WO2010121449A1 - 一种数码条幅打印碳带及其制备方法 - Google Patents

一种数码条幅打印碳带及其制备方法 Download PDF

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Publication number
WO2010121449A1
WO2010121449A1 PCT/CN2009/072766 CN2009072766W WO2010121449A1 WO 2010121449 A1 WO2010121449 A1 WO 2010121449A1 CN 2009072766 W CN2009072766 W CN 2009072766W WO 2010121449 A1 WO2010121449 A1 WO 2010121449A1
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Prior art keywords
layer
binder
resin
total weight
filler
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PCT/CN2009/072766
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English (en)
French (fr)
Inventor
张振宇
张举红
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焦作市卓立烫印材料有限公司
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Publication of WO2010121449A1 publication Critical patent/WO2010121449A1/zh

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Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41J—TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
    • B41J31/00—Ink ribbons; Renovating or testing ink ribbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382—Contact thermal transfer or sublimation processes
    • B41M5/38207—Contact thermal transfer or sublimation processes characterised by aspects not provided for in groups B41M5/385 - B41M5/395
    • B41M5/38214—Structural details, e.g. multilayer systems
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/02—Dye diffusion thermal transfer printing (D2T2)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/36—Backcoats; Back layers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M2205/00—Printing methods or features related to printing methods; Location or type of the layers
    • B41M2205/38—Intermediate layers; Layers between substrate and imaging layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/382—Contact thermal transfer or sublimation processes
    • B41M5/392—Additives, other than colour forming substances, dyes or pigments, e.g. sensitisers, transfer promoting agents
    • B41M5/395—Macromolecular additives, e.g. binders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
    • B41M5/40—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used characterised by the base backcoat, intermediate, or covering layers, e.g. for thermal transfer dye-donor or dye-receiver sheets; Heat, radiation filtering or absorbing means or layers; combined with other image registration layers or compositions; Special originals for reproduction by thermography
    • B41M5/42—Intermediate, backcoat, or covering layers
    • B41M5/44—Intermediate, backcoat, or covering layers characterised by the macromolecular compounds
    • B41M5/443—Silicon-containing polymers, e.g. silicones, siloxanes

Definitions

  • the invention belongs to the technical field of hot stamping materials, and particularly relates to a digital banner printing carbon ribbon and a preparation method thereof
  • the domestic banner production process is hand-drawn as a banner, screen printed banner and thermal transfer banner.
  • the object of the present invention is to provide a digital banner printing carbon ribbon which is reasonable in design, simple in preparation method, and easy to popularize and apply, and a preparation method thereof.
  • a digital banner printing ribbon comprising a tape base and a back coating layer and a thermal transfer layer respectively coated on both sides of the tape base, the thermal transfer layer being divided into three parts, the base side of the tape
  • the surface is a release layer, a color layer, and a tie layer from the inside to the outside.
  • the release layer is made of the following weight percentage of raw materials: binder 93 ⁇ 97%, auxiliary 3-7%;
  • the color layer is made of the following weight percentage of raw materials: ⁇ 40%, pigment 30-45%, filler 30 ⁇ 35%;
  • the joint layer is made of the following weight percentage of raw materials: 75-85% of binder, 13 ⁇ 23% of filler, 1 ⁇ 2% of additives .
  • the binder in the back coat layer, is a silicone resin, and the auxiliary agent is a silicone filler;
  • the binder is a modified acrylic polyurethane resin, and the auxiliary agent is a chlorinated paraffin wax; in the color layer, the binder is a phenol resin, and the pigment is not limited, and may be white, red, yellow, blue, green.
  • Etc. the filler is talc; in the joint layer, the binder is EVA resin and perchloroethylene resin, and the total weight percentage of the joint layer is 55 ⁇ 60% of EVA resin and 20 ⁇ 25% of perchloroethylene resin, respectively.
  • the filler is an OP wax and the auxiliary is a titanate surfactant.
  • the silicone resin is phenyltrichlorosilane, diphenyldichlorosilane, methyltrichlorosilane or phenylsiloxane, and the silicone filler is methyl.
  • the modified acrylic polyurethane resin is polyurethane diacrylate, polyurethane triacrylate, polyurethane tetraacrylate or polyurethane hexaacrylate
  • the phenolic resin is rosin modified phenolic Resin, phenol formaldehyde resin, tert-butyl phenol formaldehyde resin
  • the titanate surfactant is dodecylbenzenesulfonyl titanate, triisostearyl titanate isopropyl ester, isopropyl Trioleoyl titanate or isopropoxy triisooctanoyl titanate
  • the base is a high strength polyester film.
  • the tape base is preferably a biaxially oriented PET film.
  • a method for preparing a digital banner printing ribbon comprising the following steps:
  • the binder, filler and auxiliary agent in the proportioned joint layer are diluted and uniformly mixed, coated on the outside of the color layer, and dried to form the invention.
  • Digital banner printing ribbon
  • step a firstly dilute and mix the binder with gasoline, then mix the additives evenly within 30 minutes before use; in step b: first remove the layer with methyl ethyl ketone and butyl ester The binder is dissolved, and then the additive is uniformly mixed; in step c: first, the phenolic resin is dissolved with xylene, and then the filler and the pigment are added in proportion to the grinding; in step d: the link is made with xylene and methyl ethyl ketone. The binder in the layer is dissolved, and then the filler and the auxiliary agent are added in proportion, and uniformly mixed to form a joint layer coating liquid. [19] Further, in step c, after polishing, the pigment fineness is less than 5 ⁇ m ; in step d, the bonding layer coating liquid has a viscosity of 14 to 16 seconds at 25 °C.
  • step a the drying temperature in step a is
  • the thickness of the back coat layer is 0.2 ⁇ 0.5 ⁇ ;
  • the drying temperature in step b is 60 ⁇ 80°C, the thickness of the layer is 1 ⁇ 3 ⁇ ;
  • the drying temperature in step c is 80 ⁇ 100°C, color
  • the layer thickness is 8 ⁇ 20 ⁇ ;
  • the drying temperature in step d is 40 ⁇ 60 ° C, the thickness of the connecting layer is 4 ⁇ 10 ⁇ ;
  • the thickness of the strip is 4 ⁇ 6 ⁇ , and the total thickness of the digital strip printing ribbon is 17. 2 ⁇ 39 ⁇ 5 ⁇ .
  • the digital banner printing carbon ribbon of the invention has reasonable design, and the preparation method is simple and easy to popularize and apply.
  • the digital banner printing ribbon produced by the technical solution of the invention can be used to transfer the release layer, the color layer and the bonding layer onto the banner material through the ribbon ribbon printer to realize the one-time production of the banner.
  • the invention innovates the complicated process of the traditional banner making, which not only makes the banner making more simple, fast, economical and efficient, but also satisfies the digital and personalized design requirements of the computer design printing and finished products.
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer respectively coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is selected from phenyltrichlorosilane, which accounts for 80% of the total weight of the back coating; the auxiliary agent uses methylhydrogensiloxane, which accounts for 20% of the total weight of the back coating; and gasoline is used as a solvent.
  • the release layer is made of binder and auxiliaries.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is rosin modified phenolic resin, which accounts for 20% of the total weight of the color layer; the pigment is titanium white powder, which accounts for 45% of the total weight of the color layer; the talc powder is used for the filler, accounting for 35% of the total weight of the color layer; Solvent.
  • the resin accounts for 55% of the total weight of the joint layer, and the perchloroethylene resin accounts for 20% of the total weight of the joint layer.
  • the filler is made of OP wax, which accounts for 23% of the total weight of the joint layer.
  • the auxiliary agent is made of 12-mercaptobenzenesulfonyl titanate.
  • [33] c First, dissolve the phenolic resin with xylene, and then add the filler and the pigment according to the ratio to form a color layer coating liquid.
  • the strip base is a 4 ⁇ thick thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is 26.4 ⁇ .
  • the back coat is made of binders and auxiliaries.
  • the back coating material is phenyltrichlorosilane, which accounts for 80% of the total weight of the back coating; the platinum chloric acid is used as the auxiliary agent, which accounts for 20% of the total weight of the back coating;
  • the release layer is made of binder and auxiliaries.
  • the detached layer is selected from polyurethane triacrylate, which accounts for 95% of the total weight of the release layer;
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is selected from rosin modified phenolic resin, which accounts for 20% of the total weight of the color layer; the pigment is selected from permanent red, accounting for 45% of the total weight of the color layer; the talc is used as the filler, accounting for 35% of the total weight of the color layer; As a solvent.
  • the drying temperature in step a is 80 °C
  • the strip base is a 4 ⁇ thick thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is 17.2 ⁇ m.
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer applied to both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is selected from diphenyldichlorosilane, which accounts for the total back coating.
  • the weight is 81%;
  • the auxiliary agent is platinum chloric acid, which accounts for 19% of the total weight of the back coating;
  • ⁇ uses gasoline as a solvent.
