less. .
  • the tenter oven of the present invention the air flow (MD flow) in the running direction of the film generated in the tenter oven is suppressed.
  • the tenter oven of the present invention is a stretched film with little thickness unevenness. It is preferably used for production.
  • the MD flow in the tenter oven of the present invention is suppressed, the process in the tenter oven can be stabilized and the energy consumption can be reduced.
  • Air suction part 3 Heat exchanger 4: Circulating fan 5: Film passage surface 6: Entrance (entrance of running film) 7: Exit (Exit of traveling film) 8: Air blowing surface 8a: Air blowing opening, slit 11: Clip 12: Rail 13: Rail cover 14: Fixed nozzle portion 15: Movable nozzle portion 17: Acrylic plate 18: Outer wall 19 of model test machine 19: Vane type anemometer 20 : Air generator 21: Oven outer wall 22: Air blowing angle 23: Flow direction of air blown from the slit 24: Nozzle cross section 25: Nozzle center line 26: Rail interval 27: Rail cover for rail pattern A Movable nozzle portion connecting portion 27a: slot 28: rail cover and rail nozzle B when connected to rail pattern B 29: moving end portion fixed portion 30: moving amount of connecting portion in MD direction 31: rail cover Pin mechanism 31a for connecting the movable nozzle portions: arm 31b: pin 32: connecting rib 33: connecting rib width 34 : Gaps 35 between two adjacent connecting ribs

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  • Engineering & Computer Science (AREA)
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  • General Engineering & Computer Science (AREA)
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  • Health & Medical Sciences (AREA)
  • Oral & Maxillofacial Surgery (AREA)
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  • Shaping By String And By Release Of Stress In Plastics And The Like (AREA)

Abstract

La présente invention se rapporte à un four de rétraction à buses proximales. Un four de rétraction destiné à étirer un film de résine thermoplastique dans le sens de la largeur de ce dernier présente une ouverture soufflant de l'air associée à une buse soufflant de l'air et agencée en interne, qui souffle de l'air chaud sur un film qui passe le long d'une surface de passage de film, et qui est agencée sur une surface soufflant de l'air associée qui a la forme d'une fente, la distance (L) entre la surface soufflant de l'air et la surface de passage de film, ainsi que la largeur (B) de la fente, satisfaisant la relation exprimée par l'équation : (L/B) ≤ 10, la distance (L) étant égale ou inférieure à 150 mm.
PCT/JP2012/057462 2011-03-29 2012-03-23 Four de rétraction et procédé de fabrication d'un film étiré WO2012133152A1 (fr)

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JP2012523141A JP5949548B2 (ja) 2011-03-29 2012-03-23 テンターオーブンおよび延伸フィルムの製造方法
CN201280015361.2A CN103442879B (zh) 2011-03-29 2012-03-23 拉幅烘箱以及延伸膜的制造方法
EP12764064.7A EP2692508B1 (fr) 2011-03-29 2012-03-23 Four de rétraction et procédé de fabrication d'un film étiré
KR1020137027161A KR101879897B1 (ko) 2011-03-29 2012-03-23 텐터 오븐 및 연신 필름의 제조 방법
US14/007,780 US9522488B2 (en) 2011-03-29 2012-03-23 Tenter oven and manufacturing method for stretched film

