WO2011096070A1 - 非水電解質二次電池用電極体、及び、非水電解質二次電池 - Google Patents
非水電解質二次電池用電極体、及び、非水電解質二次電池 Download PDFInfo
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- WO2011096070A1 WO2011096070A1 PCT/JP2010/051718 JP2010051718W WO2011096070A1 WO 2011096070 A1 WO2011096070 A1 WO 2011096070A1 JP 2010051718 W JP2010051718 W JP 2010051718W WO 2011096070 A1 WO2011096070 A1 WO 2011096070A1
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/463—Separators, membranes or diaphragms characterised by their shape
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
- H01M10/0587—Construction or manufacture of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/403—Manufacturing processes of separators, membranes or diaphragms
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/46—Separators, membranes or diaphragms characterised by their combination with electrodes
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/463—Separators, membranes or diaphragms characterised by their shape
- H01M50/466—U-shaped, bag-shaped or folded
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Definitions
- the present invention relates to an electrode body for a non-aqueous electrolyte secondary battery and a non-aqueous electrolyte secondary battery using the same.
- Nonaqueous electrolyte secondary batteries such as lithium ion secondary batteries are attracting attention as power sources for portable devices and as driving power sources for vehicles such as electric vehicles and hybrid vehicles.
- a non-aqueous electrolyte secondary battery an electrode body having a positive electrode plate, a negative electrode plate, and a separator interposed between the positive electrode plate and the negative electrode plate, the positive electrode plate, the negative electrode plate, and the separator, Non-aqueous electrolyte secondary batteries having electrode bodies that overlap each other in the width direction are known (see, for example, Patent Documents 1 to 3).
- the battery may generate heat due to overcharge or the like, resulting in a high temperature, which may cause the separator to thermally shrink in the width direction.
- the separator is thermally contracted in the width direction, there is no possibility that the separator is interposed between the positive electrode plate and the negative electrode plate at the position in the width direction end, and the positive electrode plate and the negative electrode plate may come into contact with each other to cause a short circuit.
- the internal short circuit may promote the heat generation of the battery.
- Patent Document 1 discloses the following nonaqueous electrolyte secondary battery.
- a positive electrode plate, a negative electrode plate, and a separator wider than these electrode plates the width direction end of the separator (the first end located on one end side in the width direction and the first end located on the other end side)
- the wound electrode body is wound by winding the positive electrode plate, the negative electrode plate, and the separator so that the two end portions protrude outward from one end side (upper end side) and the other end side (lower end side) of the electrode body.
- the excess ends (the first end and the second end of the separator) of the separator projecting outward from one end (upper end) and the other end (lower end) of the wound electrode body are heated.
- Patent Document 2 discloses the following nonaqueous electrolyte secondary battery.
- the battery includes a positive electrode plate coated with a positive electrode mixture layer on a surface of a positive electrode current collector (aluminum foil), a negative electrode plate coated with a negative electrode mixture layer on a surface of a negative electrode current collector (copper foil), A separator having a width wider than those of the electrode plates is used, and an end of the separator in the width direction (a first end located on one end side and a second end located on the other end side in the width direction) is an electrode body.
- a wound electrode body is provided in which a positive electrode plate, a negative electrode plate, and a separator are wound so as to protrude outward from one end side and the other end side.
- an insulating film in which powder (alumina or the like) having heat resistance of 500 ° C. or higher is bound with a binder resin is fixed to both ends in the width direction of the positive electrode plate. Furthermore, an insulating film in which a powder (alumina or the like) having heat resistance of 500 ° C. or higher is bound with a binder resin is also fixed to both ends in the width direction of the negative electrode plate.
- the 1st end part (end part located in the one end side about the width direction) of a separator is made into the positive electrode one end part (width direction among positive electrode plates) about the width direction.
- the second end of the separator (the end located on the other end side in the width direction) is arranged in the width direction with the other end of the negative electrode (negative electrode plate).
- the winding electrode body is provided on the inner side of the other end portion in the width direction. In other words, in the width direction, one end of the positive electrode is disposed outside the first end of the separator, and the other end of the negative electrode is disposed outside the second end of the separator.
- a rotating electrode body is provided.
- One end of the positive electrode is constituted by a positive electrode uncoated part (part) of the positive electrode plate to which the positive electrode mixture layer is not coated, and the positive electrode one end is welded to the positive electrode terminal member.
- the plate and the positive electrode terminal member are electrically connected.
- the negative electrode other end portion is constituted by a negative electrode uncoated portion (part thereof) of the negative electrode plate to which the negative electrode mixture layer is not coated, and the negative electrode other end portion is welded to the negative electrode terminal member. And the negative electrode terminal member are electrically connected.
- the present invention has been made in view of such a situation, and “the separator is thermally contracted in the width direction, so that the positive electrode plate and the negative electrode plate are short-circuited at the position of the end in the width direction.
- An object of the present invention is to provide a non-aqueous electrolyte secondary battery electrode body and a non-aqueous electrolyte secondary battery capable of preventing “problems”.
- One embodiment of the present invention includes a positive electrode plate, a negative electrode plate, and a separator interposed between the positive electrode plate and the negative electrode plate.
- the positive electrode plate, the negative electrode plate, and the separator are respectively An electrode body for a non-aqueous electrolyte secondary battery that overlaps in the width direction, wherein the positive electrode plate has a positive electrode current collector and a positive electrode mixture layer coated on the surface thereof, and The negative electrode plate has a negative electrode current collecting member and a negative electrode mixture layer coated on the surface thereof, and the separator has a first end located on one end side and the other end in the width direction.
- a second end portion located on the side, and an intermediate portion located between the first end portion and the second end portion, and the first end portion of the separator is Of the positive electrode plate, the positive electrode is located on the inner side of one end of the positive electrode located on one end side in the width direction.
- the second end of the separator is positioned on the other end side in the width direction of the negative electrode plate in the width direction with respect to the width direction. It is located inside the end, located outside the other end of the positive electrode coating part, and located outside the other end of the negative electrode coating part, and is thicker than the thickness of the intermediate part.
- the separator has a first end located on one end side, a second end located on the other end side, and a first end in the width direction. And an intermediate portion located between the second end portion.
- the 1st end part of a separator is located inside the positive electrode one end part located in the one end side about the width direction among positive electrode plates about the width direction.
- the one end of the positive electrode is located outside the first end of the separator in the width direction.
- This one end of the positive electrode is constituted by, for example, a positive electrode uncoated portion (a part thereof) of the positive electrode plate to which the positive electrode mixture layer is not applied.
- the positive electrode plate and the positive electrode terminal member can be electrically connected by welding one end of the positive electrode to the positive electrode terminal member.
- the second end portion of the separator is located on the inner side of the other end portion of the negative electrode located on the other end side in the width direction of the negative electrode plate in the width direction.
- the other end of the negative electrode is located outside the second end of the separator in the width direction.
- the other end of the negative electrode is constituted by, for example, a negative electrode uncoated portion (a part thereof) of the negative electrode plate to which the negative electrode mixture layer is not applied.
- the negative electrode plate and the negative electrode terminal member can be electrically connected by welding the other negative electrode end to the negative electrode terminal member.
- the first end portion of the separator is located outside the one end of the positive electrode coating portion on which the positive electrode mixture layer is coated in the positive electrode plate in the width direction, and the negative electrode mixture in the negative electrode plate. It is located on the outer side of one end of the negative electrode coating portion to which the layer is applied (corresponding to one end of the negative electrode plate). Moreover, the first end portion of the separator is thicker than the thickness of the intermediate portion.
- the second end portion of the separator is located outside the other end of the positive electrode coating portion (corresponding to the other end of the positive electrode plate) in the width direction and outside the other end of the negative electrode coating portion. Is located. Moreover, the second end portion of the separator is thicker than the thickness of the intermediate portion.
- the positive electrode plate and the negative electrode plate are in contact at the position of the end in the width direction due to the thermal contraction of the separator in the width direction. Can be prevented.