  • the release layer is made of binder and auxiliaries.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is phenol formaldehyde resin, which accounts for 30% of the total color of the color layer; the pigment is chrome yellow, which accounts for 40% of the total weight of the color layer; the talc powder is used for the filler, which accounts for 30% of the total weight of the color layer; xylene is used as the solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 55% of the total weight of the connecting layer, and perchloroethylene resin accounts for 20% of the total weight of the connecting layer;
  • OP wax is used for the filling material, accounting for 23% of the total weight of the connecting layer;
  • the agent is selected from the group consisting of dodecylbenzenesulfonyl titanate, which accounts for the total weight of the joint layer.
  • the strip base is a 6 ⁇ thick thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is selected from methyltrichlorosilane, which accounts for 82% of the total weight of the back coating; the additive uses methylhydrogensiloxane, which accounts for 18% of the total weight of the back coating; and gasoline is used as a solvent.
  • the release layer is made of binder and auxiliaries. Polyurethane hexaacrylate is used as the release layer binder.
  • the color layer is made of binders, fillers and auxiliaries.
  • Color layer binder is selected from t-butyl formaldehyde resin, accounting for The total weight of the color layer is 30%; the pigment is selected from indigo, which accounts for 40% of the total weight of the color layer; the talc powder is used as the filler, accounting for 30% of the total weight of the color layer; and xylene is used as the solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 55% of the total weight of the connecting layer, and perchloroethylene resin accounts for 25% of the total weight of the connecting layer;
  • OP wax is used as the filling material, accounting for 18.2% of the total weight of the connecting layer;
  • Step a the drying temperature is 80 °C, the thickness of the back coating
  • the tape base is a biaxially stretched PET film having a thickness of 5 ⁇ m, and the total thickness of the digital strip printing ribbon is 30 ⁇ m.
  • the digital banner printing ribbon is composed of a belt base and a back coating layer and a thermal transfer layer respectively coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is sequentially from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of binder and auxiliaries.
  • the back coating material is selected from phenyl siloxane, which accounts for 83% of the total weight of the back coating; the auxiliaries use methyl hydroxy siloxane, which accounts for 17% of the total weight of the back coating; ⁇ uses gasoline as a solvent.
  • the release layer is made of binder and auxiliaries.
  • the detachment layer is selected from polyurethane diacrylate, which accounts for 95% of the total weight of the release layer;
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is selected from rosin modified phenolic resin, accounting for 33% of the total weight of the color layer; the pigment is selected from ⁇ green, accounting for 35% of the total weight of the color layer; the talc powder is used as the filler, accounting for 32% of the total weight of the color layer; As a solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 55% of the total weight of the connecting layer, and perchloroethylene resin accounts for 25% of the total weight of the connecting layer;
  • OP wax is used as the filling material, accounting for 18.5% of the total weight of the connecting layer;
  • the drying temperature in step a is 88 ° C
  • the thickness of the back coating is 0.3 ⁇
  • the drying temperature in step b is 63 ° C
  • butanone butyl ester
  • the strip base is a 5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer respectively coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is selected from methyltrichlorosilane, which accounts for 84% of the total weight of the back coating; the auxiliary agent uses methylhydrogensiloxane, which accounts for 16% of the total weight of the back coating; and gasoline is used as a solvent.
  • the release layer is made of binder and auxiliaries.
  • the detachable layer is selected from polyurethane triacrylate, which accounts for 95% of the total weight of the release layer;
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is phenol formaldehyde resin, which accounts for 20% of the total weight of the color layer; the pigment is zinc white, which accounts for 45% of the total weight of the color layer; the talc powder is used for the filler, accounting for 35% of the total weight of the color layer; .
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 55% of the total weight of the connecting layer, and perchloroethylene resin accounts for 20% of the total weight of the connecting layer;
  • OP wax is used for the filling material, accounting for 23% of the total weight of the connecting layer;
  • Step a In the preparation method of digital banner printing ribbon: Step a
  • the medium drying temperature is 80 ° C, the back coating thickness is 0.5 ⁇ ; the drying temperature in step b is 60
  • step c drying temperature in step c is 80
  • the thickness of the tie layer is 5 ⁇ ; the others are the same as in Example 1.
  • the strip base is a 4.5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is 24 ⁇ 5 ⁇ m.
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is phenyltrichlorosilane, which accounts for 85% of the total weight of the back coating; the platinum chloric acid is used as the auxiliary agent, which accounts for 15% of the total weight of the back coating;
  • the release layer is made of a binder and an auxiliary.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is phenol formaldehyde resin, which accounts for 30% of the total color of the color layer;
  • talc powder is used as the filler, accounting for 30% of the total weight of the color layer; xylene is used as the solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 55% of the total weight of the connecting layer, and perchloroethylene resin accounts for 20% of the total weight of the connecting layer;
  • OP wax is used as the filler, accounting for 23% of the total weight of the connecting layer;
  • the drying temperature in step a is 82 ° C
  • the thickness of the back coating is 0.4 ⁇
  • the strip base is a 4.5 ⁇ thick thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is 28.5 ⁇ m.
  • the digital banner printing ribbon consists of a tape base and a back coating and a thermal transfer layer applied to both sides of the tape base, respectively.
  • the thermal transfer layer is divided into three parts, and the surface of one side of the tape base is a release layer, a color layer, and a connection layer from the inside to the outside.
  • the back coat is made of binder and auxiliaries.
  • the back coating material is selected from diphenyldichlorosilane, which accounts for 86% of the total weight of the back coating;
  • the auxiliary agent is platinum chloric acid, which accounts for 14% of the total weight of the back coating;
  • the release layer is made of binder and auxiliaries.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is selected from rosin modified phenolic resin, which accounts for 30% of the total weight of the color layer; the pigment is selected from permanent solid yellow, accounting for 40% of the total weight of the color layer; the talc powder is used as the filler, accounting for 30% of the total weight of the color layer; As a solvent.
  • the tie layer is made of binder, pigment and filler.
  • the connecting layer connecting material is EVA resin and perchloroethylene resin, EVA resin accounts for 55% of the total weight of the connecting layer, and the perchloroethylene resin accounts for 25% of the total weight of the connecting layer;
  • the filler is selected with OP wax, which accounts for 19% of the total weight of the connecting layer;
  • Step a the drying temperature is 96 ° C, the thickness of the back coating is 0.3 ⁇
  • the thickness of the tie layer is 7.7 ⁇ ; otherwise the same as in Example 1.
  • the strip base is a 6 ⁇ thick thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is phenyl siloxane, which accounts for 87% of the total weight of the back coating; the auxin is platinum chloric acid, which accounts for 13% of the total weight of the back coating; ⁇ uses gasoline as a solvent.
  • the release layer is made of a binder and an auxiliary.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is t-butylformaldehyde resin, which accounts for 20% of the total weight of the color layer; the pigment is selected from Tillandsia, which accounts for 45% of the total weight of the color layer; the talc powder is used as the filler, accounting for 35% of the total weight of the color layer; Solvent.
  • step a the drying temperature in step a is 80 °C, the thickness of the back coating
  • the digital banner printing ribbon is composed of a belt base and a back coating layer and a thermal transfer layer respectively coated on both sides of the belt base, and the thermal transfer layer is divided into three parts, and the surface of the belt base is sequentially from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the additive uses methylhydrogensiloxane, which accounts for 12% of the total weight of the back coating; ⁇ uses gasoline as a solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 55% of the total weight of the connecting layer, and perchloroethylene resin accounts for 20% of the total weight of the connecting layer;
  • OP wax is used as the filler, accounting for 23% of the total weight of the connecting layer;
  • Step a the drying temperature is 93 ° C, the thickness of the back coating is 0.3 ⁇
  • the strip base is a 4 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer respectively coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an auxiliary.
  • the back-coating material is selected from diphenyldichlorosilane, accounting for 89% of the total weight of the back coating; the auxiliary agent is methylhydroxylsiloxane, which accounts for 11% of the total weight of the back coating; and gasoline is used as a solvent.
  • the release layer is made of a binder and an auxiliary. Polyurethane hexaacrylate is used as the release layer binder
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is phenol formaldehyde resin, which accounts for 30% of the total color of the color layer; the pigment is zinc oxide, which accounts for 40% of the total weight of the color layer; the talc powder is used for the filler, which accounts for 30% of the total weight of the color layer; and xylene is used as the solvent.
  • the tie layer is made of a binder, a pigment and a filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 55% of the total weight of the connecting layer, and perchloroethylene resin accounts for 20% of the total weight of the connecting layer;
  • OP wax is used for the filling material, accounting for 23% of the total weight of the connecting layer;
  • Step a the drying temperature is 80 ° C, the thickness of the back coating is 0.5 ⁇
  • the thickness of the tie layer is 4.7 ⁇ ; otherwise the same as in Example 1.
  • the strip base is a 4.5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is 19 ⁇ 7 ⁇ .
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer respectively coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an adjuvant.
  • the back coating material is selected from methyltrichlorosilane, which accounts for the total weight of the back coating.