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JP2011-071955 2011-03-29
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JP2011-250286 2011-11-16
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JP2014208456A (ja) * 2013-03-29 2014-11-06 東レ株式会社 テンターオーブン、及びそれを用いた熱可塑性樹脂フィルムの製造方法
JP2014208463A (ja) * 2013-03-29 2014-11-06 東レ株式会社 テンターオーブンおよび熱可塑性樹脂フィルムの製造方法
JP2014208462A (ja) * 2013-03-29 2014-11-06 東レ株式会社 テンターオーブンおよび熱可塑性樹脂フィルムの製造方法
EP2979843A4 (fr) * 2013-03-29 2016-11-30 Toray Industries Four de rétraction et procédé de fabrication de film de résine thermoplastique
CN106679394A (zh) * 2016-12-02 2017-05-17 汕头市远东轻化装备有限公司 薄膜横向拉伸烘箱的风箱系统单元
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CN114368136A (zh) * 2021-12-31 2022-04-19 苏州富强科技有限公司 一种气道结构及烘箱
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JP2014208456A (ja) * 2013-03-29 2014-11-06 東レ株式会社 テンターオーブン、及びそれを用いた熱可塑性樹脂フィルムの製造方法
JP2014208463A (ja) * 2013-03-29 2014-11-06 東レ株式会社 テンターオーブンおよび熱可塑性樹脂フィルムの製造方法
JP2014208462A (ja) * 2013-03-29 2014-11-06 東レ株式会社 テンターオーブンおよび熱可塑性樹脂フィルムの製造方法
EP2979843A4 (fr) * 2013-03-29 2016-11-30 Toray Industries Four de rétraction et procédé de fabrication de film de résine thermoplastique
CN103434128B (zh) * 2013-09-10 2015-09-02 青岛同飞管业有限公司 一种高质片材双向热循环生产工艺
CN103434128A (zh) * 2013-09-10 2013-12-11 青岛同飞管业有限公司 一种高质片材双向热循环生产工艺
JPWO2017115654A1 (ja) * 2015-12-28 2018-10-18 東レ株式会社 気流制御装置および延伸フィルムの製造方法
US10792844B2 (en) 2015-12-28 2020-10-06 Toray Industries, Inc. Airflow control apparatus and method for manufacturing stretched film
WO2017115654A1 (fr) * 2015-12-28 2017-07-06 東レ株式会社 Appareil de commande d'écoulement d'air et procédé de fabrication de film étiré
JP2018013760A (ja) * 2016-07-19 2018-01-25 穎台科技股▲ふん▼有限公司 二軸同期延伸方式による位相差膜の製造方法及びその位相差膜
CN106679394B (zh) * 2016-12-02 2019-01-15 汕头市远东轻化装备有限公司 薄膜横向拉伸烘箱的风箱系统单元
CN106679394A (zh) * 2016-12-02 2017-05-17 汕头市远东轻化装备有限公司 薄膜横向拉伸烘箱的风箱系统单元
JP7020402B2 (ja) 2017-03-28 2022-02-16 東レ株式会社 気流制御装置および延伸フィルムの製造方法
JPWO2018180565A1 (ja) * 2017-03-28 2020-02-06 東レ株式会社 気流制御装置および延伸フィルムの製造方法
WO2018180565A1 (fr) * 2017-03-28 2018-10-04 東レ株式会社 Dispositif de régulation d'écoulement d'air et procédé de fabrication de film étiré
US11370161B2 (en) 2017-03-28 2022-06-28 Toray Industries, Inc. Air flow controller and manufacturing method of stretched film
JP2021504179A (ja) * 2017-11-22 2021-02-15 ブリュックナー・マシーネンバウ・ゲーエムベーハー・ウント・コー・カーゲー 薄膜延伸装置の送風装置とその薄膜延伸装置
JP7278280B2 (ja) 2017-11-22 2023-05-19 ブリュックナー・マシーネンバウ・ゲーエムベーハー・ウント・コー・カーゲー 薄膜延伸装置の送風装置とその薄膜延伸装置
US11897179B2 (en) 2017-11-22 2024-02-13 Brückner Maschinenbau GmbH Ventilation module for a film stretching system and film stretching system of this type
CN107999352A (zh) * 2017-12-28 2018-05-08 北京星和众工设备技术股份有限公司 一种薄膜预热烘箱
CN109732889A (zh) * 2019-03-18 2019-05-10 合肥工业大学 一种双向拉伸膜横拉机的均匀加热装置
EP4234105A4 (fr) * 2021-07-30 2024-05-15 Contemporary Amperex Technology Co., Limited Appareil de séchage et dispositif de revêtement
CN114368136A (zh) * 2021-12-31 2022-04-19 苏州富强科技有限公司 一种气道结构及烘箱
CN114368136B (zh) * 2021-12-31 2024-04-23 苏州富强科技有限公司 一种气道结构及烘箱

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JP5949548B2 (ja) 2016-07-06
KR101879897B1 (ko) 2018-08-17
EP2692508B1 (fr) 2018-12-19
TWI583533B (zh) 2017-05-21
MY166819A (en) 2018-07-23
CN103442879A (zh) 2013-12-11
US9522488B2 (en) 2016-12-20
CN103442879B (zh) 2016-01-13
KR20140026409A (ko) 2014-03-05
TW201249631A (en) 2012-12-16
US20140013612A1 (en) 2014-01-16
EP2692508A1 (fr) 2014-02-05
EP2692508A4 (fr) 2014-11-19
JPWO2012133152A1 (ja) 2014-07-28

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