- the separator is thermally contracted in the width direction, the first end of the separator moves inward in the width direction (moves toward the other end), and the second end is inward in the width direction.
- the first end of the separator is the positive electrode. It strikes at least one end face of one end of the coating part and one end of the negative electrode coating part, and cannot move further inward in the width direction (move to the other end side).
- the second end portion of the separator hits at least one end face of the other end of the positive electrode coating portion and the other end of the negative electrode coating portion, and can move further inward in the width direction (move toward one end side). Disappear.
- the state which interposed the separator between the positive electrode plate and the negative electrode plate is hold
- first end portion and the second end portion of the separator are thicker than the thickness of the intermediate portion
- first end portion and the second end portion of the separator are folded (for example, folded twice).
- there is a form that is thicker than the thickness of the intermediate portion for example, twice the thickness of the intermediate portion.
- Another aspect of the present invention includes a positive electrode plate, a negative electrode plate, and a separator interposed between the positive electrode plate and the negative electrode plate, wherein the positive electrode plate, the negative electrode plate, and the separator are respectively An electrode body for a non-aqueous electrolyte secondary battery that overlaps with each other in the width direction, wherein the positive electrode plate has a positive electrode current collecting member and a positive electrode mixture layer coated on the surface thereof,
- the negative electrode plate includes a negative electrode current collecting member and a negative electrode mixture layer coated on a surface thereof, and the separator has a first end portion located on one end side in the width direction, and the other A second end portion located on the end side, and an intermediate portion located between the first end portion and the second end portion, the first end portion of the separator is about the width direction,
- the positive electrode plate is located on the inner side of one end of the positive electrode located on one end side in the width direction, and the positive plate One of the negative electrode coated portions of the negative electrode plate that is located outside the one end of
- the first end portion of the separator is located inside the positive electrode one end portion located on one end side in the width direction of the positive electrode plate in the width direction. .
- the one end of the positive electrode is located outside the first end of the separator in the width direction.
- This one end of the positive electrode is constituted by, for example, a positive electrode uncoated portion (a part thereof) of the positive electrode plate to which the positive electrode mixture layer is not applied.
- the positive electrode plate and the positive electrode terminal member can be electrically connected by welding one end of the positive electrode to the positive electrode terminal member.
- the second end portion of the separator is located on the inner side of the other end portion of the negative electrode located on the other end side in the width direction of the negative electrode plate in the width direction.
- the other end of the negative electrode is located outside the second end of the separator in the width direction.
- the other end of the negative electrode is constituted by, for example, a negative electrode uncoated portion (a part thereof) of the negative electrode plate to which the negative electrode mixture layer is not applied.
- the negative electrode plate and the negative electrode terminal member can be electrically connected by welding the other negative electrode end to the negative electrode terminal member.
- the first end portion of the separator is located outside the one end of the positive electrode coating portion on which the positive electrode mixture layer is coated in the positive electrode plate in the width direction, and the negative electrode mixture in the negative electrode plate. It is located on the outer side of one end of the negative electrode coating portion to which the layer is applied (corresponding to one end of the negative electrode plate). Moreover, the first end of the separator is previously heat-shrinked by heating (in the process of manufacturing the electrode body, the first end of the separator is heat-shrinked by heating).
- the second end portion of the separator is located outside the other end of the positive electrode coating portion (corresponding to the other end of the positive electrode plate) in the width direction and outside the other end of the negative electrode coating portion. Is located.
- the second end of the separator is previously heat-shrinked by heating (in the process of manufacturing the electrode body, the first end of the separator is heat-shrinked by heating).
- the positive electrode plate and the negative electrode plate are in contact at the position of the end in the width direction due to the thermal contraction of the separator in the width direction. Can be prevented. Specifically, even if the temperature of the separator heat-shrinks in the width direction due to the heat generated by the battery, the first end and the second end of the separator are preliminarily heat-shrinked by heating. Does not heat shrink in the width direction. Thereby, about the width direction, the state which interposed the separator between the positive electrode plate and the negative electrode plate can be maintained, and the electrical insulation of a positive electrode plate and a negative electrode plate can be maintained.
- another aspect of the present invention includes a positive electrode plate, a negative electrode plate, and a separator interposed between the positive electrode plate and the negative electrode plate, wherein the positive electrode plate, the negative electrode plate, and the separator are An electrode body for a non-aqueous electrolyte secondary battery that overlaps with each other in the width direction, and the positive electrode plate has a positive electrode current collector and a positive electrode mixture layer coated on the surface thereof.
- the negative electrode plate includes a negative electrode current collecting member and a negative electrode mixture layer coated on a surface thereof, and the separator includes a first end portion located on one end side in the width direction.
- the positive electrode plate With respect to the positive electrode plate, the positive electrode plate is located on the inner side of the positive electrode one end portion in the width direction.
- the negative electrode coating part which is located outside one end of the positive electrode coating part to which the positive electrode mixture layer is coated in the positive electrode plate and to which the negative electrode mixture layer is coated in the negative electrode plate.
- the second end portion of the separator is in the width direction with respect to the width direction of the positive electrode plate.
- the second end portion of the separator is in the width direction with respect to the width direction of the negative electrode plate.
- the first end portion of the separator is located inside the positive electrode one end portion located on one end side in the width direction of the positive electrode plate in the width direction. .
- the one end of the positive electrode is located outside the first end of the separator in the width direction.
- This one end of the positive electrode is constituted by, for example, a positive electrode uncoated portion (a part thereof) of the positive electrode plate to which the positive electrode mixture layer is not applied.
- the positive electrode plate and the positive electrode terminal member can be electrically connected by welding one end of the positive electrode to the positive electrode terminal member.
- the second end portion of the separator is located on the inner side of the other end portion of the negative electrode located on the other end side in the width direction of the negative electrode plate in the width direction.
- the other end of the negative electrode is located outside the second end of the separator in the width direction.
- the other end of the negative electrode is constituted by, for example, a negative electrode uncoated portion (a part thereof) of the negative electrode plate to which the negative electrode mixture layer is not applied.
- the negative electrode plate and the negative electrode terminal member can be electrically connected by welding the other negative electrode end to the negative electrode terminal member.
- the first end portion of the separator is located outside the one end of the positive electrode coating portion on which the positive electrode mixture layer is coated in the positive electrode plate in the width direction, and the negative electrode mixture in the negative electrode plate. It is located on the outer side of one end of the negative electrode coating portion to which the layer is applied (corresponding to one end of the negative electrode plate).
- the first end of the separator is thermally welded to a portion of the positive electrode plate facing the separator in the thickness direction (in the process of manufacturing the electrode body, the first end of the separator is connected to the positive electrode plate). Of these, heat-welding is performed on the part facing the separator in the thickness direction).
- the second end portion of the separator is located outside the other end of the positive electrode coating portion (corresponding to the other end of the positive electrode plate) in the width direction and outside the other end of the negative electrode coating portion. Is located. Moreover, the second end of the separator is thermally welded to a portion of the negative electrode plate facing the separator in the thickness direction (in the process of manufacturing the electrode body, the second end of the separator is attached to the negative electrode plate). Of these, heat-welding is performed on the part facing the separator in the thickness direction).
- the positive electrode plate and the negative electrode plate are in contact at the position of the end in the width direction due to the thermal contraction of the separator in the width direction. Can be prevented.
- the first end and the second end of the separator have already been heat-shrinked by heating during heat welding. Further, it is difficult to heat shrink in the width direction.
- the first end and the second end of the separator are bonded (welded) to the opposing portions of the positive electrode plate and the negative electrode plate, the first end and the second end of the separator are widened by heat shrinkage. Even when trying to move inward in the direction, it is possible to prevent the first end and the second end of the separator from moving inward in the width direction. Thereby, about the width direction, the state which interposed the separator between the positive electrode plate and the negative electrode plate can be maintained, and the electrical insulation of a positive electrode plate and a negative electrode plate can be maintained.