  • the release layer is made of a binder and an auxiliary. Polyurethane diacrylate is used as the release layer binder
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is t-butylformaldehyde resin, which accounts for 30% of the total weight of the color layer;
  • the pigment is selected from Lisor purple, accounting for 40% of the total weight of the color layer;
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material.
  • EVA resin accounts for 57% of the total weight of the connecting layer, and perchloroethylene resin accounts for 23% of the total weight of the connecting layer;
  • OP wax is used as the filler, accounting for 18.3% of the total weight of the connecting layer;
  • the drying temperature in step a is 83 °C
  • the strip base is a 5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the release layer is made of a binder and an auxiliary.
  • the color layer is made of binders, fillers and auxiliaries.
  • Color layer binder is selected from rosin modified phenolic
  • the resin accounts for 30% of the total weight of the color layer; the pigment is selected from fluorescent yellow, which accounts for 38% of the total weight of the color layer; the talc is used as the filler, accounting for 32% of the total weight of the color layer; and xylene is used as the solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material.
  • EVA resin accounts for 56% of the total weight of the connecting layer, and perchloroethylene resin accounts for 24% of the total weight of the connecting layer;
  • OP wax is used for the filling material, accounting for 18.8% of the total weight of the connecting layer;
  • Step a the drying temperature is 100 °C, the thickness of the back coating
  • the strip base is a 5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is 2
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is selected from methyltrichlorosilane, accounting for 90% of the total weight of the back coating; the auxiliary is platinum chloric acid, which accounts for 10% of the total weight of the back coating; and gasoline is used as a solvent.
  • the release layer is made of a binder and an auxiliary.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is t-butyl phenolic resin, which accounts for 25% of the total weight of the color layer; the pigment is cobalt blue, which accounts for 42% of the total color layer; the talc powder is used for the filler, which accounts for 33% of the total weight of the color layer; Solvent.
  • the tie layer is made of binder, pigment and filler.
  • the connecting layer connecting material is EVA resin and perchloroethylene resin.
  • the EVA resin accounts for 59% of the total weight of the connecting layer
  • the perchloroethylene resin accounts for 21% of the total weight of the connecting layer.
  • the filling material is OP wax, which accounts for 18.7% of the total weight of the connecting layer.
  • Step a the drying temperature is 80 ° C, the thickness of the back coating is 0.2 ⁇
  • the thickness of the tie layer is 6 ⁇ ; the others are the same as in Example 1.
  • the strip base is a 5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer respectively coated on both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside.
  • the release layer, color layer, and tie layer are divided into three parts, and the surface of the belt base is in turn from the inside to the outside.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is selected from phenyl siloxane, which accounts for 90% of the total weight of the back coating; the auxin is platinum chloric acid, which accounts for 10% of the total weight of the back coating; ⁇ uses gasoline as a solvent.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is phenol formaldehyde resin, which accounts for 40% of the total color of the color layer; the pigment is selected from fluorescent green, accounting for 30% of the total weight of the color layer; the talc powder is used for the filler, which accounts for 30% of the total weight of the color layer; xylene is used as the solvent.
  • the tie layer is made of binder, pigment and filler. EVA resin and perchloroethylene resin are used as the connecting layer connecting material, and EVA resin accounts for 58% of the total weight of the connecting layer.
  • Step a the drying temperature is 92 ° C, the thickness of the back coating is 0.2 ⁇
  • step d drying temperature in step d is 56 ° C, xylene: butanone
  • the strip base is a 5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer applied to both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside.
  • the release layer, color layer, and tie layer are divided into three parts, and the surface of the belt base is in turn from the inside to the outside.
  • the back coat is made of binders and auxiliaries.
  • the back coating material is phenyltrichlorosilane, which accounts for 90% of the total weight of the back coating; the platinum chloric acid is used as the auxiliary agent, which accounts for 10% of the total weight of the back coating;
  • the release layer is made of binder and auxiliaries.
  • the color layer is made of binders, fillers and auxiliaries.
  • Color layer binder is selected from tert-butyl phenolic resin, accounting for The total weight of the color layer is 40%; the pigment is titanium white powder, which accounts for 30% of the total weight of the color layer; the talc powder is used for the filler, which accounts for 30% of the total weight of the color layer; and xylene is used as the solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 60% of the total weight of the connecting layer, and perchloroethylene resin accounts for 20% of the total weight of the connecting layer;
  • OP wax is used as the filler, accounting for 18% of the total weight of the connecting layer; Isopropoxy triisooctanoyl titanate
  • step d drying temperature in step d is 45 ° C, xylene: butanone
  • the strip base is a 5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer applied to both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside.
  • the release layer, color layer, and tie layer are divided into three parts, and the surface of the belt base is in turn from the inside to the outside.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is selected from diphenyl dichlorosilane, accounting for 90% of the total weight of the back coating;
  • the auxiliary agent is platinum chloric acid, which accounts for 10% of the total weight of the back coating;
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is t-butyl phenolic resin, which accounts for 36% of the total weight of the color layer; the pigment is selected from Lisol, which accounts for 31% of the total weight of the color layer; the talc is used as the filler, accounting for 33% of the total weight of the color layer; Xylene is used as a solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 60% of the total weight of the connecting layer, and perchloroethylene resin accounts for 25% of the total weight of the connecting layer;
  • OP wax is used as the filling material, accounting for 13.7% of the total weight of the connecting layer;
  • step d drying temperature in step d is 60 ° C, xylene: butanone
  • the back coat is made of a binder and an adjuvant.
  • the back coating material is selected from methyltrichlorosilane, which accounts for 90% of the total weight of the back coating; the auxiliary agent uses methylhydrogensiloxane, which accounts for 10% of the total weight of the back coating; and gasoline is used as a solvent.
  • the release layer is made of a binder and an auxiliary.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is phenol formaldehyde resin, which accounts for 40% of the total color of the color layer; the pigment is made of benzidine, which accounts for 30% of the total weight of the color layer; the talc powder is used for the filler, which accounts for 30% of the total weight of the color layer; xylene is used as the solvent.
  • the tie layer is made of binder, pigment and filler.
  • the connecting layer connecting material is EVA resin and perchloroethylene resin.
  • the EVA resin accounts for 60% of the total weight of the joint layer, and the perchloroethylene resin accounts for 25% of the total weight of the joint layer.
  • the filler is made of OP wax, which accounts for 13.4% of the total weight of the joint layer.
  • Step a the drying temperature is 90 ° C, the thickness of the back coating is 0.3 ⁇
  • the strip base is a 5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is
  • the digital banner printing ribbon consists of a belt base and a back coating and a thermal transfer layer applied to both sides of the belt base.
  • the thermal transfer layer is divided into three parts, and the surface of the belt base is in turn from the inside to the outside. It is a detachment layer, a color layer, and a tie layer.
  • the back coat is made of a binder and an adjuvant.
  • the back coating material is phenyl siloxane, which accounts for 90% of the total weight of the back coating; the auxin is platinum chloric acid, which accounts for 10% of the total weight of the back coating; ⁇ uses gasoline as a solvent.
  • the release layer is made of a binder and an auxiliary.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is selected from rosin modified phenolic resin, which accounts for 40% of the total weight of the color layer; the pigment is selected from phthalocyanine blue, which accounts for 30% of the total weight of the color layer; the talc powder is used as the filler, accounting for 30% of the total weight of the color layer; As a solvent.
  • the tape base is a biaxially stretched PET film having a thickness of 5 ⁇ m, and the total thickness of the digital strip printing ribbon is 37.9 ⁇ m.
  • the digital banner print ribbon consists of a tape base and a back coat and thermal transfer layer applied to both sides of the tape base.
  • the thermal transfer layer is divided into three parts, and the surface of one side of the tape base is a release layer, a color layer, and a connection layer from the inside to the outside.
  • the back coat is made of a binder and an auxiliary.
  • the back coating material is phenyltrichlorosilane, which accounts for 90% of the total weight of the back coating; the platinum chloric acid is used as the auxiliary agent, which accounts for 10% of the total weight of the back coating;
  • the release layer is made of a binder and an adjuvant.
  • the color layer is made of binders, fillers and auxiliaries.
  • the color layer binder is selected from tert-butyl phenolic resin, which accounts for 40% of the total weight of the color layer; the pigment is selected from phthalocyanine green, accounting for 30% of the total weight of the color layer; the talc powder is used as the filler, accounting for 30% of the total weight of the color layer; As a solvent.
  • the tie layer is made of binder, pigment and filler.
  • EVA resin and perchloroethylene resin are used as the connecting layer connecting material, EVA resin accounts for 60% of the total weight of the connecting layer, and perchloroethylene resin accounts for 25% of the total weight of the connecting layer;
  • OP wax is selected for the filling material, which accounts for 13.2% of the total weight of the connecting layer;
  • Step a the drying temperature is 85 ° C, the thickness of the back coating is 0.5 ⁇
  • the thickness of the tie layer is ⁇ ; the other is the same as in the embodiment 1.
