WO2011108491A1 - 染毛剤 - Google Patents
染毛剤 Download PDFInfo
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- WO2011108491A1 WO2011108491A1 PCT/JP2011/054513 JP2011054513W WO2011108491A1 WO 2011108491 A1 WO2011108491 A1 WO 2011108491A1 JP 2011054513 W JP2011054513 W JP 2011054513W WO 2011108491 A1 WO2011108491 A1 WO 2011108491A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/35—Ketones, e.g. benzophenone
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/368—Carboxylic acids; Salts or anhydrides thereof with carboxyl groups directly bound to carbon atoms of aromatic rings
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/37—Esters of carboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4973—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom
- A61K8/498—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with oxygen as the only hetero atom having 6-membered rings or their condensed derivatives, e.g. coumarin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/58—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing atoms other than carbon, hydrogen, halogen, oxygen, nitrogen, sulfur or phosphorus
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
- A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
Definitions
- the present invention relates to a hair dye that is a non-oxidative hair dye and has good storage stability of an iron salt and is less likely to lose color due to shampoo by being dyed into the hair by appropriate reaction control.
- Hair dyes are generally divided into four types: oxidation dyes, ionic dyes, temporary dyes, and others.
- oxidation dyes are sometimes called permanent dyes, and are composed of paraphenylenediamines and paraaminophenols that are oxidized by hydrogen peroxide and become active reaction intermediates. Yes. The active intermediate then reacts with the dye coupler molecule in the hair and turns into a shampoo resistant dye.
- oxidative dyes damage hair, have contact dermatitis and prolonged permanent systemic effects, and are suspected to be mutagenic or carcinogenic.
- the ionic dye is sometimes called a semi-permanent dye and does not damage the hair.
- non-oxidative hair dyes using polyhydric phenols and iron salts have been proposed as other hair dyes (see Patent Documents 1 to 3).
- the conventional non-oxidative hair dyes are not satisfactory in terms of hair dyeability and color tone, and have a problem of discoloration due to shampoo.
- the stability of the iron salt in an aqueous solution is low, and precipitation occurs immediately in the liquid, making it difficult to produce a product in the solution.
- the iron salt contains at least one component selected from xylitol, sorbitol, pentylene glycol, dipropylene glycol, triethylene glycol, erythritol and diglycerin.
- xylitol sorbitol
- pentylene glycol dipropylene glycol
- triethylene glycol erythritol
- diglycerin has been found to provide a hair dye with good storage stability of the iron salt and with less color fading due to shampooing by being dyed to the inside of the hair by appropriate reaction control. It came to.
- a first agent containing a substance that develops color by reacting with iron and (2) (a) an iron salt and (b) xylitol, sorbitol, pentylene glycol, dipropylene glycol
- a hair dye comprising a second agent containing at least one component selected from triethylene glycol, erythritol and diglycerin in combination is provided.
- the addition amount of at least one component selected from xylitol, sorbitol, pentylene glycol, dipropylene glycol, triethylene glycol, erythritol and diglycerin is equimolar to the total amount of the second agent relative to the iron salt. On the other hand, it is 20% by weight or less.
- the component described in (2) (b) is at least one component selected from xylitol, sorbitol, pentylene glycol and dipropylene glycol.
- the component described in (2) (b) is xylitol or sorbitol.
- the substance that develops color by reacting with iron is tannic acid, gallic acid and its derivatives, pentaploid, pyrogallol, logwood, hematein, catechol, salicylic acid and its derivatives, phthalic acid, eugenol, isoeugenol, nicotinamide, Dehydroacetic acid, pyridoxine, ellagic acid, kojic acid, maltol, ferulic acid, hinokitiol, turmeric extract, curcumin, ougon extract, onion extract, quercetin, rutin, hesperetin, hesperidin, raw coffee bean extract, caffeic acid, chlorogenic acid, tea extract , Catechin, epicatechin, shikon extract, perilla extract, shisonin, grape leaf extract, butter extract, enocyanin, lacqueric acid, lac, cochineal, carminic acid, elderberry, red cabbage, murasa Potato, is tamarind, s
- the iron salt is ferrous sulfate, ferrous chloride, ferrous acetate, ferrous phosphate, ferrous oxalate, ferric sulfate, ferric hydrochloride, or ferric acetate. is there.