- the portion of the positive electrode plate where the first end of the separator is thermally welded is the positive electrode mixture layer of the positive electrode plate. It is at least part of the uncoated positive electrode uncoated portion, and the portion of the negative electrode plate where the second end of the separator is thermally welded is the negative electrode mixture layer of the negative electrode plate.
- a non-aqueous electrolyte secondary battery electrode body that is at least a part of the uncoated negative electrode uncoated portion is preferable.
- the portion of the positive electrode plate where the first end of the separator is thermally welded is not coated with the positive electrode mixture layer of the positive electrode plate. Part (part where the positive electrode current collecting member is exposed).
- the first end portion of the separator is thermally welded to the positive electrode uncoated portion (at least a part thereof) of the positive electrode plate where the positive electrode mixture layer is not applied.
- the 1st edge part of a separator can be appropriately adhere
- the portion of the negative electrode plate where the second end of the separator is thermally welded is the negative electrode not coated with the negative electrode mixture layer of the negative electrode plate. It is at least a part of the coating part (part where the negative electrode current collecting member is exposed).
- the second end portion of the separator is thermally welded to the negative electrode uncoated portion (at least a part thereof) of the negative electrode plate to which the negative electrode mixture layer is not applied. Thereby, the 2nd edge part of a separator can be appropriately adhere
- another aspect of the present invention is a nonaqueous electrolyte secondary battery comprising any one of the above electrode bodies for a nonaqueous electrolyte secondary battery.
- the non-aqueous electrolyte secondary battery described above includes any of the electrode bodies for non-aqueous electrolyte secondary batteries described above. For this reason, in the above-described nonaqueous electrolyte secondary battery, “the problem that the positive electrode plate and the negative electrode plate are short-circuited at the position of the end in the width direction due to the thermal contraction of the separator in the width direction”. Can be prevented.
- FIG. 3 is a top view of a nonaqueous electrolyte secondary battery according to Examples 1 to 3.
- FIG. It is a front view of the same nonaqueous electrolyte secondary battery.
- FIG. 2 is a longitudinal sectional view of the same nonaqueous electrolyte secondary battery and corresponds to a sectional view taken along the line CC in FIG.
- FIG. 2 is a longitudinal sectional view of the nonaqueous electrolyte secondary battery and corresponds to a sectional view taken along the line DD in FIG.
- FIG. 3 is a cross-sectional view of the electrode body of Example 1, and corresponds to a cross-sectional view taken along the line EE in FIG.
- FIG. 3 is a top view of a positive electrode plate according to Examples 1 to 3.
- FIG. FIG. 8 is a cross-sectional view of the positive electrode plate and corresponds to a cross-sectional view taken along the line FF in FIG. 7.
- 3 is a top view of a negative electrode plate according to Examples 1 to 3.
- FIG. 10 is a cross-sectional view of the negative electrode plate and corresponds to a cross-sectional view taken along the line GG in FIG. 9.
- 2 is a top view of the separator of Example 1.
- FIG. FIG. 12 is a cross-sectional view of the separator, and corresponds to a cross-sectional view taken along line HH in FIG. 11.
- FIG. 5 is a diagram illustrating a process for manufacturing the electrode body of Example 1.
- FIG. 6 is a cross-sectional view of the electrode body of Example 2, and corresponds to a cross-sectional view taken along the line EE of FIG. 6 is a top view of a separator of Example 2.
- FIG. 6 is a diagram illustrating a heat treatment process of Example 2.
- FIG. It is a figure explaining the process of manufacturing the electrode body of Example 2.
- FIG. 6 is a transverse cross-sectional view of an electrode body of Example 3, and corresponds to a cross-sectional view taken along the line EE in FIG. 6 is a diagram illustrating a process of manufacturing an electrode body of Example 3.
- the nonaqueous electrolyte secondary battery 100 includes a rectangular sealed battery case 110 including a rectangular parallelepiped battery case 110, a positive electrode terminal member 120, and a negative electrode terminal member 130. It is a lithium ion secondary battery.
- the battery case 110 is a hard case having a metal rectangular housing part 111 and a metal lid part 112 forming a rectangular parallelepiped housing space.
- An electrode body 150 and the like are disposed inside the battery case 110 (the square housing part 111).
- the rated capacity (nominal capacity) of the nonaqueous electrolyte secondary battery 100 is 5.5 Ah.
- the electrode body 150 is an oblong cross section, and is a flat wound body in which the positive electrode plate 155, the negative electrode plate 156, and the separator 157 are wound into a flat shape (see FIGS. 4 to 13).
- the positive electrode plate 155, the negative electrode plate 156, and the separator 157 are overlapped with each other in the same width direction (see FIGS. 6 and 13).
- the longitudinal direction (direction orthogonal to the width direction) of the positive electrode plate 155, the negative electrode plate 156, and the separator 157 coincides with the winding direction. 6 and 13 coincide with the respective width directions of the positive electrode plate 155, the negative electrode plate 156, and the separator 157, and also coincide with the width direction of the electrode body 150.
- the positive electrode plate 155 has a belt-like shape, and includes a positive electrode current collecting member 151 made of an aluminum foil, and a positive electrode mixture layer 152 (a mixture layer including the positive electrode active material 153) coated on the surface (both sides). (See FIGS. 7 and 8).
- a positive electrode coating portion 155d in which the positive electrode mixture layer 152 is applied to the surface of the positive electrode current collector 151, and the positive electrode mixture layer 152 is not applied to the surface of the positive electrode current collector 151.
- the positive electrode uncoated portion 155b is composed of only the positive electrode current collecting member 151, is located on one end side (the right end side in FIGS.
- the negative electrode plate 156 has a strip shape and has a negative electrode current collecting member 158 made of copper foil and a negative electrode mixture layer 159 (a mixture layer containing the negative electrode active material 154) coated on the surface thereof (FIG. 9, see FIG.
- the negative electrode plate 156 includes a negative electrode coating portion 156d in which a negative electrode mixture layer 159 is applied to the surface of the negative electrode current collector 158, and a negative electrode mixture layer 159 that is not applied to the surface of the negative electrode collector member 158.
- the negative electrode uncoated portion 156b is composed of only the negative electrode current collecting member 158, and is located on the other end side (left end side in FIGS.
- FIGS. 9 and 10 in the width direction of the negative electrode plate 156 and extends in the longitudinal direction of the negative electrode plate 156. Yes.
- the horizontal direction in FIGS. 9 and 10 matches the width direction of the negative electrode plate 156.
- 9 corresponds to the longitudinal direction of the negative electrode plate 156.
- the vertical direction of FIG. 10 corresponds to the thickness direction of the negative electrode plate 156.
- the separator 157 is made of a polypropylene / polyethylene / polypropylene three-layer composite porous sheet and has a strip shape (see FIGS. 11 and 12).
- the separator 157 is interposed between the positive electrode plate 155 and the negative electrode plate 156 to electrically insulate between the two electrode plates (see FIG. 6).
- the left-right direction in FIGS. 11 and 12 matches the width direction of the separator 157.
- 9 corresponds to the longitudinal direction of the negative electrode plate 156.
- the vertical direction of FIG. 10 corresponds to the thickness direction of the negative electrode plate 156.
- the separator 157 has, in the width direction, a first end 157b located on one end side (right end side in FIGS. 11 and 12) and a second end located on the other end side (left end side in FIGS. 11 and 12). Part 157c, and intermediate part 157d located between first end part 157b and second end part 157c.
- the first end 157b of the separator 157 has one end side in the width direction of the positive electrode plate 155 in the width direction (left-right direction in FIG. 6) ( It is located on the inner side (center side of the electrode body 150 in the width direction) than the positive electrode one end 155c located on the right end side in FIG. In other words, the positive electrode one end portion 155c is located outside the first end portion 157b of the separator 157 in the width direction (the side far from the center of the electrode body 150 in the width direction).