  • the strip base is a 5 ⁇ thick biaxially oriented PET film, and the total thickness of the digital strip printing ribbon is

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Description

说明书 一种数码条幅打印碳带及其制备方法
[1] 技术领域
[2] 本发明属于烫印材料技术领域， 具体涉及一种数码条幅打印碳带及其制备方法
[3] 背景技术
[4] 目前， 国内条幅制作工艺有手工刻绘制作条幅、 丝网印刷条幅和热转印条幅。
这几种方法的共同点是需要根据要求制造出条幅信息的轮廓， 然后再刻板或裁 剪字模， 最后再处理到条幅上做成成品。 这几种条幅制作工艺不仅复杂而且条 幅制作设计受限， 设备投资多， 生产速度慢， 成本高， 丝网印刷还对条幅制作 的批量有限制。 因此， 如何实现一次性打印即成条幅成品显然已是迫在眉睫、 亟待解决的问题。 为了能够实现一次性打印即成条幅成品， 与之相关的数码条 幅打印碳带及其制备方法技术的研究无疑是非常必要和迫切的。 但是迄今为止 ， 还未见有数码条幅打印碳带及其制备方法的相关报道。
[5] 发明内容
[6] 为克服现有技术的不足之处， 本发明的目的是提供一种设计合理、 制备方法简 便、 易于推广应用的数码条幅打印碳带及其制备方法。
[7] 本发明通过以下技术方案来实现上述目的：
[8] —种数码条幅打印碳带， 由带基和分别涂布于带基两侧的背涂层和热转印层构 成， 所述热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色 层、 连结层。
[9] 进一步地， 所述背涂层由下述重量百分比的原料制成： 连结料 80~90%， 助剂
10-20%； 所述脱离层由下述重量百分比的原料制成： 连结料 93~97%， 助剂 3-7%； 所述颜色层由下述重量百分比的原料制成： 连结料 20~40%， 颜料 30-45% , 填料 30~35%； 所述连结层由下述重量百分比的原料制成： 连结料 75-85%， 填充料 13~23%， 助剂 1~2%。
[10] 进一步地， 所述背涂层中， 连结料为有机硅树脂， 助剂为有机硅填充料； 所述 脱离层中， 连结料为改性丙烯酸聚氨酯树脂， 助剂为氯化石蜡蜡浆； 所述颜色 层中， 连结料为酚醛树脂， 颜料不作限制， 可以为白色、 红色、 黄色、 蓝色、 绿色等， 填料为滑石粉； 所述连结层中， 连结料为 EVA树脂和过氯乙烯树脂， 两者占连结层总重量百分比分别为 EVA树脂 55~60%和过氯乙烯树脂 20~25% ， 填充料为 OP蜡， 助剂为钛酸酯类表面活性剂。
[11] 进一步地， 背涂层中， 有机硅树脂为苯基三氯硅垸、 二苯基二氯硅垸、 甲基三 氯硅垸或苯基硅氧垸， 有机硅填充料为甲基氢硅氧垸或铂氯酸； 脱离层中， 改 性丙烯酸聚氨酯树脂为聚氨酯二丙烯酸酯、 聚氨酯三丙烯酸酯、 聚氨酯四丙烯 酸酯或聚氨酯六丙烯酸酯； 颜色层中， 酚醛树脂为松香改性酚醛树脂、 苯酚甲 醛树脂、 叔丁基苯酚甲醛树脂； 连结层中， 钛酸酯类表面活性剂为十二垸基苯 磺酰钛酸酯、 三异硬脂酰基钛酸异丙酯、 异丙基三油酰基钛酸酯或异丙氧基三 异辛酰基钛酸酯； 带基为高强度聚酯薄膜。
[12] 较好地， 带基优选为双向拉伸 PET膜。
[13] —种数码条幅打印碳带的制备方法， 包括以下步骤：
[14] a、 用汽油将按比例称取的背涂层的连结料和助剂稀释混合均匀后， 涂布在带 基一侧表面， 烘干形成背涂层进入到下一工序；
[15] b、 用丁酮和丁酯将按比例称取的脱离层的连结料和助剂稀释混合均匀后， 涂 布在带基另外一侧表面， 烘干形成脱离层进入到下一工序；
[16] c、 用二甲苯将按比例称取的颜色层的连结料、 颜料和填料稀释混合均匀、 研 磨后， 涂布于脱离层外面， 烘干形成颜色层进入到下一工序；
[17] d、 用二甲苯和丁酮将按比例称取的连结层中的连结料、 填充料和助剂稀释混 合均匀， 涂布在颜色层的外面， 烘干即形成本发明所述的数码条幅打印碳带。
[18] 进一步地， 步骤 a中： 先用汽油将连结料稀释混合均匀后， 然后在使用前 30 分钟内按比例加入助剂混合均匀； 步骤 b中： 首先用丁酮和丁酯将脱离层的连结 料溶解， 然后再按比例加入助剂混合均匀； 步骤 c中： 首先用二甲苯将酚醛树脂 溶解， 再按比例加入填料和颜料进行研磨； 步骤 d中： 用二甲苯和丁酮将连结层 中的连结料溶解， 然后再按比例加入填充料和助剂， 混合均匀形成连结层涂布 液。 [19] 再进一步地， 步骤 c中， 研磨之后， 颜料细度小于 5μηι; 步骤 d中， 连结层涂布 液在 25°C条件下， 黏度为 14~16秒。
[20] 再进一步地， 步骤 a中烘干温度为
80~100°C, 背涂层厚度 0.2~0.5μηι; 步骤 b中烘干温度为 60~80°C， 脱离层厚度 1~3 μηΐ; 步骤 c中烘干温度为 80~100°C， 颜色层厚度 8~20μηι; 步骤 d中烘干温度为 40 ~60°C, 连结层厚度 4~10μηι; 带基厚度 4~6μηι， 数码条幅打印碳带的总厚度为 17. 2~39·5μηι。
[21] 更进一步地， 步骤 a中按重量比计， 汽油的用量为汽油： 连结料 =9 : 1； 步骤 b中按重量比计， 丁酮和丁酯的总用量为丁酮-丁酯： 连结料 =5 : 1， 而丁酮- 丁酯中， 丁酮： 丁酯 =3~4： 1； 步骤 c中按重量比计， 二甲苯的用量为二甲苯： 酚醛树脂 =5 : 1； 步骤 d中按重量比计， 二甲苯和丁酮的总用量为二甲苯- 丁酮： 连结料 =5: 1， 且二甲苯-丁酮中， 二甲苯： 丁酮 =3~4： 1。
[22] 本发明数码条幅打印碳带设计合理， 制备方法简便、 易于推广应用。 釆用本发 明技术方案制成的数码条幅打印碳带， 经条幅碳带打印机可将脱离层、 颜色层 和连结层转印到条幅材料上， 实现条幅的一次性制作。 本发明革新了传统条幅 制作的复杂工艺， 不但使得条幅制作更加简单快捷、 经济高效， 而且满足了电 脑设计打印即成品的数字化、 个性化设计要求。
[23] 具体实施方式：
[24] 以下以具体实施例来说明本发明的技术方案， 但本发明的保护范围并不局限于 此：
[25] 实施例 1
[26] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[27] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基三氯硅垸， 占背涂层总重 80%； 助剂选用甲基氢硅氧垸， 占背涂层总重 20% ; 釆用汽油作为溶剂。
[28] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯二丙烯酸酯， 占脱离层 总重 93% ; 助剂选用氯化石蜡蜡浆， 占脱离层总重 7% ; 釆用混合的丁酮： 丁酯 = 4:1作为溶剂。
[29] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用松香改性酚醛树脂， 占颜色层总重 20%; 颜料选用钛白粉， 占颜色层总重 45%; 填料选用滑石粉， 占颜色层总重 35%; 釆用二甲苯作为溶剂。
[30] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂' EVA
树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 20%; 填充料选用 OP 蜡， 占连结层总重 23%; 助剂选用十二垸基苯磺酰钛酸酯， 占连结层总重 2%; 釆用混合的二甲苯：丁酮 = 3:1作为溶剂。
[31] 数码条幅打印碳带的制备方法：
a、 用汽油将连结料稀释混合均匀后， 在试用前 30分钟内加入助剂混合均匀， 然 后涂在带基一侧表面， 在 91°C的温度下烘干形成背涂层， 要求该层厚度 0.4μηι， 之后进入到下一工序； 其中按重量比计， 汽油的用量为汽油： 连结料 =9 : 1；
[32] b、 首先用丁酮-丁酯将脱离层的连结料溶解， 然后再按比例加入助剂混合均匀 ， 然后涂在带基另外一侧表面， 在 80°C的温度下烘干形成脱离层， 要求该层厚度 2.0μηι， 之后进入到下一工序； 其中按重量比计， 丁酮和丁酯的总用量为丁酮-丁 酯： 连结料 =5 : 1， 而丁酮-丁酯中， 丁酮： 丁酯 =4 : 1；
[33] c、 首先用二甲苯将酚醛树脂溶解， 再按比例加入填料和颜料经充分研磨制成 颜色层涂布液， 要求颜料要分散均匀、 细度小于 5μηι， 再涂于脱离层外面， 经 80 °C的温度下烘干形成颜色层， 要求该层厚度 14μηι， 保证色彩鲜艳干净； 其中按 重量比计， 二甲苯的用量为二甲苯： 酚醛树脂 =5: 1；
[34] d、 用二甲苯 -丁酮将连结层中的连结料溶解， 然后再按比例加入填充料和助剂 充分混合均匀， 形成在 25°C条件下黏度为 14~16秒、 均匀稳定的连结层涂布液， 然后涂在颜色层的外面， 经 60°C的温度下彻底烘干， 使该层厚度为 6μηι， 在常温 下成固态坚韧膜； 按重量比计， 二甲苯和丁酮的总用量为二甲苯-丁酮： 连结料 =5 ： 1， 且二甲苯-丁酮中， 二甲苯： 丁酮
=3： 1； 此吋即形成本发明所述的数码条幅打印碳带。
[35] 本实施例中， 带基为 4μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为 26.4μηι。
[36] 实施例 2
[37] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[38] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基三氯硅垸， 占背涂层总重 80%； 助剂选用铂氯酸， 占背涂层总重 20%; 釆用汽油作为溶剂。
[39] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯三丙烯酸酯， 占脱离层 总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的丁酮： 丁酯 = 3 :1作为溶剂。
[40] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用松香改性酚醛树脂， 占颜色层总重 20%; 颜料选用永固红， 占颜色层总重 45%; 填料选用滑石粉， 占颜色层总重 35%; 釆用二甲苯作为溶剂。
[41] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 20%; 填充料选 用 OP蜡， 占连结层总重 23%; 助剂选用十二垸基苯磺酰钛酸酯， 占连结层总重 2 %; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[42] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 80 °C， 背涂层厚度