- the amount of the substance that develops color by reacting with iron is 0.5 to 10% by weight with respect to the total amount of the first agent, and the amount of iron salt used is 0.5 to 10% by weight with respect to the total amount of the second agent. .
- a hair coloring method comprising applying the above-described hair dye of the present invention to hair.
- the hair dye of the present invention has good shampoo resistance, good hair dyeability and color tone, and excellent storage stability of iron salt by promoting the penetration of the dye into the hair. Yes.
- FIG. 1 shows the location of Fe (hair cross-section SEM) in hair with a high color fading (hair cross-section SEM) and the location of Fe in hair with low color fading (hair cross-section SEM).
- the hair dye of the present invention includes (1) a first agent containing a substance that develops color by reacting with iron, and (2) (a) an iron salt and (b) xylitol, sorbitol, pentylene glycol, dipropylene glycol. , A two-component hair dye containing a second agent containing at least one component selected from triethylene glycol, erythritol and diglycerin.
- reactivity is utilized by utilizing a very weak interaction between a polyhydric alcohol selected from xylitol, sorbitol, pentylene glycol, dipropylene glycol, triethylene glycol, erythritol and diglycerin and an iron salt.
- a polyhydric alcohol selected from xylitol, sorbitol, pentylene glycol, dipropylene glycol, triethylene glycol, erythritol and diglycerin and an iron salt.
- a polyhydric alcohol selected from xylitol, sorbitol, pentylene glycol, dipropylene glycol, triethylene glycol, erythritol and diglycerin and an iron salt.
- hair can be dyed even inside the hair, and shampoo resistance is improved.
- an organic compound or plant extract that develops color by reacting with iron can be used as the substance that develops color by reacting with iron used in the present invention.
- substances that develop color by reacting with iron include tannic acid, gallic acid and its derivatives, pentaploid, pyrogallol, logwood, hematein, catechol, salicylic acid and its derivatives, phthalic acid, eugenol, isoeugenol, nicotinamide , Dehydroacetic acid, pyridoxine, ellagic acid, kojic acid, maltol, ferulic acid, hinokitiol, turmeric extract, curcumin, ougon extract, onion extract, quercetin, rutin, hesperetin, hesperidin, raw coffee bean extract, caffeic acid, chlorogenic acid, Cha extract, catechin, epicatechin, shikon extract, perilla extract, shisonin, grape leaf extract, butto extract, enocyanin, laca
- tannic acid gallic acid or derivatives thereof, salicylic acid or derivatives thereof, orgone extract, hematein, turmeric extract, quercetin, tea extract, laccaic acid, korya, oxybenzone-3, and oxybenzone-4.
- derivatives of gallic acid include alkyl esters of gallic acid, and examples of alkyl esters of gallic acid include linear or branched alkyl esters having 1 to 10 carbon atoms, preferably 2 to 5 carbon atoms. Can be mentioned. For example, ethyl gallate, propyl gallate, isoamyl gallate and the like are included.
- Gallic acid or a derivative thereof may be chemically synthesized by a known method or may be isolated from a plant. What further added chemical synthesis to what was isolated from the plant may be used. Moreover, you may use the extract containing the gallic acid obtained from a plant, or its derivative (s) as it is. For example, gallic acid derived from leguminous plant cod, gallic acid derived from pentaploid which occurs in urchinaceae, or extracts containing them can be used. In addition, derivatives obtained by chemically esterifying those gallic acids can also be used.
- Salicylic acid derivatives include salicylic acid esters and salts. Examples of the salicylic acid salt include alkali metal salts of salicylic acid. Specific examples include sodium salicylate. Examples of the salicylic acid ester include methyl salicylate and ethyl salicylate.
- the amount of the substance that develops color by reacting with iron is not particularly limited as long as the effect of the present invention can be obtained, but is preferably 0.5 to 10% by weight, more preferably 1 to 6% by weight based on the total amount of the first agent. %.
- the iron salt used in the present invention is not particularly limited as long as the effects of the present invention can be obtained, but in general, ferrous sulfate, ferrous chloride, ferrous acetate, ferric sulfate, ferric chloride. Among them, iron, ferric acetate and the like can be used, and ferrous sulfate or ferric chloride is preferable.
- the amount of the iron salt used is not particularly limited as long as the effect of the present invention is obtained, but it is preferably 0.5 to 10% by weight, preferably 1 to 6% by weight, based on the total amount of the second agent.