- the positive electrode one end portion 155c is constituted by a positive electrode uncoated portion 155b (a part thereof) of the positive electrode plate 155. For this reason, as will be described later, the positive electrode plate 155 and the positive electrode terminal member 120 can be electrically connected by welding the positive electrode one end portion 155c to the positive electrode current collector 122 of the positive electrode terminal member 120 (FIG. 3).
- the second end 157c of the separator 157 is from the other end 156c of the negative electrode located on the other end side (left end side in FIG. 6) in the width direction of the negative electrode plate 156 in the width direction (left-right direction in FIG. 6). Is also located on the inner side (center side of the electrode body 150 in the width direction). In other words, the other end 156c of the negative electrode is located outside the second end 157c of the separator 157 in the width direction (the side far from the center of the electrode body 150 in the width direction).
- the other end 156c of the negative electrode is constituted by a negative electrode uncoated portion 156b (a part thereof) of the negative electrode plate 156. For this reason, as will be described later, the negative electrode plate 156 and the negative electrode terminal member 130 can be electrically connected by welding the negative electrode other end 156c to the negative electrode current collector 132 of the negative electrode terminal member 130 (FIG. 3).
- the first end 157b of the separator 157 is in the width direction (left-right direction in FIG. 6) of the positive electrode coating portion 155d of the positive electrode plate 155. It is located outside the one end 155f (right side in FIG. 6) and outside the one end 156f (corresponding to one end of the negative electrode plate 156) of the negative electrode coating portion 156d of the negative electrode plate 156 (right side in FIG. 6). ). Moreover, the first end portion 157b of the separator 157 is thicker than the intermediate portion 157d (see FIGS. 6 and 12). Specifically, the first end 157b of the separator 157 is double-folded to be thicker than the intermediate portion 157d (twice as thick as the intermediate portion 157d).
- the second end 157c of the separator 157 is outside the other end 155g of the positive electrode coating portion 155d of the positive electrode plate 155 (corresponding to the other end of the positive electrode plate 155) in the width direction (left-right direction in FIG. 6). (Left side in FIG. 6) and located outside (on the left side in FIG. 6) the other end 156 g of the negative electrode coating portion 156 d of the negative electrode plate 156.
- the second end 157c of the separator 157 is thicker than the intermediate portion 157d (see FIGS. 6 and 12). Specifically, the second end portion 157c of the separator 157 is double-folded to be thicker than the intermediate portion 157d (twice as thick as the intermediate portion 157d).
- the nonaqueous electrolyte secondary battery 100 of the first embodiment includes the electrode body 150 as described above, “because the separator 157 is thermally contracted in the width direction (left and right direction in FIG. 6), It is possible to prevent a problem that the positive electrode plate 155 and the negative electrode plate 156 come into contact with each other at a position in the width direction end portion (left and right end portions of the positive electrode coating portion 155d and the negative electrode coating portion 156d in FIG. 6). .
- the resin separator 157 is thermally contracted in the width direction.
- the first end 157b of the separator 157 attempts to move inward in the width direction (moves leftward in FIG. 6), and the second end 157c moves inward in the width direction (rightward in FIG. 6). Try to move).
- the first end 157b and the second end 157c are thicker than the thickness of the intermediate portion 157d, so the first end 157b of the separator 157 is the positive electrode coating portion. It hits the end face of one end 155f of 155d or one end 156f of the negative electrode coating portion 156d and cannot move further inward in the width direction (left side in FIG. 6). As a result, “the first end portion 157b of the separator 157 enters between the positive electrode plate 155 (positive electrode coating portion 155d) and the negative electrode plate 156 (negative electrode coating portion 156d), and one end of the positive electrode coating portion 155d.
- the second end 157c of the separator 157 abuts against the end surface of the other end 155g of the positive electrode coating portion 155d or the other end 156g of the negative electrode coating portion 156d and can move further inward in the width direction (right side in FIG. 6). Disappear.
- the second end 157c of the separator 157 enters between the positive electrode plate 155 (positive electrode coating portion 155d) and the negative electrode plate 156 (negative electrode coating portion 156d), and the other end of the positive electrode coating portion 155d.
- the 2nd end part 157c which folded the separator 157 twice is softened with heat
- the width direction of the electrode body 150 (the left-right direction in FIG. 6).
- the state in which the separator is interposed between the positive electrode plate 155 and the negative electrode plate 156 can be maintained, and the electrical insulation between the positive electrode plate 155 and the negative electrode plate 156 can be maintained.
- a method for manufacturing the nonaqueous electrolyte secondary battery 100 will be described.
- a positive electrode plate 155 in which a positive electrode mixture layer 152 is coated on the surface of a strip-shaped positive electrode current collecting member 151 is prepared.
- a negative electrode plate 156 in which a negative electrode mixture layer 159 is coated on the surface of a strip-shaped negative electrode current collecting member 158 is prepared.
- both end portions in the width direction are folded twice so as to be thicker than the thickness of the intermediate portion 157d (the intermediate portion 157d).
- a separator 157 having a double thickness) is prepared.
- the positive electrode plate 155, the negative electrode plate 156, and the separator 157 are overlapped and wound into a flat shape to form the electrode body 150 (see FIG. 5).
- the first end 157b of the separator 157 is located on the inner side (left side in FIG. 13) of the positive electrode one end 155c of the positive electrode plate 155 in the width direction (left-right direction in FIG. 13), and the positive electrode of the positive electrode plate 155 It is located on the outer side (right side in FIG. 13) of one end 155f of the coating part 155d, and is located on the outer side (right side in FIG. 13) of one end 156f of the negative electrode coating part 156d of the negative electrode plate 156.
- the second end 157c of the separator 157 is located on the inner side (right side in FIG. 13) of the negative electrode other end 156c of the negative electrode plate 156 in the width direction, and the other end 155g of the positive electrode coating portion 155d of the positive electrode plate 155. Is located on the outer side (left side in FIG. 13) and on the outer side (left side in FIG. 13) of the other end 156g of the negative electrode coating portion 156d of the negative electrode plate 156. As to positive electrode plate 155, the negative electrode plate 156, and wound by placing the separator 157.
- the positive electrode current collector 122 of the positive electrode terminal member 120 is welded to the upper end of the positive electrode one end 155c of the electrode body 150 (see FIG. 3). Further, the negative electrode current collector 132 of the negative electrode terminal member 130 is welded to the upper end of the negative electrode other end 156 c of the electrode body 150. Thereafter, the electrode body 150 is accommodated in the rectangular accommodating portion 111 and the opening of the rectangular accommodating portion 111 is closed by the lid portion 112. Next, the lid portion 112 and the square housing portion 111 are welded.
- a non-aqueous electrolyte is injected into the rectangular container 111 from a liquid injection port (not shown) formed in the lid 112 (at this time, the electrode body 150 is impregnated with the non-aqueous electrolyte). Thereafter, the liquid injection port is sealed, and the nonaqueous electrolyte secondary battery 100 of Example 1 is completed.
- the nonaqueous electrolyte secondary battery 200 of the second embodiment is different from the nonaqueous electrolyte secondary battery 100 of the first embodiment only in the separator of the electrode body, and the other is the same. Therefore, here, the description will focus on the points different from the first embodiment, and the description of the same points will be omitted or simplified.
- the separator 257 of Example 2 is made of a porous sheet of polypropylene / polyethylene / polypropylene three-layer structure, as in Example 1, and has a strip shape (see FIG. 15).
- the separator 257 is positioned on the first end 257b (hatched portion in FIG. 15) located on one end side (right end side in FIG. 15) and on the other end side (left end side in FIG. 15) in the width direction. It has the 2nd end part 257c (the hatched part in FIG. 15), and the intermediate part 257d located between the 1st end part 257b and the 2nd end part 257c.
- the left-right direction in FIG. 15 matches the width direction of the separator 157
- the up-down direction in FIG. 15 matches the longitudinal direction of the separator 157.