0.2μηι； 步骤 b中烘干温度为 60 °C， 丁酮： 丁酯 =3: 1， 脱离层厚度 Ιμηι; 步骤 c中烘干温度为 80 °C， 颜色层厚度 8μηι ; 步骤 d中烘干温度为
40°C, 二甲苯： 丁酮 =4 : 1， 连结层厚度 4.0μηι; 其它均同实施例 1 。
[43] 本实施例中， 带基为 4μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为 17.2μηι。
[44] 实施例 3
[45] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[46] 背涂层由连结料和助剂制成。 背涂层连结料选用二苯基二氯硅垸， 占背涂层总 重 81%; 助剂选用铂氯酸， 占背涂层总重 19%; 釆用汽油作为溶剂。
[47] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯四丙烯酸酯， 占脱离层 总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的丁酮： 丁酯 = 3.5 :1作为溶剂。
[48] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用苯酚甲醛树脂， 占颜 色层总重 30%; 颜料选用铬黄， 占颜色层总重 40%; 填料选用滑石粉， 占颜色 层总重 30%; 釆用二甲苯作为溶剂。
[49] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 20%; 填充料选 用 OP蜡， 占连结层总重 23%; 助剂选用十二垸基苯磺酰钛酸酯， 占连结层总重 2
%; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[50] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 81 °C， 背涂层厚度
0.5μηι； 步骤 b中烘干温度为 60 °C， 丁酮： 丁酯 =3.5 ： 1
， 脱离层厚度 3μηι; 步骤 c中烘干温度为 100 °C， 颜色层厚度 20μηι； 步骤 d 中烘干温度为 60°C， 二甲苯： 丁酮 =4 : 1， 连结层厚度 ΙΟμηι
； 其它均同实施例 1 。
[51] 本实施例中， 带基为 6μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
39.5μηι。
[52] 实施例 4
[53] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[54] 背涂层由连结料和助剂制成。 背涂层连结料选用甲基三氯硅垸， 占背涂层总重 82%； 助剂选用甲基氢硅氧垸， 占背涂层总重 18%; 釆用汽油作为溶剂。
[55] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯六丙烯酸酯，
占脱离层总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的丁 酮：丁酯 = 4 :1作为溶剂。
[56] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用叔丁基甲醛树脂， 占 颜色层总重 30%; 颜料选用酞箐蓝， 占颜色层总重 40%; 填料选用滑石粉， 占 颜色层总重 30%; 釆用二甲苯作为溶剂。
[57] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 25%; 填充料选 用 OP蜡， 占连结层总重 18.2%; 助剂选用十二垸基苯磺酰钛酸酯， 占连结层总 重 1.8%; 釆用混合的二甲苯：丁酮 = 3.2 :1作为溶剂。
[58] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 80 °C， 背涂层厚度
0.5μηι； 步骤 b中烘干温度为 80 °C， 丁酮： 丁酯 =4： 1
， 脱离层厚度 1.5μηι; 步骤 c中烘干温度为 90°C， 颜色层厚度 15μηι; 步骤 d中烘干 温度为 43°C， 二甲苯： 丁酮 =3.2: 1， 连结层厚度 8μηι; 其它均同实施例 1 。
[59] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为 30μηι。
[60] 实施例 5
[61] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[62] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基硅氧垸， 占背涂层总重 83 %; 助剂选用甲基氢硅氧垸， 占背涂层总重 17%; 釆用汽油作为溶剂。
[63] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯二丙烯酸酯， 占脱离层 总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的丁酮:丁酯= 4 :1作为溶剂。
[64] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用松香改性酚醛树脂， 占颜色层总重 33%; 颜料选用酞箐绿， 占颜色层总重 35%; 填料选用滑石粉， 占颜色层总重 32%; 釆用二甲苯作为溶剂。
[65] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 25%; 填充料选 用 OP蜡， 占连结层总重 18.5%; 助剂选用十二垸基苯磺酰钛酸酯， 占连结层总 重 1.5%; 釆用混合的二甲苯：丁酮 = 3.4 :1作为溶剂。 [66] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 88 °C， 背涂层厚度 0.3μηι； 步骤 b中烘干温度为 63°C， 丁酮： 丁酯
=4： 1， 脱离层厚度 2.7μηι; 步骤 c中烘干温度为 83°C， 颜色层厚度 ΙΟμηι; 步骤 d 中烘干温度为 46°C， 二甲苯： 丁酮 =3.4
： 1， 连结层厚度 ΙΟμηι; 其它均同实施例 1 。
[67] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
28μηι。
[68] 实施例 6
[69] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[70] 背涂层由连结料和助剂制成。 背涂层连结料选用甲基三氯硅垸， 占背涂层总重 84%； 助剂选用甲基氢硅氧垸， 占背涂层总重 16%; 釆用汽油作为溶剂。
[71] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯三丙烯酸酯， 占脱离层 总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的丁酮： 丁酯 = 3.2 :1作为溶剂。
[72] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用苯酚甲醛树脂， 占颜 色层总重 20%; 颜料选用锌钡白， 占颜色层总重 45%; 填料选用滑石粉， 占颜 色层总重 35%; 釆用二甲苯作为溶剂。
[73] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 20%; 填充料选 用 OP蜡， 占连结层总重 23%; 助剂选用十二垸基苯磺酰钛酸酯， 占连结层总重 2 %; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[74] 数码条幅打印碳带的制备方法中： 步骤 a
中烘干温度为 80°C， 背涂层厚度 0.5μηι ; 步骤 b中烘干温度为 60
°C， 丁酮： 丁酯 =3.2 : 1， 脱离层厚度 Ιμηι; 步骤 c中烘干温度为 80
°C， 颜色层厚度 13.5μηι ; 步骤 d中烘干温度为 46 °C， 二甲苯： 丁酮 =4： 1
， 连结层厚度 5μηι; 其它均同实施例 1 。 [75] 本实施例中， 带基为 4.5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度 为 24·5μιη。
[76] 实施例 7
[77] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[78] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基三氯硅垸， 占背涂层总重 85%； 助剂选用铂氯酸， 占背涂层总重 15%; 釆用汽油作为溶剂。
[79] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯二丙烯酸酯， 占脱离层 总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的丁酮： 丁酯 = 4 :1作为溶剂。
[80] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用苯酚甲醛树脂， 占颜 色层总重 30%; 颜料选用立索尔大红
， 占颜色层总重 40%; 填料选用滑石粉， 占颜色层总重 30%; 釆用二甲苯作为 溶剂。
[81] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 20%; 填充料选 用 OP蜡， 占连结层总重 23%;
助剂选用三异硬脂酰基钛酸异丙酯， 占连结层总重 2%; 釆用混合的二甲苯： 丁酮 = 3.8 :1作为溶剂。
[82] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 82°C， 背涂层厚度 0.4μηι
； 步骤 b中烘干温度为 70°C， 丁酮： 丁酯 =4 : 1， 脱离层厚度 1.6μηι; 步骤 c 中烘干温度为 80°C， 颜色层厚度 18μηι; 步骤 d中烘干温度为 55°C， 二甲苯： 丁酮
=3.8 ： 1， 连结层厚度 4μηι; 其它均同实施例 1 。
[83] 本实施例中， 带基为 4.5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度 为 28.5μηι。
[84] 实施例 8
[85] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[86] 背涂层由连结料和助剂制成。 背涂层连结料选用二苯基二氯硅垸， 占背涂层总 重 86%; 助剂选用铂氯酸， 占背涂层总重 14%; 釆用汽油作为溶剂。