- the second agent in the present invention contains at least one component selected from xylitol, sorbitol, pentylene glycol, dipropylene glycol, triethylene glycol, erythritol and diglycerin.
- xylitol, sorbitol, pentylene glycol and dipropylene glycol are preferable, and xylitol and sorbitol are particularly preferable. You may use said component in combination of 2 or more components.
- the amount of at least one component selected from xylitol, sorbitol, pentylene glycol, dipropylene glycol, triethylene glycol, erythritol and diglycerin is equimolar to the total amount of the second agent relative to the iron salt. 20% by weight or less.
- additives may be added to the first agent and / or the second agent constituting the hair dye of the present invention.
- Additives include base materials, surfactants, fats and oils, solvents, thickeners, organic acids, preservatives, antioxidants, pH adjusters, wetting agents, fragrances, metal odor masking agents, and product colorants. And UV absorbers for products.
- components used in normal cosmetics and the like within the range not impairing the object of the present invention such as hair restorer, anti-dandruff agent, antibacterial agent, softener, moisturizer, active oxygen remover, antioxidant Agents, antimicrobial agents, silicones, minerals, hydrolyzed proteins, peptides, and amino acids can be appropriately blended. The usage-amount of these additives can be suitably set within the range with the effect of this invention.
- Examples of the base include higher alcohols, hydrocarbons, fatty acid esters, vegetable oils, fatty acids and the like.
- Surfactants include polyoxyethylene alkyl ether, polyoxyethylene polyoxypropylene alkyl ether, glycerin fatty acid ester, polyglycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene alkyl ether phosphoric acid and salts thereof, alkyl glucoside, N -Acyl amino acid salts, alkyl ether carboxylates, alkyl sulfates, polyoxyethylene alkyl ether sulfates, sulfonates, alkyl ammonium salts, alkylamidopropyl betaines and the like.
- antioxidant examples include ascorbic acid and derivatives thereof, sodium sulfite and the like.
- pH adjuster ammonia, ammonium hydrogen carbonate, ammonium carbonate, potassium hydroxide, sodium hydroxide, monoethanolamine, isopropanolamine, and the like can be used.
- wetting agent examples include 1,3-butylene glycol, propylene glycol, glycerin, sodium pyrrolidonecarboxylate, amino acid, vegetable oil and the like.
- thickener examples include xanthan gum, polyethylene glycol, hydroxyethyl cellulose and the like.
- solvent examples include water, ethanol, isopropyl alcohol, 1,3 butylene glycol, 2-methyl-2,4-pentanediol, glycerin, propylene glycol and the like.
- the hair dye of the present invention is a two-component hair dye composed of a first agent and a second agent, and performs hair dyeing by mixing the first agent and the second agent.
- the first agent contains a substance that develops color by reacting with iron
- the second agent is at least one selected from iron salts and xylitol, sorbitol, pentylene glycol, dipropylene glycol, triethylene glycol, erythritol, and diglycerin. Contains the above ingredients.
- the pH of the first agent is preferably pH 6 to 10, more preferably pH 7 to 9.
- the pH of the second agent is preferably pH 2 to 6, more preferably pH 3 to 5.
- the dosage form of the hair dye of the present invention can be, for example, a cream, liquid, gel, emulsion, spray, aerosol type, etc.
- the aerosol type is preferable. Aerosol can be produced by filling a pressure-resistant container with a hair dye (first agent or second agent), compressed gas, surfactant, thickener, liquefied gas, etc. in an anaerobic atmosphere. .
- a hair dye first agent or second agent
- compressed gas nitrogen, carbonic acid, argon and the like are preferable.
- the hair can be dyed by applying the hair dye of the present invention described above to the hair.
- the first agent may be applied first and allowed to stand for a certain period of time, then the second agent may be applied, left to stand for a certain period of time, and then washed off or used.
- the agent may be applied at the same time and allowed to stand for a certain period of time before being washed away.
- the amount of the hair dye of the present invention applied is preferably about 30 g to 70 g of the first agent and about 30 g to 70 g of the second agent on hair having a length of about 20 centimeters. It is more preferable to apply about 60 g and about 2 to 40 g of the second agent. As an example, 50 g of the first agent and 50 g of the second agent can be applied.
- Each hair dye composition having the composition shown in Tables 1 to 3 was produced by a conventional method.
- surface about each compound shows weight% with respect to the whole quantity of a 1st agent and a 2nd agent.