- the first end 257 b of the separator 257 has one end side in the width direction of the positive electrode plate 155 in the width direction (left-right direction in FIG. 14). It is located on the inner side (left side in FIG. 14) of the positive electrode one end 155c located on the right end side in FIG. In other words, the positive electrode one end 155c is located on the outer side (right side in FIG. 14) than the first end 257b of the separator 257 in the width direction.
- the positive electrode one end portion 155c is constituted by a positive electrode uncoated portion 155b (a part thereof) of the positive electrode plate 155.
- the positive electrode plate 155 and the positive electrode terminal member 120 can be electrically connected by welding the positive electrode one end part 155c to the positive electrode current collecting part 122 of the positive electrode terminal member 120 ( (See FIG. 3).
- the second end portion 257c of the separator 257 is from the negative electrode other end portion 156c located on the other end side (left end side in FIG. 14) in the width direction of the negative electrode plate 156 in the width direction (left-right direction in FIG. 14). Is also located on the inner side (center side of the electrode body 250 in the width direction).
- the other end 156c of the negative electrode is positioned outside the second end 257c of the separator 257 in the width direction (the side far from the center of the electrode body 250 in the width direction).
- the other end 156c of the negative electrode is constituted by a negative electrode uncoated portion 156b (a part thereof) of the negative electrode plate 156.
- the negative electrode plate 156 and the negative electrode terminal member 130 can be electrically connected by welding the negative electrode other end part 156c to the negative electrode current collecting part 132 of the negative electrode terminal member 130 ( (See FIG. 3).
- the first end portion 257b of the separator 257 is in the width direction (left and right direction in FIG. 14) of the positive electrode coating portion 155d of the positive electrode plate 155. It is located outside the one end 155f (right side in FIG. 14) and outside the one end 156f (corresponding to one end of the negative electrode plate 156) of the negative electrode coating portion 156d of the negative electrode plate 156 (right side in FIG. 14). ).
- the first end portion 257b of the separator 257 is thermally contracted by heating in advance. Specifically, as described later, in the process of manufacturing the electrode body 250 (heat treatment process), the first end portion 257b of the separator 250 is heated to 200 ° C. and thermally contracted.
- the second end portion 257c of the separator 257 is outside the other end 155g of the positive electrode coating portion 155d of the positive electrode plate 155 (corresponding to the other end of the positive electrode plate 155) in the width direction (left-right direction in FIG. 14). 14 (on the left side in FIG. 14), and located outside the other end 156g of the negative electrode coating portion 156d of the negative electrode plate 156 (on the left side in FIG. 14).
- the second end portion 257c of the separator 257 is thermally contracted by heating in advance. Specifically, as will be described later, in the process of manufacturing the electrode body 250 (heat treatment process), the second end portion 257c of the separator 250 is heated to 200 ° C. and thermally contracted.
- the nonaqueous electrolyte secondary battery 200 of the second embodiment includes the electrode body 250 as described above, “because the separator 257 is thermally contracted in the width direction (left-right direction in FIG. 14), It is possible to prevent a problem that the positive electrode plate 155 and the negative electrode plate 156 come into contact with each other at the position of the width direction end portion (left and right end portions of the positive electrode coating portion 155d and the negative electrode coating portion 156d in FIG. 14). .
- the first end 257b and the second end 257c of the separator 257 are Since it is heat shrunk by heating in advance, it does not heat shrink further in the width direction. Specifically, it is possible to prevent the first end portion 257b of the separator 257 from shrinking inward in the width direction (left side in FIG. 14). Furthermore, the second end portion 257c can be prevented from shrinking inward (right side in FIG. 14) in the width direction.
- the first end portion 257b of the separator 257 enters between the positive electrode plate 155 (the positive electrode coating portion 155d) and the negative electrode plate 156 (the negative electrode coating portion 156d), and ends at one end of the positive electrode coating portion 155d. It is possible to prevent a problem that “155f and one end 156f of the negative electrode coating portion 156d contact”. Further, “the second end portion 257c of the separator 257 enters between the positive electrode plate 155 (positive electrode coating portion 155d) and the negative electrode plate 156 (negative electrode coating portion 156d), and the other end 155g of the positive electrode coating portion 155d. And the other end 156g of the negative electrode coating portion 156d can be prevented.
- the width direction of the electrode body 250 (the left-right direction in FIG. 14).
- the state in which the separator is interposed between the positive electrode plate 155 and the negative electrode plate 156 can be maintained, and the electrical insulation between the positive electrode plate 155 and the negative electrode plate 156 can be maintained.
- the intermediate portion 257d of the separator 257 is pressed between the positive electrode plate 155 (positive electrode coating portion 155d) and the negative electrode plate 156 (negative electrode coating portion 156d), so that the temperature at which the separator 257 thermally contracts ( For example, even when the temperature rises to 150 ° C., it is difficult to shrink in the width direction.
- a method for manufacturing the nonaqueous electrolyte secondary battery 200 will be described.
- a positive electrode plate 155 in which a positive electrode mixture layer 152 is coated on the surface of a strip-shaped positive electrode current collecting member 151 is prepared.
- a negative electrode plate 156 in which a negative electrode mixture layer 159 is coated on the surface of a strip-shaped negative electrode current collecting member 158 is prepared.
- both end portions in the width direction of the separator 257 (the first end portion 257b and the second end portion 257c) are thermally contracted by heating.
- the heat roller 11 and the heat roller 12 heated to 200 ° C. sandwich the first end portion 257b of the separator 257 in the thickness direction, and the heat roller heated to 200 ° C. 13 and the heat roller 14, the second end 257c of the separator 257 is sandwiched in the thickness direction, and the separator 257 is moved in the longitudinal direction while rotating the heat rollers 11-14.
- the 1st end part 257b and the 2nd end part 257c of the separator 257 can be heat-shrinked.
- the separator 257 in which the first end portion 257b and the second end portion 257c are thermally contracted can be manufactured.
- the positive electrode plate 155, the negative electrode plate 156, and the separator 257 are overlapped, and these are wound into a flat shape to form the electrode body 150 (see FIG. 5).
- the first end portion 257b of the separator 257 is located on the inner side (left side in FIG. 17) of the positive electrode one end portion 155c of the positive electrode plate 155 in the width direction (left and right direction in FIG. 17). It is located on the outer side (right side in FIG. 17) of one end 155f of the coating part 155d, and is located on the outer side (right side in FIG. 17) of one end 156f of the negative electrode coating part 156d of the negative electrode plate 156.
- the second end portion 257c of the separator 257 is located on the inner side (right side in FIG. 17) of the negative electrode other end portion 156c of the negative electrode plate 156 in the width direction, and the other end 155g of the positive electrode coating portion 155d of the positive electrode plate 155. Is located on the outer side (left side in FIG. 17) and on the outer side (left side in FIG. 17) of the other end 156g of the negative electrode coating portion 156d of the negative electrode plate 156. As to positive electrode plate 155, the negative electrode plate 156, and wound by placing the separator 257.
- the positive electrode current collector 122 of the positive electrode terminal member 120 is welded to the upper end of the positive electrode one end 155c of the electrode body 250 (see FIG. 3). Further, the negative electrode current collector 132 of the negative electrode terminal member 130 is welded to the upper end of the negative electrode other end 156 c of the electrode body 250. Thereafter, the electrode body 250 is accommodated in the rectangular accommodating portion 111 and the opening of the rectangular accommodating portion 111 is closed by the lid portion 112. Next, the lid portion 112 and the square housing portion 111 are welded.
- a nonaqueous electrolytic solution is injected into the rectangular accommodating portion 111 from a liquid injection port (not shown) formed in the lid portion 112 (at this time, the electrode body 250 is impregnated with the nonaqueous electrolytic solution). Thereafter, the liquid injection port is sealed, and the nonaqueous electrolyte secondary battery 200 of Example 2 is completed.
- the nonaqueous electrolyte secondary battery 300 of the third embodiment is different from the nonaqueous electrolyte secondary battery 100 of the first embodiment only in the electrode body, and the other is the same. Therefore, here, the description will focus on the points different from the first embodiment, and the description of the same points will be omitted or simplified.