[87] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯四丙烯酸酯， 占脱离层 总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的丁酮： 丁酯 = 3.8 :1作为溶剂。
[88] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用松香改性酚醛树脂， 占颜色层总重 30%; 颜料选用永固黄， 占颜色层总重 40%; 填料选用滑石粉， 占颜色层总重 30%; 釆用二甲苯作为溶剂。
[89] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 25%; 填充料选 用 OP蜡， 占连结层总重 19%;
助剂选用三异硬脂酰基钛酸异丙酯， 占连结层总重 1%; 釆用混合的二甲苯： 丁酮 = 4 :1作为溶剂。
[90] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 96°C， 背涂层厚度 0.3μηι
； 步骤 b中烘干温度为 73 °C， 丁酮： 丁酯 =3.8 : 1， 脱离层厚度 2.2μηι ; 步骤 c中烘干温度为 89 °C， 颜色层厚度 10.5μηι ; 步骤 d
中烘干温度为 50°C， 二甲苯： 丁酮 =4 : 1
， 连结层厚度 7.7μηι; 其它均同实施例 1 。
[91] 本实施例中， 带基为 6μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
26.7μηι。
[92] 实施例 9
[93] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热 转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结层
[94] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基硅氧垸， 占背涂层总重 87 %; 助剂选用铂氯酸， 占背涂层总重 13%; 釆用汽油作为溶剂。 [95] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯六丙烯酸酯， 占脱离层 总重 93%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 7%; 釆用混合的丁酮： 丁酯 = 4 :1作为溶剂。
[96] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用叔丁基甲醛树脂， 占 颜色层总重 20%; 颜料选用铁兰， 占颜色层总重 45%; 填料选用滑石粉， 占颜 色层总重 35%; 釆用二甲苯作为溶剂。
[97] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 20%; 填充料选 用 OP蜡， 占连结层总重 23%; 助剂选用三异硬脂酰基钛酸异丙酯， 占连结层总 重 2%; 釆用混合的二甲苯：丁酮 = 3.7 :1作为溶剂。
[98] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 80 °C， 背涂层厚度
0.4μηι； 步骤 b中烘干温度为 63 °C， 丁酮： 丁酯 =4: 1， 脱离层厚度 2μηι; 步骤 c中烘干温度为 83 °C， 颜色层厚度 9μηι
； 步骤 d中烘干温度为 42°C， 二甲苯： 丁酮 =3.7
： 1， 连结层厚度 6μηι; 其它均同实施例 1 。
[99] 本实施例中， 带基为 4μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
21.4μηι。
[100] 实施例 10
[101] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[102] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基硅氧垸， 占背涂层总重 88
%; 助剂选用甲基氢硅氧垸， 占背涂层总重 12%; 釆用汽油作为溶剂。
[103] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯三丙烯酸酯
， 占脱离层总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的 丁酮：丁酯 = 3.3 :1作为溶剂。
[104] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用松香改性酚醛树脂， 占颜色层总重 20%; 颜料选用铬绿， 占颜色层总重 45%; 填料选用滑石粉， 占 颜色层总重 35%; 釆用二甲苯作为溶剂。
[105] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 20%; 填充料选 用 OP蜡， 占连结层总重 23%;
助剂选用三异硬脂酰基钛酸异丙酯， 占连结层总重 2%; 釆用混合的二甲苯： 丁酮 = 3.6 :1作为溶剂。
[106] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 93°C， 背涂层厚度 0.3μηι
； 步骤 b中烘干温度为 63°C， 丁酮： 丁酯 =3.3 : 1， 脱离层厚度 1.8μηι; 步骤 c 中烘干温度为 90°C， 颜色层厚度 15.3μηι ; 步骤 d
中烘干温度为 56°C， 二甲苯： 丁酮 =3.6
： 1， 连结层厚度 6.8μηι; 其它均同实施例 1 。
[107] 本实施例中， 带基为 4μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
28.2μηι。
[108] 实施例 11
[109] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[110] 背涂层由连结料和助剂制成。 背涂层连结料选用二苯基二氯硅垸， 占背涂层总 重 89%; 助剂选用甲基氢硅氧垸， 占背涂层总重 11%; 釆用汽油作为溶剂。
[111] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯六丙烯酸酯
， 占脱离层总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的 丁酮：丁酯 = 4 :1作为溶剂。
[112] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用苯酚甲醛树脂， 占颜 色层总重 30%; 颜料选用氧化锌， 占颜色层总重 40%; 填料选用滑石粉， 占颜 色层总重 30%; 釆用二甲苯作为溶剂。
[113] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 55% , 过氯乙烯树脂占连结层总重 20%; 填充料选 用 OP蜡， 占连结层总重 23%; 助剂选用三异硬脂酰基钛酸异丙酯， 占连结层总重 2%; 釆用混合的二甲苯： 丁酮 = 4 :1作为溶剂。
[114] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 80°C， 背涂层厚度 0.5μηι
； 步骤 b中烘干温度为 80 °C， 丁酮： 丁酯 =4 : 1， 脱离层厚度 Ιμηι ; 步骤 c 中烘干温度为 82 °C， 颜色层厚度 9μηι
； 步骤 d中烘干温度为 60°C， 二甲苯： 丁酮 =4
： 1， 连结层厚度 4.7μηι; 其它均同实施例 1 。
[115] 本实施例中， 带基为 4.5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度 为 19·7μηι。
[116] 实例 12
[117] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[118] 背涂层由连结料和助剂制成。 背涂层连结料选用甲基三氯硅垸， 占背涂层总重
90%； 助剂选用甲基氢硅氧垸， 占背涂层总重 10%; 釆用汽油作为溶剂。
[119] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯二丙烯酸酯
， 占脱离层总重 95%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 5%; 釆用混合的 丁酮：丁酯 = 4 :1作为溶剂。
[120] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用叔丁基甲醛树脂， 占 颜色层总重 30%; 颜料选用立索尔紫红， 占颜色层总重 40%; 填料选用滑石粉
， 占颜色层总重 30%; 釆用二甲苯作为溶剂。
[121] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 57% , 过氯乙烯树脂占连结层总重 23%; 填充料选 用 OP蜡， 占连结层总重 18.3%; 助剂选用异丙基三油酰基钛酸酯， 占连结层总 重 1.7%; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[122] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 83 °C， 背涂层厚度
0.4μηι； 步骤 b中烘干温度为 68 °C， 丁酮： 丁酯 =4: 1， 脱离层厚度 Ιμηι; 步骤 c中烘干温度为 85 °C， 颜色层厚度 9.9μηι; 步骤 d 中烘干温度为 53°C， 二甲苯： 丁酮 =4 : 1， 连结层厚度 4.5μηι; 其它均同实施例
1
[123] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
20.8μηι。
[124] 实例 13
[125] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[126] 背涂层由连结料和助剂制成。 背涂层连结料选用二苯基二氯硅垸， 占背涂层总 重 90%; 助剂选用甲基氢硅氧垸， 占背涂层总重 10%; 釆用汽油作为溶剂。
[127] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯三丙烯酸酯， 占脱离层 总重 94%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 6%; 釆用混合的丁酮： 丁酯 = 4 :1作为溶剂。
[128] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用松香改性酚醛
树脂， 占颜色层总重 30%; 颜料选用荧光黄， 占颜色层总重 38%; 填料选用滑 石粉， 占颜色层总重 32%; 釆用二甲苯作为溶剂。