- the hair dyeing property was evaluated by the following method. The results are shown in Tables 1 to 3.
- the amounts of sodium hydroxide and hydrochloric acid are necessary for adjusting to the indicated pH.
- Hair dyeing method Apply 2g of each agent to 1g of a hair bundle of about 10cm in length (product number: manufactured by Beaulux Co., Ltd.), spread it uniformly, leave it for the indicated time, and then apply 2g each of the two agents. After extending uniformly, it was left for the indicated time. Thereafter, shampooing and rinsing were performed, and the hair bundle was dried with a dryer.
- Hair dyeing evaluation method The hair bundle that was dyed was measured with a CR200 type color difference meter manufactured by Minolta, and evaluated from the color difference ( ⁇ E value) with the original white hair according to the following criteria.
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Abstract
Description
好ましくは、(2)(b)に記載の成分は、キシリトール、ソルビトール、ペンチレングリコール及びジプロピレングリコールから選択される少なくとも一種以上の成分である。
好ましくは、(2)(b)に記載の成分はキシリトール、ソルビトールである。
好ましくは、鉄と反応して発色する物質の使用量が第1剤の全量に対し0.5~10重量%であり、鉄塩の使用量が第2剤の全量に対し0.5~10重量%である。
本発明の染毛剤は、(1)鉄と反応して発色する物質を含有する第1剤、及び(2)(a)鉄塩と(b)キシリトール、ソルビトール、ペンチレングリコール、ジプロピレングリコール、トリエチレングリコール、エリスリトール及びジグリセリンから選択される少なくとも一種以上の成分とを含有する第2剤を組み合わせて含む2剤式の染毛剤である。有機酸による鉄の反応コントロールは知られているが、染毛性自体を低下させてしまい、発色が悪くなる。本発明においては、キシリトール、ソルビトール、ペンチレングリコール、ジプロピレングリコール、トリエチレングリコール、エリスリトール及びジグリセリンから選択される多価アルコールと鉄塩との非常に弱い相互作用を利用することによって、反応性を適度にコントロールでき、かつ鉄塩の保存安定性も向上する。また、反応コントロールによって、毛髪内部まで染毛可能になり、シャンプー耐性が向上する。
鉄塩の使用量は、本発明の効果が得られる限り特に限定されないが、好ましくは第2剤の全量に対し0.5~10重量%であり、好ましくは1~6重量%である。
キシリトール、ソルビトール、ペンチレングリコール、ジプロピレングリコール、トリエチレングリコール、エリスリトール及びジグリセリンから選択される少なくとも一種以上の成分の使用量は、鉄塩に対して等モル以上第2剤の全量に対して20重量%以下である。
表1~3に示す組成の各染毛剤組成物を常法により製造した。各化合物についての表中の数値は、第1剤及び第2剤の全量に対する重量%を示す。これらの組成物について、次の方法により染毛性を評価した。結果を表1~3に示す。なお、水酸化ナトリム、塩酸の量は表示したpHに調整するための必要量である。
長さ約10センチのヤギ毛(品番:、ビューラックス社製)毛束1gに、一剤各2gを塗布し、均一にのばした後、表示した時間放置後、二剤各2gを塗布し、均一にのばした後、表示した時間放置した。その後、シャンプー及びリンス処理し、ドライヤーで毛束を乾燥させた。
染毛した毛束をミノルタ社製のCR200型色彩色差計で測色し、元の白髪との色差(ΔE値)から、下記基準で評価した。
◎:30<ΔE値(ヤギ毛が非常によく着色していることが目視でわかる)
○:20<ΔE値<30(ヤギ毛が着色していることが目視でわかる)
×:ΔE値<10(ヤギ毛がほとんど着色していないのが目視でわかる)
染毛した毛束をシャンプーおよびリンス処理し、ドライヤーで毛束を乾燥させたのち、ミノルタ社製のCR200型色彩色差計で測色し、元の毛束との色差(ΔE値)から、下記基準で評価した。
◎:ΔE値<3(色落ちが目視であまりわからない)
○:3<ΔE値<6(少し色落ちしていることが目視でわかる)
△:6<ΔE値<10(色落ちしていることが目視でわかる)
×:ΔE値>10
-:染毛性×のもの
二剤を経時したものを下記の基準で評価した。
◎:非常に安定性がよい
○:安定性がよい
×:安定性が悪い
Claims (8)
- (1)鉄と反応して発色する物質を含有する第1剤、及び(2)(a)鉄塩と(b)キシリトール、ソルビトール、ペンチレングリコール、ジプロピレングリコール、トリエチレングリコール、エリスリトール及びジグリセリンから選択される少なくとも一種以上の成分とを含有する第2剤を組み合わせて含む染毛剤。