- the first end 357 b of the separator 357 has one end side in the width direction of the positive electrode plate 155 in the width direction (left-right direction in FIG. 18). It is located inside (on the left side in FIG. 18) the positive electrode one end 155c located on the right end side in FIG. In other words, the positive electrode one end 155c is located on the outer side (right side in FIG. 18) than the first end 357b of the separator 357 in the width direction.
- the positive electrode one end portion 155c is constituted by a positive electrode uncoated portion 155b (a part thereof) of the positive electrode plate 155.
- the positive electrode plate 155 and the positive electrode terminal member 120 can be electrically connected by welding the positive electrode one end part 155c to the positive electrode current collecting part 122 of the positive electrode terminal member 120 ( (See FIG. 3).
- the second end portion 357c of the separator 357 is from the negative electrode other end portion 156c located on the other end side (left end side in FIG. 18) in the width direction of the negative electrode plate 156 in the width direction (left-right direction in FIG. 18). Is also located on the inner side (center side of the electrode body 350 in the width direction). In other words, the other end 156c of the negative electrode is located outside the second end 357c of the separator 357 in the width direction (the side far from the center of the electrode body 350 in the width direction).
- the other end 156c of the negative electrode is constituted by a negative electrode uncoated portion 156b (a part thereof) of the negative electrode plate 156.
- the negative electrode plate 156 and the negative electrode terminal member 130 can be electrically connected by welding the negative electrode other end part 156c to the negative electrode current collecting part 132 of the negative electrode terminal member 130 ( (See FIG. 3).
- the first end portion 357 b of the separator 357 has a width direction (left and right direction in FIG. 18) of the positive electrode coating portion 155 d of the positive electrode plate 155. It is located outside the one end 155f (right side in FIG. 18) and outside the one end 156f (corresponding to one end of the negative electrode plate 156) of the negative electrode coating portion 156d of the negative electrode plate 156 (right side in FIG. 18). ).
- the first end portion 357b of the separator 357 is thermally welded to a portion of the positive electrode plate 155 that faces the separator 357 in the thickness direction (downward in FIG. 18).
- the first end portion 357b of the separator 357 is disposed on the portion of the positive electrode plate 155 facing the separator 357 in the thickness direction (positive electrode uncoated portion). 155b).
- the separator 357 in contact with the upper surface of the negative electrode plate 156 (negative electrode coating portion 156d) has a first end portion 357b integrated with a first end portion 357b located below itself in FIG.
- the separator 357 is thermally welded to the positive electrode uncoated portion 155b.
- the 1st end part 357b of the separator 357 is heat-welded to the positive electrode uncoated part 155b (the part). Therefore, the first end portion 357b of the separator 357 can be appropriately bonded (welded) to the positive electrode plate 155.
- the second end portion 357c of the separator 357 is outside the other end 155g of the positive electrode coating portion 155d of the positive electrode plate 155 (corresponding to the other end of the positive electrode plate 155) in the width direction (left-right direction in FIG. 18). (On the left side in FIG. 18) and on the outer side (left side in FIG. 18) of the other end 156g of the negative electrode coating portion 156d of the negative electrode plate 156.
- the second end portion 357c of the separator 357 is thermally welded to a portion of the negative electrode plate 156 facing the separator 357 in the thickness direction (vertical direction in FIG. 18). Specifically, as will be described later, in the process of manufacturing the electrode body 350, the second end portion 357c of the separator 357 is disposed on the portion of the negative electrode plate 156 facing the separator 357 in the thickness direction (negative electrode uncoated portion). 156b). In Example 3, the second end portion 357c of the separator 357 is thermally welded to the negative electrode uncoated portion 156b (a part thereof). For this reason, the second end 357c of the separator 357 can be appropriately bonded (welded) to the negative electrode plate 156.
- the nonaqueous electrolyte secondary battery 300 of the third embodiment includes the electrode body 350 as described above, “because the separator 357 is thermally contracted in the width direction (left and right direction in FIG. 18), It is possible to prevent a problem that the positive electrode plate 155 and the negative electrode plate 156 come into contact with each other at the position of the width direction end portion (left and right end portions of the positive electrode coating portion 155d and the negative electrode coating portion 156d in FIG. 18). .
- the first end 357b and the second end 357c of the separator 357 Since heat shrinkage has already been caused by heating at the time of heat welding, heat shrinkage is further difficult in the width direction.
- the first end portion 357b of the separator 357 is bonded (welded) to a portion of the positive electrode plate 155 that faces in the thickness direction, the first end portion 357b of the separator 357 is formed on the inner side in the width direction (see FIG. 18, the first end portion 357b of the separator 357 can be prevented from moving inward in the width direction.
- the first end portion 357b of the separator 357 enters between the positive electrode plate 155 (the positive electrode coating portion 155d) and the negative electrode plate 156 (the negative electrode coating portion 156d), and ends at one end of the positive electrode coating portion 155d. It is possible to prevent a problem that “155f and one end 156f of the negative electrode coating portion 156d contact”.
- the second end portion 357c of the separator 357 is bonded (welded) to a portion of the negative electrode plate 156 facing in the thickness direction, the second end portion 357c of the separator 357 is positioned inward in the width direction (see FIG. 18, the second end portion 357 c of the separator 357 can be prevented from moving inward in the width direction.
- “the second end 357c of the separator 357 enters between the positive electrode plate 155 (positive electrode coating portion 155d) and the negative electrode plate 156 (negative electrode coating portion 156d), and the other end of the positive electrode coating portion 155d. 155g and the other end 156g of the negative electrode coating portion 156d are in contact with each other can be prevented.
- the non-aqueous electrolyte secondary battery 300 of Example 3 is about the width direction (left and right direction in FIG. 18) of the electrode body 350 even when the temperature rises to a temperature at which the separator 357 is thermally contracted (for example, 150 ° C.).
- a temperature at which the separator 357 is thermally contracted for example, 150 ° C.
- a method for manufacturing the nonaqueous electrolyte secondary battery 300 will be described.
- a positive electrode plate 155 in which a positive electrode mixture layer 152 is coated on the surface of a strip-shaped positive electrode current collecting member 151 is prepared.
- a negative electrode plate 156 in which a negative electrode mixture layer 159 is coated on the surface of a strip-shaped negative electrode current collecting member 158 is prepared.
- a strip-shaped separator 357 made of a polypropylene / polyethylene / polypropylene three-layer composite composite porous sheet is prepared.
- the positive electrode plate 155, the negative electrode plate 156, and the separator 357 are overlaid.
- the first end portion 357b of the separator 357 is located on the inner side (left side in FIG. 19) of the positive electrode one end portion 155c of the positive electrode plate 155 in the width direction (left and right direction in FIG. 19). It is located on the outer side (right side in FIG. 19) of one end 155f of the coating part 155d, and is located on the outer side (right side in FIG. 19) of one end 156f of the negative electrode coating part 156d of the negative electrode plate 156.
- the second end portion 357c of the separator 357 is located on the inner side (right side in FIG.
- the first end 357b of the separator 357 and the positive electrode of the positive electrode plate 155 are formed by the heat roller 11 and the heat roller 12 heated to 200 ° C. in a state where the positive electrode plate 155, the negative electrode plate 156, and the separator 357 are overlapped.
- the uncoated portion 155b is sandwiched (press-contacted) in the thickness direction, and the second roller 357c of the separator 357 and the negative electrode uncoated portion of the negative electrode plate 156 with the heat roller 13 and the heat roller 14 heated to 200 ° C.
- the positive electrode plate 155, the negative electrode plate 156, and the separator 357 are moved in the longitudinal direction (upward in FIG.
- the heat roller 12 is located on the back side of the heat roller 11 in FIG. 19 (the back side when viewed in the direction orthogonal to the paper surface), and the heat roller 14 is the back side of the heat roller 13 in FIG. 19 (the direction orthogonal to the paper surface). It is located on the back side).