[129] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 56% , 过氯乙烯树脂占连结层总重 24%; 填充料选 用 OP蜡， 占连结层总重 18.8%; 助剂选用异丙氧基三异辛酰基钛酸酯， 占连结 层总重 1.2%; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[130] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 100 °C， 背涂层厚度
0.2μηι； 步骤 b中烘干温度为 80 °C， 丁酮： 丁酯 =4: 1， 脱离层厚度 Ιμηι; 步骤 c中烘干温度为 100 °C， 颜色层厚度 Ι ΐμηι ; 步骤 d
中烘干温度为 60°C， 二甲苯： 丁酮 =4 : 1， 连结层厚度 4μηι; 其它均同实施例
1
[131] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为 2
1·2μπι。
[132] 实例 14 [133] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[134] 背涂层由连结料和助剂制成。 背涂层连结料选用甲基三氯硅垸， 占背涂层总重 90%； 助剂选用铂氯酸， 占背涂层总重 10%; 釆用汽油作为溶剂。
[135] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯三丙烯酸酯， 占脱离层 总重 97%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 3%; 釆用混合的丁酮： 丁酯 = 4 :1作为溶剂。
[136] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用叔丁基酚醛树脂， 占 颜色层总重 25%; 颜料选用钴兰， 占颜色层总重 42%; 填料选用滑石粉， 占颜色层总重 33%; 釆用二甲苯作为溶剂。
[137] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 59% , 过氯乙烯树脂占连结层总重 21%; 填充料选 用 OP蜡， 占连结层总重 18.7%; 助剂选用异丙氧基三异辛酰基钛酸酯， 占连结 层总重 1.3%; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[138] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 80°C， 背涂层厚度 0.2μηι
； 步骤 b中烘干温度为 60°C， 丁酮： 丁酯 =4 : 1， 脱离层厚度 1.5μηι; 步骤 c 中烘干温度为 80
°C， 颜色层厚度 12.3μηι; 步骤 d中烘干温度为 40°C， 二甲苯： 丁酮 =4： 1
， 连结层厚度 6μηι; 其它均同实施例 1 。
[139] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
25μηι。
[140] 实例 15
[141] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热 转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结层
[142] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基硅氧垸， 占背涂层总重 90 %; 助剂选用铂氯酸， 占背涂层总重 10%; 釆用汽油作为溶剂。 [143] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯四丙烯酸酯， 占脱离层 总重 97%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 3%; 釆用混合的丁酮： 丁酯 = 3.7 :1作为溶剂。
[144] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用苯酚甲醛树脂， 占颜 色层总重 40%; 颜料选用荧光绿， 占颜色层总重 30%; 填料选用滑石粉， 占颜 色层总重 30%; 釆用二甲苯作为溶剂。
[145] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 58%
， 过氯乙烯树脂占连结层总重 22%; 填充料选用 OP蜡， 占连结层总重 18.9%; 助剂选用异丙基三油酰基钛酸酯， 占连结层总重 1.1%; 釆用混合的二甲苯： 丁酮 = 4 :1作为溶剂。
[146] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 92°C， 背涂层厚度 0.2μηι
； 步骤 b中烘干温度为 63 °C， 丁酮： 丁酯 =3.7 : 1， 脱离层厚度 1.5μηι; 步骤 c 中烘干温度为 88 °C， 颜色层厚度 15.3μηι
； 步骤 d中烘干温度为 56°C， 二甲苯： 丁酮
=4： 1， 连结层厚度 8.4μηι; 其它均同实施例 1 。
[147] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
30.4μηι。
[148] 实例 16
[149] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热 转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结层
[150] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基三氯硅垸， 占背涂层总重 90%； 助剂选用铂氯酸， 占背涂层总重 10%; 釆用汽油作为溶剂。
[151] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯六丙烯酸酯， 占脱离层 总重 96%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 4%; 釆用混合的丁酮： 丁酯 = 4 :1作为溶剂。
[152] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用叔丁基酚醛树脂， 占 颜色层总重 40%; 颜料选用钛白粉， 占颜色层总重 30%; 填料选用滑石粉， 占 颜色层总重 30%; 釆用二甲苯作为溶剂。
[153] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 60% , 过氯乙烯树脂占连结层总重 20%; 填充料选 用 OP蜡， 占连结层总重 18%; 助剂选用异丙氧基三异辛酰基钛酸酯
， 占连结层总重 2%; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[154] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 85°C， 背涂层厚度 0.4μηι
； 步骤 b中烘干温度为 65 °C， 丁酮： 丁酯 =4 : 1， 脱离层厚度 1.7μηι; 步骤 c 中烘干温度为 86
°C， 颜色层厚度 14.5μηι; 步骤 d中烘干温度为 45°C， 二甲苯： 丁酮
=4： 1， 连结层厚度 9.3μηι; 其它均同实施例 1 。
[155] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
30.9μηι。
[156] 实例 17
[157] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热 转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结层
[158] 背涂层由连结料和助剂制成。 背涂层连结料选用二苯基二氯硅垸， 占背涂层总 重 90%; 助剂选用铂氯酸， 占背涂层总重 10%; 釆用汽油作为溶剂。
[159] 脱离层由连结料和助剂制成。
脱离层连结料选用聚氨酯二丙烯酸酯， 占脱离层总重 97%; 助剂选用氯化石蜡 蜡浆， 占脱离层总重 3%; 釆用混合的丁酮：丁酯 = 4 :1作为溶剂。
[160] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用叔丁基酚醛树脂， 占 颜色层总重 36%; 颜料选用立索尔宝红， 占颜色层总重 31%; 填料选用滑石粉 ， 占颜色层总重 33%; 釆用二甲苯作为溶剂。
[161] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 60% , 过氯乙烯树脂占连结层总重 25%; 填充料选 用 OP蜡， 占连结层总重 13.7%; 助剂选用三异硬脂酰基钛酸异丙酯， 占连结层 总重 1.3%; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[162] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 80°C， 背涂层厚度 0.5μηι ； 步骤 b中烘干温度为 70°C， 丁酮： 丁酯 =4 : 1， 脱离层厚度 2.6μηι; 步骤 c 中烘干温度为 100
°C， 颜色层厚度 17.3μηι; 步骤 d中烘干温度为 60°C， 二甲苯： 丁酮
=4： 1， 连结层厚度 9.1μηι; 其它均同实施例 1 。
[163] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
34.5μηι。
[164] 实例 18
[165] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[166] 背涂层由连结料和助剂制成。 背涂层连结料选用甲基三氯硅垸， 占背涂层总重 90%； 助剂选用甲基氢硅氧垸， 占背涂层总重 10%; 釆用汽油作为溶剂。
[167] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯二丙烯酸酯， 占脱离层 总重 97%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 3%; 釆用混合的丁酮： 丁酯 = 3 :1作为溶剂。
[168] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用苯酚甲醛树脂， 占颜 色层总重 40%; 颜料选用联苯胺， 占颜色层总重 30%; 填料选用滑石粉， 占颜 色层总重 30%; 釆用二甲苯作为溶剂。
[169] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 60% , 过氯乙烯树脂占连结层总重 25%; 填充料选 用 OP蜡， 占连结层总重 13.4%; 助剂选用异丙基三油酰基钛酸酯， 占连结层总 重 1.6%; 釆用混合的二甲苯：丁酮 = 4 :1作为溶剂。