- キシリトール、ソルビトール、ペンチレングリコール、ジプロピレングリコール、トリエチレングリコール、エリスリトール及びジグリセリンから選択される少なくとも一種以上の成分の添加量が鉄塩に対して等モル以上第2剤の全量に対して20重量%以下である、請求項1に記載の染毛剤。
- (2)(b)に記載の成分が、キシリトール、ソルビトール、ペンチレングリコール及びジプロピレングリコールから選択される少なくとも一種以上の成分である、請求項1又は2に記載の染毛剤。
- (2)(b)に記載の成分がキシリトール及びソルビトールから選択される少なくとも一種以上の成分である、請求項1から3の何れか1項に記載の染毛剤。
- 鉄と反応して発色する物質が、タンニン酸、没食子酸およびその誘導体、五倍子、ピロガロール、ログウッド、ヘマテイン、カテコール、サリチル酸およびその誘導体、フタル酸、オイゲノール、イソオイゲノール、ニコチン酸アミド、デヒドロ酢酸、ピリドキシン、エラグ酸、コウジ酸、マルトール、フェルラ酸、ヒノキチオール、ウコンエキス、クルクミン、オウゴンエキス、タマネギエキス、クエルセチン、ルチン、ヘスペレチン、ヘスペリジン、生コーヒー豆抽出物、カフェー酸、クロロゲン酸、チャエキス、カテキン、エピカテキン、シコンエキス、シソエキス、シソニン、ブドウ葉エキス、ブトウエキス、エノシアニン、ラッカイン酸、ラック、コチニール、カルミン酸、エルダーベリー、アカキャベツ、ムラサキイモ、タマリンド、コウリャン、アピゲニニジン、ルテオリニジン、及びオキシベンゾンからなる群から選択される少なくとも1種以上である、請求項1から4の何れか1項に記載の染毛剤。
- 鉄塩が、硫酸第一鉄、塩化第一鉄、酢酸第一鉄、硫酸第二鉄、塩酸第二鉄、又は酢酸第二鉄である、請求項1から5の何れか1項に記載の染毛剤。
- 鉄と反応して発色する物質の使用量が第1剤の全量に対し0.5~10重量%であり、鉄塩の使用量が第2剤の全量に対し0.5~10重量%である、請求項1から6の何れか1項に記載の染毛剤。
- 請求項1から7の何れか1項に記載の染毛剤を毛髪に付与することを含む、毛髪の染毛方法。
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
KR1020127025385A KR20130045247A (ko) | 2010-03-01 | 2011-02-28 | 염모제 |
US13/582,003 US8574316B2 (en) | 2010-03-01 | 2011-02-28 | Hair dye |
JP2012503127A JP5563060B2 (ja) | 2010-03-01 | 2011-02-28 | 染毛剤 |
CN201180011771.5A CN102781405B (zh) | 2010-03-01 | 2011-02-28 | 染发剂 |
EP11750601.4A EP2543355A4 (en) | 2010-03-01 | 2011-02-28 | Hair Dye |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010044021 | 2010-03-01 | ||
JP2010-044021 | 2010-03-01 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2011108491A1 true WO2011108491A1 (ja) | 2011-09-09 |
Family
ID=44542143
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2011/054513 WO2011108491A1 (ja) | 2010-03-01 | 2011-02-28 | 染毛剤 |
Country Status (6)
Country | Link |
---|---|
US (1) | US8574316B2 (ja) |
EP (1) | EP2543355A4 (ja) |
JP (1) | JP5563060B2 (ja) |
KR (1) | KR20130045247A (ja) |
CN (1) | CN102781405B (ja) |
WO (1) | WO2011108491A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2013064598A3 (en) * | 2011-11-04 | 2013-07-18 | Unilever Plc | Hair care composition |
WO2014002668A1 (ja) * | 2012-06-27 | 2014-01-03 | 富士フイルム株式会社 | 染毛剤組成物 |
JP2015105248A (ja) * | 2013-11-29 | 2015-06-08 | 富士フイルム株式会社 | 染毛剤 |
JP2015526449A (ja) * | 2012-08-24 | 2015-09-10 | ナチュラル・メディシン・インスティチュート・オブ・ジャージアン・ヤンシェンタン・カンパニー・リミテッド | 毛髪染料製品 |
WO2016047665A1 (ja) * | 2014-09-26 | 2016-03-31 | 富士フイルム株式会社 | 染毛剤及び染毛方法 |
US9539190B2 (en) | 2010-05-07 | 2017-01-10 | Conopco, Inc. | Skin conditioning compositions containing 12-hydroxystearic acid |