- the first end portion 357b of the separator 350 can be thermally welded to a portion of the positive electrode plate 155 that faces the separator 357 in the thickness direction (positive electrode uncoated portion 155b).
- the second end portion 357c of the separator 350 can be thermally welded to a portion of the negative electrode plate 156 that faces the separator 357 in the thickness direction (negative electrode uncoated portion 156b). Then, after heat welding, these (the positive electrode plate 155, the negative electrode plate 156, and the separator 357) are wound into a flat shape to form the electrode body 350 (see FIG. 5).
- an adhesive for example, a polyolefin-based adhesive
- a portion (positive electrode uncoated portion 155b) of the positive electrode plate 155 that faces the first end portion 357b of the separator 357 in the thickness direction.
- an adhesive for example, a polyolefin-based adhesive
- the positive electrode current collector 122 of the positive electrode terminal member 120 is welded to the upper end of the positive electrode one end 155c of the electrode body 350 (see FIG. 3).
- the negative electrode current collector 132 of the negative electrode terminal member 130 is welded to the upper end of the negative electrode other end 156 c of the electrode body 350.
- the electrode body 350 is accommodated in the rectangular accommodating portion 111 and the opening of the rectangular accommodating portion 111 is closed by the lid portion 112.
- the lid portion 112 and the square housing portion 111 are welded.
- a nonaqueous electrolytic solution is injected into the rectangular accommodating portion 111 from a liquid injection port (not shown) formed in the lid portion 112 (at this time, the electrode body 250 is impregnated with the nonaqueous electrolytic solution). Thereafter, the liquid injection port is sealed, and the nonaqueous electrolyte secondary battery 300 of Example 3 is completed.
- the battery capacities of the batteries of Examples 1 to 3 and the comparative example were measured in a temperature environment of 25 ° C. Specifically, charging is performed at a constant current of 1 C (5.5 A) until the voltage of each battery reaches 4.2 V, and then the current value is 0.1 C while maintaining the battery voltage at 4.2 V. The battery was charged until it reached (0.55 A). As a result, the non-aqueous electrolyte secondary battery 100 was made 100% SOC.
- the average capacity (average value of the battery capacity of five batteries) was 5.48 Ah. In the battery of Example 2, the average capacity was 5.50 Ah. In the battery of Example 3, the average capacity was 5.47 Ah. In the battery of the comparative example, the average capacity was 5.52 Ah.
- each battery was subjected to a heating test. Specifically, first, each battery was adjusted to SOC 80% (battery voltage 3.8 V), and these were placed in a test chamber of a heating test apparatus. Then, the temperature in the test chamber was raised by 5 ° C. per minute, and the temperature in the test chamber was set to 160 ° C. Thereafter, the temperature in the test chamber was maintained at 160 ° C., and each battery was left in the test chamber at 160 ° C. for 30 minutes. Meanwhile, the battery temperature was measured for each battery, and the maximum temperature reached for each battery was detected. Note that 160 ° C. is a temperature at which the separator thermally shrinks.
- the batteries of the comparative examples all had a battery voltage of 0 V by the heating test. Furthermore, the highest temperature reached in the heating test was 210 ° C., which was 50 ° C. higher than the temperature in the test chamber (160 ° C.). From this result, in the battery of the comparative example, due to the thermal contraction of the separator, the positive electrode plate and the negative electrode plate contact at the position of the width direction end portions (first end portion and second end portion) of the separator, and an internal short circuit occurs. Conceivable. The internal short circuit promotes heat generation of the battery, and it is considered that the battery temperature rises to 210 ° C.
- the batteries of Examples 1 to 3 all maintained the battery voltage at 3.8V. Furthermore, the highest temperature reached in the heating test was 160 ° C., which was not different from the temperature in the test chamber (160 ° C.). As a result, in the batteries of Examples 1 to 3, the separator was interposed between the positive electrode plate and the negative electrode plate in the width direction of the electrode body even when the heating test (the test to heat the separator to heat shrinkage) was performed. It can be said that the interposed state was maintained and the electrical insulation between the positive electrode plate and the negative electrode plate could be maintained.
- Electrode body (electrode body for nonaqueous electrolyte secondary battery) 155 Positive electrode plate 155b Positive electrode uncoated portion 155c Positive electrode one end portion 155d Positive electrode coated portion 151 Positive electrode current collecting member 152 Positive electrode mixture layer 156 Negative electrode plate 156b Negative electrode uncoated portion 156c Negative electrode other end portion 156d Negative electrode coated portion 158 Negative electrode Current collector 159 Negative electrode mixture layer 157, 257, 357 Separator 157b, 257b, 357b Separator first end 157c, 257c, 357c Separator second end 157d, 257d, 357d Separator intermediate part