[170] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 90°C， 背涂层厚度 0.3μηι
； 步骤 b中烘干温度为 60 °C， 丁酮： 丁酯 =3 : 1， 脱离层厚度 2.5μηι; 步骤 c 中烘干温度为 80 °C， 颜色层厚度 17μηι
； 步骤 d中烘干温度为 50°C， 二甲苯： 丁酮 =4： 1， 连结层厚度 9.2μηι; 其它均同实施例 1 。
[171] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
34μηι。
[172] 实例 19
[173] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[174] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基硅氧垸， 占背涂层总重 90 %; 助剂选用铂氯酸， 占背涂层总重 10%; 釆用汽油作为溶剂。
[175] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯二丙烯酸酯， 占脱离层 总重 97%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 3%; 釆用混合的丁酮:丁酯= 3 :1作为溶剂。
[176] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用松香改性酚醛树脂， 占颜色层总重 40%; 颜料选用酞菁蓝， 占颜色层总重 30%; 填料选用滑石粉， 占颜色层总重 30%; 釆用二甲苯作为溶剂。
[177] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 60% , 过氯乙烯树脂占连结层总重 25%; 填充料选 用 OP蜡， 占连结层总重 13%;
助剂选用异丙氧基三异辛酰基钛酸酯， 占连结层总重 2%; 釆用混合的二甲苯： 丁酮 = 3 :1作为溶剂。
[178] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 100°C， 背涂层厚度 0.2μ m; 步骤 b中烘干温度为 80°C， 丁酮： 丁酯 =3 : 1， 脱离层厚度 2.7μηι; 步骤 c 中烘干温度为 90°C， 颜色层厚度 20μηι; 步骤 d中烘干温度为 52°C， 二甲苯： 丁酮 =3： 1， 连结层厚度 ΙΟμηι; 其它均同实施例 1 。
[179] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为 37.9μηι。
[180] 实例 20
[181] 数码条幅打印碳带由带基和分别涂布于带基两侧的背涂层和热转印层构成， 热转印层分为三部分， 由带基一侧表面自内向外依次为脱离层、 颜色层、 连结 层。
[182] 背涂层由连结料和助剂制成。 背涂层连结料选用苯基三氯硅垸， 占背涂层总重 90%； 助剂选用铂氯酸， 占背涂层总重 10%; 釆用汽油作为溶剂。
[183] 脱离层由连结料和助剂制成。 脱离层连结料选用聚氨酯二丙烯酸酯， 占脱离层 总重 97%; 助剂选用氯化石蜡蜡浆， 占脱离层总重 3%; 釆用混合的丁酮： 丁酯 = 4 :1作为溶剂。
[184] 颜色层由连结料、 填充料和助剂制成。 颜色层连结料选用叔丁基酚醛树脂， 占 颜色层总重 40%; 颜料选用酞菁绿， 占颜色层总重 30%; 填料选用滑石粉， 占 颜色层总重 30%; 釆用二甲苯作为溶剂。
[185] 连结层由连结料、 颜料和填料制成。 连结层连结料选用 EVA树脂和过氯乙烯树 脂， EVA树脂占连结层总重 60% , 过氯乙烯树脂占连结层总重 25%; 填充料选 用 OP蜡， 占连结层总重 13.2%;
助剂选用十二垸基苯磺酰钛酸酯， 占连结层总重 1.8%; 釆用混合的二甲苯： 丁酮 = 3 :1作为溶剂。
[186] 数码条幅打印碳带的制备方法中： 步骤 a中烘干温度为 85°C， 背涂层厚度 0.5μηι
； 步骤 b中烘干温度为 75 °C， 丁酮： 丁酯 =4 : 1， 脱离层厚度 2.8μηι; 步骤 c 中烘干温度为 93 °C， 颜色层厚度 20μηι
； 步骤 d中烘干温度为 50°C， 二甲苯： 丁酮 =3 : 1
， 连结层厚度 ΙΟμηι; 其它均同实施例 1 。
[187] 本实施例中， 带基为 5μηι厚的双向拉伸 PET膜， 数码条幅打印碳带的总厚度为
38.3μπι。

Claims

权利要求书
[1] 一种数码条幅打印碳带， 其特征在于： 由带基和分别涂布于带基两侧的背 涂层和热转印层构成， 所述热转印层分为三部分， 由带基一侧表面自内向 外依次为脱离层、 颜色层、 连结层。
[2] 根据权利要求 1所述的数码条幅打印碳带， 其特征在于： 所述背涂层由下述 重量百分比的原料制成： 连结料 80~90%， 助剂 10~20%； 所述脱离层由下 述重量百分比的原料制成： 连结料 93~97%， 助剂 3~7%； 所述颜色层由下 述重量百分比的原料制成： 连结料 20~40%， 颜料 30~45%， 填料 30~35%； 所述连结层由下述重量百分比的原料制成： 连结料 75~85%
， 填充料 13~23%， 助剂 1~2%。
[3] 根据权利要求 2所述的数码条幅打印碳带， 其特征在于： 所述背涂层中， 连 结料为有机硅树脂， 助剂为有机硅填充料； 所述脱离层中， 连结料为改性 丙烯酸聚氨酯树脂， 助剂为氯化石蜡蜡浆； 所述颜色层中， 连结料为酚醛 树脂， 填料为滑石粉； 所述连结层中， 连结料为 EVA树脂和过氯乙烯树脂 ， 两者占连结层总重量百分比分别为 EVA树脂 55~60%和过氯乙烯树脂 20~2 5% , 填充料为 OP蜡， 助剂为钛酸酯类表面活性剂。
[4] 根据权利要求 3所述的数码条幅打印碳带， 其特征在于： 背涂层中， 有机硅 树脂为苯基三氯硅垸、 二苯基二氯硅垸、 甲基三氯硅垸或苯基硅氧垸， 有 机硅填充料为甲基氢硅氧垸或铂氯酸； 脱离层中， 改性丙烯酸聚氨酯树脂 为聚氨酯二丙烯酸酯、 聚氨酯三丙烯酸酯、 聚氨酯四丙烯酸酯或聚氨酯六 丙烯酸酯； 颜色层中， 酚醛树脂为松香改性酚醛树脂、 苯酚甲醛树脂、 叔 丁基苯酚甲醛树脂； 连结层中， 钛酸酯类表面活性剂为十二垸基苯磺酰钛 酸酯、 三异硬脂酰基钛酸异丙酯、 异丙基三油酰基钛酸酯或异丙氧基三异 辛酰基钛酸酯； 带基为高强度聚酯薄膜。
[5] 根据权利要求 1-4任一所述的数码条幅打印碳带， 其特征在于： 所述带基为 双向拉伸 PET膜。
[6] 一种数码条幅打印碳带的制备方法， 其特征在于包括以下步骤：
a、 用汽油将按比例称取的背涂层的连结料和助剂稀释混合均匀后， 涂布在 带基一侧表面， 烘干形成背涂层进入到下一工序， 所述背涂层中以重量百 分比计： 连结料 80~90%， 助剂 10~20%；
b、 用丁酮和丁酯将按比例称取的脱离层的连结料和助剂稀释混合均匀后， 涂布在带基另外一侧表面， 烘干形成脱离层进入到下一工序， 所述脱离层 中以重量百分比计： 连结料 93~97%， 助剂 3~7%；
c、 用二甲苯将按比例称取的颜色层的连结料、 颜料和填料稀释混合均匀、 研磨后， 涂布于脱离层外面， 烘干形成颜色层进入到下一工序， 所述颜色 层中以重量百分比计： 连结料 20~40%， 颜料 30~45%， 填料 30~35%； d、 用二甲苯和丁酮将按比例称取的连结层中的连结料、 填充料和助剂稀释 混合均匀， 涂布在颜色层的外面， 烘干即形成本发明所述的数码条幅打印 碳带， 所述连结层中以重量百分比计： 连结料 75~85%， 填充料 13~23%
， 助剂 1~2%。
[7] 根据权利要求 6所述的数码条幅打印碳带的制备方法， 其特征在于： 步骤 a 中： 所述背涂层中， 连结料为有机硅树脂， 助剂为有机硅填充料； 所述脱 离层中， 连结料为改性丙烯酸聚氨酯树脂， 助剂为氯化石蜡蜡浆； 所述颜 色层中， 连结料为酚醛树脂， 填料为滑石粉； 所述连结层中， 连结料为 EV A树脂和过氯乙烯树脂， 两者占连结层总重量百分比分别为 EVA树脂 55~60 %和过氯乙烯树脂 20~25%， 填充料为 OP蜡， 助剂为钛酸酯类表面活性剂。
[8] 根据权利要求 7所述的数码条幅打印碳带的制备方法， 其特征在于： 背涂层 中， 有机硅树脂为苯基三氯硅垸、 二苯基二氯硅垸、 甲基三氯硅垸或苯基 硅氧垸， 有机硅填充料为甲基氢硅氧垸或铂氯酸； 脱离层中， 改性丙烯酸 聚氨酯树脂为聚氨酯二丙烯酸酯、 聚氨酯三丙烯酸酯、 聚氨酯四丙烯酸酯 或聚氨酯六丙烯酸酯； 颜色层中， 酚醛树脂为松香改性酚醛树脂、 苯酚甲 醛树脂、 叔丁基苯酚甲醛树脂； 连结层中， 钛酸酯类表面活性剂为十二垸 基苯磺酰钛酸酯、 三异硬脂酰基钛酸异丙酯、 异丙基三油酰基钛酸酯或异 丙氧基三异辛酰基钛酸酯； 带基为高强度聚酯薄膜。
[9] 根据权利要求 8所述的数码条幅打印碳带， 其特征在于： 高强度聚酯薄膜为 双向拉伸 PET膜。
[10] 根据权利要求 6~9之任意一项所述的数码条幅打印碳带的制备方法， 其特征 在于： 步骤 a中按重量比计， 汽油的用量为汽油： 连结料 =9: 1； 步骤 b中按 重量比计， 丁酮和丁酯的总用量为丁酮-丁酯： 连结料
=5： 1， 而丁酮-丁酯中， 丁酮： 丁酯 =3~4： 1； 步骤 c中按重量比计， 二甲 苯的用量为二甲苯： 酚醛树脂 =5: 1； 步骤 d中按重量比计， 二甲苯和丁酮 的总用量为二甲苯-丁酮： 连结料 =5: 1， 且二甲苯-丁酮中， 二甲苯： 丁酮 =3-4： 1。
[11] 根据权利要求 10所述的数码条幅打印碳带的制备方法， 其特征在于： 步骤 a 中： 先用汽油将连结料稀释混合均匀后， 然后在使用前 30分钟内按比例加 入助剂混合均匀； 步骤 b中： 首先用丁酮和丁酯将脱离层的连结料溶解， 然 后再按比例加入助剂混合均匀； 步骤 c中： 首先用二甲苯将酚醛树脂溶解， 再按比例加入填料和颜料进行研磨； 步骤 d中： 用二甲苯和丁酮将连结层中 的连结料溶解， 然后再按比例加入填充料和助剂， 混合均匀形成连结层涂 布液。
[12] 根据权利要求 11所述的数码条幅打印碳带的制备方法， 其特征在于： 步骤 c 中， 研磨之后， 颜料细度小于 5μηι; 步骤 d中， 连结层涂布液在 25°C条件下 ， 黏度为 14~16秒。
[13] 根据权利要求 12所述的数码条幅打印碳带的制备方法， 其特征在于： 步骤 a 中烘干温度为 80~100°C， 背涂层厚度 0.2~0.5μηι; 步骤 b中烘干温度为 60~80 °C， 脱离层厚度 1~3μηι; 步骤 c中烘干温度为 80~100°C， 颜色层厚度 8~20μηι ； 步骤 d中烘干温度为 40~60°C， 连结层厚度 4~10μηι; 带基厚度 4~6μηι， 数 码条幅打印碳带的总厚度为 17.2~39.5μηι。
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