JP2019518722A (ja) * | 2016-04-22 | 2019-07-04 | ヴィトレック ビー.ヴィー.Vitreq B.V. | 眼科用染料組成物 |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2014139153A1 (zh) * | 2013-03-15 | 2014-09-18 | 北京世纪博康医药科技有限公司 | 一种染发用组合物及其应用 |
WO2015004275A1 (en) * | 2013-07-11 | 2015-01-15 | Chr. Hansen A/S | Color composition comprising carmine pigment and ferrous ions |
CN106491431B (zh) * | 2016-11-21 | 2019-07-02 | 福建泉州飞扬生物科技有限公司 | 一种天然植物染发剂 |
CN114699350A (zh) * | 2022-04-08 | 2022-07-05 | 南京斯拜科生物科技股份有限公司 | 一种石榴皮提取物为原料的染发剂及其制备方法 |
CN114699351A (zh) * | 2022-04-15 | 2022-07-05 | 南京斯拜科生物科技股份有限公司 | 一种以茶叶提取物为原料的天然染发剂及其制备方法 |
KR20230159026A (ko) * | 2022-05-13 | 2023-11-21 | 한국교통대학교산학협력단 | 단계적 헤어 컬러 조성물 및 이를 포함하는 화장료 조성물 |
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- 2011-02-28 WO PCT/JP2011/054513 patent/WO2011108491A1/ja active Application Filing
- 2011-02-28 EP EP11750601.4A patent/EP2543355A4/en not_active Withdrawn
- 2011-02-28 CN CN201180011771.5A patent/CN102781405B/zh not_active Expired - Fee Related
- 2011-02-28 US US13/582,003 patent/US8574316B2/en not_active Expired - Fee Related
- 2011-02-28 JP JP2012503127A patent/JP5563060B2/ja not_active Expired - Fee Related
- 2011-02-28 KR KR1020127025385A patent/KR20130045247A/ko not_active Application Discontinuation
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9539190B2 (en) | 2010-05-07 | 2017-01-10 | Conopco, Inc. | Skin conditioning compositions containing 12-hydroxystearic acid |
WO2013064598A3 (en) * | 2011-11-04 | 2013-07-18 | Unilever Plc | Hair care composition |
WO2014002668A1 (ja) * | 2012-06-27 | 2014-01-03 | 富士フイルム株式会社 | 染毛剤組成物 |
JP2015526449A (ja) * | 2012-08-24 | 2015-09-10 | ナチュラル・メディシン・インスティチュート・オブ・ジャージアン・ヤンシェンタン・カンパニー・リミテッド | 毛髪染料製品 |
JP2015105248A (ja) * | 2013-11-29 | 2015-06-08 | 富士フイルム株式会社 | 染毛剤 |
WO2016047665A1 (ja) * | 2014-09-26 | 2016-03-31 | 富士フイルム株式会社 | 染毛剤及び染毛方法 |
JP2019518722A (ja) * | 2016-04-22 | 2019-07-04 | ヴィトレック ビー.ヴィー.Vitreq B.V. | 眼科用染料組成物 |
JP7042751B2 (ja) | 2016-04-22 | 2022-03-28 | ヴィトレック ビー.ヴィー. | 眼科用染料組成物 |
Also Published As
Publication number | Publication date |
---|---|
US8574316B2 (en) | 2013-11-05 |
US20130047349A1 (en) | 2013-02-28 |
CN102781405B (zh) | 2015-03-18 |
JPWO2011108491A1 (ja) | 2013-06-27 |
KR20130045247A (ko) | 2013-05-03 |
EP2543355A4 (en) | 2014-01-08 |
CN102781405A (zh) | 2012-11-14 |
JP5563060B2 (ja) | 2014-07-30 |
EP2543355A1 (en) | 2013-01-09 |
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