Abstract
Description
具体的には、電池の発熱によりセパレータが幅方向に熱収縮する温度になったとしても、セパレータの第1端部及び第2端部は、予め、加熱により熱収縮させているので、それ以上幅方向に熱収縮しない。これにより、幅方向について、正極板と負極板との間にセパレータを介在させた状態を維持し、正極板と負極板との電気的絶縁を保つことができる。
次に、本発明の実施例1について、図面を参照しつつ説明する。
本実施例1の非水電解質二次電池100は、図1~図4に示すように、直方体形状の電池ケース110と、正極端子部材120と、負極端子部材130とを備える、角形密閉式のリチウムイオン二次電池である。このうち、電池ケース110は、直方体形状の収容空間をなす金属製の角形収容部111と金属製の蓋部112とを有するハードケースである。電池ケース110(角形収容部111)の内部には、電極体150などが配置されている。なお、非水電解質二次電池100の定格容量(公称容量)は5.5Ahである。
まず、図7及び図8に示すように、帯状の正極集電部材151の表面に正極合材層152が塗工された正極板155を用意する。さらに、図9及び図10に示すように、帯状の負極集電部材158の表面に負極合材層159が塗工された負極板156を用意する。さらに、図11及び図12に示すように、幅方向両端部(第1端部157b及び第2端部157c)を2重に折り重ねて、中間部157dの厚みよりも厚く(中間部157dの2倍の厚み)したセパレータ157を用意する。
本実施例2の非水電解質二次電池200は、実施例1の非水電解質二次電池100と比較して、電極体のセパレータのみが異なり、その他については同様である。従って、ここでは、実施例1と異なる点を中心に説明し、同様な点については説明を省略または簡略化する。
しかも、本実施例2では、セパレータ257の第1端部257bを、予め、加熱により熱収縮させている。具体的には、後述するように、電極体250を製造する過程(熱処理工程)で、セパレータ250の第1端部257bを200℃に加熱し、熱収縮させている。
しかも、本実施例2では、セパレータ257の第2端部257cを、予め、加熱により熱収縮させている。具体的には、後述するように、電極体250を製造する過程(熱処理工程)で、セパレータ250の第2端部257cを200℃に加熱し、熱収縮させている。
まず、図7及び図8に示すように、帯状の正極集電部材151の表面に正極合材層152が塗工された正極板155を用意する。さらに、図9及び図10に示すように、帯状の負極集電部材158の表面に負極合材層159が塗工された負極板156を用意する。
また、熱処理工程において、セパレータ257の幅方向両端部(第1端部257b及び第2端部257c)を、加熱により熱収縮させる。
本実施例3の非水電解質二次電池300は、実施例1の非水電解質二次電池100と比較して、電極体のみが異なり、その他については同様である。従って、ここでは、実施例1と異なる点を中心に説明し、同様な点については説明を省略または簡略化する。
また、本実施例3では、セパレータ357の第1端部357bを、正極未塗工部155b(その一部)に、熱溶着している。このため、セパレータ357の第1端部357bを、正極板155に対し、適切に接着(溶着)することができる。
なお、本実施例3では、セパレータ357の第2端部357cを、負極未塗工部156b(その一部)に、熱溶着している。このため、セパレータ357の第2端部357cを、負極板156に対し、適切に接着(溶着)することができる。
まず、図7及び図8に示すように、帯状の正極集電部材151の表面に正極合材層152が塗工された正極板155を用意する。さらに、図9及び図10に示すように、帯状の負極集電部材158の表面に負極合材層159が塗工された負極板156を用意する。さらに、ポリプロピレン/ポリエチレン/ポリプロピレン3層構造複合体多孔質シートからなる帯状のセパレータ357を用意する。
次に、実施例1~3の非水電解質二次電池100~300を、それぞれ5個ずつ用意した。また、比較例として、実施例2の非水電解質二次電池200と比較して、セパレータの第1端部及び第2端部を熱収縮させていない(熱処理工程を行っていない)点のみが異なる非水電解質二次電池を、5個用意した。そして、これらの電池(合計20個の電池)について、加熱試験を行い、内部短絡の発生を調査した。
また、SOCは、State Of Charge(充電状態、充電率)の略である。
110 電池ケース
150,250,350 電極体(非水電解質二次電池用電極体)
155 正極板
155b 正極未塗工部
155c 正極一方端部
155d 正極塗工部
151 正極集電部材
152 正極合材層
156 負極板
156b 負極未塗工部
156c 負極他方端部
156d 負極塗工部
158 負極集電部材
159 負極合材層
157,257,357 セパレータ
157b,257b,357b セパレータの第1端部
157c,257c,357c セパレータの第2端部
157d,257d,357d セパレータの中間部
Claims (5)
- 正極板、負極板、及び、上記正極板と上記負極板との間に介在するセパレータ、を有し、上記正極板、上記負極板、及び、上記セパレータが、それぞれの幅方向を一致させて重なり合う
非水電解質二次電池用の電極体であって、
上記正極板は、正極集電部材と、その表面に塗工された正極合材層と、を有し、
上記負極板は、負極集電部材と、その表面に塗工された負極合材層と、を有し、
上記セパレータは、上記幅方向について、一方端側に位置する第1端部と、他方端側に位置する第2端部と、上記第1端部と上記第2端部との間に位置する中間部と、を有し、
上記セパレータの第1端部は、
上記幅方向について、上記正極板のうち上記幅方向について一方端側に位置する正極一方端部よりも内側に位置し、上記正極板のうち上記正極合材層が塗工された正極塗工部の一方端よりも外側に位置し、且つ、上記負極板のうち上記負極合材層が塗工された負極塗工部の一方端よりも外側に位置し、
上記中間部の厚みよりも厚くされてなり、
上記セパレータの第2端部は、
上記幅方向について、上記負極板のうち上記幅方向について他方端側に位置する負極他方端部よりも内側に位置し、上記正極塗工部の他方端よりも外側に位置し、且つ、上記負極塗工部の他方端よりも外側に位置し、
上記中間部の厚みよりも厚くされてなる
非水電解質二次電池用電極体。 - 正極板、負極板、及び、上記正極板と上記負極板との間に介在するセパレータ、を有し、上記正極板、上記負極板、及び、上記セパレータが、それぞれの幅方向を一致させて重なり合う
非水電解質二次電池用の電極体であって、
上記正極板は、正極集電部材と、その表面に塗工された正極合材層と、を有し、
上記負極板は、負極集電部材と、その表面に塗工された負極合材層と、を有し、
上記セパレータは、上記幅方向について、一方端側に位置する第1端部と、他方端側に位置する第2端部と、上記第1端部と上記第2端部との間に位置する中間部と、を有し、
上記セパレータの第1端部は、
上記幅方向について、上記正極板のうち上記幅方向について一方端側に位置する正極一方端部よりも内側に位置し、上記正極板のうち上記正極合材層が塗工された正極塗工部の一方端よりも外側に位置し、且つ、上記負極板のうち上記負極合材層が塗工された負極塗工部の一方端よりも外側に位置し、
上記セパレータの第1端部を、予め、加熱により熱収縮させてなり、
上記セパレータの第2端部は、
上記幅方向について、上記負極板のうち上記幅方向について他方端側に位置する負極他方端部よりも内側に位置し、上記正極塗工部の他方端よりも外側に位置し、且つ、上記負極塗工部の他方端よりも外側に位置し、
上記セパレータの第2端部を、予め、加熱により熱収縮させてなる
非水電解質二次電池用電極体。 - 正極板、負極板、及び、上記正極板と上記負極板との間に介在するセパレータ、を有し、上記正極板、上記負極板、及び、上記セパレータが、それぞれの幅方向を一致させて重なり合う
非水電解質二次電池用の電極体であって、
上記正極板は、正極集電部材と、その表面に塗工された正極合材層と、を有し、
上記負極板は、負極集電部材と、その表面に塗工された負極合材層と、を有し、
上記セパレータは、上記幅方向について、一方端側に位置する第1端部と、他方端側に位置する第2端部と、上記第1端部と上記第2端部との間に位置する中間部と、を有し、
上記セパレータの第1端部は、
上記幅方向について、上記正極板のうち上記幅方向について一方端側に位置する正極一方端部よりも内側に位置し、上記正極板のうち上記正極合材層が塗工された正極塗工部の一方端よりも外側に位置し、且つ、上記負極板のうち上記負極合材層が塗工された負極塗工部の一方端よりも外側に位置し、
上記正極板のうち上記セパレータとその厚み方向について対向する部位に、熱溶着してなり、
上記セパレータの第2端部は、
上記幅方向について、上記負極板のうち上記幅方向について他方端側に位置する負極他方端部よりも内側に位置し、上記正極塗工部の他方端よりも外側に位置し、且つ、上記負極塗工部の他方端よりも外側に位置し、
上記負極板のうち上記セパレータとその厚み方向について対向する部位に、熱溶着してなる
非水電解質二次電池用電極体。 - 請求項3に記載の非水電解質二次電池用電極体であって、
前記正極板のうち前記セパレータの前記第1端部が熱溶着されている部位は、上記正極板のうち前記正極合材層が塗工されていない正極未塗工部の少なくとも一部であり、
前記負極板のうち上記セパレータの前記第2端部が熱溶着されている部位は、上記負極板のうち前記負極合材層が塗工されていない負極未塗工部の少なくとも一部である
非水電解質二次電池用電極体。 - 請求項1~請求項4のいずれか一項に記載の非水電解質二次電池用電極体、を備える
非水電解質二次電池。
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JP2009054480A (ja) * | 2007-08-28 | 2009-03-12 | Toshiba Corp | 非水電解質電池および電池パック |
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JP2013073761A (ja) * | 2011-09-27 | 2013-04-22 | Gs Yuasa Corp | 蓄電素子 |
US9698397B2 (en) | 2011-11-10 | 2017-07-04 | Toyota Jidosha Kabushiki Kaisha | Battery |
JP2013196894A (ja) * | 2012-03-19 | 2013-09-30 | Toyota Industries Corp | 蓄電装置、車両、電極体の製造方法 |
JP2014007104A (ja) * | 2012-06-26 | 2014-01-16 | Toyota Industries Corp | 蓄電装置 |
JP2014049419A (ja) * | 2012-09-04 | 2014-03-17 | Toyota Industries Corp | 蓄電装置、及び蓄電装置の製造方法 |
JP2015088247A (ja) * | 2013-10-28 | 2015-05-07 | 日立オートモティブシステムズ株式会社 | 二次電池 |
JP2017059326A (ja) * | 2015-09-14 | 2017-03-23 | 日立オートモティブシステムズ株式会社 | 二次電池 |
Also Published As
Publication number | Publication date |
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US10454140B2 (en) | 2019-10-22 |
JPWO2011096070A1 (ja) | 2013-06-10 |
CN102282716A (zh) | 2011-12-14 |
CN102282716B (zh) | 2014-07-23 |
KR20110114573A (ko) | 2011-10-19 |
KR101321201B1 (ko) | 2013-10-23 |
JP5273159B2 (ja) | 2013-08-28 |
US20110217590A1 (en) | 2011-09-08 |
US20150079478A1 (en) | 2015-03-19 |
US20180097254A1 (en) | 2018-04-05 |
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